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High-pressure capacity expansion and water injection mechanism and indicator curve model for fractured-vuggy carbonate reservoirs 碳酸盐岩油藏高压扩容注水机理与指标曲线模型
IF 4.2 Q2 ENERGY & FUELS Pub Date : 2024-01-10 DOI: 10.1016/j.petlm.2024.01.001

Water injection for oil displacement is one of the most effective ways to develop fractured-vuggy carbonate reservoirs. With the increase in the number of rounds of water injection, the development effect gradually fails. The emergence of high-pressure capacity expansion and water injection technology allows increased production from old wells. Although high-pressure capacity expansion and water injection technology has been implemented in practice for nearly 10 years in fractured-vuggy reservoirs, its mechanism remains unclear, and the water injection curve is not apparent. In the past, evaluating its effect could only be done by measuring the injection-production volume. In this study, we analyze the mechanism of high-pressure capacity expansion and water injection. We propose a fluid exchange index for high-pressure capacity expansion and water injection and establish a discrete model suitable for high-pressure capacity expansion and water injection curves in fractured-vuggy reservoirs. We propose the following mechanisms: replenishing energy, increasing energy, replacing energy, and releasing energy. The above mechanisms can be identified by the high-pressure capacity expansion and water injection curve of the well HA6X in the Halahatang Oilfield in the Tarim Basin. By solving the basic model, the relative errors of Reservoirs I and II are found to be 1.9% and 1.5%, respectively, and the application of field examples demonstrates that our proposed high-pressure capacity expansion and water injection indicator curve is reasonable and reliable. This research can provide theoretical support for high-pressure capacity expansion and water injection technology in fracture-vuggy carbonate reservoirs.

注水驱油是开发断裂凹陷碳酸盐岩油藏最有效的方法之一。随着注水次数的增加,开发效果逐渐失效。高压扩容注水技术的出现使老井的产量得以提高。虽然高压扩容注水技术在裂缝-岩浆储层中实践了近 10 年,但其机理仍不清楚,注水曲线也不明显。过去,只能通过测量注采体积来评价其效果。在本研究中,我们分析了高压扩容和注水的机理。我们提出了高压扩容注水的流体交换指标,并建立了适合裂缝-岩浆储层高压扩容注水曲线的离散模型。我们提出了以下机制:补充能量、增加能量、置换能量和释放能量。塔里木盆地哈拉哈塘油田 HA6X 井的高压产能扩张和注水曲线可以确定上述机制。通过求解基本模型,发现储层Ⅰ和储层Ⅱ的相对误差分别为 1.9%和 1.5%,现场实例的应用证明了我们提出的高压扩容注水指标曲线是合理可靠的。该研究为碳酸盐岩油藏高压扩容注水技术提供了理论支持。
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引用次数: 0
An experimental study on optimizing parameters for sand consolidation with organic-inorganic silicate solutions 利用有机-无机硅酸盐溶液优化固沙参数的实验研究
IF 4.2 Q2 ENERGY & FUELS Pub Date : 2023-12-28 DOI: 10.1016/j.petlm.2023.12.004

Sand production along with the oil/gas detrimentally affects the oil production rate, downhole & subsurface facilities. Mechanical equipment and various chemicals like epoxy resin, furan resin, phenolic resin, etc. are used in the industry to reduce or eliminate this problem. In the present study, a blend of organic and inorganic silicates are used to consolidate loose sand in the presence and absence of crude oil using a core flooding apparatus. The effects of chemical concentration, pH, curing temperature and time, and the presence of residual oil on the consolidation treatment results such as compressive strength and permeability retention, were investigated and optimized. FT-IR and FE-SEM characterization techniques were employed to investigate the interaction between the chemical molecules and the sand grains. The current binding agent exhibited a viscosity of less than 6 cP at room temperature, which facilitates efficient pumping of binding agent into the desired formation through the well bore. The developed mixture demonstrated consolidation properties across all pH conditions. Furthermore, during the experimental investigation, the curing time and temperature was carefully optimized at 12 h and 423.15K, respectively to achieve the highest compressive strength of 2021 psi while achieving the permeability retention of 64%. The current chemical system exhibited improved consolidation capacity and can be effectively utilized for sand consolidation treatment in high-temperature formations.

伴随着石油/天然气产生的砂子会对石油生产率、井下 & 以及地下设施造成不利影响。为了减少或消除这一问题,业内使用了机械设备和各种化学品,如环氧树脂、呋喃树脂、酚醛树脂等。在本研究中,使用了一种有机和无机硅酸盐混合物,在有原油存在和没有原油存在的情况下,利用岩心淹没装置加固松散的沙子。研究并优化了化学浓度、pH 值、固化温度和时间以及残余石油的存在对固结处理结果(如抗压强度和渗透保留率)的影响。采用傅立叶变换红外光谱和 FE-SEM 表征技术研究了化学分子与砂粒之间的相互作用。当前的粘结剂在室温下的粘度小于 6 cP,这有利于通过井眼将粘结剂有效地泵入所需的地层。所开发的混合物在所有 pH 值条件下均表现出固结特性。此外,在实验研究过程中,对固化时间和温度进行了精心优化,分别为 12 小时和 423.15K,以达到 2021 psi 的最高抗压强度,同时实现 64% 的渗透率保持率。目前的化学体系显示出更高的固结能力,可有效用于高温地层的固沙处理。
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引用次数: 0
Paleo-uplift forced regional sedimentary evolution: A case study of the Late Triassic in the southeastern Sichuan Basin, South China 古隆起迫使区域沉积演化:华南四川盆地东南部晚三叠世案例研究
IF 4.2 Q2 ENERGY & FUELS Pub Date : 2023-12-14 DOI: 10.1016/j.petlm.2023.12.003

The sedimentary environment of the Upper Triassic in the southeastern Sichuan Basin is obviously controlled by Luzhou paleo-uplift (LPU). However, the influence of paleo-uplift on the sedimentary patterns of the initial stages of this period in the southeastern Sichuan Basin has not yet been clear, which has plagued oil and gas exploration and development. This study shows that there is a marine sedimentary sequence, which is considered to be the first member of Xujiahe Formation (T3X1) in the southeastern Sichuan Basin. The development of LPU resulted in the sedimentary differences between the eastern and western Sichuan Basin recording T3X1 and controlled the regional sedimentary pattern. The western part is dominated by marine sediments, but the eastern paleo-uplift area is dominated by continental sedimentation in the early stage of T3X1, and it begins to transform into a marine sedimentary environment consistent with the whole basin in the late stage of the period recorded by the Xujiahe Formation. The evidences are as follows: (1) time series: based on the cyclostratigraphy analysis of Xindianzi section and Well D2, in the southeastern Sichuan Basin, the period of sedimentation of the Xujiahe Formation is about 5.9 Ma, which is basically consistent with the Qilixia section, eastern Sichuan basin, where the Xujiahe Formation is widely considered to be relatively complete; (2) distribution and evolution of palaeobiology: based on analysis of abundance evolution of major spore-pollen, many land plant fossils are preserved in the lower part of T3X1, indicates the sedimentary environment of continental facies. In the upper part of T3X1, the fossil of terrestrial plants decreased, while the fossil of marine and tidal environment appeared, this means that it was affected by the sea water in the late stages of T3X1; (3) geochemistry: calculate the salinity of water from element indicates that the uplift area is continental sedimentary environment in the early stage of T3X1, while the central and western areas of the basin are marine sedimentary environment. Until the late stage of T3X1, the southeast of the basin gradually turns into marine sedimentary environment, consisting with the whole basin; (4) types of kerogen: type Ⅲ kerogen representing continental facies was developed in the early stage of T3X1 in the uplift area, and type Ⅱ kerogen, representing marine facies, was developed in the late stage; while type Ⅱ kerogen was developed in the central and western regions of the basin as a whole in T3X1. This study is of great significance for understanding of both stratigraphic division and sedimentary evolution providing theoretical support for the exploration and development of oil and gas.

四川盆地东南部上三叠统沉积环境明显受泸州古隆起控制。然而,古隆起对四川盆地东南部该时期初期沉积格局的影响尚未明确,这一直困扰着油气勘探开发。本研究表明,四川盆地东南部有一海相沉积序列,被认为是徐家河地层(T3X1)的第一层。LPU 的发育导致了四川盆地东部和西部记录 T3X1 的沉积差异,并控制了区域沉积格局。西部以海相沉积为主,东部古隆起区在T3X1早期以大陆沉积为主,到徐家河地层记录的晚期开始转变为与整个盆地一致的海相沉积环境。证据如下(1)时间序列:根据新店子剖面和 D2 井的旋回地层学分析,四川盆地东南部徐家河地层的沉积期约为 5.9 Ma,与四川盆地东南部徐家河地层的沉积期基本一致。9Ma,这与四川盆地东部七里峡断面基本一致,普遍认为四川盆地东部徐家河地层相对完整;(2)古生物分布与演化:根据主要孢粉丰度演化分析,T3X1下部保存有大量陆生植物化石,表明其沉积环境为大陆面。在 T3X1 上部,陆生植物化石减少,而海洋和潮汐环境化石出现,说明 T3X1 晚期受到海水的影响;(3)地球化学:从元素水盐度计算,T3X1 早期隆起区为大陆沉积环境,盆地中西部为海洋沉积环境。至T3X1晚期,盆地东南部逐渐转为海相沉积环境,与整个盆地组成海相沉积环境;(4)角质类型:T3X1早期隆起区发育代表大陆相的Ⅲ型角质,晚期发育代表海相的Ⅱ型角质,T3X1盆地中西部整体发育Ⅱ型角质。该研究对了解地层划分和沉积演化具有重要意义,为油气勘探开发提供了理论支持。
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引用次数: 0
An adaptive neuro-fuzzy inference system white-box model for real-time multiphase flowing bottom-hole pressure prediction in wellbores 用于实时预测井筒内多相流井底压力的自适应神经模糊推理系统白盒模型
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2023.03.003
Chibuzo Cosmas Nwanwe , Ugochukwu Ilozurike Duru

The majority of published empirical correlations and mechanistic models are unable to provide accurate flowing bottom-hole pressure (FBHP) predictions when real-time field well data are used. This is because the empirical correlations and the empirical closure correlations for the mechanistic models were developed with experimental datasets. In addition, most machine learning (ML) FBHP prediction models were constructed with real-time well data points and published without any visible mathematical equation. This makes it difficult for other readers to use these ML models since the datasets used in their development are not open-source. This study presents a white-box adaptive neuro-fuzzy inference system (ANFIS) model for real-time prediction of multiphase FBHP in wellbores. 1001 real well data points and 1001 normalized well data points were used in constructing twenty-eight different Takagi–Sugeno fuzzy inference systems (FIS) structures. The dataset was divided into two sets; 80% for training and 20% for testing. Statistical performance analysis showed that a FIS with a 0.3 range of influence and trained with a normalized dataset achieved the best FBHP prediction performance. The optimal ANFIS black-box model was then translated into the ANFIS white-box model with the Gaussian input and the linear output membership functions and the extracted tuned premise and consequence parameter sets. Trend analysis revealed that the novel ANFIS model correctly simulates the anticipated effect of input parameters on FBHP. In addition, graphical and statistical error analyses revealed that the novel ANFIS model performed better than published mechanistic models, empirical correlations, and machine learning models. New training datasets covering wider input parameter ranges should be added to the original training dataset to improve the model's range of applicability and accuracy.

在使用实时现场油井数据时,大多数已公布的经验相关性和力学模型都无法提供准确的流动井底压力(FBHP)预测。这是因为机理模型的经验相关性和经验闭合相关性是根据实验数据集开发的。此外,大多数机器学习(ML)FBHP 预测模型都是利用实时油井数据点构建的,发布时没有任何可见的数学公式。这使得其他读者很难使用这些 ML 模型,因为开发这些模型所使用的数据集不是开源的。本研究提出了一种白盒自适应神经模糊推理系统(ANFIS)模型,用于实时预测井筒中的多相 FBHP。在构建 28 种不同的 Takagi-Sugeno 模糊推理系统(FIS)结构时,使用了 1001 个真实油井数据点和 1001 个归一化油井数据点。数据集分为两组:80%用于训练,20%用于测试。统计性能分析表明,影响范围为 0.3 并使用归一化数据集进行训练的 FIS 实现了最佳的 FBHP 预测性能。然后,将最优 ANFIS 黑箱模型转化为 ANFIS 白箱模型,并使用高斯输入和线性输出成员函数以及提取的经过调整的前提和结果参数集。趋势分析表明,新型 ANFIS 模型能够正确模拟输入参数对 FBHP 的预期影响。此外,图形和统计误差分析表明,新型 ANFIS 模型的表现优于已发布的机理模型、经验相关性模型和机器学习模型。应在原始训练数据集的基础上增加新的训练数据集,涵盖更宽的输入参数范围,以提高模型的适用范围和准确性。
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引用次数: 3
Simulation of directional propagation of hydraulic fractures induced by slotting based on discrete element method 基于离散元法的开槽诱导水力裂缝定向传播模拟
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2022.04.007
Kai Wang , Guodong Zhang , Feng Du , Yanhai Wang , Liangping Yi , Jianquan Zhang

Hydraulic fracturing (HF) technology can safely and efficiently increase the permeability of coal seam, which is conducive to CBM exploration and prevent coal and gas outburst. However, conventional HF fractures tend to expand in the direction of maximum principal stress, which may be inconsistent with the direction of fracturing required by the project. Therefore, the increased direction of coal seam permeability is different from that expected. To solve these problems, PFC2D software simulation is used to study directional hydraulic fracturing (DHF), that is the combination of slotting and hydraulic fracturing. The effects of different slotting angles (θ), different horizontal stress difference coefficients (K) and different injection pressures on DHF fracture propagation are analyzed. The results show that the DHF method can overcome the dominant effect of initial in-situ stress on the propagation direction of hydraulic fractures and control the propagation of fractures along and perpendicular to the slotting direction when θ, K and liquid injection pressure are small. When the DHF fracture is connected with manual slotting, the pressure will shake violently, and the fracturing curve presents a multi-peak type. The increase and decrease of particle pressure around the fracturing hole reflect the process of pressure accumulation and fracture propagation at the fracture tip respectively. Compared with conventional HF, DHF can not only shorten the fracturing time but also make the fracture network more complex, which is more conducive to gas flow. Under the action of in-situ stress, the stress between slots will increase to exceed the maximum horizontal principal stress. Moreover, with the change in fracturing time, the local stress of the model will also change. Hydraulic fractures are always expanding to the area with large local stress. The research results could provide certain help for DHF theoretical research and engineering application.

水力压裂(HF)技术可以安全高效地提高煤层的渗透率,有利于煤层气勘探和防止煤与瓦斯突出。然而,传统的高频裂缝倾向于向最大主应力方向扩展,这可能与项目要求的压裂方向不一致。因此,煤层渗透率的增加方向与预期方向不同。为了解决这些问题,使用 PFC2D 软件模拟研究了定向水力压裂(DHF),即开槽与水力压裂的结合。分析了不同的开槽角 (θ)、不同的水平应力差系数 (K) 和不同的注入压力对 DHF 压裂传播的影响。结果表明,当θ、K和注液压力较小时,DHF方法可以克服初始原位应力对水力裂缝扩展方向的主导作用,控制裂缝沿开槽方向和垂直于开槽方向扩展。当 DHF 压裂与人工开槽相连时,压力会发生剧烈晃动,压裂曲线呈现多峰型。压裂孔周围颗粒压力的增大和减小分别反映了压裂端压力积累和压裂扩展的过程。与常规高频相比,DHF 不仅能缩短压裂时间,还能使裂缝网络更加复杂,更有利于气体流动。在原位应力的作用下,缝间应力会增大,超过最大水平主应力。此外,随着压裂时间的变化,模型的局部应力也会发生变化。水力压裂总是向局部应力大的区域扩展。该研究成果可为DHF的理论研究和工程应用提供一定的帮助。
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引用次数: 2
A large-scale experimental simulator for natural gas hydrate recovery and its experimental applications 天然气水合物回收大型实验模拟器及其实验应用
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2021.12.005
Yang Ge , Qingping Li , Xin Lv , Mingqiang Chen , Bo Yang , Benjian Song , Jiafei Zhao , Yongchen Song

To facilitate the recovery of natural gas hydrate (NGH) deposits in the South China Sea, we have designed and developed the world's largest publicly reported experimental simulator for NGH recovery. This system can also be used to perform CO2 capture and sequestration experiments and to simulate NGH recovery using CH4/CO2 replacement. This system was used to prepare a shallow gas and hydrate reservoir, to simulate NGH recovery via depressurization with a horizontal well. A set of experimental procedures and data analysis methods were prepared for this system. By analyzing the measurements taken by each probe, we determined the temperature, pressure, and acoustic parameter trends that accompany NGH recovery. The results demonstrate that the temperature fields, pressure fields, acoustic characteristics, and electrical impedances of an NGH recovery experiment can be precisely monitored in real time using the aforementioned experimental system. Furthermore, fluid production rates can be calculated at a high level of precision. It was concluded that (1) the optimal production pressure differential ranges from 0.8 to 1.0 MPa, and the wellbore will clog if the pressure differential reaches 1.2 MPa; and (2) during NGH decomposition, strong heterogeneities will arise in the surrounding temperature and pressure fields, which will affect the shallow gas stratum.

为促进南海天然气水合物(NGH)矿藏的开采,我们设计并开发了世界上最大的公开报道的 NGH 开采实验模拟器。该系统还可用于进行二氧化碳捕获和封存实验,以及利用 CH4/CO2 置换法模拟 NGH 开采。该系统用于制备浅层天然气和水合物储层,通过水平井减压模拟 NGH 开采。为该系统准备了一套实验程序和数据分析方法。通过分析每个探头的测量结果,我们确定了伴随 NGH 开采的温度、压力和声学参数趋势。结果表明,使用上述实验系统可以实时精确地监测 NGH 回收实验的温度场、压力场、声学特性和电阻抗。此外,还可以计算出高精度的流体生产率。结论是:(1) 最佳生产压差范围为 0.8 至 1.0 兆帕,如果压差达到 1.2 兆帕,井筒就会堵塞;(2) 在 NGH 分解过程中,周围温度场和压力场会出现强烈的异质性,从而影响浅层气层。
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引用次数: 1
Forecasting oil production in unconventional reservoirs using long short term memory network coupled support vector regression method: A case study 利用长短期记忆网络耦合支持向量回归法预测非常规油藏的石油产量:案例研究
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2023.05.004
Shuqin Wen , Bing Wei , Junyu You , Yujiao He , Jun Xin , Mikhail A. Varfolomeev

Production prediction is crucial for the recovery of hydrocarbon resources. However, accurate and rapid production forecasting remains challenging for unconventional reservoirs due to the complexity of the percolation process and the scarcity of available data. To address this problem, a novel model combining a long short-term memory network (LSTM) and support vector regression (SVR) was proposed to forecast tight oil production. Three variables, the tubing head pressure, nozzle size, and water rate were utilized as the inputs of the presented machine-learning workflow to account for the influence of operational parameters. The time-series response of tight oil production was the output and was predicted by the optimized LSTM model. An SVR-based residual correction model was constructed and embedded with LSTM to increase the prediction accuracy. Case studies were carried out to verify the feasibility of the proposed method using data from two wells in the Ma-18 block of the Xinjiang oilfield. Decline curve analysis (DCA) methods, LSTM and artificial neural network (ANN) models were also applied in this study and compared with the LSTM-SVR model to prove its superiority. It was demonstrated that introducing residual correction with the newly proposed LSTM-SVR model can effectively improve prediction performance. The LSTM-SVR model of Well A produced the lowest prediction root mean square error (RMSE) of 5.42, while the RMSE of Arps, PLE Duong, ANN, and LSTM were 5.84, 6.65, 5.85, 8.16, and 7.70, respectively. The RMSE of Well B of LSTM-SVR model is 0.94, while the RMSE of ANN, and LSTM were 1.48, and 2.32.

产量预测对于油气资源的开采至关重要。然而,由于渗流过程的复杂性和可用数据的稀缺性,对于非常规油藏来说,准确而快速的产量预测仍然具有挑战性。为解决这一问题,我们提出了一种结合长短期记忆网络(LSTM)和支持向量回归(SVR)的新型模型,用于预测致密油的产量。油管头压力、喷嘴尺寸和水率这三个变量被用作所提出的机器学习工作流程的输入,以考虑操作参数的影响。致密油生产的时间序列响应是输出结果,由优化的 LSTM 模型进行预测。构建了基于 SVR 的残差修正模型,并将其嵌入 LSTM,以提高预测精度。利用新疆油田马-18 区块两口井的数据进行了案例研究,验证了所提方法的可行性。本研究还应用了递减曲线分析(DCA)方法、LSTM 和人工神经网络(ANN)模型,并与 LSTM-SVR 模型进行了比较,以证明其优越性。结果表明,在新提出的 LSTM-SVR 模型中引入残差校正可以有效提高预测性能。A 井的 LSTM-SVR 模型产生的预测均方根误差(RMSE)最小,为 5.42,而 Arps、PLE Duong、ANN 和 LSTM 的 RMSE 分别为 5.84、6.65、5.85、8.16 和 7.70。LSTM-SVR 模型井 B 的 RMSE 为 0.94,而 ANN 和 LSTM 的 RMSE 分别为 1.48 和 2.32。
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引用次数: 0
Pore scale numerical investigation of counter-current spontaneous imbibition in multi-scaled pore networks 多尺度孔隙网络中逆流自发浸润的孔隙尺度数值研究
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2022.09.001
Yuchen Wu, Xiukun Wang, Chaofan Zhang, Chenggang Xian

The multi-scaled pore networks of shale or tight reservoirs are considerably different from the conventional sandstone reservoirs. After hydraulic fracturing treatment, the spontaneous imbibition process plays an important role in the productivity of the horizontal wells. Applying the color-gradient model of Lattice Boltzmann Method (LBM) accelerated with parallel computing, we studied the countercurrent spontaneous imbibition process in two kinds of pore structures with different interlacing distributions of large and small pores. The effect of geometry configuration of pore arrays with different pore-scale and the capillary number Ca on the mechanism of counter-current spontaneous imbibition as well as the corresponding oil recovery factor are studied. We found that the wetting phase tends to invade the small pore array under small Ca in both types of geometry configurations of different pore arrays of four pore arrays zones. The wetting phase also tends to invade the pore array near the inlet for injecting the wetting phase no matter if it is a large pore array or small pore array except for the situation when the Ca is large to a certain value. In this situation, the small pore arrays show resistance to the wetting phase, so the wetting phase doesn't invade the small pore near the inlet, but invades the large pore preferentially. Both the geometry configurations of different pore arrays and Ca have a significant effect on the oil recovery factor. This work will help to solve the doubt about the selectivity of the multi-scaled pores of the wetting phase and the role of pores with different sizes in imbibition and oil draining in countercurrent spontaneous imbibition processes.

页岩或致密储层的多尺度孔隙网络与常规砂岩储层有很大不同。水力压裂处理后,自发浸润过程对水平井的产能起着重要作用。应用并行计算加速的格子波兹曼方法(LBM)颜色梯度模型,我们研究了两种大小孔隙交错分布的孔隙结构中的逆流自发浸润过程。研究了不同孔隙尺度的孔隙阵列几何构型和毛细管数 Ca 对逆流自发浸润机理以及相应采油系数的影响。我们发现,在四孔阵列区不同孔阵列的两种几何构型中,在小 Ca 条件下,润湿相倾向于侵入小孔阵列。无论是大孔隙阵列还是小孔隙阵列,润湿相都倾向于侵入注入润湿相的入口附近的孔隙阵列,除非 Ca 大到一定值。在这种情况下,小孔阵列会对润湿相产生阻力,因此润湿相不会侵入入口附近的小孔,而是优先侵入大孔。不同孔隙阵列的几何构造和 Ca 对采油系数都有显著影响。这项工作将有助于解决润湿相多尺度孔隙的选择性问题,以及不同尺寸的孔隙在逆流自发浸润过程中的浸润和排油作用问题。
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引用次数: 0
Comparative study on the inhibiting mechanism of inhibitor with primary amine groups and quaternary ammonium groups for sodium bentonite 带有伯胺基团和季铵基团的抑制剂对钠基膨润土抑制机理的比较研究
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2022.05.001
Gang Xie , Yujing Luo , Chenglong Wang , Mingyi Deng , Yang Bai

Shale hydration and swelling is the main obstacle to the development of shale gas utilizing water-based drilling fluids (WBDFs). In this work, the inhibition mechanism of alkylammonium inhibitor and alkylamine inhibitor adsorbed on sodium bentonite (Na+Bent) are investigated using infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), X-ray diffraction (XRD), zeta potential, particle size distribution tests, and thermogravimetry analysis (TGA). The results suggest that HTB and HMD can be inserted into the interlamination of Na+Bent and minimize the basal spacing compared to hydrated Na+Bent. HTB and HMD are inserted between the Na+Bent layers in a single-layer tiled manner and replace the sodium ions that are firmly fixed between the layers. Eventually, water molecules are removed from the interlayer Na+Bent. The interaction between the quaternary ammonium group and Na+Bent is more significant than between the primary amine group and Na+Bent. The inhibition performance suggests that HTB inhibits Na+Bent hydration and swelling more substantially than other inhibitors, indicating that the inhibition performance of the two quaternary ammonium groups is greater than that of the two primary amine groups. Therefore, HTB can be used as intercalation inhibition in WBDFs and has tremendous application value.

页岩水化膨胀是利用水基钻井液(WBDF)开发页岩气的主要障碍。本研究采用红外光谱(FT-IR)、扫描电子显微镜(SEM)、X射线衍射(XRD)、ZETA电位、粒度分布测试和热重分析(TGA)等方法研究了吸附在钠基膨润土(Na+Bent)上的烷基铵抑制剂和烷基胺抑制剂的抑制机理。结果表明,与水合 Na+Bent 相比,HTB 和 HMD 可以插入 Na+Bent 的层间,并最大限度地减小基底间距。HTB 和 HMD 以单层平铺的方式插入 Na+Bent 层间,取代了层间牢固固定的钠离子。最终,水分子从层间 Na+Bent 中移除。季铵基团与 Na+Bent 之间的相互作用比伯胺基团与 Na+Bent 之间的相互作用更为显著。从抑制性能来看,HTB 对 Na+Bent 水化和膨胀的抑制作用比其他抑制剂更强,说明两个季铵基团的抑制性能大于两个伯胺基团的抑制性能。因此,HTB 可用作世行纤维板的插层抑制剂,具有巨大的应用价值。
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引用次数: 1
Experimental study of water imbibition characteristics of the lacustrine shale in Sichuan Basin 四川盆地湖相页岩吸水特性试验研究
Q2 ENERGY & FUELS Pub Date : 2023-12-01 DOI: 10.1016/j.petlm.2022.04.004
Changgui Jia , Bo Xiao , Lijun You , Yang Zhou , Yili Kang

Through the stimulation method of large-scale hydraulic fracturing, the spontaneous imbibition capacity of the water phase in the shale reservoir has great influence on the effect of stimulation. Generally, the lacustrine shale has the characteristics of high clay minerals content, strong expansibility, development of nanopores and micro-pores, and underdevelopment of fractures, which leads to the unclear behavior of spontaneous imbibition of aqueous phase. The lacustrine shale of Da'anzhai Member and marine shale of Longmaxi Formation in Sichuan Basin were selected to prepare both the shale matrix sample and fractured shale sample, and the spontaneous imbibition experiment of simulated formation water was carried out. By means of an XRD test, SEM observation, nuclear magnetic resonance test and linear expansion rate test, the mineral composition, the structure of pores and fractures, the capacity of hydration and expansion of both lacustrine and marine shale are compared and analyzed. The results show that the average spontaneous imbibition rate of lacustrine shale is 60.8% higher than that of marine shale within the initial 12 hours of imbibition. The lacustrine shale has faster imbibition rate than the marine shale in the initial stage of spontaneous imbibition. However, the lacustrine shale has underdeveloped pores and fractures, as well as poor connectivity of pores. Besides, the strong hydration and expansion of clay minerals can easily lead to dispersion and migration of clay minerals on the fracture surface, which will plug up the seepage channels, resulting in poor capacity of spontaneous imbibition. The spontaneous imbibition rate in the middle and late stage of Lacustrine shale is obviously lower than that of the marine shale. The overall spontaneous imbibition rate ability of the lacustrine shale is less than that of the marine shale. According to the characteristics of water imbibition of lacustrine shale, considering the dual effects of hydration expansion of clay minerals on the effective reconstructed volume, the microfractures can be initiated and extended by fully utilizing the hydration of shale. Acidification treatment, oxidation treatment or high temperature treatment can be used to expand pore space, enhance water phase imbibition capacity and improve multi-scale mass transfer capacity of the lacustrine shale.

通过大规模水力压裂的激励方法,页岩储层中水相的自发浸润能力对激励效果有很大影响。一般来说,湖相页岩具有粘土矿物含量高、膨胀性强、纳米孔和微孔发育、裂缝不发育等特点,导致水相自发浸润行为不明显。选取四川盆地大安寨系湖相页岩和龙马溪地层海相页岩制备了页岩基质样品和裂缝页岩样品,并进行了模拟地层水自发浸润实验。通过 XRD 测试、SEM 观察、核磁共振测试和线膨胀率测试,对比分析了湖相页岩和海相页岩的矿物组成、孔隙和裂缝结构、水化膨胀能力。结果表明,在浸润的最初 12 小时内,湖相页岩的平均自发浸润率比海相页岩高 60.8%。在自发浸润初期,湖相页岩的浸润速度比海相页岩快。然而,湖相页岩的孔隙和裂缝不发达,孔隙的连通性差。此外,粘土矿物的强烈水化和膨胀作用容易导致粘土矿物在断裂面上分散和迁移,从而堵塞渗流通道,导致自渗能力差。湖相页岩中后期的自渗率明显低于海相页岩。湖相页岩的整体自发浸润率能力低于海相页岩。根据湖相页岩的吸水特性,考虑到粘土矿物的水化膨胀对有效重构体积的双重影响,充分利用页岩的水化作用,可以启动和扩展微裂隙。可通过酸化处理、氧化处理或高温处理来扩大孔隙空间,增强水相浸润能力,提高湖相页岩的多尺度传质能力。
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引用次数: 0
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Petroleum
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