Pub Date : 2026-01-08DOI: 10.1016/j.partic.2025.12.023
Ye Wang, Yuxin Xie, Xiaojing Guo, Xi Yan, Yan Chen, Ping Hu, Peng Cheng, Wanzhong Lang
The solid-state synthesis of H2TiO3 (HTO) lithium ion-sieves is highly sensitive to the particle size of the TiO2 precursor, which governs both structural properties and ultimate adsorption performance. This study reveals a striking morphological convergence during the synthesis of Li2TiO3 (LTO) intermediates: despite employing TiO2 precursors spanning 15–40 nm, the resulting LTO particles consistently exhibited a narrow size range of 28–32 nm, indicating a distinctive size-regulation mechanism in the solid-state reaction. In contrast, precursors ≥60 nm led to fragmented structures with reduced crystallinity. Leveraging this finding, we identified 40 nm as a critical precursor size for crafting optimal HTO adsorbents. The 40 nm-derived HTO (40-HTO) delivered a superior equilibrium Li+ adsorption capacity of 58.02 mg g−1, a pseudo-second-order rate constant 2.3-fold higher than that of its 150 nm-derived counterpart, and exceptional cyclic stability (<0.15 % Ti dissolution over 10 cycles). Importantly, in a simulated concentrated brine with a high Mg2+/Li+ mass ratio of 20, 40-HTO maintained a high Li+ uptake of 36.5 mg g−1 and exhibited exceptional selectivity, with a separation factor as high as 780. This work underscores precursor size engineering, targeting a critical size threshold, as a vital strategy for developing high-efficiency lithium ion-sieves.
固态合成的H2TiO3 (HTO)锂离子筛对TiO2前驱体的粒径高度敏感,这决定了其结构性能和最终吸附性能。本研究揭示了Li2TiO3 (LTO)中间体合成过程中惊人的形态收敛:尽管采用了15-40 nm的TiO2前驱体,但所得到的LTO颗粒始终保持在28-32 nm的狭窄尺寸范围内,这表明在固态反应中存在独特的尺寸调节机制。相反,前驱体≥60 nm导致结晶度降低的碎片化结构。利用这一发现,我们确定了40nm作为制作最佳HTO吸附剂的关键前驱体尺寸。40 nm衍生的HTO (40-HTO)具有58.02 mg g - 1的优异平衡Li+吸附容量,伪二级速率常数比150 nm衍生的HTO高2.3倍,并且具有优异的循环稳定性(在10个循环中溶解了0.15%的Ti)。重要的是,在Mg2+/Li+质量比为20的模拟浓盐水中,40-HTO保持了36.5 mg g - 1的高Li+吸收量,并表现出优异的选择性,分离因子高达780。这项工作强调了前驱体尺寸工程,目标是一个临界尺寸阈值,作为开发高效锂离子筛的重要策略。
{"title":"Morphological convergence in solid-state synthesis: Unveiling the critical role of TiO2 precursor size for high-performance H2TiO3 lithium ion-sieves","authors":"Ye Wang, Yuxin Xie, Xiaojing Guo, Xi Yan, Yan Chen, Ping Hu, Peng Cheng, Wanzhong Lang","doi":"10.1016/j.partic.2025.12.023","DOIUrl":"10.1016/j.partic.2025.12.023","url":null,"abstract":"<div><div>The solid-state synthesis of H<sub>2</sub>TiO<sub>3</sub> (HTO) lithium ion-sieves is highly sensitive to the particle size of the TiO<sub>2</sub> precursor, which governs both structural properties and ultimate adsorption performance. This study reveals a striking morphological convergence during the synthesis of Li<sub>2</sub>TiO<sub>3</sub> (LTO) intermediates: despite employing TiO<sub>2</sub> precursors spanning 15–40 nm, the resulting LTO particles consistently exhibited a narrow size range of 28–32 nm, indicating a distinctive size-regulation mechanism in the solid-state reaction. In contrast, precursors ≥60 nm led to fragmented structures with reduced crystallinity. Leveraging this finding, we identified 40 nm as a critical precursor size for crafting optimal HTO adsorbents. The 40 nm-derived HTO (40-HTO) delivered a superior equilibrium Li<sup>+</sup> adsorption capacity of 58.02 mg g<sup>−1</sup>, a pseudo-second-order rate constant 2.3-fold higher than that of its 150 nm-derived counterpart, and exceptional cyclic stability (<0.15 % Ti dissolution over 10 cycles). Importantly, in a simulated concentrated brine with a high Mg<sup>2+</sup>/Li<sup>+</sup> mass ratio of 20, 40-HTO maintained a high Li<sup>+</sup> uptake of 36.5 mg g<sup>−1</sup> and exhibited exceptional selectivity, with a separation factor as high as 780. This work underscores precursor size engineering, targeting a critical size threshold, as a vital strategy for developing high-efficiency lithium ion-sieves.</div></div>","PeriodicalId":401,"journal":{"name":"Particuology","volume":"110 ","pages":"Pages 1-13"},"PeriodicalIF":4.3,"publicationDate":"2026-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145986688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-08DOI: 10.1016/j.partic.2025.12.014
Zhiyuan Cheng , Xinbo Dong , Cheng Liu
The 4,4′-bismaleimidodiphenyl-methane (BDM) resin, as one of the most important thermoset resin, exhibits poor toughness, which prevents it from adapting to high technical requirements and hinder its further development. Novel poly (phthalazinone ether nitrile ketone)s (PPENK) with twisted, non-coplanar phthalazinone units and highly polar cyano side groups into the main chain of poly (aryl ether ketone) molecules were synthesized and used to modify the blends of BDM/diallyl bisphenol A (DABPA). The thermal and mechanical properties of modified BDM resin have been investigated thoroughly. The role of cyano group content of PPENK on the mechanical properties of modified BDM resin has been recognized. The impact strength of modified BDM resin reached up to 26.25 kJ/m2, and the glass transition temperature can still maintain in a high level, in the range of 280–291 °C, indicating the excellent thermal properties of modified BDM resin. Moreover, the island-structure particles have been analyzed and the toughening mechanism of BDM resin modified by PPENK particles has been revealed. This work provides a new strategy for design of high-performance thermoplastic toughening agents for BDM resin with improved toughness and thermal properties.
{"title":"Toughening modification of bismaleimide resin with a cyano-containing thermoplastic PPENK particles","authors":"Zhiyuan Cheng , Xinbo Dong , Cheng Liu","doi":"10.1016/j.partic.2025.12.014","DOIUrl":"10.1016/j.partic.2025.12.014","url":null,"abstract":"<div><div>The 4,4′-bismaleimidodiphenyl-methane (BDM) resin, as one of the most important thermoset resin, exhibits poor toughness, which prevents it from adapting to high technical requirements and hinder its further development. Novel poly (phthalazinone ether nitrile ketone)s (PPENK) with twisted, non-coplanar phthalazinone units and highly polar cyano side groups into the main chain of poly (aryl ether ketone) molecules were synthesized and used to modify the blends of BDM/diallyl bisphenol A (DABPA). The thermal and mechanical properties of modified BDM resin have been investigated thoroughly. The role of cyano group content of PPENK on the mechanical properties of modified BDM resin has been recognized. The impact strength of modified BDM resin reached up to 26.25 kJ/m<sup>2</sup>, and the glass transition temperature can still maintain in a high level, in the range of 280–291 °C, indicating the excellent thermal properties of modified BDM resin. Moreover, the island-structure particles have been analyzed and the toughening mechanism of BDM resin modified by PPENK particles has been revealed. This work provides a new strategy for design of high-performance thermoplastic toughening agents for BDM resin with improved toughness and thermal properties.</div></div>","PeriodicalId":401,"journal":{"name":"Particuology","volume":"109 ","pages":"Pages 231-237"},"PeriodicalIF":4.3,"publicationDate":"2026-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145973604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-03DOI: 10.1016/j.partic.2025.12.018
Xuecheng Wu, Dian Zhu, Zhiliang Xue, Zhiming Lin, Qiwen Jin
Gas-solid two-phase flows are common in both industrial processes and natural phenomena, and accurately detecting particle properties within these flows is crucial for process optimization and control. However, existing particle detection techniques often struggle to provide in-situ, real-time, and multi-parameter measurements in complex flow environments. To address this challenge, a new digital holographic probe, designed for compactness and 3D measurement capability, is developed in this work. The delicate structure of the probe head makes it suitable for use in pneumatically conveyed particle flows within pipes, with a measurement volume of 435.6 mm3. The measurement performance of the holographic probe has been verified on a pipeline pneumatic transport test platform under various particle size and concentration conditions. Using 3D holographic imaging, the spatial distribution of particles within the measurement volume was analyzed. Experimental results show that the relative deviation of the mass median diameter is less than 3 %, while the relative deviation of the average mass concentration is below 12 %, compared to reference results.
{"title":"In-situ measurement of size distribution and concentration in dilute particle flow with digital holographic probe","authors":"Xuecheng Wu, Dian Zhu, Zhiliang Xue, Zhiming Lin, Qiwen Jin","doi":"10.1016/j.partic.2025.12.018","DOIUrl":"10.1016/j.partic.2025.12.018","url":null,"abstract":"<div><div>Gas-solid two-phase flows are common in both industrial processes and natural phenomena, and accurately detecting particle properties within these flows is crucial for process optimization and control. However, existing particle detection techniques often struggle to provide in-situ, real-time, and multi-parameter measurements in complex flow environments. To address this challenge, a new digital holographic probe, designed for compactness and 3D measurement capability, is developed in this work. The delicate structure of the probe head makes it suitable for use in pneumatically conveyed particle flows within pipes, with a measurement volume of 435.6 mm<sup>3</sup>. The measurement performance of the holographic probe has been verified on a pipeline pneumatic transport test platform under various particle size and concentration conditions. Using 3D holographic imaging, the spatial distribution of particles within the measurement volume was analyzed. Experimental results show that the relative deviation of the mass median diameter is less than 3 %, while the relative deviation of the average mass concentration is below 12 %, compared to reference results.</div></div>","PeriodicalId":401,"journal":{"name":"Particuology","volume":"109 ","pages":"Pages 127-140"},"PeriodicalIF":4.3,"publicationDate":"2026-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145922228","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-02DOI: 10.1016/j.partic.2025.12.013
Ziliang Liu, Fuzhong Wu, Xiaodong Lv, Xinyi Dai
Clay-type lithium ores represent a vast, underexploited resource critical for future lithium supply, but their complex mineralogy hinders efficient processing. While alkaline pretreatment is a promising enrichment strategy, its optimization is hampered by elusive regulatory mechanisms. Here, we report a critical non-monotonic response where excessive pretreatment intensity paradoxically suppresses lithium recovery. We identify and verify that this response is governed by a key antagonistic mechanism, termed the Alkali Residue Effect (ARE), where residual alkaline species cause both physical dilution and chemical neutralization. Through response surface methodology (RSM) targeting the mitigation of ARE, we established an optimized processing window that achieves a 4.35-fold lithium enrichment (Li2O from 0.17 to 0.74 wt%). Microscopic analyses (SEM-EDS, XRD, XPS) confirm the optimized process selectively etches amorphous gangue, enhancing the reactivity of the Li-bearing mineral (cookeite). A techno-economic analysis projects a favorable operating cost of ∼US$81/ton. This study provides a new theoretical framework (ARE) for optimizing complex hydrometallurgical processes by balancing targeted reactions against unintended side effects.
{"title":"A key antagonistic effect in alkaline pretreatment of clay-type lithium ores and its targeted control for enhanced lithium enrichment","authors":"Ziliang Liu, Fuzhong Wu, Xiaodong Lv, Xinyi Dai","doi":"10.1016/j.partic.2025.12.013","DOIUrl":"10.1016/j.partic.2025.12.013","url":null,"abstract":"<div><div>Clay-type lithium ores represent a vast, underexploited resource critical for future lithium supply, but their complex mineralogy hinders efficient processing. While alkaline pretreatment is a promising enrichment strategy, its optimization is hampered by elusive regulatory mechanisms. Here, we report a critical non-monotonic response where excessive pretreatment intensity paradoxically suppresses lithium recovery. We identify and verify that this response is governed by a key antagonistic mechanism, termed the Alkali Residue Effect (ARE), where residual alkaline species cause both physical dilution and chemical neutralization. Through response surface methodology (RSM) targeting the mitigation of ARE, we established an optimized processing window that achieves a 4.35-fold lithium enrichment (Li<sub>2</sub>O from 0.17 to 0.74 wt%). Microscopic analyses (SEM-EDS, XRD, XPS) confirm the optimized process selectively etches amorphous gangue, enhancing the reactivity of the Li-bearing mineral (cookeite). A techno-economic analysis projects a favorable operating cost of ∼US$81/ton. This study provides a new theoretical framework (ARE) for optimizing complex hydrometallurgical processes by balancing targeted reactions against unintended side effects.</div></div>","PeriodicalId":401,"journal":{"name":"Particuology","volume":"109 ","pages":"Pages 180-191"},"PeriodicalIF":4.3,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145922232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-02DOI: 10.1016/j.partic.2025.12.008
Zepeng Zhu , Qian Zhang , Yiyang Zhang , Yaqin Liao , Qingqing Qiu , Zhong Chen , Shuiqing Li
The performance of photovoltaic cell grids critically depends on the quality of front silver paste, which is significantly influenced by the particle size of the silver powder. Liquid-route continuous synthesis is a highly promising option for the silver micro-powder production. To identify the key factors in synthesis processes impacting on the particle size of the final product, a comprehensive understanding of the continuous liquid-route reduction synthesis mechanisms is required. This study presents a coupled CFD-PBM framework of silver micro-powder synthesis that incorporates flow dynamics, chemical reactions, nucleation, and surface growth processes. The results indicate that the initial reduction rate influences the nucleation of silver powder formation, thereby determining the number of final products. The reduction rate of following stage affects the surface growth, ultimately determining the average size of the products. In a synthesis system with a fixed total reducible silver content, a high initial reduction rate tends to a larger number of smaller silver powder particles produced. Particularly in the ascorbic acid-silver nitrate reduction system, the pH value is a critical factor controlling the distribution of reaction rates. The findings reveal how the reduction rate regulates the final particle size through its influence on nucleation and growth processes, providing insights into controlling powder particle size characteristics by manipulating reaction rates within the continuous synthesis system.
{"title":"Key factors in liquid-route synthesis of photovoltaic front-side silver micro-powder: Particle growth modeling coupled with CFD","authors":"Zepeng Zhu , Qian Zhang , Yiyang Zhang , Yaqin Liao , Qingqing Qiu , Zhong Chen , Shuiqing Li","doi":"10.1016/j.partic.2025.12.008","DOIUrl":"10.1016/j.partic.2025.12.008","url":null,"abstract":"<div><div>The performance of photovoltaic cell grids critically depends on the quality of front silver paste, which is significantly influenced by the particle size of the silver powder. Liquid-route continuous synthesis is a highly promising option for the silver micro-powder production. To identify the key factors in synthesis processes impacting on the particle size of the final product, a comprehensive understanding of the continuous liquid-route reduction synthesis mechanisms is required. This study presents a coupled CFD-PBM framework of silver micro-powder synthesis that incorporates flow dynamics, chemical reactions, nucleation, and surface growth processes. The results indicate that the initial reduction rate influences the nucleation of silver powder formation, thereby determining the number of final products. The reduction rate of following stage affects the surface growth, ultimately determining the average size of the products. In a synthesis system with a fixed total reducible silver content, a high initial reduction rate tends to a larger number of smaller silver powder particles produced. Particularly in the ascorbic acid-silver nitrate reduction system, the pH value is a critical factor controlling the distribution of reaction rates. The findings reveal how the reduction rate regulates the final particle size through its influence on nucleation and growth processes, providing insights into controlling powder particle size characteristics by manipulating reaction rates within the continuous synthesis system.</div></div>","PeriodicalId":401,"journal":{"name":"Particuology","volume":"109 ","pages":"Pages 270-281"},"PeriodicalIF":4.3,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145973608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-02DOI: 10.1016/j.partic.2025.12.007
Ruiqi Bai , Tuo Zhou , Tong Wang , Xinyun Wan , Xin Meng , Man Zhang , Hairui Yang
Erosion of water-cooled walls is a major challenge affecting the reliability and efficiency of circulating fluidized bed (CFB) boilers. To mitigate this issue, this study employs computational particle fluid dynamics (CPFD) simulations to optimize the design of a novel honeycomb anti-wear structure. The results show that honeycomb installation slightly modifies local wall flow but has negligible influence on the overall pressure drop. When positioned in the dense phase region, the honeycomb effectively reduces wall erosion to less than 10 % of its original value at most locations through shielding against particle impingement. Increasing the installation height weakens this effect due to stronger lateral particle motion. Thicker honeycombs enhance protection, with 7 cm achieving optimal performance, while 5 cm is sufficient in the dense phase region. The findings demonstrate that an appropriately designed honeycomb structure can serve as an innovative and effective method to mitigate erosion and extend wall service life. The synergistic combination of this structural design with metallic–ceramic coatings presents a promising strategy for enhancing both durability and heat transfer efficiency in industrial CFB boilers.
{"title":"Optimization of honeycomb anti-wear structures for water-cooled walls in circulating fluidized beds","authors":"Ruiqi Bai , Tuo Zhou , Tong Wang , Xinyun Wan , Xin Meng , Man Zhang , Hairui Yang","doi":"10.1016/j.partic.2025.12.007","DOIUrl":"10.1016/j.partic.2025.12.007","url":null,"abstract":"<div><div>Erosion of water-cooled walls is a major challenge affecting the reliability and efficiency of circulating fluidized bed (CFB) boilers. To mitigate this issue, this study employs computational particle fluid dynamics (CPFD) simulations to optimize the design of a novel honeycomb anti-wear structure. The results show that honeycomb installation slightly modifies local wall flow but has negligible influence on the overall pressure drop. When positioned in the dense phase region, the honeycomb effectively reduces wall erosion to less than 10 % of its original value at most locations through shielding against particle impingement. Increasing the installation height weakens this effect due to stronger lateral particle motion. Thicker honeycombs enhance protection, with 7 cm achieving optimal performance, while 5 cm is sufficient in the dense phase region. The findings demonstrate that an appropriately designed honeycomb structure can serve as an innovative and effective method to mitigate erosion and extend wall service life. The synergistic combination of this structural design with metallic–ceramic coatings presents a promising strategy for enhancing both durability and heat transfer efficiency in industrial CFB boilers.</div></div>","PeriodicalId":401,"journal":{"name":"Particuology","volume":"109 ","pages":"Pages 282-291"},"PeriodicalIF":4.3,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145973601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-02DOI: 10.1016/j.partic.2025.12.010
Lele Yang , Xiaodong Chen , Ke Zhang , Yue Wu , Peng Li , Jianhou Zhou
In vertical hydraulic conveyance for deep-sea mining, localized particle aggregation can occur due to multiple factors, resulting in increased concentration and degrade transport performance. To mitigate this issue, this study proposes a novel deflector vane-type swirl generator with a simple structure that generates swirling flow without additional operations. A combined computational fluid dynamics (CFD) and discrete element method (DEM) has been used to numerically simulate liquid-solid swirling flow in a vertical pipe featuring the vane. Subsequently, an orthogonal design method was applied to evaluate the effects of vane number, vane angle, vane radius, and hub diameter on transport behavior, using the horizontal dispersion coefficient and pressure drop as performance indicators. The results demonstrate that the vane angle is the most influential factor for both particle dispersion and pressure loss, whereas vane number and vane radius have comparatively minor effects. Moreover, increasing the vane angle and hub diameter strengthens the swirl intensity, promotes particle accumulation near the pipe wall, and thereby increases the horizontal dispersion coefficient. The results offer insights that can inform the enhancement of the efficiency and safety of vertical hydraulic transport.
{"title":"Reducing particle aggregation and pressure drop in vertical hydraulic transport through swirling flow optimization","authors":"Lele Yang , Xiaodong Chen , Ke Zhang , Yue Wu , Peng Li , Jianhou Zhou","doi":"10.1016/j.partic.2025.12.010","DOIUrl":"10.1016/j.partic.2025.12.010","url":null,"abstract":"<div><div>In vertical hydraulic conveyance for deep-sea mining, localized particle aggregation can occur due to multiple factors, resulting in increased concentration and degrade transport performance. To mitigate this issue, this study proposes a novel deflector vane-type swirl generator with a simple structure that generates swirling flow without additional operations. A combined computational fluid dynamics (CFD) and discrete element method (DEM) has been used to numerically simulate liquid-solid swirling flow in a vertical pipe featuring the vane. Subsequently, an orthogonal design method was applied to evaluate the effects of vane number, vane angle, vane radius, and hub diameter on transport behavior, using the horizontal dispersion coefficient and pressure drop as performance indicators. The results demonstrate that the vane angle is the most influential factor for both particle dispersion and pressure loss, whereas vane number and vane radius have comparatively minor effects. Moreover, increasing the vane angle and hub diameter strengthens the swirl intensity, promotes particle accumulation near the pipe wall, and thereby increases the horizontal dispersion coefficient. The results offer insights that can inform the enhancement of the efficiency and safety of vertical hydraulic transport.</div></div>","PeriodicalId":401,"journal":{"name":"Particuology","volume":"109 ","pages":"Pages 258-269"},"PeriodicalIF":4.3,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145973607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-02DOI: 10.1016/j.partic.2025.12.017
Prasenjit Patra , Saikat Nandi , Saurav Misra , Partha Saha , Pranab K. Dan
This study presents a systematic methodology for producing multi-walled carbon nanotubes (MWCNTs)/Inconel 718 composite powder, especially for the Laser Directed Energy Deposition (LDED) process. This approach integrates mild oxidative functionalization of MWCNTs to reduce agglomerations and High-Energy Ball Milling (HEBM) to enhance dispersion over the Inconel 718 powder. The MWCNTs were functionalized through a two-step chemical treatment: (1) magnetic stirring in a 3:1 H2SO4 and HNO3 solution, using two distinct acid concentrations (3 M and 8 M), followed by (2) an ultrasonic bath in H2O2 solution. Structural defects were characterized using Raman spectroscopy (RS), thermogravimetric analysis (TGA), and transmission electron microscopy (TEM), while X-ray photoelectron spectroscopy (XPS) quantified the amount of oxygen-containing functional groups. Among the six functionalization processes, the treatment condition involving 4 h of magnetic stirring, then 2 h in the sonication bath, emerged as optimal, yielding a relatively high functional group attachment (11.47 %) with lower surface defects and without compromising uniformity in mixing. The FESEM analysis of the functionalized MWCNTs (up to 2 wt%)/Inconel 718 composite powder, collected from the LDED machine bed, confirmed uniform dispersion, validating the functionalization strategy. Although developed for LDED, this strategy is also suitable for MMC production processes that use powder as feedstock.
{"title":"Synthesis of MWCNT/Inconel 718 composite powder through mild surface functionalization and High-Energy Ball Milling for subsequent use in additive manufacturing of MMC parts","authors":"Prasenjit Patra , Saikat Nandi , Saurav Misra , Partha Saha , Pranab K. Dan","doi":"10.1016/j.partic.2025.12.017","DOIUrl":"10.1016/j.partic.2025.12.017","url":null,"abstract":"<div><div>This study presents a systematic methodology for producing multi-walled carbon nanotubes (MWCNTs)/Inconel 718 composite powder, especially for the Laser Directed Energy Deposition (LDED) process. This approach integrates mild oxidative functionalization of MWCNTs to reduce agglomerations and High-Energy Ball Milling (HEBM) to enhance dispersion over the Inconel 718 powder. The MWCNTs were functionalized through a two-step chemical treatment: (1) magnetic stirring in a 3:1 H<sub>2</sub>SO<sub>4</sub> and HNO<sub>3</sub> solution, using two distinct acid concentrations (3 M and 8 M), followed by (2) an ultrasonic bath in H<sub>2</sub>O<sub>2</sub> solution. Structural defects were characterized using Raman spectroscopy (RS), thermogravimetric analysis (TGA), and transmission electron microscopy (TEM), while X-ray photoelectron spectroscopy (XPS) quantified the amount of oxygen-containing functional groups. Among the six functionalization processes, the treatment condition involving 4 h of magnetic stirring, then 2 h in the sonication bath, emerged as optimal, yielding a relatively high functional group attachment (11.47 %) with lower surface defects and without compromising uniformity in mixing. The FESEM analysis of the functionalized MWCNTs (up to 2 wt%)/Inconel 718 composite powder, collected from the LDED machine bed, confirmed uniform dispersion, validating the functionalization strategy. Although developed for LDED, this strategy is also suitable for MMC production processes that use powder as feedstock.</div></div>","PeriodicalId":401,"journal":{"name":"Particuology","volume":"109 ","pages":"Pages 99-116"},"PeriodicalIF":4.3,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145922226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-02DOI: 10.1016/j.partic.2025.12.020
Pei-Wei Zhong , Hong-Xiao Yang , Wenkang Xu, Zhiyang Yu, Bei Li, Hongjuan Wang, Yonghai Cao, Hao Yu, Hao-Fan Wang
Oxygen evolution reaction (OER) plays a vital role in various pivotal electrochemical applications. To improve the energy efficiency and economic viability of these technologies, it is critical to develop cost-effective and highly active OER electrocatalysts based on earth-abundant elements. Among various candidates, transition-metal-based compounds have demonstrated notable potential for OER electrocatalysis, attributable to their adjustable electronic configurations. Nevertheless, their practical application remains constrained by limited intrinsic activity, poor electrical conductivity, and particle aggregation, which compromise their overall OER efficiency. In this study, an efficient OER electrocatalyst, S-NiFc MOF@Mo2CTx, is constructed by the sulfidation of NiFe-based metal–organic framework (MOF) precursors anchored on conductive Mo2CTx MXene. The MOF-derived NiFe sulfides offer abundant accessible active sites, and the strong interfacial coupling between NiFe sulfides and Mo2CTx enhances the catalyst's intrinsic activity. The conductive Mo2CTx matrix also guarantees efficient electron transport and homogeneous dispersion of the active phase. As a result, S-NiFc MOF@ Mo2CTx exhibits excellent OER activity, reaching 10 mA cm−2 at an overpotential of 223 mV, along with stable operation for 68 h in 1.0 M KOH solution. This study broadens the scope of MXene-based materials in electrocatalytic applications and offers valuable insights into optimizing NiFe-derived OER catalysts.
析氧反应(OER)在各种关键电化学应用中起着至关重要的作用。为了提高这些技术的能源效率和经济可行性,开发具有成本效益和高活性的基于地球丰富元素的OER电催化剂至关重要。在各种候选化合物中,过渡金属基化合物由于其可调节的电子结构而表现出显著的OER电催化潜力。然而,它们的实际应用仍然受到固有活性有限、导电性差和粒子聚集的限制,这些都会影响它们的整体OER效率。在这项研究中,一种高效的OER电催化剂S-NiFc MOF@Mo2CTx是通过将nfe基金属有机框架(MOF)前驱体固定在导电的Mo2CTx MXene上进行硫化而构建的。mof衍生的NiFe硫化物提供了丰富的可达活性位点,并且NiFe硫化物与Mo2CTx之间的强界面耦合提高了催化剂的本征活性。导电Mo2CTx基体还保证了有效的电子传输和活性相的均匀分散。因此,S-NiFc MOF@ Mo2CTx表现出优异的OER活性,在223 mV过电位下达到10 mA cm−2,并在1.0 M KOH溶液中稳定运行68小时。这项研究拓宽了mxene基材料在电催化应用中的范围,并为优化nfe衍生的OER催化剂提供了有价值的见解。
{"title":"MXene-assisted NiFe sulfides with interfacial modulation for oxygen evolution electrocatalysis","authors":"Pei-Wei Zhong , Hong-Xiao Yang , Wenkang Xu, Zhiyang Yu, Bei Li, Hongjuan Wang, Yonghai Cao, Hao Yu, Hao-Fan Wang","doi":"10.1016/j.partic.2025.12.020","DOIUrl":"10.1016/j.partic.2025.12.020","url":null,"abstract":"<div><div>Oxygen evolution reaction (OER) plays a vital role in various pivotal electrochemical applications. To improve the energy efficiency and economic viability of these technologies, it is critical to develop cost-effective and highly active OER electrocatalysts based on earth-abundant elements. Among various candidates, transition-metal-based compounds have demonstrated notable potential for OER electrocatalysis, attributable to their adjustable electronic configurations. Nevertheless, their practical application remains constrained by limited intrinsic activity, poor electrical conductivity, and particle aggregation, which compromise their overall OER efficiency. In this study, an efficient OER electrocatalyst, S-NiFc MOF@Mo<sub>2</sub>CT<sub><em>x</em></sub>, is constructed by the sulfidation of NiFe-based metal–organic framework (MOF) precursors anchored on conductive Mo<sub>2</sub>CT<sub><em>x</em></sub> MXene. The MOF-derived NiFe sulfides offer abundant accessible active sites, and the strong interfacial coupling between NiFe sulfides and Mo<sub>2</sub>CT<sub><em>x</em></sub> enhances the catalyst's intrinsic activity. The conductive Mo<sub>2</sub>CT<sub><em>x</em></sub> matrix also guarantees efficient electron transport and homogeneous dispersion of the active phase. As a result, S-NiFc MOF@ Mo<sub>2</sub>CT<sub><em>x</em></sub> exhibits excellent OER activity, reaching 10 mA cm<sup>−2</sup> at an overpotential of 223 mV, along with stable operation for 68 h in 1.0 M KOH solution. This study broadens the scope of MXene-based materials in electrocatalytic applications and offers valuable insights into optimizing NiFe-derived OER catalysts.</div></div>","PeriodicalId":401,"journal":{"name":"Particuology","volume":"109 ","pages":"Pages 211-218"},"PeriodicalIF":4.3,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145922234","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-02DOI: 10.1016/j.partic.2025.12.009
Shengxin Yang , Jianping Zhang , Boren Wang , Wen Gu , Weiguo Zhou
Aiming at enhancing the capture performance of electrostatic precipitator (ESP) for PM2.5 particles, this paper introduces a multi-field coupling model and carries out the analysis of the electromagnetic dedusting mechanism of four electric field ESP under the magnetic-field-induced trajectory modification, and investigates the capture performance of multiple electric field ESP for PM2.5 particles at different magnetic field introduction positions through numerical simulations and PIV (Particle Image Velocimetry) experiments. The PIV measurements showed flow-field patterns that were consistent with established ESP findings, where higher applied voltage and lower flue-gas velocity lead to stronger particle deflection toward the collection plate. These observed trends serve as a validation of the reliability of the present PIV setup and simulation model. Introducing a magnetic field into a specific zone resulted in particles to follow a spiral path leading to the collection plate. This motion not only altered the paths of particles in the targeted region but also influenced adjacent zones. Magnetic confinement was found to be more effective under low flue gas velocity and low operating voltage conditions. Furthermore, at lower voltages, the third electric field was more sensitive to magnetic confinement, whereas at higher voltages, the fourth electric field exhibited greater sensitivity. The findings can offer new design ideas for performance enhancement of traditional ESPs.
{"title":"Numerical simulation and experimental study on PM2.5 capture performance of multiple electric field ESP under different magnetic field introduction positions","authors":"Shengxin Yang , Jianping Zhang , Boren Wang , Wen Gu , Weiguo Zhou","doi":"10.1016/j.partic.2025.12.009","DOIUrl":"10.1016/j.partic.2025.12.009","url":null,"abstract":"<div><div>Aiming at enhancing the capture performance of electrostatic precipitator (ESP) for PM2.5 particles, this paper introduces a multi-field coupling model and carries out the analysis of the electromagnetic dedusting mechanism of four electric field ESP under the magnetic-field-induced trajectory modification, and investigates the capture performance of multiple electric field ESP for PM2.5 particles at different magnetic field introduction positions through numerical simulations and PIV (Particle Image Velocimetry) experiments. The PIV measurements showed flow-field patterns that were consistent with established ESP findings, where higher applied voltage and lower flue-gas velocity lead to stronger particle deflection toward the collection plate. These observed trends serve as a validation of the reliability of the present PIV setup and simulation model. Introducing a magnetic field into a specific zone resulted in particles to follow a spiral path leading to the collection plate. This motion not only altered the paths of particles in the targeted region but also influenced adjacent zones. Magnetic confinement was found to be more effective under low flue gas velocity and low operating voltage conditions. Furthermore, at lower voltages, the third electric field was more sensitive to magnetic confinement, whereas at higher voltages, the fourth electric field exhibited greater sensitivity. The findings can offer new design ideas for performance enhancement of traditional ESPs.</div></div>","PeriodicalId":401,"journal":{"name":"Particuology","volume":"109 ","pages":"Pages 117-126"},"PeriodicalIF":4.3,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145922227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}