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Integrating geothermal energy and a solar chimney to maximize renewable energy production: An analytical investigation of a novel hybrid system 整合地热能源和太阳能烟囱,实现可再生能源生产的最大化:新型混合系统的分析研究
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-06-17 DOI: 10.1016/j.renene.2024.120827
Mohammad Hossein Haji Molla Ali Tork, Ehsan Houshfar, Mehdi Ashjaee

Hybrid renewable energy systems, which utilize multiple renewable sources, are becoming increasingly popular due to the need for sustainable energy. In this study, a new hybrid power plant that combines a solar chimney power plant with geothermal energy is investigated. The new system that can be activated when solar radiation is inadequate is called “geothermal pipe” and can produce up to 71 kW of electricity using a 1000-m-deep well. A geothermal pipe power plant was designed to be integrated with a system similar to the Manzanares solar chimney with a well depth of 200 m, generating an average of 15 kW of power. By increasing the distance between wells to 1.5 km, the output power can reach 20 kW. The study analyzed the impact of different parameters, such as well array, size, and temperature, on the output power. The results indicate that a new type of geothermal pipe with six inlets has the potential to increase the performance of the conventional geothermal pipe (with one well) by 26 %. This hybrid renewable energy system benefits from the combination of more than one renewable source, allowing for year-round energy production despite weather conditions.

由于对可持续能源的需求,利用多种可再生能源的混合可再生能源系统越来越受欢迎。本研究调查了一种新型混合发电厂,它将太阳能烟囱发电厂与地热能结合在一起。这种可在太阳能辐射不足时启动的新系统被称为 "地热管道",利用一口 1000 米深的井可产生高达 71 千瓦的电力。地热管道发电厂的设计与曼萨纳雷斯太阳能烟囱的系统相类似,井深 200 米,平均发电量 15 千瓦。将井距增加到 1.5 千米后,输出功率可达到 20 千瓦。研究分析了不同参数(如井阵、大小和温度)对输出功率的影响。结果表明,有六个入口的新型地热管道有可能将传统地热管道(有一口井)的性能提高 26%。这种混合可再生能源系统得益于多种可再生能源的结合,可以全年生产能源,不受天气条件的影响。
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引用次数: 0
Honeycomb-shaped artificial roughness in solar air heaters: CFD-experimental insights into thermo-hydraulic performance 太阳能空气加热器中的蜂窝状人工粗糙度:热-水性能的 CFD 实验启示
IF 9 1区 工程技术 Q1 Energy Pub Date : 2024-06-16 DOI: 10.1016/j.renene.2024.120829
Somar Rajeh Ghanem, Amit C. Bhosale

This research paper presents numerical and experimental investigations to examine the effectiveness of a honeycomb pattern as a form of the geometry of artificial roughness in solar air heaters. Utilizing Computational Fluid Dynamics (CFD) through three-dimensional simulations, the study explores how Thermo-Hydraulic Performance Parameter (THPP) is affected by variations in honeycomb geometry. The research examines various parameters, including the angle of attack (Ø), relative roughness pitch (P/e), and relative roughness height (e/D) within the respective ranges of (90°-120°), (8–12), and (0.03–0.05). The system's performance is evaluated across various flow scenarios, covering Reynolds numbers from (3000) to (21,000). Incorporating the honeycomb design into an absorber is observed to improve the heat transfer rates. The system achieves a maximum Nu of (140.65) at (e/D) of 0.04, (P/e) of 10, (Ø) of 120°, and Re of (21,000). The maximum FF of (0.039) was obtained at (e/D) of 0.05, (P/e) of 9, and (Ø) of 120° at a Reynolds number of (6000). The system exhibited a THPP of (1.7) at a Reynolds number of (6000). This Maximum THPP was associated with specific parameters, including (e/D) of 0.04, (P/e) of 10, and (Ø) of 120°.

本研究论文通过数值和实验研究,探讨了蜂巢图案作为太阳能空气加热器中人工粗糙度几何形状的一种形式的有效性。该研究利用计算流体动力学(CFD)进行三维模拟,探讨蜂窝几何形状的变化如何影响热-水性能参数(THPP)。研究考察了各种参数,包括攻角 (Ø)、相对粗糙度间距 (P/e) 和相对粗糙度高度 (e/D),其范围分别为 (90°-120°)、(8-12) 和 (0.03-0.05)。在雷诺数为(3000)到(21000)的各种流动情况下,对系统的性能进行了评估。据观察,将蜂窝设计融入吸收器可提高传热率。在 (e/D) 为 0.04、(P/e) 为 10、(Ø) 为 120°、雷诺数为 (21,000) 时,该系统的最大 Nu 值为 (140.65)。当 (e/D) 为 0.05、(P/e) 为 9、(Ø) 为 120°、雷诺数为 6000 时,FF 最大值为 (0.039)。在雷诺数为(6000)时,系统的 THPP 为(1.7)。该最大 THPP 与特定参数有关,包括 (e/D) 0.04、(P/e) 10 和 (Ø) 120°。
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引用次数: 0
Comparison of non-isothermal and isothermal cycles in a novel methane-assisted two-step thermochemical process 新型甲烷辅助两步热化学工艺中的非等温循环与等温循环的比较
IF 9 1区 工程技术 Q1 Energy Pub Date : 2024-06-15 DOI: 10.1016/j.renene.2024.120817
Hao Zhang , Xiaomi Zhang , Dazhi Yang , Bai Liu , Yong Shuai , Bachirou Guene Lougou , Qian Zhou , Xing Huang , Fuqiang Wang

As driven by thermodynamics and reaction kinetics considerations, conventional two-step solar thermochemical processes typically rely on non-isothermal cycling conditions to effectively couple the endothermic reduction and exothermic oxidation reactions. Nevertheless, recent discussions on isothermal cycles based on thermodynamics simulation and material characterization have sparked dissenting opinions, as certain reaction processes operating under isothermal cycling conditions have demonstrated the possibility of achieving higher energy conversion efficiency. To delve further into such phenomenon and potentially unveil the underlying scientific principles, this study conducts a reaction kinetic analysis and lab-scale systematic experiments on a novel methane-assisted two-step thermochemical process using iron-based oxygen carriers. Despite the fact that the reaction kinetics analysis of iron oxides indicates that isothermal cycles at reaction temperatures of 573–1173 K do not provide significant advantages in terms of energy conversion efficiency, surprisingly, the experiments conducted with the prepared cobalt–nickel ferrite materials conclude oppositely. More specifically, the observed increase in material reactivity with rising oxidation temperature contributes to an approximately two-fold enhancement in the CO yield under isothermal conditions, as well as a noteworthy improvement of about 15% in solar-to-fuel efficiency. This energy efficiency improvement could be attributed, at least in part, to the stable reaction temperature during isothermal cycling, which effectively mitigates the challenges associated with solid-phase sensible heat recovery caused by significant temperature fluctuations, particularly when operating at high feed flow rates. Accordingly, the applicability of isothermal cycles is linked to two crucial factors: the reactivity of the oxygen carrier and the specific operating conditions employed. The experiments herein conducted showed that the catalytic activity of the material reached a relatively stable state after 24 h of reaction, resulting in a peak CO yield of 20.5 mL min1 g−1 and a CO2 conversion exceeding 90%. Thorough analyses reveal several optimization measures for enhancing efficiency under the setting of the reaction system.

出于热力学和反应动力学的考虑,传统的两步太阳能热化学过程通常依赖于非等温循环条件,以有效地将内热还原反应和放热氧化反应结合起来。然而,最近基于热力学模拟和材料表征对等温循环的讨论引发了不同意见,因为某些在等温循环条件下运行的反应过程已证明有可能实现更高的能量转换效率。为了进一步深入研究这种现象并揭示其潜在的科学原理,本研究对使用铁基氧载体的新型甲烷辅助两步热化学过程进行了反应动力学分析和实验室规模的系统实验。尽管铁氧化物的反应动力学分析表明,反应温度为 573-1173 K 的等温循环在能量转换效率方面并不具有显著优势,但令人惊讶的是,用制备的钴镍铁氧体材料进行的实验却得出了相反的结论。更具体地说,随着氧化温度的升高,观察到的材料反应性的增加使等温条件下的一氧化碳产量提高了约两倍,太阳能转化为燃料的效率也显著提高了约 15%。能效的提高至少部分归功于等温循环过程中稳定的反应温度,这有效缓解了固相显热回收因温度大幅波动而带来的挑战,尤其是在高进料流速下运行时。因此,等温循环的适用性与两个关键因素有关:氧载体的反应性和采用的特定操作条件。实验表明,该材料的催化活性在反应 24 小时后达到了相对稳定的状态,一氧化碳产量峰值为 20.5 mL min-1 g-1,二氧化碳转化率超过 90%。通过深入分析,我们发现了几种在反应系统设置下提高效率的优化措施。
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引用次数: 0
A hybrid numerical model for horizontal ground heat exchanger 水平地面热交换器的混合数值模型
IF 9 1区 工程技术 Q1 Energy Pub Date : 2024-06-15 DOI: 10.1016/j.renene.2024.120825
Cang Tong , Xiangli Li , Hengjin Ju , Lin Duanmu , Caifeng Huang

The horizontal ground heat exchanger (HGHE) possesses a complicated heat transfer mechanism as its extensive spatial scale, long operational duration, and vulnerability to meteorological conditions. Consequently, the long-period simulations of HGHE usually involve significant computational costs, posing challenges for its dynamic optimization implementation. Therefore, this study initially established and validated a conventional numerical (full-order) model for HGHE as the reference model. Subsequently, a hybrid model was developed using the proposed adaptive proper orthogonal decomposition (POD) method. By analyzing the influential characteristics, the study identified the solution strategy and the key parameter values for adaptive POD, followed by the generality tests. The hybrid model proved to successfully mitigate the issue of error accumulation commonly associated with native POD extrapolation. Finally, employing a long-running engineering case study, the accuracy and the solution efficiency of the hybrid model were compared against those of the conventional (full-order) model. The results demonstrated that the hybrid model maintained computational accuracy at a comparable level while exhibiting a computational efficiency 326 % higher than that of the conventional (full-order) model, without requiring additional computational resources. This study can provide efficient modeling support for the dynamic optimization design of HGHE.

水平地面热交换器(HGHE)空间尺度大,运行时间长,易受气象条件影响,传热机制复杂。因此,对 HGHE 进行长周期模拟通常需要耗费大量计算成本,为其动态优化实施带来了挑战。因此,本研究首先建立并验证了 HGHE 的常规数值(全阶)模型作为参考模型。随后,利用提出的自适应适当正交分解(POD)方法开发了混合模型。通过分析影响特征,研究确定了自适应 POD 的求解策略和关键参数值,随后进行了通用性测试。事实证明,该混合模型成功地缓解了原生 POD 外推法常见的误差累积问题。最后,通过一项长期工程案例研究,将混合模型的精度和求解效率与传统(全阶)模型进行了比较。结果表明,混合模型的计算精度与传统(全阶)模型相当,而计算效率却比传统(全阶)模型高出 326%,而且不需要额外的计算资源。这项研究可为 HGHE 的动态优化设计提供高效的建模支持。
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引用次数: 0
Approaches to improve the accuracy of estimating the diffuse fraction of 1-min resolution global horizontal irradiance using cloud images 利用云图提高 1 分钟分辨率全球水平辐照度漫射部分估算精度的方法
IF 8.7 1区 工程技术 Q1 Energy Pub Date : 2024-06-15 DOI: 10.1016/j.renene.2024.120828
Jie Fan , Lei Wang , Zhen Zhang , Ming Liu , Xinyue Cao , Min Gong , Qiuping Tang , Chao She , Fang Qi , Hucheng Si , Dan Song , Qiyuan Zhang , Peng Xie

Obtaining high-precision diffuse irradiance from global horizontal irradiance (GHI) can serve comprehensive and effective data for PV system design, operation and maintenance. This study has incorporated cloud features in an artificial neural network (ANN) model to improve the estimation accuracy of diffuse fraction on 1-min resolution dataset. The cloud features are extracted from ground-based cloud images, including spectrum features, texture features and cloud cover ratio, with image processing algorithms. After data validation, the ANN model which incorporated all the cloud features has achieved a normalized root mean square error (NRMSE) of 17.1 %, representing a 13 % reduction compared to the basic ANN model, we have investigated additional strategies that further optimize the model performance, including cloud classification, weather classification and data averaging, and quantified the effects of the proposed approaches based on actual station data. The data averaging based on proper time scale has brought about 2 % in accuracy improvement; the weather classification and cloud classification have both brought above 10 % of accuracy improvement in some cases but others may deteriorate for some reasons that need to be further investigated, based on this, we have analyzed and summarized the deficiencies in our research and proposed detailed research directions for future endeavors.

从全球水平辐照度(GHI)中获取高精度漫射辐照度可为光伏系统的设计、运行和维护提供全面有效的数据。本研究在人工神经网络(ANN)模型中加入了云特征,以提高 1 分钟分辨率数据集上漫射分量的估算精度。云特征是利用图像处理算法从地面云图像中提取的,包括光谱特征、纹理特征和云覆盖率。经过数据验证,包含所有云特征的 ANN 模型的归一化均方根误差(NRMSE)为 17.1%,与基本 ANN 模型相比降低了 13%。基于适当时间尺度的数据平均提高了约 2% 的精度;天气分类和云分类在某些情况下都提高了 10% 以上的精度,但其他情况下可能会由于某些原因而恶化,这需要进一步研究。
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引用次数: 0
Hierarchical control for collaborative electric vehicle charging to alleviate network congestion and enhance EV hosting in constrained distribution networks 分级控制电动汽车协同充电,缓解网络拥堵并提高受限配电网络中的电动汽车托管能力
IF 9 1区 工程技术 Q1 Energy Pub Date : 2024-06-15 DOI: 10.1016/j.renene.2024.120823
Amaia González-Garrido , Mikel González-Pérez , Francisco Javier Asensio , Andrés Felipe Cortes-Borray , Maider Santos-Mugica , Ibon Vicente-Figueirido

This paper introduces a novel hierarchical architecture aimed at enhancing coordination between distribution system operators and electric vehicle aggregators in order to minimize Electric Vehicle (EV) charging costs for users while optimizing EV hosting capacity to alleviate network congestion. Real-world distribution networks are employed to evaluate EV charging strategies and their impact on medium and low-voltage networks. Two distinct EV charging optimization strategies are proposed to ensure fair power allocation among EV Aggregators (EVAs), alleviating congestion while managing EV charging power efficiently. Results demonstrate that the proposed collaborative EV charging effectively flattens the load curve, reducing peak power and avoiding grid congestion. The main findings underscore the importance of incentivizing EV flexibility to support Distribution System Operator (DSO) objectives beyond static tariffs. Furthermore, a battery degradation model is introduced into the optimization problem, reducing high currents and capacity decay. Despite capturing a higher mean electricity price, the total cost of EV charging is reduced.

本文介绍了一种新颖的分层架构,旨在加强配电系统运营商与电动汽车聚合商之间的协调,以最大限度地降低用户的电动汽车(EV)充电成本,同时优化电动汽车托管容量,缓解网络拥塞。我们采用真实世界的配电网络来评估电动汽车充电策略及其对中低压网络的影响。提出了两种不同的电动汽车充电优化策略,以确保在电动汽车聚合器(EVA)之间公平分配电力,在有效管理电动汽车充电功率的同时缓解拥堵。结果表明,所提出的电动汽车协同充电能有效平滑负载曲线,降低峰值功率,避免电网拥塞。主要发现强调了激励电动汽车灵活性的重要性,以支持配电系统运营商(DSO)超越静态电价的目标。此外,在优化问题中引入了电池退化模型,减少了高电流和容量衰减。尽管平均电价较高,但电动汽车充电的总成本却降低了。
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引用次数: 0
Performance and economic analyses of a geothermal reservoir model coupled with a flash–binary cycle model 地热储层模型与闪光二元循环模型的性能和经济分析
IF 9 1区 工程技术 Q1 Energy Pub Date : 2024-06-15 DOI: 10.1016/j.renene.2024.120826
Jui-Ching Hsieh , Bo-Han Li , Bo-Heng Lee , Muhamad Aditya Royandi , Nadya Sefira Salsabilla

A reservoir model was coupled with a flash–binary cycle model to investigate the performance and economics of a geothermal system. The production temperature Tpro of the reservoir decreased with an increase in the operation time, which affected the net output power of the system; thus, a method for calculating the electricity production cost (EPCM) and payback period (PBPM) was developed. The net output power decreased with an increase in the operation time because of the effect of Tpro. This decrease resulted from the combined effect of a considerable decline and marginal increase in the net output power of a single-flash cycle (decline of 1278.86 kW) and an organic Rankine cycle (increase of 68.6 kW), respectively, with an increase in the operation time. For high flash pressure, the decreases in the output power, firs- and second-law efficiencies of the system (Wtot,net, ηtot,I, and ηtot,II, respectively) from the 1st to the 30th year of operation were 52.08 %, 34.53 %, and 24.53 %, respectively, with the percentage decrease in Wtot,net being greater than those in ηtot,I and ηtot,II. The system with a flash pressure of 800 kPa was discovered to achieve the best EPCM and PBPM values of 0.129 USD/kWh and 12.503 years, respectively.

为研究地热系统的性能和经济性,将储层模型与闪蒸二元循环模型相结合。储层的生产温度 Tpro 随运行时间的增加而降低,这影响了系统的净输出功率;因此,开发了一种计算发电成本 (EPCM) 和投资回收期 (PBPM) 的方法。由于 Tpro 的影响,净输出功率随着运行时间的增加而降低。随着运行时间的增加,单闪蒸循环(下降 1278.86 千瓦)和有机朗肯循环(增加 68.6 千瓦)的净输出功率分别大幅下降和略有增加,这是两者共同作用的结果。在高闪蒸压力下,系统的输出功率、枞树效率和第二定律效率(Wtot,net、ηtot,I 和 ηtot,II)从运行第 1 年到第 30 年的降幅分别为 52.08%、34.53% 和 24.53%,其中 Wtot,net 的降幅大于 ηtot,I 和 ηtot,II。闪蒸压力为 800 kPa 的系统实现了最佳 EPCM 和 PBPM 值,分别为 0.129 美元/kWh 和 12.503 年。
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引用次数: 0
An improved prediction model for in-stream water wheel performance 改进的内流水车性能预测模型
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-06-14 DOI: 10.1016/j.renene.2024.120803
Matthew Brandon-Toole, Cristian Birzer, Richard Kelso

As global efforts to decarbonise industries continue, there is increasing pressure to identify and proliferate sustainable methods of generating electricity, in-line with the United Nations’ Sustainable Development Goal 7. The in-stream water wheel is a pico-hydropower technology that generates electricity using only the kinetic energy in the fluid, rather than both potential and kinetic, like most forms of pico-hydropower. Current methods of estimating the power output of these turbines lack validation, robustness and proper justification for their assumptions. This study has developed a new method for predicting the power output of in-stream water wheels, based on fluid dynamics principles, and has been compared with a range of experimental results to confirm its robustness. The new model identifies novel characteristics of the power stroke of the turbine blade, including unsteady effects and negative torque production at certain blade angles. In addition, the model can be tuned to match experimental data, improving its accuracy in specific applications. The better prediction of power output aims to encourage the use of in-stream water wheels as part of the global decarbonisation strategy.

随着全球继续努力实现工业去碳化,根据联合国可持续发展目标 7,寻找和推广可持续发电方法的压力越来越大。内流水轮是一种微型水力发电技术,它只利用流体中的动能发电,而不是像大多数微型水力发电形式那样同时利用势能和动能发电。目前估算这些水轮机输出功率的方法缺乏验证、稳健性和适当的假设理由。本研究基于流体动力学原理,开发了一种预测内流水轮输出功率的新方法,并与一系列实验结果进行了比较,以确认其稳健性。新模型确定了水轮机叶片功率冲程的新特征,包括不稳定效应和叶片特定角度下产生的负扭矩。此外,该模型可根据实验数据进行调整,从而提高其在特定应用中的准确性。更好地预测功率输出旨在鼓励使用内流水轮机,作为全球去碳化战略的一部分。
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引用次数: 0
A multi-generation system with integrated solar energy, combining energy storage, cooling, heat, and hydrogen production functionalities: Mathematical model and thermo-economic analysis 集太阳能、储能、制冷、制热和制氢功能于一体的多能源系统:数学模型和热经济分析
IF 8.7 1区 工程技术 Q1 Energy Pub Date : 2024-06-14 DOI: 10.1016/j.renene.2024.120812
Penglai Wang , Qibin Li , Shukun Wang , Bo Hui

Increasing the proportion of renewable energy is of paramount importance for all countries in the world. In this work, a novel multi-generation system is designed to fully utilize solar energy, which includes a photovoltaic/thermal subsystem (PV/T), an absorption refrigeration cycle (ARC), a proton-exchange membrane (PEM) electrolysis, and a promising pumped thermal electricity storage (PTES) energy storage subsystem, which can simultaneously achieve the purposes of refrigeration, hydrogen production, heat production, and energy storage. Meanwhile, the solar radiation data of Wuwei City, Gansu Province, China for the year 2022 are selected for the study. According to different seasons, the thermodynamic and thermo-economic performances of the combined power, heat and hydrogen production (CPHH) mode operated in spring, autumn, winter, and the combined power, cooling and hydrogen production (CPCH) mode operated in summer are investigated, and multi-objective optimization is conducted. The results indicate that the direct normal irradiance (DNI) of solar, the area of PV/T, the thermal storage temperature of the PTES subsystem, and the pinch point temperature difference significantly affect the total energy efficiency, total exergy efficiency, and total product unit cost of the system. The multi-objective optimization results show that the optimal solutions of total energy efficiency and total product unit cost of the system are 85.90 %, 24.25 $·GJ−1 and 86.97 %, 24.25 $·GJ−1 for the CPHH mode in spring and winter, respectively, and 88.26 % and 22.21 $·GJ−1 for the CPCH mode in summer. This work can provide a valuable reference for the research of multi-generation systems with integrated renewable energy sources.

提高可再生能源的比例对世界各国都至关重要。本研究设计了一种充分利用太阳能的新型多联产系统,包括光伏/热子系统(PV/T)、吸收式制冷循环系统(ARC)、质子交换膜电解系统(PEM)和前景广阔的抽水蓄热储能子系统(PTES),可同时实现制冷、制氢、制热和储能的目的。同时,研究选取了中国甘肃省武威市 2022 年的太阳辐射数据。根据不同季节,分别研究了春季、秋季、冬季运行的电热制氢(CPHH)联合模式和夏季运行的电冷制氢(CPCH)联合模式的热力学性能和热经济性,并进行了多目标优化。结果表明,太阳能直接法线辐照度(DNI)、PV/T 的面积、PTES 子系统的蓄热温度和夹点温差对系统的总能效、总放能效率和总产品单位成本有显著影响。多目标优化结果表明,在春季和冬季 CPHH 模式下,系统总能效和总产品单位成本的最优解分别为 85.90 %、24.25 美元-GJ-1 和 86.97 %、24.25 美元-GJ-1;在夏季 CPCH 模式下,系统总能效和总产品单位成本的最优解分别为 88.26 % 和 22.21 美元-GJ-1。这项工作可为研究集成可再生能源的多发电系统提供有价值的参考。
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引用次数: 0
Enhancing effect of Mn2+ substitution in CuAl2O4 spinel for methanol steam reforming in a microreactor CuAl2O4 尖晶石中 Mn2+ 取代对微反应器中甲醇蒸汽转化的增强效应
IF 8.7 1区 工程技术 Q1 Energy Pub Date : 2024-06-14 DOI: 10.1016/j.renene.2024.120815
Moyu Liao , Ruofei Xiang , Xinwen Zhou , Zhongxu Dai , Li Wang , Hang Qin , Hanning Xiao

Hydrogen generation via methanol steam reforming is a promising method for producing renewable energy. In this work, a series of Mn2+-substituted CuAl2O4 spinels were prepared by solution combustion method, and the crystal structure, micromorphology, chemical constitution, reduction behavior, acidity, specific surface area and surface chemical state of the spinels were comprehensively characterized by various equipments. The obtained spinels were washcoated on Cu foams to prepare monolithic catalysts, and the catalytic performance of the catalysts was evaluated in a methanol steam reforming microreactor. Compared with the binary Cu–Al spinel, the Mn2+ substitution led to a decrease in the particle size, a change in the chemical composition and reduction behavior, a decline in the acidity, an increase in the specific surface area, and an improvement in the surface chemical state. As a result, the release rate of active Cu from the Mn-containing CuAl2O4 spinel was significantly slowed down and the formed nanoparticles were fine, which was believed to be in favor of maintaining a stable catalytic performance longer. Among the prepared catalysts, the monolithic catalyst loaded with Cu0.4Mn0.6Al2O4 exhibited the highest activity and stability. The findings of this work suggested that introducing Mn2+ might be a promising way to regulate the Cu releasing property for obtaining a better sustained release catalyst system.

通过甲醇蒸汽转化制氢是一种很有前景的生产可再生能源的方法。本研究采用溶液燃烧法制备了一系列Mn2+取代的CuAl2O4尖晶石,并通过多种仪器对尖晶石的晶体结构、微观形貌、化学组成、还原行为、酸度、比表面积和表面化学态等进行了综合表征。将得到的尖晶石洗涂在铜泡沫上制备整体催化剂,并在甲醇蒸汽转化微反应器中评估了催化剂的催化性能。与二元 Cu-Al 尖晶石相比,Mn2+ 取代导致粒径减小、化学成分和还原行为发生变化、酸度下降、比表面积增大以及表面化学状态改善。因此,含锰 CuAl2O4 尖晶石中活性 Cu 的释放速度明显减慢,形成的纳米颗粒细小,这被认为有利于更长时间地保持稳定的催化性能。在制备的催化剂中,负载 Cu0.4Mn0.6Al2O4 的整体催化剂活性和稳定性最高。这项研究结果表明,引入 Mn2+ 可能是调节 Cu 释放特性以获得更好的缓释催化剂体系的一种可行方法。
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引用次数: 0
期刊
Renewable Energy
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