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Role of PVA Flakes in Promoting Self-Degradation of Sodium Metasilicate-Activated Cement under a Hydrothermal Environment at 150°C 150℃水热环境下PVA薄片促进偏硅酸钠活化水泥自降解的作用
Pub Date : 2013-11-28 DOI: 10.6000/1929-6002.2013.02.04.6
T. Sugama, T. Pyatina, A. Muraca
We investigated the effect of flakes of polyvinyl alcohol (PVA) on the self-degradation of sodium metasilicate (SMS)-activated slag/Class C fly ash cement, which is used as temporary sealer for fractures in Enhanced Geothermal System (EGS) wells under a hydrothermal environment at ³150°C and at pressure of 1000 psi. The reactions between PVA and SMS dissolved in an aqueous medium at 85°C led to the formation of a colloidal hydroxylated silicate-cross-linked PVA gel in the cement body. This gel-incorporated cement had a compressive strength >2000 psi, so ensuring that it adequately plugs the fractures. Increasing the hydrothermal temperature to ³150°C triggered the transformation of the gel into a sol. This in-situ gel®sol phase transition played a pivotal role in promoting the cement’s self-degradation because of the extensive spreading of sol in the cement body, and its leaching from the cement. In contrast, when gel was dry heated at ³150°C, the gel®xerogel phase transformation engendered the molecular fragmentation of PVA. This fragmentation yielded polysilicate cross-linked PVA derived from the combination of extended-chain scission, carboxylation and condensation, so that it no longer served as a self-degrading promoter of cement..
研究了聚乙烯醇(PVA)片对偏硅酸钠(SMS)活性矿渣/C类粉煤灰水泥自降解的影响,该水泥在³150°C和1000 psi的热液环境下用于增强型地热系统(EGS)井的裂缝临时密封。在85°C的水溶液中溶解PVA和SMS之间的反应导致在水泥体中形成胶体羟基化硅酸盐交联PVA凝胶。这种凝胶水泥的抗压强度大于2000psi,因此可以确保其充分封堵裂缝。当水热温度升高到³150°C时,凝胶转变为溶胶。由于溶胶在水泥体内广泛扩散,并从水泥中浸出,这种原位gel®溶胶相变对促进水泥的自降解起着关键作用。相反,当凝胶在³150°C下干燥加热时,gel®干凝胶相变导致PVA分子破碎。这种破碎产生了聚硅酸交联的PVA,它是由延伸链断裂、羧基化和缩合结合而成的,因此它不再作为水泥的自降解促进剂。
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引用次数: 3
Biomass Production for Energy in India: Review 印度生物质能源生产:综述
Pub Date : 2013-11-28 DOI: 10.6000/1929-6002.2013.02.04.7
Rashad A. Hegazy
This paper presents a general view about biomass production in India and its potential energy for use in different fields. India has tremendous potential for energy generation through biomass and its residues. Biomass energy is normally produced from firewood, agricultural residues such as bagasse, crop stalks, animal dung and wastes generated from agro-based industries. With the estimated and predicted values, the generating power from the surplus biomass in India was significant and it will continue to be more effective in future. Residue use as a fuel in India is estimated to be 216 Mt as projected value in 2010, recently, around 605 MW of electricity is being produced from biomass firing and 720 MW from cogeneration activities for residue. About 185 Mt (40%) of the dung collected is used as fuel in cook stoves. The potential for biogas production annually is 8750 million m 3 from 251 Mt of dung. The amount of fuel-wood consumption during year 2004 was 205 million tonnes used as fuel for traditional cook stoves with low efficiency, 16 Mt used in industrial sector producing 10 PJ, and it was estimated that the production of fuel wood and charcoal increased to the rate of 1.98 per cent per annum. The total quantity of solid wastes generated in larger towns and cities has been estimated at 40 Mt in 2001, and in 2005 the average MSW generation in overall India was approximately 100,000 Mt/day. For the wastewater in India, in 2010, the energy estimated to be around 3929.8 TJ as energy value of CH4.
本文介绍了印度生物质生产的总体情况及其在不同领域使用的潜在能源。印度在利用生物质能及其残留物发电方面具有巨大潜力。生物质能源通常是由木柴、蔗渣等农业残留物、农作物秸秆、动物粪便和农业工业产生的废物生产的。根据估计值和预测值,印度的剩余生物质发电是显着的,并且在未来将继续更加有效。根据2010年的预测值,印度的渣滓燃料使用量估计为2.16亿吨,最近,大约605兆瓦的电力来自生物质燃烧,720兆瓦来自渣滓热电联产活动。收集的约185公吨(40%)的粪便被用作炉灶的燃料。每年从2.51亿吨粪便中生产沼气的潜力为87.5亿立方米。2004年的薪柴消耗量为2.05亿吨,用作低效率的传统炉灶的燃料,1600万吨用于生产10 PJ的工业部门,据估计,薪柴和木炭的产量以每年1.98%的速度增长。2001年,较大城镇和城市产生的固体废物总量估计为4000万吨,2005年,整个印度的平均城市生活垃圾产生量约为每天10万吨。对于印度的废水,2010年CH4的能量值估计在3929.8 TJ左右。
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引用次数: 5
The Impact of Gasfier Stoves Use on Socio-Economic and Environment in Tanzania: The Case of Arusha and Moshi Municipalities 坦桑尼亚使用煤气炉对社会经济和环境的影响:以阿鲁沙和莫希市为例
Pub Date : 2013-11-28 DOI: 10.6000/1929-6002.2013.02.04.3
A. Mwakaje
This study examined the socio-economic and environmental impact of the adoption of gasfier stoves by households in Arusha and Moshi towns in Tanzania. A total of 55 respondents were selected purposely from the gasfier stoves. For comparative purposes another 55 charcoal users were selected randomly for interview making a total sample of 110. There were also focus group consultations and key informant interviews. Structured and semi-structured questionnaires were used to collect data, which were analysed using the Statistical Package for Social Sciences. The results show that the respondents who were using gasfier stoves had significant reduction (p=0.001) in the cost of energy for cooking compared to charcoal stove users by spending only T.shs 13,396 per month compared to T.shs 36,932 for charcoal users. The use of gasfier stoves also had a positive impact on the environment. Findings show that by using gasfier stoves 15.4 ha were saved from deforestation per annum and about 365.4.tonnes of carbon were saved for sequestration an act that reduces carbon emissions and global warming. Nevertheless, despite the impressive performance of gasfier stoves for cooking, the rate of adoption has remained low. The main reason for this was reported to be the high price, poor quality of the pellets and unfriendly usability. The adoption of gasfier stoves could only be enhanced by addressing these constraining factors.
这项研究审查了坦桑尼亚阿鲁沙和莫希镇家庭采用煤气炉所产生的社会经济和环境影响。共有55名受访者是特意从气化炉中挑选出来的。为了比较起见,随机选择另外55名木炭使用者进行访谈,使总样本为110。还进行了焦点小组协商和主要资料提供者访谈。使用结构化和半结构化问卷收集数据,并使用社会科学统计软件包对数据进行分析。结果表明,与使用木炭炉的受访者相比,使用气化炉的受访者在烹饪能源成本方面显著降低(p=0.001),每月仅花费13,396先令,而使用木炭炉的受访者每月仅花费36,932先令。气化炉的使用也对环境产生了积极影响。调查结果表明,通过使用气化炉,每年可节省15.4公顷的森林,约365.4公顷。成吨的碳被封存,这一行为减少了碳排放和全球变暖。然而,尽管用于烹饪的气化炉的性能令人印象深刻,但采用率仍然很低。据报道,造成这种情况的主要原因是价格高、颗粒质量差和不友好的可用性。只有解决这些制约因素,才能促进气化炉的采用。
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引用次数: 2
Biohydrogen Production Using Immobilized Cells of Hyperthermophilic Eubacterium Thermotoga neapolitana on Porous Glass Beads 在多孔玻璃微珠上固定化超嗜热真细菌产氢
Pub Date : 2013-08-31 DOI: 10.6000/1929-6002.2013.02.03.4
T. Ngo, H. T. N. Bui
Biohydrogen fermentation using immobilized cells of Thermotoga neapolitana on porous glass beads was successfully performed in a continuously stirring anaerobic bioreactor (CSABR) system operated under the conditions of temperature 75 o C, pH 7.0 and 5.0 g/L pentose (xylose) and/or hexose (glucose). The results showed that both batch and fed-batch cultivations of the immobilized cells were effective for high-rate and high-yield H 2 production compared with those from the free cells. In the batch cultivation, the H 2 production rate and H 2 production yield of the immobilized cells, respectively achieved the highest values of 5.64 ± 0.19 mmol-H 2 L -1 h -1 and 1.84 ± 0.1 mol H 2 /mol xylose, which were almost 1.7-fold and 1.3-fold higher than those with free cells. The maximum H 2 production rate ­ (6.91 mmol L -1 h -1 ) in this proposed method was 1.5-fold higher than that of free cells in the fed-batch cultivation.
在连续搅拌厌氧生物反应器(CSABR)系统中,在温度75℃,pH 7.0和5.0 g/L戊糖(木糖)和/或己糖(葡萄糖)的条件下,成功地利用固定化热toga neapolitana细胞在多孔玻璃微珠上进行了生物氢发酵。结果表明,与游离细胞相比,固定化细胞分批培养和补料分批培养均能产生高效率高产的h2。在批量培养中,固定化细胞的H产率和H产率最高,分别为5.64±0.19 mmol-H 2 L -1 H -1和1.84±0.1 mol H 2 /mol木糖,分别是游离细胞的1.7倍和1.3倍。该方法的最大产氢率- (6.91 mmol L -1 H -1)比分批喂料培养的游离细胞高1.5倍。
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引用次数: 13
An Overview of the Downdraft Rice Husk Gasifier Technology for Thermal and Power Applications 下吸式稻壳气化炉热力与电力应用技术综述
Pub Date : 2013-08-31 DOI: 10.6000/1929-6002.2013.02.03.6
A. Belonio, J. Ramos, M. Regalado, Victoriano B. Ocon
An overview of the downdraft rice husk gasifier (DDRHG) for thermal and power applications is herein presented. The different designs of the downdraft rice husk gasifier with reactor diameter ranging from 0.10 meter to 1.20 meter are discussed in detail. Smaller units of the DDRHG were found to have performed well in fixed bed. Larger units of the gasifier, on the other hand, are suited for moving-bed type making possible continuous operation without discharging and recharging the reactor. Present thermal applications of the gasifier includes: domestic cookstove, bakery oven, dryers, rotary kiln, steam boiler, and torrefyer. The DDRHG is also used to run surplus gasoline engines for driving water pump, micro-mill, and electric generator without any modification. The advantages and limitations of the gasifier as well as its environmental and socio-economic benefits over the use of conventional fossil-fueled systems are enumerated. At present, the investment cost for the gasifier ranges from PHP2,000 to 2,500.00 (USD 1 = PHP40.00) per kWt for thermal application and PHP20,000.00 to 30,000 per kWe for power generation. The cost of using the gasifier is much cheaper than that of the conventional fossil fuel and the investment can be recovered in a shorter period.
概述了下吸式稻壳气化炉(DDRHG)的热力和电力应用。详细讨论了反应器直径为0.10 ~ 1.20 m的下吸式稻壳气化炉的不同设计方案。较小的DDRHG单元在固定床上表现良好。另一方面,较大的气化炉单元适合于移动床型,使连续操作成为可能,而无需对反应器进行放电和充电。目前气化炉的热应用包括:家用炉灶、烘干机、烘干机、回转窑、蒸汽锅炉和蒸发器。DDRHG还可以不经任何改造,带动水泵、微磨机、发电机等剩余汽油发动机。列举了气化炉的优点和局限性以及与使用传统化石燃料系统相比的环境和社会经济效益。目前,气化炉的投资成本为每千瓦时2,000至2,500菲律宾比索(1美元= 40菲律宾比索),每千瓦时发电20,000至30,000菲律宾比索。使用该气化炉的成本比传统化石燃料的成本低得多,而且投资可以在较短的时间内收回。
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引用次数: 0
Prospects of Rice Husk Gasification for Power Generation in Bangladesh 稻壳气化发电在孟加拉国的前景
Pub Date : 2013-08-31 DOI: 10.6000/1929-6002.2013.02.03.7
Barun Das, N. Mustafi, S. Hoque
Electricity is the basic requirement to promote socio-economic development. In recent years, Bangladesh is facing severe power crisis all over the country, but the rural areas are the most vulnerable. This acute electricity crisis along with the conventional fuel crunch is affecting every sector of the country and economy is being crippled. To reduce the dependency on fossil fuels, rice husk which are widely abundant agricultural waste from rice industry could play a vital role in this regards. Bangladesh is an agricultural country and produces huge quantity of rice every year. In the year 2011, the total rice production was around 50.63 million tones. Husk is the waste biomass produce during the rice processing, on average it accounts around 20% of the rice produced on weight basis (10.12 million tones). The potential of power generation from rice husk by gasification is around 310 MWe in Bangladesh. The power plant to be installed near the large rice mills `cluster areas’ in Dinajpur, Bogra, Naogaon, Chapainawabganj and Ishwardi with the surplus rice husk. This paper consolidates information from various studies on the availability of rice husk, its characterization and estimates possible power potential that can be realized.
电力是推动社会经济发展的基本要求。近年来,孟加拉国全国各地都面临着严重的电力危机,但农村地区是最脆弱的。这种严重的电力危机以及传统的燃料短缺正在影响该国的每个部门,经济正在瘫痪。为了减少对化石燃料的依赖,稻壳作为稻米工业中广泛存在的农业废弃物可以在这方面发挥至关重要的作用。孟加拉国是一个农业国家,每年生产大量的大米。2011年,水稻总产量约为5063万吨。稻壳是大米加工过程中产生的废弃生物质,平均占大米产量的20%左右(1012万吨)。在孟加拉国,稻壳气化发电的潜力约为310兆瓦。该发电厂将安装在位于Dinajpur、Bogra、Naogaon、Chapainawabganj和Ishwardi的大型碾米厂聚集区附近,处理剩余的稻壳。本文综合了各种关于稻壳可利用性、稻壳特性的研究资料,并估计了可能实现的电力潜力。
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引用次数: 2
Effect of Bacterial Invasion on the Growth and Lipid Production of the Oleaginous Yeast Rhodotorula glutinis 细菌入侵对产油酵母粘红酵母生长和产脂的影响
Pub Date : 2013-08-31 DOI: 10.6000/1929-6002.2013.02.03.3
M. Harkins, Daniel E. Lou-Hing, Lisa A. Sargeant, C. Chuck
Oleaginous microbes, grown heterotrophically on sugars derived from non-food crops or waste resources, are a renewable source of lipids. However, these cultures are prone to bacterial invasion. Ensuring optimal sterile conditions requires expensive pre-treatment techniques and has significant ramifications for the industrial-scale production of lipid derived biofuels, though, at present, it is unclear what effect a bacterial invasion would have on the organisms ability to accumulate lipid. In this investigation, the oleaginous yeast Rhodotorula glutinis ( R. glutinis ) was cultured under optimal conditions for lipid production (28 °C and pH 6.3) and the response to contamination by three common bacterial strains, Escherichia coli (E. coli), Pseudomonas fluorescens (P. fluorescens) and Bacillus subtilis (B. subtilis ) was investigated. Bacterial strains were introduced to the yeast culture at 0, 4, 8, 12, 24 and 48 hours and their effect on the yeast growth and total lipid productivity was assessed. R. glutinis cultures that had been growing for less than 12 hours were unable to compete with any of the bacterial strains introduced. Lowering the temperature and pH allowed the yeast to compete more effectively, though it was found that these conditions were detrimental to the lipid productivity. The effect of invasion was also specific to the type of bacteria. P. fluorescens was found to be the most successful bacteria in competing with R. glutinis, while B. subtilis was found to be the least. Two common antibiotics, tetracycline and sodium metabisulfite were also investigated for their ability to limit the effect of a bacterial invasion.
产油微生物,异养生长的糖来源于非粮食作物或废物资源,是一种可再生的脂质来源。然而,这些培养物容易受到细菌侵袭。确保最佳的无菌条件需要昂贵的预处理技术,并且对于脂质衍生生物燃料的工业规模生产具有重大影响,尽管目前尚不清楚细菌入侵会对生物体积累脂质的能力产生什么影响。本研究以产油酵母粘红酵母(R. glutinis)为研究对象,在最佳产脂条件(28 °C, pH 6.3)下进行了培养,研究了其对大肠杆菌(E. coli)、荧光假单胞菌(P. fluorescens)和枯草芽孢杆菌(B. subtilis)三种常见细菌污染的反应。分别于0、4、8、12、24和48 h将菌株引入酵母培养中,评估其对酵母生长和总脂产量的影响。培养时间少于12小时的粘连杆菌无法与引入的任何菌株竞争。降低温度和pH值可以使酵母更有效地竞争,尽管人们发现这些条件不利于脂质产量。入侵的影响对细菌的类型也有特异性。荧光假单胞菌在与粘滞菌的竞争中最成功,而枯草芽孢杆菌在与粘滞菌的竞争中最失败。两种常见的抗生素,四环素和焦亚硫酸钠也被研究了它们限制细菌入侵影响的能力。
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引用次数: 3
Can Renewable Energy Sustain an Age of Cheap Energy 可再生能源能否支撑廉价能源时代
Pub Date : 2013-08-31 DOI: 10.6000/1929-6002.2013.02.03.1
Hazuki Ishida
Utilizing renewable energy depends more or less upon non-renewable energy sources (mainly fossil fuels), and which implies that a continuous rise in energy prices is inevitable without technological progress in saving fossil fuel use. Using a simple Hotelling model of optimal resource extraction, this paper explores the conditions under which the continuous price rise of renewable energy is restrained in the presence of technological progress in harnessing renewable energy. The results show that to sustain the age of cheap energy, the growth rate of technology in harnessing renewable energy has to be larger than the discount rate. Even if the rate of the technological progress is faster than the discount rate, the energy price may continue to rise until the conventional system of energy generation from fossil fuels is obsolete.
利用可再生能源或多或少依赖于不可再生能源(主要是化石燃料),这意味着如果没有节约化石燃料使用的技术进步,能源价格的持续上涨是不可避免的。本文利用一个简单的最优资源开采Hotelling模型,探讨了在可再生能源利用技术进步的前提下,可再生能源价格持续上涨受到抑制的条件。结果表明,为了维持廉价能源时代,利用可再生能源的技术增长率必须大于贴现率。即使技术进步的速度快于贴现率,能源价格可能会继续上涨,直到传统的化石燃料发电系统被淘汰。
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引用次数: 1
The emergence of low carbon energy autonomy in isolated communities 孤立社区低碳能源自主权的出现
Pub Date : 2013-08-30 DOI: 10.6000/1929-6002.2013.02.03.2
Callum Rae, Fiona Bradley
This study examines the concept of switching from a centralised energy supply model, which prevails in the developed world, towards a more autonomous model based on the use of low carbon technologies, from the viewpoint of isolated communities. The study begins by establishing the importance of isolated communities within the field of energy research, and examining the concept of low carbon energy autonomy. It then analyses a number of desktop case studies from across Europe, all of which have adopted (or are in the process of adopting) a highly autonomous energy supply model based on the use of low carbon technologies. The various resulting social, technical and economic impacts are then examined. This study illustrates the importance of providing high level policy to support innovative projects and encourage a broader dissemination of energy autonomy theory. The research also stresses the need for clearer routes to funding for off-grid energy projects which have great potential for utilising autonomous energy supply as a catalyst for rural socio-economic development.
本研究从孤立社区的角度考察了从发达国家盛行的集中能源供应模式向基于低碳技术使用的更自主模式转变的概念。这项研究首先确立了孤立社区在能源研究领域的重要性,并考察了低碳能源自主的概念。然后,它分析了来自欧洲各地的一些桌面案例研究,所有这些案例都采用了(或正在采用)基于低碳技术使用的高度自主的能源供应模式。然后审查由此产生的各种社会、技术和经济影响。本研究说明了提供高水平政策支持创新项目和鼓励更广泛传播能源自主理论的重要性。该研究还强调,需要为离网能源项目提供更清晰的融资途径,这些项目具有利用自主能源供应作为农村社会经济发展催化剂的巨大潜力。
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引用次数: 2
Numerical Simulations for Average Temperature Differential Stirling Engine 平均温差斯特林发动机的数值模拟
Pub Date : 2013-08-30 DOI: 10.6000/1929-6002.2013.02.03.9
K. Bataineh
A second order mathematical model taken into account thermal losses for average temperature differential Stirling engine is developed. Dynamic simulation of the engine based on mathematical formulation is carried out under different operating and geometrical conditions to investigate the engine performance. The developed model is used to investigate the influence of geometrical and physical parameters on the performance of Stirling engine. Design optimization of Stirling engine is carried out. Finally optimal parameters have been determined
建立了考虑平均温差斯特林发动机热损失的二阶数学模型。基于数学公式对发动机进行了不同工况和几何工况下的动态仿真,研究了发动机的性能。利用所建立的模型研究了几何参数和物理参数对斯特林发动机性能的影响。对斯特林发动机进行了设计优化。最后确定了最优参数
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引用次数: 1
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Journal of Technology Innovations in Renewable Energy
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