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Mapping and modeling groundwater potential using machine learning, deep learning and ensemble learning models in the Saiss basin (Fez-Meknes region, Morocco) 在赛斯盆地(摩洛哥非斯-梅克内斯地区)利用机器学习、深度学习和集合学习模型绘制地下水潜力图并建立地下水潜力模型
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-09 DOI: 10.1016/j.gsd.2024.101281
Hind Ragragui , My Hachem Aouragh , Abdellah El-Hmaidi , Lamya Ouali , Jihane Saouita , Zineb Iallamen , Habiba Ousmana , Hajar Jaddi , Anas El Ouali

The Saïss basin in the Fez-Meknes region of Morocco, covering approximately 2100 km2, faces increased water demand due to population growth, economic development, and climate change, making groundwater a crucial resource. This study aims to delineate areas with groundwater potential (GWP) and evaluate the performance of various machine learning, deep learning, and hybrid ensemble models in predicting GWP. Using a dataset of 440 springs and wells, and 20 groundwater conditioning factors (GWCF) including topographical, hydrological, geological, and hydrogeological features, the study employed multi-collinearity analysis, variance inflation factor (VIF), tolerance (Tol) assessments, and an Information Gain (IG) test to analyze these factors. The study compared the performance of three machine learning algorithms (Gaussian Naive Bayes (GNB), k-Nearest Neighbors (KNN), Gradient Boosting Classifier (GBC)), three deep learning algorithms (Deep Learning Neural Networks (DLNN), Convolutional Neural Networks (CNN), Recurrent Neural Networks (RNN)), and a hybrid ensemble model (Random Forests (RF), Support Vector Machine (SVM), Logistic Regression (LR)) using the area under the receiver operating characteristic curve (ROC-AUC) as the evaluation metric. The results showed that the hybrid ensemble model had the highest AUC of 0.86, followed by GBC (AUC = 0.85), DLNN (AUC = 0.84), CNN (AUC = 0.83), KNN (AUC = 0.79), RNN (AUC = 0.78), and GNB (AUC = 0.75). The study revealed that 45% of the Saïss Basin exhibits high to very high GWP, particularly in Ain Taoujdat, Haj Kaddour, and Boufekrane districts, with lithology, slope, and transmissivity being the most influential factors. The resulting GWP map can guide decision-makers in planning well and borehole drilling for drinking water and agriculture, as well as artificial recharge projects, thus promoting sustainable groundwater management in the Saïss basin.

摩洛哥非斯-梅克内斯地区的塞斯盆地面积约 2100 平方公里,由于人口增长、经济发展和气候变化,该地区面临着日益增长的用水需求,地下水因此成为一种重要资源。本研究旨在划定具有地下水潜力(GWP)的区域,并评估各种机器学习、深度学习和混合集合模型在预测 GWP 方面的性能。该研究使用了一个包含 440 口泉水和水井以及 20 个地下水条件因子(GWCF)(包括地形、水文、地质和水文地质特征)的数据集,并采用了多重共线性分析、方差膨胀因子(VIF)、容忍度(Tol)评估和信息增益(IG)测试来分析这些因子。研究比较了三种机器学习算法(高斯直观贝叶斯算法(GNB)、k-最近邻算法(KNN)、梯度提升分类器(GBC))、三种深度学习算法(深度学习神经网络(DLNN)、卷积神经网络(CNN)、循环神经网络(RCN))的性能、以及一种混合集合模型(随机森林(RF)、支持向量机(SVM)、逻辑回归(LR)),使用接收器工作特征曲线下面积(ROC-AUC)作为评估指标。结果显示,混合集合模型的 AUC 最高,为 0.86,其次是 GBC(AUC = 0.85)、DLNN(AUC = 0.84)、CNN(AUC = 0.83)、KNN(AUC = 0.79)、RNN(AUC = 0.78)和 GNB(AUC = 0.75)。研究显示,萨伊斯盆地 45% 的地区显示出较高或极高的 GWP,尤其是在 Ain Taoujdat、Haj Kaddour 和 Boufekrane 地区,其中岩性、坡度和渗透率是影响最大的因素。由此绘制的全球升水潜能值地图可指导决策者规划饮用水和农业用水的打井和钻孔,以及人工补给项目,从而促进萨伊斯盆地的可持续地下水管理。
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引用次数: 0
Empowering community participation for sustainable rural water supply: Navigating water scarcity in Karak district Pakistan 增强社区参与可持续农村供水的能力:巴基斯坦卡拉克地区应对缺水问题
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-06 DOI: 10.1016/j.gsd.2024.101269
Abid Rasool , Sadia Saeed , Sareer Ahmad , Asif Iqbal , Amanat Ali

In the tapestry of life, water is the essential thread weaving through our existence. Imagine this thread not just as a simple element, but as the very pulse that sustains our communities. This study unravels the nuanced interplay between community engagement and sustainable water solutions in District Karak, shining a spotlight on a crucial but often overlooked aspect of rural water programs. Employing the theoretical framework of Social Capital Theory by Robert Putnam and Pierre Bourdieu, our research investigates the interconnected relationship between community participation and the long-term viability of water supply initiatives. Focusing randomly on three selected water supply schemes, we employed a sampling technique and collected data from 330 respondents through interviews. Community members, Community-Based Organizations (CBOs), and executing agencies were sampled to analyze the extent and impact of engagement across program phases. The findings underscore the pivotal role of participatory approaches facilitated by CBOs and executing agencies, revealing active community engagement as a linchpin for sustained water supply success. Results of the study reveal that the synergy of community satisfaction and engagement paves the way for a resilient water future, offering a blueprint for District Karak and similar regions to pursue a more secure water future and mitigate the adverse effects of water scarcity through the promotion of community participation.

在生命的织锦中,水是贯穿我们生存的重要丝线。想象一下,这根线不仅仅是一个简单的元素,而是维系我们社区的脉搏。本研究揭示了卡拉克地区社区参与和可持续水资源解决方案之间微妙的相互作用,聚焦于农村水资源项目中一个至关重要但往往被忽视的方面。我们的研究采用罗伯特-普特南(Robert Putnam)和皮埃尔-布尔迪厄(Pierre Bourdieu)的社会资本理论框架,调查了社区参与与供水项目长期可行性之间的相互关系。我们随机选取了三个供水计划,采用抽样技术,通过访谈收集了 330 名受访者的数据。我们对社区成员、社区组织(CBO)和执行机构进行了抽样调查,以分析各计划阶段的参与程度和影响。研究结果强调了由社区组织和执行机构推动的参与式方法的关键作用,揭示了积极的社区参与是持续供水成功的关键。研究结果表明,社区满意度和参与度的协同作用为未来恢复性供水铺平了道路,为卡拉克区和类似地区提供了一个蓝图,通过促进社区参与,追求更安全的未来供水,减轻缺水的不利影响。
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引用次数: 0
Hydrogeochemical processes, and health risk assessment of groundwater, in Santa María del rio aquifer: A case study of San Luis Potosí valley, Mexico Santa María del rio 含水层的水文地质化学过程和地下水健康风险评估:墨西哥圣路易斯波托西河谷的案例研究
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-05 DOI: 10.1016/j.gsd.2024.101268

The main objectives of this research were to the hydrogeochemical processes that control the groundwater chemistry, groundwater quality, and assessment of health risks of water. The drinking water that supplies the community of Santa María del Rio, S.L.P., comes from groundwater, in some municipality localities, groundwater Fluorine and arsenic are reported. Twenty-one representative groundwater samples were taken. Physicochemical parameters in situ: pH, OD, ORP, Alkalinity, STD, EC, Salinity, Total Coliforms, and E-coli, were analyzed, and in the laboratory, the heavy metals, metalloids and major constituents, cations: calcium, sodium, magnesium, and potassium, were determined by the ICP, and anions: chlorides, and sulfates, by colorimetry techniques. The results of the analyses were compared with the Mexican and EPA drinking water standards to verify their suitability and ensure that they do not exceed the permitted limit values. The results of the chemistry of the principal groundwater ions in the study area suggest that the main hydrogeochemical process that controls the variation of groundwater quality is the rock–water interaction. Groundwater has been classified into two hydrochemical facies, CaMgHCO3 and NaHCO3, consistent with the type of rock. The samples with the CaMg–HCO3 facie are associated with less evolved waters located in areas with local recharge. The dominant reactions in the aquifer are calcite, dolomite, and gypsum solutions. The presence of the N–NO3- ion is associated with agricultural and urban zone influence, which indicates that this activity has impacted the water quality. The risk index (HI) results show that values > 0.1 < 1 of HI, for Pb present low chronic risks for adults and children. In contrast, HI values > 4 for both population groups represent high chronic risk. Excessive use of fertilizers should be controlled in the study area to prevent groundwater contamination by heavy metals and metalloids and be measured regularly to check drinking water quality.

这项研究的主要目标是控制地下水化学的水文地质化学过程、地下水水质以及评估水的健康风险。Santa María del Rio, S.L.P. 社区的饮用水来自地下水,据报告,在一些城市地区,地下水中含有氟和砷。共采集了 21 个有代表性的地下水样本。在实验室中,采用 ICP 法测定重金属、类金属和主要成分,阳离子:钙、钠、镁和钾,阴离子:氯化物和硫酸盐,采用比色法。分析结果与墨西哥和美国环保署的饮用水标准进行了比较,以验证其适用性,并确保不超过允许的限值。研究区主要地下水离子的化学结果表明,控制地下水水质变化的主要水文地质化学过程是岩石与水的相互作用。根据岩石类型,地下水被分为 CaMgHCO3 和 NaHCO3 两种水化学类型。具有 CaMg-HCO3 面貌的样本与位于局部补给区的进化程度较低的水有关。含水层中的主要反应是方解石、白云石和石膏溶液。N-NO3- 离子的存在与农业和城市区域的影响有关,这表明这种活动对水质产生了影响。风险指数(HI)结果显示,铅的 HI 值为 0.1 和 1,对成人和儿童的慢性风险较低。相反,这两个人群的 HI 值为 4,则表示慢性风险较高。研究地区应控制化肥的过量使用,以防止地下水受到重金属和类金属的污染,并定期测量以检查饮用水水质。
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引用次数: 0
Land use and land cover patterns as a reflection of subsurface architecture groundwater quality in a large urban center (Varanasi) in the Ganges river basin, India 反映印度恒河流域一个大型城市中心(瓦拉纳西)地下建筑地下水质量的土地利用和土地覆盖模式
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-05 DOI: 10.1016/j.gsd.2024.101271
Oindrila Bose , Prerona Das , Ashok Shaw , Mrinal K. Layek , Martin Smith , Joy Sen , Probal Sengupta , Abhijit Mukherjee

Varanasi is an exponentially developing city in the Himalayan-sourced Ganges river basin. To understand the sustainable groundwater-sourced drinking water in Varanasi, it is essential to study the land use-land cover that reflects the surface geomorphology vis-a-vis sub-surface geology, and influence groundwater conditions. We incorporate lithological and groundwater data obtained from an extensive network of boreholes in and around the city at 110 sites, reaching a maximum depth of 100 m below ground level (bgl). The unconsolidated subsurface are primarily composed of sand, silt, clay, and gravel where, silty clay layer. Groundwater quality and stresses were determined through multi-dimensional hydrogeological approaches. The data were analyzed through multivariate statistics (Principal Component Analyses to identify the governing factor influencing the broad hydrogeochemistry. PC1 for urban areas has higher loading values for Fe, Cl compared to Semi-urban areas highlighting contamination by municipal wastewater. PC2 for urban areas shows higher loading values for Mg2+ and HCO3 compared to semi-urban areas. Due to heavy urbanization in Varanasi, the aquifer suffers substantial groundwater abstraction during particular times of the day compared to the agricultural lands. An increase of about 9% in built-up areas within a span of 10 years (2012–2022) poses a threat to the aquifer system of our study area, jeopardizing access to sustainable drinking water. With the expansion of urbanization and unregulated groundwater extraction, the vulnerability of the aquifer system will probably increase in the foreseeable future. Implementation of sustainable water management policies, engaging all economic sectors of the population in Varanasi, can expedite the process and safeguard the aquifer from attaining its emerging vulnerability. Thus, comprehending evolving groundwater risks through non-invasive methods like that discussed in the present study, holds significant promise for effectively targeting safe groundwater availability in future.

瓦拉纳西是喜马拉雅山脉源头恒河流域的一个快速发展城市。要了解瓦拉纳西的可持续地下水饮用水来源,就必须研究土地利用和土地覆盖情况,这反映了地表地貌与地下地质的关系,并对地下水条件产生影响。我们结合了从该市及其周边 110 个地点的广泛钻孔网络中获得的岩性和地下水数据,最大深度达到地下 100 米(bgl)。未固结地下主要由砂、粉砂、粘土和砾石组成,其中有淤泥质粘土层。地下水的水质和压力是通过多维水文地质方法确定的。通过多变量统计(主成分分析)对数据进行了分析,以确定影响广义水文地质化学的主要因素。与半城市地区相比,城市地区 PC1 的铁、Cl- 负荷值较高,这突出表明受到城市污水的污染。与半城市地区相比,城市地区的 PC2 显示出更高的 Mg2+ 和 HCO3- 负载值。由于瓦拉纳西的城市化程度很高,与农田相比,含水层在一天中的特定时间段会被大量抽取地下水。在 10 年内(2012-2022 年),建成区面积将增加约 9%,这对我们研究地区的含水层系统构成威胁,危及可持续饮用水的获取。随着城市化的扩张和地下水开采的无序进行,在可预见的未来,含水层系统的脆弱性可能会加剧。实施可持续的水资源管理政策,让瓦拉纳西所有经济部门的居民都参与进来,可以加快这一进程,并保护含水层,使其不再变得脆弱。因此,通过非侵入性方法(如本研究中讨论的方法)了解不断变化的地下水风险,为今后有效地确定安全的地下水供应目标带来了巨大希望。
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引用次数: 0
Groundwater hydro-geochemical inferences and eXplainable Artificial Intelligence augmented groundwater quality prediction in arid and semi-arid segment of Rajasthan, India 印度拉贾斯坦邦干旱和半干旱地区的地下水水文地球化学推断和可扩展人工智能地下水质量预测
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-04 DOI: 10.1016/j.gsd.2024.101272
Sunita , Tathagata Ghosh

Groundwater quality is a crucial aspect especially in the arid and semi-arid segments of the world due to its restricted availability. With increasing consumptions over time period, it is essential to ensure its quality by appraising complex hydro-geochemistry. In the present study, an attempt has been made to evaluate the groundwater hydro-geochemistry in the arid and semi-arid segment of Rajasthan, India and to fill the gap in understanding of groundwater quality by incorporating eXplainable Artificial Intelligence (XAI). 120 groundwater samples were collected during post monsoon season of 2022 and sixteen physico-chemical parameters were analyzed and corresponding inferences were drawn. The hydro-chemical facies indicated Na–Cl composition of groundwater with the dominance of evaporation. Majority of the samples showed reverse ion exchange process along with positive Saturation Index value of Calcite (CaCO3) and tendency towards leaching F in the groundwater. Water Quality Index for drinking as well as irrigation purpose showed relatively better quality in the central segment than the marginal region. The SHAP values derived from the XGBoost model depicted fluoride (F-) as the primary feature influencing overall groundwater quality for drinking purposes, whereas the Sodium Absorption Ratio (SAR) emerged as the key predictor influencing overall groundwater quality for irrigation. The implication of proposed method signifies the importance of incorporating hydro-geochemical inferences with machine learning technique to understand the complex character of groundwater. Further, due to its robustness as well as cost-effectiveness, the application of the method would be helpful in policymaking to safeguard the groundwater resource in arid and semi-arid regions at global scale.

由于地下水供应有限,地下水质量是一个至关重要的方面,尤其是在世界上的干旱和半干旱地区。随着消耗量的不断增加,必须通过评估复杂的水文地球化学来确保地下水的质量。本研究试图对印度拉贾斯坦邦干旱和半干旱地区的地下水水文地球化学进行评估,并通过结合可扩展人工智能(XAI)填补对地下水质量了解的空白。在 2022 年季风后季节收集了 120 个地下水样本,分析了 16 个物理化学参数,并得出了相应的推论。水化学面表明,地下水的成分为 Na-Cl,以蒸发为主。大部分样本显示了反向离子交换过程,方解石(CaCO3)饱和度指数值为正,地下水有沥滤 F- 的趋势。用于饮用和灌溉的水质指数显示,中部地区的水质相对好于边缘地区。根据 XGBoost 模型得出的 SHAP 值显示,氟化物(F-)是影响饮用地下水总体水质的主要特征,而钠吸收比(SAR)则是影响灌溉地下水总体水质的关键预测因子。所提出方法的意义表明,将水文地球化学推断与机器学习技术相结合,对于了解地下水的复杂特性非常重要。此外,由于其稳健性和成本效益,该方法的应用将有助于在全球范围内制定政策,保护干旱和半干旱地区的地下水资源。
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引用次数: 0
Optimizing performance efficiency of algal-bacterial-based wastewater treatment system using response surface methodology 利用响应面方法优化藻类-细菌废水处理系统的性能效率
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-04 DOI: 10.1016/j.gsd.2024.101273
Samar A. El-Mekkawi , Sayeda M. Abdo , Marwa A. Youssef , Gamila H. Ali

Developing wastewater treatment technologies is crucial for enhancing treatment efficiency and promoting the reuse of treated water. In this article, the Algal-Bacterial integrated system (ABIS) is employed to treat municipal wastewater collected from the Zenin wastewater treatment plant in Giza governorate, Egypt. This system relies on the synergy between heterotrophic bacteria and microalgae to form a biofilm capable of absorbing contaminants from the wastewater. The main objective of this study is to optimize the factors influencing the treatment efficiency using response surface methodology derived from the experimental design software of Design Expert 6.0.8. The optimal results revealed that using an absorber amount of 0.18 g/L for a hydraulic retention time of 1.4 d provides removal efficiency of BOD, COD, TSS, and turbidity are 88.57%, 82.7 %, 94.90%, and 95.91%, respectively. These findings were experimentally and statistically verified with an accuracy exceeding a 95% confidence interval and 95% prediction interval. The physicochemical characteristics, algal community structure, as well as the density of total coliform, fecal coliform, and Escherichia coli (E. coli), were determined for the treated wastewater and compared to the Egyptian code of practice for the use of treated municipal wastewater for agricultural purposes to assess its suitability for unrestricted irrigation.

开发废水处理技术对于提高处理效率和促进处理后水的再利用至关重要。本文采用藻类细菌综合系统 (ABIS) 处理从埃及吉萨省泽宁污水处理厂收集的城市污水。该系统依靠异养细菌和微藻之间的协同作用形成生物膜,能够吸收废水中的污染物。本研究的主要目的是利用 Design Expert 6.0.8 实验设计软件中的响应面方法优化影响处理效率的因素。优化结果表明,在水力停留时间为 1.4 d 时,吸收剂用量为 0.18 g/L,对 BOD、COD、TSS 和浊度的去除率分别为 88.57%、82.7%、94.90% 和 95.91%。这些结果经过实验和统计验证,准确率超过了 95% 的置信区间和 95% 的预测区间。对处理后废水的理化特性、藻类群落结构以及总大肠菌群、粪大肠菌群和大肠埃希氏菌(E. coli)的密度进行了测定,并与埃及将处理后的城市污水用于农业目的的操作规范进行了比较,以评估其是否适合用于无限制灌溉。
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引用次数: 0
Assessment of the vulnerability of groundwater quality with respect to aluminum on crystalline bedrock under temperate climate conditions 评估温带气候条件下结晶基岩上铝对地下水水质的脆弱性
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-02 DOI: 10.1016/j.gsd.2024.101256
Juliette Rougerie , Rémy Buzier , Valentin Robin , François Bordas , Anne Da Silva , Julie Leblanc , Delphine Devillers , Patrice Fondanèche , Karine Cleriès , Emmanuelle Ducloux , Marc Rateau , Lauriane Boulp , Gilles Guibaud

Despite meeting legal standards, drinking water quality in sparsely populated areas with scattered groundwater resources in medium mountain ranges may be compromised. This results from inaccurate assessments of human activities, such as forest exploitation, on groundwater intake watersheds or insufficient monitoring frequency to understand their full impact on groundwater quality. This study involved a 3-year monthly monitoring of 18 groundwater intakes for drinking water supply, situated in areas with crystalline bedrocks, a temperate climate, and surrounded by forest exploitation. The quality of groundwater collected from alterites up to 15 m deep was evaluated over time. The correlation between the groundwater physico-chemical parameters (measured through 382 samples between March 2017 and December 2020) and the groundwater intakes’ environment - such as the geological and pedological context, land use, climate, and depth of drains - was investigated to understand their potential impact on groundwater quality. This study revealed a significant degradation in shallow groundwater quality (up to 5 m deep) concerning dissolved aluminum (concentration up to 2 mg L−1), which results from land use and is climate dependent. Indeed, dissolved aluminum concentrations in groundwater can be correlated with the pH of the upper soil horizons, which are mostly impacted by forestry practices, as well as with rainfall events. The results of this study highlight that by integrating efforts to preserve the soil and change forestry practices (e.g., selective logging, avoiding rapid rotations), more efficient protection of groundwater quality can be achieved in the context of acidic soils present on crystalline bedrock.

尽管符合法定标准,但在人口稀少、地下水资源分散的中山脉地区,饮用水水质可能会受到影响。这是因为人类活动(如森林开采)对地下水取水流域的影响评估不准确,或者监测频率不足,无法全面了解人类活动对地下水水质的影响。这项研究对 18 个饮用水取水口进行了为期 3 年的月度监测,这些取水口位于结晶基岩地区,气候温和,周围有森林开发。对从最深 15 米的地下采集的地下水水质进行了长期评估。研究了地下水物理化学参数(通过 2017 年 3 月至 2020 年 12 月期间的 382 个样本测量)与地下水取水口环境(如地质和土壤环境、土地利用、气候和排水沟深度)之间的相关性,以了解它们对地下水质量的潜在影响。这项研究显示,浅层地下水(最深 5 米)的溶解铝(浓度最高达 2 毫克/升)质量明显下降,这是土地利用和气候造成的。事实上,地下水中的溶解铝浓度与上层土壤的 pH 值(主要受林业活动的影响)以及降雨事件相关。这项研究的结果突出表明,在结晶基岩上存在酸性土壤的情况下,通过将保护土壤和改变林业实践(如选择性采伐、避免快速轮伐)结合起来,可以更有效地保护地下水水质。
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引用次数: 0
Microplastics and nanoplastics in environment: Sampling, characterization and analytical methods 环境中的微塑料和纳米塑料:取样、表征和分析方法
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-01 DOI: 10.1016/j.gsd.2024.101267
Sarbanee Mahapatra , Jyoti Prakash Maity , Shuvendu Singha , Tanisha Mishra , Gobinda Dey , Alok Chandra Samal , Pritam Banerjee , Chhanda Biswas , Sourasis Chattopadhyay , Rasmi Ranjan Patra , Sneha Patnaik , Prosun Bhattacharya

Microplastics (MPs) and nanoplastics (NPs) have gained increasing attention in environmental research due to their ubiquitousness and potential impacts on natural environments and human health as per the UN Sustainable Development Goals (SDGs), particularly SDG-14 to address global threats where at least 12 SDGs, directly/indirectly impacts. Present review is undertaken to highlight the process of breakdown of diverse groups of plastic products in soil, surface water, and groundwater under the influence of different factors (UV, light, heat, microbe, etc.), which are mobilized as MPs/NPs to the surface water, groundwater, air, soil, and living organisms by different natural and anthropogenic processes. Review also highlights a comprehensive overview of the methodology for sampling, characterization, and analysis for these minuscule plastic particles (PPs) in various environmental samples, encompassing surface/subsurface water, sediments, soils, and biological organisms. The collection, extraction, and characterization of MPs/NPs, typically employ filtration processes, wherein a known volume of water is passed through a fine mesh to capture MPs/NPs from water samples. Sediment/soil samples require sieving and density separation techniques to isolate PPs from the surrounding matrix. Biological samples require digestion steps to remove organic matter, leaving behind plastics for analysis. Fourier-transform infrared (FTIR) spectroscopy, Raman spectroscopy, and scanning electron microscopy (SEM) are commonly utilized to determine the polymer composition, size, shape, and surface characteristics of PPs. Quantification involves several approaches, visual counting, image analysis, and spectroscopic techniques. Abundance of MPs/NPs in the respective environmental samples (water, air, soil, etc.) can be determined by comparing the richness (i.e., number/mass) of plastics to the volume or weight of the original sample. Such comprehensive analytical methodologies contribute to understand the scope and magnitude of plastic pollution and its potential repercussions for ecosystems and human well-being, which are essential for developing the effective strategies to mitigate these pressing global environmental challenges for sustainable development.

微塑料(MPs)和纳米塑料(NPs)无处不在,对自然环境和人类健康具有潜在影响,因此在环境研究中日益受到关注,这也符合联合国可持续发展目标(SDGs)的要求,特别是 SDG-14,即解决至少 12 项 SDGs 直接/间接影响的全球威胁。本综述旨在强调在不同因素(紫外线、光、热、微生物等)的影响下,土壤、地表水和地下水中各种塑料制品的分解过程,这些塑料制品通过不同的自然和人为过程,以 MPs/NPs 的形式迁移到地表水、地下水、空气、土壤和生物体中。综述还重点介绍了对各种环境样本(包括地表/地下水、沉积物、土壤和生物有机体)中这些微小塑料颗粒(PPs)进行取样、表征和分析的方法。MPs/NPs的收集、提取和表征通常采用过滤工艺,即将已知体积的水通过细网,从水样中捕捉MPs/NPs。沉积物/土壤样本需要筛分和密度分离技术,以便从周围的基质中分离出 PPs。生物样本需要消化步骤去除有机物,留下塑料供分析。傅立叶变换红外光谱(FTIR)、拉曼光谱和扫描电子显微镜(SEM)通常用于确定聚丙烯的聚合物成分、大小、形状和表面特征。定量方法包括目视计数、图像分析和光谱技术。通过比较塑料的富集度(即数量/质量)与原始样本的体积或重量,可确定相应环境样本(水、空气、土壤等)中 MPs/NPs 的富集度。此类综合分析方法有助于了解塑料污染的范围和严重程度及其对生态系统和人类福祉的潜在影响,这对于制定有效战略以缓解这些紧迫的全球环境挑战、促进可持续发展至关重要。
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引用次数: 0
Integration of remote sensing, geochemical modeling, and isotopic constraints for the detection of promising groundwater zones in arid regions. A study in Qena- Luxor area, Egypt 整合遥感、地球化学建模和同位素约束条件,探测干旱地区有潜力的地下水区。对埃及克纳-卢克索地区的研究
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-01 DOI: 10.1016/j.gsd.2024.101266
Mohamed Hassan Ramzy , Mustafa Eissa , Shaimaa M. El-Hadidy , Samah Mahmoud Morsy

The renewable groundwater resources in Egypt are restricted close to the Nile River. In the study area, two major water bearings are near the Nile: The Quaternary and the Eocene aquifers. Remote sensing (ASTER DEM, Landsat-8, and Sentinal-1 InSAR images), geochemical modeling, and isotopic constraints (δ18O and δ2H) were employed and integrated with the GIS framework for delineating the low saline and sustainable groundwater zones. Remote sensing data indicates intensive structure lineaments in the middle-eastward part, spatially congruent with subsurface features deduced from radar satellites, facilitating hydraulic connections with the Nile water. The soil moisture index, land surface temperature, and salinity index in irrigated areas, reveal a strong association between in situ electrical conductivity values and satellite-derived spectral indices. The higher groundwater salinity in the middle eastern region coincided with high lineament density zones, and higher temperature zones, leading to increased rock water interaction that leads to groundwater salinization. The isotopic composition of the Quaternary aquifer ranges between −1.30 ‰ and +5.53 ‰ for δ18O, while δ2H ranges between −11.49 ‰ and +34.47 ‰. In the Eocene aquifer, δ18O ranges between −0.46 and +3.45 ‰, while the δ2H ranges between −3.16 ‰ and +23.50 ‰, indicating subsurface recharge from the Nile water. The simulation of the mass transport geochemical NETPATH model revealed mixing ratios from the Nile water ranging from 3.4% to 93.7%. Based on the results, the area is classified into four classes, class (1) represents samples of high conduit with Nile water (<50% mixing), class (2) represents samples of moderate conduit with Nile water (10–50% mixing), class (3) represents samples of low conduit with Nile water (<1–10% mixing), class (4) represents samples of water-rock interaction. The findings would be of great importance for delineating sustainable zones of the Nile Valley aquifers.

埃及的可再生地下水资源仅限于尼罗河附近。在研究地区,尼罗河附近有两个主要的水源承载层:第四纪含水层和始新世含水层。研究采用了遥感技术(ASTER DEM、Landsat-8 和 Sentinal-1 InSAR 图像)、地球化学建模和同位素约束(δ18O 和 δ2H),并与地理信息系统框架相结合,以划定低盐度和可持续地下水区。遥感数据表明,中东部有密集的结构线形,与雷达卫星推断的地下特征在空间上一致,有利于与尼罗河水的水力联系。灌溉区的土壤水分指数、地表温度和盐度指数显示,原地电导率值与卫星光谱指数之间存在密切联系。中东部地区较高的地下水盐度与高线密度区和较高温度区相吻合,导致岩石与水的相互作用加剧,从而导致地下水盐化。第四纪含水层的同位素组成中,δ18O介于-1.30 ‰和+5.53 ‰之间,δ2H介于-11.49 ‰和+34.47 ‰之间。在始新世含水层中,δ18O介于-0.46和+3.45‰之间,而δ2H介于-3.16和+23.50‰之间,这表明地下有尼罗河水补给。质量输运地球化学 NETPATH 模型模拟显示,尼罗河水的混合比在 3.4% 至 93.7% 之间。根据研究结果,该地区被划分为四个等级,等级(1)代表尼罗河水的高导流样本(混合率 50%),等级(2)代表尼罗河水的中等导流样本(混合率 10-50%),等级(3)代表尼罗河水的低导流样本(混合率 1-10%),等级(4)代表水岩相互作用样本。这些发现对于划定尼罗河谷含水层的可持续发展区具有重要意义。
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引用次数: 0
Performance evaluation and mechanism of Al2O3/TiO2 sorbents for fluoride remediation in groundwater 用于地下水氟化物修复的 Al2O3/TiO2 吸附剂的性能评估和机理研究
IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-06-29 DOI: 10.1016/j.gsd.2024.101259
Gabriel T. Colledge, John G. Outram, Graeme J. Millar

Excessive fluoride levels in drinking water are problematic in several countries, particularly those which are relatively poor. Thus, there is a need to create cost effective sorbents which can easily be applied to make the water safe to use. Therefore, this study focussed on Al2O3/TiO2 sorbents which appear to address issues with commercially available alumina such as aluminium dissolution. Adjusting the alumina/titania ratio significantly influenced not only the fluoride uptake capacity but also the uptake of a wide range of contaminants found in groundwater. The exchange kinetics were relatively fast regardless of mixed oxide composition with equilibrium obtained within 6 h. Equilibrium isotherms were unfavourable for fluoride removal where titania compositions were dominant. In contrast, favourable isotherms were noted when alumina was the dominant oxide present. Barium, calcium, strontium, boron, iron, manganese, zinc, potassium, lithium, and silica were all substantially removed by varying the alumina/silica ratio in the sorbent. This behaviour may be valuable for broader remediation of dissolved species in groundwater (not just fluoride). Based upon the tests data a 70% Al2O3 – 30% TiO2 material was recommended to be the preferred composition for comprehensive treatment of groundwater. The sorbents appeared to comprise of alumina and titania with surface areas between 129 and 255 m2/g. There was no evidence for new oxide phases nor for a relationship between surface area and performance. Mechanistically both ion exchange and surface complexation may occur when treating groundwater.

在一些国家,尤其是相对贫穷的国家,饮用水中氟含量过高是个问题。因此,有必要开发出成本效益高、易于应用的吸附剂,以确保水的安全使用。因此,本研究重点关注 Al2O3/TiO2 吸附剂,它似乎可以解决市售氧化铝的问题,如铝溶解问题。调整氧化铝/二氧化钛的比例不仅会显著影响氟的吸收能力,还会影响对地下水中多种污染物的吸收。在二氧化钛成分占主导地位的情况下,平衡等温线不利于氟的去除。相反,当氧化铝是主要的氧化物时,平衡等温线是有利的。通过改变吸附剂中氧化铝/二氧化硅的比例,钡、钙、锶、硼、铁、锰、锌、钾、锂和二氧化硅都被大量去除。这种特性对于更广泛地修复地下水中的溶解物种(不仅仅是氟化物)可能很有价值。根据测试数据,建议采用 70%Al2O3 - 30% TiO2 材料作为综合处理地下水的首选成分。吸附剂似乎由氧化铝和二氧化钛组成,表面积在 129 至 255 平方米/克之间。没有证据表明存在新的氧化物相,也没有证据表明表面积与性能之间存在关系。从机理上讲,处理地下水时可能会发生离子交换和表面络合。
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引用次数: 0
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Groundwater for Sustainable Development
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