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Phyto-mediated biosynthesis of silver nanoparticles using Aloe barbadensis Miller leaves gel with improved antibacterial, anti-fungal, antioxidant, anti-inflammatory, anti-diabetic, and anti-cancer activities 利用米勒芦荟叶凝胶进行植物介导的银纳米粒子生物合成,提高抗菌、抗真菌、抗氧化、抗炎、抗糖尿病和抗癌活性
IF 5.45 Q1 Physics and Astronomy Pub Date : 2024-10-03 DOI: 10.1016/j.nanoso.2024.101368
Pooja V. Nagime , Dwi Marlina Syukri , Tessa Sjahriani , Dessy Hermawan , Nishat M. Shaikh , Sheeba Shafi , Vijay R. Chidrawar , Sudarshan Singh , Naheed Kausar , Aliya Elamin
An effective topical therapeutic agent requires a multifunctional attribute such as antibacterial, antioxidant, and anti-inflammatory efficacy. The green-synthesized metallic and metallic oxide nanoparticles have shown significant applicability in this regard. Hence a biosynthesis of silver nanoparticles (AgNPs) using Aloe barbadensis miller leaf gel was fabricated and evaluated for effect of imperative influences such as temperature, time, and concentration of reactant on AgNPs synthesis. Furthermore, the biomimetic qualities were assessed to ensure the safety and efficacy. The synthesis of stabilized and capped AgNPs presented a UV–vis–based plasmonic resonance at ∼ 400 nm. The reduction of silver nitrate was further confirmed by the shift in FTIR spectra for -OH around 2870 cm−1. SEM and TEM images revealed cubic shape of the AgNPs. Whereas X-ray diffraction pattern indicated crystalline structure (crystallite size of ∼ 31.14 nm) with an inter-planar spacing value of 2.77, 1.96, and 1.67 Å for (200), (220), and (311) planes, respectively. In addition, AgNPs indicated a steady dispersion, homogeneity, and strong anionic zeta potential (∼ 35.4 mV). The results of antibacterial and antifungal activity demonstrated the potential of phyto-synthesized AgNPs in mitigation of infection associated with tested bacterial strain Bacillus subtilis, Bacillus megaterium, Shigella flexneri, Trichoderma viride, Aspergillus niger, and Penicillium crysogenum. Moreover, the results of hydrogen peroxide-based scavenging, anti-inflammatory, and anti-diabetic study revealed that the biosynthesized AgNPs exhibit an improved biomimetic attribute. Additionally, the biocompatibility assay demonstrated > 80 % of CaCO-2 and L-929 cells viability at 1.67 μg/mL and 3.35 μg/mL, respectively. The anticancer activity of synthesized AgNPs against epithelium-like phenotype oral squamous carcinoma cells (CLS-354/WT) displayed IC50 of 11.58 μg/mL. The results indicate that biogenic produced AgNPs may find suitable use as a potential therapeutic agent due to multifunctional attribute.
有效的外用治疗剂需要具有抗菌、抗氧化和消炎等多功能特性。在这方面,绿色合成的金属和金属氧化物纳米粒子已显示出显著的适用性。因此,我们利用芦荟叶凝胶制作了银纳米粒子(AgNPs)的生物合成物,并评估了温度、时间和反应物浓度等必要影响因素对 AgNPs 合成的影响。此外,还对生物仿生质量进行了评估,以确保其安全性和有效性。经过稳定和封端的 AgNPs 在 400 纳米波长处产生了基于紫外可见光的等离子体共振。傅立叶变换红外光谱中 -OH 在 2870 cm-1 附近的移动进一步证实了硝酸银的还原。SEM 和 TEM 图像显示 AgNPs 呈立方体。而 X 射线衍射图样显示出晶体结构(晶粒大小为 31.14 nm),(200)、(220) 和 (311) 平面的平面间距值分别为 2.77、1.96 和 1.67 Å。此外,AgNPs 显示出稳定的分散性、均一性和较强的阴离子 Zeta 电位(∼ 35.4 mV)。抗菌和抗真菌活性结果表明,植物合成的 AgNPs 有潜力减轻与受测细菌菌株枯草芽孢杆菌、巨大芽孢杆菌、柔嫩志贺氏菌、病毒毛霉、黑曲霉和青霉相关的感染。此外,基于过氧化氢的清除、抗炎和抗糖尿病研究结果表明,生物合成的 AgNPs 具有更好的仿生特性。此外,生物相容性试验表明,在 1.67 μg/mL 和 3.35 μg/mL 的条件下,CaCO-2 和 L-929 细胞的存活率分别为 80%。合成的 AgNPs 对上皮样表型口腔鳞癌细胞(CLS-354/WT)的抗癌活性 IC50 为 11.58 μg/mL。结果表明,生物制剂产生的 AgNPs 具有多功能属性,可作为一种潜在的治疗剂。
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引用次数: 0
Strategic insights of imparting flame retardancy into nano-cellulosic materials: A review 在纳米纤维素材料中添加阻燃剂的战略见解:综述
IF 5.45 Q1 Physics and Astronomy Pub Date : 2024-10-03 DOI: 10.1016/j.nanoso.2024.101369
Shakshi Bhardwaj, Shiva Singh, Dakuri Ramakanth, Vinay Kumar Gupta, Pradip K. Maji
Nanocellulose (NC) is a biomaterial with prospective use as a futuristic material. NC-based materials have several diverse uses, and their demand is growing every year. However, because of their highly flammable nature, the use of NC in harsh settings is greatly restricted. Hence, it is crucial to minimize the risk of fire caused by NC-based materials to maintain a superior level of performance. To diminish the inherent flammability of these substances, flame-retardant elements are often added as additives to produce flame-retardant nanocomposites. Hence, in this review, we have provided a comprehensive summary of the characteristics of NC and the principles and categorization of flame retardants. Subsequently, we have discussed the methods used for the synthesis and characterization of NC-based flame-retardant materials. It also delves into the historical progressions in these materials, intending to enhance the ability to resist flames. The article investigates the fire resistance properties of several materials based on NC, including aerogels, coatings, films, and textiles. The objective of this review is to provide a comprehensive analysis of the future directions and advancements in multi-functional flame-retardant NC materials, with a focus on their potential applications in harsh situations.
纳米纤维素(NC)是一种具有未来用途的生物材料。以 NC 为基础的材料有多种用途,其需求量每年都在增长。然而,由于其极易燃烧的特性,NC 在恶劣环境中的使用受到很大限制。因此,最大限度地降低数控材料引发火灾的风险以保持其卓越的性能水平至关重要。为了降低这些物质固有的易燃性,通常会添加阻燃元素作为添加剂,以生产阻燃纳米复合材料。因此,在本综述中,我们全面总结了纳米复合材料的特性以及阻燃剂的原理和分类。随后,我们讨论了用于合成和表征基于 NC 的阻燃材料的方法。文章还深入探讨了这些材料的历史进程,旨在提高其阻燃能力。文章研究了几种基于数控技术的材料的阻燃特性,包括气凝胶、涂层、薄膜和纺织品。本综述旨在全面分析多功能阻燃数控材料的未来发展方向和进展,重点关注其在恶劣环境中的潜在应用。
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引用次数: 0
The mixed-ligand strategy for structural modification of MOF materials to enhance the photocatalytic degradation and adsorption of organic pollutants: A review 采用混合配体策略对 MOF 材料进行结构修饰,以增强其对有机污染物的光催化降解和吸附能力:综述
IF 5.45 Q1 Physics and Astronomy Pub Date : 2024-10-03 DOI: 10.1016/j.nanoso.2024.101366
Nuhaa Faaizatunnisa , Ratna Ediati , Enis Nadia MD Yusof , Arif Fadlan , Karelius Karelius , Ummu Kulsum , Muhammad Naufal Ariesta
Pollution of water raises many concerns for the community because these substances are considered hazardous and can be detrimental to the environment. Waste such as dyes and pesticide residues are the most significant contributors to organic pollution. These hazardous and toxic materials must be properly removed from the environment to ensure and protect human health, safety, and the environment. Adsorption and photodegradation are two effective water purification techniques with high efficiency, economy, and ease of operation, promising environmental remediation through efficient energy use. Metal-organic frameworks (MOFs) that combine metal ions with organic ligands have diverse physical and chemical properties, making them excellent materials for removing toxic pollutants. MOFs possess unique structural properties and are utilized in the latest technological advancements for removing pesticides, heavy metal ions, pharmaceutical waste, and dyes. The functionalization, modification, defects, and deformations of adsorbents can improve the adsorption and photocatalytic performance of MOFs. Several essential factors related to MOF synthesis have been studied concerning structural properties, the basis of linker functionalization, the synthetic strategy of MIX-MOF assembly, mixed ligands, and framework defects, which can improve MOF performance in certain areas. Several topics will be discussed in this review, including MOFs, the strategy of using mixed ligands in MOF synthesis, and their application for treating environmental pollution.
水污染引起了社会的许多关注,因为这些物质被认为是有害的,会对环境造成危害。染料和杀虫剂残留物等废物是造成有机污染的最主要因素。这些有害和有毒物质必须从环境中适当清除,以确保和保护人类健康、安全和环境。吸附和光降解是两种有效的水净化技术,具有高效、经济、操作简便等特点,有望通过有效利用能源来修复环境。金属有机框架(MOFs)将金属离子与有机配体结合在一起,具有多种物理和化学特性,是去除有毒污染物的绝佳材料。MOFs 具有独特的结构特性,可用于去除杀虫剂、重金属离子、医药废弃物和染料等最新的技术进步。吸附剂的功能化、改性、缺陷和变形可以提高 MOFs 的吸附和光催化性能。与 MOF 合成有关的几个重要因素已得到研究,包括结构特性、连接体功能化基础、MIX-MOF 组装合成策略、混合配体和框架缺陷,这些因素可以改善 MOF 在某些领域的性能。本综述将讨论几个主题,包括 MOF、在 MOF 合成中使用混合配体的策略及其在处理环境污染中的应用。
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引用次数: 0
Eco-friendly approach for carboxymethyl cellulose isolation from durian peel waste and aerogel scaffold preparation 从榴莲皮废弃物中分离羧甲基纤维素并制备气凝胶支架的生态友好型方法
IF 5.45 Q1 Physics and Astronomy Pub Date : 2024-10-02 DOI: 10.1016/j.nanoso.2024.101345
Kanchan Jha , Esam Bashir Yahya , Rahul Dev Bairwan , Mustafa Sabri , H.P.S. Abdul Khalil , Mardiana Idayu Ahmad , Indra Surya
This research introduces a sustainable method for extracting carboxymethyl cellulose (CMC) from durian peel waste via supercritical carbon dioxide (Sc.CO2) processing, leading to the development of advanced aerogel scaffolds. The study evaluates the influence of Sc.CO2 treatment times (60, 90, and 120 min) on the properties of the produced CMC, investigating enhancements in terms of thermal stability, crystallinity, and mechanical attributes through thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and mechanical strength assessments. It was discovered that a 90-minute treatment duration yielded CMC aerogels with notable improvements in porosity, structural robustness, and mechanical resilience. This innovative approach not only proposes a viable strategy for repurposing agricultural by-products but also significantly augments the functional qualities of CMC aerogels, rendering them highly applicable in diverse fields. The outcomes underscore the efficiency of Sc.CO2 treatment in refining the mechanical and thermal characteristics of CMC derived from durian peel waste, facilitating the creation of aerogel scaffolds poised for use in various sectors including drug delivery, water purification, and eco-friendly packaging, thereby contributing to the global initiatives for sustainability and efficient waste management.
本研究介绍了一种通过超临界二氧化碳(Sc.CO2)处理从榴莲皮废弃物中提取羧甲基纤维素(CMC)的可持续方法,从而开发出先进的气凝胶支架。该研究评估了 Sc.CO2 处理时间(60、90 和 120 分钟)对所生产的 CMC 性能的影响,通过热重分析(TGA)、差示扫描量热仪(DSC)和机械强度评估,研究了热稳定性、结晶度和机械属性方面的改进。研究发现,90 分钟的处理时间可产生 CMC 气凝胶,其孔隙率、结构坚固性和机械韧性都有明显改善。这种创新方法不仅为农业副产品的再利用提出了一种可行的策略,而且还大大提高了 CMC 气凝胶的功能品质,使其在不同领域都有很高的应用价值。研究结果表明,Sc.CO2 处理能有效改善从榴莲皮废弃物中提取的 CMC 的机械和热特性,促进气凝胶支架的创造,使其可用于药物输送、水净化和生态友好型包装等多个领域,从而为可持续发展和有效废物管理的全球倡议做出贡献。
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引用次数: 0
Poole-Frenkel conduction in CdS single-layered and CdS/SnS2 heterojunction electrode system CdS 单层和 CdS/SnS2 异质结电极系统中的 Poole-Frenkel 传导
IF 5.45 Q1 Physics and Astronomy Pub Date : 2024-10-02 DOI: 10.1016/j.nanoso.2024.101359
Yowa Nanung , Lohnye Tangjang , Hirendra Das , P.K. Kalita
In this communication, the prevalence of Poole-Frenkel conduction mechanism in two distinct semiconductor systems, CdS single-layered and CdS/SnS2 heterojunction electrode systems, is reported. X-ray diffraction (XRD) exhibits the formation of CdS quantum dots (QDs). A High resolution transmission electron microscopy (HRTEM) shows a discrete particle distribution of SnS2, tends to assemble into nanosheets. Poole-Frenkel conduction arises due to the trap distribution of CdS dots, modified by SnS2 sheets. Furthermore, the formation of heterojunctions with SnS2 shows promising enhancement in charge transport, characterized by reduced trap density and improved conductivity compared pristine CdS. The findings provide valuable insights into the fundamental charge transport processes in CdS/SnS2 system and offer potential avenues for optimizing the performance of electronic devices.
在这篇通讯中,报告了普尔-弗伦克尔传导机制在两种不同的半导体系统(CdS 单层和 CdS/SnS2 异质结电极系统)中的普遍存在。X 射线衍射 (XRD) 显示了 CdS 量子点 (QD) 的形成。高分辨率透射电子显微镜(HRTEM)显示 SnS2 呈离散颗粒分布,并趋向于组装成纳米片。普尔-弗伦克尔传导是由于被 SnS2 薄片修饰的 CdS 点的陷阱分布造成的。此外,与 SnS2 形成的异质结有望增强电荷传输,其特点是与原始 CdS 相比,阱密度降低,导电性提高。这些发现为了解 CdS/SnS2 系统的基本电荷传输过程提供了宝贵的见解,并为优化电子器件的性能提供了潜在的途径。
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引用次数: 0
3D carbon sponge-derived from red onion skin for solid-state supercapacitor 用于固态超级电容器的红洋葱皮三维碳海绵
IF 5.45 Q1 Physics and Astronomy Pub Date : 2024-10-01 DOI: 10.1016/j.nanoso.2024.101355
Pitchaimani Veerakumar , Arun Prakash Periasamy , Arumugam Sangili , Chih-Ching Huang , Huan-Tsung Chang
<div><div>Hierarchical pore development has been widely explored with various biomass precursors using one or more surface activating agents and porogens to prepare three-dimensional (3D) carbon materials such as activated carbons (ACs) with high specific surface areas (SSA) for the fabrication of electrical double layer (EDLC) supercapacitor (SC) for efficient charge storage. However, purity, quality and performance of biomass derived ACs are usually concerned as toxic gases are produced from activating agents and porogens. In further connection with an effective pore structure control in such ACs, selection of the activating agent and the carbonization conditions is highly crucial. We noted that zinc chloride (ZnCl<sub>2</sub>) activation has not been attempted with red onion (<em>Allium cepa. L</em>) skins for energy storage applications. This motivated us to have a detailed investigation of the ZnCl<sub>2</sub> effect on red onion skins at different temperatures. In this study to see if we can correlate the activation process to be investigated with the pore structure management in the ACs derived, mainly to see if we can deduce some meaningful relationship with the energy storage performance of the resulting 3D carbon structures. We found that 3D carbon sponges can be derived from red onion skins at 900 °C for 3 h under inert atmosphere due to the inherent assembly of quercetin molecules and anthocyanins via hydrogen bonding and π–π stacking interactions assisted surface activation, carbonization, and aromatization processes. Surface porosity measurements using BET method revealed that the SSA (∼2398 m<sup>2</sup> g<sup>−1</sup>) of 3D porous carbon sponges is comparable or higher than the most other biomass derived ACs. High resolution transmission electron microscopic (HRTEM) results confirmed that around each micropore and mesopore, five to ten graphitic nanolayers were created, which further interacted to form conducting networks on the 3D sponge surface. Such conducting networks stabilized the hierarchical pores and circulated the electrolyte in and around the micro/-nano cavity via controlled diffusion process which promoted an efficient charge storage at the electrochemical interface. As a result, the 3D carbon material provided a specific capacitance (<em>C</em><sub>sp</sub>) value of 265 F g<sup>−1</sup> at a current density (CD) of 1.0 Ag<sup>−1</sup>, with two-fold higher than that provided by commercial AC materials. The all-solid-state SC fabricated with 3D carbon sponge provided a high energy density (ED) of 19.9 Wh kg<sup>−1</sup> at a power density (PD) of 12.5 KW kg<sup>−1</sup> with minimum IR drop (∼0.05 V), which is comparable to the ED and PD values for biomass-derived ACs reported in the literature. This work provides new insights into the preparation of 3D nanostructured ACs with sponge-like texture from a biomass precursor with good control over 3D structure, graphitic networks, and porosity development for improved e
人们广泛利用各种生物质前体,使用一种或多种表面活化剂和致孔剂来制备三维(3D)碳材料,如具有高比表面积(SSA)的活性碳(AC),用于制造高效电荷存储的双电层(EDLC)超级电容器(SC)。然而,生物质衍生活性炭的纯度、质量和性能通常受到关注,因为活化剂和孔隙剂会产生有毒气体。为了进一步有效控制此类 AC 的孔隙结构,活化剂和碳化条件的选择至关重要。我们注意到氯化锌(ZnCl2)活化还没有尝试过与红洋葱(Allium cepa. L)皮一起用于储能应用。这促使我们对氯化锌在不同温度下对红洋葱皮的影响进行详细调查。在这项研究中,我们想看看是否能将所要研究的活化过程与所得到的三维碳结构中的孔隙结构管理联系起来,主要是想看看我们是否能推断出与所得到的三维碳结构的储能性能之间的一些有意义的关系。我们发现,由于槲皮素分子和花青素在表面活化、碳化和芳香化过程中通过氢键和π-π堆叠相互作用固有地组装在一起,因此在惰性气氛下于900 °C下3小时可从红洋葱皮中衍生出三维碳海绵。利用 BET 法测量表面孔隙率发现,三维多孔碳海绵的 SSA(2398 平方米克-1)与大多数其他生物质衍生 AC 相似或更高。高分辨率透射电子显微镜(HRTEM)结果证实,在每个微孔和中孔周围都形成了五到十个石墨纳米层,它们进一步相互作用,在三维海绵表面形成了导电网络。这种导电网络稳定了分层孔隙,并通过受控扩散过程使电解质在微/纳米腔内外循环,从而促进了电化学界面的高效电荷存储。因此,三维碳材料在电流密度(CD)为 1.0 Ag-1 时的比电容(Csp)值为 265 F g-1,比商用交流电材料高出两倍。用三维海绵碳制造的全固态 SC 在功率密度(PD)为 12.5 KW kg-1 时可提供 19.9 Wh kg-1 的高能量密度(ED),且红外电压降(∼0.05 V)最小,与文献报道的生物质源 AC 的 ED 值和 PD 值相当。这项工作为利用生物质前驱体制备具有海绵状质地的三维纳米结构交流电提供了新的视角,并很好地控制了三维结构、石墨网络和孔隙率的发展,从而改善了能量存储应用。
{"title":"3D carbon sponge-derived from red onion skin for solid-state supercapacitor","authors":"Pitchaimani Veerakumar ,&nbsp;Arun Prakash Periasamy ,&nbsp;Arumugam Sangili ,&nbsp;Chih-Ching Huang ,&nbsp;Huan-Tsung Chang","doi":"10.1016/j.nanoso.2024.101355","DOIUrl":"10.1016/j.nanoso.2024.101355","url":null,"abstract":"&lt;div&gt;&lt;div&gt;Hierarchical pore development has been widely explored with various biomass precursors using one or more surface activating agents and porogens to prepare three-dimensional (3D) carbon materials such as activated carbons (ACs) with high specific surface areas (SSA) for the fabrication of electrical double layer (EDLC) supercapacitor (SC) for efficient charge storage. However, purity, quality and performance of biomass derived ACs are usually concerned as toxic gases are produced from activating agents and porogens. In further connection with an effective pore structure control in such ACs, selection of the activating agent and the carbonization conditions is highly crucial. We noted that zinc chloride (ZnCl&lt;sub&gt;2&lt;/sub&gt;) activation has not been attempted with red onion (&lt;em&gt;Allium cepa. L&lt;/em&gt;) skins for energy storage applications. This motivated us to have a detailed investigation of the ZnCl&lt;sub&gt;2&lt;/sub&gt; effect on red onion skins at different temperatures. In this study to see if we can correlate the activation process to be investigated with the pore structure management in the ACs derived, mainly to see if we can deduce some meaningful relationship with the energy storage performance of the resulting 3D carbon structures. We found that 3D carbon sponges can be derived from red onion skins at 900 °C for 3 h under inert atmosphere due to the inherent assembly of quercetin molecules and anthocyanins via hydrogen bonding and π–π stacking interactions assisted surface activation, carbonization, and aromatization processes. Surface porosity measurements using BET method revealed that the SSA (∼2398 m&lt;sup&gt;2&lt;/sup&gt; g&lt;sup&gt;−1&lt;/sup&gt;) of 3D porous carbon sponges is comparable or higher than the most other biomass derived ACs. High resolution transmission electron microscopic (HRTEM) results confirmed that around each micropore and mesopore, five to ten graphitic nanolayers were created, which further interacted to form conducting networks on the 3D sponge surface. Such conducting networks stabilized the hierarchical pores and circulated the electrolyte in and around the micro/-nano cavity via controlled diffusion process which promoted an efficient charge storage at the electrochemical interface. As a result, the 3D carbon material provided a specific capacitance (&lt;em&gt;C&lt;/em&gt;&lt;sub&gt;sp&lt;/sub&gt;) value of 265 F g&lt;sup&gt;−1&lt;/sup&gt; at a current density (CD) of 1.0 Ag&lt;sup&gt;−1&lt;/sup&gt;, with two-fold higher than that provided by commercial AC materials. The all-solid-state SC fabricated with 3D carbon sponge provided a high energy density (ED) of 19.9 Wh kg&lt;sup&gt;−1&lt;/sup&gt; at a power density (PD) of 12.5 KW kg&lt;sup&gt;−1&lt;/sup&gt; with minimum IR drop (∼0.05 V), which is comparable to the ED and PD values for biomass-derived ACs reported in the literature. This work provides new insights into the preparation of 3D nanostructured ACs with sponge-like texture from a biomass precursor with good control over 3D structure, graphitic networks, and porosity development for improved e","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"40 ","pages":"Article 101355"},"PeriodicalIF":5.45,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142416240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Oxide-coated Al-Cu-based nanoparticles for enhanced solar water heating 用于增强太阳能热水器的氧化物涂层铝铜纳米粒子
IF 5.45 Q1 Physics and Astronomy Pub Date : 2024-10-01 DOI: 10.1016/j.nanoso.2024.101361
Sai Teja Banala, Adithyan TR, Saisupriyalakshmi Saravanan, Shyam V.S., Sreeram K. Kalpathy, Tiju Thomas
We report the use of oxide-coated Al-Cu nanoparticles for enhanced solar water heating purposes. Both Al and Cu are earth-abundant metals, so they are chosen in this work. Furthermore, Al- and Cu-based nanoparticles have substantial absorption cross-sections in UV, visible, and some parts of the near-infrared region (∼300–1100 nm). This makes these nanoparticles useful in solar water heating applications. An aqueous synthesis approach, which yields oxide-coated Al-Cu-based nanoparticles, is used since it is scalable and eco-friendly. The effects of particle loading between 0.025–0.1 wt% in water, for use as a nanofluid, are tested under an infrared source. The oxide-coated Al-Cu nanoparticles are mostly cubic in morphology. The particles are stable in the nanofluid with zeta potential values >30 mV. On dispersing 0.075 wt% of these nanoparticles in water, a 14–16 % enhancement in the saturation temperature is obtained. This implies that the heating kinetic constants are increased by ∼15 % upon addition of these nanoparticles to water. The scattering and absorption cross-sections for the Al-Cu-oxide based nanoparticle system were determined computationally by solving the Maxwell’s equations. The peak scattering cross-section was found to occur at a wavelength of 728 nm for a particle size of 50 nm. The values obtained computationally were used as inputs to solve the energy balance equations for simulating a water heating setup. A maximum temperature of 347.5 K is predicted for a volume of 500 ml water over a 12-hour solar heating time period, with an initial ambient temperature of 305 K. These values are commensurate with the experimental data, thus validating the model’s accuracy. These results suggest that Al-Cu-based nanoparticles would be promising candidates for use in solar water heating and thermal nanofluid applications.
我们报告了氧化物涂层铝铜纳米粒子在太阳能热水器中的应用。铝和铜都是富含地球的金属,因此本研究选择了它们。此外,铝基和铜基纳米粒子在紫外线、可见光和近红外区域(300-1100 纳米)的某些部分有很大的吸收截面。这使得这些纳米粒子在太阳能热水器应用中大有用武之地。由于水合成法具有可扩展性和生态友好性,因此采用了水合成法,这种方法可获得氧化物包覆的铝铜基纳米粒子。在红外光源下测试了水中 0.025-0.1 wt% 的颗粒负载量对用作纳米流体的影响。氧化物包覆的铝铜纳米粒子大部分呈立方形态。颗粒在纳米流体中稳定,zeta 电位为 30 mV。在水中分散 0.075 wt% 的这些纳米粒子后,饱和温度提高了 14-16%。这意味着在水中加入这些纳米粒子后,加热动力学常数增加了 15%。通过求解麦克斯韦方程,计算确定了铝铜氧化物纳米粒子系统的散射和吸收截面。在粒径为 50 纳米时,散射截面峰值出现在波长为 728 纳米处。计算得出的数值被用作模拟水加热装置的能量平衡方程的求解输入。在初始环境温度为 305 K 的情况下,预测在 12 小时的太阳加热时间内,500 毫升水的最高温度为 347.5 K。这些数值与实验数据相符,从而验证了模型的准确性。这些结果表明,铝铜基纳米粒子有望用于太阳能热水器和热纳米流体应用。
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引用次数: 0
Utilizing Mitracarpus scaber extracts for green synthesis of silver nanoparticles: Exploring physicochemical properties and potential chemopreventive activity against N-methyl-nitrosourea- induced prostate carcinoma in rats 利用糙米提取物绿色合成银纳米粒子:探索N-甲基亚硝基脲诱导的大鼠前列腺癌的理化性质和潜在化学预防活性
IF 5.45 Q1 Physics and Astronomy Pub Date : 2024-10-01 DOI: 10.1016/j.nanoso.2024.101363
Temitayo I. Adesipe , Emeka J. Iweala , Ismail O. Ishola , Omotayo A. Arotiba , Abiodun H. Adebayo
This study evaluated the influence of silver nanoparticles (AgNPs) biosynthesized using Mitracarpus scaber (M. scaber) extracts on testosterone and n-methyl-nitrosourea (MNU)-induced prostate carcinoma in rat. AgNPs were synthesized from 0.1 M AgNO3 solution using the aqueous and ethanol extracts of M. scaber (AMS and EMS) as reducing as well as capping agents. The AgNPs produced using AMS (ANP) and EMS (ENP) were then analyzed via various spectroscopic experiments. Later on, the biological effects of ANP and ENP were evaluated on testosterone and n-methyl-nitrosourea (MNU)-induced prostate carcinoma in rat. The study found that ANP and ENP have characteristic crystalline structures, with particle sizes ranging from ∼5–20 nm and prominent absorbance peak at 425 nm was observed for ANP while absorption peaks at 410 and 675 nm were observed for ENP indicating that ANP is isotropic in nature while ENP is anisotropic in nature. The findings regarding chemopreventive effects on prostate carcinogenesis revealed that ANP caused a significant (p < 0.05) reduction in prostate weight. However, both ANP and ENP, ameliorated prostatic hypertrophy (i.e., decreased prostate enlargement and acini proliferation) in rats induced with high-grade prostatic intraepithelial neoplasia. In comparison to the PCa group as well as other groups, ENP significantly (p < 0.05) decreased the mean concentrations of prostate-specific antigen (PSA), interleukin-6 (IL-6), and tumor necrosis factor-alpha (TNF-). Also, ENP significantly restored depleted activities levels of superoxide dismutase (SOD) and catalase caused by prostate carcinogenesis. Furthermore, ENP caused a significant (p < 0.05) reduction in glutathione (GSH) levels, an upregulation of DNA methyltransferase (DNMT1 and DNMT3b) expression, and activation of caspase 7. The results of the present study showed the potential anti-inflammatory, antioxidant and anti-neoplastic effects of AgNPs of M. scaber ethanol extract which implies that it could be used as an adjunct in the treatment of prostate cancer.
本研究评估了利用疮痂树(Mitracarpus scaber,M. scaber)提取物生物合成的银纳米粒子(AgNPs)对睾酮和亚硝基脲(n-methyl-nitrosourea,MNU)诱导的大鼠前列腺癌的影响。以葶苈子的水提取物和乙醇提取物(AMS和EMS)为还原剂和封端剂,从0.1 M AgNO3溶液中合成了AgNPs。使用 AMS(ANP)和 EMS(ENP)制备的 AgNPs 随后通过各种光谱实验进行了分析。随后,研究人员评估了 ANP 和 ENP 对睾酮和 n-甲基亚硝基脲(MNU)诱导的大鼠前列腺癌的生物效应。研究发现,ANP 和 ENP 具有特征性的结晶结构,粒径范围为 5-20 纳米,ANP 在 425 纳米波长处有明显的吸收峰,而 ENP 在 410 纳米波长和 675 纳米波长处有吸收峰,这表明 ANP 具有各向同性,而 ENP 具有各向异性。关于对前列腺癌发生的化学预防作用的研究结果表明,ANP 能显著(p < 0.05)减少前列腺重量。不过,ANP 和 ENP 都能改善高级别前列腺上皮内瘤变大鼠的前列腺肥大(即减少前列腺增大和尖头增生)。与 PCa 组和其他组相比,ENP 能显著降低前列腺特异性抗原(PSA)、白细胞介素-6(IL-6)和肿瘤坏死因子-α(TNF-)的平均浓度(p < 0.05)。此外,ENP 还能明显恢复前列腺癌导致的超氧化物歧化酶(SOD)和过氧化氢酶的活性水平。此外,ENP 还会导致谷胱甘肽(GSH)水平明显降低(p < 0.05)、DNA 甲基转移酶(DNMT1 和 DNMT3b)表达上调以及 caspase 7 激活。本研究结果表明,疥螨乙醇提取物中的 AgNPs 具有潜在的抗炎、抗氧化和抗肿瘤作用,这意味着它可用作治疗前列腺癌的辅助药物。
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引用次数: 0
Advancements in nanoparticles-based therapies for biomedical applications 基于纳米粒子的生物医学应用疗法的进展
IF 5.45 Q1 Physics and Astronomy Pub Date : 2024-10-01 DOI: 10.1016/j.nanoso.2024.101365
VijayaDurga V. V Lekkala , Madhava C. Reddy , Vajra C. Reddy , Swarna Kumari Kanthirigala , Sriram Chitta , Kakarla Raghava Reddy , Dakshayani Lomada
Nanoparticles present innovative approaches to enhance the treatment of various health disorders. Within a biological setting, they can penetrate cell membranes and interact with key biological molecules like nucleic acids, proteins, and lipids. Researchers have developed both inorganic and organic nanoparticles as high-quality nanocarriers for diverse biomedical purposes, including cell imaging, drug delivery, biosensors, and therapies targeting microbial infections, cancer, inflammation, and autoimmune diseases. Specifically, nanoparticles loaded with anti-inflammatory medications have shown potential in targeting specific organs, thereby improving drug effectiveness in diseases like multiple sclerosis. The immune system, a complex network of cells, organs, and tissues, defends the body against infections and diseases. Autoimmune diseases occur when immune cells become overactive within their tissues, often influenced by breakdowns in self-tolerance mechanisms and various sex-related and environmental factors. These diseases affect roughly 10 % of the global population, predominantly women. Traditional immune therapies, such as monoclonal antibodies and tumor necrosis factor inhibitors, can inadvertently suppress healthy immune cells, leading to adverse reactions. Consequently, nanoparticle-based therapies are gaining attention for their ability to target specific immune cells and enhance treatment efficacy while minimizing toxicity to non-target cells. This review provides updates on the types of nanoparticles used for treating various autoimmune disorders, focusing on strategies to limit toxicity to healthy cells.
纳米粒子是治疗各种健康疾病的创新方法。在生物环境中,它们可以穿透细胞膜,与核酸、蛋白质和脂质等关键生物分子相互作用。研究人员已开发出无机和有机纳米粒子作为高质量的纳米载体,用于多种生物医学用途,包括细胞成像、药物输送、生物传感器以及针对微生物感染、癌症、炎症和自身免疫性疾病的疗法。具体而言,装载抗炎药物的纳米粒子已显示出针对特定器官的潜力,从而提高了治疗多发性硬化症等疾病的药物疗效。免疫系统是一个由细胞、器官和组织组成的复杂网络,能够抵御感染和疾病。当免疫细胞在其组织内过度活跃时,就会发生自身免疫性疾病,这通常是受自我耐受机制的破坏以及各种与性有关的因素和环境因素的影响。这些疾病影响着全球大约 10% 的人口,主要是女性。传统的免疫疗法,如单克隆抗体和肿瘤坏死因子抑制剂,会无意中抑制健康的免疫细胞,导致不良反应。因此,基于纳米粒子的疗法因其能够靶向特异性免疫细胞并提高疗效,同时最大限度地减少对非靶细胞的毒性而备受关注。本综述提供了用于治疗各种自身免疫性疾病的纳米粒子类型的最新信息,重点介绍了限制对健康细胞毒性的策略。
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引用次数: 0
Study of hybrid nanofluid flow in a porous medium over an exponentially stretching sheet under Joule heating and thermal radiation: Finite difference 焦耳加热和热辐射条件下多孔介质在指数拉伸薄片上的混合纳米流体流动研究:有限差分
IF 5.45 Q1 Physics and Astronomy Pub Date : 2024-09-30 DOI: 10.1016/j.nanoso.2024.101350
Salma Khalil , Tasawar Abbas , R. Nawaz
The significant purpose of present investigation of the behavior of a nanofluid's in magneto-hydrodynamics (MHD), mass transfer, Joule heating, and boundary layer transfer characteristics over an exponentially stretching sheet in a porous medium and thermal radiation effects. The article's goal is to look at the fluid flow and heat transmission characteristics from a sheet of hybrid nanoparticles. The partial differential equations (PDEs) that were derived for the mathematical model were converted using the proper similarity transformation into ordinary differential equations (ODEs). The hybrid nanofluid composed of 97 % of ethyl glycol (EG) and the volume concentration of Magnetite (Fe3O4) and Copper(Cu) are ranging from 0.5 % to 2.5 % both respectively. The effects of thermal radiation, stretching rate, Joule heating, porous medium permeability, and nanoparticle volume fraction on the flow and heat transmission properties are investigated by numerical simulations using the finite difference method (FDM). The analysis reveals that the inclusion of nanofluids enhance the thermal conductivity and enhance the heat transfer rate. Additionally, the influence of variable viscosity on the flow behavior and thermal characteristics are examined graphically. The effects of variable viscosity and thermal conductivity are examined, as it has significance in optimizing system under various thermal and magnetic effects. This study offers a pathway to develop more efficient thermal management solutions, by contributing to technological advancement and energy saving. The key findings of present study reveal that the temperature profile rises significantly due to Joule heating effects. The Nusselt number reveal an improvement of about 12 % when the volume fraction of nano particles is increased by 1–4 % indicating the enhancement in heat transfer efficiency. Similarly, the velocity profile was influenced by porous medium permeability as 11 % increase in porosity result a 18 % decrease in velocity profile.
By using parametric research, the role of physical parameters in determining the local skin-friction coefficient, temperature, nanoparticle volume percentage, and longitudinal velocity profiles, local Nusselt number, and local Sherwood number are thoroughly examined. A graphic representation of the velocity, temperature, and concentration distribution findings is presented.
本文的重要目的是研究纳米流体在多孔介质中的磁流体力学(MHD)、传质、焦耳热、指数拉伸薄片上的边界层传递特性以及热辐射效应。文章的目的是研究混合纳米颗粒薄片的流体流动和热传递特性。通过适当的相似性转换,将数学模型推导出的偏微分方程(PDE)转换为常微分方程(ODE)。混合纳米流体由 97% 的乙二醇(EG)组成,磁铁矿(Fe3O4)和铜(Cu)的体积浓度分别为 0.5% 至 2.5%。通过使用有限差分法(FDM)进行数值模拟,研究了热辐射、拉伸率、焦耳热、多孔介质渗透性和纳米颗粒体积分数对流动和热传导特性的影响。分析结果表明,加入纳米流体后,导热性能增强,传热速率提高。此外,还以图形方式研究了可变粘度对流动行为和热特性的影响。研究了可变粘度和热导率的影响,因为它对在各种热效应和磁效应下优化系统具有重要意义。这项研究为开发更高效的热管理解决方案提供了一条途径,有助于技术进步和节能。本研究的主要发现表明,由于焦耳热效应,温度曲线显著上升。当纳米颗粒的体积分数增加 1-4% 时,努塞尔特数提高了约 12%,这表明热传导效率得到了提高。同样,速度曲线也受到多孔介质渗透性的影响,孔隙率增加 11% 会导致速度曲线下降 18%。通过参数研究,我们深入研究了物理参数在决定局部表皮摩擦系数、温度、纳米颗粒体积百分比、纵向速度曲线、局部努塞尔特数和局部舍伍德数方面的作用。图解显示了速度、温度和浓度分布的研究结果。
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引用次数: 0
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