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CFD-DEM simulation and mechanism analysis of filtration performance in polydisperse granular beds 多分散颗粒床过滤性能CFD-DEM模拟及机理分析
IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-20 DOI: 10.1016/j.powtec.2025.121937
Shibo Gao , Dongsheng Jiao , Daotong Li , Xinyu Gao , Liangzhi Xia
Granular filtration beds offer promising potential due to their high dust removal efficiency, temperature resistance, and pressure tolerance. This study employed the CFD-DEM method to model mixed-structure and double-layer granular beds, investigating the effects of bed structure, filter media ratio, and gas velocity on filtration efficiency and pressure drop. Results revealed that the mixed-structure exhibited superior graded dust removal efficiency within the simulated range, identifying a critical particle size: efficiency was 3 %–6 % higher for particles below this size, diminishing to only 1.5 %–2.7 % higher for larger particles. This structural advantage weakened with increasing gas velocity, becoming negligible above 0.4 m/s. Furthermore, two transition particle sizes were identified for the mixed-structure regarding velocity sensitivity; efficiency for fine particles between these sizes was significantly enhanced by velocity (up to 30 % improvement), while particles outside this range were minimally affected. Comprehensive evaluation using the Stokes number (Stk) showed efficiency increased with Stk across three distinct regions (stable, rapid growth, slow growth), with the inter-region thresholds shifting toward lower Stk values as the proportion of 2-mm media increased.
颗粒过滤床具有很高的除尘效率、耐温性和耐压性,具有广阔的应用前景。本研究采用CFD-DEM方法对混合结构和双层颗粒床进行建模,研究了床层结构、滤料比、气速对过滤效率和压降的影响。结果表明,混合结构在模拟范围内表现出优异的分级除尘效率,确定了临界粒径:低于该粒径的颗粒效率提高3% - 6%,而较大颗粒的效率仅提高1.5% - 2.7%。这种结构优势随着气速的增加而减弱,在0.4 m/s以上变得可以忽略不计。此外,在速度敏感性方面,确定了混合结构的两种过渡粒径;在这些尺寸之间的细颗粒的效率显着提高了速度(高达30%的改善),而在这个范围之外的颗粒受到的影响最小。利用Stokes数(Stk)进行的综合评价显示,在三个不同的区域(稳定、快速、缓慢生长),效率随Stk值的增加而增加,随着2mm介质比例的增加,区域间阈值向较低的Stk值转移。
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引用次数: 0
Surface modification and application properties of heat-resistant ultrafine KAl(OH)₂CO₃ dry powder fire extinguishing agent 耐热超细KAl(OH)₂CO₃干粉灭火剂的表面改性及应用性能
IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-20 DOI: 10.1016/j.powtec.2025.121935
Lirong Liu, Lanke Liu, Jinglong Huang, Renming Pan, Xia Zhou
The heat-resistant ultrafine potassium aluminum carbonate hydroxide KAl(OH)₂CO₃ (UKDW) dry powder fire extinguishing agent with hydrophobic and oleophobic properties has potential application prospect in large class B oil fires such as aircraft fires. In this study, the surface modification of UKDW was carried out by sol-gel method, and the environmentally friendly functional fluorosilane structure was introduced to obtain hydrophobic and oleophobic modified products (UKDW-FSi). The modification efficacy of UKDW-FSi under different formulation conditions was systematically investigated, with characterization of its microstructure, chemical composition, flow properties, hydrophobicity/oleophobicity, fire extinguishing performance, and resistance to reignition. Results indicate that the modified UKDW-FSi exhibits water contact angle (WCA) and oil contact angle (OCA) of 152.819° and 149.158°, respectively, demonstrating excellent hydrophobic and oleophobic properties. Simultaneously, the modified UKDW-FSi exhibited enhanced flowability, extinguishing aviation kerosene fires within 2.64 s,faster than the unmodified UKDW(2.90 s), while demonstrating anti-reignition ability with a delay time of 16.5 s. Furthermore, its outstanding thermal stability and hydrophobicity ensure long-term stable storage and application potential in complex environments such as aircraft equipment compartments.
具有疏水疏油性能的耐热超细碳酸铝钾氢氧化物KAl(OH)₂CO₃(UKDW)干粉灭火剂在飞机火灾等大型B类油类火灾中具有潜在的应用前景。本研究采用溶胶-凝胶法对UKDW进行表面改性,引入环保功能氟硅烷结构,得到疏水疏油改性产物(UKDW- fsi)。系统研究了UKDW-FSi在不同配方条件下的改性效果,并对其微观结构、化学成分、流动性能、疏水/疏油性能、灭火性能和耐重燃性能进行了表征。结果表明,改性UKDW-FSi的水接触角(WCA)和油接触角(OCA)分别为152.819°和149.158°,具有良好的疏水和疏油性能。同时,改性UKDW- fsi具有增强的流动性,在2.64 s内扑灭航空煤油火灾,比未改性UKDW(2.90 s)快,同时具有抗重燃能力,延迟时间为16.5 s。此外,其出色的热稳定性和疏水性确保了长期稳定的储存和在复杂环境(如飞机设备隔间)中的应用潜力。
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引用次数: 0
Hydrogen reduction of combusted iron powder: Role of water vapor in reaction kinetics 氢还原燃烧铁粉:水蒸气在反应动力学中的作用
IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-19 DOI: 10.1016/j.powtec.2025.121912
N.C. Stevens , A. Dolai , C.J.M. Hessels , N.G. Deen , G. Finotello
Hydrogen-based reduction of iron oxides offers a promising, low-carbon alternative to hydrocarbon fuels in steel production and plays a critical role in the Iron Power Cycle, an emerging technology for renewable energy storage and transport. However, despite its practical significance, research on hydrogen reduction in the presence of water vapor remains limited, especially for high-purity, micron-sized iron oxide powders produced from iron combustion. In this study, we investigate the reduction kinetics of combusted iron powder using thermogravimetric analysis (TGA) at three temperatures: 500 °C, 700 °C and 800 °C and partial pressure ratios (ΔPH2O/ΔPH2) ranging from 0.0 to 0.7. The results indicate that the conversion rate increases with temperature, and water vapor hinders the reduction process, particularly at lower temperatures. This emphasizes the necessity of removing water vapor during iron oxide reduction to guarantee high conversion. The reduction process is divided into distinct phases, with rate-limiting mechanisms in each phase analyzed using the Avrami constant (n). Kinetic parameters, including activation energy (Ea) and the overall water vapor reaction order (m), are determined using the isoconversional method. We propose a modified multi-step kinetic model to extract the rate constant (kapp), Avrami constant (n), and water vapor reaction order (m) for each step of the reduction pathway. The results are crucial for optimizing hydrogen-based ironmaking processes in sustainable steel production and for the Iron Power Cycle.
氢基氧化铁还原为钢铁生产提供了一种有前途的低碳替代碳氢化合物燃料,并在铁动力循环中发挥关键作用,这是一种新兴的可再生能源储存和运输技术。然而,尽管具有实际意义,但对水蒸气存在下氢还原的研究仍然有限,特别是对由铁燃烧产生的高纯度、微米级氧化铁粉末。在本研究中,我们使用热重分析(TGA)研究了燃烧铁粉在500°C、700°C和800°C三种温度下的还原动力学,分压比(ΔPH2O/ΔPH2)为0.0 ~ 0.7。结果表明,转化率随温度升高而升高,水蒸气阻碍了还原过程,特别是在较低温度下。这强调了在氧化铁还原过程中去除水蒸气以保证高转化率的必要性。还原过程分为不同的阶段,并使用Avrami常数(n)分析每个阶段的限速机制。动力学参数包括活化能(Ea)和总水蒸气反应级数(m),采用等转换法确定。我们提出了一个改进的多步动力学模型,以提取还原途径每一步的速率常数(kapp)、Avrami常数(n)和水蒸气反应阶数(m)。研究结果对于优化可持续钢铁生产中的氢基炼铁工艺和铁动力循环至关重要。
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引用次数: 0
Computational analysis of human metapneumovirus particle behaviour in the pulmonary system 肺系统中人偏肺病毒颗粒行为的计算分析
IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-19 DOI: 10.1016/j.powtec.2025.121945
Abdul Haseeb Lodhi , Hafiz Hamza Riaz , Muhammad Hamza Ali , Adnan Munir , Ming Zhao , Mohammad S. Islam , Kamal Dua , Keshav Raj Paudel
Human metapneumovirus (hMPV) is a re-emerging pathogen implicated in severe respiratory illnesses worldwide. Effective management of hMPV outbreaks relies on understanding how viral particles behave within human pulmonary airways. This study utilizes computed tomography-derived airway models and advanced computational fluid dynamics to investigate the transport and deposition of hMPV-like particles across fifteen airway generations under physiologically representative breathing conditions. The effects of viral particle size and morphology, together with dynamic inhalation–exhalation cycles, are systematically analysed. Results highlight distinct deposition hotspots for cylindrical versus spherical particles, with pronounced differences between inhalation and exhalation phases and notable sensitivity to breathing flow rate. The observed deposition trends provide new insight into shape- and phase-dependent risk regions likely to influence infection patterns and guide aerosolized therapy design. By addressing previously neglected aspects of non-spherical particle transport and transient airflow, this work advances the quantitative modelling of airborne viral pathogen exposure in the human respiratory system.
人偏肺病毒(hMPV)是一种在世界范围内与严重呼吸道疾病有关的重新出现的病原体。hMPV疫情的有效管理依赖于了解病毒颗粒在人肺气道内的行为。本研究利用计算机断层扫描衍生的气道模型和先进的计算流体动力学来研究在生理上具有代表性的呼吸条件下,hmpv样颗粒在15代气道中的运输和沉积。系统地分析了病毒颗粒大小和形态的影响,以及动态吸入-呼出周期。结果突出了圆柱形和球形颗粒的不同沉积热点,在吸入和呼出阶段之间存在明显差异,并且对呼吸流量具有显着的敏感性。观察到的沉积趋势为可能影响感染模式和指导雾化治疗设计的形状和阶段依赖风险区域提供了新的见解。通过解决以前被忽视的非球形颗粒运输和瞬态气流方面,这项工作推进了人类呼吸系统中空气传播病毒病原体暴露的定量建模。
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引用次数: 0
Effect of modified dry water on the explosion characteristics of polypropylene dust 改性干水对聚丙烯粉尘爆炸特性的影响
IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-19 DOI: 10.1016/j.powtec.2025.121936
Jingui Wang , Chensheng Lin , Jianhao Wei , Yuchen Ke , Su Zhang
<div><div>Polypropylene (<span><math><mi>PP</mi></math></span>) dust presents a material explosion hazard during handling. We quantify the suppression efficacy and mechanisms of neat “dry water” (DW; micronized water encapsulated by hydrophobic silica) and two modified variants—monoammonium phosphate DW (<span><math><mi>MAP</mi><mo>−</mo><mi>DW</mi><mo>,</mo><mi>NH</mi><mo>₄</mo><mi>H</mi><mo>₂</mo><mi>PO</mi><mo>₄</mo></math></span>) and potassium hydrogen carbonate <span><math><mi>DW</mi></math></span> (<span><math><mi>KHCO</mi><mo>₃</mo><mo>−</mo><mi>DW</mi></math></span>). Tests were performed in a <span><math><mn>20</mn><mspace></mspace><mi>L</mi></math></span> spherical vessel (<span><math><mi>EN</mi><mspace></mspace><mn>14034</mn><mo>−</mo><mn>2</mn></math></span>) across four particle sizes (<span><math><mn>10</mn><mo>/</mo><mn>30</mn><mo>/</mo><mn>60</mn><mo>/</mo><mn>140</mn><mspace></mspace><mi>μm</mi></math></span>) and from lean to fuel-rich dust concentrations. Both maximum explosion pressure <span><math><mo>(</mo><msub><mi>P</mi><mi>max</mi></msub></math></span>)and maximum pressure-rise rate (<span><math><msub><mfenced><mrow><mi>d</mi><mi>p</mi><mo>/</mo><mi>d</mi><mi>t</mi></mrow></mfenced><mi>max</mi></msub><mo>)</mo></math></span> showed unimodal dependence on concentration; for <span><math><mn>10</mn><mspace></mspace><mi>μm</mi><mspace></mspace><mi>PP</mi></math></span>, <span><math><msub><mi>P</mi><mi>max</mi></msub></math></span> was <span><math><mo>≈</mo><mn>0.68</mn><mspace></mspace><mi>MPa</mi><mspace></mspace></math></span> at <span><math><mi>ρ</mi><mo>≈</mo><mn>300</mn><mspace></mspace><mi>g</mi><mo>·</mo><msup><mi>m</mi><mrow><mo>−</mo><mn>3</mn></mrow></msup></math></span> (St-1). Under near-optimal <span><math><mi>PP</mi></math></span> baselines, dose–response assays parameterized by the dosage ratio <span><math><mi>φ</mi></math></span> showed consistent ranking <span><math><mi>KHCO</mi><mo>₃</mo><mo>−</mo><mi>DW</mi><mo>></mo><mi>MAP</mi><mo>−</mo><mi>DW</mi><mo>></mo><mi>DW</mi></math></span>. All formulations reduced <span><math><msub><mi>P</mi><mi>max</mi></msub></math></span> and <span><math><msub><mfenced><mrow><mi>d</mi><mi>p</mi><mo>/</mo><mi>d</mi><mi>t</mi></mrow></mfenced><mi>max</mi></msub></math></span> while delaying pressure-rise dynamics, and the <span><math><mn>15</mn><mspace></mspace><mi>wt</mi><mo>%</mo></math></span> KHCO₃ system (<span><math><mi>KH</mi><mo>−</mo><mn>15</mn></math></span>) achieved <span><math><mo>></mo><mn>80</mn><mo>%</mo></math></span> reduction in <span><math><msub><mi>P</mi><mi>max</mi></msub></math></span> at <span><math><mi>φ</mi><mo>≈</mo><mn>1.2</mn></math></span>, driving <span><math><msub><mi>K</mi><mi>st</mi></msub></math></span> <!--> toward St-0. a slight increase in rate was occasionally observed at very low <span><math><mi>φ</mi></math></span>, likely due to enhanced cloud dispersion. Mechanistic diagnostics coupled TG–FTIR–MS with TG–DSC. Neat <span><math
聚丙烯(PP)粉尘在处理过程中存在物质爆炸危险。我们量化了纯“干水”(DW;疏水二氧化硅包覆的微粉水)和两种改性型磷酸铵DW (MAP−DW,NH₄H₂PO₄)和碳酸氢钾DW (KHCO₃−DW)的抑制效果和机理。在20L球形容器(EN14034−2)中进行了四种粒径(10/30/60/140μm)和从贫到富燃料粉尘浓度的测试。最大爆炸压力(Pmax)和最大升压速率(dp/dtmax)均与浓度呈单峰关系;当ρ≈300g·m−3 (St-1)时,10μmPP时,Pmax≈0.68MPa。在接近最优的PP基线下,以剂量比φ参数化的剂量-反应试验显示一致的顺序为KHCO₃−DW>;MAP−DW>;DW。所有配方都降低了Pmax和dp/dtmax,同时延迟了压力上升动力学,15wt%的KHCO₃体系(KH−15)在φ≈1.2时实现了Pmax降低>;80%,推动Kst向St-0方向发展。偶尔在非常低的φ下观察到速率略有增加,可能是由于云弥散增强。机械诊断耦合TG-FTIR-MS与TG-DSC。纯PP采用C₃−C₄烯烃为主的单步热解(≈370 ~ 505℃)。DW表现出较强的低温吸热(≈30 ~ 130℃)。MAP−DW增加了高温p自由基清除和凝聚相屏障的形成,而KHCO₃−DW提供了缓慢释放的冷却/惰性(H₂O/CO₂)和可回收的气相k循环,加速了链终止反应。总之,这些结果表明改性dw -特别是KHCO₃−dw -是一种有效的多级聚合物粉尘爆炸抑制剂,并为工程应用提供配方指导。
{"title":"Effect of modified dry water on the explosion characteristics of polypropylene dust","authors":"Jingui Wang ,&nbsp;Chensheng Lin ,&nbsp;Jianhao Wei ,&nbsp;Yuchen Ke ,&nbsp;Su Zhang","doi":"10.1016/j.powtec.2025.121936","DOIUrl":"10.1016/j.powtec.2025.121936","url":null,"abstract":"&lt;div&gt;&lt;div&gt;Polypropylene (&lt;span&gt;&lt;math&gt;&lt;mi&gt;PP&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;) dust presents a material explosion hazard during handling. We quantify the suppression efficacy and mechanisms of neat “dry water” (DW; micronized water encapsulated by hydrophobic silica) and two modified variants—monoammonium phosphate DW (&lt;span&gt;&lt;math&gt;&lt;mi&gt;MAP&lt;/mi&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mi&gt;DW&lt;/mi&gt;&lt;mo&gt;,&lt;/mo&gt;&lt;mi&gt;NH&lt;/mi&gt;&lt;mo&gt;₄&lt;/mo&gt;&lt;mi&gt;H&lt;/mi&gt;&lt;mo&gt;₂&lt;/mo&gt;&lt;mi&gt;PO&lt;/mi&gt;&lt;mo&gt;₄&lt;/mo&gt;&lt;/math&gt;&lt;/span&gt;) and potassium hydrogen carbonate &lt;span&gt;&lt;math&gt;&lt;mi&gt;DW&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt; (&lt;span&gt;&lt;math&gt;&lt;mi&gt;KHCO&lt;/mi&gt;&lt;mo&gt;₃&lt;/mo&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mi&gt;DW&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;). Tests were performed in a &lt;span&gt;&lt;math&gt;&lt;mn&gt;20&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;L&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt; spherical vessel (&lt;span&gt;&lt;math&gt;&lt;mi&gt;EN&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mn&gt;14034&lt;/mn&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/math&gt;&lt;/span&gt;) across four particle sizes (&lt;span&gt;&lt;math&gt;&lt;mn&gt;10&lt;/mn&gt;&lt;mo&gt;/&lt;/mo&gt;&lt;mn&gt;30&lt;/mn&gt;&lt;mo&gt;/&lt;/mo&gt;&lt;mn&gt;60&lt;/mn&gt;&lt;mo&gt;/&lt;/mo&gt;&lt;mn&gt;140&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;μm&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;) and from lean to fuel-rich dust concentrations. Both maximum explosion pressure &lt;span&gt;&lt;math&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;msub&gt;&lt;mi&gt;P&lt;/mi&gt;&lt;mi&gt;max&lt;/mi&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;)and maximum pressure-rise rate (&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mfenced&gt;&lt;mrow&gt;&lt;mi&gt;d&lt;/mi&gt;&lt;mi&gt;p&lt;/mi&gt;&lt;mo&gt;/&lt;/mo&gt;&lt;mi&gt;d&lt;/mi&gt;&lt;mi&gt;t&lt;/mi&gt;&lt;/mrow&gt;&lt;/mfenced&gt;&lt;mi&gt;max&lt;/mi&gt;&lt;/msub&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/math&gt;&lt;/span&gt; showed unimodal dependence on concentration; for &lt;span&gt;&lt;math&gt;&lt;mn&gt;10&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;μm&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;PP&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;, &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mi&gt;P&lt;/mi&gt;&lt;mi&gt;max&lt;/mi&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; was &lt;span&gt;&lt;math&gt;&lt;mo&gt;≈&lt;/mo&gt;&lt;mn&gt;0.68&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;MPa&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;/math&gt;&lt;/span&gt; at &lt;span&gt;&lt;math&gt;&lt;mi&gt;ρ&lt;/mi&gt;&lt;mo&gt;≈&lt;/mo&gt;&lt;mn&gt;300&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;g&lt;/mi&gt;&lt;mo&gt;·&lt;/mo&gt;&lt;msup&gt;&lt;mi&gt;m&lt;/mi&gt;&lt;mrow&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mn&gt;3&lt;/mn&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/math&gt;&lt;/span&gt; (St-1). Under near-optimal &lt;span&gt;&lt;math&gt;&lt;mi&gt;PP&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt; baselines, dose–response assays parameterized by the dosage ratio &lt;span&gt;&lt;math&gt;&lt;mi&gt;φ&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt; showed consistent ranking &lt;span&gt;&lt;math&gt;&lt;mi&gt;KHCO&lt;/mi&gt;&lt;mo&gt;₃&lt;/mo&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mi&gt;DW&lt;/mi&gt;&lt;mo&gt;&gt;&lt;/mo&gt;&lt;mi&gt;MAP&lt;/mi&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mi&gt;DW&lt;/mi&gt;&lt;mo&gt;&gt;&lt;/mo&gt;&lt;mi&gt;DW&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;. All formulations reduced &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mi&gt;P&lt;/mi&gt;&lt;mi&gt;max&lt;/mi&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; and &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mfenced&gt;&lt;mrow&gt;&lt;mi&gt;d&lt;/mi&gt;&lt;mi&gt;p&lt;/mi&gt;&lt;mo&gt;/&lt;/mo&gt;&lt;mi&gt;d&lt;/mi&gt;&lt;mi&gt;t&lt;/mi&gt;&lt;/mrow&gt;&lt;/mfenced&gt;&lt;mi&gt;max&lt;/mi&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; while delaying pressure-rise dynamics, and the &lt;span&gt;&lt;math&gt;&lt;mn&gt;15&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;wt&lt;/mi&gt;&lt;mo&gt;%&lt;/mo&gt;&lt;/math&gt;&lt;/span&gt; KHCO₃ system (&lt;span&gt;&lt;math&gt;&lt;mi&gt;KH&lt;/mi&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mn&gt;15&lt;/mn&gt;&lt;/math&gt;&lt;/span&gt;) achieved &lt;span&gt;&lt;math&gt;&lt;mo&gt;&gt;&lt;/mo&gt;&lt;mn&gt;80&lt;/mn&gt;&lt;mo&gt;%&lt;/mo&gt;&lt;/math&gt;&lt;/span&gt; reduction in &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mi&gt;P&lt;/mi&gt;&lt;mi&gt;max&lt;/mi&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; at &lt;span&gt;&lt;math&gt;&lt;mi&gt;φ&lt;/mi&gt;&lt;mo&gt;≈&lt;/mo&gt;&lt;mn&gt;1.2&lt;/mn&gt;&lt;/math&gt;&lt;/span&gt;, driving &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mi&gt;K&lt;/mi&gt;&lt;mi&gt;st&lt;/mi&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; &lt;!--&gt; toward St-0. a slight increase in rate was occasionally observed at very low &lt;span&gt;&lt;math&gt;&lt;mi&gt;φ&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;, likely due to enhanced cloud dispersion. Mechanistic diagnostics coupled TG–FTIR–MS with TG–DSC. Neat &lt;span&gt;&lt;math","PeriodicalId":407,"journal":{"name":"Powder Technology","volume":"469 ","pages":"Article 121936"},"PeriodicalIF":4.6,"publicationDate":"2025-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145576399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative kinematic behavior of board-like particles and spherical particles in the disc screen discharge region 板状颗粒和球形颗粒在圆盘筛出料区的运动行为比较
IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-19 DOI: 10.1016/j.powtec.2025.121932
Yangzhen Gao , Liang Han , Yan Meng , Guancheng Dong , Jian Zhang
Enhancing sorting accuracy for municipal solid waste (MSW) is a key objective in waste management. In disc screens, sorting outcomes are determined by material motion in the discharge region, where kinematic mechanisms remain insufficiently understood. This study investigates the transport behavior of board-like particles and spherical particles using high-speed imaging and trajectory analysis. While both materials exhibit ballistic superdiffusion driven by rotating discs, spherical particles experience significantly greater trajectory variability due to strong perturbations near the disc shafts. Despite similar average path straightness, spherical particles exhibit a strongly positively skewed distribution, indicating that a few extreme tumbling events drive their motion instability and increase misclassification risk. Material properties and dimensions further modulate transport behavior: low-density foam boards have higher velocities, and aspect ratio significantly affects residence time. In contrast, large wood spheres exhibit greater transport instability, leading to prolonged retention in the discharge zone. These findings reveal the intrinsic relationship between particle shape, trajectory variability, and sorting behavior in disc screens, offering theoretical support for structural optimization and control parameter tuning. They also provide practical insights for improving material recovery facility (MRF) performance, reducing sorting errors, and supporting sustainable MSW management and circular economy goals.
提高城市固体废物分类的准确性是废物管理的一个关键目标。在圆盘筛中,分选结果是由出料区的物料运动决定的,其中的运动机制仍然没有得到充分的了解。本文利用高速成像和轨迹分析技术研究了板状粒子和球形粒子的输运行为。虽然这两种材料都表现出由旋转圆盘驱动的弹道超扩散,但由于圆盘轴附近的强烈扰动,球形颗粒经历了明显更大的轨迹可变性。尽管平均路径直线度相似,但球形颗粒表现出强烈的正偏态分布,表明少数极端翻滚事件驱动了它们的运动不稳定性,增加了误分类风险。材料性质和尺寸进一步调节传输行为:低密度泡沫板具有更高的速度,长宽比显著影响停留时间。相比之下,大的木球表现出更大的输运不稳定性,导致在放电区滞留时间延长。这些发现揭示了颗粒形状、轨迹可变性和盘式筛分选行为之间的内在关系,为结构优化和控制参数调整提供了理论支持。它们还为提高材料回收设施(MRF)的性能、减少分类错误、支持可持续的城市固体废物管理和循环经济目标提供了实用的见解。
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引用次数: 0
Incorporation of graphene into metallic porous media via co-sintering technique: Impact on capillary pressure, porosity and permeability 通过共烧结技术将石墨烯掺入金属多孔介质:对毛细管压力、孔隙度和渗透率的影响
IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-19 DOI: 10.1016/j.powtec.2025.121947
Asif Khan , Carlo S. Iorio , Mehdi Feizpour , Andrey Glushchuk
An alternative approach of graphene implementation inside a porous structure has been presented. It consists of three stages: (I) preparation of a graphene ink–binder combination; (II) incorporation of graphene inside a porous medium; and (III) co-sintering of graphene within pores. The technique was verified for nickel and stainless steel 316 L materials. The presence of graphene was confirmed by Raman spectroscopy in both cases after co-sintering. The alloy material showed improved performance that positively affected the overall flow dynamics. A significant increase in permeability, with a 60 % improvement over uncoated variants, was obtained along with a reduction in capillary pressure.
提出了在多孔结构内实现石墨烯的另一种方法。它包括三个阶段:(1)制备石墨烯油墨-粘合剂组合;(II)在多孔介质中掺入石墨烯;(三)石墨烯在孔隙内共烧结。对镍和不锈钢316l材料进行了验证。在共烧结后的两种情况下,用拉曼光谱证实了石墨烯的存在。合金材料的性能得到改善,对整体流动动力学产生了积极的影响。渗透率显著提高,与未涂覆的变体相比提高了60%,同时毛细管压力降低。
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引用次数: 0
The effect of particle packing structure on the dynamic properties of super-ellipsoid systems during uniaxial compression 颗粒堆积结构对超椭球体系单轴压缩动态性能的影响
IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-19 DOI: 10.1016/j.powtec.2025.121941
Chuang Zhao , Peng Zhang , Li Bao , Chengbo Li
The study of the dynamic properties of granular materials during uniaxial compression provides insights into the macro-micro mechanical relationships of the system, and has been a focus of research. In this study, the uniaxial compression process of super-ellipsoid systems with different packing structures is simulated using the discrete element method. The proposed characterization theory for non-spherical particle structures is applied to calculate the evolution of packing structures during compression. The influence of shear-induced anisotropy on the elastic moduli is then computed and discussed. The results show that different packing structures significantly affect the elastic modulus of the system, and that for systems with the same packing structure, the volume fraction, coordination number, and elastic modulus decrease as compression progresses. To verify the change in elastic modulus, the propagation of elastic waves within the system is simulated, and the compression and shear wave velocities are calculated using the time-of-flight method. The variation in elastic modulus during compression is further confirmed from the perspective of changes in wave velocities. The particle packing structure characterization method used in this study is universal and applicable to the decomposition of irreducible super-tensor bases in any dimension. This approach has both practical value in engineering computations and theoretical significance.
对颗粒材料在单轴压缩过程中的动态特性进行研究,有助于深入了解该体系的宏观-微观力学关系,是目前研究的热点。本文采用离散元法对具有不同填料结构的超椭球体系统的单轴压缩过程进行了数值模拟。将提出的非球形颗粒结构表征理论应用于压缩过程中堆积结构的演化计算。然后计算并讨论了剪切诱导各向异性对弹性模量的影响。结果表明:不同填料结构对体系的弹性模量有显著影响,对于相同填料结构的体系,体积分数、配位数和弹性模量随着压缩的进行而减小;为了验证弹性模量的变化,模拟了弹性波在系统内的传播,并利用飞行时间法计算了压缩波速和剪切波速。从波速变化的角度进一步证实了压缩过程中弹性模量的变化。本文所采用的粒子堆积结构表征方法具有通用性,适用于任何维度上不可约超张量基的分解。该方法具有工程计算的实用价值和理论意义。
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引用次数: 0
Effect of flow regimes on flowability of titania nanoparticle agglomerates and particle size distribution in a conical fluidized bed: evaluation of particle collision parameters and collision models 流动形式对锥形流化床中纳米二氧化钛团聚体流动性和粒径分布的影响:颗粒碰撞参数和碰撞模型的评估
IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-19 DOI: 10.1016/j.powtec.2025.121926
Alireza Bahramian , Martin Olazar
The dependence of powder flowability on particle size distribution (PSD) at different flow regimes offers new insights for a better understanding of the nanoparticle (NP) agglomeration mechanisms, which could not be recognized in detail by experiments. This study aims to evaluate the validity of collision models for the estimation of the PSD of titania NP agglomerates in a conical fluidized bed. A combination of fragile primary simple-agglomerates (∼10-70 μm) and secondary types (∼70-100 μm) was experimentally identified in the turbulent flow regime, while rigid complex-agglomerates (∼100-150 μm) were mainly formed in the partially fluidized regime. A narrow-cut PSD was observed in the spout zone, where the mean agglomerate size was approximately three times smaller than in the annular zone. CFD-DEM simulations using the adhesive Hertz-Mindlin and Johnson-Kendall-Roberts (HM-JKR) model and the linear spring-dashpot (LSD) model have been applied to adjust particle collision parameters and collision model variables. The restitution coefficient noticeably affects the particle breakage rate in the partially fluidized regime, while the coefficients of friction and wall specularity affect the agglomeration rate in the turbulent flow. The collision frequency was more influenced by the LSD model than by HM-JKR, and its magnitude was greater in the turbulent flow than in the partially fluidized regime. The agglomerate frequency is highly affected by the magnitude of the cohesive force, with Gaussian-type and narrow-cut PSDs being predicted by applying strong and weak cohesive forces, respectively. The HM-JKR model shows better agreement with the experimental data than the LSD model in turbulent flow, whereas the LSD model provides more accurate results in partially fluidized conditions.
粉末流动性对不同流动状态下粒径分布(PSD)的依赖性为更好地理解纳米颗粒(NP)团聚机制提供了新的见解,这些机制在实验中无法得到详细的认识。本研究旨在评估碰撞模型在锥形流化床中估计二氧化钛NP团聚体PSD的有效性。在紊流条件下,实验发现了脆弱的初级简单团聚体(~ 10-70 μm)和次级团聚体(~ 70-100 μm)的组合,而刚性复杂团聚体(~ 100-150 μm)主要在部分流化条件下形成。在喷口区观察到窄切PSD,其中平均团聚体大小约为环状区域的三分之一。采用粘接Hertz-Mindlin和Johnson-Kendall-Roberts (HM-JKR)模型和线性弹簧-阻尼器(LSD)模型进行CFD-DEM模拟,调整粒子碰撞参数和碰撞模型变量。在部分流化状态下,恢复系数显著影响颗粒破碎率,而在湍流状态下,摩擦系数和壁面反射系数显著影响团聚率。与HM-JKR相比,LSD模型对碰撞频率的影响更大,并且在湍流状态下碰撞频率的幅度大于部分流化状态。结块频率受黏结力大小的影响较大,分别用强黏结力和弱黏结力预测高斯型和窄切型psd。HM-JKR模型在湍流条件下比LSD模型更符合实验数据,而LSD模型在部分流化条件下更准确。
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引用次数: 0
A coupled simulation computational model for evaluating the seeds movement and airflow distribution characteristics in pneumatic centralized wheat metering device 一种评价小麦集中计量装置中种子运动和气流分布特性的耦合仿真计算模型
IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-19 DOI: 10.1016/j.powtec.2025.121914
Weiwei Wang , Mingchun Yang , Wenbing Shi , Xue An , Shun Zhang , Ce Liu , Lichao Liu , Quan Zheng , Liqing Chen
In order to enhance the unsteady control of wheat seed flow in the conveying tube and achieve instantaneous stable and accurate seeding quantity of each row, the pressurized seed supply device has been optimized and designed to improve distribution characteristics and performance of the pneumatic centralized wheat seeding system. The CFD-DEM coupling method was used to simulate and analyze the influence of the pressure distribution and seed motion in the tube on the coefficient of variation of instantaneous seeding quantity and the coefficient of variation of inter-row instantaneous seeding quantity difference under the structure and working parameters. Bench tests were designed to verify the simulation results. Through response surface analysis, the optimal seeding performance was achieved at a inclined feeding section angle of 40°, inclined feeding section height of 16 mm, and airflow velocity of 30 m/s, resulting in the coefficient of variation of instantaneous seeding quantity on the seed feeding device is 3.82 %, and the coefficient of variation of inter-row instantaneous seeding quantity difference is 4.54 %. Bench test results unveiled that, under the optimal parameter combination, with the rotation speed of the seed supply spindle controlled at 20–60 rpm, the coefficient of variation of instantaneous seeding quantity on the seed supply device is less than 5.0 %, the coefficient of variation of inter-row instantaneous seeding quantity difference is less than 5.6 %, and the seed damage rate is less than 0.15 %, which meets the agronomic requirements of wheat seeding. This research provides valuable references for optimizing the design of pneumatic centralized wheat metering device and improving the uniformity of wheat seeding.
为了加强对输送管内小麦种流的非定常控制,实现每行瞬时稳定准确的播量,对增压供种装置进行了优化设计,以改善气力式小麦集中播种系统的分配特性和性能。采用CFD-DEM耦合方法,模拟分析了在结构和工作参数下,管内压力分布和种子运动对瞬时播种量变异系数和行间瞬时播种量差变异系数的影响。设计了台架试验来验证仿真结果。通过响应面分析,在倾斜投料段角度为40°、倾斜投料段高度为16 mm、气流速度为30 m/s时,获得了最优的播种性能,使投种装置瞬时播种量的变异系数为3.82%,行间瞬时播种量差的变异系数为4.54%。台架试验结果表明,在最优参数组合下,供种主轴转速控制在20 ~ 60 rpm,供种装置瞬时播种量变异系数小于5.0%,行间瞬时播种量差异变异系数小于5.6%,害种率小于0.15%,满足小麦播种的农艺要求。该研究为优化小麦气力集中计量装置的设计,提高小麦播种均匀性提供了有价值的参考。
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Powder Technology
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