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Atmospheric ammonia concentration measurements in Japanese laying hen buildings and modeling for emission inventory 日本蛋鸡建筑大气氨浓度测量及排放清单模拟
IF 3.4 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 DOI: 10.1016/j.aeaoa.2026.100422
T. Yoshida , G. Katata , H. Kuroda , N. Tanaka
Atmospheric ammonia (NH3) from livestock contributes to PM2.5 formation and nitrogen loading in watersheds. Although chemical transport models often adopt the emission factor (EF) and monthly variation coefficient (Mf) from European NH3 emission inventories due to the limited availability of direct measurement data worldwide, their applicability to Asian countries remains unknown. In this study, we observed the spatial distributions and diurnal changes in NH3 concentrations within windowless laying hen buildings during May–October of 2022 and 2023. The observed spatial distribution showed that the major drivers of monthly NH3 emissions were air temperature and ventilation rate. Moreover, NH3 concentrations changed depending on the number of days after manure removal according to the diurnal observations. A regression analysis was conducted using observed temperature, ventilation rate, and manure removal to develop a statistical model for estimating NH3 emission rates based on ambient temperature data. Subsequently, model application to the different climatic conditions were performed by using the typical monthly mean air temperature from the surface weather databases at several major poultry production cities in Japan. The results demonstrated that the calculated EF in Japan varied substantially (0.11–0.52 kgNH3 y−1 head−1) depending on air temperature, whereas that in the Netherlands remained near the lowest values. The summertime Mf was higher in Japan than that in the Netherlands, suggesting differences in climate and manure management systems between Japan and Europe. To improve the accuracy of livestock emission inventories, further observations for NH3 emission rate estimates are required for other sources, such as manure storage and land application.
来自牲畜的大气氨(NH3)有助于PM2.5的形成和流域的氮负荷。尽管由于全球范围内直接测量数据的可用性有限,化学运输模型通常采用欧洲NH3排放清单中的排放因子(EF)和月变化系数(Mf),但它们对亚洲国家的适用性尚不清楚。本研究对2022年5 - 10月和2023年5 - 10月无窗蛋鸡建筑内NH3浓度的空间分布和日变化进行了观测。观测的空间分布表明,月NH3排放的主要驱动因素是气温和通风量。此外,根据日观测,NH3浓度随去粪天数的变化而变化。利用观测温度、通风量和粪便去除率进行回归分析,建立基于环境温度数据估算NH3排放率的统计模型。随后,利用日本几个主要家禽生产城市地面气象数据库的典型月平均气温,对不同气候条件进行了模型应用。结果表明,日本的计算EF随气温变化很大(0.11-0.52 kgNH3 y - 1 head - 1),而荷兰的计算EF则保持在最低值附近。日本的夏季Mf高于荷兰,这表明日本和欧洲在气候和粪便管理系统上存在差异。为了提高牲畜排放清单的准确性,需要对其他来源(如粪肥储存和土地利用)的NH3排放率估计进行进一步观察。
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引用次数: 0
Improved methane flux estimation from hyper-spectral imagery via log-domain matched filtering and background homogenization 基于对数域匹配滤波和背景均匀化的高光谱图像甲烷通量估算方法的改进
IF 3.4 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 DOI: 10.1016/j.aeaoa.2026.100417
Fabrizio Masin, Tiziano Maestri, Michele Martinazzo, Giorgia Proietti Pelliccia
New satellite hyper-spectral sensors, such as PRISMA of the Italian Space Agency, observe large portions of the Earth’s surface at visible and at shortwave infrared wavelengths with high spectral and spatial resolutions, enabling the investigation of individual molecular species and the localization of emission sources. The ‘Matched Filter’ (MF) methodology, widely exploited in the methane source identification and in the estimation of enhanced concentrations, is discussed in its theoretical foundations, revised and extended within an integrated processing framework. We apply an estimator (termed MF-EVO) operating in the logarithmic radiance-ratio domain, i.e. optical depth space, which allows to overcome the limitations imposed by the linearization assumption of the classical MF and improves robustness across a wide range of methane concentration enhancements. Results from MF-EVO are compared to the traditional algorithm for a set of synthetic PRISMA observations accounting for both homogeneous and heterogeneous background conditions. The MF-EVO algorithm demonstrates superior performance over the MF-Classic method in identifying methane sources across all idealized conditions. Specifically, the estimated identification limit for ΔXCH4 is approximately 0.05 ppm for MF-EVO, significantly lower than the 0.09 ppm limit for MF-Classic. Furthermore, the MF-EVO consistently outperforms the classic MF in the accurate estimation of concentration enhancements across both small and medium-to-large methane concentration scenarios. Under idealized conditions, MF-EVO achieves an error margin within 5%, which is a substantial improvement compared to the 10%–50% error range observed with the MF-Classic method. To address the challenges posed by real-world scenes, the revised MF formulation is embedded in a processing chain that includes false-positive pixel elimination and scene homogenization through image partitioning into spectrally homogeneous clusters. These steps significantly reduce background-induced artifacts and stabilize methane enhancement retrievals, enabling more reliable plume identification and flux estimation. In the application to the Mumbai metropolitan landfills, the full processing chain reduces the estimated methane fluxes by approximately 40%–55% with respect to the classical MF applied to the full scene, highlighting the impact of background homogenization and false-positive suppression on flux estimation in heterogeneous environments.
新的卫星高光谱传感器,如意大利空间局的PRISMA,以高光谱和空间分辨率以可见光和短波红外波长观测地球表面的大部分,从而能够调查单个分子种类和定位发射源。在甲烷源识别和增强浓度估计中广泛使用的“匹配过滤器”(MF)方法在其理论基础上进行了讨论,并在综合处理框架内进行了修订和扩展。我们应用了一个在对数辐射比域(即光学深度空间)操作的估计器(称为MF- evo),它可以克服经典MF线性化假设所施加的限制,并提高了在大范围的甲烷浓度增强中的鲁棒性。在考虑均匀和非均匀背景条件的一组综合PRISMA观测数据中,将MF-EVO的结果与传统算法进行了比较。在所有理想条件下,MF-EVO算法在识别甲烷源方面的性能优于MF-Classic方法。具体来说,MF-EVO对ΔXCH4的估计识别极限约为0.05 ppm,显著低于MF-Classic的0.09 ppm极限。此外,MF- evo在准确估计小、中、大甲烷浓度情景下的浓度增强方面始终优于经典MF。在理想条件下,MF-EVO的误差范围在5%以内,与MF-Classic方法观察到的10%-50%的误差范围相比,这是一个很大的改进。为了应对现实世界场景带来的挑战,修订后的MF公式被嵌入到一个处理链中,该处理链包括假阳性像素消除和通过将图像划分为光谱均匀簇的场景均匀化。这些步骤显著减少了背景诱发的伪影,稳定了甲烷增强回收,实现了更可靠的羽流识别和通量估计。在孟买都市垃圾填埋场的应用中,与应用于全场景的经典MF相比,整个处理链将估算的甲烷通量减少了约40%-55%,突出了背景均匀化和假阳性抑制对异质环境中通量估算的影响。
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引用次数: 0
Effect of filter rod structure on aerosol particle size distribution in electrically heated cigarettes 过滤棒结构对电加热卷烟中气溶胶粒径分布的影响
IF 3.4 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 DOI: 10.1016/j.aeaoa.2025.100412
Jinfeng Wu , Yihan Gao , Huaquan Sheng , Changguo Wang , Ting Fei , Cheng Liu , Jianfeng Guo , Lijun Zhu , Peicai Cui
Non-uniform and unstable particle size distributions in heated cigarette aerosols compromise the reliability of risk assessment outcomes and the quality of the smoke. This study utilized an electrically heated cigarette model to clarify how filter rod structure governs aerosol particle size distribution, which then addressed a fundamental gap in understanding how structural parameters affect aerosol evolution. Employing the SCS-DMS500 system and a controlled variable approach, the particle size distribution of aerosols from heated tobacco products was tested across varying filter segment lengths (8–24 mm) and three cooling segment structures (hollow, Collins, folded paper). Results revealed a clear competition between interception and coalescence mechanisms: within the filter segments, increasing length progressively elevated the count median diameter (CMD) while reducing number concentration (NC) and volume concentration (VC) by 48 % and 18.8 %, respectively, due to enhanced adsorptive capture. By contrast, cooling segment geometry exerted a fundamentally different form of control: Collins and folded paper filter rods yielded substantially smaller particles with higher number concentrations compared to hollow-core designs. A distinctive length-dependent reduction in CMD was observed specifically with folded paper filter rods. This study establishes the first mechanistic framework for regulating aerosol particle size through composite filter design, offering theoretical support for employing low-retention, low-coagulation control strategies aimed at reducing respiratory exposure risks.
加热后的卷烟气溶胶中颗粒大小分布的不均匀和不稳定影响了风险评估结果的可靠性和烟雾质量。本研究利用电加热香烟模型来阐明滤棒结构如何控制气溶胶粒径分布,从而解决了理解结构参数如何影响气溶胶演变的基本空白。采用SCS-DMS500系统和控制变量方法,通过不同的过滤器段长度(8-24 mm)和三种冷却段结构(空心,柯林斯,折叠纸)测试加热烟草制品气溶胶的粒径分布。结果显示,拦截和聚结机制之间存在明显的竞争:在过滤段内,由于吸附捕获增强,长度的增加逐渐提高了计数中位数直径(CMD),同时减少了数量浓度(NC)和体积浓度(VC),分别降低了48%和18.8%。相比之下,冷却段的几何形状施加了一种完全不同的控制形式:与空心芯设计相比,柯林斯和折叠的纸质过滤棒产生的颗粒更小,浓度更高。在折叠的纸过滤棒中观察到明显的长度依赖性CMD减少。本研究建立了首个通过复合过滤器设计调节气溶胶粒径的机制框架,为采用旨在降低呼吸暴露风险的低滞留、低凝控制策略提供理论支持。
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引用次数: 0
Multilinear regression analysis of PM2.5 in Kampala and Fort Portal cities: Effects of meteorological factors and lagged pollution 坎帕拉和福特Portal城市PM2.5的多元线性回归分析:气象因素和滞后污染的影响
IF 3.4 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 DOI: 10.1016/j.aeaoa.2025.100411
Fidel Raja Wabinyai , Richard Sserunjogi , Gideon Lubisia , Deo Okure , Edwin Akugizibwe , Jennifer Kutesakwe , Angela Nshimye , Alex Ndyabakira , Engineer Bainomugisha
Rapid urbanization across Sub-Saharan Africa intensifies fine particulate matter (PM2.5) pollution, yet the combined effects of meteorology and pollution persistence remain poorly understood. This study investigates the spatiotemporal variability of PM2.5 in Kampala (urban) and Fort Portal (semi-urban), Uganda, using daily observations from October 2021 to January 2024. Calibrated low-cost AirQo sensor data were integrated with meteorological parameters, including temperature, humidity, wind speed, wind direction, and precipitation, as well as one-day lagged PM2.5, to develop enhanced multilinear regression (MLR) models. Results revealed strong seasonal contrasts, with mean dry-season concentrations in Kampala (38.3 μgm−3) and Fort Portal (32.9 μgm−3) exceeding World Health Organization and NEMA-Uganda limits. Model performance varied by city, explaining up to 57 % of daily PM2.5 variability in Kampala and 80 % in Fort Portal. The inclusion of lagged PM2.5 significantly improved model accuracy, highlighting persistence effects under stagnant meteorological conditions. Wind rose analysis showed that southerly and westerly winds enhanced pollutant transport, particularly during dry months, suggesting potential transboundary contributions to Fort Portal's pollution burden. Although the models performed well during dry seasons, predictive power declined in wet seasons due to rainfall-induced washout effects not fully captured by linear formulations. These findings emphasize the importance of meteorological drivers and pollution persistence in shaping urban air quality and support data-driven interventions such as emission control, traffic management, biomass burning reduction, and regional cooperation to protect public health in rapidly urbanizing African cities.
撒哈拉以南非洲地区的快速城市化加剧了细颗粒物(PM2.5)污染,但人们对气象和污染持续性的综合影响仍知之甚少。利用2021年10月至2024年1月的日观测资料,研究了乌干达坎帕拉(城市)和波特尔堡(半城市)PM2.5的时空变化。校准后的低成本AirQo传感器数据与气象参数(包括温度、湿度、风速、风向、降水以及滞后一天的PM2.5)相结合,建立增强的多元线性回归(MLR)模型。结果显示出强烈的季节差异,坎帕拉(38.3 μgm−3)和波特尔堡(32.9 μgm−3)的旱季平均浓度超过了世界卫生组织和nema -乌干达标准。模型的性能因城市而异,坎帕拉和波尔特堡的PM2.5日变化可分别解释57%和80%。纳入滞后PM2.5显著提高了模型精度,突出了停滞气象条件下的持续效应。风玫瑰分析表明,南风和西风加强了污染物的运输,特别是在干旱月份,这表明可能对波特尔堡的污染负担有跨界贡献。尽管模型在旱季表现良好,但由于降雨引起的冲刷效应未被线性公式完全捕获,因此在雨季预测能力下降。这些研究结果强调了气象驱动因素和污染持续性在塑造城市空气质量方面的重要性,并支持数据驱动的干预措施,如排放控制、交通管理、减少生物质燃烧和区域合作,以保护快速城市化的非洲城市的公众健康。
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引用次数: 0
Assessment of contributors to airborne PAHs and heavy metals in PM10 using temporal, spatial, traffic and heating data in explainable machine learning models 在可解释的机器学习模型中使用时间、空间、交通和供暖数据评估PM10中空气中多环芳烃和重金属的贡献者
IF 3.4 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 DOI: 10.1016/j.aeaoa.2026.100413
Nikolina Račić , Stanko Ružičić , Valentino Petrić , Teo Terzić , Mario Antunović , Ivan Škaro , Gordana Pehnec , Ivan Bešlić , Ivana Jakovljević , Zdravka Sever Štrukil , Jasmina Rinkovec , Silva Žužul , Mario Lovrić
Air pollution in urban areas originates from multiple interacting sources and is strongly influenced by meteorology, yet direct emission data are often incomplete. This study quantifies how meteorological conditions, station location, and proxy indicators of traffic and residential heating affect PM10-bound polycyclic aromatic hydrocarbons (PAHs) and metals in Zagreb, Croatia. Daily concentrations of PM10, selected PAHs, metals and NO2 from four monitoring stations (2017–2020) were combined with local and ERA5 meteorology, highway traffic counts and gas consumption as emission proxies. Non-negative Matrix Factorization (NMF) was applied separately to PAHs and metals to identify dominant source-related patterns, while Random Forest regression and SHapley Additive Explanations (SHAP) were used to evaluate the influence of temporal, spatial, meteorological, traffic and heating predictors. NMF separated a heating-related PAH component dominated by Pyr and Flu from a traffic-related component characterised by BaA, Chry and BkF, and indicated enrichment of As and Pb at traffic- and industry-affected stations. Random Forest models showed higher predictive skill for PAHs (R2 ≈ 0.60–0.68) than for metals (R2 ≈ 0.24–0.42). Temperature and solar radiation were the main predictors for PAHs, whereas PM10, NO2 and station indicators dominated the prediction of metals. These results demonstrate that integrating proxy emission indicators with explainable machine learning provides an efficient framework for characterising sources and supports season- and location-specific air quality management in data-limited urban environments.
城市地区的空气污染来自多个相互作用的来源,并受到气象的强烈影响,但直接排放数据往往不完整。本研究量化了克罗地亚萨格勒布的气象条件、监测站位置以及交通和住宅供暖的代理指标对pm10结合的多环芳烃(PAHs)和金属的影响。将2017-2020年4个监测站PM10、选定多环芳烃、金属和NO2的日浓度与当地和ERA5气象、公路交通计数和汽油消耗作为排放指标相结合。采用非负矩阵分解法(NMF)分别对多环烃和金属进行分析,确定优势源相关模式;采用随机森林回归法和SHapley加性解释法(SHAP)评估时间、空间、气象、交通和供暖预测因子的影响。NMF从以BaA、Chry和BkF为特征的交通相关成分中分离出了以Pyr和Flu为主的与供暖相关的PAH成分,并表明在受交通和工业影响的站点中存在As和Pb富集。随机森林模型对多环芳烃的预测能力(R2≈0.60 ~ 0.68)高于对金属的预测能力(R2≈0.24 ~ 0.42)。温度和太阳辐射是多环芳烃的主要预测因子,PM10、NO2和气象站指标是多环芳烃的主要预测因子。这些结果表明,将代理排放指标与可解释的机器学习相结合,为表征排放源提供了一个有效的框架,并支持数据有限的城市环境中特定季节和地点的空气质量管理。
{"title":"Assessment of contributors to airborne PAHs and heavy metals in PM10 using temporal, spatial, traffic and heating data in explainable machine learning models","authors":"Nikolina Račić ,&nbsp;Stanko Ružičić ,&nbsp;Valentino Petrić ,&nbsp;Teo Terzić ,&nbsp;Mario Antunović ,&nbsp;Ivan Škaro ,&nbsp;Gordana Pehnec ,&nbsp;Ivan Bešlić ,&nbsp;Ivana Jakovljević ,&nbsp;Zdravka Sever Štrukil ,&nbsp;Jasmina Rinkovec ,&nbsp;Silva Žužul ,&nbsp;Mario Lovrić","doi":"10.1016/j.aeaoa.2026.100413","DOIUrl":"10.1016/j.aeaoa.2026.100413","url":null,"abstract":"<div><div>Air pollution in urban areas originates from multiple interacting sources and is strongly influenced by meteorology, yet direct emission data are often incomplete. This study quantifies how meteorological conditions, station location, and proxy indicators of traffic and residential heating affect PM<sub>10</sub>-bound polycyclic aromatic hydrocarbons (PAHs) and metals in Zagreb, Croatia. Daily concentrations of PM<sub>10</sub>, selected PAHs, metals and NO<sub>2</sub> from four monitoring stations (2017–2020) were combined with local and ERA5 meteorology, highway traffic counts and gas consumption as emission proxies. Non-negative Matrix Factorization (NMF) was applied separately to PAHs and metals to identify dominant source-related patterns, while Random Forest regression and SHapley Additive Explanations (SHAP) were used to evaluate the influence of temporal, spatial, meteorological, traffic and heating predictors. NMF separated a heating-related PAH component dominated by Pyr and Flu from a traffic-related component characterised by BaA, Chry and BkF, and indicated enrichment of As and Pb at traffic- and industry-affected stations. Random Forest models showed higher predictive skill for PAHs (R<sup>2</sup> ≈ 0.60–0.68) than for metals (R<sup>2</sup> ≈ 0.24–0.42). Temperature and solar radiation were the main predictors for PAHs, whereas PM<sub>10</sub>, NO<sub>2</sub> and station indicators dominated the prediction of metals. These results demonstrate that integrating proxy emission indicators with explainable machine learning provides an efficient framework for characterising sources and supports season- and location-specific air quality management in data-limited urban environments.</div></div>","PeriodicalId":37150,"journal":{"name":"Atmospheric Environment: X","volume":"29 ","pages":"Article 100413"},"PeriodicalIF":3.4,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146077693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of the area-based assimilative capacity for sustainability management of air toxic emission from petroleum and petrochemical industrial complex 发展以区域为基础的吸收能力,以可持续管理石油和石化工业综合体的空气有毒排放物
IF 3.4 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 DOI: 10.1016/j.aeaoa.2025.100409
Peemapat Jookjantra , Sarawut Thepanondh , Kiyoung Lee , Jutarat Keawboonchu , Wissawa Malakan
This study explored benzene and 1,3-butadiene emissions from a petroleum and petrochemical industrial estate in Rayong, Thailand, using a comprehensive, multi-step approach. The research combined detailed emission inventories, air dispersion modeling with AERMOD which is appropriate for assessing primary, non-reactive pollutants at near-field distances from industrial sources, and evaluations of the area's capacity to absorb pollutants. The objective was to identify emission patterns, assess environmental impacts, and pinpoint the main sources influencing pollutant levels. Results showed that storage tanks were the primary driver of benzene emissions (54 %) and wastewater treatment systems were the main source of 1,3-butadiene emissions (63 %), with source analysis confirming that benzene levels were dominated by storage tanks while 1,3-butadiene concentrations were closely tied to wastewater treatment facilities. Although most predicted ground-level concentrations complied with national ambient air quality standards, elevated levels were detected near emission sources. The assimilative capacity assessment indicated that most monitoring sites could accommodate additional emissions without exceeding regulatory limits; however, one site located beside a busy road showed a negative capacity for both pollutants, highlighting the significant impact of vehicle emissions in areas with dense industrial and traffic activities. By integrating emission inventories, dispersion modeling, and environmental thresholds, this study offers valuable insights relevant locally and transferable to other industrial regions. It stresses the importance of emission control strategies targeting both industrial processes and traffic sources. The combined methodology provides practical guidance for environmental planners and policymakers seeking to implement effective, site-specific air quality management aligned with sustainable development goals.
本研究探讨了苯和1,3-丁二烯排放从石油和石化产业在泰国罗勇,使用一个全面的,多步骤的方法。该研究结合了详细的排放清单、空气分散模型和AERMOD,该模型适用于评估工业源近场距离的主要非反应性污染物,并评估该地区吸收污染物的能力。目标是查明排放模式,评估环境影响,并查明影响污染物水平的主要来源。结果表明,储罐是苯排放的主要来源(54%),废水处理系统是1,3-丁二烯排放的主要来源(63%),污染源分析证实,苯水平主要由储罐控制,而1,3-丁二烯浓度与废水处理设施密切相关。虽然大多数预测的地面浓度符合国家环境空气质量标准,但在排放源附近检测到浓度升高。同化能力评价表明,大多数监测点可以容纳额外的排放而不超过管制限制;然而,位于繁忙道路旁的一个场地显示出两种污染物的负容量,突出了汽车排放对工业和交通活动密集地区的重大影响。通过整合排放清单、分散模型和环境阈值,本研究提供了与当地相关并可转移到其他工业区域的宝贵见解。它强调了针对工业过程和交通源的排放控制战略的重要性。综合方法为环境规划者和决策者寻求实施有效的、符合可持续发展目标的特定地点空气质量管理提供了实用指导。
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引用次数: 0
OPNet: A deep-learning approach for estimating particulate matter’s oxidative potential from satellite imagery OPNet:一种从卫星图像中估计颗粒物氧化电位的深度学习方法
IF 3.4 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-17 DOI: 10.1016/j.aeaoa.2025.100406
Alessia Carbone , Ian Hough , Gemine Vivone , Jocelyn Chanussot , Rocco Restaino , Harry Dupont , Jean-Luc Jaffrezo , Gaëlle Uzu
The oxidative potential (OP) of particulate matter (PM) reflects its ability to trigger oxidative stress in the respiratory system and is increasingly recognised as a key metric for assessing PM toxicity. Concurrently, PM has gained importance as a health indicator, leading to its inclusion in European regulations. As OP is not routinely monitored at many sites, understanding exposure and related risks remains challenging. While satellite imagery is commonly used to estimate PM mass concentration, its application to OP has not yet been explored. We present a novel deep-learning-based approach employing satellite-based surface features for OP estimation, using both OPAA and OPDTT assays on 24-hour PM10 samples collected over five years in Grenoble (France). We propose OPNet, which consists of two parts: a deep backbone that extracts surface features from one satellite image, and a predictor estimating OPAA and OPDTT using the extracted features combined with contextual variables. The architecture is trained in two stages: in the domain-adaptive task, both are jointly trained to predict daily PM10 concentration, with the backbone initialised from weights from a general classification problem. In the domain-specific task, they are jointly updated to predict either OPAA or OPDTT, with the backbone initialised from the best weights obtained in the first stage. This approach explains up to 75% of the variance in OPAA and 58% in OPDTT when using both satellite imagery and auxiliary data. It offers a cost-effective solution to improve the estimation of OP, with implications for large-scale air quality monitoring and health impact assessments.
颗粒物(PM)的氧化电位(OP)反映了其在呼吸系统中引发氧化应激的能力,并且越来越被认为是评估PM毒性的关键指标。同时,PM作为一项健康指标变得越来越重要,导致其被纳入欧洲法规。由于许多地点没有常规监测OP,因此了解暴露和相关风险仍然具有挑战性。虽然卫星图像通常用于估算PM质量浓度,但尚未探索其在OP中的应用。我们提出了一种新的基于深度学习的方法,采用基于卫星的表面特征进行OP估计,使用OPAA和OPDTT对法国格勒诺布尔五年来收集的24小时PM10样本进行分析。我们提出了OPNet,它由两部分组成:从卫星图像中提取表面特征的深层骨干,以及使用提取的特征结合上下文变量估计OPAA和OPDTT的预测器。该体系结构分为两个阶段进行训练:在领域自适应任务中,两者都被联合训练以预测每日PM10浓度,骨架从一般分类问题的权重初始化。在特定领域的任务中,它们被联合更新以预测OPAA或OPDTT,并根据第一阶段获得的最佳权重初始化骨干。当同时使用卫星图像和辅助数据时,这种方法可以解释高达75%的OPAA差异和58%的OPDTT差异。它提供了一种具有成本效益的解决办法,以改进对OP的估计,从而对大规模空气质量监测和健康影响评估产生影响。
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引用次数: 0
Methodological factors affecting ammonia emission measurement with flux chambers from field-applied biogas digestate slurry (Technical note) 影响现场应用沼气沼液通量室测量氨排放的方法学因素(技术说明)
IF 3.4 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-16 DOI: 10.1016/j.aeaoa.2025.100408
Johanna Pedersen , Sasha D. Hafner , Andreas S. Pacholski
This study evaluated technical factors influencing relative ammonia emissions following field application of biogas digestate using different slurry spreading methods. Experiments assessed: (i) slurry distribution uniformity across a trailing hose boom, (ii) the influence of driving speed, (iii) effects of hose spacing, and (iv) the effect of relocating dynamic flux chambers during measurement. Across all tests realistic application rates and representative field conditions were ensured. Results demonstrate that careful equipment setup, particularly hose selection and consistent spacing, minimized variability in measured emissions and dynamic flux chamber relocation elevated measured emissions. These findings provide practical guidance for experimental design and emission mitigation under typical farming conditions.
本研究对沼气池采用不同撒浆方式进行现场应用后影响相对氨排放的技术因素进行了评价。实验评估了:(i)尾水管臂上泥浆分布均匀性,(ii)行驶速度的影响,(iii)软管间距的影响,以及(iv)在测量过程中重新定位动态通量室的影响。在所有测试中,确保了实际的应用率和具有代表性的现场条件。结果表明,仔细的设备设置,特别是软管的选择和一致的间距,最小化了测量排放的变化,动态通量室的重新安置提高了测量排放。这些发现为典型农业条件下的试验设计和减排提供了实用指导。
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引用次数: 0
Using low-cost sensors for source attribution and health assessment: An air quality study in Brownsville, Texas 使用低成本传感器进行来源归属和健康评估:德克萨斯州布朗斯维尔的一项空气质量研究
IF 3.4 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-05 DOI: 10.1016/j.aeaoa.2025.100405
Sai Deepak Pinakana , Kabir Bahadur Shah , Daniel Jaffe , Juan L. Gonzalez , Owen Temby , Gabriel Ibarra-Mejia , Amit U. Raysoni
Air quality monitoring remains a challenge in areas lacking or having sparse federal monitoring infrastructure, posing significant barriers to public health research. This study demonstrates the usage of low-cost sensors in addressing gaps in air quality monitoring, source attribution, and health risk assessment in a Brownsville, TX neighborhood impacted by emissions from a barite and celestite mineral processing unit. PM2.5 concentrations were measured using PurpleAir sensors deployed across three residential locations, with the site nearest to the processing unit recording a 24-h averaged PM2.5 concentration of 25.12 μg/m3—approximately 2.79 times higher than the nearest Texas Commission of Environmental Quality (TCEQ) CAMS (Continuous Ambient Monitoring Station) site. Indoor air quality was also evaluated in two of the residential units to characterize the influence of outdoor pollution on indoor microenvironment. The local wind data was used to conduct source attribution, and the results suggested that the mineral processing entity located south of the neighborhood was the likely source of particulate pollution in this middle-income neighborhood. A health risk assessment for PM2.5 exposure was conducted, and the results indicate a hazard quotient level below unity, suggesting low-risk non-carcinogenic effects on the community. This study underscores the pivotal role of low-cost sensors in generating localized air quality data, and their potential to support ameliorative evidence-based interventions.
在缺乏或联邦监测基础设施很少的地区,空气质量监测仍然是一项挑战,对公共卫生研究构成重大障碍。该研究展示了低成本传感器在解决德克萨斯州布朗斯维尔附近受重晶石和天青石矿物加工装置排放影响的空气质量监测、来源归属和健康风险评估方面的差距。PM2.5浓度测量使用了部署在三个居民区的PurpleAir传感器,最靠近处理单元的站点记录的24小时平均PM2.5浓度为25.12 μg/m3,比最近的德克萨斯州环境质量委员会(TCEQ) CAMS(连续环境监测站)站点高约2.79倍。还对其中两个住宅单元的室内空气质量进行了评价,以表征室外污染对室内微环境的影响。利用当地的风力数据进行源归因,结果表明,位于社区南部的选矿实体可能是该中等收入社区颗粒物污染的来源。对PM2.5暴露进行了健康风险评估,结果显示危害商水平低于1,表明对社区的低风险非致癌性影响。这项研究强调了低成本传感器在产生局部空气质量数据方面的关键作用,以及它们支持改进的循证干预措施的潜力。
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引用次数: 0
Estimating air emissions from animal production in the United States using statistical models: Ammonia emissions from swine grow-finish barns 使用统计模型估算美国动物生产过程中的空气排放:猪生长肥育场的氨排放
IF 3.4 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-05 DOI: 10.1016/j.aeaoa.2025.100404
Ian C. Rumsey , Maliha N. Nash , John T. Walker
Animal production has the potential to emit various atmospheric pollutants including ammonia (NH3), which can impact human health, atmospheric visibility and ecosystem health through gaseous NH3 and associated NH4+ particulate matter deposition. Emission estimating methodologies were developed using statistical models to estimate daily NH3 emissions from swine grow-finish barns based on National Air Emissions Monitoring Study (NAEMS) data. Models were developed with variables that represented production, manure management and environmental conditions. Model performance was evaluated for predicting NAEMS and non-NAEMS emissions, consistency of model coefficients and sensitivity to different model input values. Accounting for ease of variable measurement, the best performing models for predicting NAEMS emissions were models 1b and 16a, both of which accounted for the influence of temperature, swine inventory and weight, but used different predictor and response variables. In predicting NAEMS emissions, model 1b had mean error (ME) and mean bias (MB) values of 1.6 kg day−1 (normalized mean error (NME) = 25.9 %) and 0.1 kg day−1 (normalized mean bias (NMB) = 1.2 %), respectively, which were slightly lower than the corresponding values for model 16a (ME/NME = 1.8 kg day−1/25.9 % and MB/NMB = 0.4 kg day−1/5.8 %). Model 1b performed better in predicting non-NAEMS emissions, but model 16a had more reasonable sensitivity when barn live animal weight was >215,000 kg. Models using nitrogen feed intake as a predictor variable also performed well in predicting emissions and although these models have greater uncertainty due to limited NAEMS measurements, they could potentially account for changes in feed practices.
动物生产有可能排放包括氨(NH3)在内的各种大气污染物,这些污染物可以通过气态NH3和相关的NH4+颗粒物沉积影响人类健康、大气能见度和生态系统健康。基于国家空气排放监测研究(NAEMS)数据,采用统计模型估算生猪育肥场每日NH3排放量,开发了排放估算方法。模型采用代表生产、粪肥管理和环境条件的变量。评估了模型预测NAEMS和非NAEMS排放的性能、模型系数的一致性以及对不同模型输入值的敏感性。考虑到变量测量的容易性,预测NAEMS排放的最佳模型是1b和16a模型,这两个模型都考虑了温度、猪存栏和体重的影响,但使用了不同的预测变量和响应变量。在预测NAEMS排放时,模型1b的平均误差(ME)和平均偏差(MB)值分别为1.6 kg day - 1(归一化平均误差(NME) = 25.9%)和0.1 kg day - 1(归一化平均偏差(NMB) = 1.2%),略低于模型16a的相应值(ME/NME = 1.8 kg day - 1/ 25.9%和MB/NMB = 0.4 kg day - 1/ 5.8%)。模型1b对非naems排放的预测效果较好,而模型16a在畜舍活畜体重为21.5万kg时具有更合理的敏感性。使用氮采食量作为预测变量的模型在预测排放方面也表现良好,尽管由于有限的NAEMS测量,这些模型具有更大的不确定性,但它们可能解释饲料实践的变化。
{"title":"Estimating air emissions from animal production in the United States using statistical models: Ammonia emissions from swine grow-finish barns","authors":"Ian C. Rumsey ,&nbsp;Maliha N. Nash ,&nbsp;John T. Walker","doi":"10.1016/j.aeaoa.2025.100404","DOIUrl":"10.1016/j.aeaoa.2025.100404","url":null,"abstract":"<div><div>Animal production has the potential to emit various atmospheric pollutants including ammonia (NH<sub>3</sub>), which can impact human health, atmospheric visibility and ecosystem health through gaseous NH<sub>3</sub> and associated NH<sub>4</sub><sup>+</sup> particulate matter deposition. Emission estimating methodologies were developed using statistical models to estimate daily NH<sub>3</sub> emissions from swine grow-finish barns based on National Air Emissions Monitoring Study (NAEMS) data. Models were developed with variables that represented production, manure management and environmental conditions. Model performance was evaluated for predicting NAEMS and non-NAEMS emissions, consistency of model coefficients and sensitivity to different model input values. Accounting for ease of variable measurement, the best performing models for predicting NAEMS emissions were models 1b and 16a, both of which accounted for the influence of temperature, swine inventory and weight, but used different predictor and response variables. In predicting NAEMS emissions, model 1b had mean error (ME) and mean bias (MB) values of 1.6 kg day<sup>−1</sup> (normalized mean error (NME) = 25.9 %) and 0.1 kg day<sup>−1</sup> (normalized mean bias (NMB) = 1.2 %), respectively, which were slightly lower than the corresponding values for model 16a (ME/NME = 1.8 kg day<sup>−1</sup>/25.9 % and MB/NMB = 0.4 kg day<sup>−1</sup>/5.8 %). Model 1b performed better in predicting non-NAEMS emissions, but model 16a had more reasonable sensitivity when barn live animal weight was &gt;215,000 kg. Models using nitrogen feed intake as a predictor variable also performed well in predicting emissions and although these models have greater uncertainty due to limited NAEMS measurements, they could potentially account for changes in feed practices.</div></div>","PeriodicalId":37150,"journal":{"name":"Atmospheric Environment: X","volume":"29 ","pages":"Article 100404"},"PeriodicalIF":3.4,"publicationDate":"2025-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145737858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Atmospheric Environment: X
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