Wind energy plays a pivotal role in the ongoing effort to reduce carbon emissions in the energy sector. With the increasing evidence of climate change, there is a growing concern regarding the planning and operation of wind energy resources. Accurate forecasts are essential to understand the frequency distribution of wind speed data in a given area and, consequently, to estimate energy production. This paper aims to analyze the wind resources under climate change, assess their potential, and create zoning maps for wind energy production in the island of Ireland. For this objective, wind speed data from 31 general circulation models (GCMs) and two climate change scenarios were utilized for both hindcast and forecast periods in 1981–2010 and 2021–2050, respectively. The GCM outputs were first bias-corrected and then post-processed using various (non–)parametric statistical distributions and 3 Copula families. The results indicate an expected decrease in the average wind speed in the region up to ∼ 21 % by 2050, contingent on the climate scenarios under consideration and the target point. Ultimately, this study concludes by presenting wind power density maps specifically to the study region, offering valuable insights for sustainable energy planning.
{"title":"A copula post-processing method for wind power projections under climate change","authors":"Sogol Moradian , Salem Gharbia , Gregorio Iglesias , Agnieszka Indiana Olbert","doi":"10.1016/j.ecmx.2024.100660","DOIUrl":"https://doi.org/10.1016/j.ecmx.2024.100660","url":null,"abstract":"<div><p>Wind energy plays a pivotal role in the ongoing effort to reduce carbon emissions in the energy sector. With the increasing evidence of climate change, there is a growing concern regarding the planning and operation of wind energy resources. Accurate forecasts are essential to understand the frequency distribution of wind speed data in a given area and, consequently, to estimate energy production. This paper aims to analyze the wind resources under climate change, assess their potential, and create zoning maps for wind energy production in the island of Ireland. For this objective, wind speed data from 31 general circulation models (GCMs) and two climate change scenarios were utilized for both hindcast and forecast periods in 1981–2010 and 2021–2050, respectively. The GCM outputs were first bias-corrected and then post-processed using various (non–)parametric statistical distributions and 3 Copula families. The results indicate an expected decrease in the average wind speed in the region up to ∼ 21 % by 2050, contingent on the climate scenarios under consideration and the target point. Ultimately, this study concludes by presenting wind power density maps specifically to the study region, offering valuable insights for sustainable energy planning.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001387/pdfft?md5=3903fc0d644b5e7f51bf5319146156c7&pid=1-s2.0-S2590174524001387-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141540711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Macroalgae blooms have been observed along the coastal zones of the Baltic Sea in recent decades, possibly as a result of global climate change. Excess algae biomass washed ashore the beaches reduces their attractiveness for recreational activities, produces greenhouse gases, and causes secondary pollution. To assess the most promising technology for processing excess beach-cast seaweed biomass into liquid biofuel, researchers conducted an inventory and a life cycle assessment analysis (LCA) of two thermochemical technologies: hydrothermal liquefaction (HTL) and pyrolysis. The resulting liquid fuels are expected to be used as heavy fuel oil (HFO) or fuel oil grade 6 in accordance with ASTM D396 in a mixture with HFO from fossil sources. The production of HFO from fossil sources was used as a basic comparison scenario. If one considers the possibility of replacing part of fossil hydrocarbons with synthetic fuels from seaweed biomass, the most climate-neutral would be Ulva sp. pyrolysis (GWP100 884.3 kg CO2-Eq per 1 Mg of fuel), but HTL would have GWP100 only for 9.6 % higher (969.6 kg CO2-Eq per 1 Mg of fuel). Environmental and climatic impacts of pyrolysis and HTL are very sensitive to the type of electricity used, so shifting from a traditional electricity source to wind energy leads to GWP100 decreasing to a level of 838 and 628 kg CO2-Eq per 1 Mg of fuel for pyrolysis and HTL, respectively, and HTL becoming a technology with less environmental impact. In baseline scenario the ozone depletion potential for the two processes under consideration is almost equal (difference is only 2.4 %). HTL is more sustainable in comparison with pyrolysis in term of human toxicity (HTL potential is 1.6 times lower) and terrestrial acidification (HTL potential is 1.9 times lower).
{"title":"Life cycle assessments of biofuel production from beach-cast seaweed by pyrolysis and hydrothermal liquefaction","authors":"Yuliya Kulikova , Galina Ilinykh , Natalia Sliusar , Olga Babich , Mohamed Bassyouni","doi":"10.1016/j.ecmx.2024.100647","DOIUrl":"https://doi.org/10.1016/j.ecmx.2024.100647","url":null,"abstract":"<div><p>Macroalgae blooms have been observed along the coastal zones of the Baltic Sea in recent decades, possibly as a result of global climate change. Excess algae biomass washed ashore the beaches reduces their attractiveness for recreational activities, produces greenhouse gases, and causes secondary pollution. To assess the most promising technology for processing excess beach-cast seaweed biomass into liquid biofuel, researchers conducted an inventory and a life cycle assessment analysis (LCA) of two thermochemical technologies: hydrothermal liquefaction (HTL) and pyrolysis. The resulting liquid fuels are expected to be used as heavy fuel oil (HFO) or fuel oil grade 6 in accordance with ASTM D396 in a mixture with HFO from fossil sources. The production of HFO from fossil sources was used as a basic comparison scenario. If one considers the possibility of replacing part of fossil hydrocarbons with synthetic fuels from seaweed biomass, the most climate-neutral would be <em>Ulva</em> sp. pyrolysis (GWP100 884.3 kg CO2-Eq per 1 Mg of fuel), but HTL would have GWP100 only for 9.6 % higher (969.6 kg CO<sub>2</sub>-Eq per 1 Mg of fuel). Environmental and climatic impacts of pyrolysis and HTL are very sensitive to the type of electricity used, so shifting from a traditional electricity source to wind energy leads to GWP100 decreasing to a level of 838 and 628 kg CO2-Eq per 1 Mg of fuel for pyrolysis and HTL, respectively, and HTL becoming a technology with less environmental impact. In baseline scenario the ozone depletion potential for the two processes under consideration is almost equal (difference is only 2.4 %). HTL is more sustainable in comparison with pyrolysis in term of human toxicity (HTL potential is 1.6 times lower) and terrestrial acidification (HTL potential is 1.9 times lower).</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001259/pdfft?md5=0f9c816e3fd79e170d0180281ff8f50c&pid=1-s2.0-S2590174524001259-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141543334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-01DOI: 10.1016/j.ecmx.2024.100686
In this paper, we introduce a novel two-degree-of-freedom piezoelectric stack hybrid energy harvester including a piezoelectric stack and a set of piezoelectric layers. By incorporating a mechanical stopper and bending leaf springs to achieve frequency up-conversion, we significantly enhance the voltage response of the system. We compare the output performance of prototypes with different spring stiffness. The experimental results show that, at a frequency of 7.8 Hz and an acceleration of 0.8 g, the piezoelectric layers on the lower beam of bending leaf springs generate a peak voltage of 18.92 V, and its instantaneous output power is 32 mW. Meanwhile, the piezoelectric stack produces a peak voltage of 28.56 V, with an instantaneous output power of 3.83 W. Moreover, an increase in the stiffness of the bending leaf spring leads to a decrease in voltage response and power output. This research can facilitate the development of hybrid piezoelectric self-powered applications.
本文介绍了一种新型二自由度压电叠层混合能量收集器,包括一个压电叠层和一组压电层。通过加入机械挡板和弯曲板簧来实现频率上转换,我们显著提高了系统的电压响应。我们比较了具有不同弹簧刚度的原型的输出性能。实验结果表明,在频率为 7.8 Hz、加速度为 0.8 g 的条件下,弯曲板簧下梁上的压电层可产生 18.92 V 的峰值电压,其瞬时输出功率为 32 mW。此外,弯曲板簧刚度的增加会导致电压响应和功率输出的下降。这项研究可促进混合压电自供电应用的发展。
{"title":"Nonlinear electromechanical behaviors of piezoelectric generators with hybrid stiffnesses","authors":"","doi":"10.1016/j.ecmx.2024.100686","DOIUrl":"10.1016/j.ecmx.2024.100686","url":null,"abstract":"<div><p>In this paper, we introduce a novel two-degree-of-freedom piezoelectric stack hybrid energy harvester including a piezoelectric stack and a set of piezoelectric layers. By incorporating a mechanical stopper and bending leaf springs to achieve frequency up-conversion, we significantly enhance the voltage response of the system. We compare the output performance of prototypes with different spring stiffness. The experimental results show that, at a frequency of 7.8 Hz and an acceleration of 0.8 g, the piezoelectric layers on the lower beam of bending leaf springs generate a peak voltage of 18.92 V, and its instantaneous output power is 32 mW. Meanwhile, the piezoelectric stack produces a peak voltage of 28.56 V, with an instantaneous output power of 3.83 W. Moreover, an increase in the stiffness of the bending leaf spring leads to a decrease in voltage response and power output. This research can facilitate the development of hybrid piezoelectric self-powered applications.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001648/pdfft?md5=a55abb388e858f4306e5b2f85fc63956&pid=1-s2.0-S2590174524001648-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141990807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-01DOI: 10.1016/j.ecmx.2024.100675
As the world addresses the increasing demand for sustainable energy solutions, biodiesel has surfaced as a viable alternative to conventional fossil fuels. The expansion of biodiesel feedstock plantations, particularly palm oil in tropical regions, can lead to deforestation, loss of biodiversity, and significant carbon emissions from the destruction of carbon-rich ecosystems. That is why this article focuses on biodiesel production from waste sources in order to maintain balance in the ecosystem. This review paper discusses the global energy landscape and the need for renewable and environmentally friendly alternatives. It explores the various waste sources in depth that are investigated for biodiesel production, comprising waste cooking oil, animal fats, algae, and other organic residues. Each feedstock is analyzed for its viability, challenges, and economic feasibility in biodiesel production. A critical assessment of different biodiesel production methods, such as transesterification, pyrolysis, thermochemical conversion, anaerobic digestion, thermal cracking, hydro-treating and enzymatic processes, is presented, highlighting the key factors influencing their efficiency and scalability. Recent developments to enhance waste-derived biodiesel production’s sustainability and economic viability to meet UN Sustainable Development Goals are also highlighted. Furthermore, the environmental impact of biodiesel, including greenhouse gas emissions and land use, is discussed to provide a holistic understanding of its ecological footprint. The biodiesel from waste sources can significantly increase the brake thermal efficiency of the engine along with a substantial decrease in emissions like CO and HC. However, the NOx and CO2 emissions are increased with the application of biodiesel from waste sources. The CO2 and NOx emissions can be reduced by exhaust gas recirculation and selective catalytic reduction techniques. The paper also addresses regulatory frameworks and standards governing biodiesel production from waste sources, emphasizing the need for harmonized policies to encourage widespread adoption. The paper concludes by outlining future research directions and potential breakthroughs that could further enhance biodiesel production’s effectiveness, sustainability, and scalability from waste sources. Waste Cooking Oil (WCO) and animal fats are currently the most economically feasible options for biodiesel production due to their low cost and established collection and processing infrastructure. Algae present high potential but require technological advancements and cost reductions to become economically viable. This review aims to assist researchers, policymakers, and industry stakeholders in advancing the utilization of waste materials for biodiesel production, promoting a more sustainable energy landscape.
随着全球对可持续能源解决方案的需求日益增长,生物柴油已成为传统化石燃料的一种可行替代品。生物柴油原料种植园的扩大,尤其是热带地区棕榈油种植园的扩大,会导致森林砍伐、生物多样性丧失,以及因破坏富碳生态系统而产生大量碳排放。因此,本文重点关注利用废物生产生物柴油,以维持生态系统的平衡。本综述文件讨论了全球能源状况以及对可再生和环保替代品的需求。文章深入探讨了用于生产生物柴油的各种废弃物来源,包括废弃食用油、动物脂肪、藻类和其他有机残留物。分析了每种原料在生物柴油生产中的可行性、挑战和经济可行性。报告对不同的生物柴油生产方法,如酯交换、热解、热化学转化、厌氧消化、热裂解、加氢处理和酶法工艺等进行了严格评估,强调了影响其效率和可扩展性的关键因素。此外,还重点介绍了为实现联合国可持续发展目标而提高废物衍生生物柴油生产的可持续性和经济可行性的最新进展。此外,还讨论了生物柴油对环境的影响,包括温室气体排放和土地使用,以全面了解其生态足迹。从废弃物中提取生物柴油可显著提高发动机的制动热效率,同时大幅减少 CO 和 HC 等排放物。然而,应用废物来源生物柴油后,氮氧化物和二氧化碳的排放量会增加。通过废气再循环和选择性催化还原技术可以减少 CO2 和 NOx 的排放。论文还讨论了利用废物生产生物柴油的监管框架和标准,强调需要统一政策以鼓励广泛采用。论文最后概述了未来的研究方向和潜在突破,这些方向和突破可进一步提高利用废物生产生物柴油的有效性、可持续性和可扩展性。废食用油 (WCO) 和动物脂肪目前是生物柴油生产中最具经济可行性的选择,因为它们的成本低,而且已有成熟的收集和加工基础设施。藻类具有很高的潜力,但需要技术进步和成本降低才能在经济上可行。本综述旨在帮助研究人员、政策制定者和行业利益相关者推动利用废弃材料生产生物柴油,促进更可持续的能源格局。
{"title":"A review of major trends, opportunities, and technical challenges in biodiesel production from waste sources","authors":"","doi":"10.1016/j.ecmx.2024.100675","DOIUrl":"10.1016/j.ecmx.2024.100675","url":null,"abstract":"<div><p>As the world addresses the increasing demand for sustainable energy solutions, biodiesel has surfaced as a viable alternative to conventional fossil fuels. The expansion of biodiesel feedstock plantations, particularly palm oil in tropical regions, can lead to deforestation, loss of biodiversity, and significant carbon emissions from the destruction of carbon-rich ecosystems. That is why this article focuses on biodiesel production from waste sources in order to maintain balance in the ecosystem. This review paper discusses the global energy landscape and the need for renewable and environmentally friendly alternatives. It explores the various waste sources in depth that are investigated for biodiesel production, comprising waste cooking oil, animal fats, algae, and other organic residues. Each feedstock is analyzed for its viability, challenges, and economic feasibility in biodiesel production. A critical assessment of different biodiesel production methods, such as transesterification, pyrolysis, thermochemical conversion, anaerobic digestion, thermal cracking, hydro-treating and enzymatic processes, is presented, highlighting the key factors influencing their efficiency and scalability. Recent developments to enhance waste-derived biodiesel production’s sustainability and economic viability to meet UN Sustainable Development Goals are also highlighted. Furthermore, the environmental impact of biodiesel, including greenhouse gas emissions and land use, is discussed to provide a holistic understanding of its ecological footprint. The biodiesel from waste sources can significantly increase the brake thermal efficiency of the engine along with a substantial decrease in emissions like CO and HC. However, the NOx and CO<sub>2</sub> emissions are increased with the application of biodiesel from waste sources. The CO<sub>2</sub> and NOx emissions can be reduced by exhaust gas recirculation and selective catalytic reduction techniques. The paper also addresses regulatory frameworks and standards governing biodiesel production from waste sources, emphasizing the need for harmonized policies to encourage widespread adoption. The paper concludes by outlining future research directions and potential breakthroughs that could further enhance biodiesel production’s effectiveness, sustainability, and scalability from waste sources. Waste Cooking Oil (WCO) and animal fats are currently the most economically feasible options for biodiesel production due to their low cost and established collection and processing infrastructure. Algae present high potential but require technological advancements and cost reductions to become economically viable. This review aims to assist researchers, policymakers, and industry stakeholders in advancing the utilization of waste materials for biodiesel production, promoting a more sustainable energy landscape.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001533/pdfft?md5=7739066aba63e3866d2812919c113922&pid=1-s2.0-S2590174524001533-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141841533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-01DOI: 10.1016/j.ecmx.2024.100668
Electricity generation will need to reach net zero emissions globally in 2050. This will require an increase in share of renewable energy and the implementation of a controllable carbon-free base-load source. Nuclear fusion is a promising option to decarbonize base-load electricity production but its capital cost still doubles the one of technologically more mature alternatives such as large photovoltaic fields or off-shore wind installations. Within this framework, the retrofit of a dismissed power-plant could allow significant cost savings, thus facilitating the realization of a fusion electricity demonstrator. Among fusion reactors, stellarators are a valid alternative to tokamaks thanks to the higher blanket temperature and inherent continuous operation. In this scenario, we posit the challenge to use a nuclear fusion stellarator-based reactor to retrofit conventional power plants (PPs). Specifically, we select a nuclear fission plant in France and a supercritical coal fired site in Italy, by constructing 4 different retrofit scenarios as a function of the re-used components. We compare each option with a greenfield and optimized plant with the same reactor thermal power. through a thermodynamic, economic, and investment analysis.
The results proves significant savings by retrofitting an existing plant, with a CapEx reduction up to compared to the greenfield plants. Specifically, the most convenient retrofit strategy is to select a site that already implements cutting edge thermodynamic parameters while reusing the most existing systems (i.e. buildings, steam cycle, electricity generation, and heat rejection). This is the case of the 2 x 660 MWe supercritical coal-fired plant in Italy. Therein, the LCOEs are 39 $/MWh and 51 $/MWh, calculated with an interest rate of and , respectively, and compare with the conventional energy technologies. Moreover, such costs are competitive in the current European energy markets and yield significant net present values at the plant end of life.
{"title":"Thermodynamic and economic analyses of the retrofit of existing electric power plants with fusion reactors","authors":"","doi":"10.1016/j.ecmx.2024.100668","DOIUrl":"10.1016/j.ecmx.2024.100668","url":null,"abstract":"<div><p>Electricity generation will need to reach net zero emissions globally in 2050. This will require an increase in share of renewable energy and the implementation of a controllable carbon-free base-load source. Nuclear fusion is a promising option to decarbonize base-load electricity production but its capital cost still doubles the one of technologically more mature alternatives such as large photovoltaic fields or off-shore wind installations. Within this framework, the retrofit of a dismissed power-plant could allow significant cost savings, thus facilitating the realization of a fusion electricity demonstrator. Among fusion reactors, stellarators are a valid alternative to tokamaks thanks to the higher blanket temperature and inherent continuous operation. In this scenario, we posit the challenge to use a nuclear fusion stellarator-based reactor to retrofit conventional power plants (PPs). Specifically, we select a nuclear fission plant in France and a supercritical coal fired site in Italy, by constructing 4 different retrofit scenarios as a function of the re-used components. We compare each option with a greenfield and optimized plant with the same reactor thermal power. through a thermodynamic, economic, and investment analysis.</p><p>The results proves significant savings by retrofitting an existing plant, with a CapEx reduction up to <span><math><mrow><mn>50</mn><mspace></mspace><mo>%</mo></mrow></math></span> compared to the greenfield plants. Specifically, the most convenient retrofit strategy is to select a site that already implements cutting edge thermodynamic parameters while reusing the most existing systems (i.e. buildings, steam cycle, electricity generation, and heat rejection). This is the case of the 2 x 660 MW<sub>e</sub> supercritical coal-fired plant in Italy. Therein, the LCOEs are 39 $/MWh and 51 $/MWh, calculated with an interest rate of <span><math><mrow><mn>2.7</mn><mspace></mspace><mo>%</mo></mrow></math></span> and <span><math><mrow><mn>6</mn><mspace></mspace><mo>%</mo></mrow></math></span>, respectively, and compare with the conventional energy technologies. Moreover, such costs are competitive in the current European energy markets and yield significant net present values at the plant end of life.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001466/pdfft?md5=6f249f55fc13e2872cc7b17d94d89c64&pid=1-s2.0-S2590174524001466-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141845047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The reversible reaction Ca(OH)2 + 104.4 kJ/mol ⇌ CaO + H2O offers several advantages as energy storage system. For example, it possesses a higher energy density than lead-acid or nickel–cadmium batteries. In addition, it has proven cyclability, low cost and worldwide availability. For this reason, it is suitable for seasonal heat storage applications. However, the raw powder material displays properties that represent a major challenge for the design of reactors that decouple power from capacity e.g. low thermal conductivity, cohesivity and tendency to form agglomerates. In order to overcome these drawbacks, different approaches to stabilize the Ca(OH)2/CaO particles have been investigated e.g. shaping, micro encapsulation, macroencapsulation, etc. The assessment of the stabilized products, however, has limitations in terms of amount of mass and reaction conditions as it is carried out in TA (thermal analyzer). Furthermore, it does not allow to analyze the structural decay and agglomeration of stabilized particles in-situ. For this reason, a more comprehensive assessment of a bulk of material under reactor conditions is necessary. In this work, a reaction chamber is developed to enable the observation of a bulk of storage material (0.1 L) during thermal cycling. Thus, two samples were subject of 20 cycles of dehydration and rehydration. The experiments were carried out at a temperature range of 350 °C – 500 °C and water vapor pressure of 0 – 1 bar. The analysis of images and post experiment tests (e.g. thermogravimetric analysis (TGA), dynamometry, X-ray diffraction (XRD) analysis) prove that the mechanical strength and structural integrity resulted enhanced for both samples. In addition, it allows to further understand the bulk behavior of Ca(OH)2 granules and thus important implications for the design of technical scale reactors can be derived.
{"title":"Real-time visualization and experimental analysis of stabilized Ca(OH)2 granules for thermal energy storage","authors":"Aldo Cosquillo Mejia , Sandra Afflerbach , Marc Linder , Matthias Schmidt","doi":"10.1016/j.ecmx.2024.100656","DOIUrl":"https://doi.org/10.1016/j.ecmx.2024.100656","url":null,"abstract":"<div><p>The reversible reaction Ca(OH)<sub>2</sub> + 104.4 kJ/mol ⇌ CaO + H<sub>2</sub>O offers several advantages as energy storage system. For example, it possesses a higher energy density than lead-acid or nickel–cadmium batteries. In addition, it has proven cyclability, low cost and worldwide availability. For this reason, it is suitable for seasonal heat storage applications. However, the raw powder material displays properties that represent a major challenge for the design of reactors that decouple power from capacity e.g. low thermal conductivity, cohesivity and tendency to form agglomerates. In order to overcome these drawbacks, different approaches to stabilize the Ca(OH)<sub>2</sub>/CaO particles have been investigated e.g. shaping, micro encapsulation, macroencapsulation, etc. The assessment of the stabilized products, however, has limitations in terms of amount of mass and reaction conditions as it is carried out in TA (thermal analyzer). Furthermore, it does not allow to analyze the structural decay and agglomeration of stabilized particles in-situ. For this reason, a more comprehensive assessment of a bulk of material under reactor conditions is necessary. In this work, a reaction chamber is developed to enable the observation of a bulk of storage material (0.1 L) during thermal cycling. Thus, two samples were subject of 20 cycles of dehydration and rehydration. The experiments were carried out at a temperature range of 350 °C – 500 °C and water vapor pressure of 0 – 1 bar. The analysis of images and post experiment tests (e.g. thermogravimetric analysis (TGA), dynamometry, X-ray diffraction (XRD) analysis) prove that the mechanical strength and structural integrity resulted enhanced for both samples. In addition, it allows to further understand the bulk behavior of Ca(OH)<sub>2</sub> granules and thus important implications for the design of technical scale reactors can be derived.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S259017452400134X/pdfft?md5=06f4fb05016820a0da4922ac240ff3af&pid=1-s2.0-S259017452400134X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141596019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-01DOI: 10.1016/j.ecmx.2024.100664
This study provides a comprehensive evaluation of the techno-economic and environmental performance of six hybrid energy systems (HESs) in Kunder Char, Bangladesh, incorporating both conventional (diesel and natural gas) and renewable energy sources (solar and wind). Using HOMER Pro software, a comparative analysis of five off-grid systems and one on-grid system are conducted for assessing their cost-effectiveness, energy efficiencies, and environmental impacts under various sensitivity conditions. After thorough evaluation the on-grid system has emerged as the most economically viable option, with a levelized cost of energy (LCOE) of $0.0436/kWh and a net present cost (NPC) of $1.43 million. It also produced minimal waste energy (0.381 %) but with high CO2 emissions. In contrast, the PV-Battery setup, though the most expensive with an LCOE of $0.266/kWh and an NPC of $3.36 million, offered the benefit of zero emissions and generated 40 % excess electricity. Sensitivity analyses highlighted the influence of solar radiation (4.45 kWh/m2/day), wind speed (4.81 m/s), and fuel price (Diesel: $1/L) on these systems, providing insights into their operational dynamics under varying environmental and economic scenarios. The findings highlight the trade-offs between cost, sustainability, and efficiency, promoting energy solutions customized to meet the specific needs of remote regions like Kunder Char. This study also helps in understanding the potential of hybrid systems to meet energy demands sustainably in challenging geographical and economic landscapes.
{"title":"Techno-economic and environmental analysis of hybrid energy systems for remote areas: A sustainable case study in Bangladesh","authors":"","doi":"10.1016/j.ecmx.2024.100664","DOIUrl":"10.1016/j.ecmx.2024.100664","url":null,"abstract":"<div><p>This study provides a comprehensive evaluation of the techno-economic and environmental performance of six hybrid energy systems (HESs) in Kunder Char, Bangladesh, incorporating both conventional (diesel and natural gas) and renewable energy sources (solar and wind). Using HOMER Pro software, a comparative analysis of five off-grid systems and one on-grid system are conducted for assessing their cost-effectiveness, energy efficiencies, and environmental impacts under various sensitivity conditions. After thorough evaluation the on-grid system has emerged as the most economically viable option, with a levelized cost of energy (LCOE) of $0.0436/kWh and a net present cost (NPC) of $1.43 million. It also produced minimal waste energy (0.381 %) but with high CO<sub>2</sub> emissions. In contrast, the PV-Battery setup, though the most expensive with an LCOE of $0.266/kWh and an NPC of $3.36 million, offered the benefit of zero emissions and generated 40 % excess electricity. Sensitivity analyses highlighted the influence of solar radiation (4.45 kWh/m<sup>2</sup>/day), wind speed (4.81 m/s), and fuel price (Diesel: $1/L) on these systems, providing insights into their operational dynamics under varying environmental and economic scenarios. The findings highlight the trade-offs between cost, sustainability, and efficiency, promoting energy solutions customized to meet the specific needs of remote regions like Kunder Char. This study also helps in understanding the potential of hybrid systems to meet energy demands sustainably in challenging geographical and economic landscapes.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001429/pdfft?md5=8bc6c876bdeb659528fe766e049db440&pid=1-s2.0-S2590174524001429-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141623511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-01DOI: 10.1016/j.ecmx.2024.100654
Anga Hackula , Xue Ning , Gillian Collins , Stephen A. Jackson , Niall D. O’Leary , Chen Deng , Richard O’Shea , Jerry D. Murphy , David M. Wall
Closed-loop systems enable circular economy systems and applications in the food and beverage sector to enhance decarbonisation. Whiskey distillation by-products are amenable to anaerobic digestion and thus facilitate resource recovery and circularity. Furthermore, biochar derived from whiskey barrels can be used as a carbonaceous additive within anaerobic digestion to enhance biomethane production. In this paper, biochar produced from the pyrolysis of discarded whiskey barrels at 300 °C, was shown to enhance biomethane production by up to 15 %. A kinetic analysis revealed that the biochar reduced the biomethane lag time by up to 42 %. The mass and energy balance of this integrated anaerobic digestion-pyrolysis system was evaluated. The overall system efficiency was assessed at 68 % of all input energy (expressed on a primary energy basis); utilisation of renewable electricity could increase this efficiency to 71 %. Biochar from discarded whiskey barrels can provide a decarbonisation pathway for whiskey distilleries but may be constrained by the total resource available.
闭环系统使循环经济系统成为可能,并应用于食品和饮料行业,以加强去碳化。威士忌蒸馏副产品适合厌氧消化,因此有利于资源回收和循环利用。此外,从威士忌酒桶中提取的生物炭可用作厌氧消化过程中的碳质添加剂,以提高生物甲烷的产量。在本文中,废弃威士忌酒桶在 300 °C 下热解产生的生物炭可提高生物甲烷产量达 15%。动力学分析表明,生物炭可将生物甲烷的滞后时间缩短 42%。对这种厌氧消化-热解综合系统的质量和能量平衡进行了评估。经评估,整个系统的效率为所有输入能量的 68%(以一次能源为基础);利用可再生能源发电可将效率提高到 71%。从废弃威士忌酒桶中提取生物炭可以为威士忌蒸馏厂提供脱碳途径,但可能会受到可用资源总量的限制。
{"title":"Investigating the effects of whiskey-barrel derived biochar addition to anaerobic digestion at a distillery: A study on energy yield and system efficiency","authors":"Anga Hackula , Xue Ning , Gillian Collins , Stephen A. Jackson , Niall D. O’Leary , Chen Deng , Richard O’Shea , Jerry D. Murphy , David M. Wall","doi":"10.1016/j.ecmx.2024.100654","DOIUrl":"https://doi.org/10.1016/j.ecmx.2024.100654","url":null,"abstract":"<div><p>Closed-loop systems enable circular economy systems and applications in the food and beverage sector to enhance decarbonisation. Whiskey distillation by-products are amenable to anaerobic digestion and thus facilitate resource recovery and circularity. Furthermore, biochar derived from whiskey barrels can be used as a carbonaceous additive within anaerobic digestion to enhance biomethane production. In this paper, biochar produced from the pyrolysis of discarded whiskey barrels at 300 °C, was shown to enhance biomethane production by up to 15 %. A kinetic analysis revealed that the biochar reduced the biomethane lag time by up to 42 %. The mass and energy balance of this integrated anaerobic digestion-pyrolysis system was evaluated. The overall system efficiency was assessed at 68 % of all input energy (expressed on a primary energy basis); utilisation of renewable electricity could increase this efficiency to 71 %. Biochar from discarded whiskey barrels can provide a decarbonisation pathway for whiskey distilleries but may be constrained by the total resource available.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001326/pdfft?md5=2489285e320fa3e1a3b1eb00996fddae&pid=1-s2.0-S2590174524001326-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141478885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-01DOI: 10.1016/j.ecmx.2024.100672
SiC-based duplex claddings, consisting of monolithic SiC and SiC/SiC fiber composite, are emerging as a promising candidate for accident-tolerant fuel (ATF) systems in nuclear reactors. To analyze the performance of ATFs with SiC-based duplex claddings, a comprehensive computational analysis framework is presented that captures the essential properties and behaviors of the UO2-SiC fuel system. Utilizing a previously developed continuum damage model, the pseudo-ductile behavior of SiC/SiC fiber composites is accurately modelled, connecting damage evolution parameters to instantaneous stiffness matrix degradation. This framework is used to investigate the performance of UO2-SiC fuel rods under normal operating conditions and a typical Loss of Coolant Accident (LOCA) scenario. We assess the effects of the thickness ratio of the monolithic SiC and SiC-based composite layers, as well as pellet-clad cold gap thickness on the failure and leakage probabilities of the cladding. These claddings, with a thickness ratio ranging from 0.25 to 0.75, demonstrated minimal failure and leakage probabilities for both the original and reduced pellet-clad gap thickness (82.5/70 µm). When the gap thickness was further reduced to 57.5 µm, pellet-cladding mechanical interaction was observed and this greatly elevated the failure probability of the MSiC layer, thus giving rise to a loss of hermeticity. This research underscores the significant role of varying individual layer thicknesses in shaping fuel rod safety and offers potential for optimization across diverse operational conditions.
{"title":"Thermomechanical analysis of SiC-based duplex claddings with varying thickness ratio for accident-tolerant nuclear fuel systems","authors":"","doi":"10.1016/j.ecmx.2024.100672","DOIUrl":"10.1016/j.ecmx.2024.100672","url":null,"abstract":"<div><p>SiC-based duplex claddings, consisting of monolithic SiC and SiC/SiC fiber composite, are emerging as a promising candidate for accident-tolerant fuel (ATF) systems in nuclear reactors. To analyze the performance of ATFs with SiC-based duplex claddings, a comprehensive computational analysis framework is presented that captures the essential properties and behaviors of the UO<sub>2</sub>-SiC fuel system. Utilizing a previously developed continuum damage model, the pseudo-ductile behavior of SiC/SiC fiber composites is accurately modelled, connecting damage evolution parameters to instantaneous stiffness matrix degradation. This framework is used to investigate the performance of UO<sub>2</sub>-SiC fuel rods under normal operating conditions and a typical Loss of Coolant Accident (LOCA) scenario. We assess the effects of the thickness ratio of the monolithic SiC and SiC-based composite layers, as well as pellet-clad cold gap thickness on the failure and leakage probabilities of the cladding. These claddings, with a thickness ratio ranging from 0.25 to 0.75, demonstrated minimal failure and leakage probabilities for both the original and reduced pellet-clad gap thickness (82.5/70 µm). When the gap thickness was further reduced to 57.5 µm, pellet-cladding mechanical interaction was observed and this greatly elevated the failure probability of the MSiC layer, thus giving rise to a loss of hermeticity. This research underscores the significant role of varying individual layer thicknesses in shaping fuel rod safety and offers potential for optimization across diverse operational conditions.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001508/pdfft?md5=c0bdcef05f6b3385ec42e7eed917993d&pid=1-s2.0-S2590174524001508-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141839237","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-01DOI: 10.1016/j.ecmx.2024.100665
Photovoltaic-thermoelectric hybrid devices aim at harvesting the entire solar spectrum via both direct photovoltaic conversion and subsequent thermoelectric conversion of the heat generated in the solar cell. One emerging strategy to improve their efficiency is to implement a photothermal interface between the photovoltaic cell and the thermoelectric module. Modeling such a complex system (photovoltaic cell, photothermal interface and thermoelectric generator) to design an optimal architecture is a challenging task, as it requires to take into account a large number of parameters in a multi-layered system, as well as the coupling between optical, thermal and electrical effects. To do so, we present here a multiphysics tool to predict the temperature distribution and power output of hybrid devices integrating a photothermal interface. Our model shows a good quantitative agreement with previous theoretical and experimental works from the literature using limited material parameters. We discuss the need for additional parameters for accurate modeling of experimental devices. We envision that our multiphysics modeling tool will be key for the design of optimal photothermal interfaces for efficient photovoltaic-thermoelectric hybrid devices.
{"title":"Multiphysics modeling tool for photovoltaic-thermoelectric hybrid devices integrating a photothermal interface","authors":"","doi":"10.1016/j.ecmx.2024.100665","DOIUrl":"10.1016/j.ecmx.2024.100665","url":null,"abstract":"<div><p>Photovoltaic-thermoelectric hybrid devices aim at harvesting the entire solar spectrum via both direct photovoltaic conversion and subsequent thermoelectric conversion of the heat generated in the solar cell. One emerging strategy to improve their efficiency is to implement a photothermal interface between the photovoltaic cell and the thermoelectric module. Modeling such a complex system (photovoltaic cell, photothermal interface and thermoelectric generator) to design an optimal architecture is a challenging task, as it requires to take into account a large number of parameters in a multi-layered system, as well as the coupling between optical, thermal and electrical effects. To do so, we present here a multiphysics tool to predict the temperature distribution and power output of hybrid devices integrating a photothermal interface. Our model shows a good quantitative agreement with previous theoretical and experimental works from the literature using limited material parameters. We discuss the need for additional parameters for accurate modeling of experimental devices. We envision that our multiphysics modeling tool will be key for the design of optimal photothermal interfaces for efficient photovoltaic-thermoelectric hybrid devices.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001430/pdfft?md5=ee75d6b3b6dcd690a68890291b552598&pid=1-s2.0-S2590174524001430-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141842561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}