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Life-cycle optimal design and energy benefits of centralized cooling systems for data centers concerning progressive loading 渐进式负载数据中心集中冷却系统的生命周期优化设计和能源效益
IF 9 1区 工程技术 Q1 Energy Pub Date : 2024-06-19 DOI: 10.1016/j.renene.2024.120847
Yingbo Zhang , Hangxin Li , Shengwei Wang

Cooling of data centers requires a significant amount of energy, comparable to the energy consumption of the servers themselves. The current design of the centralized cooling systems for data centers is based on ideal IT loading conditions (i.e., 100 % loading). However, such conventional design often results in significant oversized cooling systems and leads to substantial energy waste, since most data centers operate at part load in their lifespan. To address this issue, this study proposes an optimal design for centralized cooling systems with multiple chillers under progressive loading. The optimization problem, aimed at minimizing life-cycle cost, is formulated adopting SLSQP (Sequential Least Squares Programming) algorithm. A cooling system model is developed using the manufacturer's performance data of cooling equipment. The optimal designs in different climate zones are identified according to energy performance under full-range loads and ambient temperatures. Furthermore, this study comprehensively analyzes and compares free cooling hours, cooling energy, and life-cycle cost of the optimized designs with conventional designs. The results show that the optimized cooling systems could operate more energy-efficiently, despite decreased free cooling hours (13–860). Significant cooling energy savings over the lifespan could be achieved, i.e., 4–22 %, corresponding to the PUE reductions of 0.02–0.11, depending on climate conditions and control strategies.

数据中心的冷却需要大量能源,相当于服务器本身的能耗。目前数据中心集中冷却系统的设计是基于理想的 IT 负载条件(即 100% 负载)。然而,这种传统设计往往会导致冷却系统严重过大,造成大量能源浪费,因为大多数数据中心在其生命周期内都是在部分负荷的情况下运行的。为解决这一问题,本研究提出了渐进加载情况下多个冷却器集中冷却系统的优化设计方案。采用 SLSQP(顺序最小二乘法编程)算法提出了旨在最大限度降低生命周期成本的优化问题。利用制造商提供的冷却设备性能数据,建立了冷却系统模型。根据全范围负荷和环境温度下的能源性能,确定了不同气候区的最佳设计。此外,本研究还全面分析和比较了优化设计与传统设计的免费冷却时间、冷却能量和生命周期成本。结果表明,尽管自由冷却时间减少(13-860 小时),但优化冷却系统的运行能效更高。根据气候条件和控制策略的不同,可在整个生命周期内节省大量冷却能源,即 4-22%,相当于 PUE 降低 0.02-0.11。
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引用次数: 0
Frequency optimisation and performance analysis of photovoltaic-battery water pumping system 光伏电池抽水系统的频率优化和性能分析
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-06-19 DOI: 10.1016/j.renene.2024.120844
Kaisheng Zhou , Xun Ma , Feng Gao , Jingying Yao , Xiaobo Kan

Photovoltaic-battery water pumping systems (PVBWPSs) can provide fresh water and irrigation in off-grid areas. Previous research has focused on direct current (DC) voltage versus frequency to control the speed of a pump. However, the use of photovoltaic (PV) modules with batteries to create a high-performance hybrid system with fixed and variable frequencies of supply power remains challenging, particularly in an off-grid water pumping system with limited power and water supplies. Based on a conventional frequency conversion mode and power balance, this work addresses fixed and variable frequencies under changing solar irradiance conditions for a PV system and a PV system combined with a battery (PVB) mode to improve energy utilisation. According to DC power balance and centrifugal pump theories, a mathematical model of the power supply frequency in the PVBWPS is presented, as well as the loss of load probability (LLP) and pumping coefficient (Cp), through which the performance metrics are obtained. The formulated models are validated through the experimental PVBWPS, which includes 2.19 kWp PV modules, a 9.6 kWh battery bank, and a 0.75 kW centrifugal pump. The experimental results show that the root mean square error (RMSE) and maximum relevant error (RE) of the frequency are 0.14 Hz and 0.74 %, respectively. Consequently, the output performances are revealed via software simulation. The calculated results indicate that the maximum pumping volume for fixed-power-frequency operation is 48 Hz, which is 27.56 m3 on a sunny day and 17.63 m3 on a cloudy day. On a rainy day, the maximum pumping volume is 3.27 m3 at 41 Hz. Similarly, the Cp values reach maxima of 2.51 m3/kWh and 2.11 m3/kWh at 48 Hz in both sunny weather and cloudy weather, respectively, while on rainy days, the Cp peaks at 0.77 m3/kWh at 41 Hz. Moreover, every 1 Hz increase in the fixed frequency mode leads to a rise in the LLP, while the minimum change is at 46–48 Hz for cloudy and rainy days. Furthermore, the simulations revealed that for variable frequency control, the volume of water pumped in the PVB mode reached 40.19 m3, 29.36 m3, and 15.11 m3, which are increased by 4.91 %, 21.83 % and 103.09 % compared with the variable frequency PV mode, and 45.83 %, 66.53 % and 362.08 % higher than in PV fixed frequency mode, respectively. Compared with the PV mode, the system weighted efficiency of the variable-frequency PVB mode is increased by 2.06 %, 4.98 %, and 8.36 % under three weather conditions. This work provides critical theoretical guidelines for the design and operation of high-performance PVBWPs.

光伏电池水泵系统(PVBWPS)可为离网地区提供淡水和灌溉。以往的研究主要集中在直流电压与频率的关系上,以控制水泵的速度。然而,利用光伏(PV)模块和电池来创建一个具有固定和可变频率供电的高性能混合系统仍然具有挑战性,特别是在电力和水供应有限的离网抽水系统中。在传统变频模式和功率平衡的基础上,本研究探讨了光伏系统和光伏系统与蓄电池(PVB)相结合模式在太阳辐照度变化条件下的固定频率和可变频率,以提高能量利用率。根据直流功率平衡和离心泵理论,提出了 PVBWPS 中供电频率的数学模型,以及负载损失概率 (LLP) 和泵送系数 (Cp),并通过该模型获得了性能指标。PVBWPS 包括 2.19 kWp 光伏模块、9.6 kWh 电池组和 0.75 kW 离心泵,实验验证了所建立的模型。实验结果表明,频率的均方根误差(RMSE)和最大相关误差(RE)分别为 0.14 Hz 和 0.74 %。因此,输出性能通过软件模拟得以揭示。计算结果表明,定功率频率运行的最大抽水量为 48 Hz,晴天为 27.56 立方米,阴天为 17.63 立方米。在雨天,最大抽水量为 3.27 立方米,频率为 41 赫兹。同样,在晴天和阴天,Cp 值在 48 赫兹时分别达到 2.51 立方米/千瓦时和 2.11 立方米/千瓦时的最大值,而在雨天,Cp 值在 41 赫兹时达到 0.77 立方米/千瓦时的峰值。此外,在固定频率模式下,每增加 1 赫兹就会导致 LLP 上升,而阴天和雨天的最小变化在 46-48 赫兹。此外,模拟结果显示,在变频控制下,PVB 模式的抽水量分别达到 40.19 立方米、29.36 立方米和 15.11 立方米,与变频光伏模式相比,分别增加了 4.91 %、21.83 % 和 103.09 %,与光伏定频模式相比,分别增加了 45.83 %、66.53 % 和 362.08 %。与光伏模式相比,变频 PVB 模式的系统加权效率在三种天气条件下分别提高了 2.06 %、4.98 % 和 8.36 %。这项研究为高性能 PVBWP 的设计和运行提供了重要的理论指导。
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引用次数: 0
Exploring optimal market operations and grid effects in an office building energy community: A case study 探索办公楼能源社区的最佳市场运作和电网效应:案例研究
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-06-19 DOI: 10.1016/j.renene.2024.120824
Juhani Lepistö , Jovana Forcan , Miodrag Forcan

In this paper, we study optimal market operations and grid effects of office building from an energy community perspective. Commercial buildings such as offices can include many stakeholders and new flexible assets that can offer suitable use cases to form energy communities or enter energy and reserve markets. The office building we focus in this study has a real-world counterpart with historical measurement data and involves three stakeholders and their assets. The stakeholders are the owner, the tenant, and the operator of flexible assets. These assets are the battery energy storage system (BESS) and the electric vehicles (EV) charging system (EVCS) that both can operate in response to energy price fluctuations and in a reserve market. Different cases are studied where either the owner or the tenant is paying the EV charging, and where the flexibility of the EV charging is either active or not. We show that, when the owner pays for the energy of the EVCS and the tenant is using it, there is a beneficial case to form a coalition between them and share the benefits. Operative cost-benefit calculations are conducted where the community benefits are shared according to the Shapley value and the power flows at the building’s connection point are simulated based on the market operations. The sensitivity of the flexibility and the maximum power of EVCS to the results are studied. Harnessing benefits from the markets shows significant effects on the power flows at the connection point.

本文从能源社区的角度研究了办公建筑的最佳市场运作和电网效应。办公楼等商业建筑可能包括许多利益相关者和新的灵活资产,这些资产可以为形成能源社区或进入能源和储备市场提供合适的用例。我们在本研究中重点关注的办公楼具有与现实世界相对应的历史测量数据,并涉及三个利益相关者及其资产。利益相关者包括业主、租户和灵活资产的运营商。这些资产是电池储能系统(BESS)和电动汽车(EV)充电系统(EVCS),它们都可以根据能源价格波动并在储备市场中运行。我们研究了由业主或租户支付电动汽车充电费用的不同情况,以及电动汽车充电是否具有灵活性的情况。我们发现,当业主为电动汽车充电系统的能源付费,而租户正在使用该系统时,他们之间可以结成联盟,共享利益。在根据 Shapley 值分享社区利益的情况下,我们进行了实际成本效益计算,并根据市场运作情况模拟了建筑物连接点的电力流。研究了 EVCS 的灵活性和最大功率对结果的敏感性。从市场中获益对连接点的电力流有显著影响。
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引用次数: 0
Accelerating optimal scheduling prediction in power system: A multi-faceted GAN-assisted prediction framework 加速电力系统的优化调度预测:多元 GAN 辅助预测框架
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-06-19 DOI: 10.1016/j.renene.2024.120830
Ali Peivand, Ehsan Azad Farsani, Hamid Reza Abdolmohammadi

This study introduces a comprehensive framework aimed at enhancing power system optimality through a two-stage optimization process and the development of a deep-based model for optimal scheduling prediction (OSP). Initially, a Bidirectional Long Short-term Memory (Bi-LSTM) architecture is employed to accurately forecast wind power in the first stage. Subsequently, a convolutional Generative Adversarial Network (GAN) model utilizes these predicted wind power values to generate synthetic scenarios. These scenarios, based on the preceding 10 days’ wind power predictions, serve as inputs for the subsequent power system optimization stage. To streamline computational efficiency, the power system optimization is conducted via a two-stage model. The outputs from this process, alongside other pertinent parameters, are utilized to train the proposed deep-based OSP model. The efficacy of the proposed model in rapidly and reliably predicting optimal scheduling is evaluated using the 118-bus power system. Results indicate that the innovative approach demonstrates exceptional speed and precision in determining optimal scheduling for the power system. Specifically, the proposed OSP model accurately forecasts optimal dispatch for ten days ahead in a mere 0.38 s, with an error rate below 0.001. Furthermore, the model exhibits a 92 % correlation in predicting optimal dispatched wind power. Sensitivity analysis highlights that optimizing the arrangement of the proposed deep-based model using an automatic hyperparameter optimization software framework (OPTUNA) can significantly enhance performance accuracy, potentially by up to 24 %.

本研究介绍了一个综合框架,旨在通过两阶段优化过程和开发基于深度的优化调度预测(OSP)模型来提高电力系统的优化性。首先,在第一阶段采用双向长短期记忆(Bi-LSTM)架构来准确预测风力发电量。随后,卷积生成对抗网络(GAN)模型利用这些预测的风力值生成合成场景。这些场景基于前 10 天的风力预测值,可作为后续电力系统优化阶段的输入。为了简化计算效率,电力系统的优化通过两阶段模型进行。这一过程的输出结果与其他相关参数一起,用于训练所提出的基于深度的 OSP 模型。利用 118 总线电力系统评估了所提模型在快速、可靠地预测优化调度方面的功效。结果表明,这种创新方法在确定电力系统最优调度方面表现出了卓越的速度和精度。具体而言,拟议的 OSP 模型仅用 0.38 秒就能准确预测未来十天的最佳调度,误差率低于 0.001。此外,该模型在预测最佳风电调度方面的相关性高达 92%。敏感性分析表明,使用自动超参数优化软件框架(OPTUNA)优化所提出的基于深度的模型的布置,可显著提高性能精度,最高可达 24%。
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引用次数: 0
Frequency, duration, severity of energy drought and its propagation in hydro-wind-photovoltaic complementary systems 能源干旱的频率、持续时间、严重程度及其在水力-风力-光伏互补系统中的传播
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-06-19 DOI: 10.1016/j.renene.2024.120845
Hongxuan Lei , Pan Liu , Qian Cheng , Huan Xu , Weibo Liu , Yalian Zheng , Xiangding Chen , Yong Zhou

Analyzing low-renewable-output events, termed “energy droughts” is crucial for renewable energy systems. However, due to the challenges in hydropower regulation and complex spatiotemporal correlations among resources, the assessment and contributions of various resources to energy droughts in hydro-wind-photovoltaic (PV) energy systems (HWPSs) remain unexplored. To address these issues, this study evaluated energy droughts and compound resource droughts rather than single-resource in HWPSs, exploring the propagation. Assessments of frequency, duration, and severity relied on weather-to-resource conversion models and total power obtained through complementary operation. Estimating propagation probability from resource to energy droughts was achieved via the C-vine copula, quantifying resource contributions to drought propagation. Results of a case study in the Yalong River Basin indicated that (1) short-lived compound resource droughts have been increasingly frequent recently, peaking during winter or summer. After incorporating hydro energy resources, the severity and annual average occurrence of compound droughts decreased (from 18.56 to 5.24 events/year). (2) Complementary operation effectively reduced the probability of drought propagation. (3) Hydro and PV energy resources were pivotal contributors to drought propagation, contributing 49.1 % and 40.1 % when representing 53.4 % and 22.5 % of the total system capacity, respectively. Therefore, the study offers valuable insights into energy drought warnings and risk mitigation.

分析被称为 "能源干旱 "的低可再生能源产出事件对可再生能源系统至关重要。然而,由于水电调节面临的挑战和资源之间复杂的时空相关性,各种资源对水力-风能-光伏(HWPS)能源系统(HWPSs)能源干旱的评估和贡献仍未得到探讨。为解决这些问题,本研究评估了 HWPS 中的能源干旱和复合资源干旱,而非单一资源,并探索了其传播途径。对频率、持续时间和严重程度的评估依赖于天气到资源的转换模型以及通过互补运行获得的总功率。通过 C-vine copula 来估算从资源干旱到能源干旱的传播概率,量化资源对干旱传播的贡献。雅砻江流域的案例研究结果表明:(1) 近期短时复合资源干旱日益频繁,在冬季或夏季达到峰值。纳入水能资源后,复合干旱的严重程度和年平均发生率均有所下降(从 18.56 次/年降至 5.24 次/年)。(2)互补运行有效降低了干旱传播的概率。(3) 水电和光伏能源在干旱传播中起着关键作用,分别占系统总容量的 53.4% 和 22.5%,而对干旱传播的贡献率分别为 49.1% 和 40.1%。因此,该研究为能源干旱预警和风险缓解提供了宝贵的见解。
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引用次数: 0
The utilization of ethanol for production of 1-butanol catalysed by Li–Al mixed metal oxides enhanced by Cu 锂-铝混合金属氧化物在 Cu 强化催化下利用乙醇生产 1-丁醇
IF 9 1区 工程技术 Q1 Energy Pub Date : 2024-06-18 DOI: 10.1016/j.renene.2024.120834
Karel Frolich , Jan Malina , Martin Hájek , Jaroslav Kocík

The selective catalytic conversion of bio-ethanol into valuable chemical compounds, particularly 1-butanol (i.e., Guerbet reaction), has gained significant attention due to its potential to replace fossil sources in the future. This work continues the search for a catalyst with high ethanol conversion and selectivity toward desired products. The novelty of the study lies in its use of copper-lithium-aluminum mixed metal oxides as heterogeneous catalysts. Li–Al oxides were prepared via urea precipitation, and copper was introduced in two ways: (i) during co-precipitation and (ii) post-synthetic impregnation. Gas-phase reaction in a fixed-bed reactor was realized at varying temperatures and pressures. The properties of the mixed metal oxides proved to be crucial, as a wide range of products was observed. Catalysts that shifted from acidic to basic properties, and those with different redox properties, significantly affected ethanol conversion and selectivity toward the desired higher alcohols. Compared to previously used magnesium-aluminum mixed metal oxides, a lower amount of copper was required to achieve similar or higher ethanol conversion (71 %) and butanol selectivity (30 %) at 300–350 °C and 10 MPa. Thus, lithium-aluminum mixed metal oxides showed the potential to surpass magnesium-aluminum mixed metal oxides with further study and adjustment of their properties.

生物乙醇选择性催化转化为有价值的化合物,尤其是 1-丁醇(即格贝特反应),因其在未来替代化石能源的潜力而备受关注。这项研究继续寻找一种具有高乙醇转化率和对所需产品选择性的催化剂。这项研究的新颖之处在于使用铜-锂-铝混合金属氧化物作为异相催化剂。锂铝氧化物通过尿素沉淀制备,铜通过两种方式引入:(i) 共沉淀和 (ii) 合成后浸渍。在不同温度和压力下,在固定床反应器中实现了气相反应。事实证明,混合金属氧化物的特性至关重要,因为可以观察到多种产品。催化剂从酸性转变为碱性,以及具有不同氧化还原特性,都会显著影响乙醇转化率和对所需高级醇的选择性。与之前使用的镁铝混合金属氧化物相比,在 300-350 °C 和 10 兆帕条件下,只需较低量的铜即可实现类似或更高的乙醇转化率(71%)和丁醇选择性(30%)。因此,锂铝混合金属氧化物显示出超越镁铝混合金属氧化物的潜力,只需进一步研究和调整其特性即可。
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引用次数: 0
Energy geo-structures: A review of their integration with other sources and its limitations 能源地质结构:审查其与其他资源的整合及其局限性
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-06-18 DOI: 10.1016/j.renene.2024.120835
Lazaros Aresti , Maria Romana Alvi , Francesco Cecinato , Tao Fan , Elzbieta Halaj , Zili Li , Olena Okhay , Soren Erbs Poulsen , Sonia Quiroga , Cristina Suarez , Anh Minh Tang , Rokas Valancius , Paul Christodoulides

Ground Source Heat Pumps, in the framework of Shallow Geothermal Energy Systems, outperform conventional Heating Ventilation and Air Conditioning systems, even the high efficiency Air Source Heat Pumps. At the same time, though, they require considerably higher installation costs. The utilization of dwellings' foundations as ground heat exchanger components has recently demonstrated the potential to generate significant cost reductions primarily attributed to the reduction in expenses associated with drilling and backfill material (grout). These elements are referred to in the literature as Thermo-Active Structures or Energy Geo-structures (EGs). The current study employs a ‘mixed studies’ review (i.e., literature review, critical review and state-of-the-art review) methodology to comprehensively examine and assess the compatibility and integration of different renewable energy sources and environmentally friendly technologies with foundation elements deployed as EGs. These mainly include heat pumps, district heating and cooling networks, solar-thermal systems, waste heat, biomass and other types such as urban structures. Emphasis has been given on the advancement on this area, with the current study identifying and addressing two primary categories. The first category involves the integration of EG elements with sources that are able to supply green electricity, referring to renewable energy electricity obtained from on-grid or off-grid integration. The second category, involves a direct or indirect integration with sources that provide heat, or vice versa. The technical and non-technical barriers of such integrations have been discussed in detail, with the technical challenges generally involving engineering design, and system optimization, whereas non-technical challenges encompassing the economic, social, and policy domains.

浅层地热能源系统框架内的地源热泵性能优于传统的供暖、通风和空调系统,甚至优于高效的空气源热泵。但与此同时,它们所需的安装成本也要高得多。最近,利用住宅地基作为地热交换器组件已证明有可能显著降低成本,这主要归功于钻孔和回填材料(灌浆)相关费用的减少。这些元件在文献中被称为热活性结构或能源地质结构(EGs)。本研究采用 "混合研究 "审查(即文献审查、批判性审查和最新审查)方法,全面审查和评估不同可再生能源和环保技术与作为 EGs 部署的地基元件的兼容性和集成性。这些技术主要包括热泵、区域供热和制冷网络、太阳热能系统、废热、生物质能和其他类型(如城市结构)。本研究重点关注这一领域的进展,并确定和探讨了两个主要类别。第一类是将环境能源元件与能够提供绿色电力的资源相整合,指的是通过并网或离网整合获得的可再生能源电力。第二类是直接或间接地与提供热能的能源相结合,反之亦然。已经详细讨论了这种整合的技术和非技术障碍,技术挑战一般涉及工程设计和系统优化,而非技术挑战则包括经济、社会和政策领域。
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引用次数: 0
E. Vagnoni et al.: The new role of sustainable hydropower in flexible energy systems and its technical evolution through innovation and digitalization E.瓦格诺尼等人:可持续水电在灵活能源系统中的新作用及其通过创新和数字化实现的技术演进
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-06-18 DOI: 10.1016/j.renene.2024.120832
Elena Vagnoni , Dogan Gezer , Ioannis Anagnostopoulos , Giovanna Cavazzini , Eduard Doujak , Marko Hočevar , Pavel Rudolf

Hydropower has played an important role in Europe in recent decades, offering a unique combination of safe, low-cost, and clean power generation. Today, it is still one of the largest renewable energy sources (RES), accounting for about 35 % of RES electricity generation. However, grid stability is threatened by the increasing amount of undispatchable RES. Flexibility and dynamics such as energy storage and rapid response are urgently needed to achieve EU policy goals. In such a context, hydropower can play a key role, not only as a provider of regulated renewable energy but also due to its ability to balance a renewable energy system in the short term and the medium/long term by pumped storage technology. All these aspects underline the new role of hydropower, which aims to strengthen grid stability and power supply resilience and to enable higher penetration of volatile RES. In this context, the aim of this paper is to demonstrate the role of hydropower at the European level as well as the needs and opportunities of modernization to fully exploit its potential. In particular, this study provides, the assessment of the today flexibility offered by hydropower to the power system at the European level by leveraging a database of information collected through the participants to the working groups of the COST Action Pen@Hydropower which includes stakeholders in the hydropower sector of 34 European countries. The study confirms the key role of hydropower in future energy scenarios with 30 % of the flexibility demand at all time scales met by hydropower. Furthermore, the paper presents a review of the digitalization solutions and innovative technologies that support the growth of a new generation of sustainable hydropower together with the modernization opportunities for existing hydropower plants. The results of this work have practical implications for stakeholders in the hydropower sector and policymakers as it provides evidence at the European scale of the role of hydropower technology in balancing the power system and the need to have supportive frameworks and adequate markets to fully exploit the European hydropower potential to achieve the energy transition goals.

近几十年来,水力发电在欧洲发挥了重要作用,提供了安全、低成本和清洁发电的独特组合。如今,水电仍是最大的可再生能源之一,约占可再生能源发电量的 35%。然而,电网的稳定性正受到越来越多不可调度可再生能源的威胁。为实现欧盟的政策目标,迫切需要储能和快速反应等灵活性和动力。在这种情况下,水力发电可以发挥关键作用,不仅可以提供可调节的可再生能源,还可以通过抽水蓄能技术在短期和中长期内平衡可再生能源系统。所有这些方面都凸显了水电的新作用,其目的是加强电网的稳定性和电力供应的恢复能力,并提高波动性可再生能源的渗透率。在此背景下,本文旨在展示水电在欧洲层面的作用,以及充分挖掘其潜力的现代化需求和机遇。特别是,本研究通过利用从 COST 行动 Pen@Hydropower 工作组参与者(包括 34 个欧洲国家水电行业的利益相关者)处收集的信息数据库,对水电在欧洲层面为电力系统提供的灵活性进行了评估。该研究证实了水电在未来能源方案中的关键作用,在所有时间尺度上,水电可满足 30% 的灵活性需求。此外,论文还回顾了支持新一代可持续水电发展的数字化解决方案和创新技术,以及现有水电站的现代化机遇。这项工作的成果对水电行业的利益相关者和政策制定者具有实际意义,因为它在欧洲范围内证明了水电技术在平衡电力系统中的作用,以及需要支持性框架和充足的市场来充分利用欧洲的水电潜力,以实现能源转型目标。
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引用次数: 0
Hydrogen evolution via photocatalytic reforming of biomass with palladium nanoparticles decorated g-C3N4 nanosheets 用钯纳米颗粒装饰 g-C3N4 纳米片通过光催化转化生物质产生氢气
IF 8.7 1区 工程技术 Q1 Energy Pub Date : 2024-06-17 DOI: 10.1016/j.renene.2024.120811
Chinnu R Thara , Priyanka S. Walko , Beena Mathew

Fossil fuel depletion and environmental toxins have made photocatalytic H2 production of paramount significance. A novel and unique technique for producing sustainable H2 and valorizing biomass using infinite solar energy is biomass photoreformation. Nevertheless, this environmentally friendly method is usually linked to severe reaction circumstances, insufficient selectivity, and restricted biomass conversion. Here, we present a novel one-pot photoreformation technique over porous g-C3N4 nanosheets surface-modified with Pd nanoparticles to convert d-glucose to H2. By stacking the g-C3N4 photocatalyst into a 2D nanosheet structure, some of its inherent drawbacks can be mitigated. Furthermore, the inclusion of noble metal nanoparticles in these g-C3N4 nanosheet structures could significantly boost existing photocatalytic activity. The majority of solar radiation is composed of visible light, which makes up 45% of it, and ultraviolet light, which makes up 5%. Therefore, our focus has been on utilizing abundant visible light to facilitate biomass reformation. After 4 h of continuous irradiation, our composite photocatalyst exhibited exceptional visible light activity; its H2 evolution was 1839.84 μmolg−1h−1, or about 27 times higher than that of undoped g-C3N4 nanosheets. The effectiveness of three different Pd loadings on g-C3N4 nanosheets for glucose reforming was examined. In the quest for an improved H2 evolution visible light active photocatalyst, g-C3N4 nanosheets made at various pyrolysis temperatures loaded with optimized Pd weight percentage were also examined.

化石燃料枯竭和环境毒素使光催化制取 H2 变得至关重要。利用无限的太阳能生产可持续的 H2 并使生物质增值的一种新颖独特的技术是生物质光转化。然而,这种环境友好型方法通常存在反应环境恶劣、选择性不足和生物质转化受限等问题。在这里,我们提出了一种新颖的一锅式光转化技术,利用多孔 g-C3N4 纳米片表面修饰的钯纳米粒子将 d-葡萄糖转化为 H2。通过将 g-C3N4 光催化剂堆叠成二维纳米片结构,可以减轻其固有的一些缺点。此外,在这些 g-C3N4 纳米片结构中加入贵金属纳米颗粒还能显著提高现有的光催化活性。大部分太阳辐射由可见光和紫外线组成,其中可见光占 45%,紫外线占 5%。因此,我们的重点是利用丰富的可见光促进生物质转化。在连续辐照 4 小时后,我们的复合光催化剂表现出优异的可见光活性;其 H2 演化为 1839.84 μmolg-1h-1,是未掺杂 g-C3N4 纳米片的 27 倍。研究还考察了 g-C3N4 纳米片上三种不同钯负载对葡萄糖重整的有效性。为了寻求一种更好的 H2 演化可见光活性光催化剂,研究人员还考察了在不同热解温度下制备的 g-C3N4 纳米片,并优化了钯的重量百分比。
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引用次数: 0
Effects of biochars derived from different feedstocks and pyrolysis temperatures on the anaerobic digestion of kitchen waste 不同原料和热解温度产生的生物炭对厨余厌氧发醇的影响
IF 8.7 1区 工程技术 Q1 Energy Pub Date : 2024-06-17 DOI: 10.1016/j.renene.2024.120833
Zi-Fan Wu , Zhao-Kai Wang , Jia-Bing Li , Yu-Hong Qiu , Zu-Liang Chen , Gary Owens , Zhi-Man Yang

The aim of this work was to investigate the effects of biochars derived from different feedstocks and pyrolysis temperatures on the anaerobic digestion (AD) of kitchen waste (KW). Nine biomass feedstocks (corn straw (CS), Dicranopteris dichotoma (DD), bamboo (B), KW, tea residues (TR), mushroom cultivation waste (MW), cassava lees (CL), Chlorella (C), and sargassum (S)) were pyrolyzed at different temperatures (300 °C, 500 °C, and 800 °C). Biochar varied in physicochemical properties (e.g., specific surface area, total pore volume, and organic functional group) depending on both feedstock type and pyrolysis temperature. This further impacted the enrichment of functional microbial consortia and development of methanogenic pathways, resulting in a varied AD performance. The addition of biochars generated respectively from CS, MW, and S at 800 °C, 300 °C, and 500 °C significantly improved the maximum methane production rate (Rm) and methane yield, while other biochars enhanced either Rm or methane yield. Therefore, the efficacy of biochar on methanogenesis associated with both the feedstock type and pyrolysis temperature. The findings offer a beneficial reference for the selection and application of biochar to improve the AD performance.

这项工作的目的是研究从不同原料和热解温度中提取的生物炭对餐厨垃圾(KW)厌氧消化(AD)的影响。在不同温度(300 °C、500 °C和800 °C)下热解了九种生物质原料(玉米秸秆(CS)、二瓣竹(DD)、竹子(B)、KW、茶叶渣(TR)、蘑菇栽培废料(MW)、木薯糟(CL)、小球藻(C)和马尾藻(S))。生物炭的理化性质(如比表面积、总孔隙度和有机功能基团)因原料类型和热解温度而异。这进一步影响了功能微生物群的富集和甲烷生成途径的发展,从而导致厌氧消化(AD)性能的变化。加入分别由 CS、MW 和 S 在 800 ℃、300 ℃ 和 500 ℃ 高温下产生的生物炭,可显著提高最大甲烷产生率(Rm)和甲烷产量,而其他生物炭则会提高 Rm 或甲烷产量。因此,生物炭对甲烷生成的影响与原料类型和热解温度有关。这些发现为选择和应用生物炭以提高厌氧消化(AD)性能提供了有益的参考。
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Renewable Energy
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