Pub Date : 2017-01-02DOI: 10.6000/1929-6002.2016.05.04.1
A. Shono, K. Otake, D. Kobayashi, S. Kobayashi, Y. Saito
Reversible reaction couples of hydrogenation and dehydrogenation of organic compounds e.g. methylcyclohexane and toluene, or 2-propanol and acetone, are described in terms of hydrogen supplier to fuel cells, which will satisfy our demands of combined heat and power at various compact sizes. Carbon supported nano-sized metal particles, wetted with the liquid substrate in a reactor, was used for conversion of organic hydrides into hydrogen and organic compounds, being separable by distillation. Vigorous nucleate boiling is important for heat transfer as well as for irreversible bubble evolution, leading hydrogen to the vapor phase. Once the bubble is broken at the interface, catalytic hydrogenation will be prohibited, because gaseous hydrogen is unable to dissolve into the boiling liquid. Catalytic dehydrogenation under superheated liquid-film conditions can thus convert low-quality heats into hydrogen energy.
{"title":"Dehydrogenation Catalyst for Organic Hydride on the Basis of Superheated Liquid-Film Concept","authors":"A. Shono, K. Otake, D. Kobayashi, S. Kobayashi, Y. Saito","doi":"10.6000/1929-6002.2016.05.04.1","DOIUrl":"https://doi.org/10.6000/1929-6002.2016.05.04.1","url":null,"abstract":"Reversible reaction couples of hydrogenation and dehydrogenation of organic compounds e.g. methylcyclohexane and toluene, or 2-propanol and acetone, are described in terms of hydrogen supplier to fuel cells, which will satisfy our demands of combined heat and power at various compact sizes. Carbon supported nano-sized metal particles, wetted with the liquid substrate in a reactor, was used for conversion of organic hydrides into hydrogen and organic compounds, being separable by distillation. Vigorous nucleate boiling is important for heat transfer as well as for irreversible bubble evolution, leading hydrogen to the vapor phase. Once the bubble is broken at the interface, catalytic hydrogenation will be prohibited, because gaseous hydrogen is unable to dissolve into the boiling liquid. Catalytic dehydrogenation under superheated liquid-film conditions can thus convert low-quality heats into hydrogen energy.","PeriodicalId":394478,"journal":{"name":"Journal of Technology Innovations in Renewable Energy","volume":"122 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2017-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128131008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-01-02DOI: 10.6000/1929-6002.2016.05.04.3
M. Elsharafi, L. Saleh, B. Bai
Formation damage by gel particles has become one of the most important problems in mature reservoirs. The objective of the quantitative analytical model is to identify an analytical model to the best fit of the preformed particle gels (PPGs) filtration test results. This work will analyze the experiments results of low permeability core samples to evaluate the effect of various brine concentrations and particle sizes. This study used a linear analytical model relationship between cumulative volumes versus filtration time with a good fits result. Linear curve equations for the best fitting equation was obtained. According to quantitative analytical model for all of our filtration tests, the cumulative filtration test volume (Vcf) was explained in this paper. Quantitative analytical model results showed the value of the slop m increases as the injection pressure increases. Compared with the experiments, the results show that, if the value of the intercept b > 2 the damage occurred because the gel particles invasion started into the core surface. Results from the quantitative analytical model were indicated to have a good fitting with almost all of the experimental results. It is the first time to use quantitative analytical model to analysis the formation damage by the PPGs. The results can be used to select the best gel treatment design.
{"title":"Quantitative analytical model of the formation damage by gel particles","authors":"M. Elsharafi, L. Saleh, B. Bai","doi":"10.6000/1929-6002.2016.05.04.3","DOIUrl":"https://doi.org/10.6000/1929-6002.2016.05.04.3","url":null,"abstract":"Formation damage by gel particles has become one of the most important problems in mature reservoirs. The objective of the quantitative analytical model is to identify an analytical model to the best fit of the preformed particle gels (PPGs) filtration test results. This work will analyze the experiments results of low permeability core samples to evaluate the effect of various brine concentrations and particle sizes. This study used a linear analytical model relationship between cumulative volumes versus filtration time with a good fits result. Linear curve equations for the best fitting equation was obtained. According to quantitative analytical model for all of our filtration tests, the cumulative filtration test volume (Vcf) was explained in this paper. Quantitative analytical model results showed the value of the slop m increases as the injection pressure increases. Compared with the experiments, the results show that, if the value of the intercept b > 2 the damage occurred because the gel particles invasion started into the core surface. Results from the quantitative analytical model were indicated to have a good fitting with almost all of the experimental results. It is the first time to use quantitative analytical model to analysis the formation damage by the PPGs. The results can be used to select the best gel treatment design.","PeriodicalId":394478,"journal":{"name":"Journal of Technology Innovations in Renewable Energy","volume":"14 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2017-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134560327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-11-04DOI: 10.6000/1929-6002.2016.05.03.2
D. Coiro, F. Scherillo, G. Troise, N. Bizzarrini, G. Calise
The main object of this paper is to present the design and the results of an experimental test campaign on an innovative device for the exploitation of marine and river currents. The basic idea is to lay together one or more series of horizontal axis turbines in rows, each one connected to a generator placed on board a ship or a float. The whole system is sustained by a series of buoys, in this way is possible to avoid expensive submarine installations. All the work has been carried out at the Department of Industrial Engineering of the University of Naples “Federico II†and the test campaign has been first performed in the naval towing tank belonging to the same Department and then in real conditions in Messina Strait between Sicily island and mainland. This location is the only one in Italy suitable as test site thanks to a highly regular tidal current reaching a maximum speed of 3 m/s. The turbine’s blade was first carefully designed with particular care for the cavitation problems. Two different series of experimental tests on a reduced scale model in the naval tank aimed to optimize the general layout of the device and the tests performed in Messina Strait mainly aimed to confirm the feasibility of the system and to evaluate its response in real operating conditions. The tests have confirmed the good dynamic behavior of the whole system and its feasibility to be scaled up to real scale.
{"title":"Numerical and Experimental Test on an Innovative Device Based on Multiple Rotors in Line to Tap Clean Energy from Tidal and River Current","authors":"D. Coiro, F. Scherillo, G. Troise, N. Bizzarrini, G. Calise","doi":"10.6000/1929-6002.2016.05.03.2","DOIUrl":"https://doi.org/10.6000/1929-6002.2016.05.03.2","url":null,"abstract":"The main object of this paper is to present the design and the results of an experimental test campaign on an innovative device for the exploitation of marine and river currents. The basic idea is to lay together one or more series of horizontal axis turbines in rows, each one connected to a generator placed on board a ship or a float. The whole system is sustained by a series of buoys, in this way is possible to avoid expensive submarine installations. All the work has been carried out at the Department of Industrial Engineering of the University of Naples “Federico II†and the test campaign has been first performed in the naval towing tank belonging to the same Department and then in real conditions in Messina Strait between Sicily island and mainland. This location is the only one in Italy suitable as test site thanks to a highly regular tidal current reaching a maximum speed of 3 m/s. The turbine’s blade was first carefully designed with particular care for the cavitation problems. Two different series of experimental tests on a reduced scale model in the naval tank aimed to optimize the general layout of the device and the tests performed in Messina Strait mainly aimed to confirm the feasibility of the system and to evaluate its response in real operating conditions. The tests have confirmed the good dynamic behavior of the whole system and its feasibility to be scaled up to real scale.","PeriodicalId":394478,"journal":{"name":"Journal of Technology Innovations in Renewable Energy","volume":"26 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"117219589","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-11-04DOI: 10.6000/1929-6002.2016.05.03.1
N. Nanami, O. Ochoa
Wind energy is one of the most promising and mature alternatives to satisfy the global demand for energy as the world population and the economic activity surge. The wind energy market has grown rapidly in the last couple of decades, boosting up the size of wind turbines to generate higher power output. Typically, the larger/longer blade designs rely on hybrid material systems such as carbon and/or glass fiber (CF/GF) reinforced polymers to improve specific stiffness/strength and damage tolerance. Herein, we propose a computational design concept for a modular hybrid composite wind turbine blade that maintains its structural integrity and serviceability requirements. The modular configuration will simplify manufacturing-assembly processes and reduce expenses both in transportation and facilities requirements. The 80 m blade in this study is composed of two sections that are joined together with an innovative compression joint. Our results when compared to a single continuous blade, showed no significant alterations to its structural response. It is concluded that the proposed computational design concept that allow two modular blades to create full-length blade with robust joints is achievable. This modular concept can be easily extended for further multi-section modular blade configurations.
{"title":"Computational Assessment of a Modular Composite Wind Turbine Blade Joint","authors":"N. Nanami, O. Ochoa","doi":"10.6000/1929-6002.2016.05.03.1","DOIUrl":"https://doi.org/10.6000/1929-6002.2016.05.03.1","url":null,"abstract":"Wind energy is one of the most promising and mature alternatives to satisfy the global demand for energy as the world population and the economic activity surge. The wind energy market has grown rapidly in the last couple of decades, boosting up the size of wind turbines to generate higher power output. Typically, the larger/longer blade designs rely on hybrid material systems such as carbon and/or glass fiber (CF/GF) reinforced polymers to improve specific stiffness/strength and damage tolerance. Herein, we propose a computational design concept for a modular hybrid composite wind turbine blade that maintains its structural integrity and serviceability requirements. The modular configuration will simplify manufacturing-assembly processes and reduce expenses both in transportation and facilities requirements. The 80 m blade in this study is composed of two sections that are joined together with an innovative compression joint. Our results when compared to a single continuous blade, showed no significant alterations to its structural response. It is concluded that the proposed computational design concept that allow two modular blades to create full-length blade with robust joints is achievable. This modular concept can be easily extended for further multi-section modular blade configurations.","PeriodicalId":394478,"journal":{"name":"Journal of Technology Innovations in Renewable Energy","volume":"1207 ","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114048908","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-11-04DOI: 10.6000/1929-6002.2016.05.03.3
D. Icaza, A. Pauta, G. Saguay, F. Solís
Using wind power generation is another alternative for remote homes, where there is no electricity grid. Especially in Ecuador there are several places where the wind resource is really stable for the year, though at times the wind regime it becomes turbulent wind speeds become quite high exceeding 12 m / s affecting the wind turbine components. Generally in the Ecuadorian highlands are available permanent winds of medium intensity capable of generating electricity, but by having a system of turbulence for short periods of time it jeopardizes the deployed equipment and therefore the investments made by what this study guarantees the stability of small wind turbines that are very useful in our environment to generate electricity in field type housing shelters.
{"title":"Control System for Less than Wind Turbines 1500W","authors":"D. Icaza, A. Pauta, G. Saguay, F. Solís","doi":"10.6000/1929-6002.2016.05.03.3","DOIUrl":"https://doi.org/10.6000/1929-6002.2016.05.03.3","url":null,"abstract":"Using wind power generation is another alternative for remote homes, where there is no electricity grid. Especially in Ecuador there are several places where the wind resource is really stable for the year, though at times the wind regime it becomes turbulent wind speeds become quite high exceeding 12 m / s affecting the wind turbine components. Generally in the Ecuadorian highlands are available permanent winds of medium intensity capable of generating electricity, but by having a system of turbulence for short periods of time it jeopardizes the deployed equipment and therefore the investments made by what this study guarantees the stability of small wind turbines that are very useful in our environment to generate electricity in field type housing shelters.","PeriodicalId":394478,"journal":{"name":"Journal of Technology Innovations in Renewable Energy","volume":"35 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122643539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-07-27DOI: 10.6000/1929-6002.2016.05.02.2
Yunus Eroglu, S. Seçkiner
This study reviews and analyses the recent research and development and trends in the applications of wind energy and it also discusses and summarizes the topic. We show the usage and the influence of text mining on the different aspects of wind energy systems especially for hot topics and trends of wind energy area. Text mining provides the state of the art in this area that will be a good guidance for future research work. The main results achieved from the study have shown that the text mining technique are adequate for serving as a proof of concept and as a test-bed for deriving requirements for the development of more generally applicable text mining tools and services within wind energy science.
{"title":"Trend Topic Analysis for Wind Energy Researches: A Data Mining Approach Using Text Mining","authors":"Yunus Eroglu, S. Seçkiner","doi":"10.6000/1929-6002.2016.05.02.2","DOIUrl":"https://doi.org/10.6000/1929-6002.2016.05.02.2","url":null,"abstract":"This study reviews and analyses the recent research and development and trends in the applications of wind energy and it also discusses and summarizes the topic. We show the usage and the influence of text mining on the different aspects of wind energy systems especially for hot topics and trends of wind energy area. Text mining provides the state of the art in this area that will be a good guidance for future research work. The main results achieved from the study have shown that the text mining technique are adequate for serving as a proof of concept and as a test-bed for deriving requirements for the development of more generally applicable text mining tools and services within wind energy science.","PeriodicalId":394478,"journal":{"name":"Journal of Technology Innovations in Renewable Energy","volume":"13 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116977193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-07-27DOI: 10.6000/1929-6002.2016.05.02.3
Prapassorn Phakahan, K. Aryusuk, S. Lilitchan, K. Krisnangkura
Spent bleaching clays (SBCs) from vegetable oil refineries are industrial wastes. The clays contain large amount of oils (20-25%), which are good feedstock for biodiesels. Non-thermal in situ trans-methylation and trans-ethylation of oils in the SBC from rice bran oil (RBO), crude palm oil (CPO) and palm kernel oil (PKO) are rapid and can be accomplished in minutes with an alkaline catalyst. Thus, the process may possibly be used for large scale preparation of ethyl biodiesel.
{"title":"In Situ Trans-Esterification of Residual Oils in Spent Bleaching Clays from Vegetable Oil Refineries","authors":"Prapassorn Phakahan, K. Aryusuk, S. Lilitchan, K. Krisnangkura","doi":"10.6000/1929-6002.2016.05.02.3","DOIUrl":"https://doi.org/10.6000/1929-6002.2016.05.02.3","url":null,"abstract":"Spent bleaching clays (SBCs) from vegetable oil refineries are industrial wastes. The clays contain large amount of oils (20-25%), which are good feedstock for biodiesels. Non-thermal in situ trans-methylation and trans-ethylation of oils in the SBC from rice bran oil (RBO), crude palm oil (CPO) and palm kernel oil (PKO) are rapid and can be accomplished in minutes with an alkaline catalyst. Thus, the process may possibly be used for large scale preparation of ethyl biodiesel.","PeriodicalId":394478,"journal":{"name":"Journal of Technology Innovations in Renewable Energy","volume":"70 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116133914","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-07-27DOI: 10.6000/1929-6002.2016.05.02.4
D. Tsegaye, M. Dawit, K. Gajananda
The present study characterized the physical property, total solids (TS), volatile solids (VS) and Carbon to Nitrogen ratio (C/N ratio) of tannery solid waste (TSW). Five different combinations with or without cow dung (CD) were assessed for their biogas production suitability in triplicate batch digesters (D-1, D-2, D-3, D-4, and D-5) with a total volume of 2.8L. The results showed that TS, VS and C/N ratio of wastes were 56.37%, 76.34% and 29.05%, respectively. The results also suggested that the highest volume of biogas (4,756 ml) with a methane content of 60.37% was produced by the digester containing 75% TSW and 25% CD and the lowest biogas (2,539 ml) with quality of 68.06% was produced by digester containing 100% CD. The average methane contents of different digesters were D-1 (100% TSW) 53.23%, D-2 (75% TSW: 25% CD) 60.37%, D-3 (50% TSW: 50% CD) 58.78%, D-4 (25% TSW: 75% CD) 57.66% and D-5 (100% CD) 67.31%. Total and volatile solid removal efficiency of all digesters was in the range of 42.27-76.34% and 47.16-79.23%. The study concluded that TSW is a good feedstock for biogas production by utilizing agro-industrial based organic solid waste for bioenergy production.
{"title":"Anaerobic Digestion of Tannery Solid Waste for Biogas Production: The case of Modjo Tannery, Modjo; Ethiopia","authors":"D. Tsegaye, M. Dawit, K. Gajananda","doi":"10.6000/1929-6002.2016.05.02.4","DOIUrl":"https://doi.org/10.6000/1929-6002.2016.05.02.4","url":null,"abstract":"The present study characterized the physical property, total solids (TS), volatile solids (VS) and Carbon to Nitrogen ratio (C/N ratio) of tannery solid waste (TSW). Five different combinations with or without cow dung (CD) were assessed for their biogas production suitability in triplicate batch digesters (D-1, D-2, D-3, D-4, and D-5) with a total volume of 2.8L. The results showed that TS, VS and C/N ratio of wastes were 56.37%, 76.34% and 29.05%, respectively. The results also suggested that the highest volume of biogas (4,756 ml) with a methane content of 60.37% was produced by the digester containing 75% TSW and 25% CD and the lowest biogas (2,539 ml) with quality of 68.06% was produced by digester containing 100% CD. The average methane contents of different digesters were D-1 (100% TSW) 53.23%, D-2 (75% TSW: 25% CD) 60.37%, D-3 (50% TSW: 50% CD) 58.78%, D-4 (25% TSW: 75% CD) 57.66% and D-5 (100% CD) 67.31%. Total and volatile solid removal efficiency of all digesters was in the range of 42.27-76.34% and 47.16-79.23%. The study concluded that TSW is a good feedstock for biogas production by utilizing agro-industrial based organic solid waste for bioenergy production.","PeriodicalId":394478,"journal":{"name":"Journal of Technology Innovations in Renewable Energy","volume":"43 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124901941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-07-27DOI: 10.6000/1929-6002.2016.05.02.1
A. Osinowo, Xiaopei Lin, Z. Dongliang, W. Zhifeng
This paper presents a thirty year (1976-2005) assessment of wave energy resource within the South China Sea (SCS) by simulation. Significant wave height (SWH) between simulation and observation shows good agreement. This shows the reliability of an along-side simulated wave period in estimating wave energy in the SCS. Results show that estimates of wave power density are more reliable in the north-central SCS and most sufficient during winter. The annual mean wave power density peaked at 12.7kW/m and 12.9kW/m during years 1986 and 1999 respectively while the highest seasonal mean of 29kW/m occurred in year 1999 during winter. The wave power density is most stable in winter and is generally more stable in offshore regions of SCS. Wave power density is most stable in years 1976, 1997 and 2004 with stability values of 1.96, 1.98 and 1.9 respectively. The stability value of 0.9 in year 1980 is the greatest in the winter of all years. Relative-rich energy regions occupy the largest area during winter. The relatively richest energy is generally concentrated in the central and north-central SCS. No area is identified as a relative-rich energy region during spring. Winter 1999 has the highest relative-rich energy with value of 37kW/m.
{"title":"On the Wave Energy Assessment in the South China Sea","authors":"A. Osinowo, Xiaopei Lin, Z. Dongliang, W. Zhifeng","doi":"10.6000/1929-6002.2016.05.02.1","DOIUrl":"https://doi.org/10.6000/1929-6002.2016.05.02.1","url":null,"abstract":"This paper presents a thirty year (1976-2005) assessment of wave energy resource within the South China Sea (SCS) by simulation. Significant wave height (SWH) between simulation and observation shows good agreement. This shows the reliability of an along-side simulated wave period in estimating wave energy in the SCS. Results show that estimates of wave power density are more reliable in the north-central SCS and most sufficient during winter. The annual mean wave power density peaked at 12.7kW/m and 12.9kW/m during years 1986 and 1999 respectively while the highest seasonal mean of 29kW/m occurred in year 1999 during winter. The wave power density is most stable in winter and is generally more stable in offshore regions of SCS. Wave power density is most stable in years 1976, 1997 and 2004 with stability values of 1.96, 1.98 and 1.9 respectively. The stability value of 0.9 in year 1980 is the greatest in the winter of all years. Relative-rich energy regions occupy the largest area during winter. The relatively richest energy is generally concentrated in the central and north-central SCS. No area is identified as a relative-rich energy region during spring. Winter 1999 has the highest relative-rich energy with value of 37kW/m.","PeriodicalId":394478,"journal":{"name":"Journal of Technology Innovations in Renewable Energy","volume":"41 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127405885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-03-02DOI: 10.6000/1929-6002.2016.05.01.4
S. Hassing, K. D. Jernshøj, P. T. Nguyen, T. Lund
The working efficiency of dye-sensitized solar cells (DSCs) depends on the long-term stability of the dye itself and on the microscopic structure of the dye-semiconductor interface. Previous experimental studies of DSCs based on ruthenium dye with bipyridine ligands (N719) adsorbed to the TiO 2 substrate applied FTIR,un-polarized Raman (RS) and un-polarized resonance Raman (RRS) spectroscopy. In the un-polarized RRS studies of N719/TiO 2 – DSCs the discussion of the adsorption of N719 was based on the rather weak carbonyl or carboxyl group stretching vibrations and on minor spectral changes of overlapping Raman modes, whereas conclusions about the dye-stability was based on the observation that fresh and aged DSCs had almost identical RRS spectra. In the present paper we address the problems mentioned above, by utilizing the unique property of Raman scattering that the polarization of the scattered light is generally different from the polarization of the laser light. When the excitation is chosen within the visible absorption band of N719 only the skeleton ring-modes in N719 are enhanced and are observed as the most intense bands in the RRS spectra. We demonstrate by experimental results on N719/TiO 2 – DSCs that by combining an analysis of the wave number dependent polarization of these modes with the small shifts observed in the visible absorption spectra of adsorbed, non-adsorbed molecules and degradation products new and more reliable information about dye stability and about the adsorption of the dye on TiO 2 can be obtained. Furthermore it is found that the polarization fluorescence anisotropy is very different for adsorbed and non-adsorbed dye molecules. This information is automatically obtained when processing the Raman data. The conclusion is that if the polarization properties of the resonance Raman spectra are analyzed instead of just analyzing the minute spectral changes of the (weaker) Raman bands the potential of RRS as an on-site tool for investigation of DSCs can be greatly improved.
{"title":"In Vitro Polarized Resonance Raman Study of N719 and N719-TBP in Dye Sensitized Solar Cells","authors":"S. Hassing, K. D. Jernshøj, P. T. Nguyen, T. Lund","doi":"10.6000/1929-6002.2016.05.01.4","DOIUrl":"https://doi.org/10.6000/1929-6002.2016.05.01.4","url":null,"abstract":"The working efficiency of dye-sensitized solar cells (DSCs) depends on the long-term stability of the dye itself and on the microscopic structure of the dye-semiconductor interface. Previous experimental studies of DSCs based on ruthenium dye with bipyridine ligands (N719) adsorbed to the TiO 2 substrate applied FTIR,un-polarized Raman (RS) and un-polarized resonance Raman (RRS) spectroscopy. In the un-polarized RRS studies of N719/TiO 2 – DSCs the discussion of the adsorption of N719 was based on the rather weak carbonyl or carboxyl group stretching vibrations and on minor spectral changes of overlapping Raman modes, whereas conclusions about the dye-stability was based on the observation that fresh and aged DSCs had almost identical RRS spectra. In the present paper we address the problems mentioned above, by utilizing the unique property of Raman scattering that the polarization of the scattered light is generally different from the polarization of the laser light. When the excitation is chosen within the visible absorption band of N719 only the skeleton ring-modes in N719 are enhanced and are observed as the most intense bands in the RRS spectra. We demonstrate by experimental results on N719/TiO 2 – DSCs that by combining an analysis of the wave number dependent polarization of these modes with the small shifts observed in the visible absorption spectra of adsorbed, non-adsorbed molecules and degradation products new and more reliable information about dye stability and about the adsorption of the dye on TiO 2 can be obtained. Furthermore it is found that the polarization fluorescence anisotropy is very different for adsorbed and non-adsorbed dye molecules. This information is automatically obtained when processing the Raman data. The conclusion is that if the polarization properties of the resonance Raman spectra are analyzed instead of just analyzing the minute spectral changes of the (weaker) Raman bands the potential of RRS as an on-site tool for investigation of DSCs can be greatly improved.","PeriodicalId":394478,"journal":{"name":"Journal of Technology Innovations in Renewable Energy","volume":"17 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2016-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133079303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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