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Leakage and diffusion characteristics of underground hydrogen pipeline 地下氢气管道的泄漏和扩散特性
Q2 ENERGY & FUELS Pub Date : 2024-06-01 DOI: 10.1016/j.petlm.2023.06.002
Wenkang Zhang, Guanghui Zhao

Soil corrosion and hydrogen embrittlement are the main factors of hydrogen pipeline failure. The gas escapes, diffuses and accumulates in the soil and enters the atmosphere when leak occurs. The mechanism of gas diffusion in buried pipelines is very complicated. Mastering the evolution law of hydrogen leakage diffusion is conducive to quickly locating the leakage point and reducing the loss. The leakage model of the underground hydrogen pipeline is established in this paper. The effect of leakage hole, soil type, pipeline pressure, pipeline diameter on hydrogen leakage diffusion were investigated. The results show that when the hydrogen pipeline leaks, the hydrogen concentration increases with the increase of leakage time, showing a symmetrical distribution trend. With the pipeline pressure increase, hydrogen leakage speed is accelerated, and longitudinal diffusion gradually becomes the dominant direction. As the leakage diameter increases, hydrogen leakage per unit of time increases sharply. Hydrogen diffuses more easily in sandy soil, and its diffusion speed, concentration, and range are higher than that in clay soil. The research content provides a reference and basis for the detection and evaluation of buried hydrogen pipeline leakage.

土壤腐蚀和氢脆是氢气管道失效的主要因素。发生泄漏时,气体会在土壤中逸出、扩散和积聚,并进入大气。气体在埋地管道中的扩散机理非常复杂。掌握氢气泄漏扩散的演变规律,有利于快速定位泄漏点,减少损失。本文建立了地下氢气管道的泄漏模型。研究了泄漏孔、土壤类型、管道压力、管道直径对氢气泄漏扩散的影响。结果表明,氢气管道泄漏时,氢气浓度随泄漏时间的增加而增加,呈对称分布趋势。随着管道压力的增加,氢气泄漏速度加快,纵向扩散逐渐成为主导方向。随着泄漏直径的增大,单位时间内的氢气泄漏量急剧增加。氢气在砂土中更容易扩散,其扩散速度、浓度和范围均高于粘土。研究内容为埋地氢气管道泄漏的检测和评估提供了参考和依据。
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引用次数: 0
A hybrid machine learning approach based study of production forecasting and factors influencing the multiphase flow through surface chokes 基于混合机器学习方法的生产预测和多相流通过表面扼流圈的影响因素研究
Q2 ENERGY & FUELS Pub Date : 2024-06-01 DOI: 10.1016/j.petlm.2023.06.001
Waquar Kaleem , Saurabh Tewari , Mrigya Fogat , Dmitriy A. Martyushev

Surface chokes are widely utilized equipment installed on wellheads to control hydrocarbon flow rates. Several correlations have been suggested to model the multiphase flow of oil and gas via surface chokes. However, substantial errors have been reported in empirical fitting models and correlations to estimate hydrocarbon flow because of the reservoir's heterogeneity, anisotropism, variance in reservoir fluid characteristics at diverse subsurface depths, which introduces complexity in production data. Therefore, the estimation of daily oil and gas production rates is still challenging for the petroleum industry. Recently, hybrid data-driven techniques have been reported to be effective for estimation problems in various aspects of the petroleum domain. This paper investigates hybrid ensemble data-driven approaches to forecast multiphase flow rates through the surface choke (viz. stacked generalization and voting architectures), followed by an assessment of the impact of input production control variables. Otherwise, machine learning models are also trained and tested individually on the production data of hydrocarbon wells located in North Sea. Feature engineering has been properly applied to select the most suitable contributing control variables for daily production rate forecasting. This study provides a chronological explanation of the data analytics required for the interpretation of production data. The test results reveal the estimation performance of the stacked generalization architecture has outperformed other significant paradigms considered for production forecasting.

地面扼流圈是安装在井口的广泛使用的设备,用于控制碳氢化合物的流速。已经提出了几种相关方法来模拟油气通过表层扼流圈的多相流动。然而,由于储层的异质性、各向异性、不同地下深度储层流体特性的差异,以及生产数据的复杂性,估算碳氢化合物流量的经验拟合模型和相关系数存在很大误差。因此,对石油工业而言,估算石油和天然气的日产量仍是一项挑战。最近,有报道称混合数据驱动技术可有效解决石油领域各方面的估算问题。本文研究了混合集合数据驱动方法(即堆叠泛化和投票架构)来预测通过地表卡口的多相流量,然后评估了输入生产控制变量的影响。此外,还在北海碳氢化合物井的生产数据上对机器学习模型进行了单独训练和测试。特征工程学已被恰当地应用于为日产量预测选择最合适的贡献控制变量。本研究按时间顺序解释了解释生产数据所需的数据分析。测试结果表明,堆叠泛化架构的估算性能优于用于产量预测的其他重要范例。
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引用次数: 0
Investigation of pore structure alteration and permeability enhancement of shale matrix by supercritical water treatment after hydraulic fracturing 水力压裂后超临界水处理对页岩基质孔隙结构改变和渗透性增强的研究
Q2 ENERGY & FUELS Pub Date : 2024-06-01 DOI: 10.1016/j.petlm.2022.05.002
Yili Kang , Peisong Li , Wangkun Cao , Mingjun Chen , Lijun You , Jiang Liu , Zhehan Lai

Shale gas reservoirs are unconventional tight gas reservoirs, in which horizontal wells and hydraulic fracturing are required to achieve commercial development. The fracture networks created by hydraulic fracturing can increase the drainage area extensively to enhance shale gas recovery. However, large volumes of fracturing fluid that is difficult to flow back to the surface and remained in the shale formation, will inevitably lead to damages of the shale formations and limit the effectiveness of stimulation. Supercritical water (SCW) treatment after hydraulic fracturing is a new method to enhance shale gas recovery by using appropriate heat treatment methods to the specific formation to convert the retained fracturing fluid into a supercritical state (at temperatures in excess of 373.946°C and pressures in excess of 22.064 MPa). An experiment was conducted to simulate the reaction between shale and SCW, and the capacity of SCW treatment to enhance the permeability of the shale was evaluated by measuring the response of the shale porosity and permeability on SCW treatment. The experimental results show that the shale porosity and permeability increase by 213.43% and 2198.37%, respectively. The pore structure alteration and permeability enhancement of the shale matrix were determined by analyzing the changes in pore structure and mineral composition after SCW treatment. The mechanisms that affect pore structure and mineral composition include oxidative catalysis decomposition of organic matters and reducing minerals, acid-catalyzed decomposition of carbonate minerals and feldspar minerals, hydrothermal catalysis induced fracture extension and cementation weakening induced fracture extension. SCW treatment converts harm into a benefit by reducing the intrusion of harmful substances into the shale formation, which will broaden the scope and scale of shale formation stimulation.

页岩气藏属于非常规致密气藏,需要通过水平井和水力压裂技术实现商业开发。水力压裂所形成的裂缝网络可以大量增加排水面积,从而提高页岩气的采收率。然而,大量压裂液难以流回地表,滞留在页岩层中,势必会对页岩层造成破坏,限制增产效果。水力压裂后的超临界水(SCW)处理是一种提高页岩气采收率的新方法,它针对特定地层采用适当的热处理方法,将保留的压裂液转化为超临界状态(温度超过 373.946°C,压力超过 22.064 兆帕)。实验模拟了页岩与超临界水的反应,并通过测量页岩孔隙度和渗透率对超临界水处理的响应,评估了超临界水处理提高页岩渗透率的能力。实验结果表明,页岩的孔隙率和渗透率分别增加了 213.43% 和 2198.37%。通过分析超临界水处理后孔隙结构和矿物成分的变化,确定了页岩基质孔隙结构的改变和渗透率的提高。影响孔隙结构和矿物组成的机制包括有机物和还原性矿物的氧化催化分解、碳酸盐矿物和长石矿物的酸催化分解、热液催化诱导裂缝扩展以及胶结弱化诱导裂缝扩展。超临界水处理通过减少有害物质对页岩地层的侵入,化害为利,这将扩大页岩地层激励的范围和规模。
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引用次数: 0
Asphaltene onset pressure measurement and calculation techniques: A review 沥青质起始压力测量和计算技术:综述
Q2 ENERGY & FUELS Pub Date : 2024-06-01 DOI: 10.1016/j.petlm.2023.04.001
Sherif Fakher, Amr Yousef, Aseel Al-Sakkaf, Shams Eldakar

Asphaltene precipitation can result in several production, operational, and transportation problems during oil recovery. If asphaltene precipitates and deposits, it can reduce reservoir permeability, damage wellbore equipment, and plug the pipelines. It is therefore extremely important to evaluate the conditions at which asphaltene precipitation occurs; this is referred to as the asphaltene onset pressure. Asphaltene onset pressure has been measured using many different experimental techniques. There have also been many attempts along the years to predict asphaltene onset pressure using mathematical correlations and models. This research provides an up-to-date comprehensive review of the methods by which asphaltene onset pressure can be measured using laboratory experiments and mathematical models. The research explains the main mechanisms of all the laboratory experiments to measure asphaltene onset pressure under static conditions and how to conduct them and highlights the advantages and limitations of each method. The research also provides a summary of the commonly used mathematical models to quantify asphaltene onset pressure directly and indirectly.

在采油过程中,沥青质沉淀会导致一些生产、操作和运输问题。如果沥青质析出并沉积,会降低储油层的渗透性,损坏井筒设备,堵塞管道。因此,评估沥青质析出的条件极为重要,这被称为沥青质起始压力。沥青质析出压力的测量采用了多种不同的实验技术。多年来,也有很多人尝试使用数学关联和模型来预测沥青质析出压力。本研究全面回顾了利用实验室实验和数学模型测量沥青质起始压力的最新方法。研究解释了在静态条件下测量沥青质起始压力的所有实验室实验的主要机制以及如何进行这些实验,并强调了每种方法的优势和局限性。研究还总结了直接和间接量化沥青质起始压力的常用数学模型。
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引用次数: 0
Studying the effect of surfactant assisted low-salinity water flooding on clay-rich sandstones 研究表面活性剂辅助低盐度水浸对富粘土砂岩的影响
Q2 ENERGY & FUELS Pub Date : 2024-06-01 DOI: 10.1016/j.petlm.2023.09.006
Saeed Khezerloo-ye Aghdam , Alireza Kazemi , Mohammad Ahmadi

Sandstone reservoirs often contain clay particles that can cause damage and reduce permeability during low-salinity water flooding. In this study, the effect of surfactants on fine migration in clay-rich sandstones and its impact on oil recovery was investigated.

First, the impact of surfactants on interparticle forces in fine-matrix, fine-fine, and oil-matrix systems was modeled. The results showed that both CTAB (cetyltrimethyl ammonium bromide) and QS (quillaja saponin) cause EDL compaction, weakening the repulsive forces. However, SDS (sodium dodecyl sulfate) and TX (triton X-100) do not affect the EDL. Next, the effect of surfactants on IFT reduction and wettability alteration was experimentally investigated. All surfactants reduced IFT due to the surface excessive concentration mechanism. The wettability alteration experiment illustrated that although QS and CTAB compact EDL around oil and matrix particles leading to attraction force augmentation, they both alter wettability through adsorption on matrix and carboxylic groups present in crude oil, respectively.

Surfactant aqueous solutions were then injected into various clay-rich sandstone sanpacks, which resulted in increased oil recovery. However, the mechanisms leading to enhanced oil recovery variedby surfactant type. CTAB increased recovery by 10% through IFT reduction and wettability alteration, while SDS and TX increased recovery by 12% and 9%, respectively, through wettability alteration and extreme fine migration. In contrast, partial fine migration in the QS flooding experiment reached a recovery increase of 18%. Permeability trends through experiments were also recorded. During CTAB injection, permeability did not reduce, while QS aqueous solution reduced rock permeability to 5 mD. SDS and TX reduced the magnitude of permeability to 2 mD.

In conclusion, this study demonstrates that surfactants can effectively improve oil recovery in clay-rich sandstones by altering the interparticle forces, reducing IFT, and changing wettability. The results suggest that the type of surfactant used should be carefully selected to achieve the desired recovery increase without affecting the permeability of the reservoir.

砂岩储层通常含有粘土颗粒,在低盐度水淹时会造成破坏并降低渗透率。在这项研究中,研究了表面活性剂对富含粘土的砂岩中细粒迁移的影响及其对采油的影响。首先,模拟了表面活性剂对细粒-基质、细粒-细粒和油-基质体系中颗粒间作用力的影响。结果表明,CTAB(十六烷基三甲基溴化铵)和 QS(诃子皂苷)都会导致 EDL 压缩,削弱排斥力。然而,SDS(十二烷基硫酸钠)和 TX(triton X-100)对 EDL 没有影响。接下来,实验研究了表面活性剂对减少 IFT 和改变润湿性的影响。由于表面过度浓缩机制,所有表面活性剂都降低了 IFT。润湿性改变实验表明,虽然 QS 和 CTAB 可压实油和基质颗粒周围的 EDL,从而增强吸引力,但它们都分别通过吸附基质和原油中的羧基来改变润湿性。然而,表面活性剂类型不同,导致采油率提高的机制也不同。CTAB 通过降低 IFT 和改变润湿性使采收率提高了 10%,而 SDS 和 TX 则通过改变润湿性和极度细微迁移使采收率分别提高了 12% 和 9%。相比之下,QS 淹没实验中的部分细微迁移使回收率提高了 18%。实验还记录了渗透率的变化趋势。在注入 CTAB 时,渗透率没有降低,而 QS 水溶液则将岩石渗透率降低到 5 mD。总之,这项研究表明,表面活性剂可以通过改变颗粒间作用力、降低 IFT 和改变润湿性来有效提高富粘砂岩的采油率。研究结果表明,应谨慎选择所使用的表面活性剂类型,以便在不影响储层渗透性的情况下实现理想的提高采收率效果。
{"title":"Studying the effect of surfactant assisted low-salinity water flooding on clay-rich sandstones","authors":"Saeed Khezerloo-ye Aghdam ,&nbsp;Alireza Kazemi ,&nbsp;Mohammad Ahmadi","doi":"10.1016/j.petlm.2023.09.006","DOIUrl":"10.1016/j.petlm.2023.09.006","url":null,"abstract":"<div><p>Sandstone reservoirs often contain clay particles that can cause damage and reduce permeability during low-salinity water flooding. In this study, the effect of surfactants on fine migration in clay-rich sandstones and its impact on oil recovery was investigated.</p><p>First, the impact of surfactants on interparticle forces in fine-matrix, fine-fine, and oil-matrix systems was modeled. The results showed that both CTAB (cetyltrimethyl ammonium bromide) and QS (quillaja saponin) cause EDL compaction, weakening the repulsive forces. However, SDS (sodium dodecyl sulfate) and TX (triton X-100) do not affect the EDL. Next, the effect of surfactants on IFT reduction and wettability alteration was experimentally investigated. All surfactants reduced IFT due to the surface excessive concentration mechanism. The wettability alteration experiment illustrated that although QS and CTAB compact EDL around oil and matrix particles leading to attraction force augmentation, they both alter wettability through adsorption on matrix and carboxylic groups present in crude oil, respectively.</p><p>Surfactant aqueous solutions were then injected into various clay-rich sandstone sanpacks, which resulted in increased oil recovery. However, the mechanisms leading to enhanced oil recovery variedby surfactant type. CTAB increased recovery by 10% through IFT reduction and wettability alteration, while SDS and TX increased recovery by 12% and 9%, respectively, through wettability alteration and extreme fine migration. In contrast, partial fine migration in the QS flooding experiment reached a recovery increase of 18%. Permeability trends through experiments were also recorded. During CTAB injection, permeability did not reduce, while QS aqueous solution reduced rock permeability to 5 mD. SDS and TX reduced the magnitude of permeability to 2 mD.</p><p>In conclusion, this study demonstrates that surfactants can effectively improve oil recovery in clay-rich sandstones by altering the interparticle forces, reducing IFT, and changing wettability. The results suggest that the type of surfactant used should be carefully selected to achieve the desired recovery increase without affecting the permeability of the reservoir.</p></div>","PeriodicalId":37433,"journal":{"name":"Petroleum","volume":"10 2","pages":"Pages 306-318"},"PeriodicalIF":0.0,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2405656123000640/pdfft?md5=db1c947c4dd6b393aad4cbc74d35ac13&pid=1-s2.0-S2405656123000640-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135389456","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fracturing-flooding technology for low permeability reservoirs: A review 低渗透储层的压裂-注水技术:综述
Q2 ENERGY & FUELS Pub Date : 2024-06-01 DOI: 10.1016/j.petlm.2023.11.004
Nianyin Li , Shijie Zhu , Yue Li , Jingrui Zhao , Bo Long , Fei Chen , Erzhen Wang , Wentao Feng , Yanan Hu , Shubei Wang , Chen Jiang

The development of low-permeability oil and gas resources presents a significant challenge to traditional development methods. To address the problem of “no injection and no production” in low -permeability reservoirs, a novel fracture-injection-production integration technology named fracturing-flooding has been proposed by oilfield sites. This technology combines the advantages of conventional fracturing, water flooding, and chemical flooding, resulting in improved reservoir physical properties, increased injection, replenished energy, and increased oil displacement efficiency. The technology is especially suitable for low-permeability reservoirs that suffer from lack of energy, and strong heterogeneity. Fracturing-flooding technology has shown significant results and broad development prospects in some oilfields in China. This paper analyzes the development status of fracturing-flooding technology from its development history, technical mechanism, technical characteristics, process flow, types of fracturing and oil displacement fluids, and field applications. Physical and numerical simulations of fracturing-flooding technology are also summarized. The results suggest that fracturing-flooding technology is more effective than conventional fracturing, water flooding, and chemical flooding in stimulating low-permeability tight reservoirs and improving oil recovery. Moreover, it has a high input-output ratio and can be utilized for future reservoir stimulation and transformation.

低渗透油气资源的开发对传统开发方法提出了巨大挑战。为了解决低渗透油气藏 "不注不采 "的问题,油田现场提出了一种名为 "压裂-水淹 "的新型压裂-注采一体化技术。该技术结合了常规压裂、水淹和化学水淹的优点,可改善储层物性,提高注采量,补充能量,提高排油效率。该技术尤其适用于缺乏能量和异质性较强的低渗透油藏。压裂-注水技术在我国一些油田取得了显著成效,发展前景广阔。本文从压裂-注水技术的发展历程、技术机理、技术特点、工艺流程、压裂液和驱油液类型、现场应用等方面分析了压裂-注水技术的发展现状。同时还对压裂-注水技术的物理和数值模拟进行了总结。研究结果表明,在刺激低渗透致密油藏和提高石油采收率方面,压裂-注水技术比常规压裂、水淹和化学水淹技术更有效。此外,它还具有较高的投入产出比,可用于未来的储层刺激和改造。
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引用次数: 0
A thermo-mechanical simulation for the stability analysis of a horizontal wellbore in underground coal gasification 地下煤炭气化过程中水平井筒稳定性分析的热力学模拟
Q2 ENERGY & FUELS Pub Date : 2024-06-01 DOI: 10.1016/j.petlm.2023.11.003
Mohammadreza Shahbazi , Mehdi Najafi , Mohammad Fatehi Marji , Ramin Rafiee

The stability analysis of horizontal wells is essential for a successful underground coal gasification (UCG) operation. In this paper, a new 3D coupled thermo-mechanical numerical modeling is proposed for analyzing the stability of UCG horizontal wells. In this model, the effect of front abutment stresses, syngas pressure, syngas temperature and thermal stresses is considered to predict the mud weight window and drilling mud pressure during UCG process. The results show that the roof caving in UCG panel has a greatest impact on the stability of horizontal well. Moreover, when the time of coal gasification is increased, the well convergence increases and for more stability it is necessary to increase the drilling mud pressure. This research was carried out on the M2 coal seam in Mazino coal deposit (Iran). The results showed that the mud weight window for horizontal well drilling is between 0 and 33 MPa. The appropriate stress for the maximum stability of the horizontal well, taking all the thermal and mechanical parameters into account, is 28 MPa. The suggested numerical method is a comprehensive and consistent way for analyzing the stability of horizontal wells in UCG sites.

水平井的稳定性分析对于地下煤气化(UCG)的成功运行至关重要。本文提出了一种新的三维热力-机械耦合数值模型,用于分析 UCG 水平井的稳定性。在该模型中,考虑了前支墩应力、合成气压力、合成气温度和热应力的影响,以预测 UCG 过程中的泥浆重量窗口和钻井泥浆压力。结果表明,UCG 面板顶板塌陷对水平井稳定性的影响最大。此外,当煤炭气化时间增加时,井的收敛性增加,为了提高稳定性,有必要增加钻井泥浆压力。这项研究是在伊朗 Mazino 煤矿的 M2 煤层进行的。结果表明,水平井钻井的泥浆重量窗口在 0 至 33 兆帕之间。考虑到所有热参数和机械参数,水平井最大稳定性的适当应力为 28 兆帕。所建议的数值方法是分析铀转化天然气(UCG)场地水平井稳定性的一种全面、一致的方法。
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引用次数: 0
Investigation of the transformation of organic matter of carbonate deposits of the Semiluksky–Mendymsky horizon under hydrothermal conditions 塞米卢克斯基-门迪姆斯基地层碳酸盐沉积有机物在热液条件下的转化研究
Q2 ENERGY & FUELS Pub Date : 2024-06-01 DOI: 10.1016/j.petlm.2023.07.001
S.M. Petrov , A.I. Lakhova , E.G. Moiseeva , A.G. Safiulina
<div><p>The paper presents the results of studies on the transformation of the organic matter of siliceous-clayey carbonate rocks of the Semiluksko–Mendymsky horizon of the Romashkino oil field in a hydrothermal fluid for an hour (with a water-to-rock ratio of 33) at 340°C and 380°C and pressures of 17 and 20 MPa. As a result of hydrothermal treatment, at 340°C and 17 MPa, based on nitrogen porosimetry and electron microscopy data, transformations of rock-forming minerals in the rock are observed. They lead to an increase in the volume and average diameter of mesopores in it and the formation of micropores, as well, which improve its filtration properties. At the same time, the amount of kerogen in the composition of the organic matter decreases and the yield of the petroleum hydrocarbon extract increases, in which, according to the SARA analysis, the content of asphaltenes increases and the content of resins, aromatic and saturated hydrocarbons decreases. In the composition of aroatic hydrocarbons, the proportion of alkyltrimethylbenzenes and dibenzothiophenes increases, phenanthrene homologues appear, and in the composition of saturated hydrocarbons, the amount of iso-structure alkanes decreases relative to the content of linear alkanes. Raising the temperature and pressure of the hydrothermal fluid to 380°С and 20 MPa increases the degree of kerogen conversion from 12.4% to 23.6%. At the same time, changes occurring in the component composition of petroleum hydrocarbon extracts remains similar to the experiments carried out at 340°C and 17 MPa; the content of naphthalenes decreases, the content of dibenzothiophenes increases and C<sub>11</sub>–C<sub>17</sub>, C<sub>19</sub>–C<sub>22</sub> alkyltrimethylbenzenes appear. According to IR spectroscopy, with increasing temperature and pressure of the hydrothermal fluid the intensity of the absorption bands of the aromatic ring, aliphatic fragments, and oxygen-containing groups increases in resins; the structural-group composition of asphaltenes changes little: aromaticity and the content of condensed structures slightly increase. The revealed distinctive features in the composition of organic matter after hydrothermal impact on siliceous-clayey carbonate rocks confirm the concept of staged destruction of kerogen, when large structural heteroatomic blocks (asphaltenes) are split off at the initial stages. Changes occurring in the composition of petroleum hydrocarbon extracts indicate their involvement in the process of hydrothermal transformation of organic matter of siliceous-clayey carmbonate rocks with the predominant reactions of dehydrogenation of naphthenic compounds and oxidative polycondensation of aromatic structures. The data of electron microscopy and nitrogen porosimetry of rocks after hydrothermal exposure at 380°С and 20 MPa indicate a deterioration in their reservoir properties. The most optimal thermobaric conditions of the hydrothermal fluid for the generation of petroleum hydrocarb
本文介绍了罗曼什金诺油田塞米卢克斯科-门迪姆斯基地层硅质粘土质碳酸盐岩有机物在 340°C 和 380°C、17 和 20 兆帕压力下的热液(水岩比为 33)中转化一小时的研究结果。根据氮气孔测定法和电子显微镜数据,在 340°C 和 17 兆帕压力下进行热液处理后,岩石中的成岩矿物发生了转变。这些变化导致中孔的体积和平均直径增大,并形成了微孔,从而改善了岩石的过滤性能。同时,有机物成分中的角质含量减少,石油烃提取物的产量增加,根据 SARA 分析,其中沥青质含量增加,树脂、芳香烃和饱和烃含量减少。在芳香烃的成分中,烷基三甲基苯和二苯并噻吩的比例增加,出现了菲同系物,而在饱和烃的成分中,等结构烷烃的含量相对于线性烷烃的含量有所减少。将热液的温度和压力提高到 380°С 和 20 兆帕,可将角质转化率从 12.4% 提高到 23.6%。同时,石油烃萃取物成分的变化与在 340°C 和 17 兆帕下进行的实验相似;萘的含量减少,二苯并噻吩的含量增加,并出现了 C11-C17、C19-C22 烷基三甲基苯。红外光谱显示,随着热液温度和压力的升高,树脂中芳香环、脂肪族片段和含氧基团的吸收带强度增加;沥青质的结构基团组成变化不大:芳香度和缩合结构的含量略有增加。热液冲击硅质粘土质碳酸盐岩后,有机物组成的显著特点证实了角质层分阶段破坏的概念,即大型结构异原子块(沥青质)在最初阶段被分裂。石油烃萃取物成分的变化表明,它们参与了硅质粘土质碳酸盐岩有机物的热液转化过程,主要反应为环烷化合物的脱氢和芳香结构的氧化缩聚。在 380°С 和 20 兆帕下对岩石进行热液曝晒后,电子显微镜和氮孔测定法的数据表明,岩石的储层特性有所下降。从罗马什基诺油田塞米卢克斯科-门迪姆斯基地层硅质粘土质碳酸盐矿床的角质中生成石油烃的最理想热液热压条件是 340°С 和 17 兆帕;这意味着难以回收的重烃资源和成熟的原地转化催化方法。
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引用次数: 0
Sedimentary characteristics and lithofacies paleogeography of the Cambrian in Sichuan basin, Southwest China 中国西南四川盆地寒武纪沉积特征和岩相古地理
Q2 ENERGY & FUELS Pub Date : 2024-06-01 DOI: 10.1016/j.petlm.2022.02.003
Lin Xie , Xuefei Yang , Yanhong Zhang , Yan Xu , Deming Zeng , Ruifeng Tang , Yao Du , Xingzhi Wang

Cambrian in Sichuan basin developed thick black shale, varies carbonate and clastic rock, which deposited in different sedimentary environment. Sichuan basin in the upper Yangtze platform contained a record of environment during the Cambrian. Detail facies analyses of Cambrian enable us to discuss the sedimentary environment and palaeogeographic setting. Sedimentation commenced in the Early Cambrian with the deposition of shelf facies (Qiongzhusi Formation and Canglangpu Formation). At this stage, thick shale and clastic rock deposited in Sichuan basin. At the end of the Early Cambrian, a carbonate platform developed in upper Yangtze platform, and Sichuan basin was located in restricted platform (Longwangmiao Formation). In the Middle Cambrian, tidal flat and restricted platform developed in Sichuan basin (Douposi Formation), because of continuous regression. During the Late Cambrian, Sichuan basin was located in carbonate platform again (Xixiangchi Formation). There are three types of sedimentary system in the Cambrian of Sichuan basin: clastic sedimentary system, clastics-carbonate mixed sedimentary system and carbonate sedimentary system. Vertically, the basin shows the evolutionary character of clastic-carbonate sedimentary systems. The three sedimentary systems correspond to three “transgression-regression” cycles of the Cambrian. The transgression in the initial period of the Early Cambrian led to the formation of clastic sedimentary system in the Qiongzhusi Formation of Lower Cambrian. The transgression in the later period of the Early Cambrian led to the formation of clastic-carbonate mixed sedimentary system in the Middle-Lower Cambrian. The transgression in the initial period of the Late Cambrian led to the formation of carbonate sedimentary system in the Xixiangchi Formation of Upper Cambrian. With the end of Late Sinian continental rifting ended, Sichuan basin entered a stable evolutionary stage of the craton basin, while the paleo-land developed in the north and southwest. In Qiongzhusi-Canglangpu period, the basin developed onshore-shelf sedimentary facies from west to east; In Longwangmiao-Xixiangchi period, the basin developed tidal flat-platform-slope sedimentary facies from west to east.

四川盆地的寒武纪发育了厚厚的黑色页岩、多种多样的碳酸盐岩和碎屑岩,它们沉积在不同的沉积环境中。位于长江上游地台的四川盆地记录了寒武纪的环境。通过对寒武纪详细的岩相分析,我们可以探讨当时的沉积环境和古地理环境。早寒武世沉积始于陆架层(琼珠寺层和沧浪铺层)的沉积。在这一阶段,四川盆地沉积了厚厚的页岩和碎屑岩。早寒武世末期,长江上游地台发育碳酸盐岩平台,四川盆地位于受限平台上(龙王庙地层)。中寒武统时期,四川盆地(豆豉溪地层)因不断退缩而形成滩涂和受限平台。在晚寒武世,四川盆地又位于碳酸盐岩平台(西乡池地层)。四川盆地寒武系有三种沉积体系:碎屑岩沉积体系、碎屑岩-碳酸盐混合沉积体系和碳酸盐沉积体系。纵向上,盆地呈现碎屑岩-碳酸盐岩沉积体系的演化特征。这三种沉积体系与寒武纪的三个 "过渡-回归 "周期相对应。早寒武纪初期的横断形成了下寒武统琼珠寺组的碎屑沉积系统。早寒武世后期的横断形成了中下寒武统的碎屑岩-碳酸盐混合沉积体系。晚寒武世初期的横断,形成了上寒武世西乡池组的碳酸盐沉积体系。随着晚新元大陆裂陷的结束,四川盆地进入稳定的克拉通盆地演化阶段,北部和西南部古陆发育。在琼珠寺-沧浪铺时期,盆地自西向东发育陆相沉积面;在龙王庙-西乡池时期,盆地自西向东发育潮汐平台-斜坡沉积面。
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引用次数: 0
Iso-propyl caprylate and iso-propyl linolenate synthetic fluids as novel alternatives in deep-water drilling operations: Critical fluid properties and aerobic biodegradability assessments 辛酸异丙酯和亚麻酸异丙酯合成液作为深水钻井作业中的新型替代品:关键流体特性和好氧生物降解性评估
Q2 ENERGY & FUELS Pub Date : 2024-06-01 DOI: 10.1016/j.petlm.2023.06.007
Adewale Johnson Folayan , Adewale Dosunmu , Aleruchi Boniface Oriji
<div><p>Present drilling fluids for deep water wells have severe degenerative effect on the environment with high operational and disposal costs. Thus, making them less desirable in recent times. Ester synthetic drilling fluid provides a novel environmentally friendly alternative but conventional ester-based drilling fluids exhibit high viscosities in deep-water wells causing excessive equivalent circulating density (ECD) and increased risk of lost circulation owing to narrow mud density window. This study experimentally investigates the critical fluid properties and aerobic biodegradability potentials of two newly developed deep-water synthetic ester drilling fluids namely: iso-propyl caprylate (COIPE) and iso-propyl linolenate (LOIPE) synthetic fluids and their comparison with synthetic-paraffin (SP-SBF) and isomerized-olefin (IO-SBF) synthetic hydrocarbon fluids. The esters of iso-propyl caprylate and iso-propyl linolenate were produced from the isolation of ester mixtures that were obtained from the homogeneous catalytic transesterification of coconut and linseed plant oil biomass respectively. The COIPE was isolated from the coconut oil iso-propyl ester mixture by low-pressure fractional distillation technique. While fractional distillation and crystallization were used to isolate the LOIPE ester from the linseed oil iso-propyl ester mixture. Meanwhile, the aerobic biodegradation investigation was conducted by a modified oxygen consumption respirometry technique. The GC-MS analysis of the COIPE and LOIPE showed that the former contains essentially of lower saturated carbon compounds (C8). Whereas the latter contains higher molecular weight and unsaturated carbon compounds (C18<sup>+</sup>). The COIPE and LOIPE kinematic viscosity values are in good agreement with that of the reference synthetic hydrocarbon fluid samples (SP-SBF and IO-SBF). Although, the COIPE synthetic ester has lower viscosity value owing to the presence of shorter chain and saturated carbon atoms (C8 esters). Similarly, the linolenic oil iso-propyl ester has excellent cold flow characteristics for deep-water well drilling owing to lower values of cloud and pour points as a result of higher concentration of poly-unsaturated linolenic esters. The iso-propyl caprylate and the iso-propyl linolenate ester synthetic fluids are readily biodegradable in the sea water inoculum under aerobic condition. However, the iso-propyl caprylate is inherently biodegradable because its degradation level and that of the reference chemical sample were already above 60% during the 10-day window period. The SP-SBF and the IO-SBF synthetic fluids have lower aerobic biodegradation values because they contain little quantity of poly aromatic hydrocarbons as evident in their GC-MS profiles. Finally, esters and unsaturated synthetic-based fluid are more rapidly biodegradable than paraffinic synthetic fluids and the rate of biodegradation of organic compounds decreases as molecular weight increases</p>
目前用于深水井的钻井液对环境有严重的恶化作用,而且操作和处理成本高昂。因此,近来这些钻井液已不再受欢迎。酯类合成钻井液提供了一种新型的环境友好型替代品,但传统的酯类钻井液在深水井中表现出较高的粘度,导致当量循环密度(ECD)过高,并由于泥浆密度窗口较窄而增加了循环损失的风险。本研究通过实验研究了两种新开发的深水合成酯类钻井液(辛酸异丙酯(COIPE)和亚麻酸异丙酯(LOIPE))的关键流体特性和好氧生物降解潜力,并将其与合成石蜡(SP-SBF)和异构化烯烃(IO-SBF)合成碳氢化合物流体进行了比较。辛酸异丙酯和亚麻酸异丙酯是分别从椰子油和亚麻籽植物油生物质的均相催化酯交换反应中分离得到的酯类混合物中生产出来的。通过低压分馏技术从椰子油异丙酯混合物中分离出 COIPE。亚麻籽油异丙酯混合物中的 LOIPE 酯则是通过分馏和结晶分离出来的。同时,采用改良的耗氧量呼吸测定法进行了有氧生物降解研究。COIPE 和 LOIPE 的气相色谱-质谱分析表明,前者主要含有低饱和碳化合物(C8)。而后者含有较高分子量和不饱和碳化合物(C18+)。COIPE 和 LOIPE 的运动粘度值与参考合成碳氢化合物流体样本(SP-SBF 和 IO-SBF)的运动粘度值非常一致。不过,COIPE 合成酯的粘度值较低,这是因为它含有较短的碳链和饱和碳原子(C8 酯)。同样,亚麻油异丙酯由于含有较高浓度的多不饱和亚麻酸酯,因此浊点和倾点值较低,在深水井钻探中具有优异的冷流特性。在好氧条件下,辛酸异丙酯和亚麻酸异丙酯合成液在海水接种体中很容易生物降解。不过,辛酸异丙酯本身是可以生物降解的,因为在 10 天的窗口期内,其降解水平和参考化学样本的降解水平都已超过 60%。SP-SBF 和 IO-SBF 合成液体的有氧生物降解值较低,因为从它们的 GC-MS 图谱可以看出,它们含有少量的多芳烃。最后,与石蜡合成液体相比,酯类和不饱和合成液体的生物降解速度更快,而且有机化合物的生物降解速度随着分子量的增加而降低。
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引用次数: 0
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