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Dual-porosity model for harmonic pulse testing in fractured geothermal reservoir 裂缝性地热储层谐波脉冲测试双孔隙度模型
IF 7.6 Q1 ENERGY & FUELS Pub Date : 2026-01-28 DOI: 10.1016/j.ecmx.2026.101624
Peter A. Fokker , Eloisa Salina Borello , Francesca Verga , Dario Viberti
Well testing and conventional Pressure Transient Analysis (PTA) are fundamental and well-established methodologies for characterizing well and reservoir parameters. However, the applicability of PTA is limited during production or injection operations, since it requires a shut-in of the tested well, and it is significantly affected by interferences from neighboring wells.
In previous works, we proposed, implemented, and validated against real data a methodology called Harmonic Pulse Testing (HPT). HPT is complementary to PTA. By specifically deploying the periodicity of rate and pressure signals, it has been designed to be applied during ongoing field operations.
In this work, we present a new analytical solution for HPT in naturally fractured reservoirs. The proposed solution is also applied to geothermal systems, as it is coupled with a radial composite model capable of approximating the thermal front. The model has been validated against well-established analytical and numerical models under different scenarios. The calculation steps for converting the numerical dual-porosity model into storativity ratio and inter-porosity flow coefficient are also provided.
The results of a validation exercise demonstrate that our model is robust against potential interference from other wells and allows the detection of the thermal front. The methodology can therefore be successfully applied during ongoing operations in naturally fractured geothermal reservoirs.
试井和常规压力瞬变分析(PTA)是表征井和储层参数的基本和成熟的方法。然而,在生产或注入作业中,PTA的适用性受到限制,因为它需要关井,并且受邻近井干扰的影响很大。在以前的工作中,我们提出、实现并验证了一种称为谐波脉冲测试(HPT)的方法。HPT是PTA的补充。通过特别部署周期性的速率和压力信号,它被设计用于正在进行的现场作业。在这项工作中,我们提出了一种新的分析方法,用于天然裂缝性储层的高温高压测试。所提出的解决方案也适用于地热系统,因为它与能够近似热锋的径向复合模型相结合。该模型已在不同情景下对已建立的解析和数值模型进行了验证。给出了将双孔隙度数值模型转化为储气比和孔隙间流动系数的计算步骤。验证结果表明,我们的模型对来自其他井的潜在干扰具有鲁棒性,并且可以检测热锋。因此,该方法可以成功地应用于自然裂缝性地热储层的持续作业中。
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引用次数: 0
Passively-tuned roll-based wave energy converter for enhanced efficiency and frequency adaptability 无源调谐卷波能量转换器,提高效率和频率适应性
IF 7.6 Q1 ENERGY & FUELS Pub Date : 2026-01-28 DOI: 10.1016/j.ecmx.2026.101575
Ruben J. Paredes , David Plaza , Raju Datla , Mijail Arias-Hidalgo , Paul S. Zambrano , Jose R. Marin-Lopez , Jose M. Ahumada , Ricardo Álvarez-Briceño , Rafael Soria , Wilson Guachamin-Acero , Jesus Portilla-Yandun , Muhammad R. Hajj
Wave Energy Converters (WECs) typically exhibit natural oscillation frequencies that are significantly higher than the dominant frequencies of ocean waves, limiting their energy capture efficiency. Unlike conventional designs that rely on complex active control systems to address this mismatch, this study investigates a passive alternative based on inverted cone-shaped submerged structures that entrap seawater during upward motion, thereby increasing the effective added mass, lowering the natural frequency, and enabling resonance tuning of a roll-based WEC. Building on previous numerical validation, we present results from tests on a 1:40-scale model in regular and irregular waves. Five configurations with varying cone size and suspension distance were evaluated under regular wave excitation. The configuration achieving the highest performance reached a maximum Capture Width Ratio (CWR) of 52%, exceeding the 20%–40% range typical of conventional WECs. To assess robustness under realistic conditions, that configuration was further tested in irregular wave spectra representative of swell-dominated seas. Even under random excitation, the tuned device maintained efficiencies above 20%, demonstrating robustness against spectral variability. The experimental results show close agreement with predictions from a linear analytical model and confirm that passive tuning via cone-shaped structures effectively broadens the resonance bandwidth of roll-harvesting WECs. By combining high efficiency, robustness, and structural simplicity, this low-cost, scalable approach addresses a long-standing limitation of WECs and provides a viable pathway toward full-scale deployment with integrated power take-off damping and adaptation to diverse wave climates.
波浪能量转换器(WECs)通常表现出明显高于海浪主导频率的自然振荡频率,限制了它们的能量捕获效率。与传统设计依靠复杂的主动控制系统来解决这种不匹配的问题不同,本研究研究了一种基于倒锥形水下结构的被动替代方案,该结构在向上运动过程中捕获海水,从而增加了有效的附加质量,降低了固有频率,并实现了基于滚动的WEC的共振调谐。在先前的数值验证的基础上,我们提出了在规则和不规则波的1:40比例模型上进行测试的结果。在规则波激励下,对不同锥体尺寸和悬浮距离的五种构型进行了评价。实现最高性能的配置达到了52%的最大捕获宽度比(CWR),超过了传统WECs典型的20%-40%范围。为了评估在现实条件下的稳健性,该配置在代表汹涌主导的海洋的不规则波浪谱中进一步进行了测试。即使在随机激励下,调谐器件的效率也保持在20%以上,显示出对光谱变异性的鲁棒性。实验结果与线性分析模型的预测结果非常吻合,并证实了通过锥形结构进行被动调谐可以有效地拓宽滚收WECs的共振带宽。通过结合高效率、鲁棒性和结构简单性,这种低成本、可扩展的方法解决了WECs长期存在的局限性,并为全面部署提供了可行的途径,具有集成的功率输出阻尼和适应不同的波浪气候。
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引用次数: 0
Leveraging renewable energy for mitigating greenhouse gas emissions in Iran 利用可再生能源减少伊朗的温室气体排放
IF 7.6 Q1 ENERGY & FUELS Pub Date : 2026-01-28 DOI: 10.1016/j.ecmx.2026.101632
Mahdi Jahandideh , Ali Mahmoudi , Saman Rashidi , Mohammad Sadegh Valipour , Saadat Zirak
The global challenge of dealing climate change and decreasing greenhouse gas emissions has prompted countries to explore effective methods, such as the utilization of renewable energy resources, which have lower emissions. This study investigates the potentials, and current situations for reducing greenhouse gas emissions through renewable energy resources in Iran. This study examines Iran’s energy consumption patterns, greenhouse gas emission profiles, and the present state and policies of renewable energy development by looking at both national energy data and foreign case studies. Key findings reveal that Iran reduced approximately 696,000 tons of CO2 emissions in 2018 and saved 286 million m3 of fossil fuel in power plants. Iran’s installed renewable energy capacity as of 2021 was estimated to be 11,929 MW. Also, the increase of 7500 MW of renewable capacity by 2023 was targeted by the Ministry of Energy of Iran. In this regard, Iran is committed to a 4% greenhouse gas reduction by 2050, compared to 2010 levels. Also, considering that 560 million tons of CO2 were produced in 2010, Iran committed to reducing 22.4 million tons. The study emphasizes how important it is to have supportive government policies, to invest in RE infrastructure, particularly in solar and wind energy, and the importance of strategic investment, supportive regulations, and international cooperation in advancing Iran’s transition toward a low-carbon economy.
应对气候变化和减少温室气体排放的全球性挑战促使各国探索有效的方法,例如利用排放较低的可再生能源。本研究调查了伊朗利用可再生能源减少温室气体排放的潜力和现状。本研究通过查阅国家能源数据和国外案例研究,考察了伊朗的能源消费模式、温室气体排放概况以及可再生能源发展的现状和政策。主要调查结果显示,伊朗在2018年减少了约69.6万吨二氧化碳排放量,并在发电厂节省了2.86亿立方米的化石燃料。截至2021年,伊朗的可再生能源装机容量估计为11,929兆瓦。此外,伊朗能源部的目标是到2023年增加7500兆瓦的可再生能源容量。在这方面,伊朗承诺到2050年将温室气体排放量在2010年的基础上减少4%。此外,考虑到2010年产生了5.6亿吨二氧化碳,伊朗承诺减少2240万吨。这份研究报告强调了制定支持性政府政策,投资可再生能源基础设施,特别是太阳能和风能的重要性,以及战略投资、支持性法规和国际合作对推动伊朗向低碳经济转型的重要性。
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引用次数: 0
Design and Performance Analysis of a Hybrid Solar-Wind Tree System with IoT based Real-Time Monitoring in Bangladesh 孟加拉国基于物联网实时监测的混合太阳能风树系统设计与性能分析
IF 7.6 Q1 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1016/j.ecmx.2026.101566
Arman Jahan Eva, Al Amin, Md Nasir Uddin, Tamim Ahmed, Abu Anas Nasim, Md Sahadat Hossain Sani, Md Shamsul Arefin
The global transition toward renewable energy has intensified interest in hybrid energy solutions that combine solar and wind power to enhance sustainability and reliability. Several studies have examined such integrated systems, however, most existing designs remain expensive, visually unsuitable for public spaces, and lack real-time monitoring or optimization capabilities, particularly in developing nations such as Bangladesh. Despite Bangladesh’s favorable solar irradiance and moderate wind potential, rural and urban public areas lack an efficient, decorative, and smart energy infrastructure. To address this gap, we propose a novel IoT-enabled hybrid solar wind energy tree tailored for public and rural settings in Bangladesh. Unlike conventional solutions, our proposed design integrates both energy sources into a visually appealing and self-sustaining structure capable of live monitoring and remote management. The system uses low-cost hardware (Arduino Nano, ESP8266, INA226 sensors) and simulation tools (COMSOL Multiphysics for structural integrity, HOMER Pro for cost analysis and MATLAB Simulink for performance modeling) using MPPT. A prototype was implemented for economic evaluation under site-specific conditions in Rajbari, Bangladesh (23°40.8′N, 89°31.3′E) demonstrating a Levelized Cost of Energy (LCOE) $0.11/kWh to $0.18/kWh for a single unit, which is approximately 50% lower than a standalone solar system. The community-scale configuration achieved a daily energy generation of up to 165 kWh under optimal conditions with an LCOE of $0.2997/kWh. This integrated solution offers a scalable, cost-effective, and environmentally friendly pathway to decentralized energy access in developing regions.
随着全球向可再生能源的转变,人们对结合太阳能和风能以提高可持续性和可靠性的混合能源解决方案的兴趣日益浓厚。然而,大多数现有的设计仍然昂贵,视觉上不适合公共空间,缺乏实时监控或优化能力,特别是在孟加拉国等发展中国家。尽管孟加拉国拥有良好的太阳辐照度和中等风力潜力,但农村和城市公共区域缺乏高效、美观和智能的能源基础设施。为了解决这一差距,我们提出了一种为孟加拉国公共和农村环境量身定制的新型物联网混合太阳能风能树。与传统解决方案不同,我们提出的设计将两种能源整合到一个具有视觉吸引力和自我维持能力的结构中,能够实时监控和远程管理。该系统采用低成本硬件(Arduino Nano, ESP8266, INA226传感器)和仿真工具(COMSOL Multiphysics用于结构完整性,HOMER Pro用于成本分析,MATLAB Simulink用于性能建模),使用MPPT。在孟加拉国Rajbari(23°40.8'N, 89°31.3'E)的特定条件下实施了一个原型进行经济评估,表明单个单元的平准化能源成本(LCOE)为0.11美元/千瓦时至0.18美元/千瓦时,比独立太阳能系统低约50%。在最佳条件下,社区规模的配置实现了高达165千瓦时的日发电量,LCOE为0.2997美元/千瓦时。这一综合解决方案为发展中地区的分散式能源获取提供了一条可扩展、具有成本效益和环境友好的途径。
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引用次数: 0
The transition to sustainable aviation fuel: insights from patent analysis and policy implications 向可持续航空燃料的过渡:来自专利分析和政策影响的见解
IF 7.6 Q1 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1016/j.ecmx.2026.101634
Qiuyan Xu, Greig Mordue
The aviation industry has committed to achieving net zero carbon emissions by 2050, with sustainable aviation fuel (SAF) identified as the most promising solution. The transition to SAF is mainly influenced by technological advancements, production capacities, and policy incentives. However, the rapidly evolving and diverse nature of SAF technologies complicates the landscape, resulting in a lack of value chain transparency and difficulties in understanding regional patterns in the SAF transition. This study addresses these challenges by constructing and analyzing a global database of SAF-related patents to examine SAF technology development trends, regional differences in innovation and patenting activities, the distribution of SAF technology domains, and key players in the supply chain. The analysis reveals regional disparities in innovation ecosystems and gaps in policy design while providing insights into the roles of stakeholders across the SAF value chain. Informed by these findings, the study makes policy recommendations aimed at addressing regional disparities, harmonizing SAF mandates, and aligning production with market dynamics, thereby supporting the sustainable decarbonization of aviation systems.
航空业已承诺到2050年实现净零碳排放,可持续航空燃料(SAF)被认为是最有希望的解决方案。向SAF的过渡主要受到技术进步、生产能力和政策激励的影响。然而,SAF技术的快速发展和多样性使环境变得复杂,导致价值链缺乏透明度,并且难以理解SAF转型中的区域模式。本研究通过构建和分析SAF相关专利的全球数据库来研究SAF技术的发展趋势、创新和专利活动的区域差异、SAF技术领域的分布以及供应链中的关键参与者,从而解决这些挑战。该分析揭示了创新生态系统的区域差异和政策设计方面的差距,同时提供了对SAF价值链中利益相关者作用的见解。根据这些发现,该研究提出了政策建议,旨在解决区域差异,协调SAF任务,使生产与市场动态保持一致,从而支持航空系统的可持续脱碳。
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引用次数: 0
A thermodynamically consistent simulation of gas hydrates in porous media using Operator-Based Linearization 基于算子线性化的多孔介质中天然气水合物热力学一致性模拟
IF 7.6 Q1 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1016/j.ecmx.2026.101616
Michiel Wapperom , Sadegh M. Taghinejad , Xiaocong Lyu , Rouhi Farajzadeh , Denis Voskov
In this work, we present a kinetic simulation model for gas hydrates in porous media using the Operator-Based Linearization (OBL) technique. The OBL approach introduces algebraic operators that represent the physical terms in the mass and energy balance equations. Operators are calculated only in supporting points comprising the discretized parameter space, and operator values and partial derivatives for linear system assembly are readily obtained through (multi-)linear interpolation. Taking advantage of this setup, the implementation of advanced thermodynamic models for hydrate formation and dissociation under kinetic assumptions is simplified. We test the assumptions for thermodynamic modelling by analysing the Gibbs energy surfaces of the fluid and hydrate phases and demonstrate that, in the limit, the thermodynamic equilibrium for both kinetic and equilibrium reaction models is equivalent. We compare the simulation results with the published experimental results for CH4-hydrates and extend the assessment to a CO2-hydrate formation experiment in a semi-batch, constant-pressure configuration. The model reproduces the main pressure–temperature transients and hydrate evolution for both CH4- and CO2-systems. We demonstrate applicability at core scale for hydrate formation and, at field scale, for gas production from CH4-hydrates by thermal stimulation and depressurization. The interaction of thermal-compositional phenomena (phase changes, adiabatic expansion, kinetic rates, and reaction enthalpy) gives rise to highly nonlinear physics that an appropriate OBL discretization resolves. Overall, the patterns of hydrate formation and dissociation are highly sensitive to the kinetic-rate inputs; hence, the appropriate choice of the reaction model remains a key consideration from both physical and numerical perspectives.
在这项工作中,我们采用基于算子的线性化(OBL)技术建立了多孔介质中天然气水合物的动力学模拟模型。OBL方法引入了表示质量和能量平衡方程中的物理项的代数算子。算子只在构成离散化参数空间的支撑点上计算,通过(多次)线性插值很容易得到线性系统装配的算子值和偏导数。利用这一设置,简化了在动力学假设下水合物形成和解离的高级热力学模型的实现。我们通过分析流体和水合物相的吉布斯能面来检验热力学建模的假设,并证明,在极限情况下,动力学和平衡反应模型的热力学平衡是等效的。我们将模拟结果与已发表的ch4水合物实验结果进行了比较,并将评估扩展到半批定压配置下的co2水合物形成实验。该模型重现了CH4-和co2系统的主要压力-温度瞬态和水合物演化过程。我们证明了在岩心规模上水合物形成的适用性,以及在油田规模上通过热增产和降压从ch4水合物中开采天然气的适用性。热组成现象(相变、绝热膨胀、动力学速率和反应焓)的相互作用产生了高度非线性的物理现象,适当的OBL离散化可以解决这一问题。总的来说,水合物形成和解离模式对动力学速率输入高度敏感;因此,从物理和数值角度来看,反应模型的适当选择仍然是一个关键的考虑因素。
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引用次数: 0
Comparative optimization and exergy analysis of solar–LNG integrated Rankine cycles among different hot tank outlet temperatures 不同热罐出口温度下太阳能- lng集成朗肯循环对比优化及火用分析
IF 7.6 Q1 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1016/j.ecmx.2026.101609
Han Zhang, Huiming Mao
With solar energy playing an increasingly crucial role in the worldwide shift toward renewable resources, a comparative two-objective optimization is performed on a two-tank solar field integrated with an organic Rankine cycle (ORC) and liquefied natural gas under three hot tank outlet temperatures of 200 C, 250 C, and 300 C. Optimization objectives include maximizing the system efficiency and minimizing the electricity production cost (EPC). The comprehensive optimization includes 8 variables, 11 working fluids, and 16 structures, with the results analyzed using the thermodynamic weight. Detailed analysis is further performed on two representative scenarios: the Equal Scenario and the Thermodynamic Scenario. The findings show that the R-ORC is preferred when thermodynamic considerations are the primary focus, whereas the B-ORC is more beneficial when the economic aspect is the main priority. At a hot tank outlet temperature of 300 C, the Equal Scenario attains 97.81% of the Thermodynamic Scenario‘s system efficiency while reducing EPC by as much as 9.35%. This result demonstrates that a slight sacrifice in thermodynamic performance could yield notable economic improvements. The condenser exhibits the highest exergy loss fraction among all components.
随着太阳能在世界范围内向可再生资源的转变中发挥越来越重要的作用,我们在200°C、250°C和300°C三种热罐出口温度下,对一个结合有机朗肯循环(ORC)和液化天然气的双罐太阳能场进行了比较双目标优化。优化目标包括系统效率最大化和电力生产成本(EPC)最小化。综合优化包括8个变量、11种工质、16种结构,并利用热力学权重对优化结果进行了分析。进一步详细分析了两种具有代表性的情景:等量情景和热力情景。研究结果表明,当热力学方面的考虑是首要考虑时,R-ORC是首选,而当经济方面是主要优先考虑时,B-ORC更有利。在300°C的热罐出口温度下,等效方案的系统效率达到了热力学方案的97.81%,同时减少了9.35%的总消失温度。这一结果表明,热力学性能的轻微牺牲可以产生显着的经济改进。在所有部件中,冷凝器的火用损失比例最高。
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引用次数: 0
Flying green: Life cycle assessment and decomposition of bio-based sustainable aviation fuels production in Australia and global benchmarks 绿色飞行:澳大利亚和全球基准生物基可持续航空燃料生产的生命周期评估和分解
IF 7.6 Q1 ENERGY & FUELS Pub Date : 2026-01-26 DOI: 10.1016/j.ecmx.2026.101625
Xueting Jiang , Aditi Mankad , Walter Okelo
Sustainable aviation fuels (SAF) are critical for sustainably transitioning the aviation sector into low-carbon status depending on the type of feedstock and technology. However, studies on the key factors that drive these environmental benefits, and the effect of emerging technologies such as biomanufacturing would have on SAF production in the future are limited. Consequently, we assessed the environmental impact of bio-based SAF production and investigated the key drivers of its carbon footprint (greenhouse gas emissions), focusing on Hydroprocessed Esters and Fatty Acids (HEFA), Alcohol-to-Jet (AtJ), and Fischer-Tropsch (FT) pathways. Using Australia as a case study alongside a global benchmark, this study decomposed the life-cycle carbon footprint of SAF production into carbon intensity, energy efficiency, scalability, cost competitiveness, and industry size factors. Results reveal that the energy efficiency factor significantly reduces the SAF production carbon footprint across all three pathways. The scalability factor was a dominant challenge that greatly influenced the carbon footprint of SAF production across global scenarios, especially for HEFA and AtJ, while for Australia the effects of the scalability factor were smaller though remain a noticeable challenge for AtJ. The decomposition results in Australia resemble mostly the high- and very high- SAF production scenarios globally. Results of a sensitivity analysis suggest that biomanufacturing potentially enhances emission reductions for various SAF feedstocks in both Australia and globally, particularly for oilseed-based pathways in Australia.
根据原料类型和技术的不同,可持续航空燃料(SAF)对于航空业可持续地向低碳转型至关重要。然而,关于驱动这些环境效益的关键因素的研究,以及生物制造等新兴技术对未来SAF生产的影响都是有限的。因此,我们评估了生物基SAF生产的环境影响,并研究了其碳足迹(温室气体排放)的关键驱动因素,重点关注加氢酯和脂肪酸(HEFA)、醇制喷气(AtJ)和费托合成(FT)途径。本研究以澳大利亚为例,结合全球基准,将SAF生产的生命周期碳足迹分解为碳强度、能源效率、可扩展性、成本竞争力和行业规模等因素。结果表明,能源效率因素显著降低了所有三种途径的SAF生产碳足迹。可扩展性因素是一个主要的挑战,它在全球范围内极大地影响了SAF生产的碳足迹,特别是对于HEFA和AtJ,而对于澳大利亚,可扩展性因素的影响较小,但对AtJ来说仍然是一个明显的挑战。澳大利亚的分解结果与全球SAF产量高和非常高的情况大致相似。敏感性分析的结果表明,生物制造可能会增加澳大利亚和全球各种SAF原料的减排,特别是澳大利亚的油籽基途径。
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引用次数: 0
Economic and management evaluation of vehicle-mounted photovoltaic–battery systems in electric vehicles under urban operating conditions 城市工况下电动汽车车载光伏电池系统经济性与管理评价
IF 7.6 Q1 ENERGY & FUELS Pub Date : 2026-01-26 DOI: 10.1016/j.ecmx.2026.101628
Junfeng Niu , Nesrine Gafsi , Pooya Ghodratallah , Rabeb Younes , Mohamed Shaban , Narinderjit Singh Sawaran Singh , Amina Hamdouni
The rapid electrification of transportation demands intelligent coordination among heterogeneous energy subsystems within electric vehicles. This research establishes an analytics-driven management framework that unites photovoltaic generation, high-energy–density lithium-ion storage, and auxiliary fuel-cell support to achieve a balanced, sustainable, and economically viable propulsion system. Focusing on an urban case study in Xi’an, China, the model integrates real-time meteorological inputs and vehicle-operation data to dynamically regulate energy flows between PV modules and battery packs. A hybrid optimization layer couples techno-economic modeling with management-level decision analytics, allowing simultaneous assessment of power efficiency, operational scheduling, and lifecycle cost performance. Results show that the coordinated PV–battery strategy enhances driving range up to 61% while lowering equivalent energy cost and mitigating peak-load stress on urban charging infrastructure. Beyond the technical gains, the framework demonstrates how data-enabled decision mechanisms can inform managerial planning for fleet electrification and urban energy resilience. The study provides actionable insights for policymakers and industry practitioners seeking integrated strategies to strengthen the economic, environmental, and managerial dimensions of electric mobility, directly supporting the United Nations Sustainable Development Goal 7 on affordable and clean energy.
交通运输的快速电气化要求电动汽车内部异构能源子系统之间的智能协调。本研究建立了一个分析驱动的管理框架,将光伏发电、高能量密度锂离子存储和辅助燃料电池支持结合起来,实现平衡、可持续和经济可行的推进系统。该模型以中国西安的城市为例,整合了实时气象输入和车辆运行数据,以动态调节光伏模块和电池组之间的能量流动。混合优化层将技术经济建模与管理层决策分析相结合,允许同时评估功率效率、操作调度和生命周期成本绩效。研究结果表明,在降低等效能源成本和缓解城市充电基础设施峰值负荷压力的同时,电动汽车的续驶里程提高了61%。除了技术进步之外,该框架还展示了数据驱动的决策机制如何为车队电气化和城市能源弹性的管理规划提供信息。该研究为寻求综合战略以加强电动交通的经济、环境和管理层面的政策制定者和行业从业者提供了可操作的见解,直接支持联合国可持续发展目标7关于负担得起的清洁能源。
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引用次数: 0
Facile synthesis of 2D Mo2TiC2@PDA/MnO2 composite-based electrode material for clean and efficient energy storage 用于清洁高效储能的二维Mo2TiC2@PDA/MnO2复合电极材料的简易合成
IF 7.6 Q1 ENERGY & FUELS Pub Date : 2026-01-25 DOI: 10.1016/j.ecmx.2026.101620
Md. Romzan Ali , Asif Iqbal , Abir Hassan Talukder , Md. Abdul Khaleque , Md. Ruhul Amin , Md. Ismail Hossain , Sakibul Islam , Md. Ikram Hossain , Md. Rafiul Hasan , Mohamed Aly Saad Aly , Ghada E. Khedr , Florian J. Stadler , Md. Zaved Hossain Khan
Owing to their distinctive stacked layered structure, exceptional conductivity, large specific surface area, and abundance of redox active sites, two-dimensional transition carbon nitride, and metal carbides and nitrides efficiently store and transfer charges, thus becoming attractive electrode materials for supercapacitors. MXene-based supercapacitors are, however, seriously hindered by the low specific capacitance driven by severe self-discharge behavior and poor ambient stability due to oxidation. To overcome these limitations, herein, a Mo2TiC2@PDA/MnO2 composite was synthesized to functionalize a glassy carbon electrode (GCE) surface via a two-layer modification strategy, which enabled faster charge transfer and ion diffusion within the electrode material, thus boosting the capacitive performance of Mo2TiC2 MXene. The composite’s structure and morphology were confirmed by X-ray diffraction, transmission electron microscopy, and scanning electron microscopy. Furthermore, the electrochemical behavior of the functionalized-electrodes was assessed by galvanostatic charge–discharge (GCD), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS), which all revealed that Mo2TiC2@PDA/MnO2 can be a promising electrode material for supercapacitor. The Mo2TiC2@PDA/MnO2 modified electrode delivered a high specific capacitance of 573 Fg−1 at a current density of 1 Ag−1 and demonstrated superior cycling stability with 87.43% capacitance retention over 5000 cycles. This study shows that integrating Mo2TiC2, PDA, and MnO2 can significantly improve the capacitance, stability, and eco-friendly operation in supercapacitors. However, the current work does not evaluate the performance in portable or flexible devices, and future studies may address this limitation through full-cell assembly and real-world testing. Overall, the composite provides a strong foundation for next-generation energy storage applications.
由于其独特的堆叠层状结构、优异的导电性、大的比表面积和丰富的氧化还原活性位点,二维过渡碳氮化物、金属碳化物和氮化物能够有效地存储和转移电荷,从而成为超级电容器极具吸引力的材料。然而,严重的自放电行为和氧化导致的低比电容严重阻碍了基于mxene的超级电容器的发展。为了克服这些限制,本文合成了Mo2TiC2@PDA/MnO2复合材料,通过两层修饰策略对玻璃碳电极(GCE)表面进行功能化,使电极材料内的电荷转移和离子扩散更快,从而提高了Mo2TiC2 MXene的电容性能。通过x射线衍射、透射电镜和扫描电镜对复合材料的结构和形貌进行了表征。此外,通过恒流充放电(GCD)、循环伏安(CV)和电化学阻抗谱(EIS)对功能化电极的电化学行为进行了评估,结果表明Mo2TiC2@PDA/MnO2是一种很有前途的超级电容器电极材料。Mo2TiC2@PDA/MnO2修饰电极在1 Ag−1电流密度下具有573 Fg−1的高比电容,在5000次循环中具有87.43%的电容保持率。本研究表明,将Mo2TiC2、PDA和MnO2集成在一起,可以显著提高超级电容器的电容、稳定性和环保性能。然而,目前的工作并没有评估便携式或柔性设备的性能,未来的研究可能会通过全单元组装和实际测试来解决这一限制。总的来说,这种复合材料为下一代储能应用提供了坚实的基础。
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Energy Conversion and Management-X
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