The Abuja Federal Capital Territory is an example of a heavily anthropized aquifer, where natural water-rock interaction processes are masked by human pollution. As a result, the characterization of natural processes is particularly difficult, especially to disentangle the natural from the anthropogenic signature. Two surveys were conducted in the rainy and dry season in 2021 and 2022 using an integrated geochemical, statistical, and isotopic approach. Results show that groundwater samples are affected by mixing processes between water with a Ca-HCO3 facies (associated to natural water-rock interaction processes) and contaminated waters. The latter can be observed in some wells with a shift to NO3-dominant facies in the rainy season. The stable isotopes of the water molecule (δ18O and δ2H) suggest the presence of multiple recharge zones and strong seasonal variability. The shifts in groundwater isotopic composition suggest secondary evaporation in the rainy season and limited local precipitation influence during the dry season, with a possible domination of deep aquifer contributions.
The frequency distribution of tritium (3H) in 2021 confirms the limited impact of local precipitation during the dry season (median 0.8 TU), further supporting the dominance of deep aquifer contributions to groundwater flow. The influence of rainwater infiltration is observed as a main contribution to the remobilization of contaminants (of agricultural and domestic origin) stocked in the unsaturated zone, rather than a dilution effect. This results in a progressive increase of NO3− concentration in the rainy season (reaching 433 mg/L), highlighting the need for a more complete characterization to support a wiser sustainable environmental management in an area subject to increasing anthropogenic pressure and prone to significant population growth.