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Investigation of the reduction roasting of saprolite ores in the Caron process: effect of sulphur addition Caron工艺中腐泥土矿石还原焙烧的研究:硫添加的影响
IF 1.2 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-04-03 DOI: 10.1080/25726641.2020.1729020
J. Chen, E. Jak, P. Hayes
ABSTRACT Laboratory studies have been undertaken to determine the mechanisms and kinetics of reactions occurring during the reduction roasting of saprolite ores with 1 wt% elemental sulphur addition. The reduction was undertaken using a 15%H2/85%N2 gas mixture at temperatures between 400 and 800°C; nickel was recovered by subsequent leaching in an ammoniacial aqueous solution. The effect of sulphur on dehydroxylation, reduction and sintering was investigated. Improvements in nickel recoveries were obtained when 1 wt% S was added to the nickel-bearing serpentine ore prior to the reduction roasting. Characterisation of the reduced and leached ore samples indicated that this improved Ni recovery with S addition is due to the formation of a leachable nickel sulphide phase, and the suppression of sintering and recrystallisation of the olivine phase formed at high reduction temperatures.
摘要已经进行了实验室研究,以确定在用1 元素硫添加量的wt%。在400和800°C之间的温度下,使用15%H2/85%N2气体混合物进行还原;通过随后在氨水溶液中的浸出来回收镍。研究了硫对脱羟基、还原和烧结的影响。当1 在还原焙烧之前向含镍的蛇纹石矿石中加入wt%S。还原和浸出矿石样品的表征表明,添加S后镍回收率的提高是由于可浸出硫化镍相的形成,以及在高还原温度下形成的橄榄石相的烧结和再结晶受到抑制。
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引用次数: 1
A systematic study on extraction and separation of scandium using phosphinic acid by both solvent extraction and hollow fibre membrane 次膦酸溶剂萃取-中空纤维膜萃取分离钪的系统研究
IF 1.2 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-03-30 DOI: 10.1080/25726641.2021.1908079
P. C. Rout, K. Sarangi
ABSTRACT A method for separation of scandium and preparation of scandium oxide using hollow fibre supported liquid membrane (HFSLM) was described. Scandium was separated from a multi metal solution bearing copper, nickel, cobalt, zinc, iron, manganese and scandium using bis (2,4,4-trimethylpentyl) phosphinic acid (Cyanex 272) as the mobile carrier. The effect of parameters such as pH, extractant concentration, flow rate, metal ion concentration and strip solution concentration on extraction of scandium was investigated and maximum flux was obtained at pH 2.0, Cyanex 272 concentration of 0.3 M, flow rate of 240 mL/min and 1.0 M H2SO4 in strip solution. From the equilibrium studies the extracted species was determined to be ScR3.3RH. A comparative study between solvent extraction and HFSLM has also been carried out to predict the efficiencies of both the techniques for the present system which could be useful for the treatment of industrial wastes bearing very low amount of Sc. It was observed that Sc recovery using Cyanex 272 with HFSLM and solvent extraction was 99.9 and 91%, respectively. Scandium was separated from other metal ions with high separation factors which followed the trend Sc/Ni <  Sc/Mn <  Sc/Co <  Sc/Zn <  Sc/Fe <  Sc/Cu. High pure scandium oxide (Scandia) was prepared from the strip solution by precipitation with oxalic acid and thermal decomposition at 750°C for 1 h.
介绍了一种利用中空纤维支撑液膜(HFSLM)分离钪并制备氧化钪的方法。以双(2,4,4-三甲基戊基)膦酸(Cyanex 272)为移动载体,从含铜、镍、钴、锌、铁、锰和钪的多金属溶液中分离钪。考察了pH、萃取剂浓度、流量、金属离子浓度、带液浓度等参数对钪萃取的影响,在pH 2.0、Cyanex 272浓度0.3 M、流量240 mL/min、带液H2SO4 1.0 M条件下获得了最大萃取通量。从平衡研究中确定提取的物质为ScR3.3RH。对溶剂萃取法和溶剂萃取法进行了比较研究,预测了两种技术的效率,该系统可用于处理含钪量极低的工业废物。结果表明,使用HFSLM和溶剂萃取法,cyanex272的Sc回收率分别为99.9%和91%。钪与其他金属离子的分离因子较高,其分离规律为Sc/Ni < Sc/Mn < Sc/Co < Sc/Zn < Sc/Fe < Sc/Cu。采用草酸沉淀,750℃热分解1 h制得高纯氧化钪(Scandia)。
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引用次数: 5
Classification and regression models in Copper refinery 铜精炼厂分类与回归模型
IF 1.2 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-03-30 DOI: 10.1080/25726641.2021.1908080
L. Pérez
ABSTRACT The Chuquicamata Copper refinery has an annual production of 480,000 Tons of copper cathode (A grade). The electrochemical process has a duration of 10 days with 300 A/m2 current density. In this global context, there are a lot of process variables for the process control, like impurities, electrolyte flux in the cells, additive addition, short-cuts and electrical current efficiency. In the present work, classification and regression models are used for having a global process control. The classification models like SVM, Decision Trees, GLMNET, LDA, KNN and Logistic regression show an easy way to see the different effect of the process variables over the quality of the final product. The regression models show the future behaviour of process variables in different scenarios and how this result have a huge impact in the cost of the electrochemical process. In other line, the classification models are easy tool for the operation team. They can see the effect of process variables day by day in the electrochemical cell. The fusion of both models has a strong impact in the global process control for take future decision and minimising the process cost.
Chuquicamata铜精炼厂年产48万吨阴极铜(A级)。电化学过程持续时间为10天,电流密度为300 a /m2。在此背景下,过程控制有许多过程变量,如杂质、电池中的电解质通量、添加剂的添加、捷径和电流效率。在本工作中,分类和回归模型用于具有全局过程控制。支持向量机、决策树、GLMNET、LDA、KNN和Logistic回归等分类模型显示了一种简单的方法,可以看到过程变量对最终产品质量的不同影响。回归模型显示了过程变量在不同情况下的未来行为,以及这种结果如何对电化学过程的成本产生巨大影响。另一方面,分类模型对于操作团队来说是一个简单的工具。他们可以看到电化学电池中每天的工艺变量的影响。这两种模型的融合对全局过程控制具有重要的影响,有利于未来决策和过程成本最小化。
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引用次数: 1
Geometallurgical characterisation of a Channel Iron Deposit (CID) Ore 某水道铁矿(CID)矿的地质冶金学特征
IF 1.2 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-03-30 DOI: 10.1080/25726641.2021.1908105
Huibin Li, D. Pinson, P. Zulli, L. Lu, R. Longbottom, S. Chew, B. J. Monaghan, G. Zhang
ABSTRACT Channel iron deposits (CID), comprising pisolitic or goethitic ores, remain a prominent iron ore resource in Western Australia. Previous research work on CID pointed out their complexity in genesis, geology, geomorphology, and petrology, which provides some basic information for downstream processing. Sintering investigations have mainly focused on the overall sintering performance and the quality of sinter products rather than the behaviour of the ore components during sintering. However, individual mineral phases in the ores have their own characteristics during reaction with fluxing materials in the sintering process. In this study, the complex mineral phases in a CID goethitic ore are compared with traditional hematite ore. They are classified into several categories based on the mineral composition, including the basic mineral phases: goethite matrix, hydro-hematite, and quartz, and combined minerals: quartz-dispersed hydro-hematite, quartz-dispersed goethite, goethite with dispersed quartz and clay (gibbsite/kaolinite), and ferruginised wood. The changes of the goethitic ore when heated to different temperatures were also investigated. More cracks appeared in the ore with increasing temperature due to dehydration of the goethite matrix. The temperature induced goethite-to-hematite transformation occurred between 260°C and 300°C, as shown in TGA-DSC curves and confirmed by XRD analysis. The colour of the goethitic ore changed from brown to vermillion after 300°C due to the phase transformation, and to ochreous at 1150°C and further to black above 1250°C due to the decomposition of hematite to magnetite.
水道铁矿(CID)是西澳大利亚一个重要的铁矿资源,主要由泥质或针长石矿石组成。前人的研究工作指出了其成因、地质、地貌和岩石学的复杂性,为下游处理提供了一些基础信息。烧结研究主要集中在整体烧结性能和烧结产品的质量,而不是烧结过程中矿石成分的行为。然而,在烧结过程中,矿石中的各个矿物相在与助熔剂的反应中都有自己的特点。本研究将CID针铁矿与传统赤铁矿的复杂矿物相进行对比,根据矿物组成将其划分为基本矿物相:针铁矿基质、水赤铁矿、石英;组合矿物:石英-分散的水赤铁矿、石英-分散的针铁矿、分散的石英-粘土(三水石/高岭石)针铁矿、铁化木材。研究了针长石在不同加热温度下的变化。随着温度的升高,针铁矿基体脱水,矿石中出现更多的裂纹。温度诱导的针铁矿向赤铁矿转变发生在260℃~ 300℃之间,通过热重分析(TGA-DSC)曲线和XRD分析得到证实。针长石在300℃后因相变由棕色变为朱红色,在1150℃时变为赭色,在1250℃以上因赤铁矿分解为磁铁矿而进一步变为黑色。
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引用次数: 0
An approach to measuring and modelling the residence time distribution of cement clinker in vertical roller mills 垂直辊磨机中水泥熟料停留时间分布的测量和建模方法
IF 1.2 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-03-17 DOI: 10.1080/25726641.2021.1898266
K. Barani, M. Azadi, R. Fatahi
ABSTRACT This paper presents an experimental approach to measure and model the residence time distribution of vertical roller mill in cement clinker grinding circuit. The dispersion model, tank-in-series model, and a perfect mixer with a bypass model were employed to describe the residence time distribution. A perfect mixer with a bypass model was found to a tolerable fitting to describe the RTD of solids in VRM. The result shows 43% of the fine fraction of fresh feed as an existing bypass without spending adequate time within the VRM. The result also shows that the grinding occurs in 54% of the table surface and about 46% of the table surface can be called the dead zone.
本文提出了一种测量和建模水泥熟料粉磨回路中立式辊磨机停留时间分布的实验方法。采用分散模型、串联槽模型和带旁路模型的完美混合器来描述停留时间分布。发现一个带有旁路模型的完美混合器可以在VRM中描述固体的RTD。结果表明,43%的新鲜进料细馏分作为现有的旁路,而没有在VRM内花费足够的时间。结果还表明,研磨发生在54%的工作台表面,约46%的工作台表面积可称为死区。
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引用次数: 1
Process of Irons Smelting in Yala Local Government Area of Cross River State 克罗斯河州雅拉地区铁冶炼工艺研究
IF 1.2 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-03-10 DOI: 10.11648/J.IJMPEM.20210601.11
A. Okwoche, Tawo Alfred Oyong, Inyabri Samuel Atam
Iron smelting entails heating of iron at a particular temperature to enable smelter to form objects of desirable shape, Such temperature can be obtainable in a well-insulated medium size furnace, when efficient bellows and a suitable type of charcoal (and of course strong and experienced workers) are employs but some lower temperature can or may still give the satisfactory result of the time of operation is congruity, in Nigeria, especially the Yala axis the bellows used for smelting and forging iron was of rubber-tube. In Nigeria, irons smelting was said to have started from East precisely the Awka people, why inyala today we have black smelter who forges hole, knife, rake, axe, and other agricultural tools, but traditional iron smelting is gradually going to extinction where nobody is willing to learn iron smelting work, as such agricultural implement is becoming very expensive as the people of Yala continue to buy from the Ezza people who few of them are engaging in smelting. This paper therefore x-ray the processes and materials involved or used in forging. Descriptives method of data collection were employed.
炼铁需要在特定温度下加热铁,以使冶炼厂形成理想形状的物体,这种温度可以在绝缘良好的中型炉中获得,当使用高效的波纹管和合适类型的木炭(当然还有强壮和有经验的工人)时,但是一些较低的温度可以或可能仍然给出令人满意的结果,操作时间是一致的,在尼日利亚。特别是雅拉轴,用于冶炼和锻造铁的波纹管是橡胶管。在尼日利亚,据说铁器冶炼是从东部的Awka人开始的,为什么今天在Yala我们有黑色的冶炼厂,他们锻造孔,刀,耙子,斧头和其他农具,但是传统的铁器冶炼正在逐渐灭绝,没有人愿意学习铁器冶炼工作,因为这样的农具变得非常昂贵,因为Yala的人继续从Ezza人那里购买,他们很少从事冶炼。因此,本文用x射线分析了锻造过程中涉及或使用的工艺和材料。数据收集采用描述性方法。
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引用次数: 0
Design Principles and Improvement of the Evaluation Methods for the Shatter Strength of Metallurgical Materials 冶金材料破碎强度评定方法的设计原则与改进
IF 1.2 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.11648/J.IJMPEM.20210602.12
Tan Wendan, Junxue Zhao, Liang Niu, Lv Zhao, Tinglian Zhang
Shatter strength refers to the ability of materials to resist collisions and impacts and is an important property of metallurgical minerals. Although the current methods differ in terms of the testing equipment, implementation steps and data processing methods, these approaches are nearly identical in principle. However, the current methods are not sufficiently accurate, which makes it difficult to objectively evaluate shatter strength. Therefore, new and more accurate methods are needed. In this paper, a variety of current methods were discussed, design principles were summarized, and new methods were proposed that consider the influence of the degree of rupture and drop time when cracks are generated on the results of shatter strength tests. Based on the new design principles, new parameters such as the crack size index, number of fragments, and total mass of the fragments were added to the evaluation formula. In addition, the test processes were optimized. Then, a batch of lead-containing pellets were evaluated by the new methods. The results obtained in this test show that, compared with the old methods, the new methods can more accurately and objectively evaluate shatter strength and reflect product quality. Users can also design new methods for all kinds of brittle materials according to these principles. However, the new method is more complex than the old methods and needs to consider a greater number of factors. At present, there is no effective means to address the workload. With the development of artificial intelligence and automation devices, new design principles and methods will be more widely utilized.
破碎强度是指物料抵抗碰撞和冲击的能力,是冶金矿物的一项重要性能。虽然目前的方法在检测设备、实施步骤和数据处理方法等方面有所不同,但这些方法在原理上几乎是相同的。然而,目前的方法精度还不够,难以客观地评价破碎强度。因此,需要新的、更精确的方法。本文对现有的各种方法进行了讨论,总结了设计原则,并提出了考虑裂纹产生时的断裂程度和跌落时间对破碎强度试验结果影响的新方法。根据新的设计原则,在评价公式中加入了裂纹尺寸指数、破片数、破片总质量等新参数。并对试验工艺进行了优化。然后用新方法对一批含铅球团进行了评价。试验结果表明,与旧方法相比,新方法能更准确、客观地评价破碎强度,反映产品质量。用户还可以根据这些原理设计各种脆性材料的新方法。然而,新方法比旧方法更复杂,需要考虑更多的因素。目前,还没有有效的手段来解决这一问题。随着人工智能和自动化设备的发展,新的设计原理和方法将得到更广泛的应用。
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引用次数: 0
Reducing Uncertainties in Gold Plant Design and Operations 减少金矿厂设计和运营中的不确定性
IF 1.2 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.11648/j.ijmpem.20210603.14
C. Amoah, G. Ofori-Sarpong, Richard Kwasi Amankwah
The conventional way of designing a plant is to determine the characteristics of rocks in terms of crushability, grindability and other properties that affect the mill throughput. These properties are most of the time determined from drill cores obtained during the exploration period. Such initial exploration campaigns drill to levels shallower than the real pit that will be developed. Thus, as mining pits become deeper, the ore characteristics change and begin to impact negatively on the expected mill throughput. Such situations necessitate modification of the plant, and the first intervention usually is to supplement the initial energy input with additional size reduction equipment to achieve the required throughput. However, reconsidering the inputs used in determining the initial plant selection would help in reducing the setbacks during the operational period. To help reduce uncertainties and develop a predictive tool, this study considered a greenfield drilled up to 273 m, and the core samples obtained were tested to ascertain the variations in Bond work index to depths beyond 500 m. The study showed that within the section of the Asankragwa belt investigated, Bond work indices increased from 10.3 kW/t at the surface to 16.5 kW/t at a depth of 273 m. The Bond work index was established as a function of vertical depth in a pit (x) with the relation BWI=6E-05x2 + 0.0071x + 9.8816. The predicted value at 280 m was 16.3 kW/t while that of the blend was 15.8 kW/t, giving an error of 4%. This novel relationship between the BWI and depth predicts the BWI beyond 500m with minimum mean square error. The use of the novel Bond work index and depth relationship will eliminate the uncertainty beyond the drilled depth and give a clear understanding of what the rock characteristics will be as pits become deeper. In addition, a savings of US$62,500 per diamond drill hole and US$25,000 per one reverse drilling after the 250 m depth can be made by the use of this model. This can result in massive savings considering the number of holes that would have to be drilled across the length of the pit.
设计设备的传统方法是确定岩石的可破碎性、可磨性和其他影响磨机吞吐量的特性。这些性质大多是由勘探期间获得的岩心确定的。这种最初的勘探活动钻探到比将要开发的实际矿坑更浅的水平。因此,随着采矿坑的加深,矿石特性发生变化,并开始对预期磨机吞吐量产生负面影响。这种情况需要对装置进行改造,而第一个干预措施通常是用额外的尺寸减小设备来补充初始的能量输入,以达到所需的吞吐量。但是,重新考虑在确定最初工厂选择时所使用的投入将有助于减少业务期间的挫折。为了减少不确定性并开发预测工具,本研究考虑了一个钻深273米的绿地,并对获得的岩心样本进行了测试,以确定Bond工作指数在深度超过500米时的变化。研究表明,在Asankragwa带所调查的区域内,Bond功指数从地表的10.3 kW/t增加到273 m深度的16.5 kW/t。建立Bond工作指数作为矿井垂直深度(x)的函数,BWI=6E-05x2 + 0.0071x + 9.8816。280 m的预测值为16.3 kW/t,而混合料的预测值为15.8 kW/t,误差为4%。这种新的BWI与深度之间的关系以最小的均方误差预测了500米以上的BWI。新型Bond功指数和深度关系的使用将消除钻探深度以外的不确定性,并使人们清楚地了解随着坑的加深,岩石特征将会是什么。此外,使用该模型每个金刚石钻孔可节省62,500美元,250 m深度后每次反钻可节省25,000美元。考虑到必须在整个坑的长度上钻孔的数量,这可以节省大量的费用。
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引用次数: 0
Laser Duration of Surface Textures of Slab Design 板坯设计表面纹理的激光持续时间
IF 1.2 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.11648/j.ijmpem.20210604.13
S. Ubani
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引用次数: 0
Bioleaching: Validation of the Extraction of Precious Metals Through Selective Recovery of Iron, Copper and Zinc 生物浸出:通过选择性回收铁、铜和锌萃取贵金属的验证
IF 1.2 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.11648/j.ijmpem.20210604.11
Zambrano Johanna, Zambrano Johnny
: In Ecuador, large gold deposits were discovered in the areas of Nambija and Ponce Enríquez, but they contain metal sulfides that, when exposed to the action of air and water, intervene in a series of physical, chemical and biological phenomena. The oxidation of sulfides to sulfates occurs by the catalytic action of bacteria, in addition to the production of sulfuric acid that dissolves heavy metals such as iron, copper and zinc; a process known as bioleaching. These solutions, with a high level of acidity, are carried away by water currents or runoff, becoming a great contaminant of water and soil of the surrounding sector. Acid mine drains are one of the main problems of environmental pollution; the mining deposits are located in areas of great biodiversity. In these areas there are births of water used for human consumption, agriculture and mining work; the mismanagement of tailings, tailings and sands that are discharged into rivers and streams generate serious environmental damage. The objective of the work is to use selective precipitation to recover iron, copper and zinc from acid solutions produced by bioleaching during the extraction of precious metals at the laboratory level and from acid drainage of natural mine, to comply with environmental regulations regarding the discharge of effluents and reduce the effect of environmental pollution produced by acid mine drains. This investigation presents the conditions for a successful individual recovery of the main base metals contained in a bioleaching solution with high copper, zinc, and iron concentrations by pH-based selective precipitation. Tests were made with standard solutions of known concentrations of copper, iron, lead, and zinc and by titration the concentrations were checked, which allowed to validate the volumetric titration method. The selective precipitation of heavy metals was carried out in three phases using real acid main drainage and bioleaching solutions generated at the laboratory. The first phase in a pH range of 2 to 4 to recover iron; the second phase in a pH range of 4 to 6 to recover copper; and the third phase in a pH range of 6 to 10 to recover zinc. The selective precipitation allowed the heavy metals to be completely removed from the solution or to achieve concentrations below the maximum allowable limit to be discharged to a body of water or public sewer. Validation of SOLBIO 2 and Orenas bioleaching solutions was performed.
在厄瓜多尔,在Nambija和Ponce Enríquez地区发现了大型金矿,但它们含有金属硫化物,当暴露在空气和水的作用下,会干预一系列物理、化学和生物现象。除了产生溶解铁、铜、锌等重金属的硫酸外,还可以通过细菌的催化作用将硫化物氧化为硫酸盐;这个过程被称为生物浸出。这些高酸度的溶液被水流或径流带走,成为周围地区水和土壤的一大污染物。酸性矿井排水是环境污染的主要问题之一;矿藏位于生物多样性丰富的地区。在这些地区,有大量的水用于人类消费、农业和采矿工作;尾矿、尾砂、砂石等排入江河的管理不善,对环境造成严重破坏。这项工作的目的是利用选择性沉淀从实验室一级提取贵金属过程中生物浸出产生的酸性溶液和天然矿山的酸性排水中回收铁、铜和锌,以遵守有关废水排放的环境法规,减少酸性矿山排水产生的环境污染影响。本研究提出了通过ph基选择性沉淀,成功地从高铜、锌和铁浓度的生物浸出液中单独回收主要贱金属的条件。用已知浓度的铜、铁、铅和锌的标准溶液进行了试验,并通过滴定检查了浓度,从而验证了体积滴定法。采用实际酸性主排水和实验室生成的生物浸出液,分三个阶段进行重金属的选择性沉淀。第一阶段在pH值2 ~ 4范围内回收铁;第二阶段在pH值4 ~ 6范围内回收铜;第三阶段在pH值6 ~ 10范围内回收锌。选择性沉淀可以使重金属完全从溶液中去除,或使浓度低于排放到水体或公共下水道的最大允许限制。对solbio2和Orenas生物浸出液进行了验证。
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引用次数: 0
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Mineral Processing and Extractive Metallurgy-Transactions of the Institutions of Mining and Metallurgy
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