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N-heterocycle-based deep eutectic solvent-driven lignocellulosic biomass valorization: Efficient extraction of lignin facilitates enzymatic hydrolysis to produce bioethanol and butyric acid from corn stover 基于n -杂环的深共晶溶剂驱动的木质纤维素生物质增值:木质素的有效提取促进了玉米秸秆酶解生产生物乙醇和丁酸
IF 9.1 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-04-15 Epub Date: 2026-02-04 DOI: 10.1016/j.renene.2026.125361
Jiabin Wang , Xiang Zhou , Rui Zhang , Xinyan You , Qianyue Yang , Cheng Zhang , Yu Shao , Fang Xie , Aiyong He , Rongling Yang , Hongzhen Luo
The existence of lignin in lignocellulose largely hinders the accessibility of polysaccharides, leading to lower saccharification yield and substrate fermentability. Therefore, extraction of lignin by pretreatment is an efficient strategy for biomass valorization. The non-uniform electron density distribution in N-heterocycles affects interactions with electron-rich lignin, which is beneficial for lignin extraction. Based on this, N-heterocyclic deep eutectic solvents (DESs) were prepared using pyrazole and organic acids. Lignin extraction yield of 94.27% was achieved when pretreating corn stover at 145 °C for 180 min by pyrazole-formic acid DES (Py-FA), and >85% glucan was retained. Glucose yield of DES-pretreated substrate reached ∼100% by enzymolysis. A high correlation (R2 > 0.91) between lignin removal and hydrolysis yield was observed in N-heterocycle-based DES pretreatment. Also, Py-FA DES-extracted lignin had comparable thermostability within 200–500 °C to sodium lignosulfonate. Finally, corn stover hydrolysates were applied as feedstock for bioethanol and butyric acid production. Consequently, ethanol production and yield reached 31.77 g/L and 0.38 g/g from real hydrolysates by Saccharomyces cerevisiae. Up to 9.48 g/L butyric acid was biosynthesized by Clostridium tyrobutyricum with yield of 0.43 g/g, ∼88% of theoretical yield from glucose. Overall, N-heterocycle-based DES pretreatment provides an efficient and robust strategy to produce value-added products from lignocellulose.
木质纤维素中木质素的存在极大地阻碍了多糖的可及性,导致糖化率和底物发酵性降低。因此,预处理提取木质素是生物质增值的有效策略。n杂环中电子密度分布的不均匀影响了与富电子木质素的相互作用,有利于木质素的提取。在此基础上,用吡唑和有机酸制备了n -杂环深共晶溶剂(DESs)。采用吡唑甲酸DES (pyrazole-formic acid DES, Py-FA)预处理玉米秸秆,145℃180 min,木质素提取率为94.27%,葡聚糖保留率为85%。经des预处理的底物酶解葡萄糖产率达到~ 100%。在n -杂环DES预处理中,木质素去除率与水解率呈高度相关(R2 > 0.91)。此外,Py-FA des提取的木质素在200-500°C内具有与木质素磺酸钠相当的热稳定性。最后,将玉米秸秆水解物作为生物乙醇和丁酸生产的原料。结果表明,酿酒酵母实际水解物的乙醇产量和产率分别达到31.77 g/L和0.38 g/g。酪氨酸丁酸梭菌生物合成了高达9.48 g/L的丁酸,产率为0.43 g/g,约为葡萄糖理论产率的88%。总之,基于n -杂环的DES预处理为木质纤维素生产高附加值产品提供了一种有效而稳健的策略。
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引用次数: 0
Targeted catalytic fast pyrolysis of water hyacinth using acid-leached slag from spent Al2O3-based catalysts 废al2o3酸浸渣催化水葫芦快速热解研究
IF 9.1 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-04-15 Epub Date: 2026-02-04 DOI: 10.1016/j.renene.2026.125394
Chenzhirui Zhou , Cheng Tan , Yong Yu , Shi Cheng , Chaowei Ma , Jianhang Hu , Hua Wang
Lignocellulosic biomass possesses significant potential as a carbon-based renewable energy source. Fast pyrolysis can convert biomass into valuable derivatives, though achieving high selectivity for target compounds remains a challenge. In this study, acid-leached slag (ALS) derived from spent Al2O3-based catalysts was employed as a catalyst to investigate its effect on the pyrolysis products of water hyacinth (WH). Under optimal conditions of a WH/ALS ratio of 1:3 at 500 °C, the bio-oil yield reached 70.81 wt%, and furfural yield achieved 97.37 area% with a concentration of 83.96 mg/mL. This enhancement is attributed to the synergistic catalytic activity of Brønsted and Lewis acid sites on ALS, which substantially improves the directional selectivity toward furfural. Concurrently, biochar undergoes aromatization, forming aromatic ring structures that promote graphitization, while the proportion of combustible syngas rises to 99.84%. Additionally, N-containing heterocyclics from the bio-oil are redistributed into the biochar (as graphitic-N, pyrrolic-N, and pyridinic-N) and syngas. This study demonstrates an effective strategy for simultaneously valorizing WH and ALS, offering a novel approach for producing high-value chemicals through catalytic pyrolysis of lignocellulosic biomass.
木质纤维素生物质作为一种碳基可再生能源具有巨大的潜力。快速热解可以将生物质转化为有价值的衍生物,尽管实现对目标化合物的高选择性仍然是一个挑战。本研究以废al2o3基催化剂酸浸渣(ALS)为催化剂,研究其对水葫芦(WH)热解产物的影响。在500℃条件下,WH/ALS比为1:3,生物油收率为70.81 wt%,糠醛收率为97.37 area%,浓度为83.96 mg/mL。这种增强归因于ALS上Brønsted和Lewis酸位点的协同催化活性,这大大提高了对糠醛的定向选择性。同时,生物炭发生芳构化,形成促进石墨化的芳环结构,可燃合成气比例上升至99.84%。此外,来自生物油的含n杂环被重新分配到生物炭(石墨- n、吡咯- n和吡啶- n)和合成气中。本研究展示了一种同时活化WH和ALS的有效策略,为通过木质纤维素生物质的催化热解生产高价值化学品提供了一种新方法。
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引用次数: 0
Filling the cellulosic bio-economy gap by utilizing a wedge approach combined with stakeholder collaboration 利用楔形方法与利益相关者合作,填补纤维素生物经济的空白
IF 9.1 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-04-15 Epub Date: 2026-02-10 DOI: 10.1016/j.renene.2026.125419
Pan Yang , Ximing Cai
The price gap between the market and breakeven prices of cellulosic biomass for farmers represents a significant barrier to the development of a low-carbon cellulosic bioeconomy. Using a bottom-up, agent-based modeling tool that replicates the behaviors and interactions of key stakeholders, this study analyzes the emergence of a cellulosic bioeconomy at the local scale through a wedge approach that examines an integrated portfolio of multiple policy options, including subsidies for small-scale bioproducts and environmental credits. The role of collaboration among multiple stakeholders, such as biomass producers (farmers), bio-refinery industry, government, and society, is assessed for filling the price gap. Using the Sangamon River Basin as a case study site, we evaluate the effectiveness of the wedge approach by comparing simulation results from multiple scenarios, each incorporating different combinations of bioeconomy wedges, with and without stakeholder collaboration. Results underscore that active collaboration among stakeholders acts as a catalyst enlarging the effectiveness of bioeconomy wedges. Including the carbon credits and environmental value in the policy portfolio is found to bridge the price gap through collective contributions from diverse stakeholders, where the cellulosic biofuel and bioproduct industry plays a pivotal role. Although this study is conducted at the local watershed scale, the methodology and findings offer valuable insights for market development in other watersheds and the potential scaling of local markets to regional and national levels.
对农民来说,纤维素生物质的市场价格和盈亏平衡价格之间的价格差距是发展低碳纤维素生物经济的一个重大障碍。本研究使用自下而上、基于主体的建模工具,复制了关键利益相关者的行为和互动,通过楔形方法分析了地方尺度上纤维素生物经济的出现,该方法研究了多种政策选择的综合组合,包括对小规模生物产品的补贴和环境信贷。评估了生物质能生产商(农民)、生物精炼厂、政府和社会等多方利益相关者之间的合作在填补价格差距方面的作用。以Sangamon河流域为例,我们通过比较多个场景的模拟结果来评估楔形方法的有效性,每个场景都包含不同的生物经济楔形组合,有和没有利益相关者的合作。结果强调,利益相关者之间的积极合作是扩大生物经济楔子有效性的催化剂。将碳信用额和环境价值纳入政策组合,可以通过不同利益相关者的集体贡献弥合价格差距,其中纤维素生物燃料和生物制品工业发挥着关键作用。虽然这项研究是在当地流域尺度上进行的,但其方法和研究结果为其他流域的市场发展以及将当地市场扩大到区域和国家层面提供了有价值的见解。
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引用次数: 0
A framework for life-cycle profit-damage assessment of floating multi-energy islands with wind–wave dynamics integration 基于风浪动力学积分的多能浮岛全生命周期损益评估框架
IF 9.1 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-04-15 Epub Date: 2026-02-09 DOI: 10.1016/j.renene.2026.125412
Miaorui Ma , Chengwei Lou , Lingte Chen , Jin Yang
This study proposes a comprehensive techno-economic assessment framework for optimal offshore energy island site selection, emphasizing both economic efficiency and structural resilience. By integrating the dynamic interaction of wind and wave conditions, the framework improves decision-making accuracy to ensure that selected locations are both cost-effective and environmentally robust. Additionally, a novel multi-energy island scenario is introduced, featuring detailed hydrogen production and storage modeling to enable efficient electricity-to-hydrogen conversion and flexible energy transport. To evaluate operational performance and life cycle sustainability, the study employs Kriging surrogate models, validated using OpenFAST simulations. These models predict turbine power output and fatigue damage across varying environmental conditions, including wind speed, wave height, and wave period. This integration significantly advances the optimization process by allowing long-term behavior prediction while minimizing computational costs. Furthermore, real historical environmental datasets and multiple floating offshore wind platforms are utilized for simulation benchmarks, enhancing the framework’s practical relevance. The results demonstrate substantial improvements in life cycle profit and structural reliability through optimal site selection. Ultimately, the framework provides a practical and scalable reference for planning offshore renewable energy systems, supporting the development of sustainable, resilient, and economically viable offshore energy islands in dynamic marine environments.
本研究提出了一个综合技术经济评估框架,以优化海上能源岛选址,同时强调经济效率和结构弹性。通过整合风浪条件的动态相互作用,该框架提高了决策的准确性,以确保所选地点既经济高效又环保。此外,还介绍了一种新的多能岛情景,其中包括详细的氢气生产和储存建模,以实现高效的电力到氢转换和灵活的能源运输。为了评估运营绩效和生命周期可持续性,该研究采用了Kriging代理模型,并通过OpenFAST模拟进行了验证。这些模型预测了涡轮机在不同环境条件下的功率输出和疲劳损伤,包括风速、波浪高度和波浪周期。这种集成通过允许长期行为预测,同时最大限度地减少计算成本,大大推进了优化过程。此外,真实的历史环境数据集和多个浮式海上风电平台被用于模拟基准,增强了框架的实际相关性。结果表明,通过优化选址,在寿命周期利润和结构可靠性方面有了实质性的改善。最终,该框架为规划海上可再生能源系统提供了实用和可扩展的参考,支持在动态海洋环境中开发可持续、有弹性和经济上可行的海上能源岛。
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引用次数: 0
Multi-node and sector-coupled pathways to a 100% renewable energy system in the Galapagos Islands 在加拉帕戈斯群岛实现100%可再生能源系统的多节点和部门耦合路径
IF 9.1 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-04-15 Epub Date: 2026-02-10 DOI: 10.1016/j.renene.2026.125393
Daniel Icaza-Alvarez , Fernando González-Ladrón-de-Guevara , David Borge-Diez
This study addresses the energy transition toward a 100% renewable energy system in the Galapagos Islands by analyzing the energy potential of each inhabited island (Santa Cruz, San Cristóbal, Isabela, and Floreana) and then evaluating the potential energy production levels considering 1 node and 4 nodes operating electrically both in isolation and interconnected. Decarbonization pathways are considered integral in the Galapagos Islands due to their unique fragile ecosystems. Therefore, the analysis covers various electrical coupling configurations for the electricity demand sectors. With the support of specialized energy transition software EnergyPLAN, scenarios were developed at hourly resolution, considering commercially available technologies based on the energy potential available in the Galapagos Islands, in the most diversified manner possible. The results demonstrate that: (1) single-node systems present limited outcomes for decision-making; (2) an isolated multi-node model represents a much more realistic system and allows for detailed identification of energy production levels per island based on local resources; and; (3) the best solution for coupling and the possibility of the islands sharing energy in a coordinated manner occurs when there is electrical interconnection. It is concluded that the most appropriate solution, technically and economically, to achieve a decarbonized system is an interconnected, multi-node and multi-sector one. This study provides a much more detailed perspective on the implications of the energy transition in the Galapagos Islands. These results are encouraging for decision-makers to contribute their contribution to protecting this unique treasure on the planet, also considered a living laboratory.
本研究通过分析每个有人居住的岛屿(圣克鲁斯,圣Cristóbal,伊莎贝拉和弗洛里亚纳岛)的能源潜力,然后考虑1个节点和4个节点在隔离和互联的情况下电力运行,评估潜在的能源生产水平,从而解决了加拉帕戈斯群岛向100%可再生能源系统的能源转型。由于加拉帕戈斯群岛独特的脆弱生态系统,脱碳途径被认为是不可或缺的。因此,该分析涵盖了电力需求部门的各种电气耦合配置。在专业能源转换软件EnergyPLAN的支持下,以最多样化的方式,考虑到基于加拉帕戈斯群岛可用能源潜力的商业可用技术,以每小时分辨率开发场景。结果表明:(1)单节点系统的决策结果有限;(2)孤立的多节点模型代表了一个更现实的系统,并允许根据当地资源详细确定每个岛屿的能源生产水平;和;(3)当存在电力互联时,岛屿间耦合的最佳解和岛屿间协调共享能量的可能性最大。得出的结论是,实现脱碳系统最合适的技术和经济解决方案是互联、多节点和多部门的系统。这项研究为加拉帕戈斯群岛能源转型的影响提供了更详细的视角。这些结果鼓舞着决策者为保护这个地球上独特的宝藏做出贡献,也被认为是一个活生生的实验室。
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引用次数: 0
Optimization-driven anaerobic digestion of rice straw and potato peel waste for enhanced Biohythane production: A synergistic approach towards lignocellulosic biomass conversion to clean energy 优化驱动的秸秆和马铃薯皮废物厌氧消化以提高生物乙烷的生产:木质纤维素生物质转化为清洁能源的协同方法
IF 9.1 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-04-15 Epub Date: 2026-02-04 DOI: 10.1016/j.renene.2026.125397
Rena , Sunil Kumar , Ken Chiang , Nicky Eshtiaghi
Biohythane production from lignocellulosic biomass such as rice straw (RS) and potato peel waste (PPW) via anaerobic digestion (AD) stands as a viable biotechnological management fostering bioeconomic strategies benefiting the environment. It contributes to Sustainable Development Goals (SDG 7) concerning affordable, clean and renewable energy challenges. This study explores biomass conversion of two lignocellulosic wastes to Biohythane through “Optimization-Driven” AD. RS, a recalcitrant substrate having particle size (<0.425 mm), was co-digested with nutrient-rich co-substrate PPW in four different ratios based on weight/weight of (dry VSsubstrate), along with mixed inoculum anaerobic sludge (AS) and cow dung slurry (CDS) via AD at 11% TS. Batch experiments revealed that the [RSI-PP] ratio [(2:1):1/2] significantly improved yields of cumulative hydrogen (H2) and methane (CH4), viz., 36.98 ± 1.22 mL/g VS and 390.12 ± 3.45 mL/g VS, respectively. The S Gompertz equation exhibited excellent fit (>0.90), underscoring a positive synergy between substrate and co-substrate. The result signifies that RS in combination with PPW with homogenous particle size, mixed inoculum at 11% TS, confirms process stability and positive synergistic effects by providing essential buffer capacity, micronutrients and hydration, thereby enhancing the AD and Biohythane production. The findings of the results support the process's synergistic potential for waste biomass conversion to biofuel.
通过厌氧消化(AD)从木质纤维素生物质(如稻草(RS)和马铃薯皮废物(PPW)中生产生物乙烷是一种可行的生物技术管理,促进有利于环境的生物经济战略。它有助于实现可持续发展目标(可持续发展目标7)关于负担得起的、清洁的和可再生能源的挑战。本研究探讨了通过“优化驱动”AD将两种木质纤维素废弃物转化为生物乙烷。RS是一种粒径为0.425 mm的顽固性底物,与营养丰富的共底物PPW以4种不同的比例(基于(干燥VS底物)的重量/重量),以及混合接种的厌氧污泥(AS)和牛粪浆(CDS)通过AD在11% TS下共消化。批量实验表明,[RSI-PP]比例[(2:1):1/2]显著提高了累计氢气(H2)和甲烷(CH4)的产量,分别为36.98±1.22 mL/g VS和390.12±3.45 mL/g VS。S - Gompertz方程表现出极好的拟合(>0.90),强调了底物和共底物之间的正协同作用。结果表明,RS与均匀粒径、混合接种量为11% TS的PPW组合,通过提供必需的缓冲能力、微量营养素和水化作用,证实了工艺稳定性和正协同效应,从而提高了AD和生物乙烷的产量。研究结果支持了该工艺将废弃生物质转化为生物燃料的协同潜力。
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引用次数: 0
Stepwise multi-objective optimization for high-concentration and uniform four-dish solar concentrators 高浓度均匀四碟太阳能聚光器的逐步多目标优化
IF 9.1 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-04-15 Epub Date: 2026-01-30 DOI: 10.1016/j.renene.2026.125351
Yanlong Zhang , Pengzhen Guo , Mengfan Tian , He Chen , Rongqiang Liu , Zongquan Deng , Lifang Li
The advancement of solar-thermal concentrators requires architectures that combine high flux density, uniform focal distribution, and structural simplicity. However, multi-dish systems often suffer from coupled trade-offs among concentration, spot uniformity, and geometric stability, which can limit thermal efficiency and increase hot-spot risk in high-temperature applications. This study targets this coupled-design challenge by enabling a controllable and robust focal spot in a modular multi-dish architecture. This study presents a four-dish off-axis conjugate concentrator optimized through a global optimization framework that integrates ray-tracing simulations with a unified objective function. The objective is to achieve high effective concentration while simultaneously improving flux uniformity and spot geometry under practical alignment/manufacturing uncertainties. The framework adopts a staged dynamic-weighting strategy to achieve a smooth transition from "energy concentration" to "focal spot quality". Unlike traditional approaches that vary numerous complex structural parameters, the proposed design constrains the optimization space to radial and axial displacement, focal length, and receiver dimensions, thereby simplifying assembly requirements while still enabling high-dimensional exploration of optical behavior. Optimization results demonstrate coordinated improvements across all metrics: the concentrator sustains C95 above the design threshold (Cthreshold= 600), increases spot uniformity from 0.38 to 0.53, reduces RMS radius to 38 mm, and lowers the shape factor to 0.25, yielding a compact and geometrically stable focal spot. Outdoor validation confirmed these findings: under 35 °C and 620 W/m2, the prototype reached 783 °C within 4 s and achieved C95 742, exhibited uniform, repeatable heat maps with strong tolerance to disturbances. These results contribute a four-dish off-axis conjugate architecture that suppresses off-axis aberration-induced spot degradation, and a staged, unified optimization framework that explicitly balances concentration–uniformity–spot geometry with experimental validation, providing a practical pathway toward deployable high-flux multi-dish concentrators.
太阳能热聚光器的发展需要高通量密度、均匀焦点分布和结构简单的结构。然而,在高温应用中,多盘系统经常受到浓度、斑点均匀性和几何稳定性之间的耦合权衡的影响,这可能会限制热效率并增加热点风险。本研究针对这一耦合设计挑战,在模块化多天线架构中实现了可控和鲁棒的焦点。本研究提出了一种四碟离轴共轭聚光器,该聚光器通过整合光线追踪模拟和统一目标函数的全局优化框架进行优化。目标是在实际对准/制造不确定的情况下实现高效浓度,同时改善通量均匀性和光斑几何形状。框架采用阶段性动态加权策略,实现从“能量集中”到“焦点质量”的平稳过渡。与传统方法不同的是,该设计将优化空间限制在径向和轴向位移、焦距和接收器尺寸上,从而简化了组装要求,同时仍然能够对光学行为进行高维探索。优化结果显示了所有指标的协调改进:聚光器保持C95高于设计阈值(Cthreshold= 600),将光斑均匀性从0.38提高到0.53,将RMS半径降低到38 mm,并将形状因子降低到0.25,产生紧凑且几何稳定的焦点光斑。室外验证证实了这些发现:在35°C和620 W/m2的条件下,原型在4 s内达到783°C,达到C95≈742,具有均匀,可重复的热图,对干扰的耐受性强。这些结果提供了一个四碟离轴共轭结构,可以抑制离轴像差引起的光斑退化,以及一个分阶段的、统一的优化框架,明确地平衡了浓度-均匀性-光斑几何形状与实验验证,为可部署的高通量多碟聚光器提供了一条实用的途径。
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引用次数: 0
Adaptive pitch control for power stabilization of floating offshore wind turbines 浮式海上风力发电机功率稳定的自适应俯仰控制
IF 9.1 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-04-15 Epub Date: 2026-02-05 DOI: 10.1016/j.renene.2026.125392
Haorong Ren , Zhe Tian , Lei Han , Songping Meng , Yang Yang
The precise attenuation of wind-wave coupling perturbations on power generation stability constitutes a pivotal element in enhancing the operational efficacy of floating offshore wind turbines. A novel two-stage power stabilization control framework, integrating field data fusion forecasting with adaptive pitch regulation, is proposed to ameliorate coupled hydrodynamic-aerodynamic disturbances. A hybrid forecasting model is leveraged to predict the turbine's power output by discerning nonlinear wind-wave interactions, thereby furnishing preliminary power predictions for the subsequent two-stage variability reduction control. Spectral analysis is exploited to delineate wave-dominant frequencies in the initial stage of the control process, whilst an adaptive moving average algorithm adjusting the smoothing window dimensions dynamically, thereby refining power equilibrium. The second-stage control deploys a dual-mode pitch regulation methodology that distinguishes between two regions autonomously, applying proportional control for small-angle corrections to maximize energy capture beneath rated wind speeds judiciously, whereas constrained pitch control adjustments are activated during wind power ramp events to suppress excessive power slope variations. The robustness of the proposed framework is validated through experimental analysis utilizing offshore wind farm telemetry data, where frequency-domain decomposition reveals that 97.06% of spectral energy remains within aerodynamic-dominant frequencies, suppressing wave-induced oscillations effectively. Quantitative evaluations demonstrate a 95% reduction of wind power ramp events, accompanied by a 43.6% reduction in power slope variability and an 82.9% decrease in pitch actuator interventions.
准确衰减风波耦合扰动对发电稳定性的影响是提高海上浮式风力发电机组运行效率的关键因素。结合现场数据融合预测和自适应螺距调节,提出了一种新型的两级功率稳定控制框架,以改善水动力-气动耦合扰动。利用混合预测模型通过识别非线性风波相互作用来预测涡轮机的输出功率,从而为后续的两阶段变率减小控制提供初步的功率预测。在控制过程的初始阶段,利用频谱分析来描绘波的主导频率,而自适应移动平均算法动态调整平滑窗口的尺寸,从而细化功率平衡。第二阶段控制采用双模式俯仰调节方法,自动区分两个区域,在额定风速下合理地应用比例控制进行小角度校正,以最大限度地获取能量,而在风力坡道事件期间启动受限俯仰控制调节,以抑制过度的功率坡度变化。利用海上风电场遥测数据的实验分析验证了该框架的鲁棒性,其中频域分解显示97.06%的频谱能量保持在空气动力主导频率内,有效地抑制了波浪引起的振荡。定量评估表明,风力坡道事件减少了95%,功率斜率变异性减少了43.6%,俯仰执行器干预减少了82.9%。
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引用次数: 0
Study on a novel phase-change wood roof integrated with diurnal photovoltaic conversion and nocturnal sky radiative cooling 结合昼间光伏转换和夜间天空辐射冷却的新型相变木屋顶的研究
IF 9.1 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-04-15 Epub Date: 2026-02-13 DOI: 10.1016/j.renene.2026.125442
Weikai Wang , Zhen Zhu , Chuting Lai , Huabo Wu , Jie Ji , Niansi Li , Bendong Yu
Wooden buildings offer significant carbon reduction benefits due to their renewable nature. This study develops a phase change wood roof photovoltaic coupling system that lowers panel temperature during the day to maintain efficiency and releases stored heat at night. Using vacuum impregnation, white poplar wood achieved a paraffin loading of 41.6%, with latent heat capacities of 55.9 J/g for phase change material-38 and 54.5 J/g for phase change materia-23. Epoxy encapsulation reduced mass loss from 1.38% to 0.29%. We constructed indoor and outdoor experimental platforms to test phase change materials, showing that phase change materia-23 reduced indoor temperature fluctuations by 2.91 °C, while photovoltaic coupling further alleviated heat retention. In outdoor tests, phase change materia-23 notably lowered the noon peak indoor temperature by 2–3 °C compared to normal wood. At night, the interior wall temperature of photovoltaic phase change wood is 1–2 °C lower than that of photovoltaic normal wood structure buildings. Phase change materia-23 also achieved 13.93% photovoltaic efficiency, 4.81% higher than the reference module. A numerical model predicted that phase change materia-23 reduces annual temperature fluctuations by 4.73 °C in tropical humid climates and phase change materia-38 by 8.07 °C in arid regions.
木制建筑由于其可再生的特性,提供了显著的碳减排效益。本研究开发了一种相变木屋顶光伏耦合系统,该系统在白天降低面板温度以保持效率,并在夜间释放储存的热量。真空浸渍白杨木的石蜡负荷为41.6%,相变材料-38的潜热容量为55.9 J/g,相变材料-23的潜热容量为54.5 J/g。环氧树脂包封将质量损失从1.38%降低到0.29%。我们搭建了室内外实验平台对相变材料进行测试,相变材料-23降低了室内温度波动2.91℃,光伏耦合进一步缓解了蓄热现象。在室外测试中,相变材料-23与普通木材相比,显著降低了室内正午峰值温度2-3℃。夜间,光伏相变木的内墙温度比光伏普通木结构建筑低1-2℃。相变材料-23的光伏效率也达到了13.93%,比参考组件高出4.81%。一个数值模型预测,相变材料-23在热带潮湿气候中将年温度波动降低4.73℃,相变材料-38在干旱地区将年温度波动降低8.07℃。
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引用次数: 0
Porous cubic ZnSnO3 nanocatalysts designed via DC-glow non-thermal plasma-boosted and corn starch derived carbon-template induced co-precipitation manner: Enhanced esterification of oleic acid 采用直流辉光非热等离子体增强和玉米淀粉衍生碳模板诱导共沉淀法设计多孔立方ZnSnO3纳米催化剂:增强油酸的酯化反应
IF 9.1 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-04-15 Epub Date: 2026-01-09 DOI: 10.1016/j.renene.2026.125191
Ali Mohammadi , Mohammad Haghighi , Maryam Shabani , Omid Mohammadi Vaniar
Novel porous cubic ZnSnO3 nanocatalysts designed via co-precipitation manner boosted with corn starch derived carbon-template and DC-glow non-thermal plasma was evaluated as an acidic catalyst in biodiesel production by esterification process. The characterization of the nanocatalysts modified by corn starch derived carbon-template and DC-glow non-thermal plasma technology was performed using XRD, FESEM, BET-BJH, TPD-NH3, 3D texture analysis, TEM and HRTEM techniques. The results showed that the novel modified sample via 10 wt% corn starch derived carbon-template (ZSO (HT = 10 %)), used for the first time in biofuel production, exhibited the best activity (84.8 %). its plasma-treated form (ZSO(HT = 10 %)-P) achieved the highest conversion (90.2 %) in oleic acid esterification. Corn starch derived carbon-template and DC-glow non-thermal plasma have a significant impact on the morphology of ZnSnO3. The sample ZSO(HT = 10 %)-P, in comparison with unmodified ZSO, exhibited higher macropore density, macropore volume (0.2004 cm3/g), mean pore diameter (37.8 nm), and density of acidic sites (17.2 μmol/m2). Also, during 5 periods of repeated use of (ZSO(HT = 10 %)-P), its structure and morphology remained unchanged without any drop in conversion percentage. Finally, the proposed simplified kinetic model and reaction mechanism were investigated and optimized by genetic algorithm across different temperatures and reaction times.
采用玉米淀粉碳模板和直流辉光非热等离子体共沉淀法设计了新型多孔立方ZnSnO3纳米催化剂,并对其作为酯化法制备生物柴油的酸性催化剂进行了研究。采用XRD、FESEM、BET-BJH、TPD-NH3、3D织构分析、TEM和HRTEM等技术对玉米淀粉碳模板和DC-glow非热等离子体技术改性的纳米催化剂进行表征。结果表明,首次应用于生物燃料生产的10 wt%玉米淀粉衍生碳模板(ZSO (HT = 10%))改性后的样品活性最高(84.8%)。其等离子体处理形式(ZSO(HT = 10%)-P)在油酸酯化反应中转化率最高(90.2%)。玉米淀粉碳模板和直流发光非热等离子体对ZnSnO3的形貌有显著影响。与未改性的ZSO相比,改性后的ZSO(HT = 10%)-P样品具有更高的大孔密度、大孔体积(0.2004 cm3/g)、平均孔径(37.8 nm)和酸性位点密度(17.2 μmol/m2)。在5次重复使用(ZSO(HT = 10%)-P)期间,其结构和形态保持不变,转化率没有下降。最后,利用遗传算法对所提出的简化动力学模型和反应机理进行了研究,并对不同温度和反应时间下的反应机理进行了优化。
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Renewable Energy
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