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Calculating densities and viscosities of natural gas with a high content of C2+ to predict two-phase liquid-gas flow pattern 计算高 C2+ 含量天然气的密度和粘度,预测液气两相流动模式
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2023.01.001
Yekaterina Moisseyeva, Alexandra Saitova, Sergey Strokin

The paper is devoted to the two-phase flow simulation. The gas-condensate mixture flow in a horizontal pipe under high pressure is considered. The influence of the equation of state (EOS) choice for mixture properties modelling on the flow regime calculation results is studied for gas with high content of methane homologues. An analytical overview of the methods to predict the flow pattern is provided. Based on this analysis, two techniques are selected. For these techniques, values of density and viscosity for each phase are required. Density calculation for the gas phase is performed with Van der Waals based EOS. The propriate EOS is selected based on studies of calculation errors for test mixtures. Calculation of liquid phase density is done by means of Patela-Teja and Guo-Du equations, two different models are considered for viscosity estimation. The flow patterns of gas-condensate mixture in a range of temperatures and pressures are calculated and verified via probability map. The results of study allow to recommend the Brusilovsky EOS for calculation of densities for similar gas mixtures and make more rigorous flow regime evaluation. The probability map shows that for the chosen composition and parameters of media the flow pattern is mostly transitional between segregated and annular independent from EOS.

本文致力于两相流模拟。考虑了高压下水平管道中的气体-冷凝物混合物流动。针对甲烷同系物含量较高的气体,研究了混合物特性建模的状态方程(EOS)选择对流态计算结果的影响。分析概述了预测流动模式的方法。在此分析基础上,选择了两种技术。这两种技术都需要各相的密度和粘度值。气相的密度计算采用基于范德华的 EOS。根据对测试混合物计算误差的研究,选择合适的 EOS。液相密度计算采用 Patela-Teja 和 Guo-Du 方程,粘度估算采用两种不同的模型。在一定的温度和压力范围内,通过概率图计算并验证了气体-冷凝物混合物的流动模式。根据研究结果,推荐使用布鲁西洛夫斯基 EOS 计算类似气体混合物的密度,并进行更严格的流态评估。概率图显示,在所选介质成分和参数条件下,流动模式大多是介于分离和环形之间的过渡模式,与 EOS 无关。
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引用次数: 0
Development and application of guar gum crosslinked gel with adjustable gelation time for total loss treatment 开发和应用可调节凝胶时间的瓜尔胶交联凝胶,用于全损治疗
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2022.09.003
Zhengqiang Xiong , Fan Fu , Zhifei Zou , Xiaodong Li , Shixian Tao , Yanning Li

To remediate the problem of severe or total losses, and meet the requirements of borehole plugging and pumping at different well depths, a novel crosslinked polymer gel (named HPG/Zr gel) with controlled gelation time and high gel strength was developed as loss circulation material, which mainly comprised hydroxypropyl guar gum, zirconium compound and triethanolamine. The influence of hydroxypropyl guar gum concentration, zirconium compound concentration, triethanolamine concentration and temperature on the gelation time of HPG/Zr gel was evaluated. In addition, the performance of HPG/Zr gel was investigated in terms of temperature resistance and shear resistance property, plugging ability and supporting cement slurry ability. According to the results, HPG/Zr gel can form a viscoelastic body with a network structure, and its gelation time can be practically adjustable. The results of the plugging experiment at different temperatures, pressures and pore sizes of quartz sand revealed that HPG/Zr gel could effectively plug sand pores at 150°C, and its pressure-bearing capacity can be up to 5 MPa. Employing its flow resistance and ability of supporting cement slurry, HPG/Zr gel was successfully applied in two geological boreholes by combining with cement slurry. Overall, the results of laboratory research and field tests indicate that HPG/Zr gel is useful for mitigating the lost circulation, and it is of huge importance to engineering applications.

为了解决严重亏损或全损问题,满足不同井深的井眼封堵和抽水要求,开发了一种新型交联聚合物凝胶(名为 HPG/Zr 凝胶)作为亏损循环材料,该凝胶主要由羟丙基瓜尔胶、锆化合物和三乙醇胺组成,具有凝胶时间可控、凝胶强度高等特点。评估了羟丙基瓜尔胶浓度、锆化合物浓度、三乙醇胺浓度和温度对 HPG/Zr 凝胶凝胶化时间的影响。此外,还考察了 HPG/Zr 凝胶的耐温性、抗剪性、堵塞能力和水泥浆支撑能力。结果表明,HPG/Zr 凝胶可形成具有网络结构的粘弹性体,其凝胶时间实际上是可调的。不同温度、压力和孔径的石英砂堵塞实验结果表明,HPG/Zr 凝胶能在 150°C 温度下有效堵塞砂孔隙,其承压能力可达 5 MPa。利用 HPG/Zr 凝胶的流动阻力和支撑水泥浆的能力,将其与水泥浆结合,成功应用于两个地质钻孔。总之,实验室研究和现场试验结果表明,HPG/Zr 凝胶可用于缓解循环损失,在工程应用中具有重要意义。
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引用次数: 2
Mechanical behavior of salt rocks: A geomechanical model 盐岩的力学行为:地质力学模型
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2022.09.002
Saeed Shad , Negar Razaghi , Davood Zivar , Soheil Mellat

The geomechanical behavior of salt rocks is a significant concern during drilling and development operations in some hydrocarbon reservoirs and underground gas storage sites. In this study, the static and dynamic salt rock geomechanical properties from a field in southwest Iran were evaluated using experiments such as waves' velocities, and thermo-mechanical coupled uniaxial and triaxial compression tests. As a result and by considering both the petrophysical well logs and laboratory data of the waves’ velocities, it is observed that the elastic properties of the core samples are concentrated within a narrow range unless an abnormality causes scatter. The results of uniaxial compression tests showed that rock strength decreases with increasing temperature linearly. In addition, the reduction of rock strength was observed with increasing porosity of the core samples as expected. In the case of triaxial compression tests, applying confining pressure on the core sample caused an increment in rock strength, while temperature decreased rock strength. The temperature also increased cohesion and decreases friction angle. The ratio of changes in stress to strain was used to investigate the dynamic changes in the geomechanical state. The maximum 0.25 damage factor was observed for the core samples for different definitions of the damage factor. Finally, we propose a novel analytical model to predict the stress-strain behavior of salt rocks at different conditions. The model was validated using experimental results and indicated a satisfactory accuracy.

在一些油气藏和地下储气库的钻探和开发作业中,盐岩的地质力学行为是一个重要问题。在这项研究中,利用波速、热机械耦合单轴和三轴压缩试验等实验,对伊朗西南部一个油田的静态和动态盐岩地质力学特性进行了评估。结果显示,通过同时考虑岩石学测井记录和实验室波速数据,可以发现岩心样本的弹性特性集中在一个较窄的范围内,除非异常现象导致分散。单轴压缩试验结果表明,岩石强度随温度升高呈线性下降。此外,随着岩芯样本孔隙率的增加,岩石强度也会随之降低。在三轴压缩试验中,对岩心样本施加约束压力会增加岩石强度,而温度则会降低岩石强度。温度还增加了内聚力,减小了摩擦角。应力与应变的变化比被用来研究地质力学状态的动态变化。在不同的破坏因子定义下,岩心样本的最大破坏因子为 0.25。最后,我们提出了一个新的分析模型来预测盐岩在不同条件下的应力-应变行为。该模型利用实验结果进行了验证,结果表明其准确性令人满意。
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引用次数: 2
Evaluation on the anisotropic brittleness index of shale rock using geophysical logging 利用地球物理测井评价页岩的各向异性脆性指数
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2022.06.001
Junchuan Gui , Jianchun Guo , Yu Sang , Yaxi Chen , Tianshou Ma , P.G. Ranjith

The brittleness index plays a significant role in the hydraulic fracturing design and wellbore stability analysis of shale reservoirs. Various brittleness indices have been proposed to characterize the brittleness of shale rocks, but almost all of them ignored the anisotropy of the brittleness index. Therefore, uniaxial compression testing integrated with geophysical logging was used to provide insights into the anisotropy of the brittleness index for Longmaxi shale, the presented method was utilized to assess brittleness index of Longmaxi shale formation for the interval of 3155–3175 m in CW-1 well. The results indicated that the brittleness index of Longmaxi shale showed a distinct anisotropy, and it achieved the minimum value at β = 45°-60°. As the bedding angle increased, the observed brittleness index (BI2_β) decreased firstly and increased then, it achieved the lowest value at β = 40°–60°, and it is consistent with the uniaxial compression testing results. Compared to the isotropic brittleness index (β = 0°), the deviation of the anisotropic brittleness index ranged from 10% to 66.7%, in other words, the anisotropy of brittleness index cannot be ignored for Longmaxi shale. Organic matter content is one of the main intrinsic causes of shale anisotropy, and the anisotropy degree of the brittleness index generally increases with the increase in organic matter content. The present work is valuable for the assessment of anisotropic brittleness for hydraulic fracturing design and wellbore stability analysis.

脆性指数在页岩储层的水力压裂设计和井筒稳定性分析中发挥着重要作用。人们提出了各种脆性指数来表征页岩的脆性,但几乎所有的脆性指数都忽略了脆性指数的各向异性。因此,采用单轴压缩试验与地球物理测井相结合的方法来揭示龙马溪页岩脆性指数的各向异性。结果表明,龙马溪页岩的脆性指数呈明显的各向异性,在β=45°-60°时达到最小值。随着铺层角的增大,观测到的脆性指数(BI2_β)先减小后增大,在β=40°-60°时达到最低值,这与单轴压缩试验结果一致。与各向同性脆性指数(β = 0°)相比,各向异性脆性指数的偏差在 10% 到 66.7% 之间,也就是说,龙马溪页岩的脆性指数各向异性不容忽视。有机质含量是造成页岩各向异性的主要内在原因之一,脆性指数的各向异性程度一般随有机质含量的增加而增加。本研究对水力压裂设计和井筒稳定性分析中各向异性脆性的评估具有重要价值。
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引用次数: 8
In-service performance of emergency shutdown valves and dependent operational relationships in the offshore oil and gas industry 近海石油和天然气工业中紧急关闭阀的在役性能及相关运行关系
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2023.06.004
Keith Cameron , Andrew Lewis , Diogo Montalvão , Mohammad Reza Herfatmanesh

Industrial process plants use emergency shutdown valves (ESDVs) as safety barriers to protect against hazardous events, bringing the plant to a safe state when potential danger is detected. These ESDVs are used extensively in offshore oil and gas processing plants and have been mandated in the design of such systems from national and international standards and legislation. This paper has used actual ESDV operating data from four mid/late life oil and gas production platforms in the North Sea to research operational relationships that are of interest to those responsible for the technical management and operation of ESDVs. The first of the two relationships is between the closure time (CT) of the ESDV and the time it remains in the open position, prior to the close command. It has been hypothesised that the CT of the ESDV is affected by the length of time that it has been open prior to being closed (Time since the last stroke). In addition to the general analysis of the data series, two sub-categories were created to further investigate this possible relationship for CT and these are “above mean” and “below mean”. The correlations (Pearson's based) resulting from this analysis are in the “weak” and “very weak” categories. The second relationship investigated was the effect of very frequent closures to assess if this improves the CT. ESDV operational records for six subjects were analysed to find closures that occurred within a 24 h period of each other. However, no discriminating trend was apparent where CT was impacted positively or negatively by the frequent closure group. It was concluded that the variance of ESDV closure time cannot be influenced by the technical management of the ESDV in terms of scheduling the operation of the ESDV.

工业加工厂使用紧急停机阀(ESDV)作为安全屏障,以防止危险事件的发生,在检测到潜在危险时使工厂进入安全状态。这些 ESDV 在近海石油和天然气加工厂得到广泛应用,国家和国际标准及立法也对此类系统的设计做出了规定。本文利用北海四个中/晚期油气生产平台的实际 ESDV 运行数据,研究了负责 ESDV 技术管理和运行的人员所关心的运行关系。这两种关系中的第一种是ESDV的关闭时间(CT)与关闭指令发出前ESDV保持在打开位置的时间之间的关系。据推测,ESDV 的 CT 会受到其在关闭之前的开启时间(自上次冲程起的时间)的影响。除了对数据序列进行总体分析外,还创建了两个子类别来进一步研究 CT 的这种可能关系,即 "高于平均值 "和 "低于平均值"。该分析得出的相关性(基于皮尔逊)分为 "弱 "和 "极弱 "两类。调查的第二种关系是频繁关闭的影响,以评估这是否会改善 CT。我们分析了六个受试者的 ESDV 运行记录,以找出 24 小时内相继发生的关闭情况。然而,在频繁关闭组对 CT 产生积极或消极影响方面,没有明显的区分趋势。结论是,ESDV 关闭时间的差异不会受到 ESDV 运行安排方面的技术管理的影响。
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引用次数: 0
Shale gas potential of the lower Silurian hot shales in southern Iran and the Arabian Plate: Characterization of organic geochemistry 伊朗南部和阿拉伯板块下志留纪热页岩的页岩气潜力:有机地球化学特征
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2022.03.004
Ali Rahmani , Mahsa Naderi , Ehsan Hosseiny

A significant phase of global warming appeared during the Llandovery and productive Silurian hot shale was preserved all over the world. The lower Silurian shale is the main effective source rock for most of the Paleozoic hydrocarbon in Iran and the Arabian platform. Silurian hot shales have become prospective resources for new energy such as shale gas. The regional distribution and shale gas potential of the lower Silurian hot shale in southern Iran and the Arabian plate are determined using outcrops and exploration well samples data from previous studies. The studied area has a high organic content (on average more than 2%), maximum burial depth is 5300 m, shale thickness of 30–200 m, organic matter maturities (most comparable), clay minerals content ranging from 20% to 57%, quartz content ranges from 20% to 49%, feldspar content ranges from 10% to 15% and calcite content ranges from 1.48% to 5% which all favor shale gas generation and accumulation. We concluded that southern Iran and east-central Saudi Arabia are two of the most sustainable and favorable locations for shale gas exploration and production for lower Silurian hot shale after assessing all of the key characteristics.

兰德发现期出现了一个重要的全球变暖阶段,世界各地都保存着富产的志留纪热页岩。下志留纪页岩是伊朗和阿拉伯地台大部分古生代碳氢化合物的主要有效来源岩。志留系热页岩已成为页岩气等新能源的潜在资源。利用以往研究的露头和勘探井样本数据,确定了伊朗南部和阿拉伯地台下志留纪热页岩的区域分布和页岩气潜力。研究区域的有机质含量较高(平均超过 2%),最大埋藏深度为 5300 米,页岩厚度为 30-200 米,有机质成熟度(大部分可比),粘土矿物含量为 20% 至 57%,石英含量为 20% 至 49%,长石含量为 10% 至 15%,方解石含量为 1.48% 至 5%,这些都有利于页岩气的生成和积累。在对所有关键特征进行评估后,我们得出结论,伊朗南部和沙特阿拉伯中东部是下志留纪热页岩页岩气勘探和生产最可持续和最有利的两个地点。
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引用次数: 5
Lessons learned from coreflood experiments with surfactant-polymer and alkali-surfactant-polymer for enhanced oil recovery 使用表面活性剂-聚合物和碱-表面活性剂-聚合物进行岩心注水试验以提高石油采收率的经验教训
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2022.07.002
Ivan Kurnia , Muhammad Fatchurrozi , Riyaz Ghulam Anwary , Guoyin Zhang

A review of coreflood experiments for chemically enhanced oil recovery (EOR) is presented in this paper, particularly surfactant-polymer (SP) and alkali-surfactant-polymer (ASP) processes. The objective of this review is to gain a general outlook and insight from coreflood experiments injecting SP or ASP slug as tertiary recovery. The discussion is separated into sections based on relevant core and fluid properties as well as surfactant selection and SP/ASP slug design and their impact on incremental recovery. Most studies in this review have been published within the last twenty years but few older coreflood works have been included for benchmarking. Parameters in each reviewed study have been summarized in tables to help readers gain detailed observation. Lessons learned from these past experiments should help other chemical EOR practitioners or students of the field in benchmarking or improving the outcomes of their future SP/ASP experiments.

本文回顾了化学提高石油采收率(EOR)的岩心注水实验,特别是表面活性剂聚合物(SP)和碱-表面活性剂聚合物(ASP)工艺。本综述旨在从注入 SP 或 ASP 溶剂作为三次采油的岩心注水实验中获得总体展望和见解。讨论根据相关的岩心和流体特性、表面活性剂的选择和 SP/ASP 泥块的设计及其对增量采收率的影响分成几个部分。本综述中的大多数研究都是在过去二十年内发表的,但也包括了一些较早的岩心注水研究,以作为基准。每项综述研究中的参数都以表格形式进行了总结,以帮助读者获得详细的观察结果。从这些过去的实验中汲取的经验教训应有助于其他化学 EOR 从业人员或该领域的学生制定基准或改进其未来 SP/ASP 实验的结果。
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引用次数: 1
Systematic experimental study of the temperature dependence of viscosity and rheological behavior of water-based drilling fluids with nano-additives 含纳米添加剂的水基钻井液的粘度和流变行为随温度变化的系统实验研究
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2022.03.001
A.V. Minakov , M.I. Pryazhnikov , E.I. Mikhienkova , Y.O. Voronenkova

The paper presents the results of a systematic study of the influence of nano-additives of various concentrations, average sizes and composition on the temperature dependence of the viscosity and rheological behavior of water-based drilling fluids. Typical compositions of drilling fluids, such as water suspensions of various clay solutions and gammaxan-based polymer solutions, were considered. Hydrophilic nanoparticles of silicon and aluminum oxides were used as nano-additives at concentrations ranging from 0.25 to 3 wt%. The average nanoparticle size varied from 10 to 151 nm. The temperature of drilling fluids varied from 25°C to 80°C. It is shown that the addition of nanoparticles to drilling fluids leads to a significant change in their rheological properties depending on the temperature. It was found that with increasing temperature, the yield stress and consistency index of drilling fluids with nanoparticles increase, while the behavior index, on the contrary, decreases. This behavior depends on the size of the nanoparticles. As the particle size increases, their influence on the temperature dependence of the drilling fluids’ viscosity increases. In general, it is shown that the addition of nanoparticles makes the viscosity of drilling fluid more stable with regard to the temperature. This is an essential fact for practical application.

本文介绍了系统研究不同浓度、平均尺寸和成分的纳米添加剂对水基钻井液粘度和流变行为的温度依赖性影响的结果。研究考虑了钻井液的典型成分,如各种粘土溶液的水悬浮液和伽马仙聚合物溶液。硅和铝氧化物的亲水性纳米粒子被用作纳米添加剂,浓度范围为 0.25 至 3 wt%。纳米粒子的平均粒径在 10 到 151 纳米之间。钻井液的温度从 25°C 到 80°C 不等。结果表明,在钻井液中添加纳米粒子后,钻井液的流变特性会随着温度的变化而发生显著变化。研究发现,随着温度的升高,添加了纳米颗粒的钻井液的屈服应力和稠度指数会升高,而行为指数则会降低。这种行为取决于纳米颗粒的大小。随着颗粒尺寸的增加,它们对钻井液粘度的温度依赖性的影响也随之增加。总的来说,纳米颗粒的加入使钻井液的粘度随温度的变化更加稳定。这是实际应用中的一个基本事实。
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引用次数: 3
Enhanced heavy and extra heavy oil recovery: Current status and new trends 强化重油和特重油开采:现状和新趋势
IF 4.2 Q2 ENERGY & FUELS Pub Date : 2023-10-31 DOI: 10.1016/j.petlm.2023.10.001

Due to the increased demand for energy resources these days, especially due to the Russian-Ukrainian war, the focus of the major countries is turning strongly towards improving oil production, especially heavy and extra heavy oil, which represents 40% of the world oil reserve. Steam-based and thermal (EOR) procedures are promising techniques for recovering heavy oil reservoirs, but they suffer from a sequence of problems and complications that arise after long-term application. These complications comprise steam breakthrough, steam overlap, and steam/rock interactions. This research presents the currently applied techniques to maximize the productivity of heavy oil, such as steam injection, cyclic steam stimulation, in-situ combustion, and steam-assisted gravity drainage. Thermal technologies face numerous obstacles, as they are energy and water-intensive processes that are not environmentally friendly. The research also presents future trends in energy-saving and environmentally friendly techniques that enhance heavy oil recovery through vapor extraction (VAPEX) steam-solvent hybrid techniques, electromagnetic energy, sonication, and nanotechnology. The findings of this review reported that all the presented techniques focus on how to reduce the oil viscosity and in-situ upgrade the crude oil properties. In turn, these enhance both the productivity rate and oil recovery and minimize the production cost. This article can be considered a comprehensive review of thermal recovery methods in heavy and extra-heavy oil, in addition to screening criteria used for each method.

由于最近能源需求的增加,特别是俄乌战争的爆发,主要国家的关注点正强烈转向提高石油产量,尤其是占世界石油储量 40% 的重油和特重油。蒸汽法和热法(EOR)是采收重油储层的有前途的技术,但在长期应用后会出现一系列问题和并发症。这些复杂问题包括蒸汽突破、蒸汽重叠以及蒸汽/岩石相互作用。本研究介绍了目前用于最大限度提高重油生产率的技术,如蒸汽注入、循环蒸汽刺激、原地燃烧和蒸汽辅助重力泄油。热技术面临诸多障碍,因为它们是能源和水密集型工艺,对环境不友好。研究还介绍了通过蒸汽萃取(VAPEX)、蒸汽-溶剂混合技术、电磁能、超声和纳米技术提高重油采收率的节能环保技术的未来发展趋势。本综述的研究结果表明,所有介绍的技术都侧重于如何降低石油粘度和就地改善原油特性。反过来,这些技术既能提高生产率和石油采收率,又能最大限度地降低生产成本。本文可被视为对重油和特重油热采方法的全面综述,此外还介绍了每种方法所使用的筛选标准。
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引用次数: 0
Parameter sensitivity analysis of the axial stability for a marine flexible pipe 船用柔性管道轴向稳定性的参数敏感性分析
IF 4.2 Q2 ENERGY & FUELS Pub Date : 2023-10-06 DOI: 10.1016/j.petlm.2023.09.010

Marine unbonded flexible pipes serve as the most essential equipment in offshore oil and gas exploration and exploitation. Axial compressive loads during installation or in service in the complex marine environment usually lead to buckling failure. A flexible pipe is a composite structure with multiple functional layers, of which the tensile armor layer plays a key role with regard to the response of the pipe subjected to axial loads. In this paper, a simplified three-dimensional finite element model is developed, focusing on the tensile layer and replacing the carcass layer, pressure sheath layer, and pressure armor layer by a cylindrical rigid body to reduce computational expense. By using this model, the buckling failure modes of the tensile armor layer (in particular the birdcaging phenomenon) are analyzed. Several key parameters that affect the stability of the flexible pipe under axial compression and torsion are emphasized, and their effects on its axial and torsional stiffness are compared and discussed. The results show that both the lay angle of the steel wires and the interlayer friction coefficient have a significant influence on the axial and torsional stiffness of the pipe, whereas the damaged length of the outer sheath has virtually no effect.

海洋无粘结柔性管道是海上油气勘探和开采中最重要的设备。在复杂的海洋环境中,安装或使用过程中的轴向压缩载荷通常会导致弯曲失效。柔性管道是一种具有多个功能层的复合结构,其中拉伸铠装层对管道承受轴向载荷的响应起着关键作用。本文建立了一个简化的三维有限元模型,重点关注拉伸层,并用一个圆柱刚体取代了胴体层、压力护套层和压力铠装层,以减少计算费用。利用该模型,分析了拉伸铠装层的屈曲失效模式(尤其是鸟笼现象)。强调了影响柔性管道在轴向压缩和扭转下稳定性的几个关键参数,并比较和讨论了这些参数对其轴向和扭转刚度的影响。结果表明,钢丝的铺设角度和层间摩擦系数对管道的轴向和扭转刚度有显著影响,而外护套的损坏长度几乎没有影响。
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Petroleum
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