Pub Date : 2024-08-22DOI: 10.1016/j.ecmx.2024.100692
Marie E. Kirby , Trisha Toop , Miloud Ouadi , Lesley McEvoy , Christine Rolin , Rhiannon Inkster , Philip W. Dyer , Michael K. Theodorou
Marine macroalgae is a biomass resource for the manufacture of fuels and chemicals, which can be sustainably harvested from seaweed farms or from man-made structures where it accumulates as a biofouling organism. However, in temperate regions farmed macroalgae can only be harvested between late Spring and early Summer, limiting year-round availability. Here we show that a conventional grass ensilage procedure preserves Saccharina latissima dominated biomass on the tonne scale for 30 months, enabling year-round use of this biomass. Following processing, the resulting dried and pelletised ensiled macroalgae material was subject to Thermo-Catalytic Reforming™, comprising sequential pyrolysis (450 °C) and either dry or steam catalytic reforming (700 °C) processes. Both processing methods produced a mixture of bio-oil (1.6–1.9 wt%) and hydrogen-rich permanent gases (30.9–31.1 wt%) with higher heating values of 34.8–35.4 MJ/kg and 18.0–24.2 MJ/m3, respectively, together with char (45.5–48.5 % wt). The permanent gases can be used directly for heat generation, while hydro-treatment of the bio-oil would afford a material that can be blended with traditional transport fuels. This work demonstrates that if operated at scale, the combined harvesting, ensilaging and Thermo-Catalytic Reforming™ of preserved macroalgal biomass offers a year-round decentralised energy resource.
{"title":"Thermo-catalytic reforming pyrolysis of ensiled Saccharina latissima dominated macroalgal pellets for bioenergy production","authors":"Marie E. Kirby , Trisha Toop , Miloud Ouadi , Lesley McEvoy , Christine Rolin , Rhiannon Inkster , Philip W. Dyer , Michael K. Theodorou","doi":"10.1016/j.ecmx.2024.100692","DOIUrl":"10.1016/j.ecmx.2024.100692","url":null,"abstract":"<div><p>Marine macroalgae is a biomass resource for the manufacture of fuels and chemicals, which can be sustainably harvested from seaweed farms or from man-made structures where it accumulates as a biofouling organism. However, in temperate regions farmed macroalgae can only be harvested between late Spring and early Summer, limiting year-round availability. Here we show that a conventional grass ensilage procedure preserves <em>Saccharina latissima</em> dominated biomass on the tonne scale for 30 months, enabling year-round use of this biomass. Following processing, the resulting dried and pelletised ensiled macroalgae material was subject to Thermo-Catalytic Reforming™, comprising sequential pyrolysis (450 °C) and either dry or steam catalytic reforming (700 °C) processes. Both processing methods produced a mixture of bio-oil (1.6–1.9 wt%) and hydrogen-rich permanent gases (30.9–31.1 wt%) with higher heating values of 34.8–35.4 MJ/kg and 18.0–24.2 MJ/m<sup>3</sup>, respectively, together with char (45.5–48.5 % wt). The permanent gases can be used directly for heat generation, while hydro-treatment of the bio-oil would afford a material that can be blended with traditional transport fuels. This work demonstrates that if operated at scale, the combined harvesting, ensilaging and Thermo-Catalytic Reforming™ of preserved macroalgal biomass offers a year-round decentralised energy resource.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":"24 ","pages":"Article 100692"},"PeriodicalIF":7.1,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001703/pdfft?md5=12228832f189099a578adfea9bc0f06d&pid=1-s2.0-S2590174524001703-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142084451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Managing agricultural waste by burning it in the fields is a straightforward method, but leads to significant pollution. One promising alternative is to convert agricultural waste into solid fuel, such as charcoal, to support renewable energy from biomass. The quality of barbecue charcoal depends upon selecting suitable materials and employing heating methods to ensure efficient transformation. This research aims to study the charcoal conversion process from agricultural waste using two types of kilns: 1) direct heating (gasification kiln: GK) and 2) indirect heating (pyrolysis kiln: PK) designed to recirculate syngas from wood as fuel for the pyrolysis process. The study tested three types of agricultural waste materials, including coconut shells (CS), cassava rhizome (CR), and acacia wood (AW), to examine the differences in charcoal produced by the two heating methods. The tests revealed that the maximum temperatures inside the kilns were 792.45 ± 127.18 °C, 907.67 ± 37.3 °C, and 980.07 ± 110.56 °C for the GK, and 921.88 ± 57.84 °C, 801.93 ± 10.16 °C, and 937.82 ± 95.85 °C for the PK. The charcoal from the PK exhibited higher calorific values than the GK, with 7474.68 ± 36.62, 6429.04 ± 72.22, and 7268.33 ± 52.86 calories per gram. The charcoal yield was also higher in the PK, at 31.29 ± 4.39, 34.33 ± 3.39, and 17.58 ± 2.09 percent for coconut shells charcoal (CSC), cassava rhizome charcoal (CRC), and acacia wood charcoal (AWC), respectively. However, the PK required more fuel and longer ignition times. The resulting charcoal from the slow pyrolysis process in the PK is suitable as barbecue fuel due to its size, which is similar to the original material. In contrast, the charcoal from the GK, which tends to shrink or break into smaller pieces, is more suitable for grinding into briquettes. This study provides a guideline for producing high-quality barbecue charcoal, offering commercial benefits including the gasification and pyrolysis processes that improve combustion efficiency and reduce pollution by producing high-quality gas for fuel, unlike traditional kilns that emit a large amount of CO during the conversion of wood to charcoal and enabling the selection of appropriate raw materials for different heating methods to maximise the utility of the products. This approach adds value to agricultural raw materials and helps effectively manage agricultural waste (zero waste) for further utilisation and development.
{"title":"Sustainable conversion of agricultural waste into solid fuel (Charcoal) via gasification and pyrolysis treatment","authors":"Kantapong Khaeso , Bunyawat Sukhuna , Somporn Katekaew , Chaiyan Junsiri , Wiroon Monatrakul , Aphichat Srichat , Kritsadang Senawong , Kittipong Laloon","doi":"10.1016/j.ecmx.2024.100693","DOIUrl":"10.1016/j.ecmx.2024.100693","url":null,"abstract":"<div><p>Managing agricultural waste by burning it in the fields is a straightforward method, but leads to significant pollution. One promising alternative is to convert agricultural waste into solid fuel, such as charcoal, to support renewable energy from biomass. The quality of barbecue charcoal depends upon selecting suitable materials and employing heating methods to ensure efficient transformation. This research aims to study the charcoal conversion process from agricultural waste using two types of kilns: 1) direct heating (gasification kiln: GK) and 2) indirect heating (pyrolysis kiln: PK) designed to recirculate syngas from wood as fuel for the pyrolysis process. The study tested three types of agricultural waste materials, including coconut shells (CS), cassava rhizome (CR), and acacia wood (AW), to examine the differences in charcoal produced by the two heating methods. The tests revealed that the maximum temperatures inside the kilns were 792.45 ± 127.18 °C, 907.67 ± 37.3 °C, and 980.07 ± 110.56 °C for the GK, and 921.88 ± 57.84 °C, 801.93 ± 10.16 °C, and 937.82 ± 95.85 °C for the PK. The charcoal from the PK exhibited higher calorific values than the GK, with 7474.68 ± 36.62, 6429.04 ± 72.22, and 7268.33 ± 52.86 calories per gram. The charcoal yield was also higher in the PK, at 31.29 ± 4.39, 34.33 ± 3.39, and 17.58 ± 2.09 percent for coconut shells charcoal (CSC), cassava rhizome charcoal (CRC), and acacia wood charcoal (AWC), respectively. However, the PK required more fuel and longer ignition times. The resulting charcoal from the slow pyrolysis process in the PK is suitable as barbecue fuel due to its size, which is similar to the original material. In contrast, the charcoal from the GK, which tends to shrink or break into smaller pieces, is more suitable for grinding into briquettes. This study provides a guideline for producing high-quality barbecue charcoal, offering commercial benefits including the gasification and pyrolysis processes that improve combustion efficiency and reduce pollution by producing high-quality gas for fuel, unlike traditional kilns that emit a large amount of CO during the conversion of wood to charcoal and enabling the selection of appropriate raw materials for different heating methods to maximise the utility of the products. This approach adds value to agricultural raw materials and helps effectively manage agricultural waste (zero waste) for further utilisation and development.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":"24 ","pages":"Article 100693"},"PeriodicalIF":7.1,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001715/pdfft?md5=3e312fa048e74fc7c6c57997ccaabcdc&pid=1-s2.0-S2590174524001715-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142048241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-21DOI: 10.1016/j.ecmx.2024.100694
Ahmed E. Abu EL-Maaty , Mahmoud A. Abdalla , Mohamed Essalhi , Mahmoud M. Abdelnaby , Morsi M. Mahmoud , Mohamed A. Habib , Mohamed Antar , Rached Ben-Mansour
Adsorption cooling systems (ACS) powered by low-temperature heat offer an energy-efficient and environmentally friendly alternative to traditional vapor-compression systems. The effectiveness of ACS is significantly influenced by the alignment of the adsorbent properties with the operating conditions of the cycle. Metal-Organic Frameworks (MOFs) are considered the next generation of water harvesting and ACS. Many MOFs are synthesized and tested for water harvesting systems, one of these MOFs is MOF-303 which was reported to have very rapid water sorption dynamics under atmospheric conditions. However, MOF-303 has never been tested under the same conditions as ACS (under vacuum). In this study, the isotherms and kinetics of water adsorption on MOF-303, as an efficient adsorbent of water vapor, is experimentally investigated for the ACS using the linear driving force model. The diffusion coefficients across a wide range of relative pressures under two different temperatures were estimated. The study compares the adsorption process of MOF-303 with traditional silica gel (SG) in the context of diffusion kinetics relevant to ACS. Based on the output and at a constant temperature of 25 °C and across all relative pressure ranges, MOF-303 exhibited an average increase of approximately eight times in diffusion kinetics compared to SG. Specifically, within the relative pressure range of 10–30 %, which is optimal for ACS, MOF-303 demonstrated a seven-fold increase in diffusion kinetics over SG. The diffusion values for SG display a clear upward trend with increasing temperature. In contrast, the diffusion values for MOF-303 are subject to fluctuations with temperature changes under investigation. Notably, the isotherm for MOF-303 shows an inflection point at relative pressures between 10–15 %, causing a significant reduction in diffusion at these specific relative pressures compared to other relative pressure values. The findings in this study highlight the potential use of MOF-303 as a highly efficient water adsorbent for the ACS which will enable scientists and engineers to develop sustainable low-grade energy systems.
{"title":"Kinetics of Water Adsorption in Metal-Organic Framework(MOF-303) for Adsorption Cooling Application","authors":"Ahmed E. Abu EL-Maaty , Mahmoud A. Abdalla , Mohamed Essalhi , Mahmoud M. Abdelnaby , Morsi M. Mahmoud , Mohamed A. Habib , Mohamed Antar , Rached Ben-Mansour","doi":"10.1016/j.ecmx.2024.100694","DOIUrl":"10.1016/j.ecmx.2024.100694","url":null,"abstract":"<div><p>Adsorption cooling systems (ACS) powered by low-temperature heat offer an energy-efficient and environmentally friendly alternative to traditional vapor-compression systems. The effectiveness of ACS is significantly influenced by the alignment of the adsorbent properties with the operating conditions of the cycle. Metal-Organic Frameworks (MOFs) are considered the next generation of water harvesting and ACS. Many MOFs are synthesized and tested for water harvesting systems, one of these MOFs is MOF-303 which was reported to have very rapid water sorption dynamics under atmospheric conditions. However, MOF-303 has never been tested under the same conditions as ACS (under vacuum). In this study, the isotherms and kinetics of water adsorption on MOF-303, as an efficient adsorbent of water vapor, is experimentally investigated for the ACS using the linear driving force model. The diffusion coefficients across a wide range of relative pressures under two different temperatures were estimated. The study compares the adsorption process of MOF-303 with traditional silica gel (SG) in the context of diffusion kinetics relevant to ACS. Based on the output and at a constant temperature of 25 °C and across all relative pressure ranges, MOF-303 exhibited an average increase of approximately eight times in diffusion kinetics compared to SG. Specifically, within the relative pressure range of 10–30 %, which is optimal for ACS, MOF-303 demonstrated a seven-fold increase in diffusion kinetics over SG. The diffusion values for SG display a clear upward trend with increasing temperature. In contrast, the diffusion values for MOF-303 are subject to fluctuations with temperature changes under investigation. Notably, the isotherm for MOF-303 shows an inflection point at relative pressures between 10–15 %, causing a significant reduction in diffusion at these specific relative pressures compared to other relative pressure values. The findings in this study highlight the potential use of MOF-303 as a highly efficient water adsorbent for the ACS which will enable scientists and engineers to develop sustainable low-grade energy systems.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":"24 ","pages":"Article 100694"},"PeriodicalIF":7.1,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001727/pdfft?md5=d0ae5fd8d068980b97d669bebf48a12a&pid=1-s2.0-S2590174524001727-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142098217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-20DOI: 10.1016/j.ecmx.2024.100684
Ghaeth Fandi , Jaroslav Novák , Jan Chyský , Jakub Šrom
This research puts forward the modeling of a Hydrogen Fuel Cell Electric Vehicle (HFCEV) and its validation, in comparison with battery electrical vehicle (BEV) based on a postal vehicle and its subsystems. The main investigation parameters are the amount of hydrogen consumed, and the change in the state of charging of the battery. For the profile of the same speed route, an HFCEV model and a BEV model, consisting of multiple subsystems, were developed, and simulated in the MATLAB® Simulink environment. We make use of various sources of drive cycles to obtain our outcomes such as the New European Diving Cycle (NEDC). By running simulations for different stages, we are able to generate simulation results. The discrepancies in the graphs and the visual demonstrations guided us to variable conclusions on how different factors affect an electric vehicle’s performance and efficiency. The simulation result shows that the (BEV) is 30% more effective for NEDC drive cycle comparing with (HFCEV).
{"title":"Review and modeling on hydrogen fuel cells electric vehicle (HFCEV), in comparison with battery electrical vehicle (BEV) using MATLAB environment. Case study: Postal car","authors":"Ghaeth Fandi , Jaroslav Novák , Jan Chyský , Jakub Šrom","doi":"10.1016/j.ecmx.2024.100684","DOIUrl":"10.1016/j.ecmx.2024.100684","url":null,"abstract":"<div><p>This research puts forward the modeling of a Hydrogen Fuel Cell Electric Vehicle (HFCEV) and its validation, in comparison with battery electrical vehicle (BEV) based on a postal vehicle and its subsystems. The main investigation parameters are the amount of hydrogen consumed, and the change in the state of charging of the battery. For the profile of the same speed route, an HFCEV model and a BEV model, consisting of multiple subsystems, were developed, and simulated in the MATLAB® Simulink environment. We make use of various sources of drive cycles to obtain our outcomes such as the New European Diving Cycle (NEDC). By running simulations for different stages, we are able to generate simulation results. The discrepancies in the graphs and the visual demonstrations guided us to variable conclusions on how different factors affect an electric vehicle’s performance and efficiency. The simulation result shows that the (BEV) is 30% more effective for NEDC drive cycle comparing with (HFCEV).</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":"24 ","pages":"Article 100684"},"PeriodicalIF":7.1,"publicationDate":"2024-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001624/pdfft?md5=8d142a7f83676a3fdfee322de0d298f8&pid=1-s2.0-S2590174524001624-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142048399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-14DOI: 10.1016/j.ecmx.2024.100689
Mahboube Roostaei Firouzabad, Fathollah Pourfayaz
This article conducted a comprehensive study on a three-story residential building in Yazd, Iran, which was meticulously modeled using DesignBuilder. The primary objective was to investigate the impact of BioPCMs (Bio Phase Change Materials), which are environmentally friendly materials, on the building’s thermal performance. For this purpose, BioPCM® M182/Q21 was selected due to its effectiveness in enhancing energy efficiency. The study involved a practical comparison of the building’s energy consumption under three scenarios. The first scenario represented the baseline condition where no PCM was used. The second scenario incorporated PCM into the external walls, while the third scenario extended the use of PCM to both the external and internal walls. In the second scenario, where PCM was applied only to the external walls, there was a 9% reduction in annual energy consumption. The third scenario, which utilized PCM in both the external and internal walls, resulted in a reduction of 15.5% in annual energy consumption. Additionally, when PCM was used in both the external and internal walls, the total energy consumption for cooling and heating the building decreased by 5.4% and 18.9%, respectively.
{"title":"The impact of using PCM layers in simultaneously the external and internal walls of building on energy annual consumption","authors":"Mahboube Roostaei Firouzabad, Fathollah Pourfayaz","doi":"10.1016/j.ecmx.2024.100689","DOIUrl":"10.1016/j.ecmx.2024.100689","url":null,"abstract":"<div><p>This article conducted a comprehensive study on a three-story residential building in Yazd, Iran, which was meticulously modeled using DesignBuilder. The primary objective was to investigate the impact of BioPCMs (Bio Phase Change Materials), which are environmentally friendly materials, on the building’s thermal performance. For this purpose, BioPCM® M182/Q21 was selected due to its effectiveness in enhancing energy efficiency. The study involved a practical comparison of the building’s energy consumption under three scenarios. The first scenario represented the baseline condition where no PCM was used. The second scenario incorporated PCM into the external walls, while the third scenario extended the use of PCM to both the external and internal walls. In the second scenario, where PCM was applied only to the external walls, there was a 9% reduction in annual energy consumption. The third scenario, which utilized PCM in both the external and internal walls, resulted in a reduction of 15.5% in annual energy consumption. Additionally, when PCM was used in both the external and internal walls, the total energy consumption for cooling and heating the building decreased by 5.4% and 18.9%, respectively.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":"24 ","pages":"Article 100689"},"PeriodicalIF":7.1,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001673/pdfft?md5=bd6bdd70d3bd97d2cc47d8aad28b6674&pid=1-s2.0-S2590174524001673-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142084449","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-14DOI: 10.1016/j.ecmx.2024.100690
Cornelia Blanke, Malick Kane
With the increasing importance of energy efficiency and sustainability, the demand for high-performance district heating networks is also on the rise. As traditional engineering methods were often no longer sufficient, several packages for numerical simulation have evolved. Many of them offer high accuracy at the cost of considerable manual preparation and computational effort. However, there is still no user-friendly software that is equally suitable for simplified studies in the early project phase, for the rapid optimisation of multiple concepts and for subsequent detailed planning and dimensioning. For this reason and in cooperation with some companies from the energy sector, we had conceived a novel, highly flexible modular approach, the so-called “quantum networks”, where all parts of the district heating network are appropriately abstracted into quantum elements. Now we present our recent implementation of this model in an object-oriented C++ library. Starting from a generalised base class and making use of the concepts of inheritance and polymorphism, the idea of different levels of detail for the same element type is directly realised and can always be further refined. In addition, as all elements are derived from the same base class, they all share the same outer appearance and can thus be easily combined or interchanged. Based on these prerequisites, a dedicated thermo-hydraulic solver has then been developed. Thanks to its recursive design requiring neither outer iterations nor matrix inversions, it proves to be extremely fast and is therefore suitable for rapid design or optimisation studies in which a vast number of configurations has to be computed. To conclude this part of the work, the developed C++ library was benchmarked on two use cases covering a full year of operation that can now be computed in approximately one second of runtime.
随着能源效率和可持续性的重要性不断提高,对高性能区域供热网络的需求也在不断增加。由于传统的工程方法往往已经不能满足需要,因此出现了一些用于数值模拟的软件包。其中许多软件包在提供高精度的同时,也付出了大量的人工准备和计算工作。然而,目前仍没有一款用户友好型软件能够同样适用于项目初期的简化研究、多种概念的快速优化以及后续的详细规划和尺寸计算。为此,我们与能源行业的一些公司合作,构思了一种新颖、高度灵活的模块化方法,即所谓的 "量子网络",将区域供热网络的所有部分适当抽象为量子元素。现在,我们将介绍我们最近在面向对象的 C++ 库中对这一模型的实施。从一个通用的基类开始,利用继承和多态性的概念,可以直接实现同一元素类型的不同详细程度,并可随时进一步完善。此外,由于所有元素都来自同一个基类,因此它们都具有相同的外观,可以很容易地进行组合或互换。基于这些先决条件,我们开发了专用的热液求解器。由于其递归设计既不需要外部迭代,也不需要矩阵反演,因此速度极快,适用于需要计算大量配置的快速设计或优化研究。在结束这部分工作时,对开发的 C++ 库进行了基准测试,测试的两个用例涵盖了一整年的运行情况,现在只需约一秒钟的运行时间即可完成计算。
{"title":"An object-oriented implementation of a recursive “quantum network” solver and its application to district heating networks","authors":"Cornelia Blanke, Malick Kane","doi":"10.1016/j.ecmx.2024.100690","DOIUrl":"10.1016/j.ecmx.2024.100690","url":null,"abstract":"<div><p>With the increasing importance of energy efficiency and sustainability, the demand for high-performance district heating networks is also on the rise. As traditional engineering methods were often no longer sufficient, several packages for numerical simulation have evolved. Many of them offer high accuracy at the cost of considerable manual preparation and computational effort. However, there is still no user-friendly software that is equally suitable for simplified studies in the early project phase, for the rapid optimisation of multiple concepts and for subsequent detailed planning and dimensioning. For this reason and in cooperation with some companies from the energy sector, we had conceived a novel, highly flexible modular approach, the so-called “quantum networks”, where all parts of the district heating network are appropriately abstracted into quantum elements. Now we present our recent implementation of this model in an object-oriented C++ library. Starting from a generalised base class and making use of the concepts of inheritance and polymorphism, the idea of different levels of detail for the same element type is directly realised and can always be further refined. In addition, as all elements are derived from the same base class, they all share the same outer appearance and can thus be easily combined or interchanged. Based on these prerequisites, a dedicated thermo-hydraulic solver has then been developed. Thanks to its recursive design requiring neither outer iterations nor matrix inversions, it proves to be extremely fast and is therefore suitable for rapid design or optimisation studies in which a vast number of configurations has to be computed. To conclude this part of the work, the developed C++ library was benchmarked on two use cases covering a full year of operation that can now be computed in approximately one second of runtime.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":"24 ","pages":"Article 100690"},"PeriodicalIF":7.1,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001685/pdfft?md5=965cf7b2df403674a5f39e46cde82b24&pid=1-s2.0-S2590174524001685-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142129188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-01DOI: 10.1016/j.ecmx.2024.100651
María de los Milagros Ballari , Miroslava Filip Edelmannová , Rudolf Ricka , Martin Reli , Kamila Kočí
CO2 photocatalytic reduction is a potential and promising technology to reduce the level of the greenhouse gas in the atmosphere but also as an alternative and renewable fuel resource. However, the products yield of the reaction is still low and the identification of the optimal operating conditions that affect the process are still needed to be determined. This study investigates the impact of key operational parameters, specifically photocatalyst concentration and stirring speed, on the photocatalytic reduction of CO2 in a slurry batch photoreactor utilizing synthesized TiO2. A simplified photocatalytic kinetic model, incorporating the radiation field within the photoreactor, was developed, considering mass transfer from liquid to gas phase for the primary detected reaction products (CO, CH4, and H2). The proposed models elucidate the influence of different operating conditions on product yields. Stirring speed, controlled by a magnetic stirrer, impacts the gas–liquid mass transfer rate. Increased liquid phase stirring speed ensures faster species transport to the gas phase, with a diminishing effect beyond 900 rpm. TiO2 photocatalyst mass concentration influences the available total active surface and irradiation absorbance in the photoreactor volume. Optimal product yields were observed at the lowest tested photocatalyst concentration (0.5 g · L-1), indicating improved irradiation distribution and reduced particle agglomeration, resulting in higher available active surface for the reaction. The calculation model successfully predicted product yields even with lower photocatalyst concentration of 0.25 g · L-1, with marginal increases in predicted yields. These findings provide valuable insights for scaling up and optimizing the CO2 photocatalytic reduction process, offering a foundation for future research.
二氧化碳光催化还原技术是一项潜力巨大、前景广阔的技术,不仅可以降低大气中的温室气体含量,还可以作为一种可替代的可再生燃料资源。然而,该反应的产物产量仍然很低,而且影响该过程的最佳操作条件仍有待确定。本研究探讨了关键操作参数(特别是光催化剂浓度和搅拌速度)对利用合成 TiO2 的浆料间歇式光反应器光催化还原 CO2 的影响。考虑到主要检测反应产物(CO、CH4 和 H2)从液相到气相的传质,建立了一个简化的光催化动力学模型,其中包含光反应器内的辐射场。所提出的模型阐明了不同操作条件对产品产量的影响。由磁力搅拌器控制的搅拌速度会影响气液传质速率。提高液相搅拌速度可确保物种更快地传输到气相,但超过 900 rpm 后,效果会逐渐减弱。二氧化钛光催化剂的质量浓度会影响光反应器体积中可用的总活性表面和辐照吸收率。在测试的最低光催化剂浓度(0.5 g - L-1)下,观察到了最佳的产品产量,这表明辐照分布得到改善,颗粒团聚减少,从而为反应提供了更高的可用活性表面。即使在光催化剂浓度较低的情况下(0.25 克-升-1),计算模型也能成功预测产物产量,而且预测产量略有增加。这些发现为扩大和优化二氧化碳光催化还原过程提供了宝贵的见解,为今后的研究奠定了基础。
{"title":"Exploring kinetics and mass transfer in photocatalytic CO2 reduction: Impact of photocatalyst loading and stirrer speed","authors":"María de los Milagros Ballari , Miroslava Filip Edelmannová , Rudolf Ricka , Martin Reli , Kamila Kočí","doi":"10.1016/j.ecmx.2024.100651","DOIUrl":"https://doi.org/10.1016/j.ecmx.2024.100651","url":null,"abstract":"<div><p>CO<sub>2</sub> photocatalytic reduction is a potential and promising technology to reduce the level of the greenhouse gas in the atmosphere but also as an alternative and renewable fuel resource. However, the products yield of the reaction is still low and the identification of the optimal operating conditions that affect the process are still needed to be determined. This study investigates the impact of key operational parameters, specifically photocatalyst concentration and stirring speed, on the photocatalytic reduction of CO<sub>2</sub> in a slurry batch photoreactor utilizing synthesized TiO<sub>2</sub>. A simplified photocatalytic kinetic model, incorporating the radiation field within the photoreactor, was developed, considering mass transfer from liquid to gas phase for the primary detected reaction products (CO, CH<sub>4</sub>, and H<sub>2</sub>). The proposed models elucidate the influence of different operating conditions on product yields. Stirring speed, controlled by a magnetic stirrer, impacts the gas–liquid mass transfer rate. Increased liquid phase stirring speed ensures faster species transport to the gas phase, with a diminishing effect beyond 900 rpm. TiO<sub>2</sub> photocatalyst mass concentration influences the available total active surface and irradiation absorbance in the photoreactor volume. Optimal product yields were observed at the lowest tested photocatalyst concentration (0.5 g · L<sup>-1</sup>), indicating improved irradiation distribution and reduced particle agglomeration, resulting in higher available active surface for the reaction. The calculation model successfully predicted product yields even with lower photocatalyst concentration of 0.25 g · L<sup>-1</sup>, with marginal increases in predicted yields. These findings provide valuable insights for scaling up and optimizing the CO<sub>2</sub> photocatalytic reduction process, offering a foundation for future research.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":"23 ","pages":"Article 100651"},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001296/pdfft?md5=75c613beaec141ae4abc4c1cf80b0327&pid=1-s2.0-S2590174524001296-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141478883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-01DOI: 10.1016/j.ecmx.2024.100657
Agustina Skiarski , Nicolás Faedo , John V. Ringwood
Tidal barrage power plants utilise the tidal range variation to generate clean electricity. Although there are several operating tidal barrage schemes around the globe, there is still potential to expand the installed capacity. Given their inherent storage and the high predictability of the tides, tidal barrages can be operated with more flexibility than many other renewables. This means that the control objective of a barrage operation can vary from energy maximisation to constant power output, or demand-matching objectives. The operation of a barrage also influences its impact on the environment and economic activity of the site where it is located, which is a major cause for the slow deployment of such power plants. The aim of this study is to provide a comprehensive and critical analysis of the different strategies considered to date to optimise the operation of tidal barrages, with a focus on an in-depth analysis of the optimisation schemes employed, the barrage models utilised, and opportunities for further improvement.
{"title":"Optimisation and control of tidal range power plants operation: Is there scope for further improvement?","authors":"Agustina Skiarski , Nicolás Faedo , John V. Ringwood","doi":"10.1016/j.ecmx.2024.100657","DOIUrl":"10.1016/j.ecmx.2024.100657","url":null,"abstract":"<div><p>Tidal barrage power plants utilise the tidal range variation to generate clean electricity. Although there are several operating tidal barrage schemes around the globe, there is still potential to expand the installed capacity. Given their inherent storage and the high predictability of the tides, tidal barrages can be operated with more flexibility than many other renewables. This means that the control objective of a barrage operation can vary from energy maximisation to constant power output, or demand-matching objectives. The operation of a barrage also influences its impact on the environment and economic activity of the site where it is located, which is a major cause for the slow deployment of such power plants. The aim of this study is to provide a comprehensive and critical analysis of the different strategies considered to date to optimise the operation of tidal barrages, with a focus on an in-depth analysis of the optimisation schemes employed, the barrage models utilised, and opportunities for further improvement.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":"23 ","pages":"Article 100657"},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001351/pdfft?md5=dbdd7f6d0dac6107e677cb1e996d8d3f&pid=1-s2.0-S2590174524001351-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141623510","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The utilization of solar energy is picking up speed to counter climate change. New large-scale photovoltaic power stations are being constructed to increase solar utilization in the energy mix. A critical input of site selection for solar farms is the solar energy generation potential at a given location. Various physical and satellite-based inversion models are proposed to estimate the solar irradiation reaching the ground at potential locations, based on the meteorological features. However, the meteorological features generally contain outlier observations that distract the solar irradiation estimation models. To address this challenge, this study employs a robust fuzzy regression functions framework against the outliers to estimate the global horizontal irradiance (GHI) in Australia. Our framework is benchmarked with support vector machines, deep neural networks, and an adaptive network-based fuzzy inference system, and better GHI estimation performance is observed. The proposed framework provides 24 %, 18 %, and 23 % gain over the second-best method in terms of the rescaled mean absolute error, absolute percentage bias and rescaled root-mean-squared error. Monthly and annual GHI maps are created for Australia and compared to those from NASA POWER GHI estimates and Solargis annual GHI estimates. Our framework has an error range between 0.075 % and 2.9 % when validated against ground measurements. It provides at least an average of 40% lower monthly and annual error rates than POWER. This rate of gain rises to 69% when compared to Solargis. Our maps are not impacted by terrestrial characteristics and clear-sky conditions. This study’s results are beneficial in site selection and construction of high-precision GHI estimation models for practitioners.
{"title":"Robust estimation of global horizontal irradiance with modified fuzzy regression functions with a noise cluster in Australia","authors":"Srinivas Chakravarty , Haydar Demirhan , Furkan Baser","doi":"10.1016/j.ecmx.2024.100677","DOIUrl":"10.1016/j.ecmx.2024.100677","url":null,"abstract":"<div><p>The utilization of solar energy is picking up speed to counter climate change. New large-scale photovoltaic power stations are being constructed to increase solar utilization in the energy mix. A critical input of site selection for solar farms is the solar energy generation potential at a given location. Various physical and satellite-based inversion models are proposed to estimate the solar irradiation reaching the ground at potential locations, based on the meteorological features. However, the meteorological features generally contain outlier observations that distract the solar irradiation estimation models. To address this challenge, this study employs a robust fuzzy regression functions framework against the outliers to estimate the global horizontal irradiance (GHI) in Australia. Our framework is benchmarked with support vector machines, deep neural networks, and an adaptive network-based fuzzy inference system, and better GHI estimation performance is observed. The proposed framework provides 24 %, 18 %, and 23 % gain over the second-best method in terms of the rescaled mean absolute error, absolute percentage bias and rescaled root-mean-squared error. Monthly and annual GHI maps are created for Australia and compared to those from NASA POWER GHI estimates and Solargis annual GHI estimates. Our framework has an error range between 0.075 % and 2.9 % when validated against ground measurements. It provides at least an average of 40% lower monthly and annual error rates than POWER. This rate of gain rises to 69% when compared to Solargis. Our maps are not impacted by terrestrial characteristics and clear-sky conditions. This study’s results are beneficial in site selection and construction of high-precision GHI estimation models for practitioners.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":"23 ","pages":"Article 100677"},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001557/pdfft?md5=382fd8ca8139e02e13c5d6c49d316a9c&pid=1-s2.0-S2590174524001557-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141962094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wind energy plays a pivotal role in the ongoing effort to reduce carbon emissions in the energy sector. With the increasing evidence of climate change, there is a growing concern regarding the planning and operation of wind energy resources. Accurate forecasts are essential to understand the frequency distribution of wind speed data in a given area and, consequently, to estimate energy production. This paper aims to analyze the wind resources under climate change, assess their potential, and create zoning maps for wind energy production in the island of Ireland. For this objective, wind speed data from 31 general circulation models (GCMs) and two climate change scenarios were utilized for both hindcast and forecast periods in 1981–2010 and 2021–2050, respectively. The GCM outputs were first bias-corrected and then post-processed using various (non–)parametric statistical distributions and 3 Copula families. The results indicate an expected decrease in the average wind speed in the region up to ∼ 21 % by 2050, contingent on the climate scenarios under consideration and the target point. Ultimately, this study concludes by presenting wind power density maps specifically to the study region, offering valuable insights for sustainable energy planning.
{"title":"A copula post-processing method for wind power projections under climate change","authors":"Sogol Moradian , Salem Gharbia , Gregorio Iglesias , Agnieszka Indiana Olbert","doi":"10.1016/j.ecmx.2024.100660","DOIUrl":"https://doi.org/10.1016/j.ecmx.2024.100660","url":null,"abstract":"<div><p>Wind energy plays a pivotal role in the ongoing effort to reduce carbon emissions in the energy sector. With the increasing evidence of climate change, there is a growing concern regarding the planning and operation of wind energy resources. Accurate forecasts are essential to understand the frequency distribution of wind speed data in a given area and, consequently, to estimate energy production. This paper aims to analyze the wind resources under climate change, assess their potential, and create zoning maps for wind energy production in the island of Ireland. For this objective, wind speed data from 31 general circulation models (GCMs) and two climate change scenarios were utilized for both hindcast and forecast periods in 1981–2010 and 2021–2050, respectively. The GCM outputs were first bias-corrected and then post-processed using various (non–)parametric statistical distributions and 3 Copula families. The results indicate an expected decrease in the average wind speed in the region up to ∼ 21 % by 2050, contingent on the climate scenarios under consideration and the target point. Ultimately, this study concludes by presenting wind power density maps specifically to the study region, offering valuable insights for sustainable energy planning.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":"23 ","pages":"Article 100660"},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001387/pdfft?md5=3903fc0d644b5e7f51bf5319146156c7&pid=1-s2.0-S2590174524001387-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141540711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}