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Molecular insight into the competitive adsorption mechanism of supercritical CO2/Crude oil in shale composite model 超临界CO2/原油在页岩复合模型中竞争吸附机理的分子研究
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2026-01-14 DOI: 10.1016/j.petlm.2025.12.005
Yuanxiu Sun , Yijie Ma , Hongrui Guo , Jiang Wu , Liping Zhang , Songqi Li
With the continuous growth of global energy demand, shale oil, as an important unconventional oil and gas resource, is increasingly highlighting its strategic position. As one of the key means of shale oil development, supercritical carbon dioxide (CO2) flooding technology has significant advantages in reducing crude oil viscosity, improving reservoir pore structure and fluid occurrence state, thereby effectively enhancing oil recovery. The molecular simulation method provides an effective way to reveal the microscopic mechanism of CO2 flooding. In this paper, based on the molecular dynamics simulation method, a multi-component system model including supercritical CO2, organic-inorganic composite wall and crude oil is constructed. The microscopic mechanism of competitive adsorption between supercritical CO2 and components in both single-component and multi-component oil phase is systematically investigated. The effects of wall type, temperature and CO2 injection pressure on competitive adsorption behavior are clarified. The results show that the competitive adsorption of supercritical CO2 varies significantly among different shale oil compoents. The competitive adsorption efficiencies of supercritical CO2 for the single-component systems, n-hexane, toluene, acetic acid, and n-dodecane, are 55.17%, 51.72%, 44.83%, and 27.59%, respectively. In the multi-component oil system, the competitive adsorption efficiencies of supercritical CO2 are as follows: n-hexane (66.58%), n-dodecane (47.06%), toluene (49.46%), and acetic acid (78.78%). This indicates that the competitive adsorption efficiency is closely related to the molecular polarity, molecular weight and the component's position in the adsorption layer. In addition, the competitive adsorption efficiency of CO2 for n-hexane first increases and then decreases with increasing temperature, reaching a maximum of 50.57% at 383.15K and the injection pressure of 10.5 MPa. The increase of injection pressure significantly improves the competitive adsorption efficiency, and 10.5 MPa is considered as the minimum miscibility pressure (MMP). This study reveals the competitive adsorption mechanism between supercritical CO2 and shale oil at the molecular scale, thus providing theoretical support for the technical optimization and scheme design of shale oil of efficienyt development through CO2 injection.
随着全球能源需求的不断增长,页岩油作为一种重要的非常规油气资源,其战略地位日益凸显。超临界CO2驱油技术作为页岩油开发的关键手段之一,在降低原油粘度、改善储层孔隙结构和流体赋存状态,从而有效提高原油采收率方面具有显著优势。分子模拟方法为揭示CO2驱油微观机理提供了有效途径。本文基于分子动力学模拟方法,构建了包括超临界CO2、有机-无机复合壁和原油在内的多组分系统模型。系统研究了超临界CO2在单组分和多组分油相中与组分竞争吸附的微观机理。阐明了壁面类型、温度和CO2注入压力对竞争吸附行为的影响。结果表明,不同组分页岩油对超临界CO2的竞争吸附存在显著差异。超临界CO2对正己烷、甲苯、乙酸和正十二烷等单组分体系的竞争吸附效率分别为55.17%、51.72%、44.83%和27.59%。在多组分油体系中,超临界CO2的竞争吸附效率分别为:正己烷(66.58%)、正十二烷(47.06%)、甲苯(49.46%)和乙酸(78.78%)。这表明竞争吸附效率与分子极性、分子量和组分在吸附层中的位置密切相关。此外,CO2对正己烷的竞争吸附效率随温度的升高先升高后降低,在383.15K、注入压力10.5 MPa时达到最大值50.57%。注入压力的增加显著提高了竞争吸附效率,并将10.5 MPa作为最小混相压力(MMP)。本研究揭示了超临界CO2与页岩油在分子尺度上的竞争吸附机理,为页岩油注二氧化碳高效开发的工艺优化和方案设计提供理论支持。
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引用次数: 0
A quantitative risk assessment model for lightning-induced failures in natural gas automated metering systems 天然气自动计量系统雷电致故障的定量风险评估模型
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-11-27 DOI: 10.1016/j.petlm.2025.11.002
Xia Wu , Jiujiang Cai , Hanqing Liu , Wenlong Jia , Changjun Li , Mengjun Teng
As one of the most probable natural hazards leading to technological disasters, lightning can easily damage analytical instruments in oil and gas stations, resulting in data loss and operational anomalies. Compared with other equipment, Natural Gas Automated Metering Systems (NGAMS), which comprise various precision analytical instruments, are more susceptible to lightning strikes. This vulnerability often leads to production shutdowns, inaccurate metering, and commercial disputes. A quantitative risk assessment model for lightning-induced failures in NGAMS is proposed to enhance the integrity management of metering stations. The model consists of a lightning failure probability model and a consequence evaluation method that incorporates reputational loss. First, a lightning identification criterion is established based on the electro-geometric model, and a basic lightning probability model is developed using Monte Carlo simulations. Second, a basic failure probability model is constructed by modeling the system's equivalent circuit and incorporating the insulation withstand characteristics of the equipment. Two correction factors, specifically the location factor and lightning protection measures, are subsequently incorporated to establish the comprehensive lightning failure probability model. Furthermore, a reputational loss evaluation method is proposed by developing a reputation loss indicator system and integrating the Z-BWM method with cloud model. Case study results show that when the average lightning probability is 1.03 × 10−2, the maximum system failure probability reaches 4.14 × 10−5, representing a 35.29% increase over the inherent failure probability. The corresponding reputational loss is classified as low risk, verifying the effectiveness and practicality of the proposed model.
雷电是最容易引发技术灾害的自然灾害之一,容易损坏油气站的分析仪器,造成数据丢失和运行异常。与其他设备相比,天然气自动计量系统(NGAMS)包含各种精密分析仪器,更容易受到雷击。这个漏洞经常导致生产停工、计量不准确和商业纠纷。为了加强对测量站的完整性管理,提出了NGAMS雷电致故障的定量风险评估模型。该模型由雷电破坏概率模型和考虑名誉损失的后果评价方法组成。首先,建立了基于电几何模型的雷电识别准则,并利用蒙特卡罗模拟建立了雷电基本概率模型。其次,通过对系统等效电路进行建模,结合设备的绝缘耐压特性,建立了基本的故障概率模型;随后,将位置因素和防雷措施两个校正因素纳入综合雷击失效概率模型。在此基础上,建立了企业声誉损失评价指标体系,并将Z-BWM方法与云模型相结合,提出了企业声誉损失评价方法。实例分析结果表明,当平均雷击概率为1.03 × 10−2时,系统最大失效概率达到4.14 × 10−5,比固有失效概率提高35.29%。相应的声誉损失被归为低风险,验证了所提出模型的有效性和实用性。
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引用次数: 0
The obstructing implications of the deteriorating diagenetic factors on the reservoir quality and flow capacity of the gas-bearing siliciclastic sequence in the Obaiyed Field, northern Western Desert, Egypt 埃及西部沙漠北部奥拜耶德气田含气硅屑层序成岩因素恶化对储层质量和流动能力的影响
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2026-02-04 DOI: 10.1016/j.petlm.2026.01.005
Hoda A. Diab , Bassem S. Nabawy , Ahmed Diab , Ahmed S. Mansour , Walaa S.M. Afify
The Obaiyed Gas Field is a significant gas-producing field in the northern Western Desert of Egypt. It is considered a tight gas reservoir because of its highly compact nature resulting from its intensive diagenetic history. This study presents a profound investigation and an integrated assessment of petrophysical and geological data, comprising core measurements, well logs for formation evaluation, sedimentological studies, and diagenetic modifications. The investigation focuses on characterizing the heterogeneous reservoirs of the siliciclastic sequences of the Lower Paleozoic-Middle Jurassic sequence, intending to aid in the exploration and development of hydrocarbon reservoirs in the Obaiyed Field. Several petrophysical parameters, such as the discrete rock type, reservoir quality index, normalized porosity index, flow zone indicator, and effective pore throat radius, were calculated to assess the quality of the reservoirs being studied. Seven microfacies were identified and summed into 5 reservoir rock types (RRTs). The quartz arenite and kaolinitic quartz arenite of the Lower Safa Member had the best reservoir quality. The micaceous clayey and siliceous quartz arenite of the Shifah Formation have the lowest quality. The main dominant key diagenetic features that control reservoir quality are compaction, cementation, quartz overgrowth, dispersed authigenic minerals, fracturing, and dissolution. Reservoir zonation shows that the Shifah Formation is not as promising as the Lower Safa Member because of its highly heterogeneous nature. The southeastern and central regions of the field exhibit a significant increase in the reservoir quality. The applied workflow is applicable to the other gas/condensate fields in the Western Desert and NE Africa, which are similar in the same stratigraphic and structural settings.
Obaiyed气田是埃及西部沙漠北部的一个重要气田。由于其强烈的成岩历史导致其高度致密性,因此被认为是致密气藏。本研究对岩石物理和地质数据进行了深入的调查和综合评估,包括岩心测量、地层评价的测井、沉积学研究和成岩改造。重点研究下古生统—中侏罗统硅屑层序非均质储层特征,以期为油田油气勘探开发提供依据。计算了离散岩石类型、储层质量指数、归一化孔隙度指数、流区指标、有效孔喉半径等岩石物性参数,对储层质量进行了评价。识别出7个微相,并将其归纳为5种储集岩类型(RRTs)。下沙法段的石英砂岩和高岭石型石英砂岩储层质量最好。石法组的云母质粘土质和硅质石英砂质质量最差。控制储层质量的主要关键成岩特征是压实作用、胶结作用、石英过度生长、分散的自生矿物、压裂作用和溶蚀作用。储层分带表明,由于Shifah组的高度非均质性,其前景不如Safa下段。油田的东南部和中部地区的储层质量显著提高。所应用的工作流程也适用于西部沙漠和非洲东北部的其他天然气/凝析气田,这些气田具有相同的地层和构造背景。
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引用次数: 0
A novel DMAA/AMPS/VM/IA quadripolymer as a high temperature and salt resistance fluid loss additive for well cementing 一种新型的DMAA/AMPS/VM/IA四聚体,作为固井的高温耐盐滤失剂
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2026-01-07 DOI: 10.1016/j.petlm.2026.01.001
Qi Feng , Chengwen Wang , Wenjian Yue , Chengli Wang , Tao Song
Cementing in deep and ultra-deep reservoirs often faces the critical challenge of additive degradation in high-temperature environments. Addressing this, 1-vinylimidazole (VM) was incorporated into the copolymerization of N,N-dimethylacrylamide, itaconic acid, and 2-acrylamido-2-methylpropanesulfonic acid to synthesize a tetrapolymer (PDVI). Using aqueous free radical polymerization optimized by response surface methodology, the resulting PDVI exhibited superior fluid loss reduction in high-temperature and high-salinity conditions. Compared to the control sample PDI, PDVI reduced fluid loss from 64.7 mL to 25 mL at 200 °C and from 105.7 mL to 42.5 mL at 240 °C, while maintaining filtration below 70 mL in 20% NaCl. Structural characterization via 1H NMR and FTIR, combined with TGA and aging tests, confirmed that VM's rigid five-membered ring significantly enhanced thermal stability; molecular weight retention after aging at 220 °C increased from 46.13% to 68.31%. Furthermore, DLS, SEM, and zeta potential analyses indicated that VM's cationic nature facilitates robust polymer adsorption on cement particles. This mechanism ensures effective particle dispersion and the formation of a dense filter cake even under extreme conditions. These findings provide essential insights for developing high-performance polymeric additives for cementing in complex downhole environments.
在高温环境下,深、超深油藏固井往往面临添加剂降解的严峻挑战。为了解决这个问题,将1-乙烯基咪唑(VM)加入到N,N-二甲基丙烯酰胺、衣康酸和2-丙烯酰胺-2-甲基丙磺酸的共聚中,合成了一种四聚物(PDVI)。采用响应面法优化的水溶液自由基聚合,得到的PDVI在高温和高盐度条件下表现出优异的降滤失性能。与对照样品PDI相比,PDVI在200°C时将滤失液从64.7 mL减少到25 mL,在240°C时从105.7 mL减少到42.5 mL,同时在20% NaCl条件下滤过率保持在70 mL以下。通过1H NMR和FTIR进行结构表征,结合TGA和老化测试,证实VM的刚性五元环显著提高了热稳定性;220℃时效后的分子量保留率由46.13%提高到68.31%。此外,DLS、SEM和zeta电位分析表明,VM的阳离子性质有助于聚合物在水泥颗粒上的牢固吸附。这种机制确保有效的颗粒分散和形成致密的滤饼,即使在极端条件下。这些发现为开发用于复杂井下环境的高性能聚合物固井添加剂提供了重要见解。
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引用次数: 0
Enhanced oil recovery in tight conglomerate reservoirs using CO2 flooding: A visual model with fractal-based zoning 利用CO2驱提高致密砾岩油藏采收率:基于分形分区的可视化模型
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2026-01-05 DOI: 10.1016/j.petlm.2025.12.004
Yuhao Lu , Jian Wang , Xiang Luo , Tianhan Xu , Danling Wang , Hongkun Wei
CO2 flooding has emerged as a valuable method for enhancing oil recovery (EOR) in fossil fuel reservoirs. However, the impact of micro-heterogeneity, particularly variations in pore sizes, on CO2 flooding following water flooding in conglomerate reservoirs remains insufficiently understood. This study introduces an advanced visual model integrating outcrop and nuclear magnetic resonance (NMR) analyses to overcome the limitations of traditional micromodels. Simulating reservoir conditions, the model evaluates oil displacement and sweep efficiency through a fractal-based pore classification system, categorizing pores into four types: small pores (P1), medium pores (P2 and P3), and large pores (P4). This classification provides a comprehensive analysis of residual oil patterns during water and CO2 flooding. Results show that water flooding primarily displaces oil from larger pores (P3 and P4), leaving residual oil trapped in smaller pores (P1 and P2). After 0.4 PV injection, oil begins migrating from smaller to larger pores(P4), reaching an oil recovery efficiency of 28.91% at 0.8 PV. In contrast, CO2 flooding significantly expands the sweep area and improves displacement efficiency despite minor gas channeling. NMR analysis indicates that CO2 flooding rapidly mobilizes oil in large pores (P4), while its effect on smaller pores (P1 and P2) remains limited. The cumulative signal amplitude decreases from 2914 to 2498, resulting in a displacement efficiency of 10.15% and a total recovery factor of 39.06%. This study provides valuable insights into optimizing CO2 immiscible flooding strategies and improving oil recovery efficiency in tight conglomerate reservoirs.
CO2驱油已成为提高化石燃料油藏采收率的一种有价值的方法。然而,微观非均质性,特别是孔隙大小的变化,对砾岩储层水驱后CO2驱的影响仍未得到充分的了解。为了克服传统微观模型的局限性,提出了一种结合露头和核磁共振分析的先进可视化模型。该模型模拟储层条件,通过基于分形的孔隙分类系统,将孔隙分为小孔隙(P1)、中等孔隙(P2和P3)和大孔隙(P4)四种类型,对驱油效果和波及效率进行了评价。该分类提供了水驱和CO2驱过程中剩余油形态的综合分析。结果表明:水驱油主要从较大孔隙(P3和P4)中驱油,剩余油被困在较小孔隙(P1和P2)中;注入0.4 PV后,原油开始由较小孔隙向较大孔隙(P4)运移,0.8 PV时采收率达到28.91%。相比之下,CO2驱油可以显著扩大波及面积,提高驱替效率,尽管存在较小的气窜。核磁共振分析表明,CO2驱油对大孔隙(P4)中的原油具有快速的动员作用,而对较小孔隙(P1和P2)的影响仍然有限。累计信号幅值从2914减小到2498,驱替效率为10.15%,总采收率为39.06%。该研究为致密砾岩油藏优化CO2非混相驱策略和提高采收率提供了有价值的见解。
{"title":"Enhanced oil recovery in tight conglomerate reservoirs using CO2 flooding: A visual model with fractal-based zoning","authors":"Yuhao Lu ,&nbsp;Jian Wang ,&nbsp;Xiang Luo ,&nbsp;Tianhan Xu ,&nbsp;Danling Wang ,&nbsp;Hongkun Wei","doi":"10.1016/j.petlm.2025.12.004","DOIUrl":"10.1016/j.petlm.2025.12.004","url":null,"abstract":"<div><div>CO<sub>2</sub> flooding has emerged as a valuable method for enhancing oil recovery (EOR) in fossil fuel reservoirs. However, the impact of micro-heterogeneity, particularly variations in pore sizes, on CO<sub>2</sub> flooding following water flooding in conglomerate reservoirs remains insufficiently understood. This study introduces an advanced visual model integrating outcrop and nuclear magnetic resonance (NMR) analyses to overcome the limitations of traditional micromodels. Simulating reservoir conditions, the model evaluates oil displacement and sweep efficiency through a fractal-based pore classification system, categorizing pores into four types: small pores (P1), medium pores (P2 and P3), and large pores (P4). This classification provides a comprehensive analysis of residual oil patterns during water and CO<sub>2</sub> flooding. Results show that water flooding primarily displaces oil from larger pores (P3 and P4), leaving residual oil trapped in smaller pores (P1 and P2). After 0.4 PV injection, oil begins migrating from smaller to larger pores(P4), reaching an oil recovery efficiency of 28.91% at 0.8 PV. In contrast, CO<sub>2</sub> flooding significantly expands the sweep area and improves displacement efficiency despite minor gas channeling. NMR analysis indicates that CO<sub>2</sub> flooding rapidly mobilizes oil in large pores (P4), while its effect on smaller pores (P1 and P2) remains limited. The cumulative signal amplitude decreases from 2914 to 2498, resulting in a displacement efficiency of 10.15% and a total recovery factor of 39.06%. This study provides valuable insights into optimizing CO<sub>2</sub> immiscible flooding strategies and improving oil recovery efficiency in tight conglomerate reservoirs.</div></div>","PeriodicalId":37433,"journal":{"name":"Petroleum","volume":"12 1","pages":"Pages 154-166"},"PeriodicalIF":3.5,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147420537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrocarbon generation potential evaluation of high–over mature Permian source rocks in the Southwestern part of the central depression, Junggar Basin 准噶尔盆地中央坳陷西南部二叠系高过熟烃源岩生烃潜力评价
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2026-01-23 DOI: 10.1016/j.petlm.2026.01.002
Chenyu Wang , Guanlong Zhang , Xiangchun Chang , Fengkai Shang , Bingbing Shi , Yansheng Qu , Tianjiao Liu , Shangbin Wang , Zhuanghao Peng
<div><div>A comprehensive study was conducted on the hydrocarbon generation potential of the deeply buried Permian source rocks with high–over mature in the southwestern part of the Central Depression, Junggar Basin. Using rock-eval pyrolysis, carbon-sulfur analysis, kerogen macerals analysis, adamantane quantification, molecular geochemistry, and major and trace element analysis, coupled with organic carbon recovery methods. The evaluation primarily focused on thermal maturation, types, and abundance of organic matter, with an emphasis on summarizing methods for evaluating high–over mature source rocks. The results demonstrate that the Permian source rocks in the Shawan Sag (Well Zhengshen-101) and the Penyijingxi Sag (Well Zhuangshen-1) have reached a high–over mature stage, as evidenced by vitrinite reflectance (<em>Ro</em>), adamantane parameters, methyl phenanthrene indices (MPI), and Laser Raman spectroscopy. Horizontally, for the Fengcheng (P<sub>1</sub><em>f</em>) and Lower Wuerhe (P<sub>2</sub><em>w</em>) formations, the Well Zhengshen-101 in the Shawan Sag is thermally more matured than the Well Zhuangshen-1 in the Penyijingxi Sag, while vertically, both wells show that the P<sub>1</sub><em>f</em> is thermally more mature than the P<sub>2</sub><em>w</em>. Raman and Fourier transform infrared (FTIR) spectroscopy confirm that Type II kerogen is the dominant organic matter type. Through material balance, degradation ratio, and inorganic element methods, obtain the original content of organic carbon (TOC<sub>0</sub>) and hydrocarbon generation potential (S<sub>1</sub>+S<sub>2</sub>). After restoration, the P<sub>1</sub><em>f</em> samples from Well Zhengshen-101 in the Shawan Sag show moderate to high-quality organic matter abundance, predominantly high-quality; the P<sub>2</sub><em>w</em> samples are classified as high-quality source rocks. The Xiazijie Formation (P<sub>2</sub><em>x</em>) and the P<sub>2</sub><em>w</em> samples from Well Zhuangshen-1 in the Penyijingxi Sag range from poor to high-quality, predominantly good to high-quality. Horizontally, the P<sub>2</sub><em>w</em> samples from Well Zhengshen-101 in the Shawan Sag exhibit higher organic matter abundance compared to those from Well Zhuangshen-1 in the Penyijingxi Sag. Notably, the P<sub>2</sub><em>x</em> source rocks in the Penyijingxi Sag demonstrate superior potential compared to the P<sub>2</sub><em>w</em>, highlighting their underexplored significance. Comprehensive analysis of the depositional environment in the study area indicates that the Well Zhengshen-101 in the Shawan Sag may experience a deeper, stable reducing environment with moderate sedimentation rates, stable water stratification, and a more abundant nutrient supply, all of which favor organic matter enrichment. This systematic evaluation advances methodologies for assessing high–over mature source rocks and underscores the exploration potential of high–over mature Permian source rocks in the Junggar Basin.
对准噶尔盆地中央坳陷西南部二叠系深埋高过熟烃源岩的生烃潜力进行了综合研究。采用岩石热解、碳硫分析、干酪根组分分析、金刚烷定量、分子地球化学、主微量元素分析等方法,结合有机碳回收方法。评价主要集中在热成熟度、有机质类型、有机质丰度等方面,重点总结了高过成熟烃源岩评价方法。通过镜质体反射率(Ro)、金刚烷参数、甲基菲指数(MPI)和激光拉曼光谱分析表明,沙湾凹陷(正深-101井)和盆一靖西凹陷(庄深-1井)二叠系烃源岩处于高过成熟阶段。在水平方向上,沙湾凹陷正深-101井的丰城组(P1f)和乌尔河下组(P2w)的热成熟度高于盆一靖西凹陷庄深-1井,而在垂直方向上,两口井的P1f井的热成熟度高于P2w井。拉曼光谱和傅里叶变换红外光谱(FTIR)证实了II型干酪根是主要的有机质类型。通过物质平衡法、降解比法和无机元素法,得到原始有机碳含量(TOC0)和生烃潜力(S1+S2)。恢复后,沙湾凹陷正深101井P1f样品有机质丰度为中~优质,以优质有机质为主;P2w样品为优质烃源岩。盆一靖西凹陷庄深1井夏子街组(P2x)和P2w样品由劣质到优质,以优质到优质为主。水平上,沙湾凹陷正深-101井的P2w样品有机质丰度高于盆一靖西凹陷庄深-1井。值得注意的是,盆一靖西凹陷P2x烃源岩潜力明显优于P2w烃源岩,凸显了其未被充分开发的意义。综合分析研究区沉积环境,认为沙湾凹陷正深101井可能处于较深、稳定的还原环境,沉积速率适中,水体分层稳定,养分供给较为充足,有利于有机质富集。系统评价了准噶尔盆地高过成熟烃源岩的评价方法,突出了准噶尔盆地二叠系高过成熟烃源岩的勘探潜力。同时,通过与四川盆地高度成熟的海相页岩对比,进一步凸显了本研究方法的创新性。
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引用次数: 0
A two-organoclay formulation approach for enhanced performance of oil-based drilling fluids 提高油基钻井液性能的双有机粘土配方方法
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2026-01-02 DOI: 10.1016/j.petlm.2025.12.003
Ali Mahmoud, Rahul Gajbhiye, Salaheldin Elkatatny
High-pressure and high-temperature (HPHT) drilling environments challenge the stability and efficiency of conventional oil-based drilling fluids (OBDFs). This study introduces a novel dual-organoclay (OC) formulation combining Claytone-II and Claytone-IMG 400 at a 1:1 ratio, designed to enhance OBDF performance under HPHT conditions. The selected OCs possess distinct mineralogies: one is rich in anorthite, while the other is dominated by montmorillonite, offering complementary properties. Comprehensive characterization using X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM), and particle size distribution (PSD) analysis revealed significant structural and compositional differences that underpin the observed synergy.
Experimental evaluation showed that the OC mixture outperformed individual OCs and a commercial benchmark (MC-TONE) in critical areas including rheology, filtration, and sag stability. Under 275 °F and 500 psi conditions, the dual-OC system improved plastic viscosity by 15.5%, yield point by 33%, and reduced filtrate volume and filter cake thickness by 16.5% and 11.5%, respectively. These enhancements contribute to better cuttings transport, reduced fluid loss, and improved wellbore stability.
The approach offers a cost-neutral yet performance-enhancing solution using commercially available OCs. It holds promise for extending OBDF applicability in HPHT wells while supporting safer, more efficient, and environmentally responsible drilling operations.
高压高温(HPHT)钻井环境对常规油基钻井液(OBDFs)的稳定性和效率提出了挑战。本研究介绍了一种新型双有机粘土(OC)配方,该配方将Claytone-II和Claytone-IMG 400以1:1的比例组合在一起,旨在提高高温条件下OBDF的性能。所选的OCs具有不同的矿物学:一种富含钙长石,而另一种以蒙脱石为主,具有互补的特性。通过x射线衍射(XRD)、x射线荧光(XRF)、扫描电镜(SEM)和粒度分布(PSD)分析,综合表征发现了支撑观察到的协同作用的显著结构和成分差异。实验评估表明,在流变性、过滤性和沉降稳定性等关键领域,OC混合物的性能优于单个OC和商业基准(MC-TONE)。在275°F和500 psi条件下,双oc体系将塑料粘度提高了15.5%,屈服点提高了33%,滤液体积和滤饼厚度分别减少了16.5%和11.5%。这些改进有助于更好地输送岩屑,减少流体漏失,提高井筒稳定性。该方法提供了一种成本中立但性能增强的解决方案,使用市售的oc。它有望扩大OBDF在高温高压井中的适用性,同时支持更安全、更高效、更环保的钻井作业。
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引用次数: 0
Research on the influence of silica fume on the long-term strength development of lightweight cement 硅灰对轻质水泥长期强度发展影响的研究
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-12-18 DOI: 10.1016/j.petlm.2025.12.002
Haodong Li , Chengwen Wang , Dingye Li , Wenjian Yue , Feng Zhao , Yuanbo Xia
Silica fume (SF) is commonly added to lightweight cement slurry (LWCS) to enhance strength and stability due to its nanoscale properties. However, the long-term strength development of SF-modified cement remains unclear. This study explores the effect of SF on the long-term strength of LWCS cured at 75 °C, 90 °C, and 105 °C, using compressive strength tests and microstructural analyses (XRD, SEM, EDS, TGA). SF initially improves strength through pozzolanic reactions, but over time, the C–S–H gel formed during hydration becomes more porous and looser. The addition of SF promotes the transformation of the C–S–H gel from a high Ca/Si ratio to a lower one, with rapid CH consumption accelerating porosity development. This weakens the bond between cement and hollow glass microspheres (HGMs), causing microcracks from stress differentials. These changes lead to internal bond deterioration and up to 56.76% strength reduction. While SF enhances early strength, it negatively affects long-term strength, raising the risk of cementing failure in oil and gas wells. Future research should focus on addressing long-term strength decline at higher temperatures and identifying alternative materials to mitigate this issue.
硅粉(SF)通常被添加到轻质水泥浆(LWCS)中,由于其纳米级特性,可以提高强度和稳定性。然而,sf改性水泥的长期强度发展仍不清楚。本研究通过抗压强度测试和微观结构分析(XRD, SEM, EDS, TGA),探讨了SF对75°C, 90°C和105°C固化LWCS长期强度的影响。SF最初通过火山灰反应提高强度,但随着时间的推移,水化过程中形成的C-S-H凝胶变得更加多孔和松散。SF的加入促进了C-S-H凝胶由高Ca/Si比向低Ca/Si比转变,CH的快速消耗加速了孔隙度的发育。这削弱了水泥与中空玻璃微球(HGMs)之间的结合,导致应力差产生微裂缝。这些变化导致内部结合恶化,强度降低达56.76%。虽然SF提高了早期强度,但对长期强度产生了负面影响,增加了油气井固井失败的风险。未来的研究应侧重于解决高温下的长期强度下降问题,并确定替代材料来缓解这一问题。
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引用次数: 0
Production optimization in shale formations: Focus on proppant delivery schedules and mitigation of fracture conductivity damage 页岩地层的生产优化:重点关注支撑剂的投放计划和减少裂缝导流性损害
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-12-13 DOI: 10.1016/j.petlm.2025.12.001
Ruud Weijermars
This study presents recent advances in modeling capacity and provides optimization guidelines for key operational parameters controlling well performance, using real well data. A new Gaussian solution method can both accurately forecast well rates prior to drilling and history match actual well performance after completion once early production data become available. Unlike other history-matching tools, excellent matches are achieved with daily production data spanning just a few months. The study also addresses key challenges in achieving precision in hydraulic fracturing and horizontal well design, emphasizing unresolved subsurface heterogeneity, variability in treatment quality, and modeling tool limitations. Advanced analytical methods, such as the Gaussian Production Forecasting (GPT) method, offer improved accuracy and computational efficiency for production predictions. Empirical data from the Eagle Ford and Wolfcamp formations demonstrate significant performance gains over the past decade, driven by optimized fracture spacing, increased lateral lengths, and enhanced proppant usage. However, performance gaps persist due to poor proppant conductivity, closure stress impacts, and proppant transport inefficiencies. This study highlights the critical impact of fracture conductivity damage on shale well performance, as revealed by Gaussian well performance curves derived from historical data. The findings emphasize the need for integrating advanced modeling tools, optimizing proppant delivery strategies, and improving transport simulations to achieve sustained productivity gains in shale reservoirs.
该研究展示了建模能力的最新进展,并利用实际井数据为控制井性能的关键操作参数提供了优化指导。一种新的高斯解方法既可以在钻井前准确预测井速,又可以在获得早期生产数据后,在完井后与实际井况匹配。与其他历史匹配工具不同,只需几个月的日常生产数据就可以实现出色的匹配。该研究还解决了实现水力压裂和水平井设计精度的关键挑战,强调了未解决的地下非均质性、处理质量的可变性以及建模工具的局限性。先进的分析方法,如高斯生产预测(GPT)方法,提高了生产预测的准确性和计算效率。来自Eagle Ford和Wolfcamp地层的经验数据表明,在过去十年中,由于优化了裂缝间距、增加了水平段长度和增加了支撑剂的使用,该油藏的性能得到了显著提高。然而,由于支撑剂导流性差、闭合应力影响和支撑剂输送效率低下,性能差距仍然存在。该研究强调了裂缝导流性损害对页岩井性能的关键影响,正如由历史数据导出的高斯井动态曲线所揭示的那样。研究结果强调,需要集成先进的建模工具,优化支撑剂输送策略,改进输送模拟,以实现页岩储层持续的产能提高。
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引用次数: 0
Nanoparticles and nanocomposites in enhanced oil recovery, asphaltene inhibition, and carbon dioxide sequestration: Mechanisms and prospects 纳米颗粒和纳米复合材料在提高采收率、沥青烯抑制和二氧化碳封存中的应用:机制和前景
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2026-01-31 DOI: 10.1016/j.petlm.2026.01.006
Ehsan Jafarbeigi , Amir H. Mohammadi
This study provides a comprehensive review of nano-particles and nano-composites applications in oilfield, focusing on their roles in enhanced oil recovery (EOR), asphaltene deposition mitigation, and CO2 storage. Building on prior research, it identifies the most promising nanotechnology-based approaches and outlines a detailed roadmap for future breakthroughs. Thus, in this regard, the review evaluates 21 nanomaterials, including Al2O3 (γ/α phases), SiO2, MgO, CuO, ZrO2, NiO, graphene oxide (GO), SnO, CaCO3, CeO2, TiO2, carbon nanotubes (CNT), and hybrid composites (e.g., SiO2/γ-Al2O3, TiO2/MgO, ZnO/γ-Al2O3, ZnO/CuO, ZnO/ZrO2, TiO2/SiO2, TiO2/ZnO, Fe3O4/SiO2, and CuO/Al2O3), demonstrating their superior performance in improving operational efficiency. The findings demonstrate that nanotechnology offers superior performance, highlighting its potential to revolutionize the oil industry by improving oil production efficiency. On the other hand, nano-particles such as ZnO, Al2O3, SiO2, and TiO2 stand out due to their strong adsorption capacity, thermal stability, and ability to tune deposition mechanisms. Also, notably, nano-composites (such as SiO2+Al2O3 and Fe2O3+Al2O3) excel in asphaltene inhibition due to synergistic nano-particle-hydrocarbon interactions. The results also show that nano-composites (TiO2@SiO2) increase the integrity of CO2 storage. Generally, this study highlights key challenges hindering large-scale implementation and serves as a critical resource for researchers advancing nanotechnology in petroleum engineering.
本研究综述了纳米颗粒和纳米复合材料在油田中的应用,重点介绍了纳米颗粒和纳米复合材料在提高采收率(EOR)、减缓沥青质沉积和二氧化碳储存方面的作用。在先前研究的基础上,它确定了最有前途的基于纳米技术的方法,并概述了未来突破的详细路线图。因此,本文评价了21种纳米材料,包括Al2O3 (γ/α相)、SiO2、MgO、CuO、ZrO2、NiO、氧化石墨烯(GO)、SnO、CaCO3、CeO2、TiO2、碳纳米管(CNT)和混合复合材料(如SiO2/γ-Al2O3、TiO2/MgO、ZnO/γ-Al2O3、ZnO/CuO、ZnO/ZrO2、TiO2/SiO2、TiO2/ZnO、Fe3O4/SiO2和CuO/Al2O3),展示了它们在提高操作效率方面的卓越性能。研究结果表明,纳米技术提供了卓越的性能,突出了其通过提高石油生产效率来彻底改变石油行业的潜力。另一方面,纳米颗粒如ZnO、Al2O3、SiO2和TiO2因其强大的吸附能力、热稳定性和调节沉积机制的能力而脱颖而出。此外,值得注意的是,纳米复合材料(如SiO2+Al2O3和Fe2O3+Al2O3)由于协同的纳米颗粒-碳氢化合物相互作用,在沥青质抑制方面表现优异。结果还表明,纳米复合材料(TiO2@SiO2)提高了CO2储存的完整性。总的来说,这项研究突出了阻碍大规模实施的关键挑战,并为研究人员在石油工程中推进纳米技术提供了重要资源。
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引用次数: 0
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Petroleum
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