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Novel thermochemical fracturing: A breakthrough in sustainable and efficient enhanced geothermal systems (EGS) 新型热化学压裂:可持续高效增强型地热系统(EGS)的突破
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/j.petlm.2025.07.004
Ahmed Al-Ghamdi , Amjed Hassan , Mohamed Mahmoud , Talal Al-Shafloot
Enhanced geothermal systems (EGS) are crucial for accessing earth's vast geothermal potential, particularly in low-permeability formations. However, conventional EGS stimulation via hydraulic fracturing often entails high operational costs, substantial water consumption, potential environmental impacts, and risks of induced seismicity. This study presents a novel thermochemical fracturing approach to enhance EGS performance and sustainability while addressing these limitations. The in-situ exothermic reaction of sodium nitrite (NaNO2) and ammonium chloride (NH4Cl) was applied to a 12-inch carbonate rock sample. A specialized core flooding apparatus enabled real-time evaluation of temperature profiles, permeability, and heat transfer enhancements. The thermochemical stimulation increased permeability by 109% (from 19.01 to 39.70 mD) and enhanced heat transfer by 530%. These improvements stem from an extensive micro-fracture network generated by high-pressure nitrogen gas pulses, contrasting with larger planar fractures from hydraulic fracturing. Notably, this was achieved with only a 3.3% increase in porosity, indicating preserved rock integrity. The exothermic reaction prevented core cooling during ambient-temperature stimulation fluid injection, avoiding thermal shock. The thermochemical stimulation primarily generates nitrogen gas (N2) and a brine solution as byproducts. The generated N2 offers the additional benefit of providing well lifting energy, simplifying flowback operations. The novel application of thermochemical stimulation in EGS represents a promising, eco-friendly, and operationally efficient alternative to conventional EGS stimulation techniques.
增强型地热系统(EGS)对于开发地球巨大的地热潜力至关重要,特别是在低渗透地层中。然而,通过水力压裂进行的常规EGS增产通常需要高昂的操作成本、大量的水消耗、潜在的环境影响以及诱发地震活动的风险。该研究提出了一种新的热化学压裂方法,以提高EGS的性能和可持续性,同时解决了这些限制。将亚硝酸钠(NaNO2)与氯化铵(NH4Cl)的原位放热反应应用于12英寸的碳酸盐岩样品。专门的岩心驱油设备能够实时评估温度分布、渗透率和传热增强。热化学增产使渗透率提高了109%(从19.01 mD提高到39.70 mD),传热提高了530%。这些改进源于高压氮气脉冲产生的广泛微裂缝网络,与水力压裂产生的较大平面裂缝形成对比。值得注意的是,孔隙度仅增加了3.3%,表明岩石完整性得到了保护。放热反应防止了注入常温增产液时岩心冷却,避免了热冲击。热化学增产主要产生氮气(N2)和盐水溶液作为副产物。生成的氮气还可以提供举升能量,简化反排作业。热化学增产在EGS中的新应用代表了传统EGS增产技术的一种有前途、环保、高效的替代方案。
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引用次数: 0
Investigation of natural surfactant for oil recovery potential 天然表面活性剂采油潜力的研究
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/j.petlm.2025.09.001
Aibike Tukhfatova , Azza Hashim Abbas , Sonny Irawan , Peyman Pourafshary
Advancing the use of natural surfactants in enhanced oil recovery is crucial for sustainable practices in the oil and gas industry. This research assesses the applicability of neem-derived natural surfactants in offshore fields, encompassing surfactant synthesis via saponification, characterization through FT-IR, SEM, and EDS, and measuring surface and interfacial tension across various conditions. Adsorption studies determined the surfactant's adsorption characteristics onto rock, and core flooding tests assessed its efficacy. Surface tension measurements in deionized water (DIW) and brine confirmed the surfactant's surface activity. As the concentration increased from 1 wt% to 6 wt%, the interfacial tension (IFT) significantly decreased from 22.5 mN/m to 7.9 mN/m, marking a 64.8% reduction. Additionally, surfactants formed micelles more efficiently in saline water, with the critical micelle concentration (CMC) dropping from 4.0 wt% in DIW to 0.9 wt%.Adsorption on limestone showed over 50% higher adsorption than sandstone, confirming stronger interactions and higher adsorption saturation. Core flooding experiments demonstrated the surfactant's effectiveness in oil and water-wet conditions. When injected into sandstone, the surfactant achieved a significant additional oil recovery of 24.6% in deionized water, compared to 10.2% in limestone. Conversely, in saline conditions, the surfactant's performance was better in limestone, achieving an additional recovery of 4.9%, whereas in sandstone, it was only 1.6%. This research offers a unique perspective on how natural surfactants perform across different rock types. The findings suggest that neem-derived surfactants hold significant promise for enhancing oil recovery in Kazakhstan's oil fields.
推进天然表面活性剂在提高采收率方面的应用,对于油气行业的可持续实践至关重要。本研究评估了neem衍生的天然表面活性剂在海上油田的适用性,包括通过皂化合成表面活性剂,通过FT-IR, SEM和EDS进行表征,以及在各种条件下测量表面和界面张力。吸附研究确定了表面活性剂在岩石上的吸附特性,岩心驱油试验评估了其效果。在去离子水(DIW)和盐水中的表面张力测量证实了表面活性剂的表面活性。当浓度从1 wt%增加到6 wt%时,界面张力(IFT)从22.5 mN/m显著降低到7.9 mN/m,降低了64.8%。此外,表面活性剂在盐水中更有效地形成胶束,临界胶束浓度(CMC)从DIW中的4.0%下降到0.9 wt%。在灰岩上的吸附比砂岩高50%以上,表明相互作用更强,吸附饱和度更高。岩心驱油实验证明了该表面活性剂在油和水湿条件下的有效性。当注入砂岩时,表面活性剂在去离子水中获得了24.6%的显著额外采收率,而在石灰岩中则为10.2%。相反,在盐水条件下,表面活性剂在石灰石中的表现更好,可实现4.9%的额外采收率,而在砂岩中仅为1.6%。这项研究为研究天然表面活性剂在不同岩石类型上的表现提供了一个独特的视角。研究结果表明,neem衍生的表面活性剂在提高哈萨克斯坦油田的采收率方面具有重要的前景。
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引用次数: 0
Numerical simulation study on reservoir damage caused by adsorption and capture retention in polymer injection 聚合物注入过程中吸附和捕获滞留对储层损害的数值模拟研究
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/j.petlm.2025.08.003
Xinsheng Xue , Xiang Chen , Chengxi Huang , Juan Du , Pingli Liu , Yuejun Zhu , Zhengyou Tang
Polymer flooding is a key technology for improving oil recovery in reservoirs with heavy to medium crude oil. However, the adsorption and retention of polymers in reservoir pores can cause reservoir damage. This study investigates the dynamic changes at the wellhead pressure and reservoir damage induced during polymer injection due to adsorption and retention. By integrating continuity equations, polymer flow equilibrium equations, and pore permeability damage equations, a mathematical model is proposed to calculate polymer damage. The model is discretely solved using the finite difference method, effectively simulating the reduction in reservoir porosity and permeability caused by polymer adsorption and retention, as well as the changes in wellhead pressure caused by permeability variations of reservoir and viscosity variations of polymer solutions. Numerical simulation under different injection conditions reveals that the viscosity of polymer solutions is primarily influenced by polymer concentration and Darcy velocity, showing a trend of initial increase followed by decrease radially. The extent of reservoir damage and the rate of increase in wellhead pressure of the injection well correlate positively with polymer concentration and injection volume, with significant reservoir damage concentrated within approximately 2 m around the wellbore. Considering interlayer heterogeneity, inflow is identified as the main factor causing uneven damage distribution. This research enriches the study of damage caused by injection wells and provides a new mathematical model for diagnosing such damage.
聚合物驱是稠油-中稠油油藏提高采收率的关键技术。然而,聚合物在储层孔隙中的吸附和滞留会对储层造成损害。研究了聚合物在注入过程中由于吸附和滞留引起的井口压力和储层损害的动态变化。通过对连续性方程、聚合物流动平衡方程和孔隙渗透率损伤方程的整合,建立了计算聚合物损伤的数学模型。采用有限差分法对模型进行离散求解,有效模拟了聚合物吸附和滞留引起的储层孔隙度和渗透率降低,以及储层渗透率变化和聚合物溶液粘度变化引起的井口压力变化。不同注入条件下的数值模拟表明,聚合物溶液的粘度主要受聚合物浓度和达西速度的影响,呈现先增大后减小的趋势。注水井的油藏损害程度和井口压力的增加速度与聚合物浓度和注入量呈正相关,显著的油藏损害集中在井筒周围约2 m范围内。考虑层间非均质性,认为流入是造成损伤分布不均匀的主要因素。该研究丰富了注水井损伤研究,为注水井损伤诊断提供了新的数学模型。
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引用次数: 0
Preparation of a supramolecular sand-inhibiting and water-control agent and study of its applicability to oil reservoirs 一种超分子防砂防水剂的制备及其油藏适用性研究
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/j.petlm.2025.09.003
Tianmeng Lei , Yefei Wang , Mingchen Ding , Wuhua Chen , Zhenye Yu , Zhixue Huang , Motorova Kseniya Alexandrovna
To solve the problem whereby an oil reservoir with applicable boundaries of the current sand-inhibiting and water-control agent is unclear, a supramolecular sand-inhibiting and water-control agent PDKM was prepared using acrylamide (AM), methacryloxyethyltrimethyl ammonium chloride (DMC), styrene (SM), and γ-methacryloyloxypropyltrimethoxysilane (KH570) as comonomers. The molecular structure of PDKM was verified by 1H-NMR and FT-IR. On the basis of establishing an evaluation method that can screen the performance of sand-inhibiting agent at a flow rate of 100 mL/min, the oil reservoir applicable boundaries of PDKM were obtained through the evaluation of sand-inhibiting and water-control performance. The experimental results show that when the concentration of PDKM is 5000 mg/L, the oil reservoir conditions are temperature ≤90 °C, formation water salinity ≤21,249 mg/L, the degree of sand production corresponding to slight sand production and particle migration, crude oil viscosity ≤50 mPa·s, primary water flooding water cut ≥75%, and formation permeability contrast ≤2. The performance with respect to sand inhibiting and water control can all reach an excellent level. Therefore, the PDKM solves the problem whereby the applicability of the current sand-inhibiting and water-control agent is unclear, and provides direction for the selection of suitable products in the oilfield production site.
为解决现有防砂防水剂适用范围不明确的油藏问题,以丙烯酰胺(AM)、甲基丙烯氧基乙基三甲基氯化铵(DMC)、苯乙烯(SM)、γ-甲基丙烯酰氧基丙基三甲氧基硅烷(KH570)为共聚单体,制备了超分子防砂防水剂PDKM。通过1H-NMR和FT-IR对PDKM的分子结构进行了验证。在建立了100 mL/min流速下可筛选防砂剂性能的评价方法的基础上,通过对PDKM防砂防水性能的评价,得出了PDKM的油藏适用边界。实验结果表明,当PDKM浓度为5000 mg/L时,油藏条件为温度≤90℃,地层水矿化度≤21249 mg/L,出砂程度对应轻微出砂和颗粒运移,原油粘度≤50 mPa·s,一次水驱含水率≥75%,地层渗透率对比≤2。防砂防水性能均达到优异水平。因此,PDKM解决了现有防砂防水剂适用性不明确的问题,为油田生产现场选择合适的产品提供了指导。
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引用次数: 0
Integrated selection and design method for PDC bits and positive displacement motor PDC钻头与容积马达的综合选型设计方法
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/j.petlm.2025.07.011
Zhaowei Wang, Xiangchao Shi, Ye Jiao, Shuai Chen, Rongrong Wang, Zonglin Lv
It has been found that the rock breaking tools combination of positive displacement motors (PDM) with different output parameters (positive rotational speed and positive torque) and polycrystalline diamond compact (PDC) bits with different design features exhibits significant differences in rock breaking efficiency and stability. This indicates that studying the compatibility between PDC bit and PDM before conducting drilling process is necessary. The Φ215.9 mm wellbore condition in Longmaxi formation was taken as an example, the positive rotational speed and positive torque exerted by Φ197mm PDM with different number of lobes and pitch length were calculated, PDC bit with different cutting strategies were designed. Then finite element method (FEM) models considering PDM output parameters were established to study rock breaking process. Required weight on bit (WOB), required mechanical specific energy (MSE), reaction torque on bit (TOB), and vibration characteristics at near-bit position under the designed rate of penetration (ROP) were obtained. Research results showed that: (1) The energy required for PDC bit with certain design features breaking shale is not a constant value, but a value changes with rotational speed and positive torque exerted by different PDM. (2) The ability controlling vibration of PDM tends to stabilize when the number of lobes N and pitch length h exceeds 5 and 140 mm respectively in general conditions, Thus combination design parameters when N = 5, h = 140 mm were suggested to balance rock breaking efficiency and service life of drill strings. (3) Compared with other cutting strategies, when rock breaking pattern consist of “face to face” interaction and “point to point” interaction, both rock breaking efficiency and stability were higher. While when matched with this cutting strategy, N = 8 and h = 140/200 mm were recommended for PDM design instead of N = 5 and h = 140 mm obtained in most cases, which cloud minimize the loss of rock breaking efficiency and improve the axial/circumferential stability by 14.24%–17.23% and 24.93%–35.73% respectively. An integrated selection and design method of PDC bit and PDM was established and implemented, which revealed the rock breaking efficiency and stability patterns of different rock breaking tools combinations, providing theoretical support and suggestions for the integrated selection and design of PDC bits and PDM in Longmaxi formation.
研究发现,不同输出参数(正转速和正扭矩)的正排量马达(PDM)与不同设计特征的聚晶金刚石钻头(PDC)组合的破岩工具在破岩效率和稳定性方面存在显著差异。这表明,在进行钻井作业之前,有必要研究PDC钻头与PDM的相容性。以龙马溪地层Φ215.9 mm井眼条件为例,计算了Φ197mm PDM不同叶数和节距长度下的正转速和正扭矩,设计了不同切削策略的PDC钻头。在此基础上,建立了考虑PDM输出参数的有限元模型,研究岩石破碎过程。获得了设计钻速(ROP)下所需钻压(WOB)、所需机械比能(MSE)、钻头反作用力(TOB)以及近钻头位置的振动特性。研究结果表明:(1)具有一定设计特征的PDC钻头破页岩所需能量不是一个恒定值,而是随着不同PDM施加的转速和正转矩的变化而变化。(2)一般情况下,当叶片数N大于5、节距长度h大于140 mm时,PDM控制振动的能力趋于稳定,因此建议采用N = 5、h = 140 mm时的组合设计参数来平衡破岩效率和钻柱使用寿命。(3)与其他切割策略相比,当破岩模式由“面对面”和“点对点”两种模式组成时,破岩效率和稳定性都更高。与此切割策略相匹配时,PDM设计建议采用N = 8和h = 140/200 mm,而不是大多数情况下的N = 5和h = 140 mm,这样可以最大限度地减少破岩效率的损失,并使轴向/周向稳定性分别提高14.24% ~ 17.23%和24.93% ~ 35.73%。建立并实施了PDC钻头与PDM的一体化选择设计方法,揭示了不同破岩工具组合的破岩效率和稳定性规律,为龙马溪地层PDC钻头与PDM的一体化选择设计提供了理论支持和建议。
{"title":"Integrated selection and design method for PDC bits and positive displacement motor","authors":"Zhaowei Wang,&nbsp;Xiangchao Shi,&nbsp;Ye Jiao,&nbsp;Shuai Chen,&nbsp;Rongrong Wang,&nbsp;Zonglin Lv","doi":"10.1016/j.petlm.2025.07.011","DOIUrl":"10.1016/j.petlm.2025.07.011","url":null,"abstract":"<div><div>It has been found that the rock breaking tools combination of positive displacement motors (PDM) with different output parameters (positive rotational speed and positive torque) and polycrystalline diamond compact (PDC) bits with different design features exhibits significant differences in rock breaking efficiency and stability. This indicates that studying the compatibility between PDC bit and PDM before conducting drilling process is necessary. The <em>Φ</em>215.9 mm wellbore condition in Longmaxi formation was taken as an example, the positive rotational speed and positive torque exerted by <em>Φ</em>197mm PDM with different number of lobes and pitch length were calculated, PDC bit with different cutting strategies were designed. Then finite element method (FEM) models considering PDM output parameters were established to study rock breaking process. Required weight on bit (WOB), required mechanical specific energy (MSE), reaction torque on bit (TOB), and vibration characteristics at near-bit position under the designed rate of penetration (ROP) were obtained. Research results showed that: (1) The energy required for PDC bit with certain design features breaking shale is not a constant value, but a value changes with rotational speed and positive torque exerted by different PDM. (2) The ability controlling vibration of PDM tends to stabilize when the number of lobes <em>N</em> and pitch length <em>h</em> exceeds 5 and 140 mm respectively in general conditions, Thus combination design parameters when <em>N</em> = 5, <em>h</em> = 140 mm were suggested to balance rock breaking efficiency and service life of drill strings. (3) Compared with other cutting strategies, when rock breaking pattern consist of “face to face” interaction and “point to point” interaction, both rock breaking efficiency and stability were higher. While when matched with this cutting strategy, <em>N</em> = 8 and <em>h</em> = 140/200 mm were recommended for PDM design instead of <em>N</em> = 5 and <em>h</em> = 140 mm obtained in most cases, which cloud minimize the loss of rock breaking efficiency and improve the axial/circumferential stability by 14.24%–17.23% and 24.93%–35.73% respectively. An integrated selection and design method of PDC bit and PDM was established and implemented, which revealed the rock breaking efficiency and stability patterns of different rock breaking tools combinations, providing theoretical support and suggestions for the integrated selection and design of PDC bits and PDM in Longmaxi formation.</div></div>","PeriodicalId":37433,"journal":{"name":"Petroleum","volume":"11 5","pages":"Pages 587-600"},"PeriodicalIF":3.5,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145435648","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Review of EOR-based techniques for enhancing sweep efficiency in carbon geo-storage 提高地质储碳波及效率的eor技术综述
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/j.petlm.2025.08.001
Muhammad Shehryar , Arshad Raza , Guenther Glatz , Muhammad Shahzad Kamal , Mohamed Mahmoud , Ahmad Mahboob , Saad Alafnan
Carbon dioxide (CO2) storage in geological reservoirs faces viscous fingering, gravity override, and poor mobility control due to its low viscosity and resulting inefficient distribution and compromised storage capacity. Therefore, an urgent need arises to thicken the CO2 and enhance its viscosity for better mobility control and uniform distribution across the reservoir. This study examines the different schemes to enhance sweep efficiency in subsurface storage. In the context of polymer-, surfactant-, and foam-based technologies, the study defines optimization for CO2 injection and retention. Sweep efficiency is critical in maximizing reservoir usage and minimizing the risk of leakage by ensuring even dispersion of CO2. Polymers could increase CO2 viscosity, thereby yielding better mobility control and wider reservoir coverage. Surfactants reduce interfacial tension, enabling CO2 to invade less permeable areas, while foams act as conformance control agents, changing the flow path of CO2 away from the high permeability and into the underused areas. The study further includes advanced materials like CO2-soluble polymers, fluorinated surfactants, and nanoparticle-stabilized foams with superior stability under high-pressure, high-temperature conditions typical of deep reservoirs. Though effective, these approaches are challenged with chemical degradation, economic feasibility and environmental consequences. The study delves into these limitations and suggests integrated approaches involving polymers, and surfactant foams for enhanced sweep efficiency. These findings are a step towards realizing surfactant efficient and sustainable carbon sequestration technologies and contribute to the efforts of the world to mitigate climate change.
地质储层中的二氧化碳(CO2)由于其低粘度而面临粘指、重力覆盖和流动性控制差的问题,从而导致分布效率低下和存储容量受损。因此,迫切需要增稠CO2并提高其粘度,以更好地控制流动性和均匀分布在整个油藏中。本研究探讨了不同的方案,以提高地下储存的扫描效率。在聚合物、表面活性剂和泡沫技术的背景下,该研究定义了二氧化碳注入和保留的优化。扫描效率对于最大限度地提高储层利用率和通过确保二氧化碳均匀分散来最小化泄漏风险至关重要。聚合物可以增加二氧化碳粘度,从而获得更好的流动性控制和更大的储层覆盖范围。表面活性剂降低了界面张力,使CO2能够侵入渗透性较低的区域,而泡沫作为一致性控制剂,改变CO2从高渗透性区域的流动路径,进入未充分利用的区域。该研究进一步采用了二氧化碳可溶性聚合物、氟化表面活性剂和纳米颗粒稳定泡沫等先进材料,这些材料在深部油藏典型的高压、高温条件下具有优异的稳定性。这些方法虽然有效,但面临着化学降解、经济可行性和环境后果的挑战。该研究深入研究了这些局限性,并提出了包括聚合物和表面活性剂泡沫在内的综合方法,以提高扫描效率。这些发现是实现表面活性剂高效和可持续碳封存技术的一步,有助于世界减缓气候变化的努力。
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引用次数: 0
Research progress of thickener for supercritical carbon dioxide fracturing fluid 超临界二氧化碳压裂液增稠剂的研究进展
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/j.petlm.2025.08.002
Wanfen Pu , Jintao Li , Daijun Du , Jinzhou Zhao , Tong Wu , Ying Xiong , Pengfei Chen , Rui Jiang
Compared to traditional water-based fracturing fluids, which often result in reservoir fracturing damages, water consumption, and incomplete flowback, supercritical carbon dioxide (scCO2) fracturing technology has gained attention from scholars as a promising anhydrous fracturing technique. This is primarily due to its unique properties such as being waterless, causing no reservoir damages, providing an excellent energy-enhancing effect, and enabling thorough backflow. In addition to improving the recovery efficiency through CO2 injection during fracturing, scCO2 fracturing technology also enables CO2 geological storage. However, the low viscosity of pure CO2 as a fracturing fluid significantly limits its productivity enhancement effect. Therefore, the identification of a suitable thickener is necessary to increase the viscosity of supercritical CO2 fracturing fluids, consequently enhancing their reservoir reconstruction efficiency. This paper explores and discusses four types of supercritical CO2 thickeners, namely siloxane polymers, hydrocarbon and oxygenated hydrocarbon polymers, surfactants, and fluoropolymers, through comprehensive research conducted domestically and internationally. The solubility, thickening ability, experimental conditions, and challenges associated with scCO2 thickeners are analyzed and evaluated. Finally, the characteristics of each type of thickener are summarized, and future research directions are proposed.
与传统水基压裂液容易造成储层压裂损伤、耗水量大、返排不完全等问题相比,超临界二氧化碳(scCO2)压裂技术作为一种很有发展前景的无水压裂技术受到了学者们的关注。这主要是由于其独特的特性,如无水,不会对储层造成损害,提供出色的能量增强效果,并实现彻底的回流。scCO2压裂技术除了通过压裂过程中注入二氧化碳提高采收率外,还实现了二氧化碳的地质封存。然而,纯二氧化碳作为压裂液的低粘度严重限制了其增产效果。因此,为了提高超临界CO2压裂液的粘度,提高其储层改造效率,有必要选择合适的增稠剂。本文通过国内外综合研究,对硅氧烷聚合物、碳氢化合物及含氧碳氢化合物聚合物、表面活性剂、含氟聚合物四类超临界CO2增稠剂进行了探索和探讨。对scCO2增稠剂的溶解度、增稠能力、实验条件和挑战进行了分析和评价。最后总结了各类增稠剂的特点,并提出了今后的研究方向。
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引用次数: 0
Recent progress of using carbon fiber in reinforcing cement-based composite and their enlightenment for oil-well cement future 碳纤维增强水泥基复合材料的研究进展及其对油井水泥发展的启示
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/j.petlm.2025.09.002
Zehua Chen , Wenjian Yue , Chengwen Wang
The incorporation of fibers represents a crucial technique for improving the mechanical properties and other relevant characteristics of cement-based composites (CBC), including concrete, cement mortar, and oil-well cement. Especially, carbon fiber (CF) has a great potential for reinforcing oil-well cement due to its high strength, modulus, stiffness, high temperature, corrosion and fatigue resistance as well as chemical stability. There is a huge amount of waste CFs all over the world which show better performance in cement industry, while their reuse will realize waste recovery (good environment impact) and greatly reduce cost. This review paper presents the recent progress of using CF in enhancing mechanical properties of CBC. We put high emphasis on the CF surface modification for reinforcing bond strength at the cement/CF interface. Comprehensive discussion with respect to effects of CF and modified CF on CBC properties is performed. The key properties of CBC examined in this study encompass mechanical characteristics (compressive strength, flexural strength, and tensile strength), dimensional stability (shrinkage behavior), durability indicators (water absorption and permeability), and fracture-related properties (toughness, crack resistance, and impact performance). Thus, suggestions are given for the future study and application of CF in oil-well cement.
纤维的掺入是改善水泥基复合材料(CBC)的机械性能和其他相关特性的关键技术,包括混凝土、水泥砂浆和油井水泥。特别是碳纤维(CF),由于其高强度、高模量、高刚度、耐高温、耐腐蚀、耐疲劳以及化学稳定性,在油井水泥加固方面具有很大的潜力。世界上有大量的废碳纤维,在水泥工业中表现出较好的性能,而它们的再利用将实现废物回收(良好的环境影响)并大大降低成本。本文综述了近年来利用CF增强CBC力学性能的研究进展。我们重点研究了CF表面改性,以增强水泥/CF界面的粘结强度。全面讨论了CF和改性CF对CBC性能的影响。本研究检测的CBC的关键性能包括机械特性(抗压强度、抗折强度和抗拉强度)、尺寸稳定性(收缩行为)、耐久性指标(吸水率和透气性)以及断裂相关性能(韧性、抗裂性和冲击性能)。最后,对CF在油井水泥中的进一步研究和应用提出了建议。
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引用次数: 0
Enhancing P(AM-co-AA) hydrogel performance: Dual crosslinking effects on structural strength, thermal stability, swelling capacity, and rheological behavior for effective sand production control in oil reservoirs 增强P(AM-co-AA)水凝胶性能:双交联效应可提高结构强度、热稳定性、膨胀能力和流变特性,有效控制油藏出砂
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/j.petlm.2025.07.010
Fardin Saghandali , Mahsa Baghban Salehi , Farzin Saghandali , Vahid Taghikhani
The efficiency of mechanical methods in controlling water production and fine migration in reservoirs has been limited, prompting researchers to focus on developing more resilient chemical methods. However, the challenge lies in the limited resistance and stability of these chemical methods in harsh reservoir conditions. To address this challenge, a study evaluated a dual crosslinker polyethyleneimine compound as a double crosslink in hydrogel composite structures. Using FTIR techniques, the study examined the structure of hydrogel compounds with single and double crosslinkers. Microscopic imaging, including SEM and ESEM analyses, provided insights into sample morphology. Equilibrium swelling and rheological tests assessed the hydrogels' three-dimensional structure and solvent retention capacity, while TGA determined sample stability. The study confirmed chemical bond formation between double crosslinkers via FTIR analysis. SEM and ESEM images displayed a porous, homogeneous, three-dimensional structure. The increase in pore size in the swollen state without tearing highlighted the hydrogel's elastic and self-healing properties. TGA revealed reduced weight loss with double crosslinking at 120 °C. Strain sweep and frequency sweep tests demonstrated enhancements in critical strain and frequency with the dual crosslinker, supporting the sample's viscoelastic behavior. The hydrogel with a single crosslink maintained linear viscoelastic behavior up to 85 °C, while the dual crosslinked sample retained it up to 200 °C, suitable for high-temperature conditions. Swelling tests confirmed the sample's ability to absorb 2000% of water under reservoir conditions. Sandpack compressive strength testing indicated a fivefold increase in strength with the dual crosslinked hydrogel composite, effectively preventing fine migration.
机械方法在控制油藏产水和精细运移方面的效率有限,这促使研究人员将重点放在开发更具弹性的化学方法上。然而,挑战在于这些化学方法在恶劣储层条件下的抗性和稳定性有限。为了解决这一挑战,一项研究评估了双交联剂聚乙烯亚胺化合物作为水凝胶复合结构中的双交联剂。利用红外光谱技术,研究了具有单交联剂和双交联剂的水凝胶化合物的结构。显微成像,包括SEM和ESEM分析,提供了对样品形态的见解。平衡膨胀和流变测试评估了水凝胶的三维结构和溶剂保留能力,而TGA测试了样品的稳定性。研究通过红外光谱分析证实了双交联剂之间的化学键形成。SEM和ESEM图像显示多孔,均匀,三维结构。在没有撕裂的肿胀状态下,孔隙大小的增加突出了水凝胶的弹性和自愈特性。热重分析显示,在120°C时,双交联减少了重量损失。应变扫描和频率扫描测试表明,双交联剂增强了临界应变和频率,支持了样品的粘弹性行为。单交联的水凝胶在85°C下保持线性粘弹性,而双交联的水凝胶在200°C下保持线性粘弹性,适用于高温条件。膨胀测试证实,在储层条件下,样品能够吸收2000%的水。砂堆抗压强度测试表明,双交联水凝胶复合材料的强度提高了5倍,有效地防止了细颗粒的运移。
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引用次数: 0
Experimental study on the influence of heavy mud loss during workover on re-fracturing of high-pressure gas wells 修井时严重漏泥对高压气井再压裂影响的实验研究
IF 3.5 Q2 ENERGY & FUELS Pub Date : 2025-10-01 DOI: 10.1016/j.petlm.2025.07.002
Yuxuan Liu , Minghao Jiang , Jianchun Guo , Xinggui Yang , Jiamin Wu , Liansong Wu , Xiaopeng Chen , Zhiming Wen , Chuanyun Zhou
During workover operations in high-pressure gas wells, heavy mud losses may occur, reducing gas production. Refracturing is an effective means to restore production. The influence of heavy mud loss on refracturing is still unclear. In this paper, split core is designed to simulate the fractures of the initial transformation, transparent sand-filled pipe is designed to simulate the sand filled fractures, and the experiment of heavy mud leakage in artificial fractures under different conditions is carried out by using the displacement device, combined with CT scanning and pressure monitoring means. The influence of heavy mud loss on permeability of artificial fracture, repeated reconstruction construction pressure and flow channel configuration in artificial fracture is analyzed. The results show that workover heavy mud (WHM) loss has the greatest permeability damage to the proppant fracture packed with large particle size, up to 97%, and the fracture permeability damage of 40/70 mesh ceramsite packing is only 0.3%–0.7%. Slit core permeability damage is the least, and the decrease range is 10%–20%. The damage of matrix core permeability measured by gas is no less than 60%. Before and after the loss of WHM, the injection pressure increases significantly, up to 80 times. Combined with the CT scan results, it is found that after WHM loss, the nitrogen blowout and refracturing incompletely remove the pollution, and there is a “pollution cage” in the fracture, which is the main reason for the high construction pressure of refracturing and low production after refracturing. The research results provide theoretical basics for the refracturing of WHM loss wells.
在高压气井的修井作业中,可能会发生严重的泥浆漏失,从而降低产气量。重复压裂是恢复生产的有效手段。大量泥浆漏失对重复压裂的影响尚不清楚。本文采用裂心模拟裂缝初始变形,采用透明充砂管模拟充砂裂缝,采用驱替装置,结合CT扫描和压力监测手段,进行了不同条件下人工裂缝重泥浆泄漏实验。分析了大量泥浆漏失对人工裂缝渗透率、重复改造施工压力和人工裂缝内流道形态的影响。结果表明,修井重泥浆(WHM)漏失对大粒径支撑剂充填裂缝的渗透率损害最大,可达97%,而40/70目陶粒充填裂缝的渗透率损害仅为0.3% ~ 0.7%。裂隙岩心渗透率损害最小,降低幅度为10% ~ 20%。气体测量对基质岩心渗透率的破坏不小于60%。失WHM前后,注入压力显著升高,最高可达80倍。结合CT扫描结果发现,在WHM损失后,喷氮和重复压裂不能完全去除污染,裂缝中存在“污染笼”,这是重复压裂施工压力高、重复压裂后产量低的主要原因。研究结果为高含水率漏失井的重复压裂提供了理论依据。
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引用次数: 0
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Petroleum
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