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Corrigendum to “Experimental investigation of a photovoltaic solar air conditioning system and comparison with conventional unit in the context of the state of Piaui, Brazil” [Sol. Energy 272 (2024) 112492] 对 "巴西皮奥伊州光伏太阳能空调系统的实验研究及与传统设备的比较 "的更正[Sol. Energy 272 (2024) 112492]
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-17 DOI: 10.1016/j.solener.2024.113115
F.W.D. Rebelo , K.A.R. Ismail , F.A.M. Lino , G.A. Sousa
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引用次数: 0
Sustainable desalination through hybrid photovoltaic/thermal membrane distillation: Development of an off-grid prototype 通过光伏/热膜混合蒸馏实现可持续海水淡化:开发离网原型
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-17 DOI: 10.1016/j.solener.2024.113090
Farzaneh Mahmoudi, Derrick Ng, Kian Ang, Zongli Xie
<div><div>Global freshwater scarcity is a critical challenge, particularly severe in remote Australian communities where seawater intrusion and aquifer salinisation exacerbate the need for alternative water resources. Conventional desalination technologies are energy-intensive and unsuitable for rural areas. This study introduces a novel, off-grid, sustainable desalination solution utilising solar-integrated membrane distillation (MD) technology. An innovative, stand-alone prototype combining a hybrid photovoltaic/thermal (PV/T) system with direct contact MD (DCMD) has been designed and developed. This fully integrated PV/T collector efficiently supplies the thermal and electrical energy required for the MD process. The photovoltaic panel generates the necessary electrical energy, while the heat from the PV panel warms the MD system’s feed solution, enhancing overall efficiency through the solar cell cooling effect. In addition, an innovative fan-cooled radiator equipped with two DC fans with a low power consumption rating was designed and customized to be applied as MD system cooling medium within the outdoor setting. The concept development and feasibility of the system are explored in detail through a comprehensive experimental investigation employing an innovative and practical approach to design and examine the integrated hybrid solar MD unit. This unique system was designed, constructed, and tested under dynamic outdoor conditions, during the summer season in Melbourne, to assess the integration strategy and evaluate its long-term operational performance. The performance of the integrated PV/T-MD system was evaluated using two commercial hydrophobic membranes with different pore sizes under various outdoor conditions and PV/T fluid flow rates. Key performance metrics analysed include solar irradiance intensity, temperature profiles of the PV/T panel and MD module, power, current and voltage profiles of the unit components, permeate flux, specific water productivity (<em>SWP</em>) and the thermal (<em>η<sub>thermPV/T</sub></em>) and electrical (<em>η<sub>elecPV/T</sub></em>) efficiencies, along with the gained output ratio (<em>GOR</em>). Comprehensive experimental assessments in indoor and outdoor settings were undertaken to confirm the technical viability of the system. The study demonstrates the feasibility of such systems through real-world trials and addresses key challenges in energy efficiency and internal heat recovery. The experimental trials demonstrated permeate flux values ranging between 8–16 kg/m<sup>2</sup>h outdoors, compared to 22–30 kg/m<sup>2</sup>h indoors, reflecting the impact of fluctuating environmental conditions. The system’s power consumption was measured 130–140 W, about one-third of the PV/T power rating. The maximum power generation reached 280 W in battery charging mode. achieving a maximum <em>η<sub>thermPV/T</sub></em> of 20 % and an <em>η<sub>elecPV/T</sub></em> of 18 %. Additionally, the cooling effect of t
全球淡水匮乏是一个严峻的挑战,在澳大利亚偏远社区尤为严重,海水入侵和含水层盐碱化加剧了对替代水资源的需求。传统的海水淡化技术能耗高,不适合农村地区。本研究介绍了一种利用太阳能集成膜蒸馏(MD)技术的新型离网可持续海水淡化解决方案。我们设计并开发了一种创新的独立原型,将光伏/热能(PV/T)混合系统与直接接触式膜蒸馏(DCMD)相结合。这种完全集成的 PV/T 集热器能有效地提供 MD 过程所需的热能和电能。光伏电池板产生必要的电能,而光伏电池板的热量可加热 MD 系统的进料溶液,通过太阳能电池冷却效应提高整体效率。此外,还设计并定制了一种创新的风扇冷却散热器,配备两个低功耗直流风扇,作为 MD 系统的室外冷却介质。通过全面的实验研究,采用创新和实用的方法设计和检验了集成式混合太阳能 MD 单元,详细探讨了系统的概念开发和可行性。在墨尔本夏季的动态室外条件下,对这一独特的系统进行了设计、建造和测试,以评估其集成策略和长期运行性能。在各种室外条件和 PV/T 流体流速下,使用两种不同孔径的商用疏水膜对集成 PV/T-MD 系统的性能进行了评估。分析的关键性能指标包括太阳辐照强度、PV/T 面板和 MD 模块的温度曲线、单元组件的功率、电流和电压曲线、渗透通量、比水生产力(SWP)、热效率(ηthermPV/T)和电效率(ηelecPV/T)以及增益输出比(GOR)。在室内和室外环境中进行了全面的实验评估,以确认系统的技术可行性。这项研究通过实际试验证明了此类系统的可行性,并解决了能效和内部热回收方面的关键难题。实验证明,室外的渗透通量值为 8-16 千克/平方米小时,而室内为 22-30 千克/平方米小时,这反映了环境条件波动的影响。据测量,该系统的耗电量为 130-140 瓦,约为 PV/T 额定功率的三分之一。在电池充电模式下,最大发电量达到 280 W,最大 ηthermPV/T 为 20%,ηelecPV/T 为 18%。此外,PV/T 面板的冷却效果使温度降低了 1.5-2 °C,使电力输出提高了 0.8-1.2 %。研究结果凸显了该系统在为偏远的离网社区提供可靠、高效的淡水生产方面的巨大潜力,为应对全球水资源短缺的挑战提供了一个可扩展的解决方案。
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引用次数: 0
Optimal study of a hybrid solar-biomass heating system for rural household in cold regions of China 中国寒冷地区农村家庭太阳能-生物质混合供暖系统的优化研究
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-16 DOI: 10.1016/j.solener.2024.113101
Jing Li , Xuebin Ma , Ganhua Shen , Yucheng Ren , Yuwei Ma , Ziwei Yu , Qiugang Wang , Reaihan E , Ning Ai , Jie Li , Mingguo Ma , Junfeng Li

Background

Currently, the heating measures for rural households face significant disadvantages such as reliance on fossil fuels, poor thermal comfort, and high carbon emissions.

Objectives

This study designed a solar-coupled domestic biomass boiler parallel heating system (SBPHS) with collaborative optimization.

Methods

The SBPHS was developed based on a typical rural residence in cold regions. Subsequently, a parametric analysis was performed on both component configuration and operating parameters. Furthermore, we determined optimal configurations of the SBPHS using the life cycle cost (LCC) as the optimization objective. Solar fraction, total power consumption, effective heat collection and boiler runtime were used as performance indicators to evaluate the system.

Results

Simulation results were in good agreement with measured data. Parametric analyses indicated that component design should consider energy performance and economics, especially in rural areas. As a start/stop signal for the collector system, the collector-tank temperature difference significantly affected effective heat collection and system energy consumption. Further, flow rates had significant impacts on all performance indicators, especially collector flow rate. Considering the optimum operating conditions throughout the system’s life cycle, Hooke-Jeeves algorithm was adopted to optimize component configurations and operating parameters simultaneously. Post-optimization, LCC of the SBPHS was reduced by 12.3 %. The optimized system could achieve a solar energy share of up to 62.7 %, total energy consumption reduction of 13.6 %, and biomass fuel consumption reduction of 26.3 %, indicating significant energy savings.

Conclusion

These findings enhance the feasibility of implementing the SBPHS in rural residences in cold areas and provide theoretical foundation for the design and operation of system.
背景目前,农村家庭的供暖措施面临着依赖化石燃料、热舒适度差、碳排放量高等显著弊端。方法根据寒冷地区典型的农村住宅开发了太阳能耦合家用生物质锅炉并联供暖系统(SBPHS)。随后,对组件配置和运行参数进行了参数分析。此外,我们还以生命周期成本(LCC)为优化目标,确定了 SBPHS 的最佳配置。结果 模拟结果与测量数据非常吻合。参数分析表明,组件设计应考虑能源性能和经济性,尤其是在农村地区。作为集热器系统的启动/停止信号,集热器-水箱温差对有效集热和系统能耗有显著影响。此外,流量对所有性能指标都有重大影响,尤其是集热器流量。考虑到整个系统生命周期内的最佳运行条件,我们采用了胡克-杰维斯算法来同时优化组件配置和运行参数。优化后,SBPHS 的 LCC 降低了 12.3%。优化后的系统太阳能占比高达 62.7%,总能耗降低 13.6%,生物质燃料消耗降低 26.3%,节能效果显著。
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引用次数: 0
Design and analysis of inorganic tandem architecture with synergistically optimized BaSnS3 top and AgTaS3 bottom perovskite Sub-Cells 设计和分析具有协同优化的顶部 BaSnS3 和底部 AgTaS3 包晶子电池的无机串联结构
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-16 DOI: 10.1016/j.solener.2024.113111
Tanvir Ahmed , Sheikh Noman Shiddique , Abdul Kuddus , Mainul Hossain , Shinichiro Mouri , Jaker Hossain
Perovskite materials are revolutionizing the solar cell (SC) industry, continually enhancing their properties and establishing a prominent photovoltaic technology. Among these, BaSnS3 (BTS) and AgTaS3 (ATS) stand out for their strong potential as absorber layers. These inorganic chalcogenide perovskites address the drawbacks of their organic counterparts, being both lead-free and non-toxic, thereby making them highly suitable for photovoltaic (PV) applications. The exploration of BTS and ATS as absorber layers in a tandem solar cell’s top and bottom cells has yielded remarkable outcomes. The innovative tandem solar cell design features a top cell structured as n-WS2/p-BaSnS3/p+-MoS2 and a bottom cell configured as n-WS2/p-AgTaS3/p+-GeS. This theoretical study using SCAPS-1D demonstrates a high efficiency of 42.57 % with a VOC of 2.03 V, a JSC of 23.29 mA/cm2, and an FF of 89.85 %. These impressive results are achieved with adjusted layer thickness, carrier doping and defect levels, highlighting the strong potential of BaSnS3 and AgTaS3 photoactive materials. The findings reveal the viability of innovative, all-inorganic perovskite-based tandem solar cells, offering a promising avenue for future sustainable and high-efficiency photovoltaic device technologies.
过氧化物材料正在彻底改变太阳能电池(SC)行业,不断提高其性能,并成为一种重要的光伏技术。其中,BaSnS3 (BTS) 和 AgTaS3 (ATS) 因其作为吸收层的强大潜力而脱颖而出。这些无机瑀质包晶解决了有机包晶的缺点,既无铅又无毒,因此非常适合光伏(PV)应用。将 BTS 和 ATS 作为串联太阳能电池顶部和底部电池的吸收层的探索取得了显著成果。创新的串联太阳能电池设计采用了 n-WS2/p-BaSnS3/p+-MoS2 结构的顶部电池和 n-WS2/p-AgTaS3/p+-GeS 结构的底部电池。这项使用 SCAPS-1D 进行的理论研究表明,在 2.03 V 的 VOC、23.29 mA/cm2 的 JSC 和 89.85 % 的 FF 下,效率高达 42.57 %。通过调整层厚、载流子掺杂和缺陷水平,这些令人印象深刻的结果得以实现,凸显了 BaSnS3 和 AgTaS3 光活性材料的强大潜力。这些研究结果揭示了创新的、基于全无机包晶的串联太阳能电池的可行性,为未来的可持续高效光伏器件技术提供了一条前景广阔的途径。
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引用次数: 0
Designing and optimizing the lead-free double perovskite Cs2AgBiI6/Cs2AgBiBr6 bilayer perovskite solar cell 设计和优化无铅双包晶 Cs2AgBiI6/Cs2AgBiBr6 双层包晶太阳能电池
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-16 DOI: 10.1016/j.solener.2024.113087
Huan Chen , Chaoen Li , Wenquan Zhou , Jili Wen , Mei Ma , Yuelin Chen , Kai Huang , Yang Ling , Jiang Wu , Yang Zhao , Xin Zeng , Yuxiang Wu
Due to their potential to be an absorber layer in perovskite solar cells with cheap cost, outstanding stability, and high efficiency, lead-free double perovskite Cs2AgBiI6 and Cs2AgBiBr6 have attracted tremendous attention recently. In this work, Cs2AgBiI6 and Cs2AgBiBr6 are introduced to create a perovskite-perovskite bilayer solar cell FTO/ETL/Cs2AgBiI6/Cs2AgBiBr6/HTL/Au through SCAPS-1D. The Cs2AgBiI6/Cs2AgBiBr6 double absorber layer structure significantly reduces lead toxicity while improving the device’s stability and light absorption capabilities, according to the results. We chose the optimal hole transport layer (HTL) and electron transport layer (ETL) to examine the impacts of several HTLs and ETLs on the PSC. The device’s performance appears to be significantly impacted by the energy level alignment of the absorber and transport layers, and that ideal energy band structure facilitates the carriers’ transportation and separation. Through numerical simulations, the impacts of some factors containing the absorber layer thickness, defect density and doping concentration of the perovskite layers, operating temperature, and different back-contact electrodes, were examined. The optimized results are PCE = 34.36 %, FF = 93.35 %, Jsc = 24.78 mA/cm2, and Voc = 1.48 V. This work demonstrates that double perovskite Cs2AgBiI6 and Cs2AgBiBr6 hold great potential for application in photovoltaic and optoelectronic devices.
无铅双包晶石 Cs2AgBiI6 和 Cs2AgBiBr6 具有成本低廉、稳定性好、效率高等特点,可作为包晶太阳能电池的吸收层,因此近年来备受关注。在这项研究中,我们引入了 Cs2AgBiI6 和 Cs2AgBiBr6,通过 SCAPS-1D 制作了一种包晶-包晶双层太阳能电池 FTO/ETL/Cs2AgBiI6/Cs2AgBiBr6/HTL/Au。结果表明,Cs2AgBiI6/Cs2AgBiBr6 双吸收层结构显著降低了铅毒性,同时提高了器件的稳定性和光吸收能力。我们选择了最佳空穴传输层(HTL)和电子传输层(ETL),考察了几种 HTL 和 ETL 对 PSC 的影响。器件的性能似乎受到吸收层和传输层能级排列的显著影响,理想的能带结构有利于载流子的传输和分离。通过数值模拟,研究了吸收层厚度、过氧化物层的缺陷密度和掺杂浓度、工作温度以及不同背接触电极等因素的影响。优化后的结果为:PCE = 34.36 %,FF = 93.35 %,Jsc = 24.78 mA/cm2,Voc = 1.48 V。这项研究表明,双包晶石 Cs2AgBiI6 和 Cs2AgBiBr6 在光伏和光电设备中具有巨大的应用潜力。
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引用次数: 0
Exploring bamboo based bio-photovoltaic devices: Pioneering sustainable solar innovations- A comprehensive review 探索基于竹子的生物光伏装置:开拓可持续太阳能创新--综合评述
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-16 DOI: 10.1016/j.solener.2024.113039
Biswajeet Acharya , Amulyaratna Behera , Bimalendu Chowdhury , Srikanta Moharana , Suresh Sagadevan , Suchismeeta Behera
The widespread adoption of eco-friendly and renewable energy sources has driven to the demand for cutting-edge innovations. This in-depth analysis examines the feasibility of bamboo-based biophotovoltaic devices as ground-breaking solutions in the search of environmentally friendly solar applications. This typical review summarizes and also evaluates the utilization of bamboo to harness solar energy for generating clean, renewable power. Furthermore, this present analysis investigates the merits and demerits of these tools, providing further information about their potential as a long-term solar power production. The results of this analysis explores the capacity of biophotovoltaic devices made from bamboo and their importance in developing green energy solutions for a more environmentally friendly and sustainable future.
环保型可再生能源的广泛采用推动了对尖端创新技术的需求。本报告通过深入分析,探讨了竹基生物光电设备作为环保型太阳能应用领域开创性解决方案的可行性。这篇典型的综述总结并评估了利用竹子利用太阳能产生清洁、可再生电力的情况。此外,本分析报告还对这些工具的优缺点进行了调查,为其作为长期太阳能发电工具的潜力提供了进一步的信息。分析结果探讨了用竹子制成的生物光伏装置的能力,以及它们在开发绿色能源解决方案以实现更加环保和可持续发展的未来方面的重要性。
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引用次数: 0
Evaluating tracking bifacial solar PV based agrivoltaics system across the UK 评估英国各地基于农业光伏系统的跟踪式双面太阳能光伏发电系统
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-16 DOI: 10.1016/j.solener.2024.113102
Shanza Neda Hussain, Aritra Ghosh
The increasing competition of land for various purposes has led to the consideration of using it effectively while catering to energy and food security. This study investigates the integration of photovoltaics (PV) systems with farmlands that cultivate potatoes in the UK, analysing energy production and crop yields across eleven regions. Using PVsyst for solar simulations and DSSAT for crop modelling for various PV setups including both monofacial and bifacial systems in both fixed and tracking configurations were examined. This work revealed significant regional disparities in solar irradiance, temperature, and precipitation, impacting both electricity and agricultural output. This study indicates that tracking bifacial 440Wp systems (TB) generated an average of 24.6% more energy than static bifacial (SB) systems with the highest difference of 26.37% in Brighton but at the cost of reduced crop yields. The land equivalent ratio (LER) varies, with SB systems generally achieving higher values with the highest obtained value of 1.39 reflecting their balance between energy and crop production. Financial analysis demonstrates that same area tracking monofacial (SATM) configurations offer the highest internal rate of return (IRR) though there is a huge variation in the outcomes when comparing the lowest and highest there is a difference of 41.16%. The levelized cost of electricity (LCOE) was the lowest, with regions receiving more irradiance (Brighton) indicating the increased economic feasibility for the proposed system. This evaluation emphasizes the potential of agrivoltaics to optimise land use for dual purposes, promoting sustainable energy and food production while highlighting the importance of considering local climatic conditions and system design to utilise the benefits of agrivoltaics.
由于各种用途的土地竞争日益激烈,人们开始考虑在满足能源和粮食安全的同时有效利用土地。本研究调查了光伏(PV)系统与英国马铃薯种植农田的整合情况,分析了 11 个地区的能源生产和作物产量。使用 PVsyst 进行太阳能模拟,使用 DSSAT 进行作物建模,对各种光伏设置(包括固定和跟踪配置的单面和双面系统)进行了研究。这项工作揭示了太阳辐照度、温度和降水方面的显著地区差异,对电力和农业产出都产生了影响。研究表明,跟踪式双向 440Wp 系统(TB)比静态双向系统(SB)平均多发电 24.6%,其中布莱顿地区的差异最大,为 26.37%,但代价是作物减产。土地当量比(LER)各不相同,SB 系统的土地当量比通常较高,最高值为 1.39,反映了其在能源和作物产量之间的平衡。财务分析表明,同面积单面跟踪(SATM)配置的内部收益率(IRR)最高,但结果差异很大,最低和最高的内部收益率相差 41.16%。在辐照度(Brighton)较高的地区,平准化电力成本(LCOE)最低,这表明拟议系统的经济可行性更高。该评估强调了农业光伏技术在优化土地利用、促进可持续能源和粮食生产等双重目的方面的潜力,同时强调了考虑当地气候条件和系统设计以利用农业光伏技术优势的重要性。
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引用次数: 0
Enhancing performance of Cu2ZnSn(S, Se)4 solar cells via non-uniform gradient and flat bands induced by Cd substitution 通过镉替代引起的非均匀梯度和平坦带提高 Cu2ZnSn(S,Se)4 太阳能电池的性能
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.solener.2024.113063
Mengge Li , Ding Ma , Chunkai Wang , Ting Wang , Bin Yao , Yongfeng Li , Zhanhui Ding , Yuting Sun , Xiaofei Sun , Yan Zhu , Ning Ding , Liyuan Shi
Severe carrier recombination at the back (Mo/CZTSSe) and front (CZTSSe/CdS) interfaces is one of the most important reasons hindering the development of open-circuit voltage (VOC) and fill factor (FF) in Cu2ZnSn(S, Se)4 (CZTSSe) solar cells. In this study, we intentionally introduced a non-uniform distribution of Cd impurities into the middle of the absorber layer, designing and fabricating a CZTSSe solar cell with a non-uniform “V”-shaped graded bandgap structure. This structure is aimed at providing a favorable back electric field, reducing carrier recombination at the Mo/CZTSSe interface. The PCE of the CZTSSe solar cell improved from 8.88 % to 10.89 %, significantly enhancing FF and VOC. Additionally, we utilized the solar cell simulation software SCAPS-1D to simulate the position of the minimum point in the V-shaped graded bandgap and combined this with experimental results to explore the effect of Cd doping location on the performance of CZTSSe solar cells. It’s worth noting that the non-uniform Cd-doped solar cell displayed exceptional stability, demonstrating an efficiency enhancement from 10.28 % to 10.94 % after being exposed to air for 30 days.
背面(Mo/CZTSSe)和正面(CZTSSe/CdS)界面严重的载流子重组是阻碍 Cu2ZnSn(S,Se)4(CZTSSe)太阳能电池开路电压(VOC)和填充因子(FF)发展的最重要原因之一。在这项研究中,我们有意在吸收层中间引入了非均匀分布的镉杂质,设计并制造了一种具有非均匀 "V "形梯度带隙结构的 CZTSSe 太阳能电池。这种结构旨在提供有利的背电场,减少钼/CZTSSe 界面的载流子重组。CZTSSe 太阳能电池的 PCE 从 8.88% 提高到 10.89%,显著提高了 FF 和 VOC。此外,我们还利用太阳能电池仿真软件 SCAPS-1D 模拟了 V 型分级带隙中最小点的位置,并结合实验结果探讨了掺镉位置对 CZTSSe 太阳能电池性能的影响。值得注意的是,非均匀掺杂镉的太阳能电池表现出了超强的稳定性,在暴露于空气中 30 天后,效率从 10.28% 提高到了 10.94%。
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引用次数: 0
Ultra-wideband solar absorber based on refractory metal titanium for high-performance photothermal conversion 基于难熔金属钛的高性能光热转换超宽带太阳能吸收器
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.solener.2024.113095
Shiyi Song , Yan Chen , Shanjun Chen , Zao Yi , Liping Fu
In recent years, metamaterial absorbers are widely used in solar energy harvesting and utilizations. Nevertheless, it is difficult to achieve simultaneously high absorption, insensitivity with a large angle of incidence, polarization independence and, highly efficient photothermal conversion over a wide range of wavelengths for existing solar energy absorbers. Herein, an ultra-wideband and high-performance solar perfect absorber for the spectral range of 200–5000 nm has been proposed. It consists of a Ti metal substrate, a Ti-Al2O3 pattern layer with etched square annular air cavity, and a Si3N4 dielectric layer surrounding the bottom of the pattern layer. Over the spectral range spanning from 200 to 5000 nm, the average absorbance is 97.7 %, and the minimum absorbance is above 91 %. In solar energy system, its total photothermal conversion efficiency is 90.9 % at 1000 K, with as much as 96.41 % of sunlight absorbed. The interactions between surface plasmon resonance (SPR), guided mode resonance (GMR), magnetic resonance (MR), and cavity resonance (CR) are responsible for excellent performance of the ultra-broadband absorber. Additionally, the absorber is not sensitive to wide angles of incidence and is polarization independent. More interestingly, large angle incidence at TE and TM polarizations has equally excellent performance. Besides, the absorber meets a certain tolerance for geometric manufacturing errors, allowing for low-cost practical manufacturing. The designed absorber is expected to be applied to solar cells and thermo-photovoltaic devices.
近年来,超材料吸收体被广泛应用于太阳能收集和利用领域。然而,现有的太阳能吸收器很难同时实现高吸收、大入射角不敏感、偏振无关以及宽波长范围内的高效光热转换。在此,我们提出了一种光谱范围为 200-5000 纳米的超宽带、高性能太阳能完美吸收器。它由钛金属基底、带蚀刻方形环形气腔的 Ti-Al2O3 图案层和环绕图案层底部的 Si3N4 介电层组成。在 200 纳米到 5000 纳米的光谱范围内,平均吸收率为 97.7%,最小吸收率超过 91%。在太阳能系统中,1000 K 时的总光热转换效率为 90.9%,对太阳光的吸收率高达 96.41%。表面等离子体共振(SPR)、导模共振(GMR)、磁共振(MR)和空腔共振(CR)之间的相互作用造就了这种超宽带吸收器的卓越性能。此外,该吸收器对大入射角不敏感,而且不受极化影响。更有趣的是,TE 和 TM 极化的大角度入射也具有同样出色的性能。此外,该吸收器还能满足一定的几何制造误差容限,从而实现低成本的实际制造。所设计的吸收器有望应用于太阳能电池和热光电设备。
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引用次数: 0
Enhancing efficiency: A study on all-inorganic CsSnBr3 metal halide perovskites with micro-band offset using DFT and SCAPS-1D modeling 提高效率:利用 DFT 和 SCAPS-1D 建模研究具有微带偏移的无机 CsSnBr3 金属卤化物包光体
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.solener.2024.113051
Shazia Akhtar Dar , Basharat Want , Brajendra Singh Sengar
In this study, we simulated a non-toxic, all-inorganic CsSnBr3 perovskite solar cell (PSC). Using first-principles PBE functional analysis, we evaluated the optoelectronic characteristics of the CsSnBr3 and performed numerical simulations and optimizations with SCAPS-1D. Our findings indicate that CsSnBr3, possessing a direct band gap of 1.78 eV, represents an optimal inorganic perovskite material for PSCs. The micro-band offset (MBO) energy structure of ZnOS/CsSnBr3/CuI, characterized by a small energy band offset, generates an intrinsic electric field (Ebi) that greatly improves carrier transport and facilitates the separation of photogenerated electron-hole pairs, resulting in a peak power conversion efficiency (PCE) of 18.89 %. Optimization of this structure involved adjusting the doping concentrations in the electron transport layer (ETL) and hole transport layer (HTL) to 1017 cm−3 for the ETL and 1019 cm−3, respectively. Increasing the absorber layer thickness improved photovoltaic characteristics, although high defect densities negatively impacted carrier diffusion length and PSC performance. Additionally, we examined the effect of varying metal back electrode (BME) and the thermal stability analysis on the PV performance of the device The micro-band offset (MBO) energy structure, as revealed by our analysis of the carrier transport pathway, enhances energy level transitions and facilitates more efficient carrier transport. Under optimal conditions, the PSCs with the MBO-energy structure demonstrated exceptional performance, with PCE = 23.98 %, Voc = 1.40 V, Jsc = 19.68 mA/cm2, and FF = 86.74 %. These results highlight the significant potential of the MBO-energy structure for Sn-based PSCs. They offer valuable insights for developing stable, highly efficient, cost-effective, and environmentally friendly CsSnBr3-based PSCs.
在这项研究中,我们模拟了一种无毒、全无机的 CsSnBr3 包晶石太阳能电池(PSC)。通过第一原理 PBE 函数分析,我们评估了 CsSnBr3 的光电特性,并利用 SCAPS-1D 进行了数值模拟和优化。我们的研究结果表明,CsSnBr3 具有 1.78 eV 的直接带隙,是 PSC 的最佳无机包晶材料。ZnOS/CsSnBr3/CuI 的微带偏移(MBO)能量结构具有能带偏移小的特点,它产生的本征电场(Ebi)大大改善了载流子传输,促进了光生电子-空穴对的分离,从而使峰值功率转换效率(PCE)达到 18.89%。该结构的优化包括将电子传输层(ETL)和空穴传输层(HTL)的掺杂浓度分别调整到 1017 cm-3 和 1019 cm-3。尽管高缺陷密度对载流子扩散长度和 PSC 性能产生了负面影响,但增加吸收层厚度还是改善了光伏特性。此外,我们还研究了不同金属背电极(BME)和热稳定性分析对器件光伏性能的影响。 我们对载流子传输路径的分析表明,微带偏移(MBO)能量结构增强了能级转换,有利于提高载流子传输效率。在最佳条件下,具有 MBO 能量结构的 PSC 表现出卓越的性能,PCE = 23.98 %,Voc = 1.40 V,Jsc = 19.68 mA/cm2,FF = 86.74 %。这些结果凸显了 MBO 能量结构在锡基 PSC 中的巨大潜力。它们为开发稳定、高效、经济和环保的 CsSnBr3 基 PSCs 提供了宝贵的启示。
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