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Metal tungstate as an electron transport layer: Diverse preparation methods and photovoltaic applications 作为电子传输层的金属钨酸盐:多种制备方法和光伏应用
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-17 DOI: 10.1016/j.solener.2024.113007
Radwa S. Mostafa , Ahmed Mourtada Elseman , A.G. Al-Gamal , Mostafa M.H. Khalil , Mohamed M. Rashad
Nanomaterials derived from metal tungstates featuring transition metals have emerged as a focal point in electrochemical research due to their abundant natural sources, cost-effectiveness, and environmentally friendly characteristics. This review examines the potential of metal tungstate (MWOx) as an electron transport material (ETM) to enhance the performance of photovoltaic (PV) devices, proposing it as an alternative to traditional TiO2-based ETMs. The first section explores various preparation methods, including wet chemical processes, solid-state synthesis, and bombardment techniques. The second section critically investigates recent advancements in utilizing MWOx for high-performance PV devices, revealing its significant potential to replace conventional ETMs. The application of ultra-thin transition metal oxides (TMOs) in dye-sensitized, organic PV, and perovskite (PSK)-based solar cells is discussed in detail. We also highlight the rapidly expanding research interest in this topic over the past several years. Finally, we provide a perspective on the challenges and future directions in this field.
以过渡金属为特征的金属钨酸盐衍生出的纳米材料因其丰富的天然来源、成本效益和环境友好特性而成为电化学研究的焦点。本综述探讨了金属钨酸盐(MWOx)作为电子传输材料(ETM)在提高光伏(PV)设备性能方面的潜力,并建议将其作为基于二氧化钛(TiO2)的传统 ETM 的替代品。第一部分探讨了各种制备方法,包括湿化学工艺、固态合成和轰击技术。第二部分批判性地研究了将 MWOx 用于高性能光伏器件的最新进展,揭示了其取代传统 ETM 的巨大潜力。我们详细讨论了超薄过渡金属氧化物 (TMO) 在染料敏化、有机光伏和基于包光体 (PSK) 的太阳能电池中的应用。我们还重点介绍了过去几年中对这一主题迅速扩大的研究兴趣。最后,我们展望了该领域的挑战和未来发展方向。
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引用次数: 0
A comparative study on the optical performance of retro-reflective coatings before and after the aging process 老化前后逆反射涂层光学性能的比较研究
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-17 DOI: 10.1016/j.solener.2024.113006
Alessia Di Giuseppe , Aron Pazzaglia , Andrea Nicolini , Federico Rossi , Beatrice Castellani
Retro-reflective (RR) materials are largely included among the strategies to mitigate Urban Heat Island (UHI) phenomenon in the urban spaces thanks to their optical directional properties. As materials potentially used in the building exterior envelope, RR materials are subjected to outdoor aging and soiling processes, which could alter their optical behaviour. In this perspective, the investigation focuses on the characterization of the optical performance of several types of RR plaster coatings after outdoor aging and soiling processes. The RR plaster coatings were previously developed and studied, before undergoing the outdoor exposure. The RR samples were developed covering the support with a reflective white paint and glass beads. Five different microsphere diameter ranges and three different microsphere superficial density ranges have been employed. In this paper, the RR plaster coatings were tested in terms of optical properties after outdoor aging and soiling and results were compared with data of the same plaster coatings pre-aging. Generally, all RR aged samples show a lower solar reflectance in the Vis region with respect to the pre-aging conditions. The RR behaviour is qualitatively maintained after aging and soiling. The RR sample made of glass beads of 200–300 μm diameter range could represent the best solution both in pre- and post-conditions and both in terms of solar reflectance and retro-reflective behaviour, regardless of the density of microspheres used.
逆反射(RR)材料凭借其光学定向特性,在很大程度上被纳入缓解城市热岛现象的策略中。作为可能用于建筑外围护结构的材料,RR 材料会受到户外老化和脏污过程的影响,从而改变其光学特性。从这一角度出发,研究重点是几种 RR 灰泥涂层在经过户外老化和弄脏过程后的光学性能特征。在进行户外曝晒之前,已对 RR 灰泥涂层进行了开发和研究。开发的 RR 样品在支架上覆盖了反光白色涂料和玻璃珠。采用了五种不同的微球直径范围和三种不同的微球表面密度范围。本文测试了 RR 灰泥涂层在户外老化和弄脏后的光学特性,并将结果与相同灰泥涂层老化前的数据进行了比较。一般来说,与老化前相比,所有老化后的 RR 样品在可见光区域的太阳反射率都较低。经过老化和弄脏后,RR 的性能在质量上得以保持。由直径范围为 200-300 微米的玻璃珠制成的 RR 样品,无论在老化前还是老化后条件下,无论在太阳反射率还是逆反射特性方面,都是最佳解决方案,而与所使用的微球密度无关。
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引用次数: 0
Trapezoidal solar evaporators with salt resistant and extraction working modes 梯形太阳能蒸发器具有耐盐和提取工作模式
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-16 DOI: 10.1016/j.solener.2024.112998
Fahad Nawaz , Qi Zhao , Mengyuan Qiang, Yalu Mo, Yihong Liu, Yawei Yang, Wenxiu Que
Interfacial solar evaporators utilize sunlight to produce sustainable freshwater but salt accumulation on evaporator surfaces hinders its efficiency. In this study, we present a novel bilayer symmetric evaporator for interfacial solar evaporation, composed of trapezoidal structures designed for efficient salt resistance, and salt extraction. The evaporator is made of carbonized coconut fiber cloth and incorporates the innovative Symmetrical Trapezoidal Salt Resistance (STS-R) and Symmetrical Trapezoidal Salt Resistance Extraction (STS-E) models. This innovative design achieved an evaporation rate of 2.26 kg m–2 h–1 under one sun, with a conversion efficiency of 80.16 %. The evaporator showed excellent salt resistance and salt extraction performance in 14 ∼ 16 wt% NaCl solutions, as well as sea salt solution while maintaining a high evaporation rate. STS enables directional ion migration, enhances capillary action and wicking, maximizes surface area and light absorption, promotes heat localization, and facilitates a self-cleaning mechanism. This unique approach effectively tackles salt accumulation issues in water purification and desalination processes.
界面太阳能蒸发器利用太阳光生产可持续淡水,但蒸发器表面的盐分积累阻碍了其效率。在这项研究中,我们提出了一种用于界面太阳能蒸发的新型双层对称蒸发器,该蒸发器由梯形结构组成,设计用于高效抗盐和提取盐分。蒸发器由碳化椰子纤维布制成,采用了创新的对称梯形抗盐(STS-R)和对称梯形抗盐萃取(STS-E)模型。这一创新设计在一个太阳下的蒸发率达到 2.26 kg m-2 h-1,转化效率为 80.16 %。该蒸发器在 14 ∼ 16 wt% NaCl 溶液以及海盐溶液中均表现出优异的耐盐性和盐萃取性能,同时还能保持较高的蒸发率。STS 可使离子定向迁移,增强毛细作用和吸水能力,最大限度地扩大表面积和光吸收,促进热定位,并有利于自清洁机制。这种独特的方法可有效解决水净化和海水淡化过程中的盐积累问题。
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引用次数: 0
Picosecond pulsed laser scribing of Cd2SnO4-based CdTe thin-film solar cells on flexible glass 在柔性玻璃上用皮秒脉冲激光刻划基于 Cd2SnO4 的碲化镉薄膜太阳能电池
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-16 DOI: 10.1016/j.solener.2024.112999
Kai Huang, Qiuchen Wu, Xiangxin Liu
CdTe photovoltaic modules are the most commercially successful thin-film solar cells. In particular, flexible CdTe modules are a promising development in photovoltaic architecture. Cd2SnO4 (CTO) is a low-cost transparent conductive material with excellent optical and electrical properties. Although laser scribing is commonly used to produce cell interconnects in the manufacturing of thin-film PV modules, the laser scribing process window for CTO-based CdTe cells is narrow, and more research is needed on direct laser scribing of flexible CdTe solar cells. In this study, the picosecond pulsed laser scribing of CdTe solar cells with CTO front electrodes and flexible glass substrates was investigated using lasers with the wavelengths of 355 and 532 nm. The flexible cells were suctioned onto a working platform, and a direct ablation method was adopted. The damage and removal thresholds of the CTO, CdTe, and Ni layers were studied and the effects of the spot spacing, multilayer conditions, and laser polarization state were investigated. A method for determining the scribing parameters was proposed. Very smooth scribing grooves were obtained using the optimized laser scribing process. The series and shunt resistances of the cells after laser scribing showed no significant differences compared to those of the control cells.
碲化镉光伏组件是商业上最成功的薄膜太阳能电池。特别是,柔性碲化镉模块是光伏结构中一个很有前途的发展方向。Cd2SnO4(CTO)是一种低成本的透明导电材料,具有优异的光学和电气性能。虽然在薄膜光伏组件的制造过程中,激光划片通常用于生产电池互连器件,但基于 CTO 的碲化镉电池的激光划片工艺窗口较窄,因此需要对柔性碲化镉太阳能电池的直接激光划片进行更多研究。本研究使用波长分别为 355 和 532 nm 的激光器,研究了皮秒脉冲激光划片 CdTe 太阳能电池(带 CTO 前电极和柔性玻璃基板)。将柔性电池吸到工作平台上,采用直接烧蚀法。研究了 CTO、CdTe 和 Ni 层的损伤和去除阈值,并探讨了光斑间距、多层条件和激光偏振态的影响。提出了一种确定划线参数的方法。使用优化的激光划线工艺获得了非常平滑的划线沟槽。激光划线后电池的串联电阻和并联电阻与对照电池相比没有明显差异。
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引用次数: 0
Modeling Escherichia coli inactivation during solar disinfection: Effects of UV intensity, water temperature, and turbidity 太阳能消毒过程中的大肠杆菌灭活模型:紫外线强度、水温和浑浊度的影响
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-15 DOI: 10.1016/j.solener.2024.113000
Ekene Jude Nwankwo , Benjamin Nnamdi Ekwueme
The study aimed to develop a comprehensive regression model to estimate the inactivation rate constant of Escherichia coli during Solar Disinfection (SODIS) of drinking water. The model incorporates key parameters: UV intensity, water temperature, and turbidity, including their interactions and quadratic terms. The effects of expressing water temperature as maximum absolute temperature (Tm) and maximum temperature increase (ΔTm) on multicollinearity, significance, and model adequacy were also investigated. Experiments were conducted over 5 months to obtain the regression dataset, covering various combinations of these parameters. The results showed that the model using UV intensity and maximum temperature increase (ΔTm) as predictors achieved the highest performance (R-square: 0.93, predicted R-square: 0.91, RMSE: 0.261). Using ΔTm improved predictive accuracy, reduced collinearity, and enhanced significance compared to Tm. Turbidity in the range of 1 – 30 NTU was significant in 40 % of models. Interactions were found between UV intensity and temperature, and temperature and turbidity, while no interaction was found between UV intensity and turbidity. The study highlights the importance of considering all possible regression models to avoid misleading interpretations of parameter significance. The developed model can estimate day-to-day fluctuations in SODIS efficiency, exposure period, and SODIS applicability in various regions, providing valuable insights for optimizing SODIS treatment strategies.
该研究旨在建立一个综合回归模型,以估算饮用水太阳能消毒(SODIS)过程中大肠埃希氏菌的灭活率常数。该模型包含以下关键参数紫外线强度、水温和浊度,包括它们之间的相互作用和二次项。此外,还研究了以最高绝对温度 (Tm) 和最高温度增幅 (ΔTm) 表示水温对多重共线性、显著性和模型充分性的影响。通过 5 个月的实验获得了回归数据集,涵盖了这些参数的各种组合。结果表明,使用紫外线强度和最大温升(ΔTm)作为预测因子的模型性能最高(R 方:0.93,预测 R 方:0.91,RMSE:0.261)。与 Tm 相比,使用 ΔTm 提高了预测精度,减少了共线性,并增强了显著性。在 40% 的模型中,浊度在 1 - 30 NTU 范围内具有显著性。紫外线强度与温度、温度与浊度之间存在交互作用,而紫外线强度与浊度之间没有交互作用。这项研究强调了考虑所有可能的回归模型的重要性,以避免误导对参数重要性的解释。所开发的模型可估算出 SODIS 效率、暴露期和 SODIS 在不同地区适用性的逐日波动,为优化 SODIS 处理策略提供了宝贵的见解。
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引用次数: 0
Ambient processed highly stable self-powered lead-free Cs2AgBiBr6 double perovskite photodetector in HTM-free architecture with Carbon as electrode 以碳为电极、采用无 HTM 结构的常温加工高稳定自供电无铅 Cs2AgBiBr6 双包晶光电探测器
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-15 DOI: 10.1016/j.solener.2024.112989
B. Kumaar Swamy Reddy , Aswin S. Kumar , R. Akash , Easwaramoorthi Ramasamy , Sushmee Badhulika , Ganapathy Veerappan , Pramod H. Borse
Conventional Lead-based hybrid perovskite photodetectors face significant challenges due to toxicity and poor ambient stability. This study contributes to the development of sustainable and efficient photodetectors by leveraging the exceptional properties of Lead-free Cs2AgBiBr6 double perovskite. A key feature of this work is the use of Cs2AgBiBr6 in a hole transport material (HTM)-free architecture with carbon electrodes, simplifying fabrication and enhancing device stability. The Cs2AgBiBr6 films are fabricated using a one-step spin-coating method under ambient conditions. Structural and optical analysis confirms the formation of a cubic perovskite phase with a 2.02 eV bandgap. The photodetector operates in a self-powered mode, detecting a broad spectral range from 350 to 600 nm, with impressive responsivity (50 mA/W), detectivity (5.1 × 1011 Jones), and a fast rise time (160 ms). The Type-II band alignment at the Cs2AgBiBr6-TiO2 interface enables the self-powered operation. The inherent structural stability of Cs2AgBiBr6 results in excellent durability, maintaining performance over multiple photocycles (>500), prolonged exposure to simulated sunlight (>1 h), high humidity (RH ∼ 90 % for 4 h), and elevated temperatures (80 °C for 4 h). Moreover, the device retained its responsivity for more than 60 days when stored under ambient conditions without encapsulation. With its simplified HTM-free architecture and Carbon electrode, the detector exhibits excellent photoresponse and resilience under harsh conditions, demonstrating the potential of Cs2AgBiBr6 in addressing the lead toxicity and stability issues in photodetectors.
由于毒性和环境稳定性差,传统的铅基混合包晶光电探测器面临着巨大挑战。本研究利用无铅 Cs2AgBiBr6 双包晶石的优异特性,为开发可持续的高效光电探测器做出了贡献。这项研究的一个主要特点是将 Cs2AgBiBr6 用于无空穴传输材料(HTM)结构中的碳电极,从而简化了制造过程并提高了器件的稳定性。Cs2AgBiBr6 薄膜是在环境条件下采用一步旋涂法制造的。结构和光学分析证实,形成的立方包晶相具有 2.02 eV 带隙。该光电探测器以自供电模式工作,可探测 350 纳米到 600 纳米的宽光谱范围,具有令人印象深刻的响应度(50 mA/W)、探测度(5.1 × 1011 琼斯)和快速上升时间(160 毫秒)。Cs2AgBiBr6-TiO2 界面上的 II 类波段排列实现了自供电运行。Cs2AgBiBr6 固有的结构稳定性使其具有出色的耐用性,在多次光周期(500 次)、长时间暴露于模拟阳光(1 小时)、高湿度(4 小时内相对湿度为 90%)和高温(4 小时内温度为 80 °C)下仍能保持性能。此外,该器件在无封装的环境条件下存放 60 多天后仍能保持其响应性。由于采用了简化的无 HTM 结构和碳电极,该检测器在恶劣条件下表现出卓越的光响应和弹性,证明了 Cs2AgBiBr6 在解决光检测器中铅毒性和稳定性问题方面的潜力。
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引用次数: 0
Design and realization of a new solar dryer assisted by a parabolic trough concentrator (PTC) with a dual-axis solar tracker 抛物槽聚光器(PTC)与双轴太阳能跟踪器辅助新型太阳能干燥器的设计与实现
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-15 DOI: 10.1016/j.solener.2024.113001
Seif Eddine Bousbia Salah , Abdelouahab Benseddik , Noureddine Meneceur , Ali Zine , Khalil Deghoum
This article presents the design, fabrication, and testing of a new solar dryer equipped with a tracking system. The dryer was assisted by a cylindrical-parabolic concentrator which moved along two vertical and horizontal axes. The study was conducted at El-Oued University (latitude 33°23′N and longitude 6°51′E). The experimental performance evaluation involved drying 10 kg of apricots from 69 % to 8 % moisture content (wb). The thermal efficiency of the dryer was tested under no-load and full-load conditions. The results indicated that the solar dryer achieved a temperature of up to 115 °C at the receiver in the focal line and 70 °C in the drying chamber, which was sufficient for effective drying of various agricultural products. Additionally, an economic analysis further substantiates the viability of our solar dryer, showcasing a notably low capital cost and negligible electricity expenses. With a substantial difference in the cost of fresh versus dried apricots, our system boasts a reduced payback period estimated at 0.43 years. This research demonstrates the potential of using solar power to dry crops and reduce dependence on fossil fuels.
本文介绍了一种配备跟踪系统的新型太阳能干燥器的设计、制造和测试。该干燥器由一个沿两个垂直和水平轴移动的圆柱抛物面聚光器辅助。研究在 El-Oued 大学(北纬 33°23′,东经 6°51′)进行。实验性能评估包括将 10 公斤杏子从含水量 69% 干燥到含水量 8%。在空载和满载条件下测试了干燥机的热效率。结果表明,太阳能干燥器在焦线接收器处的温度高达 115 °C,在干燥室中的温度为 70 °C,足以有效干燥各种农产品。此外,经济分析进一步证实了太阳能干燥机的可行性,表明其资本成本明显较低,电费支出可忽略不计。由于新鲜杏子和干杏子的成本差别很大,我们系统的投资回收期估计为 0.43 年。这项研究证明了利用太阳能干燥农作物和减少对化石燃料依赖的潜力。
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引用次数: 0
Enhancing photovoltaic thermal (PVT) performance with hybrid solar collector using phase change material, porous media, and nanofluid 利用相变材料、多孔介质和纳米流体提高混合太阳能集热器的光电热(PVT)性能
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-14 DOI: 10.1016/j.solener.2024.112983
Zainab M. Mahdi , Ali N. Al-Shamani , Ahmed Al-Manea , Hazim A. Al-zurfi , Raed Al-Rbaihat , K. Sopian , Ali Alahmer
This study presents a novel and low-complexity cooling system designed to enhance the performance of Photovoltaic Thermal (PVT) systems integrated with a Hybrid Air-Water Solar Collector (HAWSC), termed traditional PVT-HAWSC systems. The research addresses the limitations of these systems, such as low heat transfer fluid outlet temperature, thermal exergy, thermal and electrical efficiencies, and thermal power. This is achieved by incorporating phase change material (PCM), porous media (PM), and multi-walled carbon nanotubes (MWCNT)-water nanofluid into the traditional PVT-HAWSC system, resulting in a modified PVT-HAWSC system. The modified system features a double-pass single-duct air solar collector with steel wool-PM and a sheet-tube water thermal collector integrated with paraffin wax-PCM. Experimental investigations were conducted under varying flow rates of air, water, and nanofluid. The performance analysis included exergy, energy, thermal, and electrical assessments. Results demonstrated that fluid type and flow rate significantly impact performance. The modified system with nanofluid reduced the PV panel surface temperature by 28 °C, compared to 22 °C without nanofluid. Additionally, the average daily improvements in overall efficiency, total thermal efficiency, and electrical efficiency were 16.49 %, 56.25 %, and 93.64 % for the modified system, compared to 12.80 %, 43.16 %, and 79.90 % for the traditional system. Total thermal energy gained and average daily exergy efficiency were 302.72 W and 14.32 % for the modified system, compared to 235.4 W and 14 % for the traditional system. The modified PVT-HAWSC system achieved lower levelized cost of energy (LCOE) of 0.043 $/kWh, a 4.36-year payback, 36.55 tons of CO2 mitigation, and $529.98 in carbon credits.
本研究提出了一种新颖、低复杂度的冷却系统,旨在提高与混合空气-水太阳能集热器(HAWSC)集成在一起的光伏热(PVT)系统(称为传统 PVT-HAWSC 系统)的性能。该研究解决了这些系统的局限性,如低导热流体出口温度、热放热、热效率、电效率和热功率。为此,研究人员在传统的 PVT-HAWSC 系统中加入了相变材料 (PCM)、多孔介质 (PM)、多壁碳纳米管 (MWCNT) - 水纳米流体,形成了改进型 PVT-HAWSC 系统。改进后的系统采用了带有钢棉-PM 的双通道单导管空气太阳能集热器和集成了石蜡-PCM 的片管水热集热器。在空气、水和纳米流体的不同流速下进行了实验研究。性能分析包括放能、能量、热能和电能评估。结果表明,流体类型和流速对性能有很大影响。使用纳米流体的改良系统可将光伏板表面温度降低 28 °C,而不使用纳米流体时仅为 22 °C。此外,改良系统的总体效率、总热效率和电效率的日均提高率分别为 16.49%、56.25% 和 93.64%,而传统系统的日均提高率分别为 12.80%、43.16% 和 79.90%。改进型系统获得的总热能和日平均放能效率分别为 302.72 瓦和 14.32%,而传统系统分别为 235.4 瓦和 14%。改进后的 PVT-HAWSC 系统的平准化能源成本(LCOE)较低,为 0.043 美元/千瓦时,投资回收期为 4.36 年,减少了 36.55 吨二氧化碳排放,并获得了 529.98 美元的碳信用额度。
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引用次数: 0
Managing photovoltaic Waste: Sustainable solutions and global challenges 光伏废物管理:可持续的解决方案和全球挑战
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-14 DOI: 10.1016/j.solener.2024.112985
Balaqis Al Zaabi, Aritra Ghosh
The global shift to clean energy has resulted in a significant increase in photovoltaic (PV) panel installations. However, with their limited lifespan of 25–30 years, end-of-life (EoL) management is becoming an environmental and economic challenge to the sector. Currently, PV panels are disposed of in landfills, raising concerns about resource loss and environmental contamination. This research paper addresses this by using a novel quantitative modelling framework that employs historical data and Bass diffusion equations to project future PV waste generation in key markets, including China, India, the USA, Japan, and Germany. The findings emphasise the necessity of exploring alternative EoL management options, such as repair, reuse, and recycling, to prevent resource loss and environmental contamination. The study’s novel methodology and detailed analysis highlight a lack of specific regulations for PV waste management globally. The study necessitates global policy frameworks, international standards, and public awareness to support the transition to a circular economy.
全球向清洁能源的转变导致光伏(PV)电池板安装量大幅增加。然而,由于光伏板的使用寿命只有 25-30 年,其报废(EoL)管理正成为该行业面临的环境和经济挑战。目前,光伏电池板被丢弃在垃圾填埋场,引起了人们对资源损失和环境污染的担忧。针对这一问题,本研究论文采用了一个新颖的定量建模框架,利用历史数据和巴斯扩散方程来预测未来主要市场(包括中国、印度、美国、日本和德国)的光伏废物产生量。研究结果强调,有必要探索替代性的 EoL 管理方案,如维修、再利用和回收,以防止资源损失和环境污染。研究采用的新颖方法和详细分析凸显了全球光伏废物管理缺乏具体法规的问题。该研究认为有必要制定全球政策框架、国际标准并提高公众意识,以支持向循环经济过渡。
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引用次数: 0
Single-stage fabrication of buffer and window layers of CIGS thin-film solar cells using pulsed laser deposition 利用脉冲激光沉积技术单级制造 CIGS 薄膜太阳能电池的缓冲层和窗口层
IF 6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-12 DOI: 10.1016/j.solener.2024.112993
Evripides Kyriakides , Christiana Nicolaou , Panagiotis S. Ioannou , Paris Papagiorgis , Grigorios Itskos , John Giapintzakis
Photovoltaic devices based on Cu(In,Ga)Se2 (CIGS) are showing great promise as sources of clean and renewable energy production in the global efforts to reverse climate change. They hold several advantages over other technologies and are continuously being improved, leading to ever higher device efficiencies and lifetimes. However, state-of-the-art CIGS-based solar cells require a variety of techniques for the deposition of their constituent layers.
This work reports on the utilization of pulsed laser deposition (PLD) as a single technique for the preparation of the buffer (CdS) and window (intrinsic and Al-doped ZnO) layers of a complete CIGS-based solar cell. Employing a single deposition technique for the buffer and window layers greatly reduces manufacturing complexity. Furthermore, it potentially decreases processing time and fabrication costs through streamlined production lines. The methods and materials presented are also applicable to other solar cell types, such as Cu2ZnSnS4-based solar cells and other thin-film technologies.
The results presented herein discuss the methodology employed for the realization of the single-stage growth objective. The properties of the PLD-grown thin films with respect to structure, composition, and morphology were parametrically investigated through X-ray diffraction, energy-dispersive X-ray spectroscopy, scanning electron microscopy, and atomic force microscopy. These characterization results enabled the optimization of the PLD process parameters for each individual thin film, leading to improved device performance. Optoelectronic measurements were carried out in photovoltaic testing systems to assess the behavior of the complete solar cell. Using the optimal process parameters produced solar cells with PLD-grown buffer and window layers with 10.44% efficiency.
基于铜(In,Ga)Se2(CIGS)的光伏设备作为清洁的可再生能源,在全球努力扭转气候变化的过程中显示出巨大的前景。与其他技术相比,它们具有多项优势,并在不断改进,使设备效率和寿命不断提高。然而,最先进的 CIGS 太阳能电池需要多种技术来沉积其组成层。这项研究报告了利用脉冲激光沉积 (PLD) 作为一种单一技术来制备完整的 CIGS 太阳能电池的缓冲层(CdS)和窗口层(本征和掺铝 ZnO)。采用单一沉积技术制备缓冲层和窗口层可大大降低制造复杂性。此外,它还能通过简化生产线缩短加工时间,降低制造成本。本文介绍的方法和材料也适用于其他类型的太阳能电池,如基于 Cu2ZnSnS4 的太阳能电池和其他薄膜技术。通过 X 射线衍射、能量色散 X 射线光谱、扫描电子显微镜和原子力显微镜,对 PLD 生长的薄膜在结构、成分和形态方面的特性进行了参数化研究。这些表征结果有助于优化每种薄膜的 PLD 工艺参数,从而提高器件性能。在光伏测试系统中进行了光电测量,以评估整个太阳能电池的性能。使用最佳工艺参数生产出的带有 PLD 生长缓冲层和窗口层的太阳能电池效率为 10.44%。
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