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2011 37th IEEE Photovoltaic Specialists Conference最新文献

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CdCl2 activation-induced chemical interaction at the CdTe/ZnO1−xSx thin-film solar cell interface CdCl2激活诱导CdTe/ZnO1−xSx薄膜太阳电池界面化学相互作用
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186505
M. Bar, J. Perrenoud, R. Wilks, S. Buecheler, L. Kranz, C. Fella, J. Skarp, M. Blum, W. Yang, L. Weinhardt, C. Heske, A. Tiwari
We have used soft x-ray emission spectroscopy to study the impact of the CdCl2 activation treatment on the chemical structure of the CdTe/ZnO1−xSx interface. We find a pronounced chemical interaction, most prominently the interfacial intermixing of Cd and Zn. Furthermore, the formation of S-Cd bonds at the expense of S-Zn bonds can be observed.
我们利用软x射线发射光谱研究了CdCl2活化处理对CdTe/ZnO1−xSx界面化学结构的影响。我们发现了明显的化学相互作用,最显著的是Cd和Zn的界面混合。此外,可以观察到S-Cd键的形成以S-Zn键为代价。
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引用次数: 0
Multi-crystalline silicon ingots growth with an innovative induction heating directional solidification furnace 多晶硅锭生长采用创新的感应加热定向凝固炉
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186381
F. Dughiero, M. Forzan, D. Ciscato, Francesco Giusto
Multi-crystalline silicon ingots produced using directional solidification systems (DSS) represent the best way to obtain high quality crystalline silicon at low prices and with high throughputs. The DSS technology is widespread among PV silicon ingot producers and hundreds of furnaces are manufactured worldwide every year. The present challenge for crystal growers is to increase the maximum ingot mass in order to benefit from scale economy profits and to reduce energy consumption. This reason has pushed some companies to develop new DSS furnaces able to grow ingots up to 650 kg. As a matter of fact, the increase in size defines new challenges in design and process optimization due of the intensification of radial thermal instabilities and consequently of buoyancy driven flows in the melt [1]. These phenomena are related to heat and mass transfer during the solidification process and are important to control both the liquid/solid interface shape and the impurities distribution in the crystal [2,3,4,5,6]. The main features and the characteristic design of the hot-zone in the iDSS (induction-DSS) furnace are taken into account, especially in comparison with the standard DSSs ones. The reduction in thickness of the insulation boards and the smaller size of the hot-zone itself, together with the selective lateral induction coil system, all lead to an optimal control of the thermal instabilities into the silicon melt, increasing the ingot quality. In fact, the lateral induction coil system equipped with independent turns connections can be used to force selectively — at different vertical positions — the most suitable thermal condition. In this way one is able to compensate the radiative thermal losses and create a “virtual” adiabatic wall, producing a perfectly planar solidification front or modeling the radial thermal gradient in order to obtain the desired solidification front shapes. The results from a set of electro-magnetic, thermal and fluid-dynamic simulation are presented; the first data collected from the real scale prototype are shown.
使用定向凝固系统(DSS)生产的多晶硅锭代表了以低价格和高产量获得高质量晶体硅的最佳途径。DSS技术在光伏硅锭生产商中广泛应用,全球每年生产数百台电炉。晶体种植者目前面临的挑战是提高最大铸锭质量,以从规模经济利润中获益,并降低能耗。这一原因促使一些公司开发新的DSS炉,使其能够生产重达650公斤的钢锭。事实上,由于径向热不稳定性的加剧以及熔体中浮力驱动流动的加剧,尺寸的增加给设计和工艺优化带来了新的挑战[1]。这些现象与凝固过程中的传热传质有关,对控制结晶液固界面形状和杂质分布具有重要意义[2,3,4,5,6]。分析了感应式dss炉热区的主要特点和特点设计,并与标准的感应式dss炉进行了比较。隔热板厚度的减小和热区本身尺寸的减小,加上选择性的横向感应线圈系统,都能对硅熔体的热不稳定性进行最佳控制,从而提高铸锭质量。事实上,配备独立匝连接的横向感应线圈系统可用于选择性地在不同的垂直位置施加最合适的热条件。通过这种方式,人们能够补偿辐射热损失并创建一个“虚拟”绝热壁,产生一个完美的平面凝固锋或模拟径向热梯度,以获得所需的凝固锋形状。给出了一组电磁、热学和流体动力学模拟的结果;从实际规模的原型中收集的第一批数据显示。
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引用次数: 2
Extraction of recombination parameters of amorphous silicon/crystalline silicon solar cell from lifetime spectroscopy 非晶硅/晶体硅太阳电池复合参数的寿命光谱提取
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186225
K. Ghosh, Ghosh, Nam-Kyu Song, M. Oh, Dong-Seop Kim, S. Bowden
A technique to measure the recombination parameter of a-Si/c-Si heterojunction solar cell is described in the work. In this methodology, the experimentally measured inverse lifetime by Sinton lifetime tester is fitted with A+BΔn+CΔn2 to determine the recombination parameters. The coefficients B and C are radiative and auger recombination coefficient while coefficient A depends on bulk lifetime and surface recombination velocity. The radiative and auger recombination coefficients determined from the work agrees well with previously published results while the surface recombination velocity extracted from coefficient A is typical of well passivated c-Si surface in a-Si/c-Si heterojunction solar cell.
本文介绍了一种测量A - si /c-Si异质结太阳能电池复合参数的方法。该方法采用A+BΔn+CΔn2拟合Sinton寿命测试仪实验测量的逆寿命,确定复合参数。系数B和C是辐射复合系数和螺旋复合系数,而系数A取决于体寿命和表面复合速度。从该工作中确定的辐射和螺旋复合系数与先前发表的结果一致,而从系数A中提取的表面复合速度是A - si /c-Si异质结太阳能电池中钝化良好的c-Si表面的典型特征。
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引用次数: 0
Solar electric propulsion for advanced planetary missions 先进行星任务的太阳能电力推进
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186253
G. Landis, S. Oleson, M. Mcguire, J. Fincannon, Kristen M. Bury
Use of solar electric propulsion can result in mass and propellant savings for future NASA missions to explore the solar system, enabling lightweight probes to targets in the solar system that have previously been out of reach. However, such electric-propulsion missions require large amounts of power, and require extremely lightweight solar arrays. The NASA Glenn COMPASS team was used to perform conceptual designs for several advanced missions, in order to develop a top-level understanding of the difficulties and the technologies needed, and the interaction of the power system with the propulsion system requirements for missions both close to, and far from, the Sun. Some near term and farther term missions analyzed include an exploration mission to a binary asteroid, a mission to land on and return a sample from the large main-belt asteroid Ceres, a mission to land a surface probe on Mercury, and a mission to the outer planet Uranus.
使用太阳能电力推进可以为NASA未来探索太阳系的任务节省质量和推进剂,使轻型探测器能够到达太阳系中以前无法到达的目标。然而,这种电力推进任务需要大量的电力,并且需要极轻的太阳能电池阵列。NASA Glenn COMPASS团队被用来执行几个高级任务的概念设计,以便对困难和所需的技术以及近太阳和远离太阳的任务中动力系统与推进系统要求的相互作用有一个顶层的理解。分析的一些短期和长期任务包括对一颗双星小行星的探测任务,在大型主带小行星谷神星上着陆并带回样本的任务,在水星上着陆表面探测器的任务,以及到外行星天王星的任务。
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引用次数: 4
Temperature-dependent Photoluminescence imaging and characterization of a multi-crystalline silicon solar cell defect area 多晶硅太阳电池缺陷区域的温度依赖性光致发光成像和表征
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6185848
S. Johnston, Fei Yan, Jian V. Li, K. Zaunbrecher, M. Romero, M. Al‐Jassim, O. Sidelkheir, A. Blosse
Photoluminescence (PL) imaging is used to detect areas in multi-crystalline silicon that appear dark in band-to-band imaging due to high recombination. Steady-state PL intensity can be correlated to effective minority-carrier lifetime, and its temperature dependence can provide additional lifetime-limiting defect information. An area of high defect density has been laser cut from a multi-crystalline silicon solar cell. Both band-to-band and defect-band PL imaging have been collected as a function of temperature from ∼85 to 350 K. Band-to-band luminescence is collected by an InGaAs camera using a 1200-nm short-pass filter, while defect band luminescence is collected using a 1350-nm long pass filter. The defect band luminescence is characterized by cathodoluminescence. Small pieces from adjacent areas within the same wafer are measured by deep-level transient spectroscopy (DLTS). DLTS detects a minority-carrier electron trap level with an activation energy of 0.45 eV on the sample that contained defects as seen by imaging.
光致发光(PL)成像用于检测多晶硅中由于高复合而在带对带成像中呈现黑暗的区域。稳态PL强度可以与有效的少数载流子寿命相关,其温度依赖性可以提供额外的寿命限制缺陷信息。从多晶硅太阳能电池上用激光切割出了一个高缺陷密度的区域。波段到波段和缺陷波段的PL成像都是作为温度从~ 85到350 K的函数收集的。采用1200 nm的短通滤波器采集InGaAs相机的带间发光,采用1350 nm的长通滤波器采集缺陷带发光。缺陷带的发光特征为阴极发光。用深能级瞬态光谱(DLTS)测量同一晶圆内邻近区域的小块。DLTS检测到含有成像缺陷的样品上具有0.45 eV活化能的少数载流子电子陷阱能级。
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引用次数: 4
Integration of aluminium oxide as a passivation layer in a high efficiency industrial process on n-type silicon solar cells 在n型硅太阳能电池上集成氧化铝作为钝化层的高效工业工艺
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186127
P. Brand, Y. Veschetti, V. Sanzone, R. Cabal, X. Pagès, K. Vanormelingen, P. Vermont
This work aims at evaluating aluminium oxide (Al2O3) as an emitter passivation layer for Cz-silicon n-type solar cells fabricated with screen-printed metallization. The effect of firing on the emitter saturation current density obtained with Al2O3/SiNx was studied and compared to the one obtained with thermal SiO2/SiNx. An efficiency of 18.3% was achieved using Al2O3 for n-type solar cells, still limited by a low fill factor due to a high contact resistance.
这项工作旨在评估氧化铝(Al2O3)作为用丝网印刷金属化制造的cz -硅n型太阳能电池的发射极钝化层。研究了烧成对Al2O3/SiNx的发射极饱和电流密度的影响,并与热SiO2/SiNx的发射极饱和电流密度进行了比较。Al2O3用于n型太阳能电池的效率为18.3%,但由于接触电阻高,填充系数低,因此受到限制。
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引用次数: 0
Concentration effects of tunnel diode for optimizations of multi-junction solar cells 隧道二极管的浓度效应在多结太阳能电池优化中的应用
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6185999
Guo Hong, P. Yu
Tunnel diodes, also known as Esaki diodes, play an important role in III-V multi junction solar cells. In this work, we theoretically investigated the electrical characteristics of a GaAs tunnel diode and its performance against the illumination conditions such as light intensity, spatial profile, etc. We then developed a methodology to optimize a triple junction InGap/GaAs/Ge solar cell with a GaAs tunnel junction. The conversion efficiency drops with the increase of the concentration ratio is also discussed.
隧道二极管,也称为Esaki二极管,在III-V型多结太阳能电池中起着重要作用。在这项工作中,我们从理论上研究了砷化镓隧道二极管的电学特性及其对光照条件(如光强,空间轮廓等)的性能。然后,我们开发了一种方法来优化具有GaAs隧道结的InGap/GaAs/Ge三结太阳能电池。还讨论了随着浓度比的增大,转化效率下降的现象。
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引用次数: 0
Normalization of data from two matching photovoltaic arrays 两个匹配光伏阵列数据的归一化
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186604
Abhijeet Dubhashi, John Wood
The power output of two solar arrays with same configuration and same type of solar modules is not equal due to module mismatch and array wiring. In addition, differences in ambience can create difficulty in side-by-side comparison tests. This paper illustrates and describes two experiments performed in the Xandex Solar Lab and demonstrates how normalization was performed using two arrays with the same system size.
相同配置、相同类型太阳能组件的两个太阳能电池阵列,由于组件不匹配、阵列接线等原因,输出功率不相等。此外,环境的差异会给并排比较测试带来困难。本文说明并描述了在Xandex太阳能实验室进行的两个实验,并演示了如何使用具有相同系统大小的两个阵列进行规范化。
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引用次数: 0
Effect of defect-rich epitaxy on crystalline silicon / amorphous silicon heterojunction solar cells and the use of low-mobility layers to improve peformance 富缺陷外延对晶硅/非晶硅异质结太阳能电池的影响及使用低迁移率层提高性能
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186222
M. Deceglie, H. Atwater
We present two-dimensional device physics simulations of amorphous silicon / crystalline silicon heterojunction solar cells to explain the effects of full and localized epitaxial layers, sometimes observed in the early stages of amorphous Si deposition, on cell performance. Minimizing the defect density, thickness, and wafer area fraction covered by the epitaxial region are shown to be important factors for maximizing cell open circuit voltage. We find that localized defect-rich epitaxial patches covering small percentages of the wafer surface (∼5%) can cause significant reduction in open circuit voltage, which is explained by considering lateral carrier flow in the device. We also show that a thin layer of low-mobility material, such as microcrystalline silicon, included between the wafer and amorphous regions can impede lateral carrier flow and improve conversion efficiencies in cases where isolated defective pinholes limit device performance.
我们提出了非晶硅/晶体硅异质结太阳能电池的二维器件物理模拟,以解释在非晶硅沉积的早期阶段有时观察到的完整和局部外延层对电池性能的影响。最小化缺陷密度、厚度和外延区覆盖的晶圆面积是最大化电池开路电压的重要因素。我们发现覆盖一小部分晶圆表面(~ 5%)的局部富含缺陷的外延片可以显著降低开路电压,这可以通过考虑器件中的横向载流子流来解释。我们还表明,在晶圆和非晶区之间包含一层薄的低迁移率材料,如微晶硅,可以阻止横向载流子流动,并在孤立的缺陷针孔限制器件性能的情况下提高转换效率。
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引用次数: 3
Review of photovoltaic status in a European (EU) perspective 欧盟视角下的光伏现状综述
Pub Date : 2011-06-19 DOI: 10.1109/PVSC.2011.6186641
D. Verma, O. Midtgård, Tor O. Satre
In the EU continent, a generation cost around 0.15€/kWh has been achieved [1]. Around the world, there is a mission to stimulate this green source of energy and it is believed that by 2030, PV will be able to deliver around 9 % of the world's electricity demands. According to an International Energy Agency (IEA) report [2], it is expected that PV will accomplish grid parity in at least 10% of the world by 2020. There was a significant 60 % annual growth in the grid connected PV systems in the span of 2004–2009 [3]. The present article will bring out the status & review of PV technology and the details of PV system standards as suggested by IEA. In the present paper, the main attention has been paid to the grid connected systems.
在欧盟大陆,发电成本约为0.15欧元/千瓦时[1]。在世界范围内,有一个使命是刺激这种绿色能源,据信到2030年,光伏将能够提供全球约9%的电力需求。根据国际能源署(IEA)的报告[2],预计到2020年,光伏发电将在全球至少10%的地区实现并网平价。在2004-2009年期间,并网光伏系统的年增长率显著达到60%[3]。本文将介绍光伏技术的现状和回顾,以及国际能源署建议的光伏系统标准的细节。本文主要对并网系统进行了研究。
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引用次数: 24
期刊
2011 37th IEEE Photovoltaic Specialists Conference
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