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Feature review of photovoltaic modeling software utilizing blind performance assessment 基于盲性能评估的光伏建模软件特点综述
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1016/j.solener.2025.114207
Lelia Deville , Kevin S. Anderson , Juergen Sutterlueti , Terrence L. Chambers , Karel De Brabandere , Felix Perez Cicala , Javier Lopez-Lorente , Brian Mirletz , Anja Neubert , Maitheli Nikam , Michele Oliosi , Matthew Prilliman , Kurt Rhee , Branislav Schnierer , Jason Spokes , Bruno Wittmer , Marios Theristis
While confidence in photovoltaic (PV) modeling software has always been essential, the rapid pace of new PV plant developments makes accuracy and credibility more critical than ever. Independent assessments, particularly through blind modeling comparisons, are therefore necessary to ensure unbiased benchmarking across PV modeling software. Previous studies have been limited by a narrow range of models compared, anonymized results, or system size. This study presents results from the first-ever onymous blind modeling comparison, evaluated using both lab- and utility-scale fixed-tilt, monofacial, south-facing systems at sub-hourly time intervals. Seven commercially used PV software tools were compared: 3E SynaptiQ, PlantPredict, PVsyst, RatedPower, SAM, SolarFarmer, and Solargis Evaluate. Predictions were submitted directly by software representatives, providing unique insights into each software’s implementation and resulting prediction behavior. Notable features, including plane-of-array (POA) transposition model, module temperature model, shading model, and performance model were analyzed and compared. Four summary tables compile these features of the software, serving as a resource to help users understand the methodological differences and select the most suitable software for their applications. The software tools show deviations from mean error in annual yield up to 2.5 % in the lab-scale system, increasing to 6.0 % for the utility-scale system. These differences arise from a combination of user decisions and the inherent behavior of the software, indicating the need for continuous and rigorous validation of modeling methods using these software tools against complex, real-world systems.
虽然对光伏(PV)建模软件的信心一直是必不可少的,但新光伏电站发展的快速步伐使得准确性和可信度比以往任何时候都更加重要。因此,独立评估,特别是通过盲目的建模比较,对于确保PV建模软件的公正基准是必要的。以前的研究受到模型比较范围狭窄、匿名结果或系统大小的限制。本研究展示了首次匿名盲建模比较的结果,使用实验室和公用事业规模的固定倾斜、单面、朝南系统进行评估,每隔一小时进行一次。比较了7种商用光伏软件工具:3E SynaptiQ、PlantPredict、PVsyst、RatedPower、SAM、SolarFarmer和Solargis Evaluate。预测由软件代表直接提交,提供了对每个软件实现和最终预测行为的独特见解。对阵列平面(POA)换位模型、模块温度模型、遮阳模型和性能模型进行了分析和比较。四个汇总表汇编了软件的这些功能,作为资源帮助用户了解方法上的差异,并为他们的应用程序选择最合适的软件。软件工具显示,在实验室规模的系统中,年产量与平均误差的偏差高达2.5%,在公用事业规模的系统中增加到6.0%。这些差异来自用户决策和软件固有行为的组合,表明需要使用这些软件工具对复杂的、真实的系统进行持续和严格的建模方法验证。
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引用次数: 0
Experimental investigation of solar air lift pump seasonal performance and efficiency 太阳能气举泵季节性能及效率的实验研究
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1016/j.solener.2025.114233
Hayder Mohsin Ali , Ali M. Ashour , Hamzah M. Jaffar , Saif Ali Kadhim , Farhan Lafta Rashid , Abdallah Bouabidi
This study represents an experimental characterization of a solar air-lift pump developed to dismantle solar-heated compressed air into bubbles inside a vertically submerged pipe for water lifting with no moving mechanical parts. The outdoor testing was done during the summer and winter periods, from 6:00 AM to 6:00 PM. Solar radiation, ambient temperature, water lift height, and volume flow rate were accounted for in the analysis and efficiency matrices, like thermal efficiency, air-to-mechanical, isentropic, pump, air-lift hydraulic, and overall efficiencies as well. The results showed a very high positive correlation between system performance and solar radiation, with the summer peaks always exceeding the winter values. The maximum water lift height was 85.8 cm in summer, compared to 58.5 cm in winter, and the maximum flow rate increased from 0.985 mL/s in winter to 1.716 mL/s in summer. The maximum value of thermal efficiency achieved in summer was 47.9 % in summer and 35.9 % in winter. A maximum overall efficiency was 5.0 % in summer and 3.73 % in winter was observed, clearly depicting the seasonal variation of the performance of solar air-lift pump. Results indicate that the thermal-to-hydraulic energy conversion recovery is efficiently influenced by seasonal effects, where summer shows significant benefit and is effective for bubble generation, water lifting ability, and overall system performance. This work offers valuable insights for the design of solar air-lift pump applications in irrigation, aquaculture, and off-grid drinking water supply systems.
本研究展示了一种太阳能空气提升泵的实验特性,该泵可以将太阳能加热的压缩空气分解成垂直水下管道内的气泡,用于没有移动机械部件的升水。室外测试在夏季和冬季进行,从早上6:00到下午6:00。在分析和效率矩阵中考虑了太阳辐射、环境温度、升水高度和体积流量,如热效率、空气-机械、等熵、泵、空气-液压和整体效率。结果表明,系统性能与太阳辐射呈非常高的正相关,夏季峰值总是超过冬季值。夏季最大升水高度为85.8 cm,冬季最大升水高度为58.5 cm,最大流量由冬季的0.985 mL/s增加到夏季的1.716 mL/s。夏季热效率最大值为47.9%,冬季为35.9%。夏季最高总效率为5.0%,冬季最高效率为3.73%,清楚地反映了太阳能气举泵性能的季节变化。结果表明,热-液能量转换回收受季节影响较大,其中夏季效益显著,对气泡产生、升水能力和系统整体性能均有显著影响。这项工作为太阳能气举泵在灌溉、水产养殖和离网饮用水供应系统中的应用设计提供了有价值的见解。
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引用次数: 0
Waste polymer-based interfacial solar photothermal catalytic system for hydrogen production and vapor generation 废聚合物基界面太阳能光热催化制氢和蒸汽系统
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1016/j.solener.2025.114200
Jingxian He , Jianxia Liu , Jiabin Zhu , Hao Gou , Shuaibing Li , Zhuoqun Li , Yishu Zhang , Yong He , Zhaoxin Yan , Lei Ling
Utilizing solar energy to drive interface heating to achieve water evaporation, while the photothermal catalyst decomposes water vapor to produce hydrogen. This synergistic strategy integrates clean energy conversion and water resource utilization, providing an innovative technological path for alleviating global energy crises and freshwater scarcity. To achieve both low production cost and high solar-thermal hydrogen production efficiency, an interfacial solar photothermal-photocatalytic system based on modified polyethylene foam (M−EPE), referred to as Co3O4@ZIS/M−EPE, was developed. Notably, the Co3O4@ZIS/M−EPE system exhibited high synergistic photothermal effects in both steam generation and hydrogen production, attributed to its unique two-dimensional channel structure, hydrophilicity, thermal insulation properties, and low thermal conductivity. Under an optical power density of 250 mW/cm2, the water evaporation rate of the Co3O4@ZIS/M−EPE system was noted to be 0.785 kg·m−2h−1, with a hydrogen production rate of 3411.75 µmol g−1h−1. In this scenario, the solar-to-steam conversion efficiency (η1) can reach up to 84.8 %, the solar-to-hydrogen energy conversion efficiency (η2) can reach 34 %. Cyclic experiments confirmed the long-term stability of the system. Moreover, the hydrogen production efficiency of the Co3O4@ZIS/M−EPE system using non-pure water was comparable to that achieved with pure water. This study highlights the potential of interfacial photothermal evaporation systems for hydrogen production from non-pure water and their relevance to industrial contexts.
利用太阳能驱动界面加热实现水分蒸发,光热催化剂分解水蒸气生成氢气。这一协同战略将清洁能源转化与水资源利用相结合,为缓解全球能源危机和淡水短缺提供了创新的技术途径。为了实现低生产成本和高光热制氢效率,开发了一种基于改性聚乙烯泡沫(M - EPE)的界面太阳能光热-光催化体系(Co3O4@ZIS/M - EPE)。值得注意的是,Co3O4@ZIS/M−EPE体系由于其独特的二维通道结构、亲水性、绝热性能和低导热性,在蒸汽生成和制氢方面都表现出高度的协同光热效应。在光功率密度为250 mW/cm2时,Co3O4@ZIS/M−EPE体系的蒸发速率为0.785 kg·M−2h−1,制氢速率为3411.75µmol g−1h−1。在此情景下,太阳能制汽转换效率(η1)可达84.8%,太阳能制氢转换效率(η2)可达34%。循环实验证实了系统的长期稳定性。此外,使用非纯水的Co3O4@ZIS/M−EPE系统的制氢效率与使用纯水的制氢效率相当。这项研究强调了界面光热蒸发系统从非纯水生产氢的潜力及其与工业环境的相关性。
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引用次数: 0
Spatio-temporal multi-head graph attention network for power forecasting of regional photovoltaic plants 区域光伏电站功率预测的时空多头图关注网络
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1016/j.solener.2025.114202
Jingjing Xie , Yan Ma , Conghao Wang , Yanting Wang , Sen Yang , Quan Ouyang
Improved prediction accuracy of regional photovoltaic (PV) generation significantly enhances multi-area coordination efficiency in modern power systems. This paper proposes a novel PV power forecasting model IIMGAT that integrates Improved Variational Mode Decomposition (IVMD), an improved Time-series Mixer architecture (Tsmixer), and a multi-head Graph Attention Network (GAT). First, the IVMD effectively extracts the key trend components from PV data as model inputs to mitigate interference from abrupt cloud cover changes. An innovative spatiotemporal dual-design framework is then employed to capture temporal patterns and extract spatial features. The proposed IIMGAT model achieves high precision forecasting by comprehensively capturing spatio-temporal correlations among regional PV power stations. The proposed model achieves R2 values of 0.981 and 0.991 on the PVOD and DKASC datasets, respectively. The values of R2 indicate the model’s high robustness.
区域光伏发电预测精度的提高显著提高了现代电力系统的多区域协调效率。本文提出了一种集成了改进变分模态分解(IVMD)、改进时间序列混合器架构(Tsmixer)和多头图注意网络(GAT)的新型光伏功率预测模型IIMGAT。首先,IVMD有效地从PV数据中提取关键趋势分量作为模型输入,以减轻云覆盖突变的干扰。然后采用创新的时空双重设计框架来捕获时间模式并提取空间特征。本文提出的IIMGAT模型通过综合捕捉区域光伏电站间的时空相关性,实现了高精度的预测。该模型在PVOD和DKASC数据集上的R2值分别为0.981和0.991。R2的值表明模型具有较高的鲁棒性。
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引用次数: 0
Heat transfer and flow analysis of a double-pass solar air heater with sandwich-structured PCM cylinders 夹层结构PCM双通道太阳能空气加热器的传热与流动分析
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1016/j.solener.2025.114212
Sahibzada Imad Ud Din , Adnan Ibrahim , Ahmad Fazlizan , Norasikin Ahmad Ludin , Muhammad Aqil Afham Rahmat , Muhammad Ashhad Shahid , Anwer.B. Al-Aasam , Mohd Afzanizam Mohd Rosli , Muhammad Amir Aziat Bin Ishak
There is a growing focus on solar air heater systems due to their enhanced efficiency and performance. However, due to poor convective heat transfer coefficient and the intermittent nature of solar energy, these systems cannot provide reliable thermohydraulic performance. This research study introduced a novel design to improve the thermal and hydraulic performance of a double-pass solar air heater. For this purpose, a three-dimensional numerical analysis is performed to evaluate the thermohydraulic performance of a newly developed DPSAH design with sandwich-structured PCM cylinders in the second channel. The parameters selected for this study include PCM cylinder diameter ranging from 0.06 to 0.09 m, channel height-to-total height ratio ranging from 0.19 to 0.38, and Reynolds number ranging from 4700 to 23,250. The maximum Nusselt number was found to be 278 with a corresponding friction factor value of 0.074, and a maximum thermohydraulic performance parameter value of 2.17 was attained for a cylinder diameter of 0.07 m and a channel height ratio of 0.38 at a Reynolds number of 23,250. For the same parameters, the heat transfer enhancement ratio was 4.63 times with a friction factor increment ratio of 11.1 compared to the smooth plate.
由于效率和性能的提高,太阳能空气加热系统受到越来越多的关注。然而,由于对流换热系数差和太阳能的间歇性,这些系统不能提供可靠的热水力性能。本研究介绍了一种改善双通道太阳能空气加热器热工性能的新设计。为此,采用三维数值分析方法,对新设计的第二通道夹层结构PCM柱的DPSAH热工性能进行了评价。本研究选取的参数包括:PCM气缸直径为0.06 ~ 0.09 m,通道高度与总高度之比为0.19 ~ 0.38,雷诺数为4700 ~ 23250。在雷诺数为23,250时,圆柱直径为0.07 m,通道高度比为0.38时,最大努塞尔数为278,摩擦系数为0.074,最大热工性能参数值为2.17。在相同参数下,与光滑板相比,换热强化比为4.63倍,摩擦因数增量比为11.1倍。
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引用次数: 0
Bayesian probabilistic photovoltaic power forecasting and stochastic model-predictive control for an agricultural microgrid 农业微电网光伏功率贝叶斯概率预测及随机模型预测控制
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2025-12-06 DOI: 10.1016/j.solener.2025.114197
Paul Brown, Murat Göl
This paper describes a novel probabilistic forecasting method for photovoltaic power for use in energy management for an agricultural microgrid. The forecasting method utilizes recent historical data and a general weather forecast to fit a spline + Gaussian process (GP) model using no-u-turn sampling (NUTS) to infer model parameters in a Bayesian modeling framework. The method seamlessly transitions from a near-term forecast dominated by recent output to a regime where output is dominated by the meteorological forecast. The forecasts are evaluated using proper scoring rules for multivariate probabilistic forecasts and are compared to a reference multivariate persistence forecast and to an LSTM-based forecasting method. The probabilistic method is integrated into a simulation of stochastic model-predictive control (SMPC) for an off-grid agricultural microgrid incorporating photovoltaic generation, a battery storage system, irrigation pumping, and local electrical loads. A 20 %–35 % reduction in simulated operating cost is achieved using the probabilistic forecast compared to a simple expected-value point forecast.
本文提出了一种用于农业微电网能源管理的光伏发电概率预测方法。该方法利用最近的历史数据和一般天气预报,拟合样条+高斯过程(GP)模型,在贝叶斯建模框架中使用无掉头抽样(NUTS)来推断模型参数。该方法无缝地从近期产出主导的近期预测过渡到产出由气象预测主导的状态。使用适当的多变量概率预测评分规则对预测进行评估,并将其与参考多变量持久性预测和基于lstm的预测方法进行比较。将概率方法集成到一个包含光伏发电、电池存储系统、灌溉泵和本地电力负荷的离网农业微电网的随机模型预测控制(SMPC)仿真中。与简单的期望值点预测相比,使用概率预测可将模拟运行成本降低20% - 35%。
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引用次数: 0
Experimental review and recent advances in deep learning techniques for solar irradiance forecasting and prediction 太阳辐照度预测与预报中深度学习技术的实验回顾与最新进展
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2025-12-06 DOI: 10.1016/j.solener.2025.114175
Chinedu I. Otuka , Dongsheng Cai , Chiagoziem C. Ukwuoma , Shuang Luo , Zhihui Yang , Olusola Bamisile , Chibueze D. Ukwuoma , Chizoba U. Otuka , Nkiruka O. Otuka , Qi Huang
The growing demand for clean energy has greatly improved solar energy forecasting, especially for Global Horizontal Irradiance (GHI), which is important for solar photovoltaic (PV) installation planning, grid integration, and energy management. Traditional forecasting methods, such as statistical and physical models, often fail to capture solar irradiance data’s complex, nonlinear, and dynamic nature. Researchers have turned to deep learning techniques, which have demonstrated superior accuracy by effectively capturing spatiotemporal dependencies. While previous surveys have explored traditional forecasting and deep learning approaches for GHI solar forecasting, many focus on limited model types, lack of comprehensive analysis of the different model disadvantages, a Benchmark dataset, feature extraction techniques, and experimental analysis to support their claims. To address this gap, this Prisma-based systematic and Experimental Review critically examines recent improvements in deep learning techniques such as Convolutional Neural Networks (CNNs), Recurrent Neural Networks (RNNs), hybrid and ensemble methods, and Transformers, providing an analysis of their strengths, weaknesses, and real-world applicability for solar irradiance forecasting while supporting its claim with experimental analysis. This review identifies that CNNs excel in spatial feature extraction, particularly from sky images, while RNNs are well-suited for sequential data analysis. Hybrid and ensemble methods leverage multiple approaches to improve robustness and forecasting precision. Transformers have brought about a breakthrough in long-range dependency handling through their attention mechanisms, enhancing sequence-to-sequence tasks, which can be seen from the reported experiment. However, challenges such as dependency on large labelled datasets, overfitting with limited data, and computational demands remain significant limitations. In addition, this review article presents a novel dual-input transformer-based model for 30-minute solar forecasting. The designed dual-feature input transformer fuses information from sky images and numerical data to make a forecast of solar irradiance (SI) with high accuracy, specifically an R2 of 0.979 on sunny days and 0.976 on cloudy days, showing robust performance under different weather conditions. The findings emphasise the practical implications of deep learning models in enhancing energy production, improving grid stability, and optimising energy storage, thereby contributing to a sustainable energy future.
对清洁能源日益增长的需求极大地改善了太阳能预测,特别是对全球水平辐照度(GHI)的预测,这对太阳能光伏(PV)安装规划、电网整合和能源管理非常重要。传统的预测方法,如统计和物理模型,往往无法捕捉太阳辐照度数据的复杂性、非线性和动态性。研究人员已经转向深度学习技术,该技术通过有效地捕获时空依赖关系显示出卓越的准确性。虽然以前的调查已经探索了用于GHI太阳预测的传统预测和深度学习方法,但许多调查都侧重于有限的模型类型,缺乏对不同模型缺点的综合分析,缺乏基准数据集,特征提取技术和实验分析来支持他们的主张。为了解决这一差距,这篇基于prisma的系统和实验综述批判性地研究了深度学习技术的最新进展,如卷积神经网络(cnn)、循环神经网络(rnn)、混合和集成方法以及变压器,分析了它们的优点、缺点和对太阳辐照度预测的实际适用性,同时通过实验分析支持其主张。这篇综述指出,cnn在空间特征提取方面表现出色,特别是从天空图像中提取,而rnn则非常适合于序列数据分析。混合和集成方法利用多种方法来提高鲁棒性和预测精度。变形金刚通过其注意机制突破了远程依赖处理,增强了序列到序列的任务,这从报道的实验中可以看出。然而,诸如对大型标记数据集的依赖、有限数据的过拟合以及计算需求等挑战仍然是显着的限制。此外,本文还提出了一种新的基于双输入变压器的30分钟太阳预报模型。设计的双特征输入变压器融合了天空图像和数值数据信息,对太阳辐照度(SI)进行了高精度的预报,晴天和阴天的预报R2分别为0.979和0.976,在不同天气条件下均表现出较强的预报能力。研究结果强调了深度学习模型在提高能源生产、改善电网稳定性和优化能源储存方面的实际意义,从而为可持续能源的未来做出贡献。
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引用次数: 0
DFT investigation of spin-tuned radicals of doped graphene quantum dots for efficient hole transport 有效空穴输运掺杂石墨烯量子点自旋调谐自由基的DFT研究
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2025-12-06 DOI: 10.1016/j.solener.2025.114159
Tushima Basak , Tista Basak
The optimal performance of perovskite solar cells (PSCs) is critically dependent on the appropriate selection of stable and high-efficiency hole transporting materials (HTMs) that facilitate directional hole-transfer and impede electron-flow. This computational work demonstrates a unique technique for designing potential HTMs by the site-selective incorporation of suitable dopants in the radicals of graphene quantum dots (GQDs). We first demonstrate that band-gap tuning is dictated by the electron-inducing capability of the dopant atoms, spin multiplicity of the ground-state and the spin-paired/unpaired radical character of the GQDs. The computed spectral profile establishes that doping results in a generic red-shift of the optical profile and the magnitude of this shift is more pronounced for electron-donating Al dopants as compared to electron-withdrawing N substituents. A comprehensive analysis of the essential properties for prospective HTMs such as interfacial layer alignment, dipole moment, open-circuit voltage, fill-factor, mobility, light harvesting efficiency, excitonic character and binding energy highlights that the selective integration of N dopants in the spin-paired radicals of GQD with singlet ground state yields a suitable HTM for high-efficiency PSCs. This operational approach can be exploited for the rational design of stable, cost-effective HTMs that can successfully overcome the fabrication complexity and high-expenses associated with the conventional Spiro-OMeTAD HTM.
钙钛矿太阳能电池(PSCs)的最佳性能关键取决于适当选择稳定和高效的空穴传输材料(HTMs),以促进定向空穴转移和阻止电子流。这项计算工作展示了一种独特的技术,通过在石墨烯量子点(GQDs)的自由基中选择性地掺入合适的掺杂剂来设计潜在的HTMs。我们首先证明了带隙调谐是由掺杂原子的电子诱导能力、基态的自旋多重性和GQDs的自旋配对/未配对自由基特征决定的。计算的光谱分布表明,掺杂导致光学分布的一般红移,并且与吸电子的N取代基相比,这种位移的幅度对于给予电子的Al掺杂更为明显。通过对界面层取向、偶极矩、开路电压、填充因子、迁移率、光收集效率、激子特性和结合能等基本特性的综合分析,强调了N掺杂剂在GQD的自旋对自由基中与单线态基态的选择性集成可以产生适合于高效psc的HTM。这种操作方法可用于合理设计稳定、经济高效的HTM,成功克服传统Spiro-OMeTAD HTM的制造复杂性和高成本。
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引用次数: 0
Carbohydrate-Assisted eco-friendly synthesis of CoFe2O4/CoCo2O4/CeO2 magnetic photocatalyst for efficient dye degradation 碳水化合物辅助生态合成CoFe2O4/CoCo2O4/CeO2磁性光催化剂高效降解染料
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2025-12-05 DOI: 10.1016/j.solener.2025.114216
Saba Roostaei , Mina Ahmadi-Kashani , Hiba J. Turki , Zainab Muhsin Bdaiwi , Layth S. Jasim , Masoud Salavati-Niasari
Air, water, and soil contamination form a worldwide crisis, posing grave risks to the health of Earth’s ecosystems and all living beings, particularly humans. Considerable efforts have been made to develop low-cost, green, and highly effective strategies for degrading organic dyes and contaminants in aqueous environments. This study introduces, for the first time, the design and controlled synthesis of a novel ternary CoFe2O4/CoCo2O4/CeO2 nano-photocatalyst with magnetic recyclability, achieved via a facile single-step sol–gel auto-combustion strategy. This pioneering approach highlights the integration of three components for efficient pollutant degradation. This ternary photocatalyst combines the magnetic properties of CoFe2O4, the structural stability and redox versatility of CoCo2O4, and the oxygen storage capacity and photocatalytic functionality of CeO2. The coexistence of variable oxidation states in transition metals (e.g., Co2+/Co3+, Fe2+/Fe3+, and Ce3+/Ce4+) enables efficient multi-electron redox processes, which are critical for generating reactive oxygen species (•OH, •O2) that drive rapid dye degradation. This ternary nano-photocatalyst exhibited superior photocatalytic capabilities by degrading 86.15 % of Erythrosine (ER). Scavenger experiments confirmed that holes (h+) were the dominant reactive species in the CoFe2O4/CoCo2O4/CeO2 nanocomposite under visible-light irradiation, playing the most critical role in driving the photocatalytic degradation mechanism. In addition, a detailed mechanism for the catalytic reaction under light irradiation, along with the hole-creation process in the CoFe2O4/CoCo2O4/CeO2 system, was outlined. A detailed analysis of kinetic behavior, catalyst reusability, and variable effects like pollutant concentration and catalyst dosage was conducted during photocatalytic testing. Owing to its multi-functional design, the CoFe2O4/CoCo2O4/CeO2 system demonstrates exceptional promise for eco-friendly water treatment, efficiently degrading diverse pollutants without secondary waste generation.
空气、水和土壤污染构成了全球性危机,对地球生态系统和所有生物,特别是人类的健康构成严重威胁。为开发低成本、绿色、高效的降解水环境中的有机染料和污染物的策略,人们付出了巨大的努力。本研究首次介绍了一种新型的具有磁性可回收性的三元CoFe2O4/CoCo2O4/CeO2纳米光催化剂的设计和控制合成,该催化剂通过简单的单步溶胶-凝胶自燃烧策略实现。这种开创性的方法强调了有效降解污染物的三个组成部分的整合。该三元光催化剂结合了CoFe2O4的磁性、CoCo2O4的结构稳定性和氧化还原通用性,以及CeO2的储氧能力和光催化功能。过渡金属中多种氧化态的共存(如Co2+/Co3+、Fe2+/Fe3+和Ce3+/Ce4+)实现了高效的多电子氧化还原过程,这对于生成驱动染料快速降解的活性氧(•OH、•O2 -)至关重要。该三元纳米光催化剂可降解86.15%的红素(ER),表现出优异的光催化性能。清除剂实验证实,在可见光照射下,孔洞(h+)是CoFe2O4/CoCo2O4/CeO2纳米复合材料的优势活性物质,在光催化降解机制中起着最关键的作用。此外,还详细介绍了光照射下CoFe2O4/CoCo2O4/CeO2体系中催化反应的机理和空穴形成过程。在光催化测试过程中,对动力学行为、催化剂可重复使用性以及污染物浓度和催化剂用量等变量影响进行了详细分析。由于其多功能设计,CoFe2O4/CoCo2O4/CeO2系统在生态友好型水处理方面表现出非凡的前景,有效地降解各种污染物而不会产生二次废物。
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引用次数: 0
Experimental performance of a PVT collector during nocturnal operation 夜间操作时PVT收集器的实验性能
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2025-12-05 DOI: 10.1016/j.solener.2025.114184
Evangelos I. Sakellariou , Petros J. Axaopoulos , Giorgos Sofiadis , Kosmas A. Kavadias
This study experimentally investigates the nocturnal operation of a photovoltaic thermal (PVT) collector to assess its heat rejection capacity during summer nights in a Mediterranean climate. A key objective was to evaluate the proportion of heat rejection attributed to thermal radiation. The PVT collector was connected to a storage tank in a closed-loop configuration through a circulation pump. The experimental setup was installed in Argolis, Greece, and operated during July and August under varying summer weather conditions, fluid flow rates, and collector inclinations. The results show that the average specific cooling power of the collector ranged between 43 and 60 W m−2, values comparable to those reported in the literature for unglazed PVT collectors. Radiative cooling contributed 10–18 % of the total cooling power, while natural convection was the dominant mechanism. During nighttime operation, the PVT collector was capable of reducing the storage tank water temperature slightly below ambient, primarily due to thermal radiation from the collector to the sky. Using the experimental dataset, a multivariable polynomial regression model was developed to predict cooling power as a function of inlet water temperature, ambient temperature, relative humidity, wind speed, and fluid flow rate. The model achieved an R2 of 0.889 with a standard error of 10.34 W, demonstrating strong predictive performance under clear-sky conditions, though reduced accuracy was observed during overcast nights. These findings indicate that nocturnal PVT operation can enhance the performance of shallow geothermal heat pump systems in Mediterranean climates by cooling down the ground temperatures adjacent to the ground heat exchanger during cooling-dominated periods, thereby improving the performance of the heat pump system.
本研究通过实验研究了一个光伏热(PVT)集热器的夜间运行,以评估其在地中海气候下夏夜的散热能力。一个关键的目标是评估由于热辐射而产生的热量流失的比例。PVT收集器通过循环泵以闭环配置连接到储罐上。实验装置安装在希腊的Argolis,并于7月和8月在不同的夏季天气条件、流体流速和收集器倾角下运行。结果表明,集热器的平均比冷却功率在43 ~ 60 W m−2之间,与文献中报道的无釉PVT集热器的值相当。辐射冷却占总冷却功率的10 - 18%,而自然对流是主要的冷却机制。在夜间运行期间,PVT收集器能够将储罐水温降低到略低于环境温度,这主要是由于收集器对天空的热辐射。利用实验数据,建立了一个多变量多项式回归模型,预测了进口水温、环境温度、相对湿度、风速和流体流量对冷却功率的影响。该模型的R2为0.889,标准误差为10.34 W,在晴空条件下显示出较强的预测性能,尽管在阴天夜间观察到精度降低。这些结果表明,夜间PVT运行可以通过降低地面热交换器附近的地面温度,从而提高地中海气候条件下浅层地源热泵系统的性能,从而提高热泵系统的性能。
{"title":"Experimental performance of a PVT collector during nocturnal operation","authors":"Evangelos I. Sakellariou ,&nbsp;Petros J. Axaopoulos ,&nbsp;Giorgos Sofiadis ,&nbsp;Kosmas A. Kavadias","doi":"10.1016/j.solener.2025.114184","DOIUrl":"10.1016/j.solener.2025.114184","url":null,"abstract":"<div><div>This study experimentally investigates the nocturnal operation of a photovoltaic thermal (PVT) collector to assess its heat rejection capacity during summer nights in a Mediterranean climate. A key objective was to evaluate the proportion of heat rejection attributed to thermal radiation. The PVT collector was connected to a storage tank in a closed-loop configuration through a circulation pump. The experimental setup was installed in Argolis, Greece, and operated during July and August under varying summer weather conditions, fluid flow rates, and collector inclinations. The results show that the average specific cooling power of the collector ranged between 43 and 60 W m<sup>−2</sup>, values comparable to those reported in the literature for unglazed PVT collectors. Radiative cooling contributed 10–18 % of the total cooling power, while natural convection was the dominant mechanism. During nighttime operation, the PVT collector was capable of reducing the storage tank water temperature slightly below ambient, primarily due to thermal radiation from the collector to the sky. Using the experimental dataset, a multivariable polynomial regression model was developed to predict cooling power as a function of inlet water temperature, ambient temperature, relative humidity, wind speed, and fluid flow rate. The model achieved an R<sup>2</sup> of 0.889 with a standard error of 10.34 W, demonstrating strong predictive performance under clear-sky conditions, though reduced accuracy was observed during overcast nights. These findings indicate that nocturnal PVT operation can enhance the performance of shallow geothermal heat pump systems in Mediterranean climates by cooling down the ground temperatures adjacent to the ground heat exchanger during cooling-dominated periods, thereby improving the performance of the heat pump system.</div></div>","PeriodicalId":428,"journal":{"name":"Solar Energy","volume":"304 ","pages":"Article 114184"},"PeriodicalIF":6.0,"publicationDate":"2025-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145682071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Solar Energy
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