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2011 37th IEEE Photovoltaic Specialists Conference最新文献

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Thin film solar cells for indoor use 室内使用的薄膜太阳能电池
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186049
P. Yang, I. Chan, C. H. Lin, Y. L. Chang
The effect of low irradiance for thin film solar cells is investigated in this work. First, a-Si:H/CIGS/DSSC/OPV four kinds of thin film solar cells are fabricated and measured with the sun simulator (AM 1.5G, 100 mW/cm2). Then, the saturation current density J0 is extracted from the Voc and Jsc. Spectral irradiance of the desk light, LED light, sun light at the windowsill and fluorescent lamp are used to calculate the electrical parameters of the solar cells in indoor lighting conditions. From the calculation, a-Si solar cell under the LED light achieves the highest cell efficiency of 17.68%. In real measurement, it is also demonstrated that the cell efficiency of a-Si solar cell can reach 15.2% under the irradiance of 1.1 mW/cm2 LED light.
本文研究了低辐照度对薄膜太阳能电池的影响。首先,制作了a-Si:H/CIGS/DSSC/OPV四种薄膜太阳能电池,并在太阳模拟器(AM 1.5G, 100 mW/cm2)上进行了测量。然后,从Voc和Jsc中提取饱和电流密度J0。利用台灯、LED灯、窗台阳光和荧光灯的光谱辐照度计算太阳能电池在室内照明条件下的电参数。由计算可知,LED光下的a-Si太阳能电池效率最高,达到17.68%。实测表明,在1.1 mW/cm2的LED光辐照下,a-Si太阳能电池的电池效率可达15.2%。
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引用次数: 7
Crystalline silicon solar cells selective emitter pattern design 晶体硅太阳能电池选择性发射极图样设计
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186387
Yen-Chih Liu, Wei-Yu Chen, Chien-Hung Lin, Chi-Chun Li
Selective emitter in crystalline silicon solar cells improves the cell efficiency by reducing the recombination in the emitter region while maintaining low contact resistance to the front side electrodes. There are many approaches to realize selective emitter solar cells, some more complicated than the others, but all involve creating heavier doping in the region under electrodes. In this paper, we present the effect of selective emitter patterns, with or without heavy doping under busbars, on the solar cell performance. The results showed basically identical electrical characteristics for both types of patterns. Even though the selective emitter structure in this study was made with a printable dopant approach, the same results could apply to other selective emitter methods, including laser doping and ion implantation. This conclusion points to potentially significant savings in materials and/or processing time as heavy doping is needed only to cover the finger area but not the busbars.
晶体硅太阳能电池中的选择性发射极通过减少发射极区域的复合,同时保持与前侧电极的低接触电阻来提高电池效率。实现选择性发射极太阳能电池的方法有很多,有些比其他的更复杂,但都涉及在电极下的区域产生更重的掺杂。在本文中,我们提出了选择发射极模式,在母线下有或没有重掺杂,对太阳能电池性能的影响。结果显示,这两种模式的电特性基本相同。尽管本研究中的选择性发射极结构是用可打印的掺杂方法制成的,但同样的结果也适用于其他选择性发射极方法,包括激光掺杂和离子注入。这一结论指出了材料和/或处理时间的潜在显著节省,因为只需要覆盖手指区域而不需要覆盖母线。
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引用次数: 0
Efficiency enhancement of the thin-silicon photovoltaics using indium-tin-oxide nanowhiskers 利用氧化铟锡纳米晶须提高薄硅光伏电池的效率
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186540
Wei-Lun Chang, En-Ting Liu, Chia‐Hua Chang, P. Yu, Chien-Hung Wu
Thin wafer-based solar cells have the potential to significantly decrease the cost of photovoltaics. Light trapping is particularly critical in such thin-wafer crystalline silicon solar cells in order to increase light absorption and hence cell efficiency. In this article we investigate the indium-tin-oxide nanowhisker on textured silicon surface for enhancing the near-infrared absorbance of silicon photovoltaics. The nanowhiskers facilitate optical transmission in the near-infrared by functioning as impedance matching layers with effective refractive indices gradually varying from 1 to 1.3. Materials with such unique refractive index characteristics are not readily available in nature. As a result, the solar cell with combined textures achieves quantum efficiencies enhancement for a broad wavelength range of 900 to 1100 nm, which is crucial to the development of advanced thin-substrate silicon solar cells.
薄晶圆基太阳能电池具有显著降低光伏成本的潜力。为了增加光吸收从而提高电池效率,光捕获在这种薄晶硅太阳能电池中尤为关键。本文研究了在硅表面添加氧化铟锡纳米晶须以提高硅光电器件的近红外吸光度。纳米晶须的有效折射率在1 ~ 1.3之间逐渐变化,起到阻抗匹配层的作用,有利于近红外的光传输。具有这种独特折射率特性的材料在自然界中是不容易得到的。结果表明,复合结构太阳能电池在900 ~ 1100nm宽波长范围内实现了量子效率的提高,这对发展先进的薄衬底硅太阳能电池至关重要。
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引用次数: 0
Grids on TCOs for higly transparent materials with a resistivity below 1 Ohm/sq 电阻率低于1欧姆/平方的高透明材料的tco上的栅格
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186066
J. van Deelen, H. Rendering, Hero het Mannetje, A. Hovestad
Various transparent conducting materials are compared based on their transparency versus sheet resistance characteristics. At present, transparent conducting oxides (TCOs) are still superior in performance compared to various recent alternatives and can only be surpassed by the combination of TCOs with a metal grid. Results on modeling and design optimization are presented using a monolithically integrated CIGS cell configuration as case. This study showed that considerable efficiency enhancement (17% in power output) can be achieved for metal grid TCO combinations compared to single TCOs. Conductivity improvement has been experimentally verified on both commercial ITO PET foil as well as on ZnO coated glass with electrochemically deposited metal grids. Conductivities below 0,1 Ohm/sq were reached and 80 times and 400 times conductivity improvements were obtained at a transparency loss of only 3% and 6%, respectively. It was also found that electrochemical deposition results in more conductive and more transparent grids than obtained by Ag-ink screen printing.
对各种透明导电材料的透明度与片电阻特性进行了比较。目前,透明导电氧化物(tco)在性能上仍然优于最近的各种替代品,只有将tco与金属网格结合才能超越。以单片集成CIGS电池配置为例,给出了建模和设计优化的结果。该研究表明,与单一TCO相比,金属网格TCO组合可以实现相当大的效率提高(输出功率提高17%)。电导率的提高已经在商用ITO PET箔和电化学沉积金属网格的ZnO镀膜玻璃上得到了实验验证。电导率低于0.1欧姆/平方,在透明度损失仅3%和6%的情况下,电导率分别提高了80倍和400倍。与银墨丝网印刷相比,电化学沉积可获得更导电、更透明的网格。
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引用次数: 3
Simulation and computer aided design of silicon solar cells for process and performance parameters optimization 硅太阳能电池工艺及性能参数优化的仿真与计算机辅助设计
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186553
H. Muthurajan, D. Lai, C. Tan
We have developed a novel software package which is able to simulate the performance parameters of the solar cells based on diffusion process parameters as well as finger-bus design parameters. An algorithm for computer aided design (CAD) incorporated in this software package is useful for designing and optimizing the finger-bus dimension for optimum solar energy harvesting. The CAD algorithm of this software package can save the optimized finger-bus design in a .dxf format which can then be directly used as layout for mask making of the metallization layers using screen printing, CMOS based lithography or e-beam writer. The .dxf format file generated by our software package can also be viewed using other CAD softwares such as AutoCAD, L-Edit, etc. This software package also simulate the sheet resistivity of the doped poly-silicon layer based on the process parameters — POCl3 diffusion temperature, duration of POCl3 diffusion reaction, annealing temperature and annealing duration. This research paper presents the new algorithm incorporated in the novel software as discussed above as well as the optimization of the process parameters and finger-bus design.
我们开发了一个基于扩散过程参数和手指总线设计参数模拟太阳能电池性能参数的软件包。该软件包中包含的计算机辅助设计(CAD)算法可用于设计和优化手指总线尺寸以实现最佳太阳能收集。该软件包的CAD算法可以将优化后的手指总线设计保存为。dxf格式,然后可以直接用作丝网印刷,CMOS光刻或电子束书写机的金属化层掩模制作的布局。我们的软件包生成的。dxf格式文件也可以使用其他CAD软件(如AutoCAD、L-Edit等)查看。该软件包还根据工艺参数——POCl3扩散温度、POCl3扩散反应持续时间、退火温度和退火持续时间,模拟了掺杂多晶硅层的片材电阻率。本文介绍了上述新型软件中引入的新算法,以及工艺参数的优化和手指总线的设计。
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引用次数: 1
Ultrafast carrier relaxation and nonequilibrium phonons in hot carrier solar cells 热载流子太阳能电池中的超快载流子弛豫和非平衡声子
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186359
S. Goodnick, C. Honsberg
Third generation concepts in photovoltaic devices depend critically on the dynamics of ultrafast carrier relaxation and electron-phonon interactions on very short times scales in nanostructures such as quantum wells, wires and dots. Hot carrier solar cells in particular depend on the reduction in the energy relaxation rate in an absorber material, where hot carriers are extracted through energy selective contacts. Here we investigate the short time carrier relaxation in quantum well, hot electron solar cells under varying photoexcitation conditions using ensemble Monte Carlo (EMC) simulation coupled with rate equation models, to understand the limiting factors affecting cell performance. In particular, we focus on the potential role of hot phonons in reducing the energy loss rate in order to achieve sufficient carrier temperature for efficient performance.
第三代光电器件的概念主要依赖于超快载流子弛豫和电子-声子相互作用在极短时间尺度上在纳米结构(如量子阱、线和点)中的动力学。热载流子太阳能电池特别依赖于吸收材料中能量松弛率的降低,其中热载流子通过能量选择接触被提取。本文利用集成蒙特卡罗(EMC)模拟和速率方程模型,研究了不同光激发条件下量子阱热电子太阳能电池的短时间载流子弛豫,以了解影响电池性能的限制因素。我们特别关注热声子在降低能量损失率以获得足够的载流子温度以实现高效性能方面的潜在作用。
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引用次数: 6
A reactive power control strategy for distributed solar inverters in low voltage rural distribution grids without communication infrastructure 无通信基础设施的低压农村配电网分布式太阳能逆变器无功控制策略
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186477
E. Demirok, P. C. González, Martin C. Svendsen, Kenn H. B. Frederiksen, D. Sera, R. Teodorescu
The main objective of this study is to increase penetration level of photovoltaic (PV) power production in the grid by considering line overvoltage and transformer overloading limitations. The study presents a reactive power control method based on sensitivity analysis for grid-connected distributed solar inverters. The sensitivity analysis shows that reactive power support is more effective on the grid voltage regulation if the solar inverter is located at the end of the feeder. Therefore, higher power factor (PF) should be set for the inverter which is connected closer to substation due to smaller impedance observed from connection point to upstream network. Based on this knowledge, location-dependent PF set values are assigned to each solar inverter. In order to prevent unnecessary reactive power absorption from the grid, active power variation is also measured and considered in the control method. Compared to the equally fixed PF dispatching among inverters, the proposed method provides smaller network losses and MV/LV transformer loading that allows more PV system installations. Performance comparison of different reactive control methods is achieved by simulation of a real test network. Additionally, experimental reactive power control setup has been built together with a solar simulator and a single-stage 2-level inverter. The setup verifies that the control method can be easily integrated into inverters.
本研究的主要目的是在考虑线路过电压和变压器过载限制的情况下,提高光伏发电在电网中的渗透水平。提出了一种基于灵敏度分析的并网分布式太阳能逆变器无功控制方法。灵敏度分析表明,太阳能逆变器安装在馈线末端时,无功支撑对电网电压调节效果更好。因此,从连接点到上游网络观察到的阻抗较小,离变电站较近的逆变器应设置较高的功率因数(PF)。基于这些知识,将位置相关的PF设定值分配给每个太阳能逆变器。为了防止电网吸收不必要的无功功率,在控制方法中还测量和考虑了有功功率的变化。与逆变器之间同样固定的PF调度相比,该方法提供了更小的网络损耗和中压/低压变压器负载,从而允许更多的光伏系统安装。通过对实际测试网络的仿真,比较了不同无功控制方法的性能。此外,还建立了实验无功功率控制装置,以及太阳能模拟器和单级2电平逆变器。该装置验证了该控制方法可以很容易地集成到逆变器中。
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引用次数: 1
Rapid deposition of titania nanoparticles on tin oxide for dye solar cell anodes using fluid mechanics and eletrokinetics 用流体力学和电动力学研究二氧化钛纳米颗粒在染料太阳能电池阳极氧化锡上的快速沉积
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186167
Rocco A. Panella, B. Ydstie, D. Prieve
Using electrokinetics and fluid mechanics, we are designing a method to rapidly deposit titania nanoparticles onto transparent conductive oxide surfaces for use in dye solar cell anodes. Manipulating the pH and ionic strength of an aqueous solution makes it possible to control the surface potential of submerged oxide surfaces such as titania and tin oxide. By using pH values near and below 5.5, it is possible to create conditions where titania nanoparticles are stable and electrostatically repel each other in a dilute, aqueous suspension, but are attracted to various tin oxide surfaces. We can then use fluid flow such as that from a rotating disk or impinging jet to deliver nanoparticles adequately close to the surface such that they adhere via strong van der waals forces. For particles which are made in solution via oxidation, this technique offers the major advantage of never drying the particles, thus allowing them to remain un-aggregated until they deposit onto the surface. We have shown that we can monitor particle deposition in situ by measuring the zeta potential of a surface using a rotating disk electrode apparatus. The measured difference in iso-electric point of titania and both fluorine- and indium-tin oxide shown in this work indicates that we should have some control over the rate and extent of particle deposition. Currently, we have deposited titania nanoparticle layers which are several layers thick and consist of particles with diameters smaller than 10 nm; these tightly packed layers have applications as blocking layers to prevent unwanted shunts in dye solar cells.
利用电动力学和流体力学,我们正在设计一种方法,将二氧化钛纳米颗粒快速沉积到透明导电氧化物表面,用于染料太阳能电池阳极。通过控制水溶液的pH值和离子强度,可以控制氧化钛和氧化锡等被淹没的氧化表面的表面电位。通过使用接近或低于5.5的pH值,可以创造条件,使二氧化钛纳米颗粒在稀释的水悬浮液中稳定且静电排斥,但被各种氧化锡表面吸引。然后,我们可以利用旋转圆盘或撞击射流等流体流动,将纳米颗粒充分靠近表面,使它们通过强大的范德华力粘附在一起。对于通过氧化在溶液中生成的颗粒,该技术的主要优点是永远不会使颗粒干燥,从而使它们在沉积到表面之前保持未聚集状态。我们已经证明,我们可以通过使用旋转圆盘电极装置测量表面的zeta电位来监测颗粒沉积。本文所测得的氧化钛、氧化氟和氧化铟锡等电点的差异表明,我们应该对颗粒沉积的速度和程度有一定的控制。目前,我们已经沉积了几层厚度的二氧化钛纳米颗粒层,这些纳米颗粒由直径小于10纳米的颗粒组成;这些紧密堆积的层被用作阻挡层,以防止染料太阳能电池中不必要的分流。
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引用次数: 1
Grain boundary passivation with small polar molecules for photovoltaics 光伏小极性分子晶界钝化
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186240
Wentao Wang, Lei Wang, Fude Liu
Grain boundaries (GBs) play a major role in determining the device performance of in particular polycrystalline thin film solar cells including Si, CdTe and CIGS. Hydrogen passivation has been traditionally applied to passivate the defects at GBs. However, hydrogenated films such as amorphous silicon (a-Si:H) and microcrystalline silicon (μc-Si:H) are subject to light-induced degradation effects. In this study on multicrystalline (mc)-Si wafers, we found an excellent correlation between the grain misorientation and the corresponding electrical resistivity across grain boundaries. In particular, the charge transport across GBs was greatly enhanced after the wafers were properly treated in acetonitrile (CH3CN). The results were explained to be due to the more effective charge neutralization of polar molecules on GBs. These findings may help us achieve high-quality materials at low cost for high-efficient solar cells by improving the carrier transport and minimizing the carrier recombination. We also believe that this study will help us with a deeper understanding on GBs and their behaviors for the applications not only in photovoltaics, but also in other solid-state devices such as thin-film transistors.
晶界(GBs)在决定器件性能方面起着重要作用,特别是多晶薄膜太阳能电池,包括Si, CdTe和CIGS。传统上采用氢钝化方法来钝化GBs缺陷。然而,非晶硅(a-Si:H)和微晶硅(μc-Si:H)等氢化膜受到光诱导降解的影响。在对多晶硅晶片的研究中,我们发现晶粒取向偏差与相应的晶界电阻率之间存在良好的相关性。特别是,在乙腈(CH3CN)中适当处理后,晶圆上的电荷输运大大增强。结果被解释为由于极性分子在gb上更有效的电荷中和。这些发现可能有助于我们通过改善载流子运输和减少载流子重组,以低成本获得高质量的高效太阳能电池材料。我们也相信这项研究将有助于我们更深入地了解gb及其行为,不仅在光伏领域,而且在其他固态器件如薄膜晶体管中的应用。
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引用次数: 0
Development of a test station for accurate in situ I-V curve measurements of photovoltaic modules in Southern Norway 开发一个测试站,用于在挪威南部对光伏组件进行精确的原位I-V曲线测量
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186610
A. G. Imenes, G. Yordanov, O. Midtgård, T. O. Saetre
The development of an outdoor test station for accurate in situ I-V curve measurements of photovoltaic (PV) modules is described. The modules are installed in an open-rack configuration at the University of Agder in Southern Norway. Seven new and three aged PV modules of different type and make are being tested, including mono-and multicrystalline silicon from differing manufacturing routes, triple-junction amorphous silicon, and CIS. Data acquisition is controlled with a multichannel electronic load system and LabVIEW software, recording high-resolution I-V curves at one-minute intervals. Between I-V curve sweeps, each module is operated at the maximum power point. Characteristic electrical parameters are extracted and stored together with values of module temperatures and in-plane solar irradiance, the latter recorded at sub-second resolution. The paper describes the experimental set-up in more detail, discusses some local environmental effects, and presents a sample of test results.
本文介绍了一种用于精确测量光伏组件I-V曲线的室外测试站的研制。这些模块安装在挪威南部阿格德大学的开放式机架结构中。7种不同类型和制造的新型光伏组件和3种旧的光伏组件正在测试中,包括不同制造路线的单晶硅和多晶硅,三结非晶硅和CIS。数据采集由多通道电子负载系统和LabVIEW软件控制,每隔一分钟记录高分辨率的I-V曲线。在I-V曲线扫描之间,每个模块在最大功率点运行。提取特征电参数并与模块温度和面内太阳辐照度值一起存储,后者以亚秒分辨率记录。本文较详细地介绍了试验装置,讨论了一些局部环境影响,并给出了试验结果的实例。
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引用次数: 29
期刊
2011 37th IEEE Photovoltaic Specialists Conference
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