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Techno-economic evaluation and comparison of the optimal PV/Wind and grid hybrid system with horizontal and vertical axis wind turbines 采用水平轴和垂直轴风力涡轮机的最佳光伏/风力和电网混合系统的技术经济评估与比较
IF 6.3 Q1 Energy Pub Date : 2024-05-28 DOI: 10.1016/j.ecmx.2024.100638
Ahmad Shah Irshad , Nqibullah Kargar , M.H. Elkholy , Gul Ahmad Ludin , Said Elias , Ahmadullah Hilali , Tomonobu Senjyu , Mahmoud M.Gamil , Gabor Pinter

Applications for alternative energy sources range from very small scale to large scale grid-coupled hybrid energy systems. In addition, hybrid energy systems are safer to generate power and cheaper to produce than single-source energy systems. The main goal of this study is to determine whether renewable energy hybrid system with horizontal axis wind turbine (HAWT) or vertical axis wind turbine (VAWT) is more efficient and cost effective in terms of energy, economics, and environmental performance. The use of the Multi Objective Genetic Algorithm (MOGA) in MATLAB software for the sizing of hybrid sustainable energy system with wind turbine (horizontal and vertical axis), solar photovoltaic, and grid connection is evaluated in this study. The results revealed that the cost of energy, NPC and system total cost for the case where HRES consists of HAWT is $0.02 /kWh, $85,905, and $332,240, respectively, while for the case when VAWT is used, these values are $0.06 /kWh, $129,932 and $502,511, respectively. The renewable fraction and CO2 emission saving are 80.5% and 73.2% for cases 1 and 2, respectively. The use of renewable energy sources will spread more widely and there will be less air pollution as a result of less reliance on grid electricity. The findings from both situations show that adopting HAWTS-based HRESs is more cost effective and efficient for electrifying rural areas. This study paves the way for researchers to focus on types of wind turbines while designing HRESs.

替代能源的应用范围从非常小的规模到大规模的电网耦合混合能源系统。此外,与单一能源系统相比,混合能源系统发电更安全,生产成本更低。本研究的主要目标是确定采用水平轴风力涡轮机(HAWT)或垂直轴风力涡轮机(VAWT)的可再生能源混合系统在能源、经济和环境性能方面是否更高效、更具成本效益。本研究评估了在 MATLAB 软件中使用多目标遗传算法(MOGA)来确定风力涡轮机(水平轴和垂直轴)、太阳能光伏发电和电网连接的混合可持续能源系统的规模。结果显示,在使用 HAWT 的情况下,HRES 的能源成本、NPC 和系统总成本分别为 0.02 美元/千瓦时、85,905 美元和 332,240 美元,而在使用 VAWT 的情况下,这些数值分别为 0.06 美元/千瓦时、129,932 美元和 502,511 美元。案例 1 和案例 2 的可再生能源比例和二氧化碳减排量分别为 80.5% 和 73.2%。由于减少了对电网电力的依赖,可再生能源的使用将得到更广泛的推广,空气污染也将减少。这两种情况的研究结果表明,采用基于 HAWTS 的 HRES 在实现农村地区电气化方面更具成本效益和效率。这项研究为研究人员在设计 HRES 时关注风力涡轮机类型铺平了道路。
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引用次数: 0
Extraction and characterization of Cucumis melon seeds (Muskmelon seed oil) biodiesel and studying its blends impact on performance, combustion, and emission characteristics in an internal combustion engine 瓜子(麝香瓜子油)生物柴油的提取和表征,以及研究其混合物对内燃机性能、燃烧和排放特性的影响
IF 6.3 Q1 Energy Pub Date : 2024-05-28 DOI: 10.1016/j.ecmx.2024.100637
Ala’a K. Al-Bawwat , Mohamed R. Gomaa , Antonio Cano , Francisco Jurado , Eid M. Alsbou

This study examines the performance, combustion, and emissions characteristics of a single-cylinder internal combustion diesel engine when fueled with a blend of diesel and biodiesel derived from muskmelon seeds. The kinematic viscosity of the extracted muskmelon seed oil was 6.1 cSt at 40 °C, which is higher than the kinematic viscosity of petroleum diesel of 2.6 cSt. Muskmelon biodiesel was further analyzed using thin-layer chromatography (TLC) and high-voltage separator tests. A comparison of the fuel properties of muskmelon biodiesel with conventional diesel fuel revealed that muskmelon biodiesel could be used alone or in a diesel–biodiesel blend to fuel compression diesel engines. In this study, muskmelon seed biodiesel was blended with diesel fuel at proportions of 10 %, 20 %, and 50 % (BD10, BD20, and BD50, respectively). At a relatively low rotational speed of 1200 rpm, the brake thermal efficiency (BTE) of the engine operated with BD10 and BD20 blends were 36.1 % and 36.0 %, respectively, while the brake-specific fuel consumption (BSFC) of the two blends were 0.260 kg/kWh, and 0.262 kg/kWh, respectively. These values closely resemble those typically observed in diesel fuel engines. Indeed, the average BTE of the BD20 blend was only 3.24 % less than the average BTE of diesel fuel. Diesel fuel generates less NOx and SO2 emissions compared to biodiesel blends: BD100 emitted the most NOx pollution of all fuels tested. In addition, BD10 released significantly more SO2 emissions compared to the other fuels tested. However, the BD20 blend outperformed all other blends in terms of CO, NOx, and SO2 emissions at high engine speeds. The only exception was H2S emissions, which were higher than BD50 and BD100. BD20 also exhibited significantly reduced CO emissions compared to diesel fuel, while BD10 emitted significantly more CO emissions than the other biodiesel blends. Our findings revealed that BD20 exhibited the best engine performance and lower emissions among all fuels tested. In other words, BD20 is the ideal fuel blend for use in diesel engines and does not require any alterations to the engine. Muskmelon waste seeds represent a non-edible waste stream that can be exploited in the production of biodiesel fuel, allowing for the upcycling of a potentially problematic thermochemical conversion feedstock. This potentially valuable use for waste muskmelon seeds in the energy sector could address the wastefulness associated with this particular waste stream.

本研究考察了单缸内燃柴油发动机在混合柴油和从麝香瓜籽中提取的生物柴油后的性能、燃烧和排放特性。提取的麝香瓜籽油在 40 °C 时的运动粘度为 6.1 厘斯,高于石油柴油 2.6 厘斯的运动粘度。使用薄层色谱法(TLC)和高压分离器测试对麝香瓜生物柴油进行了进一步分析。通过比较麝香瓜生物柴油与传统柴油的燃料特性,发现麝香瓜生物柴油可单独使用,也可用于柴油-生物柴油混合燃料,为压缩式柴油发动机提供燃料。在这项研究中,麝香瓜籽生物柴油与柴油的混合比例分别为 10%、20% 和 50%(BD10、BD20 和 BD50)。在相对较低的转速(1200 转/分)下,使用 BD10 和 BD20 混合物的发动机的制动热效率(BTE)分别为 36.1% 和 36.0%,而两种混合物的制动油耗(BSFC)分别为 0.260 千克/千瓦时和 0.262 千克/千瓦时。这些数值非常接近柴油发动机的典型值。事实上,BD20 混合物的平均 BTE 仅比柴油的平均 BTE 低 3.24%。与生物柴油混合物相比,柴油产生的氮氧化物和二氧化硫排放量较少:在所有测试燃料中,BD100 的氮氧化物污染排放量最大。此外,与其他测试燃料相比,BD10 的二氧化硫排放量要高得多。然而,在发动机高速运转时,BD20 混合燃料在 CO、NOx 和 SO2 排放方面的表现优于所有其他混合燃料。唯一的例外是 H2S 排放量,它高于 BD50 和 BD100。与柴油相比,BD20 的一氧化碳排放量也明显减少,而 BD10 的一氧化碳排放量则明显高于其他生物柴油混合物。我们的研究结果表明,在所有测试燃料中,BD20 的发动机性能最好,排放也较低。换句话说,BD20 是用于柴油发动机的理想混合燃料,而且不需要对发动机进行任何改动。麝香瓜废弃种子是一种非食用废弃物流,可用于生产生物柴油燃料,从而实现对可能存在问题的热化学转换原料的升级再循环。废弃麝香瓜籽在能源领域的这一潜在宝贵用途可以解决与这一特殊废物流相关的浪费问题。
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引用次数: 0
The GCC’s path to a sustainable future: Navigating the barriers to the adoption of energy efficiency measures in the built environment 海湾合作委员会通往可持续未来之路:克服在建筑环境中采用节能措施的障碍
IF 6.3 Q1 Energy Pub Date : 2024-05-27 DOI: 10.1016/j.ecmx.2024.100636
Muhammad Imran Khan , Yusuf Bicer , M. Asif , Tareq A. Al-Ansari , Mushtaq Khan , Tonni Agustiono Kurniawan , Sami G. Al-Ghamdi

The built environment is a significant contributor to global energy demand, particularly in the Gulf Cooperation Council (GCC) countries, where it accounts for roughly two-thirds of total energy consumption. The GCC region is known for its high per capita energy consumption, and addressing the building sector’s excessive energy use is crucial for a sustainable future. Despite efforts by GCC governments to encourage the adoption of building energy efficiency (BEE) measures, numerous barriers hinder their implementation and diffusion. This paper provides a comprehensive exploration of the barriers to BEE adoption in the GCC, identifying and categorizing 46 such barriers into six distinct clusters: governmental and institutional, economic and financial, technical and technological, capacity and awareness, social and cultural, and market and industry barriers. The study employs a qualitative methodology, utilizing content analysis to identify common themes and patterns in the data collected from various sources, including academic literature, government publications, and international agency reports. The findings underscore that while GCC states have the financial capacity to augment energy efficiency measures through a state-driven approach, they have yet to fully embrace these initiatives, largely due to low energy tariffs and the political dynamics of rentier states. To effectively address these barriers, the study argues for a holistic, interconnected approach that recognizes the government’s role in promoting energy efficiency and sustainability. The implications of this study are crucial for stakeholders, offering insights to facilitate the enhancement of BEE measures in the GCC’s existing and new buildings. By identifying and understanding the complex interplay of factors hindering BEE adoption, policymakers and organizations can develop targeted strategies and policies to overcome these barriers and foster a more sustainable built environment in the GCC region.

建筑环境是全球能源需求的重要贡献者,尤其是在海湾合作委员会(GCC)国家,建筑环境的能耗约占总能耗的三分之二。海湾合作委员会地区以人均能耗高而著称,因此,解决建筑行业过度使用能源的问题对于实现可持续发展的未来至关重要。尽管海湾合作委员会各国政府努力鼓励采用建筑节能 (BEE) 措施,但仍有许多障碍阻碍了这些措施的实施和推广。本文对海湾合作委员会采用 BEE 的障碍进行了全面探讨,确定了 46 个此类障碍并将其分为六大类:政府和机构障碍、经济和金融障碍、技术和工艺障碍、能力和意识障碍、社会和文化障碍以及市场和行业障碍。研究采用了定性方法,利用内容分析来确定从学术文献、政府出版物和国际机构报告等各种来源收集的数据中的共同主题和模式。研究结果强调,虽然海湾合作委员会国家有财力通过国家驱动的方法来提高能效措施,但它们尚未完全接受这些举措,这主要是由于能源关税低和租界国家的政治动态造成的。为了有效应对这些障碍,本研究主张采用一种整体的、相互关联的方法,承认政府在促进能源效率和可持续性方面的作用。本研究的意义对利益相关者至关重要,它为促进海湾合作委员会现有建筑和新建建筑加强 BEE 措施提供了真知灼见。通过识别和理解阻碍采用 BEE 的各种因素之间复杂的相互作用,政策制定者和组织可以制定有针对性的战略和政策,以克服这些障碍,在海湾合作委员会地区营造一个更具可持续性的建筑环境。
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引用次数: 0
2D thermo-fluidynamic rotary model of an elastocaloric cooling device: The energy performances 弹性冷却装置的二维热流体力学旋转模型:能量性能
IF 6.3 Q1 Energy Pub Date : 2024-05-25 DOI: 10.1016/j.ecmx.2024.100635
Luca Cirillo, Adriana Greco, Claudia Masselli

Elastocaloric cooling has been considered a promising solid-state technology for cooling and heat pumping among the alternatives to vapor compression, at room temperature range. The technology is based on elastocaloric effect that is a thermophysical phenomenon occurring in materials like Shape Memory Alloys (SMA). The effect is detectable as a temperature change in the material if adiabatically subjected to a forcing field of mechanical nature. The latter provokes to the materials a stress that can derive from tension, compression, bending, torsion solicitations. As a result, the SMA experiments a structural phase change from austenite to martensite (coupled with heat addition) and temperature rise. Dually when the stress is removed, the SMA releases heat with a temperature decrease. In this paper the SUSSTAIN-EL rotary elastocaloric heat pump has been deeply investigated to test the energy performances while it works on open loop and closed loop, through a 2D numerical model based on the finite element method, for cooling and heating operation modes. The device employs a binary NiTi SMA as elastocaloric refrigerant and air as heat transfer medium. A wide set of working conditions has been considered like variable inlet mass flow rate, rotation frequency and thermal loads. The acquired results demonstrate that, both in open and closed loop, the prototype’s energy performances are promising and highly favourable for the intended macroscale collocation of the device.

在室温范围内,弹性冷却被认为是一种很有前途的固态冷却和热泵技术,是蒸汽压缩的替代技术之一。该技术基于弹性热效应,这是一种发生在形状记忆合金(SMA)等材料中的热物理现象。这种效应在绝热状态下受到机械性质的强制场作用时,可检测到材料的温度变化。后者会对材料产生拉伸、压缩、弯曲和扭转等应力。因此,SMA 会发生从奥氏体到马氏体的结构相变(加上热量)和温度升高。同样,当应力消除时,SMA 释放热量,温度降低。本文对 SUSSTAIN-EL 旋转弹性热泵进行了深入研究,通过基于有限元法的二维数值模型,测试其在开环和闭环冷却和加热运行模式下的能量性能。该设备采用二元镍钛 SMA 作为弹性制冷剂,空气作为传热介质。考虑了多种工作条件,如不同的入口质量流量、旋转频率和热负荷。获得的结果表明,无论是开环还是闭环,原型的能源性能都很好,非常适合该装置的宏观配置。
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引用次数: 0
Economic impacts of power-to-liquid fuels in aviation: A general equilibrium analysis of production and utilization in Germany 电转液燃料对航空业的经济影响:对德国生产和使用情况的一般均衡分析
IF 6.3 Q1 Energy Pub Date : 2024-05-25 DOI: 10.1016/j.ecmx.2024.100632
Tobias Mueller , Etti Winter , Ulrike Grote

The aviation industry faces an urgent need to adopt sustainable aviation fuels for significant decarbonization. Power-to-Liquid (PtL) fuel is considered a potential game changer, but questions remain about the wider economic impacts of introducing PtL fuel in the aviation sector. This paper examines the economic impacts of introducing PtL fuel blending quotas along with a price policy consisting of a kerosene tax and PtL fuel subsidies for the case of Germany. Based on a detailed supply chain analysis, we apply a social accounting matrix and a computable general equilibrium model to take into account both, the production and utilization perspectives of PtL jet fuel. Our results show that the influence of low blending quotas is mainly limited to the aviation sector, with a 10 % blending quota increasing consumer prices by 7.9 % and reducing aviation industry output by 3.1 %. When quota levels increase, however, the effects go beyond the air transport system. On inter-sectoral level, we identify three main patterns: First, industries that substantially contribute to the PtL fuel supply chain, such as metal products and electrical equipment, see increasing levels in both, domestic production, and imports. Second, aviation upstream industries like transport infrastructure and aircraft production see reduced domestic production and imports. Third, aviation downstream industries, such as delivery services and travel agencies, see substitution effects, where imports partly replace domestic output. Macroeconomic indicators are affected negatively by the quota scenarios, but the relative impact is low as the maximum decrease in the gross domestic product (GDP) does not exceed 0.35 %. PtL fuel production subsidies can largely mitigate the decrease in aviation demand but come at the cost of a stronger reduction in the GDP and government income. Moreover, the sensitivity analysis emphasizes that various assumptions and parameters, such as the cost projections of PtL fuel, import options, and elasticities of demand, affect the intensity of economic consequences. Our analysis implies the trade-offs of policymaking between sectoral and macroeconomic interests in the context of sustainable fuels. The main contribution of this study is the investigation of the broader economic effects resulting from the adoption of PtL fuels in aviation. In particular, the production as well as the utilization perspective are considered simultaneously in this study.

航空业亟需采用可持续航空燃料,以大幅降低碳排放。动力液化(PtL)燃料被认为有可能改变游戏规则,但在航空领域引入 PtL 燃料的广泛经济影响仍存在疑问。本文以德国为例,研究了引入 PtL 燃料混合配额以及由煤油税和 PtL 燃料补贴组成的价格政策的经济影响。基于详细的供应链分析,我们应用了社会核算矩阵和可计算的一般均衡模型,从生产和使用两个角度考虑了铂液喷气燃料。我们的研究结果表明,低混合配额的影响主要局限于航空业,10% 的混合配额会使消费价格上涨 7.9%,航空业产出减少 3.1%。然而,当配额水平提高时,其影响超出了航空运输系统。在跨行业层面,我们发现了三种主要模式:首先,对 PtL 燃料供应链有重大贡献的行业,如金属制品和电气设备,其国内生产和进口水平都在上升。其次,运输基础设施和飞机制造等航空上游产业的国内生产和进口都有所减少。第三,航空下游产业,如快递服务和旅行社,出现了替代效应,即进口部分替代了国内产出。宏观经济指标受到配额方案的负面影响,但相对影响较小,因为国内生产总值(GDP)的最大降幅不超过 0.35%。PtL 燃料生产补贴可以在很大程度上缓解航空需求的下降,但代价是国内生产总值和政府收入的大幅减少。此外,敏感性分析强调,各种假设和参数,如 PtL 燃料的成本预测、进口选择和需求弹性,都会影响经济后果的强度。我们的分析表明,在可持续燃料的背景下,部门利益和宏观经济利益之间的政策制定需要权衡利弊。本研究的主要贡献在于调查了航空业采用 PtL 燃料所产生的更广泛的经济影响。特别是,本研究同时考虑了生产和使用的角度。
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引用次数: 0
Transient analysis of an efficient solar assisted air-conditioning system for subtropical climate with various solar thermal collectors 采用各种太阳能集热器的亚热带气候高效太阳能辅助空调系统的瞬态分析
IF 6.3 Q1 Energy Pub Date : 2024-05-24 DOI: 10.1016/j.ecmx.2024.100634
Ghulam Qadar Chaudhary , Muhammad Waheed Azam , Fabio Bozzoli , Uzair Sajjad , Pamela Vocale , Luca Cattani , Rasoul Fallahzadeh

The air conditioning demand of the world is largely fulfilled by vapor compression systems; however, these systems are also responsible for depleting ozone layer due to the nature of refrigerants. Desiccant cooling systems integrated with solar thermal energy technologies could be an attractive alternative with some performance enhancement techniques. In this study, transient seasonal performance investigation is performed for an innovative solar integrated desiccant cooling system that uses regenerative evaporative cooler known as solar assisted desiccant integrated Maisotsenko cycle cooler for better cooling performance. Furthermore, transient annual performance analysis of solar system for meeting thermal energy requirement for regenerating the desiccant wheel in summer season and handling heating load of the building in winter season is also carried out with three different solar thermal collector technologies for finding out more efficient technology. The key performance indicators in this study are useful energy gain, solar source efficiency, auxiliary energy sharing, coefficient of performance, and solar fraction. The results of the key performance parameters are reported as monthly average values. The proposed integrated system resulted to be very efficient with a maximum COP value of 1.13 in April when latent cooling loads are low and 0.78 in August when latent cooling loads are higher. The system’s maximum cooling capacity is 24 kW in April corresponding to a sensible heat factor of 0.720. Furthermore, the regeneration temperature requirements ranged from 50 °C to 78 °C, respectively that makes it favorable to use low grade thermal energy through non concentrating solar thermal collectors. The regeneration thermal energy requirement for desiccant wheel fluctuates throughout the year, maximizing in August due to higher dehumidification requirements. The study also revealed that the evacuated tube collector technology is most suitable with average annual efficiency of around 36 %.

全世界的空调需求主要由蒸汽压缩系统来满足;然而,由于制冷剂的性质,这些系统也是消耗臭氧层的罪魁祸首。与太阳能热能技术相结合的干燥剂冷却系统可以通过一些性能提升技术成为一种有吸引力的替代方案。在本研究中,对创新的太阳能集成干燥剂冷却系统进行了瞬态季节性能调查,该系统使用再生蒸发冷却器(称为太阳能辅助干燥剂集成麦索岑科循环冷却器),以获得更好的冷却性能。此外,还利用三种不同的太阳能集热器技术,对太阳能系统进行了瞬态年度性能分析,以满足夏季再生干燥剂轮和冬季处理建筑物供热负荷的热能需求,从而找出更高效的技术。这项研究的关键性能指标是有用能量增益、太阳光源效率、辅助能源分担、性能系数和太阳光分量。关键性能参数的结果以月平均值的形式报告。拟议的集成系统非常高效,在潜冷负荷较低的四月,最大 COP 值为 1.13;在潜冷负荷较高的八月,最大 COP 值为 0.78。该系统在四月份的最大制冷量为 24 千瓦,显热系数为 0.720。此外,再生温度要求分别在 50 °C 至 78 °C 之间,这有利于通过非聚光太阳能集热器使用低品位热能。干燥轮的再生热能需求全年波动,8 月份由于除湿需求较高而达到最大。研究还表明,抽真空管集热器技术最合适,年平均效率约为 36%。
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引用次数: 0
Kinetics and thermodynamic studies on biodiesel synthesis via Soxhlet extraction of Scenedesmus parvus algae oil 通过索氏提取副藻油合成生物柴油的动力学和热力学研究
IF 6.3 Q1 Energy Pub Date : 2024-05-23 DOI: 10.1016/j.ecmx.2024.100633
Jebrel Abdeljawad Rashd , Japareng Lalung , Mohd Asyraf Kassim , Dani Wijaya , Akrm Mohamed Masaud Allzrag , Marwan Abdulhakim Shaah

In recent times, there has been a notable surge in interest regarding the utilization of microalgae for biodiesel production through wastewater treatment. This can be attributed to the versatile nature of microalgae to thrive in various water systems, including wastewater systems, and their ability to show a high rate of photosynthesis. This research aims to assess the viability of utilizing Scenedesmus parvus microalgae, commonly used in the treatment of wastewater, as a potential source of oil feedstock for biofuel production. To extract oil from microalgae, a Soxhlet extraction technique was employed, using methanol for both extraction and separation processes. The extraction process was carried out under differing experimental conditions, including variable extraction temperatures (40–80 °C), extraction period (3–12 h), and algae to solvent ratios (S/L) (1:05–1:10). The microalgae exhibited a maximum oil yield of about 24% when subjected to the extraction conditions of an 8-hour extraction period, an extraction temperature of 70 °C, and a methanol to algae ratio of 1:10. The extraction process of algae oil using the Soxhlet method was analyzed for its thermodynamic and kinetic properties using a second-order equation and Eyring's theory, respectively. In this process, biodiesel was successfully produced with an efficiency of approximately 92.2 ± 0.8% through an alkaline transesterification reaction. This reaction was conducted at a temperature of 65 °C, using a catalyst concentration of 1 wt% (KOH), with the ratio of algae oil to methanol set at 1:9, for 3 h. The biodiesel obtained from microalgae in this research conformed to the global biodiesel standards, specifically ASTM D6751 and EN 14214. The findings emphasize the viability of Scenedesmus parvus microalgae as a valuable resource for biodiesel production.

近来,人们对利用微藻通过废水处理生产生物柴油的兴趣明显增加。这是因为微藻类具有在各种水系统(包括废水系统)中茁壮成长的多面性,而且能够显示出较高的光合作用率。本研究旨在评估利用常用于废水处理的副鳞藻作为生物燃料生产的潜在油原料来源的可行性。为了从微藻中提取油,研究人员采用了索氏提取技术,在提取和分离过程中都使用了甲醇。萃取过程在不同的实验条件下进行,包括不同的萃取温度(40-80 °C)、萃取时间(3-12 小时)和藻与溶剂的比例(S/L)(1:05-1:10)。在萃取期为 8 小时、萃取温度为 70 °C、甲醇与藻类的比例为 1:10 的萃取条件下,微藻类的最高产油量约为 24%。索氏提取法萃取海藻油的过程分别用二阶方程和艾林理论分析了其热力学和动力学特性。在此过程中,通过碱性酯交换反应成功生产出生物柴油,效率约为 92.2 ± 0.8%。该反应在 65 °C 的温度下进行,催化剂浓度为 1 wt%(KOH),藻油和甲醇的比例设定为 1:9,反应时间为 3 小时。研究结果表明,副鳞藻类微藻是生产生物柴油的宝贵资源。
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引用次数: 0
Biodiesel production from marine macroalgae Ulva lactuca lipids using novel Cu-BTC@AC catalyst: Parametric analysis and optimization 使用新型 Cu-BTC@AC 催化剂从海洋大型藻类乳莼脂中生产生物柴油:参数分析与优化
IF 6.3 Q1 Energy Pub Date : 2024-05-23 DOI: 10.1016/j.ecmx.2024.100628
Muhammad Zubair Yameen , Dagmar Juchelková , Salman Raza Naqvi , Tayyaba Noor , Arshid Mahmood Ali , Khurram Shahzad , Muhammad Imtiaz Rashid , Aishah Binti Mahpudz

The pursuit of renewable fuels for the transportation sector, particularly for combustion engines like diesel, is crucial in reducing greenhouse gas emissions. This study introduces an innovative strategy for biodiesel production utilizing marine macroalgae Ulva lactuca as the primary feedstock, emphasizing sustainability and resource efficiency. Lipids were extracted from the macroalgae via a Soxhlet process and characterized using GC–MS and FTIR to ascertain fatty acid composition and functional groups. The Cu–BTC@AC catalyst, synthesized from the lipid-extracted algae residue via pyrolysis and hydrothermal treatment, underwent characterization using SEM–EDS, XRD, and FTIR techniques. Subsequently, the Cu–BTC@AC catalyst was employed in the transesterification process to efficiently convert the extracted algal lipids into biodiesel, achieving a high yield of 92.56 % under RSM-optimized conditions: 65 °C temperature, 3.96 wt% catalyst amount, 15:1 methanol-to-lipid ratio, and 140 min reaction time. Kinetic and thermodynamic parameters for biodiesel production were calculated as follows: Ea = 33.20 kJ mol−1, ΔH# = 30.39 kJ mol−1, ΔS# = –165.86 J mol−1 K−1, and ΔG# = 86.48 kJ mol−1. GC–MS analysis identified a significant FAME content in the biodiesel, comprising 98.12 % of its composition. Notably, the Cu–BTC@AC catalyst exhibited excellent reusability, maintaining 80.21 % biodiesel yield after the third cycle. Moreover, physicochemical analysis of the biodiesel confirmed its compliance with ASTM D6751 specifications, underscoring its potential as a viable alternative fuel for the transportation sector.

为交通部门,特别是柴油等内燃机寻求可再生燃料,对于减少温室气体排放至关重要。本研究介绍了一种利用海洋大型藻类莼菜作为主要原料生产生物柴油的创新战略,强调可持续性和资源效率。通过索氏提取法从大型藻类中提取脂质,并使用气相色谱-质谱联用仪(GC-MS)和傅立叶变换红外光谱仪(FTIR)对脂质进行表征,以确定脂肪酸组成和官能团。Cu-BTC@AC 催化剂由提取脂质的藻类残渣经热解和水热处理合成,使用 SEM-EDS、XRD 和 FTIR 技术对其进行表征。随后,将 Cu-BTC@AC 催化剂用于酯交换反应过程,在 RSM 优化条件下将提取的藻类脂质有效地转化为生物柴油,并获得了 92.56% 的高产率:温度为 65 °C,催化剂用量为 3.96 wt%,甲醇与脂质的比例为 15:1,反应时间为 140 分钟。生物柴油生产的动力学和热力学参数计算如下Ea = 33.20 kJ mol-1,ΔH# = 30.39 kJ mol-1,ΔS# = -165.86 J mol-1 K-1,ΔG# = 86.48 kJ mol-1。气相色谱-质谱分析确定生物柴油中含有大量的 FAME,占其成分的 98.12%。值得注意的是,Cu-BTC@AC 催化剂表现出极佳的重复利用率,在第三个循环后生物柴油产量仍保持在 80.21%。此外,生物柴油的理化分析证实其符合 ASTM D6751 规范,凸显了其作为运输行业可行替代燃料的潜力。
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引用次数: 0
Enhanced hydrogen production through methane dry reforming: Evaluating the effects of promoter-induced variations in reducibility, basicity, and crystallinity on Ni/ZSM-5 catalyst performance 通过甲烷干重整提高制氢能力:评估促进剂引起的还原性、碱性和结晶度变化对 Ni/ZSM-5 催化剂性能的影响
IF 6.3 Q1 Energy Pub Date : 2024-05-22 DOI: 10.1016/j.ecmx.2024.100631
Kirankumar J. Chaudhary , Ahmed S. Al-Fatesh , Ahmed A. Ibrahim , Ahmed I. Osman , Anis H. Fakeeha , Mansour Alhoshan , Naif Alarifi , Ala’a H. Al-Muhtaseb , Rawesh Kumar

The pursuit of sustainable hydrogen production through the conversion of methane (CH4) and carbon dioxide (CO2), two prevalent greenhouse gases, is advanced by utilizing cost-effective Ni-supported catalysts within the framework of methane dry reforming. Utilizing crystalline porous zeolite, specifically ZSM-5, enhances the dispersion of nickel (Ni) across the catalyst surface and within its pore channels, hence increasing catalytic efficiency. Herein, we investigate the impact of incorporating various promoters (Ce, Cs, Cu, Fe, Sr) into the 5Ni/ZSM-5 catalyst, systematically examining how these modifications influence the reducibility, basicity, and crystallinity of the catalyst’s active sites, thereby affecting its hydrogen yield potential.

Our findings reveal that the inferior activity of Cu-promoted catalysts is due to the depletion of basic sites and larger NiO crystallite size (than rest-promoted catalysts). The introduction of Fe results in a highly dispersed Ni with a stable NiFe phase, but dilution of active sites results in low hydrogen yield. Conversely, Sr promotion enhances the basicity and accessibility of NiO active sites both on the surface and within the pore channels of the zeolite, leading to a notable hydrogen yield of 28 % at 700℃ after 300 min. Furthermore, the addition of 2 wt% ceria significantly optimizes Ni dispersion within the pore channels and surges the maximum population of basic sites (including the presence of very strong basic sites), achieving 35 % hydrogen yield at 700 °C and ∼ 70 % at 800℃. This investigation underscores the critical role of promoter-induced modifications in enhancing catalyst performance for hydrogen production, contributing to the development of more efficient and sustainable energy conversion technologies.

在甲烷干重整的框架内,利用具有成本效益的镍支撑催化剂,通过甲烷(CH4)和二氧化碳(CO2)这两种普遍存在的温室气体的转化,实现可持续制氢。利用结晶多孔沸石(特别是 ZSM-5)可增强镍(Ni)在催化剂表面及其孔道内的分散,从而提高催化效率。在此,我们研究了在 5Ni/ZSM-5 催化剂中加入各种促进剂(Ce、Cs、Cu、Fe、Sr)的影响,系统地探讨了这些改性如何影响催化剂活性位点的还原性、碱性和结晶度,从而影响其产氢潜力。铁的引入使镍高度分散,形成稳定的镍铁相,但活性位点的稀释导致氢气产量低。相反,锶的促进则增强了沸石表面和孔道内氧化镍活性位点的碱性和可接近性,从而在 300 分钟后,700℃ 时的产氢量显著提高到 28%。此外,添加 2 wt% 的铈可显著优化孔道内镍的分散,并增加碱性位点的最大数量(包括存在非常强的碱性位点),从而在 700 ℃ 时获得 35% 的氢产率,在 800 ℃ 时达到 70%。这项研究强调了促进剂诱导的改性在提高催化剂制氢性能方面的关键作用,有助于开发更高效、更可持续的能源转换技术。
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引用次数: 0
Design optimization of the cooling systems with PCM-to-air heat exchanger for the energy saving of the residential buildings 利用 PCM 空气热交换器优化住宅建筑节能冷却系统的设计
IF 6.3 Q1 Energy Pub Date : 2024-05-19 DOI: 10.1016/j.ecmx.2024.100630
Qian Zhang , Thor Alexis Salazar Sazon , Fredrik Skaug Fadnes , Xianyong Peng , Naveed Ahmed , Homam Nikpey , Mohammad Mansouri , Mohsen Assadi

Driven by a rapid surge in cooling demand in buildings, the energy consumption dedicated to cooling has experienced remarkable growth. To address this challenge, the adoption of latent heat thermal energy storage utilizing phase change materials (PCM) has gained significant momentum in recent years. This paper presents the design and evaluation of an integrated latent heat thermal energy storage (ILHTES) system tailored for residential buildings. This system integrates a PCM-to-air heat exchanger (PAHX) with an air conditioning unit. Modelica language is utilized to develop a numerical model for the ILHTES system. The heat transfer model of the PAHX is developed and validated using existing literature data. To simulate the dynamic behavior and energy consumption of the residential building, the open-source library AixLib is adopted. The developed ILHTES system model is used for the optimization of key design variables, including the PCM slab thickness and air flow rate, based on the results of long-term simulations covering the entire cooling season. Evaluation of the energy saving potential of the optimized ILHTES systems is carried out in comparison to conventional air conditioning systems, considering various climatic conditions in five European cities. The results highlight the profound impact of PCM types on the Energy Saving Ratio (ESR) throughout the entire cooling season. Among the four commercially available PCMs examined—RT27, RT25, RT20, and RT18—RT25 consistently outperforms the others. Across all five cities investigated, using RT25 leads to a minimum ESR of 16% in Catania and a maximum ESR of 44.7% in Stockholm for the entire cooling season.

在建筑物制冷需求急剧增长的推动下,用于制冷的能耗也经历了显著增长。为应对这一挑战,近年来,利用相变材料(PCM)进行潜热蓄热的发展势头迅猛。本文介绍了一种专为住宅楼量身定制的集成潜热蓄热系统(ILHTES)的设计和评估。该系统集成了 PCM 空气热交换器 (PAHX) 和空调设备。Modelica 语言用于开发 ILHTES 系统的数值模型。PAHX 的传热模型是利用现有文献数据开发和验证的。为了模拟住宅楼的动态行为和能耗,采用了开源库 AixLib。根据整个制冷季节的长期模拟结果,开发的 ILHTES 系统模型用于优化关键设计变量,包括 PCM 板厚度和空气流速。考虑到欧洲五个城市的各种气候条件,与传统空调系统相比,对经过优化的 ILHTES 系统的节能潜力进行了评估。结果凸显了 PCM 类型对整个制冷季节节能率(ESR)的深远影响。在所研究的四种市售 PCM(RT27、RT25、RT20 和 RT18)中,RT25 的性能始终优于其他 PCM。在调查的所有五个城市中,使用 RT25 可使卡塔尼亚在整个制冷季节的 ESR 最低达到 16%,而斯德哥尔摩的 ESR 最高达到 44.7%。
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引用次数: 0
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Energy Conversion and Management-X
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