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Solvent Isotope Effect on Transfer Hydrogenation of H2O with Glycerine under Alkaline Hydrothermal Conditions 碱性水热条件下溶剂同位素对水与甘油转移加氢反应的影响
Pub Date : 2014-05-28 DOI: 10.6000/1929-6002.2014.03.02.5
Zheng Shen, Minyan Gu, Shiyang Liu, Wenjie Dong, Yalei Zhang
Solvent isotope effect was investigated with 1 H-, 2 H-NMR, LC-MS and Gas-MS analyses on transfer hydrogenation of H 2 O with glycerine under alkaline hydrothermal conditions. The results from solvent isotope studies showed that (1) the H on the I²-C of lactate was almost exchanged by D 2 O, which suggests that the hydroxyl (-OH) group on the 2-C of glycerine was first transformed into a carbonyl (C=O) group and then was converted back into a -OH group to form lactate; (2) The presence of large amounts of D was found in the produced hydrogen gas, which shows that the water molecules acted as a reactant; and (3) D% in the produced hydrogen gas was far more than 50%, which straightforwardly shows that acetol was formed in the first place as the most probable intermediate by undergoing a dehydration reaction rather than a dehydrogenation reaction.
采用1h - nmr、2h - nmr、LC-MS和Gas-MS分析了碱性水热条件下h2o与甘油的转移加氢反应的溶剂同位素效应。溶剂同位素研究结果表明:(1)乳酸I²-C上的H几乎被d2o交换,说明甘油2-C上的羟基(-OH)先转化为羰基(C=O),然后再转化为-OH形成乳酸;(2)生成的氢气中存在大量的D,表明水分子充当了反应物;(3)生成的氢气中D%远大于50%,直接说明乙醇作为最可能的中间体首先是通过脱水反应而不是脱氢反应生成的。
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引用次数: 0
Zinc Oxide Nanostructures for Efficient Energy Conversion in Organic Solar Cell 用于有机太阳能电池高效能量转换的氧化锌纳米结构
Pub Date : 2014-04-01 DOI: 10.6000/1929-6002.2014.03.01.5
M. F. Nurfazliana, S. Kamaruddin, M. S. Alias, N. Nafarizal, H. Saim, M. Z. Sahdan
We present a new approach of solution-processed using zinc oxide (ZnO) nanostructures as extraction layer material for organic solar cells. It is low chemical reaction compatibility with all types of organic blends and its good adhesion to both surfaces of ITO/glass substrate and the active layer (blends). Parameters such as the thickness and the morphology of the films were investigated to prove that these factors greatly affect the efficiency of organic solar cells. In this work, ZnO layer with thickness of approximately 53 nm was used as an interlayer to prevent pin-holes between the electrode and the polymer layer. The polymer layer was coated on the ZnO layer with the thickness of about 150 nm. The thick polymer layer will form a non-uniform surface because of the solvent, 1-2dichlorobenzene will etch away some region of the polymer layer and forming pin-holes. ZnO nanostructures layer was used to prevent pin-holes between the polymer layer and electrode. From the surface morphology of ZnO layer, it shows a uniform surface with particle grain size obtained between 50 -100 nm. The presence of the interlayer has a positive effect on the electrical characteristics of the solar cells. It was found that an organic solar cell with thickness less than 150 nm shows the optimum performance with efficiency of 0.0067% and Fill Factor (FF) of about 19.73.
提出了一种利用氧化锌纳米结构作为有机太阳能电池萃取层材料的溶液处理新方法。它与所有类型的有机共混物具有较低的化学反应相容性,并且在ITO/玻璃基板表面和活性层(共混物)表面都具有良好的附着力。研究了薄膜的厚度和形貌等参数,证明了这些因素对有机太阳能电池的效率有很大影响。在这项工作中,使用厚度约为53 nm的ZnO层作为中间层来防止电极和聚合物层之间的针孔。将聚合物层包覆在氧化锌层上,厚度约为150 nm。由于溶剂的作用,较厚的聚合物层会形成不均匀的表面,1-2二氯苯会腐蚀掉聚合物层的某些区域,形成针孔。ZnO纳米结构层用于防止聚合物层与电极之间的针孔。从ZnO层的表面形貌来看,ZnO层表面均匀,晶粒尺寸在50 ~ 100 nm之间。中间层的存在对太阳能电池的电特性有积极的影响。结果表明,厚度小于150 nm的有机太阳能电池性能最佳,效率为0.0067%,填充系数(FF)约为19.73。
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引用次数: 1
Optimal Design of PID Controller for Doubly-Fed Induction Generator-Based Wave Energy Conversion System Using Multi-Objective Particle Swarm Optimization 基于多目标粒子群算法的双馈感应发电机波能转换系统PID控制器优化设计
Pub Date : 2014-03-25 DOI: 10.6000/1929-6002.2014.03.01.4
A. El-Gammal
This paper presents the complete modeling and simulation of Wave Energy Conversion System (WECS) driven doubly-fed induction generator with a closed-loop vector control system. Two Pulse Width Modulated voltage source (PWM) converters for both rotor- and stator-side converters have been connected back to back between the rotor terminals and utility grid via common dc link. The closed-loop vector control system is normally controlled by a set of PID controllers which have an important influence on the system dynamic performance. This paper presents a Multi-objective optimal PID controller design of a doubly-fed induction generator (DFIG) wave energy system connected to the electrical grid using Particle Swarm Optimization (PSO) and Genetic Algorithm (GA). PSO and GA are used to optimize the controller parameters of both the rotor and grid-side converters to improve the transient operation of the DFIG wave energy system under a fault condition as compared with the conventional methods to design PID controllers.
本文介绍了基于闭环矢量控制系统的波浪能量转换系统驱动双馈感应发电机的完整建模与仿真。两个用于转子侧和定子侧变流器的脉宽调制电压源(PWM)变流器通过公共直流链路在转子终端和公用电网之间背靠背连接。闭环矢量控制系统通常由一组PID控制器控制,PID控制器对系统的动态性能有重要影响。本文利用粒子群算法和遗传算法对并网双馈感应发电机(DFIG)波浪能系统进行了多目标PID优化设计。与传统的PID控制器设计方法相比,采用粒子群算法和遗传算法对转子和电网侧变流器的控制器参数进行优化,改善了DFIG波能系统在故障状态下的暂态运行。
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引用次数: 7
A Single Chip Standalone Water Splitting Photoelectrochemical Cell 单片独立水分解光电化学电池
Pub Date : 2014-03-25 DOI: 10.6000/1929-6002.2014.03.01.2
Mourad Frites, W. Ingler, Shahed U. M. Khan
Water splitting photoelectrochemical cell (PEC) was fabricated in which the electrolyzer parts were made on a single chip. This was achieved by depositing an optically transparent Mn-oxide-TiO 2 thin layer on the front of a triple junction amorphous Si photovoltaic cell which acted as the anode and the back stainless steel layer acted as the cathode under illumination of light. This single chip water electrolysis cell operates like an artificial leaf. Water splitting was observed by simply submersing the device in a basic electrolyte solution under solar simulated light of 1 sun (0.1 W cm -2 ). This self-driven PEC was found to produce hydrogen gas at the rate of 12.42 L m -2 h -1 and a solar to hydrogen efficiency (STHE) of 3.25 % from the collected H 2 gas in 2.5 M KOH solution. No signs of degradation of this single chip PEC were observed during water splitting when the device was run continuously for 6 hours.
研制了一种将电解槽部件组装在单芯片上的水分解光电化学电池。这是通过在光的照射下,在三结非晶硅光伏电池的正面沉积一层光学透明的氧化锰-二氧化钛薄层作为阳极,背面的不锈钢层作为阴极来实现的。这种单芯片电解水电池的工作原理就像一片人造叶子。在1个太阳(0.1 W cm -2)的太阳模拟光下,简单地将器件浸入碱性电解质溶液中,观察到水的分裂。该自驱动PEC在2.5 m KOH溶液中以12.42 L m -2 h -1的速率产生氢气,并从收集的h2气体中获得3.25%的太阳能氢效率(STHE)。当设备连续运行6小时时,在水分解过程中没有观察到这种单片PEC降解的迹象。
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引用次数: 6
Shaping Porous Materials for Hydrogen Storage Applications: A Review 多孔成形储氢材料研究进展
Pub Date : 2014-03-25 DOI: 10.6000/1929-6002.2014.03.01.3
Jianwei Ren, B. North
Development of safe and effective hydrogen storage systems becomes a critical factor for further implementation of fuel cell and hydrogen technologies. Among new approaches aimed at improving the performance of such systems, the concept of porous materials-based adsorptive hydrogen storage is now considered as a long-term solution due to the reversibility, good kinetics and absence of thermal management issues. However, the low packing densities associated with the porous materials such as carbon structure materials, zeolites, metal-organic frameworks lead to the compromised volumetric capacity, potential pipe contaminations and difficulties in handling, when introducing the powdered adsorbents into hydrogen storage systems. Some efforts have been devoted to solve this problem by shaping the porous materials into beads, pellets or monoliths and achieve higher storage densities at more moderate temperatures and pressures. This review will firstly state the essential properties of shaped structures for hydrogen adsorption, and then highlight the recent attributes that potentially can be utilized to shape porous materials into specific configurations for hydrogen storage applications. Later, several testing techniques on structured porous material will be also discussed.
开发安全有效的储氢系统成为进一步实施燃料电池和氢技术的关键因素。在旨在改善此类系统性能的新方法中,基于多孔材料的吸附储氢概念现在被认为是一种长期解决方案,因为它具有可逆性、良好的动力学和无热管理问题。然而,当将粉状吸附剂引入储氢系统时,与多孔材料(如碳结构材料、沸石、金属有机框架)相关的低填充密度导致体积容量受损,潜在的管道污染和处理困难。为了解决这个问题,人们已经做出了一些努力,将多孔材料塑造成珠状、颗粒状或单体状,并在更温和的温度和压力下实现更高的存储密度。本文将首先阐述用于氢吸附的形状结构的基本特性,然后强调可能用于将多孔材料形状成特定构型用于储氢应用的最新属性。随后,还将讨论几种结构多孔材料的测试技术。
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引用次数: 18
Simulation of Ice Growth in Process of Liquor Evaporation- Freezing by Fractal Theory 用分形理论模拟白酒蒸发冻结过程中冰的生长
Pub Date : 2014-03-25 DOI: 10.6000/1929-6002.2014.03.01.1
Gao Penghui, Zhou Xingye, Zhang Donghai, Wang Yi-jiang
Considering complexity in process of the liquor’s evaporation-freezing and irregularity on the liquor surface, generating and developing model of ice on liquor surface was proposed by humidity difference based on fractal theory and diffusion limited aggregation model (DLA). The effect of gas flow velocity and humidity difference between gas and liquor surface on generating and developing of ice above liquor surface were analyzed by numerical simulation. The results showed that the fractal method could simulate the process generating and developing model of ice above liquor surface. It provided the new idea and method for the study of the liquor evaporation-freezing and ice growth.
考虑到白酒蒸发冻结过程的复杂性和白酒表面的不规则性,基于分形理论和扩散限制聚集模型(DLA),提出了基于湿度差的白酒表面冰的产生和发展模型。通过数值模拟分析了气体流速和液面湿度差对液面冰产生和发展的影响。结果表明,分形方法能较好地模拟液面冰的生成和发展过程。为研究白酒的蒸发冻结和冰的生长提供了新的思路和方法。
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引用次数: 5
Gasification of High and Low Density Crop Residues 高、低密度作物残茬的气化
Pub Date : 2013-11-28 DOI: 10.6000/1929-6002.2013.02.04.8
A. Parihar, V. B. Kulkarni, G. Sridhar
Crop residue constitutes a large fraction of biomass particularly in agricultural based economies like India. The most abundantly generated crop residues are paddy husk, paddy straw, coconut shell, cotton stalk and sugar cane trash. It is estimated that the potential of power generation using crop residue is close to 14 GWe in a country like India. Even though the potential is large, the main drawback with crop residue is that it is sparsely distributed and being of low density causes collection and transportation problem. This drawback could be converted into an advantage by adopting distributed power generation technologies. The distributed power generation would fare well in the power range of few hundred kilowatts and the most appropriate technology would be the biomass gasification technology. Among the biomass gasification technologies, the downdraft technology is ideally suited for power generation. The downdraft technology is proven with solid or woody biomass, whereas there are limitations in terms of acceptance of all types of crop residues. In this paper, performance study of two vastly differing crop residues, namely coconut shell and cotton stalk has been discussed; both the feedstocks have been tested in “post-harvested” condition with minimum amount of pre-processing. The performance with cotton stalk was found to be comparable at part load; however at higher load the gas composition deteriorated due to poor material movement within the reactor. This had implication in terms of maximum power generated. There was loss of power to an extent of 12%. The operational issues with post-harvested cotton stalk has been brought out which are based on detailed measurements.
农作物残渣构成了生物质的很大一部分,特别是在像印度这样的农业经济中。产生最多的农作物秸秆是稻壳、稻秆、椰子壳、棉秆和甘蔗垃圾。据估计,在印度这样的国家,利用农作物秸秆发电的潜力接近14吉瓦。尽管潜力很大,但作物秸秆的主要缺点是分布稀疏,密度低,导致收集和运输问题。通过采用分布式发电技术,这一缺点可以转化为优势。分布式发电在几百千瓦的功率范围内表现良好,最合适的技术是生物质气化技术。在生物质气化技术中,下吸式技术最适合于发电。下沉气流技术已被证明适用于固体或木质生物质,但在接受所有类型的作物残留物方面存在局限性。本文讨论了椰子壳和棉花秸秆两种差异很大的作物秸秆的性能研究;这两种原料都在€œpost-harvested—条件下进行了测试,预处理量最少。在部分负荷下,与棉秆的性能相当;然而,在高负荷时,由于反应器内物料移动不良,气体成分恶化。这对产生的最大功率有影响。电力损失达到了12%。在详细测量的基础上,提出了采后棉秆的操作问题。
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引用次数: 2
Modeling and Global Sensitivity Analysis of a Solar Powered Air Cooling System Using Liquid Desiccant 液体干燥剂太阳能风冷系统建模及全局灵敏度分析
Pub Date : 2013-11-28 DOI: 10.6000/1929-6002.2013.02.04.4
H. T. Rakotondramiarana, S. Andrianomena, A. Andriamamonjy, M. Rakotomalala
Solar energy technology is an option for energy saving in building air conditioning. A theoretical investigation of an open cycle solar air cooling system using aqueous Lithium Chloride solution as liquid desiccant is presented in this paper. The purpose of this work is to analyze the influences of both internal loads and external forcing, on the studied system by developing a computational code related to its mathematical model. The simulation results justify the choice of the system design. Indeed, it was highlighted that the higher is the outdoor temperature; the better is the coefficient of performance (COP) of the system. Furthermore, a global sensitivity analysis of the system model, achieved using Fourier Amplitude Sensitivity Test method, allowed us to identify the most influential factors that were ranked in a decreasing order of their influence degree on the system COP. Hence, key factors to be controlled for improving the system overall performance are specified.
太阳能技术是建筑空调节能的一种选择。本文对采用氯化锂水溶液作为液体干燥剂的开式循环太阳能空气冷却系统进行了理论研究。这项工作的目的是通过开发与其数学模型相关的计算代码来分析内部载荷和外部力对所研究系统的影响。仿真结果验证了系统设计的选择。事实上,它强调室外温度越高;系统的性能系数(COP)越好。此外,使用傅里叶振幅灵敏度测试方法对系统模型进行全局灵敏度分析,使我们能够确定影响最大的因素,这些因素对系统COP的影响程度按降序排列。因此,要控制的关键因素,以提高系统的整体性能是明确的。
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引用次数: 0
Interconnection of a Wind Driven DC Machine with the Power Utilities Grid 风力直流电机与电网的互联
Pub Date : 2013-11-28 DOI: 10.6000/1929-6002.2013.02.04.2
M. Taleb
A wind driven DC machine is interconnected with the power utilities grid. The wind driven DC machine is operated in the regenerative mode and that is to guaranty the extraction of the real power from the wind driven generator and inject it into the power grid. This is done through the use of a single phase full wave controlled converter operating in “ an inverter mode of operation”. At any pretended surrounding weather conditions, maximum extraction of power from the renewable energy source (ie. Wind energy source) is targeted. This is done through the realization of a self-adjusted firing angle controller responsible of triggering the semiconductor elements of the controlled converter. An active power filter is shunted with the proposed setup to guaranty the sinusoid quality of the power utilities line current. The overall performance of the proposed system has been simulated in MATLAB/SIMULINK environment. Quite satisfactory and encouraging results have been obtained.
风力驱动的直流电机组与电网相连。风力直流电机组以蓄电方式运行,即保证从风力发电机中抽出实电并注入电网。这是通过使用在逆变器操作模式下运行的单相全波控制转换器来完成的。在任何假想的周围天气条件下,从可再生能源中最大限度地提取电力(即。风能资源)是有针对性的。这是通过实现一个自调节发射角控制器来实现的,该控制器负责触发被控变换器的半导体元件。采用该方法并联了有源电力滤波器,保证了电力线路电流的正弦波质量。在MATLAB/SIMULINK环境下对系统的整体性能进行了仿真。取得了相当令人满意和鼓舞人心的结果。
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引用次数: 0
Latent Heat Storage with Phase Change Materials (PCMs) 相变材料(PCMs)潜热储存技术
Pub Date : 2013-11-28 DOI: 10.6000/1929-6002.2013.02.04.5
Huili Zhang, J. Baeyens, J. Degrève, François Pitié
Latent heat thermal energy storage with phase change materials (PCMs) is attractive since providing a high energy density storage due to the phase change by solidification/melting at constant temperature. Relative to sensible heat energy storage systems, latent heat storage with PCMs requires a smaller weight and volume of material for a given amount of captured/stored energy, and has the capacity to store heat of fusion at a constant or nearly constant temperature, thus maintaining a high and constant temperature difference between the heat exchanging surface and the PCMs. The present review paper will summarize the required properties of PCMs, with their respective advantages and disadvantages; the current state of development and manufacturing; the development of PCM applications, including their incorporation into heat exchangers, insertion of a metal matrix into the PCM, the use of PCM dispersed with high conductivity particles. PCM uses will be illustrated through some case-studies.
潜热相变材料(PCMs)由于在恒温下凝固/熔化的相变而提供了高能量密度的储能,因此具有很大的吸引力。相对于显热蓄能系统,pcm的潜热蓄能需要更小的材料重量和体积来捕获/储存一定量的能量,并且具有在恒定或接近恒定温度下储存聚变热的能力,从而保持换热表面和pcm之间的高且恒定的温差。本文综述了PCMs的性能要求,以及各自的优点和缺点;开发制造现状;PCM应用的发展,包括将其纳入热交换器,在PCM中插入金属基体,使用分散在高导电性颗粒中的PCM。将通过一些案例研究说明PCM的使用。
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引用次数: 7
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Journal of Technology Innovations in Renewable Energy
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