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Numerical simulation of the effect of coaxial and cross-axis injection modes on pulverized coal combustion in the raceway of blast furnace tuyere 同轴和横轴喷射模式对高炉炉膛滚道内煤粉燃烧影响的数值模拟
IF 4.1 2区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-06-28 DOI: 10.1016/j.partic.2024.06.010
Yunpeng Wang, Lei Gao, Xiaolei Zhou

The aim of this study is to investigate the influence of the angle of the pulverized coal (PC) injection lance on the combustion characteristics of fuel in the raceway of blast furnace tuyeres. Using FLUENT software, a Euler-Lagrange three-dimensional numerical model was constructed to analyze the influence of different positions of blast furnace tuyere coal powder injection lance (coaxial and cross-axis) on key parameters such as temperature distribution, gas flow, and combustion efficiency. The results demonstrate that adjusting the angle of the injection lance significantly modifies the average and peak temperatures in the raceway, while the composition of gas components remains relatively stable. When the injection lance angle is 10°, the average temperature and peak temperature in the raceway are 2294 K and 2747 K, respectively. When the injection lance angle is 12°, the combustion efficiency of the PC reaches 80.8%. This study reveals the significant impact of the injection lance angle on the combustion process. Especially at an angle of 12°, the combustion efficiency of the blast furnace significantly improves. With coaxial injection, the combustion rate increases as the distance between the injection lance tip and the tuyere increases. This paper is instructive for the optimization of the blast furnace combustion system, which improve fuel utilization efficiency and reduce environmental emissions. This paper provides practical recommendations for adjusting blast furnace operational parameters, offering insights for achieving more efficient and environmentally friendly industrial production.

本研究旨在探讨煤粉喷枪的角度对高炉风口燃料燃烧特性的影响。利用 FLUENT 软件构建了欧拉-拉格朗日三维数值模型,分析了高炉风口煤粉喷枪不同位置(同轴和横轴)对温度分布、煤气流量和燃烧效率等关键参数的影响。结果表明,调整喷枪角度可显著改变滚道内的平均温度和峰值温度,而煤气成分的组成则保持相对稳定。当喷枪角度为 10° 时,滚道内的平均温度和峰值温度分别为 2294 K 和 2747 K。当喷枪角度为 12°时,PC 的燃烧效率达到 80.8%。这项研究揭示了喷枪角度对燃烧过程的重要影响。特别是当喷射角为 12°时,高炉的燃烧效率明显提高。在同轴喷射的情况下,随着喷枪枪尖与风口之间距离的增加,燃烧率也会增加。本文对优化高炉燃烧系统、提高燃料利用效率和减少环境排放具有指导意义。本文为调整高炉运行参数提供了实用建议,为实现更高效、更环保的工业生产提供了启示。
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引用次数: 0
Numerically investigation of particle distribution in industrial-scale DTB crystallizer based on CFD modelling 基于 CFD 建模的工业规模 DTB 结晶器颗粒分布数值研究
IF 4.1 2区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-06-28 DOI: 10.1016/j.partic.2024.06.006
Jinju Ma , Weiyu Wang , Wei Huang , Wei Liu , Xinding Yao , Tao Li , Baozeng Ren

The suspension state of crystals in the crystallizer is one of the important indicators for evaluating the adaptability of the crystallizer. This study adopted the Euler-Eulerian two-fluid model to simulate and analyze the fluid motion of solid-liquid two-phase flow in the industrial-grade DTB crystallization kettle, as well as the phase suspension distribution of crystal particles. The main influencing factors investigated are: the heat transfer effect, the height of the bottom of the crystallizer, the number and position of the stirring paddle, crystal size and crystal volume fraction. Based on the research of Euler-Eulerian method to simulate fluids, the Euler-Lagrangian method was further used to simulate the motion state of particle phases with different particle sizes in the crystallizer. It was found that the designed DTB crystallizer has good recycle mixing effect. The particles can be mixed evenly during the operation, which can fully realize the solid-liquid mixing and suspension effect of the drug under study.

结晶器中晶体的悬浮状态是评价结晶器适应性的重要指标之一。本研究采用欧拉-欧勒二流体模型模拟分析了工业级 DTB 结晶釜内固液两相流的流体运动以及晶体颗粒的相悬浮分布。研究的主要影响因素包括:传热效果、结晶器底部高度、搅拌桨的数量和位置、晶体尺寸和晶体体积分数。在研究欧拉-欧拉法模拟流体的基础上,进一步采用欧拉-拉格朗日法模拟结晶器中不同粒度颗粒相的运动状态。结果发现,所设计的 DTB 结晶器具有良好的循环混合效果。颗粒在运行过程中能够均匀混合,充分实现了所研究药物的固液混合和悬浮效果。
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引用次数: 0
Preparation and characterization of high-reactivity explosive-based nano-boron microspheres 高活性炸药基纳米硼微球的制备与表征
IF 4.1 2区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-06-27 DOI: 10.1016/j.partic.2024.06.009
Chen Dong , Yi Wang , Kanghui Jia , Dan Song , Xiaolan Song , Chongwei An

Boron nanoparticles, with their remarkably high gravimetric and volumetric calorific values, emerge as the most promising fuel in energetic fields. However, challenges such as susceptibility to oxidation, high ignition temperature, and low combustion efficiency have constrained their further applications. In this study, we fabricated high explosives based nano-boron microspheres with uniform size using the electrostatic spray method, in which the boron nanoparticles and high explosives (CL-20 or PETN) are closely bonded together by fluorinated polymer (F2602) and evenly distributed. The results indicated that the microspheres exhibited high sphericity and showed an enhanced antioxidant capability. The addition of high-energy explosives not only reduced the thermal oxidation temperature of nano-boron powder within the microspheres but also significantly enhanced the pressurization rate. Additionally, the microspheres with added high-energy explosives released more energy during the combustion process. Compared to physically mixed samples, electrostatically sprayed microspheres with a uniform microstructure still exhibited higher reactivity. Therefore, the design and synthesis of microspheres with controllable structures using the electrostatic spray method show promising application prospects.

硼纳米粒子具有极高的重力热值和体积热值,是能源领域最有前途的燃料。然而,易氧化、点火温度高和燃烧效率低等挑战限制了它们的进一步应用。在本研究中,我们采用静电喷涂法制备了尺寸均匀的基于高能炸药的纳米硼微球,其中硼纳米粒子和高能炸药(CL-20 或 PETN)通过含氟聚合物(F2602)紧密结合在一起并均匀分布。结果表明,微球具有很高的球形度,抗氧化能力也有所增强。高能炸药的加入不仅降低了微球内纳米硼粉末的热氧化温度,还显著提高了加压速度。此外,添加了高能炸药的微球在燃烧过程中释放出更多的能量。与物理混合样品相比,具有均匀微观结构的静电喷涂微球仍然表现出更高的反应活性。因此,利用静电喷雾法设计和合成具有可控结构的微球具有广阔的应用前景。
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引用次数: 0
The transition to turbulent fluidization in a gas-solid fluidized bed operating from ambient temperature to 1600 °C 从环境温度到 1600 °C 的气固流化床向湍流化的过渡
IF 4.1 2区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-06-26 DOI: 10.1016/j.partic.2024.06.008
Qingjin Zhang , Liangliang Fu , Guangwen Xu , Dingrong Bai

Turbulent fluidized bed proves effective in industrial processes due to superior heat and mass transfer and chemical reaction performance. However, understanding the transition to turbulent fluidization remains limited, especially at temperatures exceeding 1000 °C, making it challenging to develop high-temperature fluidized bed applications. This paper presents an experimental investigation on the turbulent fluidization onset velocity (Uc), measured in a 30 mm diameter bed using corundum particles with average diameters from 0.68 mm to 1.58 mm in temperatures from ambient to 1600 °C. Experimental results reveal that Uc increases with temperature up to 600 °C, stabilizes within the 600–1200 °C range, and then decreases above 1200 °C, demonstrating the varying relative significance of hydrodynamic and interparticle forces at different temperatures. To help design and operate high-temperature applications of turbulent fluidization, we developed Uc correlations based on experimental data from both literature sources and this study, covering temperatures of up to 1600 °C and particles of Groups A to D.

湍流床因其卓越的传热、传质和化学反应性能而被证明在工业过程中非常有效。然而,对湍流化过渡的了解仍然有限,尤其是在温度超过 1000 °C 的情况下,这使得开发高温流化床应用具有挑战性。本文介绍了一项关于湍流化起始速度(Uc)的实验研究,该实验是在一个直径为 30 毫米的床中,使用平均直径为 0.68 毫米至 1.58 毫米的刚玉颗粒,在环境温度至 1600 ℃ 的条件下进行的。实验结果表明,Uc 在 600 ℃ 以下随温度升高而增加,在 600-1200 ℃ 范围内趋于稳定,然后在 1200 ℃ 以上降低,这表明流体动力和颗粒间作用力在不同温度下的相对重要性各不相同。为了帮助设计和操作湍流流化的高温应用,我们根据文献资料和本研究的实验数据开发了 Uc 相关性,涵盖温度高达 1600 °C、A 至 D 组的颗粒。
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引用次数: 0
Experimental and theoretical analysis of loading characteristics of electret filter media for charged particles 带电粒子驻极体过滤介质负载特性的实验和理论分析
IF 4.1 2区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-06-21 DOI: 10.1016/j.partic.2024.06.007
Yiqi Cai , Rongrong Cai , Lizhi Zhang

The degradation of filtration performance in electret filter media during usage poses a significant challenge. Pre-charging of aerosols has been identified as an effective method to mitigate this issue. However, the effects of particle charging characteristics on the loading characteristics of electret filters still need a comprehensive understanding. In this study, a needle-cylinder corona charger was employed to pre-charge aerosols, and the particle charge state was determined by multiphysics simulation. The effects of particle charge polarity and charge quantity on the loading performance of the electret filter were quantitatively investigated. The results showed that the particle charge polarity had a negligible impact on the loading performance under the condition of the equivalent particle charge quantity. In addition, the charged particles effectively improved the efficiency degradation during the loading process of electret media, with higher charge quantities resulting in more pronounced improvements. The electrostatic attenuation factor showed a negative exponential correlation with the particle charge quantity. This was attributed to the uneven particle deposition on fiber surface due to the attraction of charged particles by the opposite charges on the electret fibers, which alleviated the effect of electrostatic shielding.

驻极体过滤介质在使用过程中过滤性能下降是一个重大挑战。预充气溶胶被认为是缓解这一问题的有效方法。然而,颗粒充电特性对驻极体过滤器负载特性的影响仍需全面了解。本研究采用针筒式电晕充电器对气溶胶进行预充电,并通过多物理场模拟确定粒子的电荷状态。定量研究了粒子电荷极性和电荷量对驻极体过滤器负载性能的影响。结果表明,在等效颗粒电荷量的条件下,颗粒电荷极性对装载性能的影响可以忽略不计。此外,带电粒子能有效改善驻极体介质加载过程中的效率衰减,电荷量越高,改善效果越明显。静电衰减系数与粒子电荷量呈负指数关系。这是因为带电粒子被驻极体纤维上的相反电荷吸引,导致粒子在纤维表面沉积不均匀,从而减轻了静电屏蔽效果。
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引用次数: 0
Facile formation of hierarchical magnesium silicate hydrate microspheres as an adsorbent for the textile dyes 轻松形成作为纺织染料吸附剂的分层硅酸镁水合物微球
IF 4.1 2区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-06-18 DOI: 10.1016/j.partic.2024.06.005
Tin Kyawoo , Naveed Karim , Chao Jiang , Saeed Ahmed , Weiliang Tian , Huiyu Li , Yongjun Feng

Hierarchical porous magnesium silicate hydrate (MSH) microspheres composed of sheets are successfully developed under facile conditions using a hard template. The role of hexadecyltrimethylammonium bromide (CTAB) on the formation and adsorption behavior was also observed for the methyl orange and methylene blue. The formed MSH possesses a surface area of 453.24 m2/g, an average pore size of 6.38 nm, and a pore volume of 0.75 cm3/g without CTAB. Based on the role of CTAB and the change in the ratio of Mg/Si, the MSH retained its sphere-like structure with a variation in pore parameters. The formed MSH was used as an adsorbent to remove methylene blue and methyl orange. The pseudo-second-order kinetic and Langmuir Isotherm models are well-fitted, with a 256.4 mg/g removal capacity and 84.2 mg/g for methylene blue and methyl orange, respectively. The modified MSH with CTAB played a positive role for the methyl orange and a negative role for the methylene blue regarding removal performance.

利用硬模板,在简便条件下成功开发了由片状组成的分层多孔硅酸镁水合物(MSH)微球。同时还观察了十六烷基三甲基溴化铵(CTAB)对甲基橙和亚甲基蓝的形成和吸附行为的作用。形成的 MSH 具有 453.24 m2/g 的表面积、6.38 nm 的平均孔径和 0.75 cm3/g 的孔体积(不含 CTAB)。根据 CTAB 的作用和 Mg/Si 比例的变化,MSH 在孔隙参数变化的情况下保持了球状结构。形成的 MSH 可用作吸附剂去除亚甲基蓝和甲基橙。伪二阶动力学模型和 Langmuir 等温线模型拟合良好,对亚甲基蓝和甲基橙的去除率分别为 256.4 mg/g 和 84.2 mg/g。添加 CTAB 的改性 MSH 对甲基橙的去除性能起积极作用,对亚甲基蓝的去除性能起消极作用。
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引用次数: 0
Simulation of rice grain breakage process based on Tavares UFRJ model 基于塔瓦雷斯 UFRJ 模型的稻谷破碎过程模拟
IF 4.1 2区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-06-18 DOI: 10.1016/j.partic.2024.05.019
Shaohang Shen , Shouyu Ji , Dan Zhao , Yanlong Han , Hao Li , Ze Sun , Zhuozhuang Li , Anqi Li , Wenyu Feng , Jiaming Fei , Fuguo Jia , Yang Li

Understanding the breakage characteristics of rice grains is an important means to reduce rice breakage rate. However, the dynamic breakage mechanism of rice grain is unclear due to the lack of a reasonable breakage model. In this study, the uniaxial compression test and drop weight test of single rice were carried out, the breakage model of rice grain was constructed, the reliability of rice model was verified by the experiment and simulation results. The results showed that the fracture energy distribution of rice can be obtained by uniaxial compression test, the specific fracture energy of rice accords with a lognormal distribution, and the median specific fracture energy of rice is 479.75 J/kg. The damage accumulation coefficient and fragment size distribution of rice can be acquired by drop test, the result of damage accumulation coefficient of rice was 4.3. Rice grain breakage mainly occurs in the milling section of the vertical circulation rice mill.

了解米粒的破损特性是降低米粒破损率的重要手段。然而,由于缺乏合理的破损模型,米粒的动态破损机理尚不清楚。本研究对单粒大米进行了单轴压缩试验和落重试验,构建了米粒的破损模型,并通过试验和模拟结果验证了米粒模型的可靠性。结果表明,通过单轴压缩试验可以得到稻谷的断裂能分布,稻谷的比断裂能符合对数正态分布,稻谷比断裂能的中位数为 479.75 J/kg。大米的损伤累积系数和碎片大小分布可通过跌落试验获得,大米的损伤累积系数结果为 4.3。米粒破碎主要发生在立式循环碾米机的碾米段。
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引用次数: 0
Experimental and numerical investigation of iron ore pellet firing using coupled CFD-DEM method 使用 CFD-DEM 耦合方法对铁矿石球团烧制进行实验和数值研究
IF 4.1 2区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-06-17 DOI: 10.1016/j.partic.2024.05.018
Hafez Amani , Eskandar Keshavarz Alamdari , Mostafa Keshavarz Moraveji , Bernhard Peters

Iron ore pellets are the main feedstock in ironmaking processes. While extensive research has addressed numerical modeling of the iron ore pellet induration process, little effort has been made to describe the intricate thermochemical processes occurring within the reactor starting from the pellet and particularly at the intra-particle scale. In this regard, discrete-continuous methods like CFD-DEM can generate more realistic, irregular particle assemblies, which leads to significantly more accurate predictions of voidage variation, wall effects, temperature distribution, and associated mass transfer phenomena. This study presents a numerical model based on computational fluid dynamics (CFD) coupled with the discrete element method (DEM) to simulate the thermal induration process of iron ore pellets. The presented model solving heat, mass, and momentum conservation equations for both continuous and discrete phases, provides detailed information on the thermochemical aspects of the process. Pilot-scale induration experiment was conducted to validate model predictions in terms of thermal history and final conversion fraction. It was found that inlet charge specifications, such as particle and pellet size, significantly impact the productivity of pelletizing plants, highlighting the potential of the presented model to optimize the process and improve plant productivity.

铁矿球团是炼铁工艺的主要原料。虽然对铁矿球团压入过程的数值建模进行了大量研究,但对反应器内从球团开始发生的复杂热化学过程,特别是颗粒内部尺度的热化学过程的描述却很少。在这方面,CFD-DEM 等离散-连续方法可以生成更真实、不规则的颗粒集合体,从而对空隙变化、壁效应、温度分布和相关传质现象进行更准确的预测。本研究提出了一种基于计算流体动力学(CFD)和离散元素法(DEM)的数值模型,用于模拟铁矿石球团的热压 缩过程。该模型解决了连续相和离散相的热量、质量和动量守恒方程,提供了该过程热化学方面的详细信息。为验证模型在热历史和最终转化率方面的预测,进行了中试规模的压延实验。实验发现,颗粒和球团大小等入口装料规格对造粒设备的生产率有显著影响,这凸显了该模型在优化工艺和提高设备生产率方面的潜力。
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引用次数: 0
Steady-state multiscale CFD simulation of a circulating fluidized bed riser 循环流化床立管的稳态多尺度 CFD 模拟
IF 4.1 2区 材料科学 Q2 Chemical Engineering Pub Date : 2024-06-13 DOI: 10.1016/j.partic.2024.06.004
Zhaojie Ke , Yujie Tian , Fei Li , Bona Lu , Wei Wang

Compared to transient simulation, steady-state simulation of circulating fluidized bed risers is more efficient, but is also harder to perform due to the complex scale-dependency of dense gas-solid flows. In this work, steady-state computational fluid dynamics (CFD) simulation of a riser is performed using the steady energy-minimization multi-scale (EMMS) drag. It is found that the steady state corresponds to an extremely large scale of length and time, thus the grid size required in steady-state simulation is larger than that in transient one. The time-averaged two-fluid model (TFM) coupled with the steady-state EMMS/1M drag model enables a good prediction of the S-shaped, axial solids distribution and the choking transition, whereas the two-phase turbulence and solids stress models are important in predicting the radially core-annular distribution of solids. So far as we know, this is the first time that one can predict the choking transition in a steady-state CFD simulation. Further improvement may need an EMMS modeling of the time-averaged solid stresses.

与瞬态模拟相比,循环流化床立管的稳态模拟更有效,但由于高密度气固流的复杂尺度依赖性,稳态模拟也更难进行。在这项工作中,利用稳定能量最小化多尺度(EMMS)拖曳对立管进行了稳态计算流体动力学(CFD)模拟。研究发现,稳态对应的长度和时间尺度都非常大,因此稳态模拟所需的网格尺寸要大于瞬态模拟。时间平均双流体模型(TFM)与稳态 EMMS/1M 阻力模型相结合,可以很好地预测 S 形轴向固体分布和窒息转变,而两相湍流和固体应力模型对预测固体的径向核心环状分布非常重要。据我们所知,这是第一次可以在稳态 CFD 模拟中预测窒息转变。进一步的改进可能需要对时间平均固体应力进行 EMMS 建模。
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引用次数: 0
Voidage correction method for DEM study of 3D pebble flows in a bed of cycloidal base 用于摆线基床中三维卵石流 DEM 研究的空隙修正方法
IF 3.5 2区 材料科学 Q2 Chemical Engineering Pub Date : 2024-06-10 DOI: 10.1016/j.partic.2024.06.003
Zirui Xia , Minglei Shi , Quan Zou , Nan Gui , Xingtuan Yang , Jiyuan Tu , Shengyao Jiang

Voidage (porosity or void fraction) in packed particles (or pebbles) is of fundamental importance in calculating the pressure drop, obtaining the drag, predicting the bed permeability, estimating the neutron streaming, etc. For the case when particles are deformed, a method of voidage correction during the packing state is proposed using a Discrete Element Method (DEM) simulation of 3D pebble flow inside a bed of cycloidal base. A function to evaluate the remaining volume of a pebble intercepted by horizontal and vertical planes is proposed for voidage calculation. After that, the process of solving voidage distribution is provided in detail. Using this method, the voidage inside the cycloidal-base pebble bed is obtained to refer to reported similar data for validation. This method can be potentially used for dynamical voidage calculation in CFD-DEM simulation which can get suitable voidage distribution after the correction.

填料颗粒(或鹅卵石)中的空隙(孔隙率或空隙率)对于计算压降、获得阻力、预测床层渗透性、估算中子流等具有重要意义。针对颗粒变形的情况,利用离散元法(DEM)模拟摆线基床内的三维卵石流,提出了填料状态下的空隙率修正方法。在计算空隙率时,提出了一个评估卵石被水平和垂直平面截取的剩余体积的函数。随后,详细介绍了空隙分布的求解过程。利用这种方法,可以获得摆线基卵石床内部的空隙率,并参考已报道的类似数据进行验证。该方法可用于 CFD-DEM 模拟中的动态空隙计算,修正后可得到合适的空隙分布。
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引用次数: 0
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Particuology
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