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Impact of coupled climate change and human exploitation on groundwater dynamics in agricultural intensive planting areas 气候变化与人类开发耦合对农业集约种植区地下水动态的影响
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-30 DOI: 10.1016/j.gsd.2025.101575
Jiajun Li , Bo Li , Peng Qi , Zhijun Li , Yunfei Bai
Groundwater resources are essential for agricultural production, especially in areas of intensive agricultural. Using western Jilin Province, China, as a case study, this paper systematically evaluates groundwater dynamics under the combined impacts of climate change and human exploitation. Although extensive research has explored the effects of climate change on groundwater systems, the integration of climate models with groundwater-exploitation scenarios remains understudied. Accordingly, we used GMS–MODFLOW to construct a three-dimensional groundwater flow model. Using observed groundwater-level data from 10 observation wells, we simulated the groundwater flow field for 2007–2016 and validated the model. Building on this setup, we conducted scenario-based simulations to project the spatiotemporal dynamics of groundwater levels for 2021–2080, using six Global Climate Models (GCMs) and the four Shared Socioeconomic Pathways (SSPs) (SSP1-2.6, SSP2-4.5, SSP3-7.0, and SSP5-8.5), and imposing exploitation-rate adjustments of ±20 % relative to current levels. Results show that precipitation accounts for approximately 95 % of total recharge. Across all scenarios, groundwater discharge exceeds recharge, producing a long-term negative change in storage whose magnitude increases under higher-emissions forcing; the mean annual storage deficit rises from 1.20 × 108 m3/yr (SSP1-2.6) to 2.20 × 108 m3/yr (SSP5-8.5). The regional mean groundwater-level decline rate ranges from 1.68 to 3.00 cm/yr, yielding a cumulative drop of 0.98–1.80 m by 2080. However, a 20 % reduction in groundwater exploitation can partially mitigate this trend: relative to the +20 % exploitation scenario, the regional mean decline rate falls by about 50 %, hotspots of serve decline contract markedly, and exploitation-driven spatial heterogeneity is reduced. The analysis further indicates that higher-emissions scenarios exacerbate human impacts on groundwater, whereas lower-emissions scenarios help alleviate these effects. Our distinctive contribution is an integrated modeling framework that tightly couples climate-change projections with groundwater-abstraction scenarios, yielding actionable insights for groundwater management in agricultural regions, informing adaptive pumping strategies, and supporting long-term sustainable use.
地下水资源对农业生产至关重要,特别是在集约化农业地区。以吉林省西部为例,系统评价了气候变化和人类开发共同影响下的地下水动态。尽管广泛的研究已经探讨了气候变化对地下水系统的影响,但将气候模式与地下水开采情景相结合的研究仍然不足。因此,我们使用GMS-MODFLOW构建了三维地下水流动模型。利用10口观测井的地下水位观测数据,模拟了2007-2016年地下水流场,并对模型进行了验证。在此基础上,采用6种全球气候模式(GCMs)和4种共享社会经济路径(SSP1-2.6、SSP2-4.5、SSP3-7.0和SSP5-8.5),对2021-2080年地下水水位的时空动态进行了基于场景的模拟,并对开采率进行了相对于当前水平±20%的调整。结果表明,降水约占总补给量的95%。在所有情景中,地下水排放均超过补给,导致库存量长期负变化,其幅度在高排放强迫下增加;年平均库容亏从1.20 × 108 m3/yr (SSP1-2.6)增加到2.20 × 108 m3/yr (SSP5-8.5)。区域平均地下水位下降速率为1.68 ~ 3.00 cm/年,到2080年累计下降0.98 ~ 1.80 m。然而,减少20%的地下水开采可以部分缓解这一趋势:相对于+ 20%的开采情景,区域平均下降率下降约50%,服务减少热点显著缩小,开发驱动的空间异质性减弱。分析进一步表明,高排放情景会加剧人类对地下水的影响,而低排放情景则有助于减轻这些影响。我们的独特贡献是一个集成的建模框架,将气候变化预测与地下水开采情景紧密结合起来,为农业地区的地下水管理提供可操作的见解,为适应性抽水策略提供信息,并支持长期可持续利用。
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引用次数: 0
Enrichment characteristics of colloid−bound ammonium and phosphorus in groundwater systems: Insights into their sources and controls 地下水系统中胶态铵和磷的富集特征:对其来源和控制的认识
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-30 DOI: 10.1016/j.gsd.2025.101573
Shuxin Huang , Mingjian Gao , Jiasen Li , Ruihan Xiong , Bing Liu , Hengyi Wang , Caixiang Zhang
High levels of colloid−bound ammonium (C−NH4+) and phosphorus (C−P) have been proved to exist in groundwater systems, which can pose a potential threat on human health and ecosystems. However, field−scale studies of their enrichment characteristics remain limited. In this study, high levels of C−NH4+ (up to 19.7 mg/L) and C−P (up to 3.28 mg/L) were found in groundwater systems of Jianghan Plain, China. Among them, C−NH4+ was mainly distributed in small molecular weight fraction (1 − 10 kDa), while C−P was mainly distributed in large and medium molecular weight fraction (10 kDa −0.45 μm). The release of C−NH4+ (up to 105 mg/kg) and C−P (up to 652 mg/kg) from sediments could be a main source of colloids in groundwater. Moreover, correlation and principal component analysis (PCA) results indicated another source of anthropogenic input for C−NH4+ and C−P. Importantly, the enrichment of C−NH4+ was mainly regulated by colloidal Fe/Mn (C−Fe/Mn), whereas that of C−P was coupling controlled with C−Fe/Mn and dissolved organic matter. Fluorescence excitation−emission matrices with parallel factor analysis (EEM−PARAFAC) results revealed the terrestrial humic−like and tryptophan−like components of different colloidal fractions. Large and medium molecular weight C−P (10 kDa−0.45 μm) regulated by terrestrial humic−like dissolved organic matter (DOM) could form complex colloids through surface active sites (DOM−P binary complexes). Small molecular weight C−P (1−10 kDa) was closely related to the degradation or the release of internal proteinaceous substances (e.g., tryptophan) by microorganisms. This study provides new insights into the enrichment of C−NH4+/P in groundwater systems.
地下水系统中存在高水平的胶体结合铵(C−NH4+)和磷(C−P),这可能对人类健康和生态系统构成潜在威胁。然而,对其富集特征的野外研究仍然有限。研究发现,江汉平原地下水系统中C - NH4+和C - P含量分别高达19.7 mg/L和3.28 mg/L。其中,C−NH4+主要分布在小分子量组分(1 ~ 10 kDa), C−P主要分布在大、中分子量组分(10 kDa ~ 0.45 μm)。沉积物中释放的C−NH4+(高达105 mg/kg)和C−P(高达652 mg/kg)可能是地下水中胶体的主要来源。此外,相关性和主成分分析(PCA)结果表明,C−NH4+和C−P的人为输入是另一个来源。重要的是,C−NH4+的富集主要受胶体Fe/Mn (C−Fe/Mn)的调控,而C−P的富集则受C−Fe/Mn和溶解有机质的耦合控制。荧光激发-发射基质平行因子分析(EEM - PARAFAC)结果揭示了不同胶体组分的类腐殖质和类色氨酸组分。大、中分子量C−P (10 kDa−0.45 μm)在类陆生腐殖质溶解有机物(DOM)的调控下,可通过表面活性位点(DOM−P二元配合物)形成复杂的胶体。小分子量C−P(1−10 kDa)与微生物降解或释放内部蛋白质物质(如色氨酸)密切相关。该研究为地下水系统中C−NH4+/P的富集提供了新的见解。
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引用次数: 0
Groundwater hydrochemistry, pollution source analysis, and health risk in western Jilin, China 吉林西部地下水水化学、污染源分析及健康风险
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-26 DOI: 10.1016/j.gsd.2025.101560
Tao Li , Xinying Cui , Dongmei Ruan , Jianmin Bian
Groundwater (GW) components in western Jilin are shaped by natural geology and anthropogenic activities (particularly water projects), driving groundwater quality (GWQ) variations with health implications. Consequently, effective GW management requires accurate GW information including GWQ, pollution source identification, and human health risk assessment (HHRA).
This paper presented integrated methods for comprehensive evaluation of these elements. From the GWQ perspective, SNWTM integrated groundwater quality evaluation methods (GWQEM) with TOPSIS to enhance accuracy, method interpretability, and overcome single-method limitations for diverse water samples. To accurately identify GW pollution sources, this study utilized Self-Organizing Map (SOM) and Positive Matrix Factorization (PMF), whose integration provided complete pollution source characterization through combined qualitative-quantitative analysis, enabling targeted identification. In HHRA, this study developed a novel method for selecting the most probable value interval (TMPVI) in trapezoidal fuzzy numbers (TFN) and subsequently integrated with cloud model (CM) and Monte Carlo (MC) to establish TCM, that overcame data limitations and process uncertainty of conventional HHRA including the four-step method (TFM) and triangular stochastic (TSS).
SNWTM indicated higher GWQ in unconfined water (UW) versus confined water (CW). SOM (4 clusters) and PMF (6 factors) identified a geogenic–anthropogenic interaction, with geogenic Mn and the three-nitrogen species as the dominant contributors (maximum PMF shared 59.76 % and 62.67 %, respectively). TCM indicated that the risk was higher in UW versus CW, and higher for children than for adults. In 2022–2023, the UW-children 95th-percentile output was 1.26, exceeding the risk threshold.
吉林西部地区地下水(GW)成分受自然地质和人为活动(特别是水利工程)的影响,导致地下水质量(GWQ)变化,并对健康产生影响。因此,有效的GW管理需要准确的GW信息,包括GWQ、污染源识别和人类健康风险评估(HHRA)。本文提出了综合评价这些要素的综合方法。从GWQ的角度出发,SNWTM将地下水质量评价方法(GWQEM)与TOPSIS相结合,提高了准确性和方法的可解释性,克服了单一方法对不同水样的限制。为了准确识别GW污染源,本研究采用了自组织映射(SOM)和正矩阵分解(PMF),两者的结合通过定性和定量相结合的分析提供了完整的污染源表征,从而实现了有针对性的识别。在HHRA中,本文提出了一种梯形模糊数(TFN)中最可能值区间(TMPVI)的选择方法,并将其与云模型(CM)和蒙特卡罗(MC)相结合建立TCM,克服了传统HHRA的数据局限性和过程不确定性,包括四步法(TFM)和三角随机法(TSS)。SNWTM表明非承压水(UW)的GWQ高于承压水(CW)。SOM(4个聚类)和PMF(6个因子)确定了地-人为交互作用,以地源Mn和三氮种为主(最大PMF分别占59.76%和62.67%)。中医提示UW患者的风险高于CW患者,儿童高于成人。2022-2023年,UW-children第95百分位产出为1.26,超过风险阈值。
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引用次数: 0
Evaluation of groundwater management strategies by optimization under land subsidence constraints 地表沉降约束下地下水管理策略的优化评价
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-23 DOI: 10.1016/j.gsd.2025.101569
Juan José Díaz-Nigenda , Eric Morales-Casique , Mauricio Carrillo-García , Mario Alberto Vázquez-Peña , Selene Olea-Olea
Land subsidence is one of the most critical consequences of groundwater depletion, underscoring the need for management tools capable of evaluating how extraction decisions affect both aquifer conditions and ground deformation. Computational optimization models provide a powerful means to support such decision-making; however, most groundwater management studies addressing subsidence-prone systems impose constraints solely on aquifer drawdown, without explicitly controlling land subsidence. Here we develop an optimization framework that integrates management constraints on both aquifer drawdown and land subsidence rate, enabling simultaneous control of hydraulic conditions and deformation. Three constraint strategies were defined and applied to a simulated aquifer–aquitard system to evaluate the coupled response between aquifer drawdown and aquitard compression. The methodology involved formulating optimization models with alternative constraints, simulating multi-year scenarios, and comparing their impacts on groundwater dynamics and land subsidence behavior. Results demonstrate that the choice of management constraints strongly influences aquifer depletion, aquitard response, and total land subsidence. When only drawdown is constrained, total settlement reaches roughly 10 % of the aquitard thickness. Introducing a subsidence-rate constraint limits settlement to about 1.25 %, while applying only a subsidence-rate constraint reduces settlement to 0.04 % of the aquitard thickness. However, a trade-off would arise between controlling land subsidence and supplying groundwater as the volume of water produced through the management period is also reduced. These outcomes highlight the effectiveness of integrated management constraints and illustrate how integrated constraints can inform groundwater management decisions in subsidence-prone settings.
地面沉降是地下水枯竭最严重的后果之一,因此需要能够评估开采决策如何影响含水层条件和地面变形的管理工具。计算优化模型为支持这种决策提供了有力的手段;然而,大多数针对易下沉系统的地下水管理研究仅对含水层的下降施加限制,而没有明确控制地面沉降。在这里,我们开发了一个优化框架,该框架集成了对含水层下降和地面沉降率的管理约束,能够同时控制水力条件和变形。定义了三种约束策略,并将其应用于模拟含水层-含水层系统,以评估含水层下降和含水层压缩之间的耦合响应。该方法包括制定具有备选约束的优化模型,模拟多年情景,并比较它们对地下水动态和地面沉降行为的影响。结果表明,管理约束的选择对含水层衰竭、含水层响应和地面沉降总量有强烈影响。当只限制沉降时,总沉降量约为含水层厚度的10%。引入沉降速率约束将沉降限制在1.25%左右,而仅应用沉降速率约束将沉降减少到含水层厚度的0.04%。然而,在控制地面沉降和供应地下水之间会产生权衡,因为在管理期间产生的水量也会减少。这些结果突出了综合管理约束的有效性,并说明了综合约束如何在容易下沉的环境中为地下水管理决策提供信息。
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引用次数: 0
Locating nitrogen sources in high inorganic nitrogen zones of a shallow coastal aquifer using an integrated analytical framework 利用综合分析框架在浅海含水层高无机氮带定位氮源
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-19 DOI: 10.1016/j.gsd.2025.101570
Qiaona Huang , Ya Wang , Shan Ye , Bingfa Zhi , Zhongzhong Wang
Groundwater nitrogen contamination poses a critical global environmental challenge. To address this significant regional to global scale groundwater challenge, identifying the exact locations of nitrogen sources is essential for pollution source management and control. This study systematically analyzed 83 shallow groundwater samples from Zhuhai through an integrated analytical framework. This framework progressively follows the steps of qualitative identification of inorganic nitrogen pollution sources, spatial identification of pollution hotspots, and delineation of specific spatial boundaries of potential sources, by integrating multiple techniques such as isotopic analysis, hydrochemical characteristics, land use analysis, and hydrogeological features etc., ultimately achieving precise positioning of inorganic nitrogen emissions. Spatial interpolation indicated that elevated inorganic nitrogen predominantly occurred in the densely populated western agricultural and industrial region, where groundwater was highly vulnerable to anthropogenic impacts. Based on the qualitative identification of hotspot nitrogen sources, this study successfully constrained the specific locations of nitrogen sources through land use and groundwater flow field analysis to site scale with limited area. Pollution sites for three NH4+-N hotspots of Zhuhai, which were dominantly influenced by cropland, domestic sewage, and local industrial wastewater were clearly identified. The NO3-N hotspot's nitrogen source was traced to anthropogenic wastewater within a 100 m radius to the southeast. This study demonstrated the effectiveness of the proposed integrated analytical framework, the results achieved is very convenient for pollution source management and control and could be applied to locate inorganic nitrogen pollution sources in other regions globally.
地下水氮污染是一项重大的全球环境挑战。为了解决这一重大的区域乃至全球地下水挑战,确定氮源的确切位置对于污染源管理和控制至关重要。本研究采用综合分析框架对珠海市83份浅层地下水样本进行了系统分析。该框架通过整合同位素分析、水化学特征、土地利用分析、水文地质特征等多种技术,逐步遵循无机氮污染源定性识别、污染热点空间识别、潜在污染源具体空间边界圈定等步骤,最终实现无机氮排放的精准定位。空间插值结果表明,无机氮升高主要发生在人口密集的西部工农业地区,地下水极易受到人为影响。本研究在定性识别热点氮源的基础上,通过土地利用和地下水流场分析,成功地将氮源的具体位置限定在有限面积的场地尺度上。明确了我市3个NH4+-N污染热点的污染位点,主要受农田、生活污水和当地工业废水的影响。NO3−-N热点的氮源为东南方向100 m半径范围内的人为废水。本研究验证了所提出的综合分析框架的有效性,所获得的结果为污染源管理和控制提供了便利,并可用于全球其他地区无机氮污染源的定位。
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引用次数: 0
Deep and fossil aquifers in Morocco: A multidisciplinary assessment of groundwater dynamics and salinization 摩洛哥深层和化石含水层:地下水动态和盐碱化的多学科评估
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-19 DOI: 10.1016/j.gsd.2025.101566
Ayoub Ayaou , Yassine Ait Brahim , Mohammed Hssaisoune , Meryem Miftah , Ahmed El-Azhari , Lhoussaine Bouchaou
In Morocco, groundwater serves as a strategic water resource for drinking, domestic, agriculture, and industrial purposes due to the scarcity of surface water and high vulnerability to climate change. This dependency stems from the arid to semi-arid climate conditions where ecosystems depend on groundwater. Successive droughts, population growth, and economic development, particularly in agriculture, lead to the overexploitation of groundwater, especially shallow aquifers during the three last decades. This situation necessitates an investigation of these deep aquifers to manage this essential resource effectively. Hence, the aim of this study is to provide insights into deep aquifers, including their geometry, hydrodynamic, hydrochemical characteristics, recharge origins, geothermal potential, and residence times to determine which aquifers take longer to recharge and which should remain unexploited. The investigated deep aquifers exhibit a wide range of salinity, with electrical conductivity values ranging from 231 to 49 040 μs/cm, whereas pH values range from 5.64 to 10.76. The high salinity is primarily attributed to Cl, SO42−, Na+ and HCO3 with average concentrations of 829, 475, 463, and 316 mg/l, respectively. The recharge of the majority studied deep aquifers, particularly the Cretaceous ones (Souss, Essaouira, Ouarzazate, Tadla, Haouz, and Errachidia), is mainly from the High Atlas Mountains, except for the deep aquifers of Sahara where recharge is carried out during a specific context. The deep Jurassic aquifers, including the South Rifain Corridor, High and Middle Moulouya, High Plateaus, Horst Chain, Taourirt-Oujda Corridor, Beni-Bouyahi, and Bni-Znassen aquifers, are recharged from the Middle Atlas and North-Eastern Moroccan Mountains. Most investigated deep aquifers containing old waters are considered fossil or less renewable, with residence times exceeding 20 kiloannum before present (ka BP). The deep Sahara aquifers are the most significant groundwater potential reserves due to their lithologic composition, and their extensive area of approximately 90 000 km2, but with very low groundwater replenishment rates dating back over 46.5 ka BP according to radiocarbon dating. Because of their variable mineralization related to their variable geological contexts and human activities, all the investigated systems show a high vulnerability mainly within their outcrops, which are mainly karstic or fissured areas. These deep aquifers require more stringent management and protection due to arid climate and very low precipitation through all the investigated regions. The results provide key information on the functioning of Moroccan deep aquifers and highlight the need for careful management and conservation.
在摩洛哥,由于地表水的稀缺和对气候变化的高度脆弱性,地下水作为饮用、家庭、农业和工业用途的战略水资源。这种依赖源于干旱到半干旱的气候条件,那里的生态系统依赖地下水。连续的干旱、人口增长和经济发展,特别是农业的发展,在过去三十年中导致地下水,特别是浅层含水层的过度开采。这种情况需要对这些深层含水层进行调查,以有效地管理这一重要资源。因此,本研究的目的是深入了解深层含水层,包括其几何形状、水动力学、水化学特征、补给来源、地热潜力和停留时间,以确定哪些含水层需要更长的补给时间,哪些含水层应该保持未开发状态。所研究的深层含水层盐度范围广,电导率值为231 ~ 49 040 μs/cm, pH值为5.64 ~ 10.76。高盐度主要由Cl−、SO42−、Na+和HCO3−组成,平均浓度分别为829、475、463和316 mg/l。大多数研究的深层含水层,特别是白垩纪含水层(Souss, Essaouira, Ouarzazate, Tadla, Haouz和Errachidia)的补给主要来自高阿特拉斯山脉,除了撒哈拉的深层含水层,在特定环境下进行补给。深侏罗系含水层,包括南里法恩走廊、高、中穆卢亚、高原、霍斯特链、taouritt - oujda走廊、Beni-Bouyahi和Bni-Znassen含水层,是由中阿特拉斯和东北摩洛哥山脉补给的。大多数被调查的含有古老水的深层含水层被认为是化石或可再生性较差,其停留时间超过20千年(ka BP)。根据放射性碳测年,撒哈拉深层含水层的岩性组成和面积约为9万平方公里,是最重要的地下水潜在储量,但地下水补给率非常低,可追溯到46.5 ka BP以上。由于不同的地质环境和人类活动导致不同的矿化程度,所有被调查的系统主要在其露头(主要是岩溶或裂隙区)内表现出高度脆弱性。由于所有调查地区的干旱气候和极低的降水,这些深层含水层需要更严格的管理和保护。研究结果提供了关于摩洛哥深层含水层功能的关键信息,并强调了谨慎管理和保护的必要性。
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引用次数: 0
Isotope-hydrogeochemical delineation of recharge zones in the Sierra Madre Oriental, Mexico 墨西哥东部马德雷山脉补给带的同位素-水文地球化学圈定
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-18 DOI: 10.1016/j.gsd.2025.101571
J.A. Ramos-Leal , J. Moran-Ramirez , Oscar Almanza Tovar , Ana Elizabeth Marín Celestino , Ana Beatriz Rubio Arellano , Ulises Rodríguez Robles
Aquifers in karst systems are highly complex, and understanding their hydrodynamics and geochemical evolution is a significant challenge. A clear example of this complexity is found in the Sierra Madre Oriental, where carbonate and sulfate rocks predominate. To study these systems, water-rock interactions and the isotopic composition of groundwater and meteoric water have been analyzed.
Through these investigations, three types of groundwater flow were identified and recharge zones were delineated in the region. Isotopic techniques made it possible to locate these zones, revealing that regional recharge occurs at altitudes up to 2,733 m above sea level, with an average of 1,342 m, while local recharge is recorded from 233 m above sea level. These data indicate that the recharge process is distributed along the entire altitudinal gradient of the Sierra Madre Oriental.
The results obtained provide key information on the geochemical controls that influence the evolution of spring water in the Huasteca. Among the most relevant processes are the dissolution and precipitation of minerals such as calcite and dolomite, as well as the mixing of groundwater within the system. These mechanisms are fundamental in shaping the region's characteristic karst landscape.
Finally, the recharge zones of the main springs were delineated using flow lines derived from equipotentials and isotopic recharge altitudes, allowing for a more precise characterization of the hydrogeological system.
岩溶系统中的含水层非常复杂,了解其水动力学和地球化学演化是一个重大挑战。这种复杂性的一个明显例子是在Sierra Madre Oriental发现的,那里主要是碳酸盐和硫酸盐岩。为了研究这些系统,分析了水岩相互作用以及地下水和大气水的同位素组成。通过调查,确定了三种地下水流动类型,并划定了区内地下水补给带。同位素技术使这些区域的定位成为可能,揭示了区域补给发生在海拔2733米以上,平均1342米,而局部补给记录在海拔233米以上。这些数据表明,补给过程沿东部马德雷山脉的整个海拔梯度分布。研究结果为研究影响华斯特卡地区泉水演化的地球化学控制因素提供了关键信息。其中最相关的过程是方解石和白云石等矿物的溶解和沉淀,以及系统内地下水的混合。这些机制是形成该地区特色喀斯特景观的基础。最后,利用由等电位和同位素补给高度得出的流水线划定了主泉的补给带,从而可以更精确地表征水文地质系统。
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引用次数: 0
Fe-and Mg-functionalized chicken manure biochar immobilized Cd, Cr, and Pb in aged soil and decreased their leaching into groundwater 铁和镁功能化的鸡粪生物炭固定化了老化土壤中的Cd、Cr和Pb,减少了它们向地下水的淋滤
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-14 DOI: 10.1016/j.gsd.2025.101568
Yasir Hamid , Qiang Lin , Muhammad Saqib Rashid , Muhammad Usman , Yonglong Chen , Esmat F. Ali , Hamada Abdelrahman , Temoor Ahmed , Sabry M. Shaheen , Sang Soo Lee , Xiaoe Yang
The influence of functionalized biochar on the leachability and bioavailability of metal cations in contaminated soils remains insufficiently explored, particularly under aging conditions and multiple leaching cycles. This study investigated the performance of pristine, Mg-, and Fe-functionalized biochar in reducing the leachability of Cd, Cr, and Pb in co-contaminated soil. Preliminary screening revealed that pristine chicken manure biochar (CB), and Mg (MCB)-, and Fe (FCB)-functionalized biochars were more effective in decreasing metals leachability. Consequently, their effects on metals leachability, bioavailability, and fractionation were evaluated through nine leaching cycles and aging experiments (aged soil for 1, 10, 20, 30, 40, and 50 days). Addition of CB to the soil columns significantly decreased the metals concentrations in the leachate. Specifically, Cd concentration (mg L−1) decreased from 5.84 in CK to 0.41 in FCB, 0.53 in MCB, and 0.52 in CB treatments; Pb concentration (mg L−1) decreased from 114.2 in CK to 4.4 in FCB, 5.9 in MCB, and 10.5 in CB treatments; and Cr concentration (mg L−1) decreased from 34.6 in CK to 1.6 in FCB, 1.8 in MCB, and 3.2 in CB treatments. The FCB and MCB redistributed the metals mobile fraction to the residual fraction thereby reducing their mobilization (CaCl2-extrcated form) and availability (DTPA-extracted form) in the treated soil compared to CK soil. The immobilization effect of FCB and MCB remained stable during aging periods, leaching cycles, and under acidic pH, indicating their strong ability for metal capturing. However, long-term investigation of biochar-immobilized metals in aged soils is needed. These findings confirm that functionalizing CB with Fe and/or Mg effectively immobilized Cd, Cr, and Pb in aged soil, reducing the leaching of these toxic metals into groundwater, making this engineered biochar a viable option for soil remediation.
功能化生物炭对污染土壤中金属阳离子的浸出性和生物利用度的影响尚未得到充分探讨,特别是在老化条件和多次浸出循环下。本研究考察了原始生物炭、镁功能化生物炭和铁功能化生物炭在降低共污染土壤中Cd、Cr和Pb的浸出能力方面的性能。初步筛选表明,原始鸡粪生物炭(CB)、Mg (MCB)-和Fe (FCB)-功能化生物炭对降低金属浸出率更有效。因此,通过9个浸出循环和老化实验(老化土壤1、10、20、30、40和50天)评估了它们对金属浸出性、生物利用度和分异的影响。在土壤柱中添加CB显著降低了渗滤液中的金属浓度。Cd浓度(mg L−1)从CK的5.84降至FCB的0.41、MCB的0.53和CB的0.52;铅浓度(mg L−1)从CK的114.2降至FCB的4.4、MCB的5.9和CB的10.5;Cr浓度(mg L−1)从CK的34.6降至FCB的1.6、MCB的1.8和CB的3.2。与对照土壤相比,FCB和MCB将金属的可移动部分重新分配到残余部分,从而降低了它们在处理土壤中的动员(cacl2萃取形式)和有效性(dtpa萃取形式)。在老化期、浸出周期和酸性pH条件下,FCB和MCB的固定效果保持稳定,表明它们具有较强的金属捕获能力。然而,对老化土壤中生物炭固定化金属的长期研究是必要的。这些发现证实,用Fe和/或Mg功能化CB有效地固定了老化土壤中的Cd、Cr和Pb,减少了这些有毒金属向地下水的浸出,使这种工程生物炭成为土壤修复的可行选择。
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引用次数: 0
Early warning of soil and groundwater pollution by heavy metals: Progresses, perspectives and challenges 土壤和地下水重金属污染预警:进展、展望与挑战
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-14 DOI: 10.1016/j.gsd.2025.101567
Enhao Huang , Yunhao Li , Yuanbo Ge , Jun Dong , Weihong Zhang
Pollution early warning (PEW) of soil and groundwater by heavy metals is critical for preventing irreversible damage to ecosystems and human health. This review provides a novel, data-driven synthesis of the field by uniquely combining a quantitative bibliometric analysis of over 1400 publications with a systematic technological evaluation. Our analysis reveals a substantial growth trend and identifies a clear three-stage technological evolution: from reliance on single-indicator assessment (1999–2015), to the rise of model-based prediction (2016–2019), and the current era of big data-driven intelligence (2020–present). We critically assess four major PEW categories and find that traditional monitoring and biological methods are constrained by poor selectivity, environmental susceptibility, and instability. In contrast, this review highlights that AI-driven models and multi-source data fusion are pivotal advancements, significantly enhancing predictive accuracy and timeliness. The primary challenge ahead is bridging the gap between sophisticated models and robust, real-time data acquisition. We conclude that future breakthroughs will depend on advancing sensor technology and multi-scale coupled models, fundamentally shifting the paradigm from reactive remediation to proactive prevention.
土壤和地下水重金属污染预警(PEW)对于防止对生态系统和人类健康造成不可逆转的损害至关重要。这篇综述提供了一种新颖的、数据驱动的领域综合,通过独特地将超过1400份出版物的定量文献计量分析与系统的技术评估相结合。我们的分析揭示了一个显著的增长趋势,并确定了一个明确的三个阶段的技术演变:从依赖单一指标评估(1999-2015),到基于模型的预测的兴起(2016-2019),以及当前大数据驱动的智能时代(2020年至今)。我们批判性地评估了皮尤研究中心的四个主要类别,发现传统的监测和生物方法受到选择性差、环境敏感性和不稳定性的限制。相比之下,这篇综述强调了人工智能驱动的模型和多源数据融合是关键的进步,显著提高了预测的准确性和及时性。未来的主要挑战是弥合复杂模型与强大的实时数据采集之间的差距。我们的结论是,未来的突破将取决于先进的传感器技术和多尺度耦合模型,从根本上将模式从被动修复转变为主动预防。
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引用次数: 0
Groundwater vulnerability assessment of the Djibouti aquifer system (East Africa Rift System): A comparative study of DRASTIC, Hybrid-DRASTICs, and DRASTIC-based multi-objective evolutionary algorithm 东非裂谷系吉布提含水层系统地下水脆弱性评价:DRASTIC、hybrid -DRASTIC和基于DRASTIC的多目标进化算法的比较研究
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-13 DOI: 10.1016/j.gsd.2025.101564
Mohamed Osman Awaleh , Golab Moussa Omar , Abdi-Basid Ibrahim Adan , Mohammad Najafzadeh , Christelle Marlin , Magued Al-Aghbary , Mohamed Abdillahi Robleh , Awaleh Djama Iltireh , Jafar Al-Jawad , Moussa Mohamed Waberi , Rachid Robleh Ragueh , Bahdon Elmi Ragueh , Omar Assowe Dabar , Moussa Mahdi Ahmed , Mahamoud Ali Chirdon , Abdillahi Elmi Adaneh , Nasri Hassan Ibrahim , Nima Moussa Egueh , Ismail Abdillahi Guireh , Omar Ibrahim Elmi
The comprehensive mapping of groundwater contamination zones is vital for sustainable water resource management, especially in underdeveloped countries facing urban and industrial pressures. This study investigates, for the first time, the groundwater vulnerability of the Djibouti aquifer system located in the north of the East Africa Rift System (EARS). This area, which is home to 72.8 % of the country's inhabitants, has been impacted by rapid urbanization including industrial activities and the discharge of untreated wastewater. This study compares multiple groundwater vulnerability modeling frameworks, including DRASTIC (Depth to groundwater, net Recharge, Aquifer media, Soil media, Topography, Impact of the vadose zone, and hydraulic Conductivity), DRASTIC–LULC (Land Use Land Cover), DRASTIC–AHP (Analytic Hierarchy Process), AHP–DRASTIC–LULC, DRASTIC–NSGA-II (Non-dominated Sorting Genetic Algorithm-II), and NSGA-II–DRASTIC–LULC. Spatial autocorrelation analysis (Moran's I > 0.95) has been used to improve the reliability and interpretability of the vulnerability maps. Groundwater vulnerability maps indicate that high and very high vulnerability zones (13.59–47.47 % and 1.02–21.70 %, respectively) are primarily located in the eastern and northern sectors. Moderate to low vulnerability zones (30.81–56.45 %) are prevalent in the central part of the study area. Sensitivity analysis identified key parameters such as aquifer depth, vadose zone impact, and aquifer medium. The LULC factors significantly improved model sensitivity and enabled better identification of at risk zones. The NSGA-II–DRASTIC–LULC model outperformed other modified DRASTIC methods, achieving a correlation of 0.58, an AUC of 0.84, and an RMSE of 1.13. These findings may provide a critical scientific basis for Djibouti's policymakers to prioritize land-use zoning and implement targeted protection measures in the identified high-risk zones, thereby securing a sustainable water future for the region's growing population.
地下水污染区的全面测绘对于可持续水资源管理至关重要,特别是在面临城市和工业压力的不发达国家。本文首次对位于东非裂谷系北部的吉布提含水层系统的地下水脆弱性进行了研究。该地区居住着全国72.8%的居民,受到快速城市化的影响,包括工业活动和未经处理的废水排放。本研究比较了DRASTIC(地下水深度、净补给、含水层介质、土壤介质、地形、渗透带影响和水力导电性)、DRASTIC - lulc(土地利用-土地覆盖)、DRASTIC - ahp(层次分析法)、AHP-DRASTIC-LULC、DRASTIC - nsga - ii(非支配排序遗传算法- ii)和NSGA-II-DRASTIC-LULC等多个地下水脆弱性建模框架。利用空间自相关分析(Moran's I > 0.95)提高脆弱性图的可靠性和可解释性。地下水脆弱性图显示,高、高脆弱性区(13.59 ~ 47.47%)和极高脆弱性区(1.02 ~ 21.70%)主要位于东部和北部。研究区中部普遍存在中、低易损区(30.81 ~ 56.45%)。敏感性分析确定了含水层深度、渗透带影响和含水层介质等关键参数。LULC因子显著提高了模型的敏感性,并能更好地识别风险区域。NSGA-II-DRASTIC-LULC模型优于其他改进的DRASTIC方法,相关系数为0.58,AUC为0.84,RMSE为1.13。这些发现可以为吉布提的政策制定者提供重要的科学依据,以确定土地利用分区的优先顺序,并在确定的高风险区域实施有针对性的保护措施,从而为该地区不断增长的人口确保可持续的水资源未来。
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Groundwater for Sustainable Development
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