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STUDY OF THE PASSAGE OF ELECTRONS WITH ENERGY OF 12 – 15 keV THROUGH GLASS TAPERED CAPILLARIES 能量为12 - 15kev的电子通过玻璃锥形毛细血管的研究
Pub Date : 1900-01-01 DOI: 10.14489/glc.2022.02.pp.027-031
A. D. Piatigor, L. Myshelovka, K. Vokhmyanina, V. Sotnikova, A. A. Kubankina, Yuri V. Grigoriev
This paper presents the results of experimental studies on the passage of an electron beam with an energy of 12 and 15 keV through glass tapered macrocapillaries. As a result of the measurement, the absence of an explicit dependence of the output current on the electron energy was shown. Time-dependent measurements of the beam current at the exit from the capillaries were carried out.
本文介绍了能量为12 keV和15 keV的电子束通过玻璃锥形大毛细血管的实验研究结果。测量的结果表明,输出电流对电子能量没有明确的依赖关系。对毛细管出口处的光束电流进行了随时间的测量。
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引用次数: 0
EFFECT OF CALCIUM ADDITION ON THE PROPERTIES AND MICROSTRUCTURE OF FLY ASH-BASED GEOPOLYMERS FOR APPLICATIONS IN SUSTAINABLE CONSTRUCTIONE 掺钙对可持续建筑用粉煤灰基地聚合物性能和微观结构的影响
Pub Date : 1900-01-01 DOI: 10.14489/glc.2022.02.pp.032-039
N. Klimenko, K. I. Kiseleva, L. Delitsyn, V. Sigaev
The article describes a study of the physical and mechanical properties and microstructure of geopolymer materials for construction based on low-calcium fly ash from CHP-22, depending on the type of activator, temperature and humidity conditions of curing and the introduction of an additional source of calcium (CaO) in the amount of 10, 15 and 20 wt. %.It was found that for the fly ash under study, the most promising type of activator is a sodium silicate solution with a silicate modulus SiO2 / Na2O = 1; the preferred curing mode is steam treatment at 90 °C. With the introduction of 15 % CaO into the geopolymer mixture, it was possible to increase the compressive strength by more than 2.5 times (to 38 МПа), the open porosity decreased from 24 to 7 %, and the water absorption from 15 to 3 %. However, a further increase in the CaO content leads to degradation of properties due to a significant reduction in the setting time of the raw mixture.
本文描述了一项基于CHP-22低钙粉煤灰的建筑用地聚合物材料的物理力学性能和微观结构的研究,这取决于活化剂的类型、养护的温度和湿度条件以及添加10%、15%和20%重量%的钙(CaO)的额外来源。研究发现,对于所研究的粉煤灰,最有前途的活化剂是硅酸盐模量SiO2 / Na2O = 1的水玻璃溶液;优选的固化方式为90℃的蒸汽处理。在地聚合物混合物中加入15%的CaO,可以将抗压强度提高2.5倍以上(达到38 МПа),开放孔隙率从24%降至7%,吸水率从15%降至3%。然而,由于原料混合物凝固时间的显著减少,CaO含量的进一步增加会导致性能的退化。
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引用次数: 0
POLARIZATION CONTROLLED BIREFRINGENCE IN LITHIUM ALUMINOSILI-CATE GLASS 硅铝酸锂玻璃偏振控制双折射
Pub Date : 1900-01-01 DOI: 10.14489/glc.2022.02.pp.003-007
V. Sigaev, A. Lipatiev, S. Fedotov, S. Lotarev, A. S. Naumov, D. M. Shevyakina
The rise of polarization-controlled birefringence under a series of femtosecond laser pulses in the bulk of lithium silicate and lithium aluminosilicate glasstentatively attributed to the formation of nanogratings is demonstrated. The dependences of the retardance of the light passing through the modified regions on the parameter of laser radiation and the chemical composition of the glass are determined. It is shown that an increase of Al2O3 content at the expense of alkali content in glass composition leads to an increase in the minimum number of pulses for the formation of a birefringent region, as well as an increase in the retardance.
在一系列飞秒激光脉冲作用下,由于纳米光栅的形成,硅酸锂和硅酸铝锂的偏振控制双折射率上升。确定了激光辐射参数和玻璃的化学成分对通过改性区的光阻的依赖关系。结果表明,以牺牲玻璃组分中碱含量为代价而增加Al2O3含量,会导致形成双折射区的最小脉冲数增加,以及延迟增加。
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引用次数: 0
CERAMICS IN THE Na2O–CaO–SO3 SYSTEM AS A PROMISING INORGANIC POROGEN na20 - cao - so3体系中的陶瓷作为一种有前途的无机孔隙剂
Pub Date : 1900-01-01 DOI: 10.14489/glc.2022.03.pp.009-018
T. V. Safronova, T. Shatalova, Y. Filippov, O. Toshev, A. Knotko, L. A. Vaimugin, D. V. Savchenkova
Ceramics with phase composition after firing in the range of 600 – 900 °C represented by anhydrous calcium sulfate CaSO4, and calcium sodium sulfates (Na0,8Ca0,1)2SO4 and Na6Ca(SO4)4 were obtained from a powder mixture of sodium sulfate Na2SO4 and calcium sulfate dihydrate CaSO42H2O, taken at a molar ratio CaSO42H2O/Na2SO4 = 1. The phase composition of the powder mixture after homogenization in a planetary mill in an acetone medium, in addition to the starting salts, also included hydrated sodium calcium sulfate Na4Ca(SO4)32H2O. When kept in water for 5 and 60 min the mass loss of ceramic sample fired at 700 °C was 15 and 75 % respectively. Ceramics in the Na2O–CaO–SO3 system in the form of granules or complex shapes obtained using 3D printing can be used as a removable (soluble or leachable) porogen and/or a prototype of a porous space with a given architecture when creating porous polymer or inorganic materials.
以硫酸钠和二水合硫酸钙CaSO4为原料,按摩尔比(CaSO4 /Na2SO4 = 1)制得煅烧后相组成为无水硫酸钙CaSO4、硫酸钙钠(Na0,8Ca0,1)2SO4和Na6Ca(SO4)4的陶瓷。在丙酮介质中行星磨均质后的粉末混合物的相组成,除起始盐外,还包括水合硫酸钙钠Na4Ca(SO4)3。当陶瓷样品在水中保持5和60分钟时,700°C烧制的质量损失分别为15%和75%。使用3D打印获得的颗粒或复杂形状的na20 - cao - so3体系中的陶瓷可以用作可移动(可溶性或可浸出)的孔隙剂和/或在创建多孔聚合物或无机材料时具有给定结构的多孔空间的原型。
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引用次数: 0
POLARIZATION CONTROLLED BIREFRINGENCE IN SODIUM ALUMINOBORATE GLASS 铝酸钠玻璃的偏振控制双折射
Pub Date : 1900-01-01 DOI: 10.14489/glc.2022.03.pp.003-008
S. Fedotov, A. Lipatiev, T. Lipateva, S. Lotarev, N. K. Prichach, V. Sigaev
The formation of birefringent nanogratings by a femtosecond laser beam in the volume of sodium aluminoborate glasses is demonstrated. The dependences of the optical retardance of the nanogratings on the parameters of laser exposure and the chemical composition of the glass are determined. It was shown that an increase in the Al2O3 concentration at a constant [Na2O]/([B2O3 + Al2O3]) molar ratio does not affect the ranges of laser exposure parameter for nanogratings formation but leads to an increase in the retardance of the nanogratings.
用飞秒激光束在铝酸钠玻璃中形成双折射纳米光栅。研究了激光曝光参数和玻璃的化学成分对纳米光栅光学延迟的影响。结果表明,在一定的[Na2O]/([B2O3 + Al2O3])摩尔比下,Al2O3浓度的增加不会影响纳米光栅形成的激光曝光参数范围,但会导致纳米光栅的延迟增加。
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引用次数: 0
CERAMICS BASED ON FLUORINATED TALC 含氟滑石粉陶瓷
Pub Date : 1900-01-01 DOI: 10.14489/glc.2022.02.pp.020-026
S. Sharafeev, V. Vereschagin, A. Mezhenin
A dense-sintered protoenstatite ceramics based on fluorinated talc was obtained. Influence of BaO and Al2O3 additives on the sinterability, structure and strength of ceramics was investigated. It makes possible to reduce the sintering temperature to 1225 – 1250 °C due to formation of glassy phase. Additive of ZnO intensifies solid phase sintering at 1320 °C. It significantly improves compressive strength of ceramics up to 660 MPa that exceeds the strength of traditional steatite materials by 3 times.
以含氟滑石粉为基料,制备了致密烧结的原顽辉石陶瓷。研究了BaO和Al2O3添加剂对陶瓷烧结性能、组织和强度的影响。由于玻璃相的形成,使烧结温度降低到1225 ~ 1250℃成为可能。ZnO的加入强化了1320℃固相烧结。显著提高陶瓷抗压强度,达到660 MPa,是传统滑石材料抗压强度的3倍。
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引用次数: 0
THE USE OF TECHNOGENIC METALLURGICAL RAW MATERIALS FOR THE PRODUCTION OF CERAMIC MATERIALS WITH AN ANORTHITE PHASE 利用技术冶金原料生产具有钙长石相的陶瓷材料
Pub Date : 1900-01-01 DOI: 10.14489/glc.2022.03.pp.019-025
M. Semenovykh, N. Skripnikova, O. Volokitin, V. Shekhovtsov
Studies have been carried out on the topic of obtaining ceramic materials for construction purposes with an anorthite phase. Clay and blast-furnace gas cleaning sludge were used as raw materials. The chemical compositions of raw materials for their use in the production of ceramic products have been studied. The calcium- and iron-containing compounds included in the composition of the gas cleaning sludge contribute to a decrease in the temperature of the formation of solid solutions and the anorthite phase. It has been established that with the addition of sludge up to 80 wt.% into the composition of the ceramic mixture increases the likelihood of an anorthite phase formation. The physico-mechanical parameters of the obtained ceramic samples have been studied. It has been established that the amount of gas cleaning sludge in the composition of the charge is 10 – 40 wt.% allows to obtain products with compressive strength 18 % higher than the control sample. The improvement in physical and mechanical properties is associated with an increase in the amount of the formed anorthite phase, which is confirmed by the data of X-ray phase analysis.
研究的主题是获得用于建筑目的的陶瓷材料与钙长石相。以粘土和高炉煤气清洗污泥为原料。研究了陶瓷产品生产中所用原料的化学成分。气体净化污泥组成中的含钙和含铁化合物有助于降低固溶体和钙长石相形成的温度。已经确定,在陶瓷混合物的组成中添加高达80wt .%的污泥会增加钙长石相形成的可能性。对所得陶瓷样品的物理力学参数进行了研究。已经确定,在装料组成中,气体清洗污泥的量为10 - 40 wt.%,可以获得抗压强度比对照样品高18%的产品。物理力学性能的改善与钙长石相数量的增加有关,x射线相分析数据证实了这一点。
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引用次数: 0
PHYSICO-CHEMICAL PROPERTIES OF MINERAL FIBERS OBTAINED ON THE BASIS OF ANDESIBASALTS 安山岩基矿物纤维的物理化学性质
Pub Date : 1900-01-01 DOI: 10.14489/glc.2022.03.pp.038-045
Sh. M. Niyazova, Z. R. Kadyrova, Kh. L. Usmanov, A. A. Éminov, F. Khomidov
The article presents the results of research on the development of prototypes for obtaining mineral fibers based on the andesibazalt–slag–dolomit composition and the results of testing their physicochemical properties. Tests of chemical resistance of optimal compositions in aggressive conditions showed that the chemical resistance of the fibers depends on the content of metal oxides in the glass and their ratios that take into account the mutual influence of SiO2, Al2O3, Fe2O3, CaO, MgO, Na2O, K2O. It has been established that the studied andesibasalt of the Karahtay field is a promising raw material component for obtaining mineral fibers.
本文介绍了以安山石-矿渣-白云石组成为原料制备矿物纤维原型的研究结果及其理化性能测试结果。在腐蚀性条件下对最佳组合物的耐化学性进行了测试,结果表明,纤维的耐化学性取决于玻璃中金属氧化物的含量及其比例,并考虑了SiO2、Al2O3、Fe2O3、CaO、MgO、Na2O、K2O的相互影响。研究表明,克拉塔伊安山岩是一种很有前途的矿物纤维原料组分。
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引用次数: 0
METHODS OF UNCREASING OF THE WAX MODEL SURFACE PRIMARY WETTABILITY DURING LOST-WAX CASTING 失蜡铸造过程中降低蜡模表面初级润湿性的方法
Pub Date : 1900-01-01 DOI: 10.14489/glc.2022.03.pp.032-037
E. Novokreshchennykh, A. Gulyaeva, N. Uglev
Lost-wax casting is one of the most advanced ways to obtain geometrically complex castings of high quality. One of the main factors influenced on the casting properties is the quality of the ceramic mold face layer. A uniform deposition of the ceramic slurry can be achieved by condition of the wax surface is well wetted by the suspension dispersion medium. Since the surface of the wax model is hydrophobic and the dispersion medium of ceramic suspension is water, an increase of wettability may be achieved not only by SAS-wetting agent adding in suspension composition but also by activating of the model surface by chemical or physical methods.The paper presents the results of the different ways of chemical activation influence on the wettability of the wax model surface.
失蜡铸造是获得高质量几何复杂铸件的最先进方法之一。影响铸件性能的主要因素之一是陶瓷模面层的质量。在悬浮分散介质湿润蜡表面的条件下,可以实现陶瓷浆料的均匀沉积。由于蜡模型的表面是疏水性的,而陶瓷悬浮液的分散介质是水,因此增加润湿性不仅可以通过在悬浮液组合物中加入sas润湿剂,还可以通过化学或物理方法激活模型表面。介绍了不同化学活化方式对蜡模型表面润湿性的影响。
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引用次数: 0
CERAMIC TILE BASED ON LOCAL HYDROMICA CLAY AND PEGMATITE DUST REMOVAL WASTE 瓷砖基于局部的水云母粘土和伟晶岩粉尘去除废弃物
Pub Date : 1900-01-01 DOI: 10.14489/glc.2022.02.pp.012-019
V. Ilyina
The goal of the present contribution is to study the possible use of local clay of hydromica type for facing tile production. Pegmatite dust removal waste from the Chupa Milling and Dressing Factory was added as flux to the clay. Mineralogical, chemical and grain-size analyses of the clay and waste were performed. The mineral composition of the waste and clay were analyzed using the laboratory equipment of the Analytical Centre at the Institute of Geology, Karelian Research Centre, RAS. Experimental samples of ceramic tile were produced and the physico-mechanical properties of the products were assessed. The ceramics produced can be used for facing walls and furnaces. Local clay of hydromica type and pegmatite dust removal waste can be used to increase the mechanical bending strength and heat resistance of facing tiles, to decrease their thermal conductivity in comparison with samples containing clay, kaolin, feldspar and lime and to contribute to pegmatite waste utilization.
本文的目的是研究当地水云母型粘土用于面砖生产的可能性。将Chupa磨选厂的伟晶岩除尘废料作为助熔剂添加到粘土中。对粘土和废料进行了矿物学、化学和粒度分析。废物和粘土的矿物成分是利用欧洲科学院卡累利阿研究中心地质研究所分析中心的实验室设备进行分析的。制作了瓷砖的实验样品,并对产品的物理力学性能进行了评价。所生产的陶瓷可用于墙面和炉面。与含粘土、高岭土、长石、石灰等样品相比,采用局部的水云母型粘土和伟晶岩除尘废土可以提高饰面砖的机械抗弯强度和耐热性,降低其导热系数,有利于伟晶岩废土的利用。
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引用次数: 0
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Steklo i Keramika
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