首页 > 最新文献

Science Bulletin最新文献

英文 中文
High-loading single-atom photocatalysts for high-selectivity conversion of CO2 to ethanol. 高负荷单原子光催化剂用于高选择性CO2转化为乙醇。
IF 21.1 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2026-01-09 DOI: 10.1016/j.scib.2026.01.007
Long-Shuai Zhang, Feiyao Wu, Shenrui Liang, Qianqian Tang, Hui Li, Huang Zhou, Fanqi Meng, Xunheng Jiang, Haiyan Liu, Qing Sun, Meifeng Wu, Yitao Cui, Weili Dai, Tianyi Ma, Yuen Wu, Jian-Ping Zou
{"title":"High-loading single-atom photocatalysts for high-selectivity conversion of CO<sub>2</sub> to ethanol.","authors":"Long-Shuai Zhang, Feiyao Wu, Shenrui Liang, Qianqian Tang, Hui Li, Huang Zhou, Fanqi Meng, Xunheng Jiang, Haiyan Liu, Qing Sun, Meifeng Wu, Yitao Cui, Weili Dai, Tianyi Ma, Yuen Wu, Jian-Ping Zou","doi":"10.1016/j.scib.2026.01.007","DOIUrl":"https://doi.org/10.1016/j.scib.2026.01.007","url":null,"abstract":"","PeriodicalId":421,"journal":{"name":"Science Bulletin","volume":" ","pages":""},"PeriodicalIF":21.1,"publicationDate":"2026-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146040144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A fast powerful X-ray transient from possible tidal disruption of a white dwarf. 一颗白矮星可能的潮汐崩解产生的快速、强大的x射线瞬变。
IF 21.1 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2026-01-08 DOI: 10.1016/j.scib.2025.12.050
Dongyue Li, Wenda Zhang, Jun Yang, Jin-Hong Chen, Weimin Yuan, Huaqing Cheng, Fan Xu, Xinwen Shu, Rong-Feng Shen, Ning Jiang, Jiazheng Zhu, Chang Zhou, Weihua Lei, Hui Sun, Chichuan Jin, Lixin Dai, Bing Zhang, Yu-Han Yang, Wenjie Zhang, Hua Feng, Bifang Liu, Hongyan Zhou, Haiwu Pan, Mingjun Liu, Stéphane Corbel, Sitha K Jagan, Maria Cristina Baglio, Christopher R Burns, Floriane Cangemi, Chun Chen, Yehao Cheng, Alexis Coleiro, Francesco Coti Zelati, Sourya R Das, Zhongnan Dong, Luis Galbany, Noa Grollimund, Daniel Kelson, Dong Lai, Xia Li, Yuan Liu, Alessio Marino, Brenna Mockler, Paul O'Brien, Erlin Qiao, Nanda Rea, L Resmi, Jérome Rodriguez, Richard Saxton, Luming Sun, Lian Tao, Tinggui Wang, Yilong Wang, Xuefeng Wu, Dong Xu, Yijia Zhang, Guoying Zhao, Congying Bao, Zhiming Cai, Yehai Chen, Yong Chen, Bertrand Cordier, Chenzhou Cui, Weiwei Cui, Zhou Fan, He Gao, Giancarlo Ghirlanda, Ju Guan, Dawei Han, Jinxin Hao, Jingwei Hu, Maohai Huang, Yong-Feng Huang, Shumei Jia, Ge Jin, Stefanie Komossa, Chengkui Li, Zhixing Ling, Congzhan Liu, Heyang Liu, Huaqiu Liu, Fangjun Lu, Kirpal Nandra, Jan-Uwe Ness, Arne Rau, Jeremy Sanders, Liming Song, Roberto Soria, Shengli Sun, Xiaojin Sun, Yuyin Tan, Eleonora Troja, Sixiang Wen, Haitao Xu, Changbin Xue, Yongquan Xue, Yi-Han Iris Yin, Chen Zhang, Shuang-Nan Zhang, Yonghe Zhang

Stars getting close enough to black holes (BHs) can be torn apart by strong tidal forces, producing electromagnetic flares. To date, more than 100 tidal disruption events (TDEs) have been observed, each involving invariably normal gaseous stars whose debris falls onto the BH, sustaining the flares over years. White dwarfs (WDs), which are the most prevalent compact stars and a million times denser-and therefore tougher-than gaseous stars, can only be disrupted by intermediate-mass black holes (IMBHs) of 102-105 solar masses. WD-TDEs are considered to generate more powerful and short-lived flares, but their evidence has been lacking. Here we report observations of a fast and luminous X-ray transient EP250702a detected by Einstein Probe. Its one-day-long X-ray peak as luminous as 1047-49ergs-1showed strong recurrent flares with hard spectra extending to several tens of MeV gamma-rays, as detected by Fermi/GBM and Konus-Wind, indicating relativistic jet emission. The jet's X-rays dropped sharply from 3×1049ergs-1 to around 1044ergs-1within 20 days (10 days in the source rest frame). These characteristics are inconsistent with any previously known transient phenomena. We suggest that this fast-evolving event over the unprecedentedly short timescale arises likely from disruption of a WD by an IMBH. At late times, a soft component progressively dominates the X-ray spectrum, reaching a luminosity as high as 1044 erg s-1, which is consistent with being extreme super-Eddington emission from an accretion disk expected to form in an IMBH-WD TDE. WD-TDEs open a new window for investigating the elusive IMBHs and their surrounding stellar environments, and they are prime sources of gravitational waves in the band of space-based interferometers.

离黑洞足够近的恒星会被强大的潮汐力撕裂,产生电磁耀斑。迄今为止,已经观测到100多次潮汐破坏事件(tde),每次都涉及到正常的气态恒星,它们的碎片落在黑洞上,耀斑持续多年。白矮星(WDs)是最普遍的致密恒星,密度是气态恒星的100万倍,因此比气态恒星更坚硬,只有102-105太阳质量的中等质量黑洞(IMBHs)才能破坏白矮星。wd - tde被认为产生更强大和更短暂的耀斑,但缺乏证据。在这里,我们报告了爱因斯坦探测器探测到的快速发光x射线瞬态EP250702a的观测结果。Fermi/GBM和Konus-Wind探测到,它长达一天的x射线峰亮度为1047-49ergs-1,显示出强烈的周期性耀斑,其硬光谱延伸到几十MeV的伽马射线,表明相对论性喷流发射。喷气机的x射线在20天内从3×1049ergs-1急剧下降到1044ergs-1左右(在源静止帧中为10天)。这些特征与以往任何已知的瞬态现象都不一致。我们认为,这一快速演变的事件在前所未有的短时间内可能是由IMBH对WD的破坏引起的。在后期,软成分逐渐主导x射线光谱,亮度高达1044 erg - s-1,这与IMBH-WD TDE中预计形成的吸积盘的极端超级爱丁顿辐射相一致。wd - tde为研究难以捉摸的IMBHs及其周围的恒星环境打开了一个新的窗口,它们是天基干涉仪波段引力波的主要来源。
{"title":"A fast powerful X-ray transient from possible tidal disruption of a white dwarf.","authors":"Dongyue Li, Wenda Zhang, Jun Yang, Jin-Hong Chen, Weimin Yuan, Huaqing Cheng, Fan Xu, Xinwen Shu, Rong-Feng Shen, Ning Jiang, Jiazheng Zhu, Chang Zhou, Weihua Lei, Hui Sun, Chichuan Jin, Lixin Dai, Bing Zhang, Yu-Han Yang, Wenjie Zhang, Hua Feng, Bifang Liu, Hongyan Zhou, Haiwu Pan, Mingjun Liu, Stéphane Corbel, Sitha K Jagan, Maria Cristina Baglio, Christopher R Burns, Floriane Cangemi, Chun Chen, Yehao Cheng, Alexis Coleiro, Francesco Coti Zelati, Sourya R Das, Zhongnan Dong, Luis Galbany, Noa Grollimund, Daniel Kelson, Dong Lai, Xia Li, Yuan Liu, Alessio Marino, Brenna Mockler, Paul O'Brien, Erlin Qiao, Nanda Rea, L Resmi, Jérome Rodriguez, Richard Saxton, Luming Sun, Lian Tao, Tinggui Wang, Yilong Wang, Xuefeng Wu, Dong Xu, Yijia Zhang, Guoying Zhao, Congying Bao, Zhiming Cai, Yehai Chen, Yong Chen, Bertrand Cordier, Chenzhou Cui, Weiwei Cui, Zhou Fan, He Gao, Giancarlo Ghirlanda, Ju Guan, Dawei Han, Jinxin Hao, Jingwei Hu, Maohai Huang, Yong-Feng Huang, Shumei Jia, Ge Jin, Stefanie Komossa, Chengkui Li, Zhixing Ling, Congzhan Liu, Heyang Liu, Huaqiu Liu, Fangjun Lu, Kirpal Nandra, Jan-Uwe Ness, Arne Rau, Jeremy Sanders, Liming Song, Roberto Soria, Shengli Sun, Xiaojin Sun, Yuyin Tan, Eleonora Troja, Sixiang Wen, Haitao Xu, Changbin Xue, Yongquan Xue, Yi-Han Iris Yin, Chen Zhang, Shuang-Nan Zhang, Yonghe Zhang","doi":"10.1016/j.scib.2025.12.050","DOIUrl":"https://doi.org/10.1016/j.scib.2025.12.050","url":null,"abstract":"<p><p>Stars getting close enough to black holes (BHs) can be torn apart by strong tidal forces, producing electromagnetic flares. To date, more than 100 tidal disruption events (TDEs) have been observed, each involving invariably normal gaseous stars whose debris falls onto the BH, sustaining the flares over years. White dwarfs (WDs), which are the most prevalent compact stars and a million times denser-and therefore tougher-than gaseous stars, can only be disrupted by intermediate-mass black holes (IMBHs) of 10<sup>2</sup>-10<sup>5</sup> solar masses. WD-TDEs are considered to generate more powerful and short-lived flares, but their evidence has been lacking. Here we report observations of a fast and luminous X-ray transient EP250702a detected by Einstein Probe. Its one-day-long X-ray peak as luminous as 10<sup>47-49</sup>ergs<sup>-1</sup>showed strong recurrent flares with hard spectra extending to several tens of MeV gamma-rays, as detected by Fermi/GBM and Konus-Wind, indicating relativistic jet emission. The jet's X-rays dropped sharply from 3×10<sup>49</sup>ergs<sup>-1</sup> to around 10<sup>44</sup>ergs<sup>-1</sup>within 20 days (10 days in the source rest frame). These characteristics are inconsistent with any previously known transient phenomena. We suggest that this fast-evolving event over the unprecedentedly short timescale arises likely from disruption of a WD by an IMBH. At late times, a soft component progressively dominates the X-ray spectrum, reaching a luminosity as high as 10<sup>44</sup> erg s<sup>-1</sup>, which is consistent with being extreme super-Eddington emission from an accretion disk expected to form in an IMBH-WD TDE. WD-TDEs open a new window for investigating the elusive IMBHs and their surrounding stellar environments, and they are prime sources of gravitational waves in the band of space-based interferometers.</p>","PeriodicalId":421,"journal":{"name":"Science Bulletin","volume":" ","pages":""},"PeriodicalIF":21.1,"publicationDate":"2026-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146008406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to "Engineered platelets-based nano-aircraft system for precise tumor chemo-immunotherapy with graded drug delivery and self-recognized tumor targeting" [Sci. Bull. 70(9) (2025) 1462-1477]. “基于工程血小板的纳米飞机系统用于精确的肿瘤化学免疫治疗,具有分级给药和自我识别的肿瘤靶向”的更正。牛。70(9)(2025)1462-1477]。
IF 21.1 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2026-01-06 DOI: 10.1016/j.scib.2026.01.001
Meijuan Geng, Huiping Du, Xuan Wei, Siyu Chen, Jiamin Cheng, Siyu Meng, Liyang Gong, Hui Yang, Kaiyong Cai, Liangliang Dai
{"title":"Corrigendum to \"Engineered platelets-based nano-aircraft system for precise tumor chemo-immunotherapy with graded drug delivery and self-recognized tumor targeting\" [Sci. Bull. 70(9) (2025) 1462-1477].","authors":"Meijuan Geng, Huiping Du, Xuan Wei, Siyu Chen, Jiamin Cheng, Siyu Meng, Liyang Gong, Hui Yang, Kaiyong Cai, Liangliang Dai","doi":"10.1016/j.scib.2026.01.001","DOIUrl":"https://doi.org/10.1016/j.scib.2026.01.001","url":null,"abstract":"","PeriodicalId":421,"journal":{"name":"Science Bulletin","volume":" ","pages":""},"PeriodicalIF":21.1,"publicationDate":"2026-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146008376","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An ultrasoft, breathable, and multichannel ear-computer interface patch. 一种超软,透气,多通道耳机接口贴片。
IF 21.1 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2026-01-02 DOI: 10.1016/j.scib.2025.12.042
Ying Sun, Weijia Liu, Hao Zhang, Zhijian Du, Haiqing Liu, Kang Ma, Dapeng Li, Shuai Wang, Shangchun Fan, La Li, Dezhi Zheng, Guozhen Shen

Brain-computer interface (BCI) presented by the non-invasive electroencephalography (EEG) cap/band or implantable chips enabling people to fast and reliable control computers or mobile devices with thoughts has redefined the boundaries of human capabilities. However, the existing cap/band-adhered sticky gel usually needs to be tightly fixed on the scalp through the hair to ensure intimate contact, which inconveniences the user. And the implantable chips represented by Neuralink gave a living example of how BCI can make quadriplegic live better, but the destructive unacceptable for healthy people. Here we proposed a multichannel wearable ear-computer interface (ECI) patch worn behind the ears for direct communication and control via brain activity. The 8-channel ECI patch based on MXene electrode was prepared by a facile direct inject print approach on the soft, thin, and breathable medical film that enables superior adherence. The fatigue induction experiments tested by the ECI patch offer an average classification accuracy of 90.5%, showing effective monitoring of the fatigue state. Participants wearing the ECI patch also perform the 4-target steady state visual evoked potential (SSVEP) BCI classification offline and online experiment, the online 4-route tasks reap a comparable average accuracy of 93.5% to the commercial cap. Moreover, the complex route task relied on the subjects who gave commands while observing the unmanned vehicle completed 3 times, demonstrating the reliability and possibility of the ECI patch.

以无创脑电图(EEG)帽/带或植入式芯片为代表的脑机接口(BCI)使人们能够快速可靠地用思想控制计算机或移动设备,重新定义了人类能力的界限。然而,现有的帽/带粘胶通常需要通过头发紧紧固定在头皮上,以保证亲密接触,这给使用者带来了不便。以Neuralink为代表的植入式芯片给了一个活生生的例子,说明脑机接口如何使四肢瘫痪的人生活得更好,但对健康的人来说,破坏性是不可接受的。在这里,我们提出了一种多通道可穿戴耳机接口(ECI)贴片,佩戴在耳后,通过大脑活动进行直接通信和控制。基于MXene电极的8通道ECI贴片是通过简单的直接注射打印方法在柔软、薄、透气的医用薄膜上制备的,具有优异的粘附性。ECI贴片测试的疲劳诱导实验平均分类准确率为90.5%,显示出对疲劳状态的有效监测。佩戴ECI贴片的参与者还进行了4目标稳态视觉诱发电位(SSVEP) BCI分类离线和在线实验,在线4路线任务的平均准确率与商业帽相当,达到93.5%。此外,复杂路线任务依赖于受试者在观察无人驾驶车辆的同时完成3次命令,证明了ECI贴片的可靠性和可能性。
{"title":"An ultrasoft, breathable, and multichannel ear-computer interface patch.","authors":"Ying Sun, Weijia Liu, Hao Zhang, Zhijian Du, Haiqing Liu, Kang Ma, Dapeng Li, Shuai Wang, Shangchun Fan, La Li, Dezhi Zheng, Guozhen Shen","doi":"10.1016/j.scib.2025.12.042","DOIUrl":"https://doi.org/10.1016/j.scib.2025.12.042","url":null,"abstract":"<p><p>Brain-computer interface (BCI) presented by the non-invasive electroencephalography (EEG) cap/band or implantable chips enabling people to fast and reliable control computers or mobile devices with thoughts has redefined the boundaries of human capabilities. However, the existing cap/band-adhered sticky gel usually needs to be tightly fixed on the scalp through the hair to ensure intimate contact, which inconveniences the user. And the implantable chips represented by Neuralink gave a living example of how BCI can make quadriplegic live better, but the destructive unacceptable for healthy people. Here we proposed a multichannel wearable ear-computer interface (ECI) patch worn behind the ears for direct communication and control via brain activity. The 8-channel ECI patch based on MXene electrode was prepared by a facile direct inject print approach on the soft, thin, and breathable medical film that enables superior adherence. The fatigue induction experiments tested by the ECI patch offer an average classification accuracy of 90.5%, showing effective monitoring of the fatigue state. Participants wearing the ECI patch also perform the 4-target steady state visual evoked potential (SSVEP) BCI classification offline and online experiment, the online 4-route tasks reap a comparable average accuracy of 93.5% to the commercial cap. Moreover, the complex route task relied on the subjects who gave commands while observing the unmanned vehicle completed 3 times, demonstrating the reliability and possibility of the ECI patch.</p>","PeriodicalId":421,"journal":{"name":"Science Bulletin","volume":" ","pages":""},"PeriodicalIF":21.1,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146017031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modulation of the nanoscale chimney effect in metal-organic frameworks enables efficient guest diffusion and separation. 调制纳米级烟囱效应在金属有机框架实现有效的客体扩散和分离。
IF 21.1 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2026-01-02 DOI: 10.1016/j.scib.2025.12.049
Sha-Sha Meng, Hanxi Guan, Han Yang, Hai-Yue Wei, Mo-Han Gu, Jian Zhang, Ming Xu, Lina Wu, Zhi-Yuan Gu
{"title":"Modulation of the nanoscale chimney effect in metal-organic frameworks enables efficient guest diffusion and separation.","authors":"Sha-Sha Meng, Hanxi Guan, Han Yang, Hai-Yue Wei, Mo-Han Gu, Jian Zhang, Ming Xu, Lina Wu, Zhi-Yuan Gu","doi":"10.1016/j.scib.2025.12.049","DOIUrl":"https://doi.org/10.1016/j.scib.2025.12.049","url":null,"abstract":"","PeriodicalId":421,"journal":{"name":"Science Bulletin","volume":" ","pages":""},"PeriodicalIF":21.1,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146027956","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Organic chemicals of Arctic concern in Russian coastal seas. 俄罗斯沿海海域的北极问题有机化学品。
IF 21.1 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-12-31 DOI: 10.1016/j.scib.2025.12.054
Xi-Ze Min, Xianming Zhang, Zhi-Yong Xie, Anatoly Nikolaev, Katrin Vorkamp, Jian-Min Ma, Lars-Otto Reiersen, Li Li, Ming-Hong Cai, Nan-Qi Ren, Yi-Fan Li, Zi-Feng Zhang, Roland Kallenborn, Derek Muir

Arctic ecosystems face significant threats from chemicals of global concern. Persistent organic pollutants (POPs) and polycyclic aromatic hydrocarbons (PAHs) have been consistently detected in the Arctic through decades of monitoring. POPs are known to bioaccumulate in food webs, and both POPs and PAHs are toxic posing risks to wildlife and human health. While regular monitoring activities have been implemented in most Arctic countries, information from the Russian Arctic is still limited. This review synthesizes the existing knowledge on environmental fate and distribution pathways of POPs, PAHs, and Chemicals Of Emerging Arctic Concern (CEACs) in the Russian Arctic. Except for recent studies on microplastics, data on CEACs remain very limited. Considering mass exchange processes between environmental compartments, including the cryosphere, this review focuses on the Russian Arctic coastal seas, where riverine transport and atmospheric deposition are the main sources of legacy POPs and PAHs. Northward-draining Russian Arctic rivers have been loading legacy POPs from historical sources to coastal seawater. Ongoing volatilization of low-molecular-weight PAHs from both sediments and seawater in the Russian Arctic coastal seas is likely to be accelerated with the ongoing warming climate. PAH and POPs stored in the cryosphere of the Russian Arctic are expected to be released with the ice/snow melting and permafrost thaws. However, more up-to-date information on these chemicals is needed to evaluate these processes and their significance for Arctic pollution.

北极生态系统面临着全球关注的化学品的重大威胁。通过几十年的监测,北极地区一直检测到持久性有机污染物(POPs)和多环芳烃(PAHs)。众所周知,持久性有机污染物会在食物网中生物积累,持久性有机污染物和多环芳烃都是有毒的,对野生动物和人类健康构成风险。虽然在大多数北极国家开展了定期监测活动,但来自俄罗斯北极的信息仍然有限。本文综述了俄罗斯北极地区持久性有机污染物、多环芳烃和新兴北极关注化学品(CEACs)的环境命运和分布途径的现有知识。除了最近对微塑料的研究外,关于ceac的数据仍然非常有限。考虑到包括冰冻圈在内的环境区域之间的物质交换过程,本综述将重点放在俄罗斯北极沿海海域,在那里,河流运输和大气沉积是遗留的持久性有机污染物和多环芳烃的主要来源。向北排水的俄罗斯北极河流将历史上遗留下来的持久性有机污染物装载到沿海海水中。俄罗斯北极沿海沉积物和海水中低分子量多环芳烃的持续挥发可能会随着持续变暖的气候而加速。储存在俄罗斯北极冰冻圈的多环芳烃和持久性有机污染物预计将随着冰雪融化和永久冻土融化而释放。然而,需要更多关于这些化学物质的最新信息来评价这些过程及其对北极污染的意义。
{"title":"Organic chemicals of Arctic concern in Russian coastal seas.","authors":"Xi-Ze Min, Xianming Zhang, Zhi-Yong Xie, Anatoly Nikolaev, Katrin Vorkamp, Jian-Min Ma, Lars-Otto Reiersen, Li Li, Ming-Hong Cai, Nan-Qi Ren, Yi-Fan Li, Zi-Feng Zhang, Roland Kallenborn, Derek Muir","doi":"10.1016/j.scib.2025.12.054","DOIUrl":"https://doi.org/10.1016/j.scib.2025.12.054","url":null,"abstract":"<p><p>Arctic ecosystems face significant threats from chemicals of global concern. Persistent organic pollutants (POPs) and polycyclic aromatic hydrocarbons (PAHs) have been consistently detected in the Arctic through decades of monitoring. POPs are known to bioaccumulate in food webs, and both POPs and PAHs are toxic posing risks to wildlife and human health. While regular monitoring activities have been implemented in most Arctic countries, information from the Russian Arctic is still limited. This review synthesizes the existing knowledge on environmental fate and distribution pathways of POPs, PAHs, and Chemicals Of Emerging Arctic Concern (CEACs) in the Russian Arctic. Except for recent studies on microplastics, data on CEACs remain very limited. Considering mass exchange processes between environmental compartments, including the cryosphere, this review focuses on the Russian Arctic coastal seas, where riverine transport and atmospheric deposition are the main sources of legacy POPs and PAHs. Northward-draining Russian Arctic rivers have been loading legacy POPs from historical sources to coastal seawater. Ongoing volatilization of low-molecular-weight PAHs from both sediments and seawater in the Russian Arctic coastal seas is likely to be accelerated with the ongoing warming climate. PAH and POPs stored in the cryosphere of the Russian Arctic are expected to be released with the ice/snow melting and permafrost thaws. However, more up-to-date information on these chemicals is needed to evaluate these processes and their significance for Arctic pollution.</p>","PeriodicalId":421,"journal":{"name":"Science Bulletin","volume":" ","pages":""},"PeriodicalIF":21.1,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146027811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Frequent weak seismic shakings affect landslide occurrence and threaten 20% of Nepal's population. 频繁的弱地震震动影响了山体滑坡的发生,并威胁到尼泊尔20%的人口。
IF 21.1 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-12-31 DOI: 10.1016/j.scib.2025.12.057
Fang Chen, Bo Yu, Huadong Guo, Pascal Lacroix, Noélie Bontemps, Shengwen Qi, Umesh K Haritashya, Jeffrey S Kargel, Ni Huang, Lei Wang
{"title":"Frequent weak seismic shakings affect landslide occurrence and threaten 20% of Nepal's population.","authors":"Fang Chen, Bo Yu, Huadong Guo, Pascal Lacroix, Noélie Bontemps, Shengwen Qi, Umesh K Haritashya, Jeffrey S Kargel, Ni Huang, Lei Wang","doi":"10.1016/j.scib.2025.12.057","DOIUrl":"https://doi.org/10.1016/j.scib.2025.12.057","url":null,"abstract":"","PeriodicalId":421,"journal":{"name":"Science Bulletin","volume":" ","pages":""},"PeriodicalIF":21.1,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146027805","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tuning Ni-O orbital interactions to steer oxygen activation for enhanced hydrogen peroxide photosynthesis. 调整Ni-O轨道相互作用以引导氧活化以增强过氧化氢光合作用。
IF 21.1 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-12-31 DOI: 10.1016/j.scib.2025.12.053
Chao Xing, Yunjie Zou, Longjie Liu, Dongdong Chu, Dayu Sun, Qi Cheng, Wenhai Chu, Lan Ling

Nickel-based co-catalysts are attractive candidates for H2O2 photosynthesis via the two-electron oxygen reduction reaction (2e- ORR). However, inherently strong O2 adsorption and overactivation at Ni sites promote undesired O-O bond cleavage, compromising both selectivity and activity. Here, we introduce an orbital-level modulation strategy that tailors O2 activation at Ni centers by tuning the Ni 3d-O 2p interactions through atomic ligand regulation. Specifically, incorporation of electronegative phosphorus ligands into Ni-decorated poly(triazine imide) (Ni/PTI) reconfigures the Ni 3d orbital distribution, constructing Ni2P/PTI that suppresses excessive O2 activation and reverses the H2O2 decomposition observed in Ni/PTI. This strategy achieves a 4.7-fold enhancement in H2O2 production under visible light in pure water. Mechanistically, phosphorus-mediated electronic tuning diminishes Ni 3 dyz orbital contributions to O2 π* antibonding orbitals, thereby preventing O-O bond cleavage and stabilizing key intermediates. Concurrently, phosphorus-induced Ni coordination adjustment promotes *OOH protonation and inhibits H2O2 decomposition, jointly reinforcing 2e- ORR selectivity and efficiency. These findings establish atomic ligand-driven orbital modulation as a powerful principle for steering O2 activation on Ni-based co-catalysts, offering a blueprint for designing transition-metal sites with optimized electronic structures and coordination environments for efficient H2O2 photosynthesis.

镍基助催化剂是通过双电子氧还原反应(2e- ORR)进行H2O2光合作用的有吸引力的候选催化剂。然而,固有的强氧吸附和Ni位点的过度活化会促进不希望的O-O键裂解,从而损害选择性和活性。在这里,我们引入了一种轨道级调制策略,通过原子配体调节Ni 3d- o2p相互作用来调整Ni中心的O2活化。具体来说,将电负性磷配体掺入Ni修饰的聚(三嗪亚胺)(Ni/PTI)中,重新配置了Ni的三维轨道分布,构建了Ni2P/PTI,抑制了过量的O2活化,逆转了Ni/PTI中观察到的H2O2分解。该策略在可见光下的纯水中H2O2产量提高了4.7倍。在机制上,磷介导的电子调谐减少了Ni 3dyz轨道对O2 π*反键轨道的贡献,从而阻止了O-O键的裂解并稳定了关键中间体。同时,磷诱导的Ni配位调节促进*OOH质子化,抑制H2O2分解,共同增强2e- ORR的选择性和效率。这些发现确立了原子配体驱动的轨道调制是控制ni基共催化剂上O2活化的有力原理,为设计具有优化电子结构和配位环境的过渡金属位点以实现高效H2O2光合作用提供了蓝图。
{"title":"Tuning Ni-O orbital interactions to steer oxygen activation for enhanced hydrogen peroxide photosynthesis.","authors":"Chao Xing, Yunjie Zou, Longjie Liu, Dongdong Chu, Dayu Sun, Qi Cheng, Wenhai Chu, Lan Ling","doi":"10.1016/j.scib.2025.12.053","DOIUrl":"https://doi.org/10.1016/j.scib.2025.12.053","url":null,"abstract":"<p><p>Nickel-based co-catalysts are attractive candidates for H<sub>2</sub>O<sub>2</sub> photosynthesis via the two-electron oxygen reduction reaction (2e<sup>-</sup> ORR). However, inherently strong O<sub>2</sub> adsorption and overactivation at Ni sites promote undesired O-O bond cleavage, compromising both selectivity and activity. Here, we introduce an orbital-level modulation strategy that tailors O<sub>2</sub> activation at Ni centers by tuning the Ni 3d-O 2p interactions through atomic ligand regulation. Specifically, incorporation of electronegative phosphorus ligands into Ni-decorated poly(triazine imide) (Ni/PTI) reconfigures the Ni 3d orbital distribution, constructing Ni<sub>2</sub>P/PTI that suppresses excessive O<sub>2</sub> activation and reverses the H<sub>2</sub>O<sub>2</sub> decomposition observed in Ni/PTI. This strategy achieves a 4.7-fold enhancement in H<sub>2</sub>O<sub>2</sub> production under visible light in pure water. Mechanistically, phosphorus-mediated electronic tuning diminishes Ni 3 d<sub>yz</sub> orbital contributions to O<sub>2</sub> π* antibonding orbitals, thereby preventing O-O bond cleavage and stabilizing key intermediates. Concurrently, phosphorus-induced Ni coordination adjustment promotes *OOH protonation and inhibits H<sub>2</sub>O<sub>2</sub> decomposition, jointly reinforcing 2e<sup>-</sup> ORR selectivity and efficiency. These findings establish atomic ligand-driven orbital modulation as a powerful principle for steering O<sub>2</sub> activation on Ni-based co-catalysts, offering a blueprint for designing transition-metal sites with optimized electronic structures and coordination environments for efficient H<sub>2</sub>O<sub>2</sub> photosynthesis.</p>","PeriodicalId":421,"journal":{"name":"Science Bulletin","volume":" ","pages":""},"PeriodicalIF":21.1,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145964759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optical spin Hall effect driven by hybrid spin-orbit coupling in organic microcavities. 有机微腔中杂化自旋轨道耦合驱动的光自旋霍尔效应。
IF 21.1 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-12-31 DOI: 10.1016/j.scib.2025.12.056
Yongsheng Hu, Yuanjun Guan, Teng Long, Wei Xie, Hongxing Xu, Qing Liao, Zheng Sun, Jian Wu

The optical spin Hall effect (OSHE) bridges photonics and spintronics by enabling spin-dependent manipulation of light-where the "spin" of light refers to its polarization state-which is critical for on-chip photonic technologies. While OSHE with distinct topological textures has been demonstrated separately using transverse electric-transverse magnetic (TE-TM) splitting or birefringent crystals, achieving multiple spin textures within a single system remains elusive. Here, we report the first observation of OSHE driven by the interplay between TE-TM splitting and Rashba-Dresselhaus spin-orbit coupling (RDSOC) in an organic microcavity at room temperature. Polarization-resolved measurements reveal hybrid spin textures: quadrupole patterns at high momenta from TE-TM splitting and mirror-symmetric textures at low momenta from RDSOC. This interplay generates a persistent spin bias with a polarization lifetime of ∼300 ps, indicating robust spin coherence for stable spin-photonic and polarization-preserving devices. Our findings establish organic microcavities as versatile platforms for engineering hybrid spin-orbit coupling, advancing topological photonics and integrated spin-based information processing.

光自旋霍尔效应(OSHE)通过实现光的自旋依赖操纵来架起光子学和自旋电子学的桥梁,其中光的“自旋”指的是它的偏振态,这对片上光子技术至关重要。虽然具有不同拓扑结构的OSHE已经分别使用横向电-横向磁(TE-TM)分裂或双折射晶体进行了演示,但在单个系统中实现多个自旋结构仍然是难以捉摸的。本文报道了在室温下有机微腔中TE-TM分裂和Rashba-Dresselhaus自旋轨道耦合(RDSOC)相互作用驱动的OSHE的首次观测。偏振分辨测量揭示了混合自旋纹理:TE-TM分裂在高动量下的四极模式和RDSOC在低动量下的镜像对称纹理。这种相互作用产生了持续的自旋偏置,其偏振寿命为~ 300 ps,表明稳定的自旋光子和偏振保持器件具有强大的自旋相干性。我们的发现建立了有机微腔作为工程混合自旋轨道耦合的通用平台,推进了拓扑光子学和基于自旋的集成信息处理。
{"title":"Optical spin Hall effect driven by hybrid spin-orbit coupling in organic microcavities.","authors":"Yongsheng Hu, Yuanjun Guan, Teng Long, Wei Xie, Hongxing Xu, Qing Liao, Zheng Sun, Jian Wu","doi":"10.1016/j.scib.2025.12.056","DOIUrl":"https://doi.org/10.1016/j.scib.2025.12.056","url":null,"abstract":"<p><p>The optical spin Hall effect (OSHE) bridges photonics and spintronics by enabling spin-dependent manipulation of light-where the \"spin\" of light refers to its polarization state-which is critical for on-chip photonic technologies. While OSHE with distinct topological textures has been demonstrated separately using transverse electric-transverse magnetic (TE-TM) splitting or birefringent crystals, achieving multiple spin textures within a single system remains elusive. Here, we report the first observation of OSHE driven by the interplay between TE-TM splitting and Rashba-Dresselhaus spin-orbit coupling (RDSOC) in an organic microcavity at room temperature. Polarization-resolved measurements reveal hybrid spin textures: quadrupole patterns at high momenta from TE-TM splitting and mirror-symmetric textures at low momenta from RDSOC. This interplay generates a persistent spin bias with a polarization lifetime of ∼300 ps, indicating robust spin coherence for stable spin-photonic and polarization-preserving devices. Our findings establish organic microcavities as versatile platforms for engineering hybrid spin-orbit coupling, advancing topological photonics and integrated spin-based information processing.</p>","PeriodicalId":421,"journal":{"name":"Science Bulletin","volume":" ","pages":""},"PeriodicalIF":21.1,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146017001","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bridging social-ecological impacts of protected area strategy through ecosystem services. 通过生态系统服务弥合保护区战略的社会生态影响。
IF 21.1 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-12-31 DOI: 10.1016/j.scib.2025.12.055
Hong Jiang, Jian Peng, Zihan Xu
{"title":"Bridging social-ecological impacts of protected area strategy through ecosystem services.","authors":"Hong Jiang, Jian Peng, Zihan Xu","doi":"10.1016/j.scib.2025.12.055","DOIUrl":"https://doi.org/10.1016/j.scib.2025.12.055","url":null,"abstract":"","PeriodicalId":421,"journal":{"name":"Science Bulletin","volume":" ","pages":""},"PeriodicalIF":21.1,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146040164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Science Bulletin
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1