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2022 IEEE 49th Photovoltaics Specialists Conference (PVSC)最新文献

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Performance and stability of electrodeposited mixed perovskites $text{MAPbI}_{3-mathrm{x}}text{Cl}_{mathrm{x}}$ and $text{MA}_{1-mathrm{y}}text{FA}_{mathrm{y}}text{PbI}_{3-mathrm{x}}text{Br}_{mathrm{x}}$ 电沉积混合钙钛矿的性能和稳定性$text{MAPbI}_{3- mathm {x}}text{Cl}_{ mathm {x}}$和$text{MA}_{1- mathm {y}}text{FA}_{ mathm {y}}text{PbI}_{3- mathm {x}}text{Br}} { mathm {x}}$
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938928
Mirella Al Katrib, L. Perrin, E. Planès
Electrodeposition was investigated in this work as a substitute method to develop large area perovskite active layer for solar device application. Along with the simple MAPbI3 perovskite, the deposition of mixed $text{MAPbI}_{3-mathrm{x}}text{Cl}_{mathrm{x}}$ and $text{MA}_{1-} {}_{mathrm{y}}text{FA}_{mathrm{y}}text{PbI}_{3-mathrm{x}}text{Br}_{mathrm{x}}$ perovskites was studied. This present study is one of its kind, since these mixed perovskite were never developed using electrodeposition before. It was detected that using these mixed perovskites in a solar device enhances its photovoltaic activity. It also enhances its stability when evaluated in mild ageing conditions (40°C, under vacuum or ambient atmosphere) during 500h. The different perovskites fabricated using electrodeposition experience a maturation phenomenon.
本文研究了电沉积法制备大面积钙钛矿活性层的替代方法。除了简单的MAPbI3钙钛矿外,还研究了混合钙钛矿$text{MAPbI}_{3- mathm {x}}text{Cl}_{ mathm {x}}$和$text{MA}_{1-} {{ mathm {y}}text{FA} { mathm {y}}text{PbI}_{3- mathm {x}}text{Br} { mathm {x}}$的沉积。目前的研究是此类研究中的一个,因为这些混合钙钛矿以前从未使用电沉积方法开发过。研究发现,在太阳能器件中使用这些混合钙钛矿可以增强其光伏活性。当在轻度老化条件下(40°C,真空或环境气氛下)500h评估时,它也增强了其稳定性。采用电沉积法制备的不同钙钛矿均经历成熟现象。
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引用次数: 0
Planar Transparent Conductive Oxide/Ag Rear Contacts for High Efficiency III-V Photovoltaics 用于高效III-V型光伏的平面透明导电氧化物/银后触点
Pub Date : 2022-06-05 DOI: 10.1109/pvsc48317.2022.9938673
Christopher Gregory, Sean J. Babcock, R. King
Photon recycling in photovoltaic devices can be attained by using highly reflective back surfaces. Some of the highest reflectance surfaces are composed of a plane of dielectric material deposited on a highly reflective metal such as Ag or Au. Although optically effective, the use of a planar dielectric layer complicates electrical contact to the device, leading to approaches such as point contacts. A simple solution-that may not result in significant optical or resistive losses-is to use a planar transparent conductive oxide (TCO) layer instead of a dielectric layer. This work investigates the viability of a such a contact. It is observed that contact resistivities of the TCO/Ag stack on a highly doped AlGaAs or GaAs contact layer are below 0.1 Ω cm2 for TCO doping concentrations on the order of 1019 cm-3. The contact resistivity can be reduced further by increasing the doping in the semiconductor layer. Internal hemispheric reflectances of the proposed contacts are expected to reach up to 98% at the wavelength of interest, facilitating photon recycling. The performance of this contact structure suggests use in technologies such as photonic power converters and thermophotovoltaics.
光电器件中的光子回收可以通过使用高反射背表面来实现。一些反射率最高的表面是由沉积在高反射率金属(如Ag或Au)上的介电材料组成的。虽然光学上有效,但平面介质层的使用使器件的电接触变得复杂,导致诸如点接触的方法。一个简单的解决方案——可能不会导致显著的光学或电阻损失——是使用平面透明导电氧化物(TCO)层代替介电层。这项工作调查了这种接触的可行性。当TCO掺杂浓度为1019 cm-3量级时,高掺杂AlGaAs或GaAs接触层上的TCO/Ag堆叠的接触电阻率低于0.1 Ω cm2。通过增加半导体层中的掺杂,可以进一步降低接触电阻率。所提出的触点的内部半球反射率有望在感兴趣的波长达到98%,促进光子回收。这种接触结构的性能建议在诸如光子功率转换器和热光伏等技术中使用。
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引用次数: 0
Combining nanoscale 3D printing with spark ablation to achieve novel nanostructured surfaces for photovoltaic applications 结合纳米级3D打印和火花烧蚀,实现光伏应用的新型纳米结构表面
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938859
I. Panžić, Alexander Jelinek, Floren Radovanović-Perić, D. Kiener, V. Mandić
Laser polymerization has emerged as a direct writing technique allowing the fabrication of complex 3D structures with microscale resolution. The technique provides rapid prototyping capabilities for a broad range of applications, but to meet the growing interest in 3D nanoscale structures the resolution limits need to be pushed beyond the 100 nm benchmark, which is challenging in practical implementations. By using a two-photon polymerization process precise structures in the range of 40 to 50 nm can be achieved. Subsequent post-processing of the printed nanostructures by means of plasma etching or pyrolysis opens the possibilities to obtain even smaller 3D structures, only limited by the mechanical properties of the polymerize resist and the geometry. On the other hand, spark ablation recently emerged as a technique capable of preparing reproducibly sized and clean nanoparticles in a cost-effective manner. Here we employ the outcome of combining the abovementioned processes. Spark ablation process was used to decorate the printed 3D surface to yield specific surfaces with metal/metal oxide core-shell nanoparticles. Broad characterization was applied using microscopy (SEM, AFM), mechanical testing (in situ SEM mechanical testing), diffraction analysis (XRD), and electrical characterization (J/V)) before and after the assembly of complete solar cells. Namely, such formations were found to be prosperous for electron transport layers in perovskite solar cells.
激光聚合已经成为一种直接写入技术,允许制造具有微尺度分辨率的复杂3D结构。该技术为广泛的应用提供了快速成型能力,但为了满足对3D纳米结构日益增长的兴趣,分辨率限制需要超越100纳米基准,这在实际实施中具有挑战性。通过双光子聚合工艺,可以在40 ~ 50 nm范围内获得精确的结构。随后通过等离子体蚀刻或热解的方式对打印的纳米结构进行后处理,可以获得更小的3D结构,仅受聚合抗蚀剂的机械性能和几何形状的限制。另一方面,火花烧蚀最近成为一种能够以经济有效的方式制备可重复大小和清洁纳米颗粒的技术。这里我们使用结合上述过程的结果。采用火花烧蚀工艺对3D打印表面进行修饰,获得金属/金属氧化物核壳纳米颗粒的特定表面。在整个太阳能电池组装前后,使用显微镜(SEM, AFM),力学测试(原位SEM力学测试),衍射分析(XRD)和电学表征(J/V)进行了广泛的表征。也就是说,这种结构被发现是钙钛矿太阳能电池中电子传输层的繁荣。
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引用次数: 0
Implications of Agriculturally Co-Located Solar PV Installations on the FEW Nexus in the Central Valley 在中央山谷的少数联系上农业共同定位的太阳能光伏装置的影响
Pub Date : 2022-06-05 DOI: 10.1109/pvsc48317.2022.9938746
Jacob T. Stid, Siddharth Shukla, A. Anctil, A. Kendall, D. Hyndman
Understanding agriculturally co-located solar PV installation practices and preferences is imperative to foster a future where solar power and agriculture co-exist with limited impact on agricultural production. We investigate the impacts of adjacently co-locating solar PV and agriculture on agricultural fields in California’ Central Valley. We recently developed a comprehensive remotely-sensed dataset of 694 arrays (2,052 MW) which are agriculturally adjacent co-located. We calculated the food production, electricity generation, and change in water consumption relative to the prior agricultural land use for the expected 25 year lifespan of each array. We calculated that by 2042, these arrays which converted 34 km2 of cropland would remove 1.7 trillion kcal of crop from production. Assuming cropland irrigation was forgone rather than redistributed, the total forgone irrigation water use exceeded operation and maintenance water use by a factor of 7. We also estimated the expected value of generated electricity and show that these installations are profitable, typically exceeding lost revenue from agricultural production by a factor of 15. With its profitability, agricultural co-location will likely continue to expand. Unregulated conversion of high value land could have impacts on future crop prices and availability. Thus, our research suggests the need to account for location-specific food and water resources when co-locating solar PV to reduce impacts on U.S. agricultural production and water as solar becomes more prevalent. Our results also indicate a potential use of renewable energy as a method for agricultural risk management in regions of high water stress and years of drought.
了解农业太阳能光伏安装的实践和偏好对于促进太阳能和农业共存的未来至关重要,并且对农业生产的影响有限。我们研究了太阳能光伏与农业相邻共存对加州中央山谷农田的影响。我们最近开发了一个综合的遥感数据集,其中包括694个阵列(2,052 MW),这些阵列在农业上相邻并置。我们计算了每个阵列预期25年寿命的粮食生产、发电和相对于先前农业用地的用水量变化。我们计算出,到2042年,这些转化34平方公里农田的阵列将从生产中减少1.7万亿千卡的作物。假设放弃农田灌溉而不是重新分配,放弃的灌溉用水总量将超过运行和维护用水的7倍。我们还估计了发电的预期价值,并表明这些设施是有利可图的,通常是农业生产收入损失的15倍。凭借其盈利能力,农业托管可能会继续扩大。不受管制的高价值土地转换可能对未来的作物价格和供应量产生影响。因此,我们的研究表明,在太阳能光伏发电日益普及的情况下,需要考虑到特定地点的食物和水资源,以减少对美国农业生产和水的影响。我们的研究结果还表明,在高水资源压力和多年干旱的地区,可再生能源可能被用作农业风险管理的一种方法。
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引用次数: 0
Elimination of the carbon-rich layer in Cu2ZnSn(S, Se)4 absorbers prepared from nanoparticle inks 纳米油墨制备Cu2ZnSn(S, Se)4吸收剂中富碳层的消除
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938678
S. Campbell, M. Duchamp, N. Beattie, Michael D K Jones, G. Zoppi, V. Barrioz, Y. Qu
Kesterite Cu2ZnSn(S, Se)4 (CZTSSe) is a promising photovoltaic material attracting significant research interests in recent years. Among the variety of techniques employed for preparation of the absorber thin films, the best results are observed for a hydrazine-based method with efficiency up to 12.6 %. On the other hand, Cu2ZnSnS4 (CZTS) nanoparticle inks annealed in the presence of Se have shown efficiency as high as 9.3 %. Importantly, CZTS nanoparticle inks have the power to be compatible with high volume, high value manufacturing with a variety of substrates including flexible foils, plastics and ultra-thin glass. However, one of the current limitations of the nanoparticle ink technology is the presence of a fine-grain (FG) layer between the CZTSSe large grain (LG) layer and the back contact. The presence of this FG layer is likely to reduce device performance via carrier recombination through traps, interface states and increased grain boundary density. CZTS nanoparticles were synthesized by injection of cold sulphur $({25} hat{mathrm{A}}{ }^{circ}mathrm{C})$ into hot metallic precursors ($({225} hat{mathrm{A}}{ }^{circ}mathrm{C})$). The long carbon chain molecule, oleylamine used in the nanoparticle synthesis step is believed to be the direct reason of the FG layer. Herein, a higher soft-baking temperature of ${400} hat{mathrm{A}}{ }^{circ}mathrm{C}$ is studied to evaporate the carbon rich solvent efficiently from the nanoparticle precursor thin films before the selenization process. As a result, the absorber is found to be composed of a single LG CZTSSe layer where the carbon-rich FG layer is eliminated.
Kesterite Cu2ZnSn(S, Se)4 (CZTSSe)是近年来备受关注的一种极具发展前景的光伏材料。在制备吸收剂薄膜的各种技术中,以肼为基础的方法效果最好,效率高达12.6%。另一方面,在Se存在下退火的Cu2ZnSnS4 (CZTS)纳米颗粒油墨的效率高达9.3%。重要的是,CZTS纳米颗粒油墨具有与各种基材(包括柔性箔、塑料和超薄玻璃)的大批量、高价值制造兼容的能力。然而,目前纳米颗粒油墨技术的局限性之一是在CZTSSe大颗粒(LG)层和背面接触之间存在细颗粒(FG)层。该FG层的存在可能会通过陷阱、界面态和晶界密度增加的载流子重组来降低器件性能。将冷硫$({25} hat{mathrm{A}}{ circ}mathrm{C})$注入热金属前驱体$({225} hat{mathrm{A}}{ circ}mathrm{C})$中,合成了CZTS纳米粒子。在纳米颗粒合成步骤中使用的长碳链分子,油胺被认为是FG层形成的直接原因。在硒化前,研究了较高的软焙温度${400} hat{ mathm {a}}{}^{circ} mathm {C}$使富碳溶剂从纳米颗粒前驱体薄膜中高效蒸发。结果发现,吸收剂由单一的LG CZTSSe层组成,其中富碳FG层被消除。
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引用次数: 0
Demystifying the effect of hydrogen treatment on silicon photovoltaics 揭开氢处理对硅光伏的影响
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938621
Govind Nanda, Sara M. Almenabawy, R. Prinja, G. Sharma, N. Kherani
Interactions between hydrogen and silicon play an integral role in determining the quality of surface and bulk passivation of various device structures in silicon photovoltaics. The efficacy of a hydrogen treatment method is known to be dependent on whether the interacting hydrogen species is atomic, ionic, or molecular. Furthermore, these concentrations can be altered by controlling the substrate temperature of the silicon substrate. Moreover, an important consideration is the time and atmosphere the treatment is carried out in, as it influences the desorption of hydrogen from silicon. Hence, it is important to undertake a comprehensive investigation of both the theoretical and experimental aspects of hydrogen passivation of silicon devices, thereby developing a clear understanding of how hydrogen behaves within different solar cell structures, and its dependence on substrate properties. In the theoretical study presented, we assume that the total concentration of hydrogen in the silicon substrate does not remain constant when temperature is increased, and that longer exposures to higher temperatures may cause further loss of hydrogen. This will be augmented by experimental studies of a-Si passivation layers on silicon subjected to hydrogen treatments and follow-on stepwise annealing with resulting loss of hydrogen and examination of its effect on the minority carrier lifetime.
氢和硅之间的相互作用在决定硅光伏中各种器件结构的表面和体钝化质量方面起着不可或缺的作用。已知氢处理方法的功效取决于相互作用的氢是原子的、离子的还是分子的。此外,这些浓度可以通过控制硅衬底的衬底温度来改变。此外,一个重要的考虑因素是进行处理的时间和气氛,因为它会影响氢从硅中的解吸。因此,重要的是对硅器件的氢钝化的理论和实验方面进行全面的研究,从而清楚地了解氢在不同太阳能电池结构中的行为,以及它对衬底性质的依赖。在提出的理论研究中,我们假设当温度升高时,硅衬底中氢的总浓度不会保持不变,并且长时间暴露在较高的温度下可能会导致氢的进一步损失。这将通过对经过氢处理的硅上的a-Si钝化层的实验研究和随后的逐步退火来增强,从而导致氢的损失,并检查其对少数载流子寿命的影响。
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引用次数: 0
The potential use of spark ablation in development of AgNP decorated copper oxide thin films for photodetection applications 火花烧蚀技术在开发用于光探测的AgNP修饰氧化铜薄膜中的潜在应用
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938943
Floren Radovanović-Perić, V. Mandić, I. Panžić
Recently, CuO (p-type) semiconductor thin films have been investigated for sensing applications due to their excellent optical properties and narrow bandgap. It has been proposed that the performance of CuO thin films in photosensing applications depends strongly on the grain size, morphology and nanostructure which introduces the possibility of fabricating these materials by spark ablation, a novel, low cost and efficient method capable of producing controlled and clean nanoparticles with various subsequent deposition methods that further broaden the synthesis possibilities. Here we investigated the potential of this method for fabricating photosensing devices through the ability to control the properties of both the deposited copper oxide thin-films as well as nanoparticles of gold. Copper oxide films were obtained on Si wafers by; i) vacuum jet deposition of either Cu or CuxOy layers that were thermally treated to obtain pure CuO phase, ii) spin coating of the Cu or CuxOy nanoparticles (NPs) solution produced by spark ablation which were collected in 2-methoxyethanol. After the CuO nanofilms were obtained, they were decorated with AuNPs by vacuum jet deposition. Phase purity, morphology and particle size were investigated by Grazing Incidence X-ray Diffraction (GIXRD), Atomic Force Microscopy (AFM) and Scanning Electron Microscopy (SEM), while optical absorption was determined by UV/Vis spectrometry and photoluminescence spectroscopy (PL). To determine the photocurrent, I/V characteristics were performed both in light and dark conditions. It was determined that produced films show comparable properties with competitive commercial devices.
近年来,CuO (p型)半导体薄膜由于其优异的光学性能和窄带隙而被研究用于传感应用。有人提出,CuO薄膜在光敏应用中的性能在很大程度上取决于晶粒尺寸、形貌和纳米结构,这就引入了通过火花烧蚀制造这些材料的可能性,这是一种新颖、低成本和高效的方法,能够通过各种后续沉积方法生产可控和清洁的纳米颗粒,从而进一步扩大了合成的可能性。在这里,我们通过控制沉积的氧化铜薄膜和金纳米颗粒的性能,研究了这种方法制造光敏器件的潜力。在硅片上制备了铜氧化物薄膜;i)真空喷射沉积Cu或CuxOy层,并对其进行热处理以获得纯CuO相;ii)在2-甲氧基乙醇中收集的火花烧蚀产生的Cu或CuxOy纳米粒子(NPs)溶液进行自旋涂层。制备出CuO纳米膜后,采用真空喷射沉积法对纳米膜进行aunp修饰。采用掠入射x射线衍射(GIXRD)、原子力显微镜(AFM)和扫描电镜(SEM)研究相纯度、形貌和粒度,采用紫外/可见光谱法和光致发光光谱法(PL)测定光吸收。为了确定光电流,在光照和黑暗条件下都进行了I/V特性测试。经确定,所生产的薄膜具有与竞争性商业设备相当的性能。
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引用次数: 0
Assessing the Alignment of Solar Facilities with Global Climate Goals 评估太阳能设施与全球气候目标的一致性
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938558
P. Sinha, Liv Hammann
Climate science-based targets have become the state-of-the-art approach for greenhouse gas goal setting by companies and institutions. As companies try to maximize the climate benefit of their renewable energy investments and lower their Scope 3 emissions, climate science-based target setting can be extended to solar facilities themselves. By evaluating the embodied carbon and economic emissions intensity of a solar facility and globally extrapolating, the solar park's temperature alignment can be calculated with the X-Degree Compatibility Model. A case study of 100 MWdc solar facilities in North Carolina indicates that solar facilities are well aligned with global climate goals for a 1.75°C (i.e. 'well below 2°C’) warming scenario. While the analysis shows that both, CdTe and mono-c-Si PV systems, are compatible with the chosen global warming scenario, the CdTe PV system has a lower climate impact, measurable in °C. The most sensitive variables contributing to economic emissions intensity are PPA price, O&M cost, system lifetime, and embodied carbon. Continued progress in lowering the embodied carbon and increasing the lifetime of PV systems is needed to counteract the tendency for increasing economic emissions intensity from declining PPA prices.
以气候科学为基础的目标已经成为企业和机构制定温室气体目标的最先进方法。随着企业试图将可再生能源投资的气候效益最大化,并降低其范围3的排放,基于气候科学的目标设定可以扩展到太阳能设施本身。通过评估太阳能设施的隐含碳排放强度和经济排放强度,并进行全球外推,利用x度相容模型计算太阳能园区的温度一致性。对北卡罗来纳州100兆瓦dc太阳能设施的案例研究表明,太阳能设施与1.75°C(即1.75°C)的全球气候目标完全一致。“远低于2°C”)变暖情景。虽然分析表明,CdTe和单碳硅光伏系统都与所选择的全球变暖情景兼容,但CdTe光伏系统的气候影响较低,以°C为单位可测量。影响经济排放强度的最敏感变量是PPA价格、运维成本、系统寿命和隐含碳。为了抵消购电协议价格下降带来的经济排放强度增加的趋势,需要在降低隐含碳和延长光伏系统寿命方面继续取得进展。
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引用次数: 1
Development of Hierarchical Control for a Lunar Habitat DC Microgrid Model Using Power Hardware-in-the-Loop 基于电力半在环硬件的月球生境直流微电网模型层次控制研究
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938880
A. Dow, R. Darbali-Zamora, J. Flicker, F. Palacios, J. Csank
As interest in space exploration grows, developing a lunar habitat has become a key component of extending missions into deep space. To guarantee reliable power management of a lunar habitat's DC microgrid, control schemes are needed that can manage the different assets (batteries, photovoltaics, loads) effectively. Proposed hierarchical control schemes are further developed into hardware solutions using Opal-RT's real-time simulation software and Power Hardware-in-the-Loop platform. Experimental results of a simulated DC microgrid and physical DC/DC components can allow better realization and performance of applications such as battery discharge control.
随着人们对太空探索兴趣的增长,开发月球栖息地已成为将任务扩展到深空的关键组成部分。为了保证月球栖息地直流微电网的可靠电源管理,需要能够有效管理不同资产(电池、光伏、负载)的控制方案。利用Opal-RT的实时仿真软件和Power硬件在环平台,将提出的分层控制方案进一步发展为硬件解决方案。模拟直流微电网和物理DC/DC组件的实验结果可以更好地实现电池放电控制等应用。
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引用次数: 2
CuCl Doping Variations in High Efficiency Polycrystalline CdSeTe/CdTe Thin Film Solar Cells CuCl掺杂在高效多晶CdSeTe/CdTe薄膜太阳能电池中的变化
Pub Date : 2022-06-05 DOI: 10.1109/pvsc48317.2022.9938587
Zach Lustig, T. Shimpi, Akash Shah, W. Sampath
In this paper, the influence of CuCl doping process parameters on the performance of solar cells was studied. The devices were fabricated with graded CdSeTe/CdTe absorber. The critical parameters for CuCl doping process were identified and varied in a 2-level 3-factor statistically designed experiment. The analysis of response data generated from the performance of the devices was analyzed using JMP software. The performances of devices with 19%+ revealed two different optimal processing conditions for CuCl doping.
本文研究了CuCl掺杂工艺参数对太阳能电池性能的影响。该器件采用CdSeTe/CdTe梯度吸收材料制备。在一个2水平3因素统计设计的实验中,确定并改变了CuCl掺杂过程的关键参数。使用JMP软件对设备性能产生的响应数据进行分析。19%+器件的性能揭示了CuCl掺杂的两种不同的最佳工艺条件。
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引用次数: 0
期刊
2022 IEEE 49th Photovoltaics Specialists Conference (PVSC)
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