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Source differentiation of co-mingled petroleum derivatives in groundwater at a historically oil-contaminated urban aquifer in South Korea 韩国历史上受石油污染的城市含水层地下水中混合石油衍生物的来源分化
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-13 DOI: 10.1016/j.gsd.2025.101565
Jung-Woo Hwang , Seong-Taek Yun , Soonyoung Yu , Kyung-Jin Lee , Jeong-Eun Oh , Jeong Hee Kim
Groundwater contamination source identification is challenging due to delayed detection and changes in fingerprints during transport. In this study, multiple methods were combined to characterize the sources of petroleum derivatives in groundwater near a subway station, where petroleum derivatives, including benzene, toluene, ethylbenzene, and xylene (BTEX), have been detected for over two decades. The techniques used included hydrochemistry, oil fingerprinting, compound specific C and H isotopes, and multivariate statistical and temporal trend analysis. An integrated interpretation differentiated two contamination zones. Zone 1, near the station, showed older contamination from middle distillates, based on low total petroleum hydrocarbon levels compared to the previously high concentrations, decreasing trends of BTEX, high mole fractions of xylene, and the presence of heavier hydrocarbons. Conversely, Zone 2, to the south, revealed high BTEX concentrations, high mole fractions of benzene, and lighter hydrocarbons, indicating more recent contamination from light distillates. Anaerobic biodegradation was revealed to occur in Zone 1 based on principal component analysis (PCA), δ13C and δ2H of BTEX, and increasing benzene/toluene but decreasing toluene/ethylbenzene with time. Meanwhile, benzene degradation appeared recalcitrant in Zone 2. This study demonstrated that oil fingerprints and mole fractions are valuable in distinguishing sources, while PCA and isotope analysis help assess contaminant fate in groundwater when access to potential sources was limited. Combined application of these techniques, along with site history, is expected to differentiate contamination sources in urban groundwater with multiple potential sources across times and locations.
由于检测延迟和运输过程中指纹的变化,地下水污染源识别具有挑战性。在这项研究中,多种方法相结合,以表征地下水中石油衍生物的来源附近的地铁站,其中石油衍生物,包括苯,甲苯,乙苯和二甲苯(BTEX),已经检测了超过二十年。使用的技术包括水化学、油指纹图谱、化合物特定碳和氢同位素、多元统计和时间趋势分析。综合解释区分了两个污染区。靠近监测站的1区显示了来自中间馏分油的较早污染,这是基于与之前的高浓度相比,较低的总石油烃水平、BTEX的下降趋势、二甲苯的高摩尔分数以及较重碳氢化合物的存在。相反,南部的2区显示出高BTEX浓度,高苯摩尔分数和较轻的碳氢化合物,表明较近的污染来自轻馏分。主成分分析(PCA)、BTEX的δ13C和δ2H表明,1区发生厌氧生物降解,苯/甲苯随时间升高,甲苯/乙苯随时间降低。同时,2区苯的降解表现为顽固性。该研究表明,油指纹和摩尔分数在区分污染源方面是有价值的,而PCA和同位素分析有助于在潜在污染源有限的情况下评估地下水中的污染物命运。这些技术的综合应用,以及现场历史,有望区分城市地下水中的污染源与不同时间和地点的多个潜在污染源。
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引用次数: 0
A comparative study of key factors influencing groundwater in a temperate and a semi-arid regions 温带与半干旱区地下水影响因素的比较研究
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-12 DOI: 10.1016/j.gsd.2025.101562
Mahdi Miri , Mehdi Zarei , Diana M. Allen
Groundwater depletion is a critical issue with significant impacts on water availability in diverse climatic settings. This study uses a range of statistical methods and remote-sensing techniques to investigate the factors, specifically, climatic, hydrological, and human-driven changes, that influence groundwater levels (GWLs) in aquifers in a temperate region (three aquifers in southwestern Canada) and a semi-arid region (four aquifers in southern Iran). Change point and trend analyses reveal significant declines in GWL (groundwater depletion) in one aquifer in the temperate region and in all aquifers in the semi-arid region, despite climate variables such as precipitation, temperature, and potential evapotranspiration showing minimal changes over the study period. In contrast, human-induced factors, including agricultural expansion, deforestation, and increases in the number of pumping wells, have occurred in the aquifers of both regions. The comparative design highlights contrasting resilience: Canadian aquifers exhibit partial recovery under management interventions, whereas Iranian aquifers demonstrate persistent over-extraction with limited recharge. These findings emphasize that human pressure, rather than climate, is the primary driver of depletion and that adaptive, region-specific groundwater governance is critical for sustainable management under future climate and land-use change.
地下水枯竭是一个关键问题,对不同气候条件下的水资源供应有重大影响。本研究使用一系列统计方法和遥感技术来调查影响温带地区(加拿大西南部的三个含水层)和半干旱地区(伊朗南部的四个含水层)含水层地下水位(gwl)的因素,特别是气候、水文和人为驱动的变化。变化点和趋势分析显示,尽管降水、温度和潜在蒸散发等气候变量在研究期间变化很小,但温带地区的一个含水层和半干旱区的所有含水层的GWL(地下水枯竭)都显著下降。相比之下,这两个地区的含水层都出现了人为因素,包括农业扩张、森林砍伐和抽水井数量的增加。对比设计突出了对比的恢复能力:加拿大含水层在管理干预下表现出部分恢复,而伊朗含水层则表现出持续的过度开采和有限的补给。这些发现强调,人类的压力,而不是气候,是枯竭的主要驱动因素,适应性的、特定区域的地下水治理对于未来气候和土地利用变化下的可持续管理至关重要。
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引用次数: 0
Source apportionment and uncertainty assessment of nitrate and phosphate pollution in shallow groundwater in agricultural watersheds based on multi-isotope methods 基于多同位素方法的农业流域浅层地下水硝酸盐和磷酸盐污染源解析及不确定性评价
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-12 DOI: 10.1016/j.gsd.2025.101561
Qingfei Chen , Chi Wang , Anqiang Chen , Rongyang Cui , Wanli Hu , Bin Fu , Cunzheng Jiang , Xingwei Chen , Dan Zhang
Quantitative identification of the sources of nitrate (NO3) and phosphate (PO43−) in water bodies is crucial for controlling nonpoint source pollution in agricultural watersheds. However, accurate quantification of the contributions of pollution sources to NO3 and PO43− in groundwater has not been thoroughly studied. The typical agricultural watershed of Xingyun Lake was selected as the object, a combination of multi-isotopes (δ2H, δ18O-H2O, δ15N-NO3, δ18O-NO3 and δ18O-PO4) and the SIAR model was used to evaluate the contributions of various pollution sources to NO3 and PO43− in shallow groundwater within the watershed, and the uncertainties in different sources were analysed. The results revealed that domestic sewage (CE), livestock manure (LM), and soil N (SN) were the main sources of NO3 in groundwater during the rainy season (RS), with contribution rates of 32 % (uncertainty index (UI90) = 0.53), 24 % (UI90 = 0.41) and 24 % (UI90 = 0.46), respectively. CE (26 %, UI90 = 0.49), SN (25 %, UI90 = 0.47) and N fertilizer (22 %, UI90 = 0.44) were the main sources of NO3 in groundwater during the dry season (DS). NO3 in groundwater was dominated by nitrification during the DS, and weak denitrification existed during the RS. Microbially driven PO43− fractionation processes were not obvious. P fertilizer, LM and soil P, CE were the main sources of PO43− in groundwater during the RS and DS, with contribution rates of 29 % (UI90 = 0.42), 22 % (UI90 = 0.47) and 28 % (UI90 = 0.51), 27 % (UI90 = 0.50), respectively. Uncertainty analysis revealed that the contributions of N and P from CE and soil to groundwater pollution exhibited relatively high uncertainty. The sampling frequency should be increased, and the sampling period should be extended to enhance the monitoring of these pollution sources and increase the accuracy of the quantification of source contributions.
定量鉴定水体中硝酸盐(NO3−)和磷酸盐(PO43−)的来源对于控制农业流域非点源污染至关重要。然而,污染源对地下水NO3−和PO43−贡献的准确定量研究尚未深入。以云湖典型农业流域为研究对象,采用多同位素(δ2H、δ18O-H2O、δ15N-NO3、δ18O-NO3和δ18O-PO4)组合和SIAR模型,评价了不同污染源对流域浅层地下水NO3−和PO43−的贡献,并对不同污染源的不确定性进行了分析。结果表明:生活污水(CE)、畜禽粪便(LM)和土壤氮(SN)是雨季地下水NO3−的主要来源,贡献率分别为32%(不确定度指数(UI90) = 0.53)、24%(不确定度指数(UI90) = 0.41)和24% (UI90 = 0.46)。旱季地下水NO3−的主要来源为CE (26%, UI90 = 0.49)、SN (25%, UI90 = 0.47)和氮肥(22%,UI90 = 0.44)。水体中NO3−以硝化作用为主,RS期存在弱反硝化作用,微生物驱动的PO43−分异作用不明显。在RS和DS期间,磷肥、LM和土壤P、CE是地下水PO43−的主要来源,贡献率分别为29% (UI90 = 0.42)、22% (UI90 = 0.47)和28% (UI90 = 0.51)、27% (UI90 = 0.50)。不确定性分析表明,土壤和土壤中氮、磷对地下水污染的贡献具有较高的不确定性。应增加采样频率,延长采样周期,以加强对污染源的监测,提高污染源贡献量化的准确性。
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引用次数: 0
Application of sulfur isotopes to investigate the generation and migration of acid mine drainage in a uranium mine 应用硫同位素研究某铀矿酸性矿井水的生成与运移
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-12 DOI: 10.1016/j.gsd.2025.101563
Fernanda Cristina Fonseca Camargo , Carlos Alberto de Carvalho Filho , Ricardo Gomes Passos , Stela Dalva Santos Cota , Paulo Sérgio Pelógia Minardi , Virgílio Lopardi Bomtempo , Thiago Fernando de Ávila Navarro
When sulfide minerals are exposed to oxidizing conditions, acid mine drainage (AMD) is generated. While this process can occur naturally, mining activities significantly accelerate it, often leading to groundwater contamination. This study reports the use of stable sulfur isotopes to characterize the predominant chemical processes involved in AMD generation within a uranium mining waste pile and its subsequent migration to adjacent areas. The sulfur isotopic composition of dissolved sulfate in water and the oxygen isotopic composition in sulfate and water molecules were analyzed to confirm AMD formation and identify the primary reaction pathway for pyrite oxidation. The δ34SSO42 values ranged from −1.5 to +0.7 ‰, while the δ18OSO42 values ranged from −2.8 to −1.5 ‰. The relative contribution of water molecules to pyrite oxidation, as determined using the stoichiometric isotopic balance model, varied between 82 and 101 ‰ when water isotopic enrichment factors near 4 ‰ were applied. The primary mechanism for pyrite oxidation was identified as pyrite oxidation by ferric ions. These findings demonstrate that studying sulfur isotopic signatures in groundwater and surface waters offers valuable insights for developing AMD mitigation strategies and other related environmental protection measures.
当硫化物矿物暴露在氧化条件下时,就会产生酸性矿井水(AMD)。虽然这一过程可以自然发生,但采矿活动大大加速了这一过程,往往导致地下水污染。本研究报告了使用稳定硫同位素来表征铀矿废物堆中AMD生成及其随后向邻近地区迁移的主要化学过程。通过分析水中溶解硫酸盐的硫同位素组成以及硫酸盐和水分子中的氧同位素组成,确定了黄铁矿氧化的主要反应途径。δ34SSO42‐值在−1.5 ~ +0.7‰之间,δ18OSO42‐值在−2.8 ~−1.5‰之间。利用化学计量同位素平衡模型确定,当水同位素富集因子接近4‰时,水分子对黄铁矿氧化的相对贡献在82 ~ 101‰之间变化。确定了黄铁矿氧化的主要机理为铁离子氧化黄铁矿。这些发现表明,研究地下水和地表水中的硫同位素特征为制定AMD缓解策略和其他相关的环境保护措施提供了有价值的见解。
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引用次数: 0
Global distribution, synergistic interactions, and advances in in-situ remediation of prevalent heavy metal(loid)s in groundwater systems 地下水系统中重金属的全球分布、协同作用及原位修复研究进展
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-06 DOI: 10.1016/j.gsd.2025.101559
Diksha Dangwal , Rahul Silori , Balendu Shekher Giri
Groundwater contamination by heavy metals (HMs) is a critical environmental and public health challenge, threatening a critical source of drinking water. This review synthesizes research from the past 1.5 decades on the global occurrence, spread, mobility, interaction mechanisms and in-situ remediation of four prevalent HMs: Arsenic (As), Lead (Pb), Cadmium (Cd), and Chromium (Cr), highlighting their widespread distribution and underlying causes of contamination across groundwater systems. HMs bio-mimic vital elements and disrupt biological functions. HMs may form reactive oxygen species (ROS) and destabilize DNA, RNA and protein. Findings reveal contamination is pervasive; particularly affecting South Asian and developed nations such as Italy, Canada, Spain, Australia and USA. The maximum concentration of As, which has geogenic causes as origin, was recorded at Nigeria (3.06 mg/L), followed by USA (3 mg/L). Pb contamination by anthropogenic intervention is humungous in Kenya, attaining 121.40 mg/L. The chief sources of Cr in Tamil Nadu, India, are the mining and tannery industries, with concentration peaking to 40.52 mg/L. Cd contamination, caused by anthropogenic activities, reached 8 mg/L (Kenya), establishing Kenya as the hotspot of contamination. Microplastics increase metal bioaccumulation, PPCPs modify metal toxicity, HMs cause antimicrobial gene transfer, which causes greater mobility and persistence of HMs. Emerging PRB setups and novel media like sulfidated nZVI, goethite promises solutions of 90 % HM removal, electrocoagulation brought 80 % As removal in most field trials. By consolidating recent findings, this review equips researchers and policymakers with a comprehensive understanding of groundwater contamination scenario, associated implications and protection strategies.
地下水重金属污染是一项重大的环境和公共卫生挑战,威胁着饮用水的重要来源。本文综述了近15年来关于砷(As)、铅(Pb)、镉(Cd)和铬(Cr)四种主要有害物质的全球发生、扩散、迁移、相互作用机制和原位修复的研究,重点介绍了它们在地下水系统中的广泛分布和污染的潜在原因。HMs生物模拟重要元素,破坏生物功能。HMs可以形成活性氧(ROS),破坏DNA、RNA和蛋白质的稳定。调查结果显示,污染无处不在;尤其是影响南亚和发达国家,如意大利、加拿大、西班牙、澳大利亚和美国。砷含量最高的国家是尼日利亚(3.06 mg/L),其次是美国(3 mg/L)。肯尼亚人为干预造成的铅污染巨大,达到121.40 mg/L。在印度泰米尔纳德邦,铬的主要来源是采矿和制革工业,其浓度最高达到40.52毫克/升。人为活动造成的Cd污染达到8 mg/L(肯尼亚),肯尼亚成为污染热点。微塑料增加金属的生物积累,PPCPs改变金属毒性,HMs引起抗菌基因转移,这导致HMs更大的流动性和持久性。在大多数现场试验中,新兴的PRB装置和新型介质,如硫化nZVI、针铁矿,有望实现90%的HM去除率,电凝法可以去除80%的As。通过整合最近的研究结果,本综述使研究人员和决策者能够全面了解地下水污染情况、相关影响和保护策略。
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引用次数: 0
Efficient removal of long- and short-chain PFAS from contaminated groundwater onto trimetallic nanoparticles and halloysite nanotubes assembled mesoporous alginate polymer beads 三金属纳米颗粒和高岭土纳米管组装的介孔海藻酸盐聚合物微球有效去除污染地下水中的长链和短链PFAS
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-05 DOI: 10.1016/j.gsd.2025.101558
Masud Hassan , Ravi Naidu , Amal Kanti Deb , Fangjie Qi , Bing Wang , Tao Jiang , Jianhua Du , Md Ariful Ahsan , Yanju Liu
Perfluoroalkyl and polyfluoroalkyl substances (PFAS) are a class of toxic organofluoride chemicals that should be effectively remediated from soil and water environments to avoid biotoxicity. This study employs tri-metallic nanoparticles (NiZnFe4O4) and halloysite nanotubes (HNTs) to assemble mesoporous alginate polymer beads (NiZnFe4O4-HNTs@alg) for the separation of multicomponent PFAS from realistic groundwater. NiZnFe4O4-HNTs@alg efficiently removed short- and long-chain PFAS compounds, including FASAAs (CnF2n+1SO2NHC2H4COOH), FASAs (CnF2n+1SO2NH2), FASEs (CnF2n+1SO2NHCH2CH2OH), PFSAs (CnF2n+1-SO2-R), PFCAs (CnF2n+1COOH), and FTSs (CnF2n+1C2H4-R). Synergistic mechanisms were identified, where NiZnFe4O4 provided magnetic separability, and HNTs increased the number of hydrophilic active sites. The adsorbent achieved >99.95 % removal efficiency for all the studied short- and long-chain PFAS from groundwater in the presence of heavy metals, including manganese (0.037 ± 0.03 μg/L), cobalt (0.138 ± 0.14 μg/L), arsenic (1.668 ± 0.127 μg/L), selenium (0.360 ± 0.14 μg/L), cadmium (0.360 ± 0.14 μg/L), and antimony (0.360 ± 0.14 μg/L). A higher adsorption performance of PFAS was achieved in the presence of a realistic groundwater matrix, including the metal ions, total organic carbon (3.93 ± 0.04 mg/L), and inorganic carbon (21.66 ± 0.45 mg/L). The unique capability of the adsorbent is its ability to facilitate easy separation of PFAS-exhausted adsorbents, which is a challenging issue for most conventional adsorbents. These findings establish a transformative platform for ex-situ groundwater remediation, highlighting the potential of NiZnFe4O4-HNTs@alg to address PFAS separation challenges and pave the way for enabling field-scale implementation.
全氟烷基和多氟烷基物质(PFAS)是一类有毒的有机氟化物化学品,应有效地从土壤和水环境中修复,以避免生物毒性。本研究采用三金属纳米颗粒(NiZnFe4O4)和高岭土纳米管(HNTs)组装介孔海藻酸盐聚合物珠(NiZnFe4O4-HNTs@alg),用于从实际地下水中分离多组分PFAS。NiZnFe4O4-HNTs@alg有效去除短链和长链PFAS化合物,包括FASAAs (CnF2n+1SO2NHC2H4COOH)、FASAs (CnF2n+1SO2NH2)、FASEs (CnF2n+1SO2NHCH2CH2OH)、PFSAs (CnF2n+1-SO2-R)、PFCAs (CnF2n+1COOH)和FTSs (CnF2n+1C2H4-R)。发现了协同机制,其中NiZnFe4O4提供磁分离性,而HNTs增加了亲水性活性位点的数量。该吸附剂对地下水中锰(0.037±0.03 μg/L)、钴(0.138±0.14 μg/L)、砷(1.668±0.127 μg/L)、硒(0.360±0.14 μg/L)、镉(0.360±0.14 μg/L)、锑(0.360±0.14 μg/L)等重金属的去除率均达到99.95%。在真实地下水基质中,PFAS对金属离子、总有机碳(3.93±0.04 mg/L)和无机碳(21.66±0.45 mg/L)具有较高的吸附性能。该吸附剂的独特性能在于它能够方便地分离pfas耗尽的吸附剂,这对于大多数传统吸附剂来说是一个具有挑战性的问题。这些发现为非原位地下水修复建立了一个变革性的平台,突出了NiZnFe4O4-HNTs@alg解决PFAS分离挑战的潜力,并为实现现场规模实施铺平了道路。
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引用次数: 0
Tracing the causes of fluoride enrichment in the groundwater sources of the Upper Bhavani River Basin, Southwest India–An integrated approach for its management in mountainous terrains 追踪印度西南部上巴瓦尼河流域地下水中氟化物富集的原因:山区管理氟化物的综合办法
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-01 DOI: 10.1016/j.gsd.2025.101557
Gayathri J A, Vipin T Raj, Sreelash K, Maya K, Padmalal D
Hydrogeochemistry, geochemical evolution, and fluoride enrichment were evaluated in the Attappadi Critical Zone Observatory within the Upper Bhavani River Basin, using 104 groundwater samples collected seasonally from open wells and bore wells. Groundwater is predominantly of Ca-HCO3 and mixed Ca-Na-HCO3 types, reflecting significant influence from silicate and carbonate weathering. Bivariate plots and multivariate statistical analyses (correlation, PCA, HCA) confirm that geogenic processes primarily control groundwater chemistry, although anthropogenic inputs are evident in agriculture and settlement-influenced zones. Both open well and bore well samples are saturated to oversaturated with carbonate minerals such as calcite, aragonite, dolomite, and magnesite, often leading to scaling. Fluoride concentration ranged from 0.10 mg/l to 1.41 mg/l in open well and 0.11 mg/l to 3.11 mg/l in bore well samples. F/Cl ratio and stable isotope data (δ18O and δ2H) suggest that fluoride enrichment is predominantly governed by geogenic process. Overall, the data reveal that geogenic factors play a major role in F- enrichment in the groundwater of the study area. These findings provide a clear understanding of the geochemical processes influencing the groundwater quality, and provide a scientific basis for implementing sustainable management strategies in the hard rock terrains, particularly within mountainous watersheds where groundwater is a vital drinking water source.
在巴瓦尼河上游的Attappadi临界带观测站,利用从露天井和钻孔井季节性采集的104个地下水样本,对水文地球化学、地球化学演化和氟化物富集进行了评价。地下水以Ca-HCO3和Ca-Na-HCO3混合类型为主,受硅酸盐和碳酸盐风化的影响较大。双变量图和多变量统计分析(相关性、PCA、HCA)证实,地质过程主要控制地下水化学,尽管在农业和定居影响区明显存在人为输入。裸井和井内样品都含有饱和或过饱和的碳酸盐矿物,如方解石、文石、白云石和菱镁矿,经常导致结垢。裸井样品的氟化物浓度为0.10 mg/l至1.41 mg/l,井内样品的氟化物浓度为0.11 mg/l至3.11 mg/l。F/Cl比值和稳定同位素(δ18O和δ2H)数据表明,氟的富集主要受地质作用的控制。综上所述,地质因素对研究区地下水富F起主要作用。这些发现提供了对影响地下水质量的地球化学过程的清晰认识,并为在硬岩地形,特别是在地下水是重要饮用水源的山区流域实施可持续管理战略提供了科学依据。
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引用次数: 0
Managed Aquifer Recharge: Modeling approaches to integrated assessment of groundwater interventions 含水层补给管理:地下水干预综合评估的建模方法
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-11-28 DOI: 10.1016/j.gsd.2025.101552
Mina Yazdani , Peter van Thienen , Sija F. Stofberg , Marjolein H.J. van Huijgevoort , Ruud P. Bartholomeus
Groundwater resources are under increasing pressure due to water abstractions and climate change, leading to water scarcity problems and threats to groundwater-dependent ecosystems. Managed Aquifer Recharge (MAR) techniques offer a promising strategy for mitigating water scarcity problems and advancing sustainable management of groundwater resources. These measures aim at intentional recharge and storage of water in aquifers by linking periods of surplus with periods of shortage to overcome the temporal imbalance. While MAR has traditionally been implemented at local scales, growing challenges related to water scarcity and groundwater depletion have led to their increasing adoption across broader regions. This shift highlights the need for modeling approaches that can adequately represent MAR within regional water systems, emphasizing interactions with both hydrological and anthropogenic components while allowing investigation of trade-offs when planning these measures. This paper provides an overview of the modeling methodologies used to assess MAR interventions in a regional context. We begin by discussing the inherent complexity of the effects of groundwater interventions such as MAR at the regional level, particularly regarding water quantity. We then look into a range of modeling approaches available in the literature to capture these complexities, based on the modeling objective, data availability, and the required spatial and temporal scales. We further emphasize the importance of incorporating multiple levels of uncertainty throughout the planning and implementation of MAR projects and model-based analyses. Our study highlights that, despite their promise, integrated and holistic modeling approaches remain underutilized in groundwater research, including MAR, highlighting a need for broader development and adoption.
由于水资源抽取和气候变化,地下水资源面临越来越大的压力,导致水资源短缺问题和对地下水依赖生态系统的威胁。含水层管理补给(MAR)技术为缓解水资源短缺问题和促进地下水资源的可持续管理提供了一种有前途的策略。这些措施旨在通过将盈余期与短缺期联系起来,有意地在含水层中补充和储存水,以克服时间上的不平衡。虽然MAR传统上是在地方范围内实施的,但与水资源短缺和地下水枯竭有关的挑战日益增加,导致它们在更广泛的地区得到越来越多的采用。这一转变突出了对能够充分代表区域水系统内MAR的建模方法的需求,强调与水文和人为成分的相互作用,同时允许在规划这些措施时进行权衡调查。本文概述了用于评估区域背景下MAR干预措施的建模方法。我们首先讨论地下水干预措施(如区域一级的MAR)的内在复杂性,特别是在水量方面。然后,我们根据建模目标、数据可用性以及所需的空间和时间尺度,研究文献中可用的一系列建模方法来捕获这些复杂性。我们进一步强调在MAR项目的规划和实施以及基于模型的分析中纳入多层次不确定性的重要性。我们的研究强调,尽管有希望,综合和整体建模方法在地下水研究中仍未得到充分利用,包括MAR,强调需要更广泛的开发和采用。
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引用次数: 0
The potential of localized near-nature managed aquifer recharge in the context of climate change adaption – An assessment within Brandenburg's lower spree catchment 气候变化适应背景下局部近自然管理含水层补给的潜力——勃兰登堡下游集水区的评估
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-11-01 DOI: 10.1016/j.gsd.2025.101549
Jan Stautzebach, Jörg Steidl, Christoph Merz
Adaptation strategies are required to strengthen the resilience of groundwater resources that are primarily challenged by climatic and anthropogenic impacts. In this regard, active management through groundwater recharge and recovery techniques known as managed aquifer recharge (MAR) may stabilize groundwater storage and connected surface waters. One option for this management is the surface-induced recharge of available surplus water (infiltration basin), which seeps through the unsaturated soil zone, is stored in an evapotranspiration-free aquifer beneath it, and is recovered when needed. However, surface-induced MAR is underrepresented within the lower catchment of the river Spree. This study therefore assessed potential and individual recharge locations. Including thematic maps derived from a set of weighted criteria, a broad spectrum of suitable conditions were shown using indices in terms of land use, infiltration characteristics, hydrogeology, and economic feasibility. They were consistent with the recharge capabilities found for a dense network of natural topographic sinks, some of which can be employed for decentralized near-natural and semi-constructed groundwater recharge. Accordingly, surplus discharge water volumes from extreme weather events were assessed to be a sufficient source for many recharge locations, including those with storage capabilities that could be increased through construction. Altogether, around one quarter of the study area was found to be predominantly moderately to highly suitable, including some isolated and many closely spaced sinks of varying sizes, which can also be used for grouped groundwater recharge. These can therefore be regarded as scalable groundwater recharge clusters and are available for further comprehensive decision-making and model-based analysis.
需要采取适应战略来加强主要受到气候和人为影响挑战的地下水资源的复原力。在这方面,通过被称为管理含水层补给(MAR)的地下水补给和恢复技术的积极管理可以稳定地下水储存和连接地表水。这种管理的一种选择是地表诱导的可用剩余水的补给(渗透盆地),它通过非饱和土壤带渗透,储存在其下方无蒸发蒸腾的含水层中,并在需要时回收。然而,在施普雷河下游的集水区中,地表诱发的MAR代表性不足。因此,本研究评估了潜在的和个别的充电位置。包括从一套加权标准中得出的专题地图,利用土地利用、渗透特征、水文地质和经济可行性方面的指数,显示了广泛的适宜条件。它们与密集的自然地形汇网所发现的补给能力相一致,其中一些可用于分散的近自然和半人工地下水补给。因此,极端天气事件的剩余排放水量被评估为许多补给地点的足够来源,包括那些可以通过建设增加储存能力的地点。总的来说,大约四分之一的研究区域被发现主要是中等到高度适合的,包括一些孤立的和许多大小不同的紧密间隔的水槽,这些水槽也可以用于分组地下水补给。因此,这些可被视为可扩展的地下水补给集群,可用于进一步的综合决策和基于模型的分析。
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引用次数: 0
Explainable deep learning-based simulation for evaluating climate-driven future groundwater level changes in South Korea 可解释的基于深度学习的模拟,用于评估韩国气候驱动的未来地下水水位变化
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-11-01 DOI: 10.1016/j.gsd.2025.101541
Jimin Hwang , Kang-Kun Lee
Simulating groundwater levels (GWL) under future climate scenarios using meteorological inputs enables the evaluation of climate-driven impacts on groundwater systems and informs adaptive management. Although the use of artificial intelligence (AI) for GWL projection has increased, such models are often applied without assessing their plausibility or explainability, which may result in physically implausible outcomes. This study developed explainable deep learning model to simulate GWL variation through the end of the 21st century under the Shared Socioeconomic Pathways (SSP1–2.6 and SSP5–8.5), and applied them to national groundwater monitoring wells installed in alluvial and bedrock aquifers in South Korea. The framework applied interpretation algorithms to AI models, allowing verification of hydrogeologically plausible relationships before long-term simulations. The models projected more unstable GWL patterns under SSP5–8.5 than under SSP1–2.6, with prolonged low-GWL periods and a long-term decline. Relative reductions in period-mean GWL from the reference to future periods reached −1.41 % under SSP5–8.5, compared to less than −0.56 % under SSP1–2.6. Statistically significant declining trends appeared mainly under SSP5–8.5 and were more pronounced in alluvial aquifers than in bedrock aquifers. As only the direct impacts of climate change were considered, these differences are interpreted as resulting from variations in the climate-driven recharge signal due to altered rainfall patterns and increased evapotranspiration. By applying explainable deep learning models, this study improved the robustness and reliability of AI-based GWL projections. The overall results showing reduced resilience of groundwater systems to climate-induced stress suggest the need for adaptive management strategies in the future to ensure groundwater sustainability.
利用气象输入模拟未来气候情景下的地下水位(GWL),可以评估气候驱动对地下水系统的影响,并为适应性管理提供信息。尽管人工智能(AI)在GWL预测中的应用有所增加,但此类模型的应用往往没有评估其合理性或可解释性,这可能导致物理上不可信的结果。本研究建立了可解释的深度学习模型,模拟了共享社会经济路径(SSP1-2.6和SSP5-8.5)下到21世纪末的GWL变化,并将其应用于韩国冲积层和基岩含水层的国家地下水监测井。该框架将解释算法应用于人工智能模型,允许在长期模拟之前验证水文地质上合理的关系。与SSP1-2.6相比,SSP5-8.5模式预估的GWL型更加不稳定,低GWL期延长,且长期下降。与SSP1-2.6相比,SSP5-8.5时期平均GWL相对减少量达到- 1.41%,而ssp1 - 8.5时期平均GWL相对减少量不到- 0.56%。统计上显著的下降趋势主要出现在SSP5-8.5以下,冲积含水层比基岩含水层更明显。由于只考虑了气候变化的直接影响,这些差异被解释为由于降雨模式改变和蒸散发增加而导致的气候驱动补给信号的变化。通过应用可解释的深度学习模型,本研究提高了基于ai的GWL预测的鲁棒性和可靠性。总体结果表明,地下水系统对气候引起的压力的适应能力降低,这表明未来需要适应性管理策略来确保地下水的可持续性。
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Groundwater for Sustainable Development
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