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The impact of Fintech and green bonds on the Indian renewable energy production 金融科技和绿色债券对印度可再生能源生产的影响
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-08 DOI: 10.1016/j.renene.2024.121807
Nenavath Sreenu
This study explores the important roles of Fintech and green bonds in promoting clean energy generation in India, while also analyzing the related risk dynamics. Expanding on prior research that emphasizes the significant influence of digital finance and innovative financial instruments on sustainable development, this study employs a rigorous methodology and thorough data analysis to offer fresh perspectives on their collaborative connection. Previous research has shown how Fintech can make finance more accessible to everyone, lower transaction costs, and improve transparency by utilizing technologies like digital platforms, mobile payments, and blockchain. In the same vein, green bonds have gained recognition for their ability to attract investment for environmental initiatives. This study expands on these findings in the Indian context, demonstrating how Fintech can further improve financing for renewable energy projects and how green bonds can contribute to sustainable energy initiatives. The research highlights the significance of proactive regulatory frameworks to adapt to the changing market landscape, guaranteeing strong regulations and effective risk management. This study provides valuable insights into the role of policymaking in promoting a sustainable future, which can help enhance environmental sustainability efforts in India.
本研究探讨了金融科技和绿色债券在促进印度清洁能源发电方面的重要作用,同时还分析了相关的风险动态。此前的研究强调了数字金融和创新金融工具对可持续发展的重要影响,本研究在此基础上,采用严谨的方法和全面的数据分析,为两者的合作关系提供了新的视角。以往的研究表明,金融科技如何通过利用数字平台、移动支付和区块链等技术,让每个人都能更方便地获得金融服务,降低交易成本,提高透明度。同样,绿色债券也因其能够为环保举措吸引投资而获得认可。本研究在印度的背景下扩展了这些研究成果,展示了金融科技如何进一步改善可再生能源项目的融资,以及绿色债券如何为可持续能源计划做出贡献。研究强调了积极的监管框架对于适应不断变化的市场环境、保证强有力的监管和有效的风险管理的重要意义。本研究为政策制定在促进可持续未来中的作用提供了宝贵的见解,有助于加强印度的环境可持续发展努力。
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引用次数: 0
Synergistic solar electricity-water generation through an integration of semitransparent solar cells and multistage interfacial desalination 通过整合半透明太阳能电池和多级界面海水淡化技术,实现太阳能发电和制水的协同效应
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-08 DOI: 10.1016/j.renene.2024.121837
Yushi Chen , Hanxuan Zeng , Hao Peng , Zhouyang Luo , Hua Bao
Energy shortage and freshwater scarcity are critical challenges for the sustainable development of the society. The photovoltaic-thermal (PVT) hybrid system offers a promising strategy by harnessing solar energy for electricity and water cogeneration. However, existing systems suffer from relatively low efficiency due to incomplete solar spectrum utilization. To address this, we propose a novel PVT integrated system that combines semi-transparent solar cells and multistage interfacial stills to maximize solar spectrum utilization, allowing for efficient electricity and freshwater co-production. Experimental results demonstrate a record-high solar-to-vapor efficiency of 210 % with a production rate of 3.17 L m−2 h−1 under one-sun, while maintaining an uncompromised electrical efficiency of 19.57 %. Furthermore, we employ a verified theoretical framework to provide optimized strategies for concurrent enhancement of electricity-water production, by improving internal heat and mass transfer and effectively reducing the thickness of the interstage air gap. Moreover, we introduce a non-contact model for system structure optimization proposed to match the high transmittance of solar cells. This work realizes full solar spectrum utilization to cogenerate electricity and freshwater, offering optimized strategies from the thermal perspective for future research.
能源短缺和淡水匮乏是社会可持续发展面临的严峻挑战。光伏-热能(PVT)混合系统利用太阳能进行发电和水热电联产,提供了一种前景广阔的战略。然而,由于太阳光谱利用不完全,现有系统的效率相对较低。为解决这一问题,我们提出了一种新型 PVT 集成系统,该系统结合了半透明太阳能电池和多级界面蒸馏器,可最大限度地利用太阳光谱,从而实现高效的电力和淡水联产。实验结果表明,该系统的太阳能转化为水蒸气的效率达到了创纪录的 210%,单太阳下的生产率为 3.17 L m-2 h-1,同时电气效率保持在 19.57%。此外,我们还采用了经过验证的理论框架,通过改善内部传热和传质以及有效减小级间气隙的厚度,为同时提高电-水生产提供了优化策略。此外,我们还介绍了一种用于系统结构优化的非接触模型,该模型是为匹配太阳能电池的高透光率而提出的。这项工作实现了太阳能光谱的充分利用,实现了电力和淡水的共同生产,从热学角度为未来研究提供了优化策略。
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引用次数: 0
Driving renewable energy innovation investments: Is venture capital a novel strategic choice? Evidence from China 推动可再生能源创新投资:风险投资是一种新的战略选择吗?来自中国的证据
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-08 DOI: 10.1016/j.renene.2024.121856
Boqiang Lin, Yongjing Xie
The relationship between venture capital (VC) and corporate innovation has been a topic of debate. Most existing studies have focused on the general effects of VC on innovation investments, neglecting the specific mechanisms. In the global transition toward low-carbon energy, renewable energy (RE) is increasingly becoming a focus area for VC. However, whether VC can effectively stimulate innovation investments in RE firms remains uncertain. This study addressed these gaps by systematically investigating the impact of VC on renewable energy innovation investments (REII) using data from 114 listed RE companies in China from 2011 to 2023. Our findings demonstrate that VC significantly stimulates REII, with a particularly pronounced effect in high-growth and profitable companies, thereby providing new empirical evidence to the ongoing debate on VC's role in corporate innovation. Furthermore, we uncover that VC not only alleviates financial mismatch but also reduces rent-seeking costs, thereby indirectly fostering innovation. These mechanisms help explain how VC can enhance the innovation capabilities of RE companies. Lastly, we find that joint VC, state-owned VC, and long-term VC are especially conducive to promoting innovation. Based on these findings, we offered targeted policy suggestions to boost the innovation potential of China's RE sector.
风险投资(VC)与企业创新之间的关系一直是一个争论不休的话题。现有研究大多关注风险投资对创新投资的一般影响,而忽视了具体机制。在全球向低碳能源转型的过程中,可再生能源(RE)日益成为风险投资的重点领域。然而,风险投资能否有效刺激可再生能源企业的创新投资仍不确定。本研究利用 2011 年至 2023 年中国 114 家可再生能源上市公司的数据,系统研究了风险投资对可再生能源创新投资(REII)的影响,从而弥补了上述不足。我们的研究结果表明,风险投资极大地刺激了可再生能源创新投资,对高增长和高盈利公司的影响尤为明显,从而为目前关于风险投资在企业创新中的作用的讨论提供了新的经验证据。此外,我们还发现,风险投资不仅能缓解财务错配,还能降低寻租成本,从而间接促进创新。这些机制有助于解释风险投资如何增强可再生能源公司的创新能力。最后,我们发现联合风险投资、国有风险投资和长期风险投资尤其有利于促进创新。基于这些发现,我们提出了有针对性的政策建议,以提升中国可再生能源行业的创新潜力。
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引用次数: 0
Fuel properties evaluation and inherent correlation analysis of oxidatively torrefied corn stalk 氧化焦化玉米秸秆的燃料特性评估和内在关联分析
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-08 DOI: 10.1016/j.renene.2024.121855
Congyu Zhang , Yong Zhan , Wei-Hsin Chen , Ying Zhang
Fuel properties evaluation and inherent correlation analysis of the biochar are important in assessing the variation of fuel performance. This study investigates fuel performance changes under different oxidative torrefaction conditions of corn stalks. The obtained results imply that such a method is conducive to enhancing fuel properties, with the values of energy-mass co-benefit index (EMCI), upgrading energy index (UEI), Hardgrove grindability index (HGI), and equilibrium moisture content (EMC) range at 4–9, 500–3500, 60–120, and 9.5–12. This indicates that oxidative torrefaction is efficient for fuel performance improvement. For elemental transformation and carbonization degree, the oxidatively torrefied biochar possesses a higher proportion of elemental carbon content and better graphitization degree (GD), thus contributing to a more stable structure. Good linear relationships are exhibited from the analysis of comprehensive pyrolysis index (CPI) versus elemental carbon proportion (ECP), comprehensive combustion index (CCI) versus ECP, CPI versus GD, and CCI versus GD, with correlation coefficients of 0.9741, 0.9524, 0.9689, and 0.9166, respectively. This suggests that the carbonization extent is highly related to biochar pyrolysis and combustion characteristics. Overall, the obtained results are conducive to enhancing inherent correlation cognition of fuel property indicators. In doing so, the fuel property can be better adjusted for performance enhancement, thus facilitating efficient biochar production with better industrial application potential.
生物炭的燃料特性评估和内在相关性分析对于评估燃料性能的变化非常重要。本研究调查了玉米秸秆在不同氧化热解条件下的燃料性能变化。结果表明,这种方法有利于提高燃料性能,其能量-质量协同效益指数(EMCI)、升级能量指数(UEI)、哈德格罗夫可磨性指数(HGI)和平衡含水量(EMC)的值范围分别为 4-9、500-3500、60-120 和 9.5-12。这表明氧化焦烧能有效改善燃料性能。在元素转化和碳化程度方面,氧化焦烧生物炭的元素碳含量比例更高,石墨化程度(GD)更高,因此结构更稳定。综合热解指数(CPI)与元素碳比例(ECP)、综合燃烧指数(CCI)与 ECP、CPI 与 GD、CCI 与 GD 的相关系数分别为 0.9741、0.9524、0.9689 和 0.9166。这表明碳化程度与生物炭热解和燃烧特性高度相关。总之,所得结果有利于增强燃料特性指标的内在关联认知。这样,就可以更好地调整燃料特性以提高性能,从而促进生物炭的高效生产,并具有更好的工业应用潜力。
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引用次数: 0
Unveiling the potential of Au cocatalysts to induce SPR charges on CuO/CdS system for sunlight driven hydrogen production† 揭示金催化剂在 CuO/CdS 系统上诱导 SPR 电荷的潜力,以实现阳光驱动的制氢†。
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-08 DOI: 10.1016/j.renene.2024.121817
Abubakar Ishaq, Khezina Rafiq, Muhammad Zeeshan Abid, Umme Aiman, Ejaz Hussain
Atmospheric pollution and increasing costs of the fossil fuels have compelled researchers to explore the alternative sources. Objective of current project is to discover catalysts that can drive water splitting reaction with sunlight. To the purpose, visible light active catalysts i.e., CdS, CuO/CdS, and Au@CuO/CdS have been synthesized and evaluated for hydrogen generation activities. Gold cocatalysts have been employed to enhance the surface stability and catalytic efficiencies. Whereas, CuO/CdS heterojunction have been synthesized to improve charge separation ability. The optical characteristics, structural properties, and morphology of catalysts have been evaluated by UV–Vis/DRS, XRD, Raman, BET, SEM, AFM, PL and FTIR techniques. Chemical compositions, photocurrent or charge transfer have been verified with XPS, EDX and EIS results. Catalytic reactions were performed in photoreactor (150 mL/Pyrex), whereas hydrogen production activities were predicted via online GC-TCD (Shimadzu-2010/Japan). Results depict that catalyst with 0.8 % of Au on CuO/CdS exhibit relatively higher activity (i.e., 32.13 mmol g−1 h−1) than the other catalysts of the series. Higher activities were attributed to the presence of Au cocatalysts. It has been predicted that existence of gold develops Schottky junctions that progressively rectify the surface charges (i.e., movement of electrons). Additionally, gold induces the SPR charges and enhances activity of electrons. Schottky junctions formed by Au cocatalysts on CuO/CdS system restrict the charge recombination i.e., back reactions. In this study, various factors like temperature, pH, light intensity and dose of catalysts have been assessed and discussed. On the basis of activities, it has been concluded that work reported herein hold promise to replace the conventional catalysts used for hydrogen energy technologies.
大气污染和化石燃料成本的增加迫使研究人员探索替代能源。当前项目的目标是发现能够利用太阳光驱动水分离反应的催化剂。为此,我们合成了可见光活性催化剂,即 CdS、CuO/CdS 和 Au@CuO/CdS,并对其制氢活性进行了评估。为了提高表面稳定性和催化效率,还使用了金助催化剂。同时,还合成了 CuO/CdS 异质结,以提高电荷分离能力。催化剂的光学特性、结构特性和形态已通过 UV-Vis/DRS、XRD、Raman、BET、SEM、AFM、PL 和 FTIR 技术进行了评估。化学成分、光电流或电荷转移已通过 XPS、EDX 和 EIS 结果进行了验证。催化反应是在光反应器(150 mL/Pyrex)中进行的,而制氢活性则是通过在线 GC-TCD(Shimadzu-2010/日本)进行预测的。结果表明,在 CuO/CdS 上添加 0.8 % 金的催化剂比该系列的其他催化剂具有更高的活性(即 32.13 mmol g-1 h-1)。较高的活性归因于金助催化剂的存在。据预测,金的存在会形成肖特基结,使表面电荷(即电子移动)逐步整流。此外,金还能诱导 SPR 电荷并增强电子的活性。金催化剂在 CuO/CdS 系统上形成的肖特基结限制了电荷重组(即逆反应)。本研究对温度、pH 值、光照强度和催化剂剂量等各种因素进行了评估和讨论。根据这些活动得出的结论是,本文报告的工作有望取代用于氢能技术的传统催化剂。
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引用次数: 0
Optimizing production well geometry in the Utah FORGE geothermal project using machine learning and fluid flow modeling 利用机器学习和流体流动建模优化犹他州 FORGE 地热项目中生产井的几何形状
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-07 DOI: 10.1016/j.renene.2024.121767
Yanrui Ning , Jeffrey R. Bailey , Jeff Bourdier , Prathik Prasad , Israel Momoh
This study addresses the critical challenge of optimizing well placement in Enhanced Geothermal Systems (EGS), specifically within the framework of the Utah FORGE geothermal project, as part of the 2023 Society of Petroleum Engineers (SPE) Geothermal Datathon. Effective well placement is essential for enhancing geothermal production efficiency and maximizing resource utilization. We employed a discrete fracture network (DFN) modeling approach, utilizing the Density-Based Spatial Clustering of Applications with Noise (DBSCAN) algorithm from the Scikit-Learn library to analyze microseismic event location data. Through rigorous simulations conducted in the open-source GeoDT fluid flow simulator, we identified an optimal production well configuration characterized by a spacing of 400 m, an injection rate of 0.03 m³/s, and alignment parameters that significantly improve thermal recovery. The results indicate a projected net present value (NPV) of $75 million over a 20-year operational horizon, underscoring the economic potential of optimized well placement strategies. This study offers valuable insights for the operation of the FORGE geothermal site. More importantly, it exclusively utilizes open-source tools, enhancing accessibility and adaptability for the broader geothermal community.
作为 2023 年美国石油工程师学会(SPE)地热数据马拉松的一部分,本研究探讨了强化地热系统(EGS)中优化井位的关键挑战,特别是在犹他州 FORGE 地热项目的框架内。有效的井位布置对于提高地热生产效率和资源利用最大化至关重要。我们采用离散断裂网络 (DFN) 建模方法,利用 Scikit-Learn 库中的基于密度的噪声应用空间聚类 (DBSCAN) 算法分析微地震事件位置数据。通过在开源 GeoDT 流体流动模拟器中进行严格模拟,我们确定了最佳生产井配置,其特点是间距为 400 米,注入率为 0.03 立方米/秒,对准参数可显著提高热采收率。研究结果表明,在 20 年的运营期内,预计净现值 (NPV) 为 7500 万美元,凸显了优化井位策略的经济潜力。这项研究为 FORGE 地热基地的运营提供了宝贵的见解。更重要的是,它完全采用了开源工具,提高了广大地热社区的可访问性和适应性。
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引用次数: 0
Investigation of the transient characteristics of the Francis turbine during runaway process 研究混流式水轮机在失控过程中的瞬态特性
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-07 DOI: 10.1016/j.renene.2024.121840
Yanyan Li , Longgang Sun , Pengcheng Guo
Transient hydraulic phenomena, including flow separation, vortex structure and high amplitude pressure fluctuation, occur in the turbine during runaway process, significantly affecting the safe and stable operation. To clarify the unsteady flow characteristics in the runaway process, this paper focus on a low head model Francis turbine, examining the transient flow dynamics from rated speed to runaway speed. Numerical simulations show good agreement with experimental test results for the runaway speed and discharge. Results identify that two typical cavitation vortex structures within the runner: A cloud cavitation vortex near the hub on the pressure side and a columnar cavitation vortex on the suction side. Further analysis reveals that the pressure fluctuation induced by the former are low-frequency (0.08fn and harmonics), whereas those induced by the latter are high-frequency (1.16fn and harmonics). Entropy production analysis in homogeneous flow indicates that energy dissipation mainly occurs in the runner and draft tube during the runaway process. Turbulent entropy production within the turbine comprises a significant portion of the total entropy production. Additionally, areas around the recirculation zone exhibit considerable high entropy production, indicating that the energy of the fluid is dissipated by cavitation vortex structures generated in these areas. Additionally, the analysis indicates that the entropy production rate correlates with vapor generation, underscoring the cavitation vortex as the primary cause of energy dissipation. This investigation can provide valuable insights into the energy dissipation mechanisms during the runaway process.
水轮机在失控过程中会出现瞬态水力现象,包括水流分离、涡流结构和高振幅压力波动,严重影响水轮机的安全稳定运行。为阐明失控过程中的非稳态流动特性,本文以低水头混流式水轮机为研究对象,探讨了从额定转速到失控转速的瞬态流动动力学特性。数值模拟结果表明,失控转速和排量与实验测试结果十分吻合。结果发现转轮内有两种典型的气蚀涡结构:压力侧靠近轮毂的云状空化漩涡和吸入侧的柱状空化漩涡。进一步分析发现,前者引起的压力波动是低频的(0.08fn 和谐波),而后者引起的压力波动是高频的(1.16fn 和谐波)。均质流中的熵产生分析表明,在失控过程中,能量耗散主要发生在流道和引流管中。涡轮机内的湍流熵产生占总熵产生的很大一部分。此外,再循环区周围的区域显示出相当高的熵产生量,这表明流体的能量是由这些区域产生的空化涡流结构耗散的。此外,分析表明,熵产生率与蒸汽产生率相关,突出了空化漩涡是能量耗散的主要原因。这项研究可以为了解失控过程中的能量耗散机制提供有价值的见解。
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引用次数: 0
State-of-the-art nonstationary hypersurface damage assessment approach for energy harvesters 最先进的能量收集器非稳态超表面损伤评估方法
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-07 DOI: 10.1016/j.renene.2024.121824
Oleg Gaidai, Shicheng He, Fang Wang
Since EH (Energy Harvesters) constitute nowadays a vital part of renewable energy engineering, experimental research is required in addition to numerical modeling, serving reliable structural design and ensuring prolonged device service time. The performance of GPEH (GalloPing EH) has been examined in this case study, utilizing comprehensive laboratory wind tunnel tests, carried out under realistic windspeed conditions. Novel structural multivariate risks assessment methodology, presented here, being feasible for nonstationary nonlinear GPEH dynamic systems, that had been either physically measured over a representative period, providing jointly quasi-ergodic time-series, or directly numerically MCS (Monte Carlo Simulated). Based on laboratory-measured GPEH dynamics, the presented analysis demonstrates that the proposed multivariate hypersurface methodology offers robust predictions of the structural failure/damage risks. Furthermore, when dealing with raw measured timeseries, representing the high-dimensional dynamic system, existing risk assessment techniques struggle to handle nonlinear inter-correlations between GPEH critical components. This case study's main objective has been to validate and benchmark the novel multimodal risk assessment methodology, which utilizes multivariate nonstationary lab-recorded time histories to extract relevant design information from the underlying GPEH dynamics.
The proposed state-of-the-art nonstationary hypersurface reliability approach being of a generic nature, offering additional capacity for damage/failure risks prognostics for a wide range of nonlinear multidimensional nonstationary systems. Forecasted damage and failure risks have been supplied with confidence bands, demonstrating the experimental setup's robustness, as well as the useful design features of the presented nonstationary hypersurface risks assessment methodology. It should be noted that the presented reliability methodology being mathematically exact, and it does not rely on simplifying assumptions.
由于能量收集器(EH)如今已成为可再生能源工程的重要组成部分,因此除了数值建模之外,还需要进行实验研究,以进行可靠的结构设计,并确保延长设备的使用寿命。本案例研究利用实验室风洞综合测试,在实际风速条件下对 GPEH(GalloPing EH)的性能进行了检验。本文介绍的新型结构多元风险评估方法适用于非稳态非线性 GPEH 动态系统,该系统在一个具有代表性的时期内进行了物理测量,提供了共同的准啮合时间序列,或直接进行了蒙特卡罗模拟(MCS)。基于实验室测量的 GPEH 动力学,所做的分析表明,所提出的多元超曲面方法可对结构失效/损坏风险进行可靠预测。此外,在处理代表高维动态系统的原始测量时间序列时,现有的风险评估技术很难处理 GPEH 关键部件之间的非线性相互关系。本案例研究的主要目的是验证和基准测试新型多模态风险评估方法,该方法利用实验室记录的多变量非稳态时间序列,从 GPEH 基本动态中提取相关设计信息。预测的损坏和失效风险带有置信带,证明了实验装置的稳健性,以及所介绍的非稳态超表面风险评估方法的有用设计特征。值得注意的是,所提出的可靠性方法在数学上是精确的,并不依赖于简化假设。
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引用次数: 0
Theoretical prediction of a high-performance two-dimensional type-II MoSi2N4/As vdW heterostructure for photovoltaic solar cells 用于光伏太阳能电池的高性能二维 II 型 MoSi2N4/As vdW 异质结构的理论预测
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-07 DOI: 10.1016/j.renene.2024.121802
Deobrat Singh , Nabil Khossossi , Raquel Lizárraga , Yogesh Sonvane
Solar cells are expected to become one of the dominant electricity generation technologies in the coming decades. Developing high-performance absorbers made from thin materials is a promising pathway to improve efficiency and reduce cost, accelerating the widespread adoption of these photovoltaic cells. In the present work, we have systematically investigated the 2D MoSi2N4/Arsenene van der Waals (vdW) heterostructure, which exhibits a type-II band alignment with an indirect band gap semiconductor (1.58 eV), that can effectively separate the photogenerated electron–hole (e–h+) pairs. Compared to the isolated MoSi2N4 and Arsenene monolayers, the optical absorption strength can be significantly enhanced in MoSi2N4/Arsenene vdW heterostructure (in the order of 105 cm−1 in the visible region). The calculated optical absorption gaps are 2.12 eV (Arsenene) and 1.76 eV (MoSi2N4), with excitonic binding energies of 0.05 eV for arsenene and 0.48 eV for MoSi2N4, indicating that both materials can effectively form excitons and separate charges. Moreover, we found a high spectroscopic limited maximum efficiency of 27.27% for the MoSi2N4/Arsenene vdW heterostructure, which is relatively higher compared to previously reported 2D heterostructures. Ab-initio molecular dynamics (AIMD) simulations at 300 K, 600 K, and 900 K were conducted to evaluate the thermal stability of the MoSi2N4/Arsenene heterostructure. Simulations in the presence of water and NO2 at 300 K were also performed to assess its resilience to humidity and pollutants. The results suggest strong stability under harsh environmental conditions. Our findings demonstrate that the 2D MoSi2N4/Arsenene vdW heterostructure is an excellent candidate for both photovoltaic device applications and optoelectronic nanodevices.
太阳能电池有望在未来几十年内成为最主要的发电技术之一。开发由薄材料制成的高性能吸收器是提高效率和降低成本的一条大有可为的途径,可加速这些光伏电池的广泛应用。在本研究中,我们系统地研究了二维 MoSi2N4/Arsenene 范德瓦耳斯(vdW)异质结构,该结构具有间接带隙半导体(1.58 eV)的 II 型带排列,能有效分离光生电子-空穴(e-h+)对。与孤立的 MoSi2N4 和砷单层相比,MoSi2N4/砷 vdW 异质结构的光吸收强度明显增强(在可见光区域大约为 105 cm-1)。计算得出的光吸收间隙分别为 2.12 eV(砷烯)和 1.76 eV(MoSi2N4),其中砷烯的激子结合能为 0.05 eV,MoSi2N4 为 0.48 eV,这表明这两种材料都能有效地形成激子并分离电荷。此外,我们还发现 MoSi2N4/Arsenene vdW 异质结构的光谱限制最大效率高达 27.27%,与之前报道的二维异质结构相比相对较高。为了评估 MoSi2N4/Arsenene 异质结构的热稳定性,研究人员分别在 300 K、600 K 和 900 K 下进行了原子内分子动力学(AIMD)模拟。此外,还在水和二氧化氮存在的 300 K 条件下进行了模拟,以评估其对湿度和污染物的适应性。结果表明,这种异质结构在恶劣的环境条件下具有很强的稳定性。我们的研究结果表明,二维 MoSi2N4/Arsenene vdW 异质结构是光伏器件应用和光电纳米器件的绝佳候选材料。
{"title":"Theoretical prediction of a high-performance two-dimensional type-II MoSi2N4/As vdW heterostructure for photovoltaic solar cells","authors":"Deobrat Singh ,&nbsp;Nabil Khossossi ,&nbsp;Raquel Lizárraga ,&nbsp;Yogesh Sonvane","doi":"10.1016/j.renene.2024.121802","DOIUrl":"10.1016/j.renene.2024.121802","url":null,"abstract":"<div><div>Solar cells are expected to become one of the dominant electricity generation technologies in the coming decades. Developing high-performance absorbers made from thin materials is a promising pathway to improve efficiency and reduce cost, accelerating the widespread adoption of these photovoltaic cells. In the present work, we have systematically investigated the 2D MoSi<sub>2</sub>N<sub>4</sub>/Arsenene van der Waals (vdW) heterostructure, which exhibits a type-II band alignment with an indirect band gap semiconductor (1.58 eV), that can effectively separate the photogenerated electron–hole (e<span><math><msup><mrow></mrow><mrow><mo>−</mo></mrow></msup></math></span>–h<span><math><msup><mrow></mrow><mrow><mo>+</mo></mrow></msup></math></span>) pairs. Compared to the isolated MoSi<sub>2</sub>N<sub>4</sub> and Arsenene monolayers, the optical absorption strength can be significantly enhanced in MoSi<sub>2</sub>N<sub>4</sub>/Arsenene vdW heterostructure (in the order of <span><math><mo>∼</mo></math></span>10<sup>5</sup> cm<sup>−1</sup> in the visible region). The calculated optical absorption gaps are 2.12 eV (Arsenene) and 1.76 eV (MoSi<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>N<span><math><msub><mrow></mrow><mrow><mn>4</mn></mrow></msub></math></span>), with excitonic binding energies of 0.05 eV for arsenene and 0.48 eV for MoSi<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>N<span><math><msub><mrow></mrow><mrow><mn>4</mn></mrow></msub></math></span>, indicating that both materials can effectively form excitons and separate charges. Moreover, we found a high spectroscopic limited maximum efficiency of 27.27% for the MoSi<sub>2</sub>N<sub>4</sub>/Arsenene vdW heterostructure, which is relatively higher compared to previously reported 2D heterostructures. <em>Ab-initio</em> molecular dynamics (AIMD) simulations at 300 K, 600 K, and 900 K were conducted to evaluate the thermal stability of the MoSi<sub>2</sub>N<sub>4</sub>/Arsenene heterostructure. Simulations in the presence of water and NO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> at 300 K were also performed to assess its resilience to humidity and pollutants. The results suggest strong stability under harsh environmental conditions. Our findings demonstrate that the 2D MoSi<sub>2</sub>N<sub>4</sub>/Arsenene vdW heterostructure is an excellent candidate for both photovoltaic device applications and optoelectronic nanodevices.</div></div>","PeriodicalId":419,"journal":{"name":"Renewable Energy","volume":"237 ","pages":"Article 121802"},"PeriodicalIF":9.0,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142658556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Validation through internal flow physics of response surface methodology optimized mixed flow pump as turbine 通过响应面方法优化混流泵作为涡轮机的内部流动物理学验证
IF 9 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-07 DOI: 10.1016/j.renene.2024.121838
Xu Zhou , Sun Sheng Yang , Punit Singh , Ling Zhou
In order to determine the optimal working efficiency of mixed flow pumps as turbine (MF-PAT) under a design condition of 10m3kw, this study takes the number of blades, blade wrap angle, impeller outer diameter, and impeller inlet width as design variables. Based on the center combination design method, experimental scheme design is carried out, and the head, shaft power, and efficiency of the turbine are used as evaluation indicators. A response surface model is constructed for optimization analysis, and the optimal geometric parameter combination of the impeller for MF-PAT is determined. For MF-PAT with forward-curved blade impeller in this paper, the optimal parameter combination is recommended as blade number Z = 6, blade wrap angle α = 47°, impeller outer diameter D2 = 140 mm and impeller inlet width b2 = 34 mm. The results show that compared with the original scheme, its efficiency has increased by 7.8 %. The established response surface model can reflect the relationship between evaluation indicators and design variables, and can be used for optimizing the geometric parameters of MF-PAT impellers. It can effectively enhance the blade's constraint ability on liquid flow, reduce hydraulic losses, and improve the performance of MF-PAT. Apply the ns-ds methodology for this and future mixed flow optimized pumps as turbines.
为了确定混流泵作为涡轮机(MF-PAT)在 10m3kw 设计条件下的最佳工作效率,本研究以叶片数、叶片包角、叶轮外径和叶轮入口宽度为设计变量。以中心组合设计法为基础,进行试验方案设计,以水轮机的扬程、轴功率和效率作为评价指标。建立响应面模型进行优化分析,确定了 MF-PAT 叶轮的最佳几何参数组合。对于采用前弯叶片叶轮的 MF-PAT,本文推荐的最佳参数组合为叶片数 Z = 6,叶片包角 α = 47°,叶轮外径 D2 = 140 mm,叶轮入口宽度 b2 = 34 mm。结果表明,与原方案相比,其效率提高了 7.8%。所建立的响应面模型能够反映评价指标与设计变量之间的关系,可用于优化 MF-PAT 叶轮的几何参数。它能有效增强叶片对液流的约束能力,减少水力损失,提高 MF-PAT 的性能。将 ns-ds 方法应用于该混流优化泵和未来的涡轮机。
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Renewable Energy
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