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Broadband efficient light-absorbing SS-PPy@CNT membranes prepared by electrochemical deposition for photothermal conversion 通过电化学沉积制备宽带高效光吸收 SS-PPy@CNT 膜,用于光热转换
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-16 DOI: 10.1016/j.renene.2024.121926
Mengyan Liu , Benfeng Zhu , Na Chen , Jie Zhu , Caihe Lei , Ruopeng Li , Yumeng Yang , Jiao Liu , Zhao Zhang , Peixia Yang , Oleg Levin , Elena Alekseeva , Bo Fang , Guoying Wei , Jingjing Yang
Solar energy is an eco-conscious substitute, for solar energy absorption and subsequent light-to-heat conversion, light-absorbing materials require broad-spectrum light absorption capabilities. Herein, we present the fabrication of broadband light-absorbing polypyrrole-carboxylated carbon nanotube membranes via a facile electrochemical deposition route. By manipulating electrochemical deposition time, the structure of the membranes was tailored, resulting in enhanced absorption, achieving over 98.95 % across the entire solar spectrum. The membranes demonstrated exemplary thermal efficacy and insensitivity to incident angles in photothermal conversion, the membranes facilitated a notable 12 °C temperature elevation within a simulated greenhouse compared to ambient conditions. Thus, these membranes exhibit considerable potential for widespread application in photothermal conversion and greenhouse technology.
太阳能是一种具有环保意识的替代能源,为了吸收太阳能并将其转化为热能,光吸收材料需要具有宽光谱的光吸收能力。在此,我们介绍了通过简便的电化学沉积路线制备宽光谱光吸收聚吡咯-羧基碳纳米管膜的方法。通过操纵电化学沉积时间,对膜的结构进行了定制,从而增强了吸收能力,在整个太阳光谱范围内的吸收率超过 98.95%。在光热转换过程中,薄膜表现出了出色的热效率和对入射角度的不敏感性,与环境条件相比,薄膜使模拟温室内的温度明显升高了 12 °C。因此,这些膜在光热转换和温室技术的广泛应用方面具有相当大的潜力。
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引用次数: 0
Multi-objective optimization of geothermal heating systems based on thermal economy and environmental impact evaluation 基于热经济和环境影响评估的地热供暖系统多目标优化
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-14 DOI: 10.1016/j.renene.2024.121858
Zhenhua Xia , Guosheng Jia , Zeyu Tao , Wei Jia , Yishu Shi , Liwen Jin
High-temperature geothermal resources are increasingly being explored as an alternative to coal and natural gas for space heating. In light of the growing demand for energy conservation and emission reduction, it is crucial to conduct a comprehensive evaluation of geothermal energy according to environmental impact and energy cost. Based on geothermal heating systems in Xi'an, China, this study develops a model involving the life cycle assessment (LCA) method to assess the borehole heat exchanger (BHE) in heating systems, encompassing carbon intensity (Cintensity). The response surface method was employed to optimize the drilling depth, operating flow, and pipe diameter ratio, which influences carbon intensity. The findings revealed that the minimum Cintensity is 24.11 g(CO2)·kWh−1, corresponding to a 4000 m burial depth, 20 m3 h−1 flow rate, and 0.54 diameter ratio. However, these results diverge from the minimum levelized cost of energy (LCOE) of $7.84/GJ, with 3912.8 m, 34.32 m3 h−1, and 0.64. A dual-objective optimization indicates the allocation of weights to the objective functions influences the optimal drilling depth (the optimal value is between 3920.51 m and 3921.62 m) and operating flow rate (ranging from 28.8 to 31.4 m3 h−1). The optimal outcomes for LCOE and Cintensity are contingent upon the decision-makers' weight allocation.
作为煤炭和天然气的替代品,高温地热资源正被越来越多地用于空间供暖。随着节能减排要求的不断提高,根据环境影响和能源成本对地热能进行综合评价至关重要。本研究以中国西安的地热供暖系统为基础,采用生命周期评估(LCA)方法建立了一个模型,用于评估供暖系统中的井孔换热器(BHE),包括碳强度(Cintensity)。采用响应面法对影响碳强度的钻孔深度、工作流量和管道直径比进行了优化。研究结果表明,最低碳强度为 24.11 g(CO2)-kWh-1,与 4000 米埋深、20 立方米/小时流量和 0.54 的管径比相对应。然而,这些结果与 3912.8 米、34.32 立方米/小时和 0.64 的最小平准化能源成本(LCOE)(7.84 美元/千焦耳)相去甚远。双目标优化表明,目标函数的权重分配会影响最佳钻井深度(最佳值介于 3920.51 米和 3921.62 米之间)和作业流量(介于 28.8 至 31.4 立方米/小时之间)。LCOE 和 Cintensity 的最佳结果取决于决策者的权重分配。
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引用次数: 0
Bi-level multi-objective optimization for a hybrid carbon pricing initiative towards biomass co-firing with coal 针对生物质与煤炭混合燃烧的混合碳定价倡议的双层多目标优化
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-13 DOI: 10.1016/j.renene.2024.121829
Qian Huang , Qing Feng
Coal-fired power generation is one of the major contributors to global carbon emissions. Biomass co-firing with coal is a cost-effective approach for carbon abatement. This paper formulates a hybrid carbon pricing initiative that combines an emission trading system (ETS) and a carbon tax, with ETS being applied to large power plants and carbon tax being applied to small power plants. A bi-level multi-objective optimization model is established to assist the multiple stakeholders to develop optimal strategies, and quantify environmental and economic impacts. In the proposed model, decision sequence from the authority to the coal-fired power plants is considered, and trade-offs between social welfare and carbon intensity is determined. Bi-level interactive fuzzy approach is adopted to search for satisfactory solutions. A case study is conducted to demonstrate the model’s practicality and efficiency, and the results reveal that this model is adequate for finding Stackelberg equilibrium between the hierarchical decision-makers with conflicting objectives. Sensitivity analyses are conducted to provide the stakeholders with reasonable and practical strategies under various situations. It is found that higher preferences for economic benefits and satisfactory degrees would increase carbon tax price. Management recommendations are provided to support the hybrid initiative for biomass co-firing with coal.
燃煤发电是造成全球碳排放的主要因素之一。生物质与煤炭联合燃烧是一种具有成本效益的碳减排方法。本文提出了一种混合碳定价方案,将排放交易体系(ETS)和碳税相结合,其中排放交易体系适用于大型发电厂,碳税适用于小型发电厂。本文建立了一个双层多目标优化模型,以帮助多方利益相关者制定最优策略,并量化对环境和经济的影响。在建议的模型中,考虑了从当局到燃煤发电厂的决策顺序,并确定了社会福利和碳强度之间的权衡。该模型采用双层互动模糊方法来寻找令人满意的解决方案。通过案例研究证明了该模型的实用性和高效性,结果表明该模型足以在目标相互冲突的分层决策者之间找到斯台克尔伯格均衡。敏感性分析为利益相关者提供了各种情况下合理实用的策略。结果发现,对经济效益和满意度的更高偏好将提高碳税价格。提出了支持生物质与煤炭混合燃烧的管理建议。
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引用次数: 0
Rural energy poverty alleviation in OECD nations: An integrated analysis of renewable energy, green taxation, and the United Nations agenda 2030 经合组织国家的农村能源减贫:对可再生能源、绿色税收和联合国 2030 年议程的综合分析
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-13 DOI: 10.1016/j.renene.2024.121900
Muhammad Salman , Guimei Wang
Energy poverty in the Organisation for Economic Co-operation and Development (OECD) countries is a complex issue that needs careful and targeted solutions. Tens of millions of households in OECD countries struggle to pay for enough electricity and heating to meet their basic needs. Thus, it is essential to make a detailed assessment of rural energy poverty with an integrated approach. In so doing, we first measure rural energy poverty composite index across 38 OECD countries and their 5 major partners from 2000 to 2021. We then explored the linear effect of renewable energy technologies on energy poverty alleviation. Moreover, the mediating effect of green taxes on rural energy poverty through renewable energy technologies was analysed. Finally, the fuzzy regression discontinuity (FRD) method is employed to address the endogeneity issue associated with the assignment of the 2030 United Nations (UN) Agenda and to identify treatment effects. The results show that rural energy poverty improves over time. However, significant spatiotemporal disparities in alleviation efforts are found across countries. The results of Method of Moment Quantile Regression (MMQR) approach reveal that renewable energy technologies can accelerate rural energy poverty mitigation in the sample countries. We find that green taxation is an important mediating channel through which the adoption of renewable energy technologies alleviates rural energy poverty. The results of the Fuzzy-RD show that the 2030 UN agenda was effective in increasing the likelihood of rural energy poverty mitigation. The results remain consistent after a battery of robustness tests. This study offers valuable insights that can aid policymakers in formulating robust public policies.
经济合作与发展组织(OECD)国家的能源贫困是一个复杂的问题,需要谨慎和有针对性的解决方案。在经济合作与发展组织(OECD)国家中,数以千万计的家庭难以支付足够的电费和取暖费,以满足其基本需求。因此,必须采用综合方法对农村能源贫困进行详细评估。为此,我们首先测算了 2000 年至 2021 年 38 个经合组织国家及其 5 个主要合作伙伴的农村能源贫困综合指数。然后,我们探讨了可再生能源技术对能源减贫的线性影响。此外,我们还分析了绿色税收通过可再生能源技术对农村能源贫困的中介效应。最后,我们采用模糊回归不连续法(FRD)解决了与 2030 年联合国(UN)议程分配相关的内生性问题,并确定了处理效应。结果显示,随着时间的推移,农村能源贫困状况有所改善。然而,各国在缓解贫困方面存在明显的时空差异。矩量回归方法(MMQR)的结果显示,可再生能源技术可以加速样本国家农村能源贫困的缓解。我们发现,绿色税收是采用可再生能源技术缓解农村能源贫困的一个重要中介渠道。Fuzzy-RD 的结果表明,2030 年联合国议程能有效提高农村能源贫困缓解的可能性。经过一系列稳健性检验后,结果保持一致。这项研究提供了宝贵的见解,有助于决策者制定稳健的公共政策。
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引用次数: 0
Dynamic response and power performance of a combined semi-submersible floating wind turbine and point absorber wave energy converter array 半潜式浮动风力涡轮机和点吸收器波能转换器组合阵列的动态响应和功率性能
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-13 DOI: 10.1016/j.renene.2024.121903
Shuaijun Xu , Baifeng Ji , Fan Xu , Changkun Chen
With the global demand for renewable energy rising, offshore renewable energy development has gained more attention. The combination of wind and wave energy is a new trend. Ensuring stability in combined systems is crucial for efficiency of absorbing energy. A novel combined wind and wave energy system with a semi-submersible floating wind turbine (FWT) and an array of six torus-shaped point absorber wave energy converters (WECs) is proposed. The dynamic response of combined system is investigated using 3D potential flow theory by comparing to the original system. The effects of power take-off (PTO) damping, WEC float shape and seasonal variation on the dynamic response and power performance of combined system are studied. The results show that the addition of WEC array improves the stability and power production of combined system. Meanwhile, the total power of combined system is approximately 2.5%–6.5 % higher than that of original system. PTO damping mainly affects the heave motion of combined system. As PTO damping increases, the first peak of mean power of WEC array shifts towards the long period, while the second peak of that shifts towards the short period. The conical-bottom WEC generates the most power compared to the flat-bottom WEC, hemispherical-bottom WEC and concave-bottom WEC. The combined system generates the most power in winter, and the total annual electricity output can be up to 2.99 × 104 MWh.
随着全球对可再生能源需求的不断增长,近海可再生能源的开发受到越来越多的关注。风能和波浪能的结合是一种新趋势。确保组合系统的稳定性对于提高吸收能量的效率至关重要。本文提出了一种新型风能和波浪能组合系统,该系统由一台半潜式浮动风力涡轮机(FWT)和六个环形点吸收波能转换器(WECs)组成。通过与原始系统进行比较,利用三维势流理论研究了组合系统的动态响应。研究了功率输出(PTO)阻尼、波浪能转换器浮子形状和季节变化对组合系统动态响应和功率性能的影响。结果表明,增加风电机组阵列可提高组合系统的稳定性和发电量。同时,组合系统的总功率比原系统高出约 2.5%-6.5 %。PTO 阻尼主要影响组合系统的摆动。随着 PTO 阻尼的增加,水力发电阵列平均功率的第一个峰值向长周期移动,而第二个峰值向短周期移动。与平底式水力发电阵列、半球形水力发电阵列和凹底式水力发电阵列相比,锥底式水力发电阵列产生的功率最大。组合系统在冬季发电量最大,年总发电量可达 2.99 × 104 兆瓦时。
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引用次数: 0
A hybrid soft sensor framework for real-time biodiesel yield prediction: Integrating mechanistic models and machine learning algorithms 用于实时生物柴油产量预测的混合软传感器框架:机理模型与机器学习算法的整合
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-13 DOI: 10.1016/j.renene.2024.121888
Mustafa Kamal Pasha , Lingmei Dai , Dehua Liu , Wei Du , Miao Guo
Biodiesel yield prediction is vital for optimizing process efficiency, minimizing costs, and maintaining product quality. Traditional methods are labor-intensive, costly, and lack real-time capabilities, leading to inefficiencies in operations. Data-driven soft sensors offer real-time prediction but require extensive, high-quality datasets, posing practical challenges. To address these limitations, this study proposes a hybrid soft sensor model that integrates mechanistic and data-driven approaches. Mechanistic models were utilized to generate computational data via MATLAB®, reducing the reliance on costly laboratory experiments. A comprehensive dataset (n = 1500) comprising seven input variables—catalyst type, feedstock type, temperature, reaction time, free fatty acid (FFA) content, water content, and methanol-to-oil ratio—along with one output variable (biodiesel yield) was developed. This dataset was used to train various machine learning algorithms, with the artificial neural network (ANN) model demonstrating the highest predictive accuracy, achieving an R2 (goodness of fit) of 0.998 and root mean square error (RMSE) of 0.303. Hyperparameter tuning further enhanced the model's performance, reducing RMSE and the mean absolute error (MAE) by 63 % and 61.7 %, respectively. By combining mechanistic and data-driven techniques, this hybrid model effectively overcomes the limitations of traditional and purely data-driven methods, providing a cost-effective and efficient solution for biodiesel yield prediction and data generation.
生物柴油产量预测对于优化工艺效率、降低成本和保持产品质量至关重要。传统方法耗费大量人力物力,成本高昂,而且缺乏实时性,导致操作效率低下。数据驱动的软传感器可提供实时预测,但需要大量高质量的数据集,带来了实际挑战。为了解决这些局限性,本研究提出了一种混合软传感器模型,该模型整合了机理和数据驱动方法。机理模型通过 MATLAB® 生成计算数据,减少了对成本高昂的实验室实验的依赖。开发了一个综合数据集(n = 1500),其中包括七个输入变量--催化剂类型、原料类型、温度、反应时间、游离脂肪酸 (FFA) 含量、水含量和甲醇与油的比例,以及一个输出变量(生物柴油产量)。该数据集用于训练各种机器学习算法,其中人工神经网络 (ANN) 模型的预测精度最高,R2(拟合优度)为 0.998,均方根误差 (RMSE) 为 0.303。超参数调整进一步提高了模型的性能,将 RMSE 和平均绝对误差 (MAE) 分别降低了 63% 和 61.7%。通过结合机理和数据驱动技术,该混合模型有效克服了传统方法和纯数据驱动方法的局限性,为生物柴油产量预测和数据生成提供了一种经济高效的解决方案。
{"title":"A hybrid soft sensor framework for real-time biodiesel yield prediction: Integrating mechanistic models and machine learning algorithms","authors":"Mustafa Kamal Pasha ,&nbsp;Lingmei Dai ,&nbsp;Dehua Liu ,&nbsp;Wei Du ,&nbsp;Miao Guo","doi":"10.1016/j.renene.2024.121888","DOIUrl":"10.1016/j.renene.2024.121888","url":null,"abstract":"<div><div>Biodiesel yield prediction is vital for optimizing process efficiency, minimizing costs, and maintaining product quality. Traditional methods are labor-intensive, costly, and lack real-time capabilities, leading to inefficiencies in operations. Data-driven soft sensors offer real-time prediction but require extensive, high-quality datasets, posing practical challenges. To address these limitations, this study proposes a hybrid soft sensor model that integrates mechanistic and data-driven approaches. Mechanistic models were utilized to generate computational data via MATLAB®, reducing the reliance on costly laboratory experiments. A comprehensive dataset (n = 1500) comprising seven input variables—catalyst type, feedstock type, temperature, reaction time, free fatty acid (FFA) content, water content, and methanol-to-oil ratio—along with one output variable (biodiesel yield) was developed. This dataset was used to train various machine learning algorithms, with the artificial neural network (ANN) model demonstrating the highest predictive accuracy, achieving an R<sup>2</sup> (goodness of fit) of 0.998 and root mean square error (RMSE) of 0.303. Hyperparameter tuning further enhanced the model's performance, reducing RMSE and the mean absolute error (MAE) by 63 % and 61.7 %, respectively. By combining mechanistic and data-driven techniques, this hybrid model effectively overcomes the limitations of traditional and purely data-driven methods, providing a cost-effective and efficient solution for biodiesel yield prediction and data generation.</div></div>","PeriodicalId":419,"journal":{"name":"Renewable Energy","volume":"237 ","pages":"Article 121888"},"PeriodicalIF":9.0,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663239","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance of latent heat storage exchangers: Evaluation framework and fast prediction model 潜热储存交换器的性能:评估框架和快速预测模型
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-13 DOI: 10.1016/j.renene.2024.121896
Wei Su , Zhengtao Ai , Bin Yang
Given the lack of consensus on the selection and design of appropriate latent heat storage exchangers (LHSEs) for practical applications, this study presents a framework for evaluating the performance of various LHSEs and a novel prediction model without involving complex differential equation systems is proposed to quickly predict the performance of LHSEs. The prediction accuracy is guaranteed by comparing against the validated numerical simulations under different geometries, inlet heat transfer fluid (HTF) parameters, and PCM properties. The proposed model performs well in predicting the LHSE performance under different geometries, inlet HTF parameters, and PCM properties. The maximum prediction errors for the effective operating time and air outlet temperature are 0.9 h and 1.9 °C, respectively. It implies that the proposed model has the potential to predict the performance of the LHSE under various conditions. Due to ignoring the temperature gradient within the PCM containers and the sensible thermal energy storage of the PCM, the predicted average PCM temperature is slightly overestimated during the first half and underestimated during the second half of the melting process. This study is anticipated to provide a new solution for performance evaluation and fast prediction of LHSEs.
鉴于在为实际应用选择和设计合适的潜热蓄热式热交换器(LHSE)方面缺乏共识,本研究提出了一个评估各种 LHSE 性能的框架,并提出了一个不涉及复杂微分方程系统的新型预测模型,以快速预测 LHSE 的性能。通过与不同几何形状、入口导热流体 (HTF) 参数和 PCM 属性下的验证数值模拟进行比较,保证了预测的准确性。所提出的模型在预测不同几何形状、入口导热液体参数和 PCM 特性下的 LHSE 性能方面表现良好。有效运行时间和空气出口温度的最大预测误差分别为 0.9 h 和 1.9 °C。这意味着所提出的模型具有在各种条件下预测 LHSE 性能的潜力。由于忽略了 PCM 容器内的温度梯度和 PCM 的显热储能,预测的 PCM 平均温度在熔化过程的前半部分被略微高估,而在后半部分被低估。这项研究有望为 LHSE 的性能评估和快速预测提供新的解决方案。
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引用次数: 0
Spectral correction of photovoltaic module electrical properties 光伏组件电气性能的光谱校正
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-13 DOI: 10.1016/j.renene.2024.121907
Wenhu Sang , Yuxin Ma , Senyuan Li , Peng Xue , Bojia Li , Jinqing Peng , Man Fan
Except for irradiance and temperature, the distribution of solar spectrum also affects the electrical performance of photovoltaic (PV) modules. To explore the effect, this study conducted long-term experimental measurements on the wide range of full solar radiation spectrum with monocrystalline silicon (m-Si) and cadmium telluride (CdTe), and established new spectral correction function (SCF) under horizontal conditions based on the average photon energy (APE). It is verified with a good agreement R2 of 0.95, and the maximum RMSE is only 0.017 %. Moreover, the application of the SCFs to building vertical façade has also been well verified, and the accuracy of electrical performance prediction can be improved by 14.51 % (m-Si) and 3.57 % (CdTe). In addition, this study combines the annual horizontal total solar radiation spectrum in Beijing and gives the annual spectral gain and loss (SGL) ratio of two PV panels. The power generation performance of the two PV modules under the actual spectrum will be underestimated for about 53.5 % and 99.7 % of the time in the whole year. This study broadens the dimension of evaluating the electrical performance parameters of PV panels and provides a basis and guidance for the accurate prediction and calculation of photovoltaic power generation.
除辐照度和温度外,太阳光谱的分布也会影响光伏组件的电气性能。为了探究这一影响,本研究对单晶硅(m-Si)和碲化镉(CdTe)的全太阳辐射光谱范围进行了长期实验测量,并根据平均光子能量(APE)建立了水平条件下的新光谱校正函数(SCF)。经过验证,其 R2 为 0.95,具有良好的一致性,最大 RMSE 仅为 0.017%。此外,SCFs 在建筑垂直立面上的应用也得到了很好的验证,电性能预测的准确性提高了 14.51 %(间硅)和 3.57 %(碲化镉)。此外,本研究结合北京地区的年水平太阳辐射总谱,给出了两种光伏电池板的年光谱损益比。在实际光谱下,两种光伏组件全年约有 53.5% 和 99.7% 的时间发电性能会被低估。该研究拓宽了光伏电池板电气性能参数的评估维度,为准确预测和计算光伏发电量提供了依据和指导。
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引用次数: 0
Thermal performance of south-facing envelopes in solar enrichment zone of Qinghai–Tibet plateau: Field measurements of multiple dwellings in winter and transition seasons 青藏高原太阳能富集区朝南围护结构的热性能:在冬季和过渡季节对多个住宅进行实地测量
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-12 DOI: 10.1016/j.renene.2024.121869
Liu Yang , Yiyang Ye , Yuhao Qiao , Hengli Feng , Jingduo Wang , Mei Dou , Yanwen Wu , Qimeng Cao , Yan Liu
Utilizing solar energy is essential for achieving zero carbon emissions in buildings, especially in solar enrichment zone, such as the Qinghai-Tibet Plateau. Given a climate characterized by low temperatures and high solar radiation, the thermal performance of south-facing envelopes is crucial for the collection and utilization of solar radiation, necessitating detailed field investigations. This study conducted field measurements on three typical dwellings in Litang County and Ngari Prefecture during winter and transition seasons. Transparent envelopes had heat gains of 20.7 MJ⋅m-2 but lost 26.4 MJ⋅m-2, with indoor temperature fluctuation of 17.2 °C. Opaque envelopes gained 132.3 W⋅m-2 from solar radiation and lost 99.3 W⋅m-2 through convection, storing 2.5 MJ⋅m-2 with over 85 % lost to the outdoor environment. This research revealed the dynamic thermal characteristics of heat collection, storage, and insulation performance of south-facing envelopes in local climate, indicated that the existing thermal performance is not yet sufficient to cope with the low temperature and high radiation climate. This work can provide reference for the development of solar utilization envelopes for the Qinghai-Tibet Plateau.
利用太阳能对于实现建筑物零碳排放至关重要,尤其是在青藏高原等太阳能富集区。由于青藏高原的气候特点是低温和高太阳辐射,朝南围护结构的热性能对于太阳辐射的收集和利用至关重要,因此有必要进行详细的实地调查。本研究在冬季和过渡季节对理塘县和阿里地区的三栋典型住宅进行了实地测量。透明围护结构的得热量为 20.7 兆焦耳-米-2,失热量为 26.4 兆焦耳-米-2,室内温度波动为 17.2 °C。不透明围护结构从太阳辐射中获得 132.3 W-m-2,通过对流损失 99.3 W-m-2,储存 2.5 MJ-m-2,其中 85% 以上损失到室外环境中。这项研究揭示了当地气候条件下朝南围护结构的集热、蓄热和隔热性能的动态热特性,表明现有的热性能还不足以应对低温高辐射气候。这项工作可为青藏高原太阳能利用围护结构的发展提供参考。
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引用次数: 0
Non-noble Co supported on beta framework for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to renewable biofuel 2,5-dimethylfuran 贝塔框架上支持的非贵金属钴,用于将生物质衍生的 5-羟甲基糠醛氢解为可再生生物燃料 2,5-二甲基呋喃
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-12 DOI: 10.1016/j.renene.2024.121880
Zhongrui Wang, Yulin Ma, Lei Chen, Tingyu Yan, Ningzhao Shang, Huiliang Li, Yunan Han, Xue Liu
Selective transformation of biomass platform molecule 5-hydroxymethylfurfural (HMF) into biofuel 2,5-dimethylfuran (DMF) through hydrogenolysis path has attracted significant attention in the field of biomass catalytic conversion. In general, this process required supported noble catalysts under elevated temperature (423–533 K) and enough H2 pressure (1–4 MPa). Herein, Co/Beta-DA catalysts with various Co loadings of 5–20 wt% were post-synthesized through wet impregnation. Benefiting from the relatively open channel systems and strong metal-support interactions, the obtained 10Co/Beta-DA with ∼10 wt% Co contents facilitated the hydrogenation of C=O bonds and the cleavage of C-O bonds, which was efficient for the selective hydrogenolysis from HMF to DMF (Conv.HMF ≥ 99.9 %, Sel.DMF ≥ 99.9 %) under mild reaction conditions (H2 pressure, 1.0 MPa; temp., 423 K; time, 3 h). The innovative strategy of designing and preparing rational non-noble impregnated zeolite provided brand-new perspectives to solve the problems of high cost and harsh reaction conditions in the HMF hydrogenolysis process, which has the potential to convert biomass into renewable liquid fuels.
通过氢解途径将生物质平台分子 5-hydroxymethylfurfural (HMF) 选择性转化为生物燃料 2,5-二甲基呋喃 (DMF)在生物质催化转化领域备受关注。一般来说,这一过程需要在高温(423-533 K)和足够的氢气压力(1-4 MPa)条件下使用支撑惰性催化剂。在此,我们通过湿法浸渍后合成了 Co/Beta-DA 催化剂,其 Co 的负载量为 5-20 wt%。在温和的反应条件下(H2 压力,1.0 MPa;温度,423 K;时间,3 h),Co 含量为 10 wt%~10wt%的 Co/Beta-DA 催化剂可促进 C=O 键的氢化和 C-O 键的裂解,从而有效地实现从 HMF 到 DMF 的选择性氢解(Conv.HMF ≥ 99.9 %,Sel.DMF ≥ 99.9 %)。设计和制备合理的非贵金属浸渍沸石的创新策略为解决 HMF 加氢分解工艺中的高成本和苛刻反应条件问题提供了全新的视角,该工艺具有将生物质转化为可再生液体燃料的潜力。
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引用次数: 0
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