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EFFECT OF SURFACE GLAZE TREATMENT AND MECHANICAL POLISHING ON THE COLOR STABILITY OF TWO TYPES OF CAD/CAM CERAMICS 表面釉处理和机械抛光对两种 CAD/CAM 陶瓷颜色稳定性的影响
Pub Date : 2023-09-01 DOI: 10.14489/glc.2023.09.pp.060-062
S. Ghazaee, E. Moslehifard, T. Ghaffari, F. O. Nasirpouri
The effect of immersion in a coffee drink solution on the color stability of two CAD/CAM ceramic restorations was investigated in this in vitro study. To this end, zirconia-reinforced lithium silicate (ZLS) and lithium disilicate (LDS) glass-ceramic blocks were surface-treated using mechanical polishing and glazing techniques. In addition, their color was examined before and after immersion in a coffee solution using a spectrophotometer, and the color changes were evaluated. A two-way analysis of variance (ANOVA) was used to examine the color changes. The material type significantly influenced color changes (P < 0.001). After glazing and mechanical polishing, LDS exhibited considerably less color change in both groups than ZLS. In both types of ceramics, the glazed group experienced less color variation than the mechanically polished group. Color changes were clinically acceptable across all groups. The glazing surface treatment produced superior color stability than the mechanical polishing technique. LDS exhibited more color stability than ZLS in both surface treatments.
本体外研究调查了浸泡在咖啡饮料溶液中对两种 CAD/CAM 陶瓷修复体颜色稳定性的影响。为此,使用机械抛光和上釉技术对氧化锆增强硅酸锂(ZLS)和二硅酸锂(LDS)玻璃陶瓷块进行了表面处理。此外,还使用分光光度计检测了它们在浸入咖啡溶液前后的颜色,并对颜色变化进行了评估。采用双因素方差分析(ANOVA)来研究颜色的变化。材料类型对颜色变化有明显影响(P < 0.001)。在上釉和机械抛光后,两组中 LDS 的颜色变化都比 ZLS 少得多。在两种类型的陶瓷中,上釉组的颜色变化都比机械抛光组要小。所有组别的颜色变化在临床上都是可以接受的。与机械抛光技术相比,上釉表面处理的颜色稳定性更好。在两种表面处理方法中,LDS 的颜色稳定性均高于 ZLS。
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引用次数: 0
DETERMINATION OF THE CHEMICAL AND MINERALOGICAL COMPOSITION OF TRACHIBASALTIC PORPHIRITE FROM THE GAVASAY FOR OBTAINING MINERAL FIBER 确定从加瓦萨耶获取矿物纤维的特斜长孔雀石的化学和矿物成分
Pub Date : 2023-08-01 DOI: 10.14489/glc.2023.08.pp.056-061
Z. Kadyrova, I. K. Shokosimov, M. Kazakova
The results of studies of the chemical and mineralogical compositions and the main characteristics for determining the suitability of trachybasaltic porphyrite from the Gavasay deposit of Uzbekistan for obtaining heat-insulating material, in particular mineral fiber, are presented. It has been established that this new deposit of igneous rock can be used as the main raw material component for the production of basalt fiber products, a widely demanded and modern material in the construction industry.
本文介绍了对化学成分和矿物成分的研究结果,以及确定乌兹别克斯坦加瓦萨依矿床中的赤玄武质玢岩是否适合用于生产隔热材料(尤其是矿物纤维)的主要特征。研究证实,这种新的火成岩矿床可用作生产玄武岩纤维产品的主要原料成分,玄武岩纤维是建筑行业广泛需求的现代材料。
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引用次数: 0
EFFECT OF DYSPROSIUM DOPING ON MICROSTRUCTURE AND DEGREE OF TEXTURING OF BISMUTH TELLURIDE-BASED THERMOELECTRIC MATERIALS 掺杂镝对碲化铋热电材料微观结构和纹理化程度的影响
Pub Date : 2023-08-01 DOI: 10.14489/glc.2023.08.pp.039-047
M. Yaprintsev, O. N. Ivanov
The purpose of this work was to prepare and identify the features of the microstructure and the degree of texturing of the thermoelectric material Bi2Te2.7Se0.3 doped with dysprosium. Textured Bi2-xDyxTe2.7Se0.3 compounds with x = 0.0000; 0.0010; 0.0025; 0.0050; 0.0100 and 0.0200 were prepared by using solvothermal synthesis and spark plasma sintering of starting powders. Dy-doping results in several interconnected effects. First of them is reducing in size of particles in starting powders with increasing x. This effect is attributed to increasing in ionic bonding fraction in polar covalent Bi(Dy)–Te bonds with increasing Dy content due to difference in electronegativity of Bi and Dy. With increasing x, grain size in bulk samples is also reducing, which is governed by relevant changing in the size of particles in the starting powders with different dopant content. This effect also results in enhancing in texturing degree in samples.
这项工作的目的是制备和确定掺杂镝的热电材料 Bi2Te2.7Se0.3 的微观结构特征和纹理程度。通过溶热合成和火花等离子烧结起始粉末,制备了 x = 0.0000; 0.0010; 0.0025; 0.0050; 0.0100 和 0.0200 的纹理 Bi2-xDyxTe2.7Se0.3 化合物。掺杂镝会产生几种相互关联的效应。由于 Bi 和 Dy 的电负性不同,随着 Dy 含量的增加,极性共价 Bi(Dy)-Te 键中的离子键比例也会增加。随着 x 值的增加,块状样品中的晶粒尺寸也在减小,这是由于不同掺杂剂含量的起始粉末中的颗粒尺寸发生了相关变化。这种效应还导致样品的纹理度增加。
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引用次数: 0
ELECTROTECHNICAL PORCELAIN BASED ON RAW MATERIALS OF UZBEKISTAN 基于乌兹别克斯坦原材料的电工瓷器
Pub Date : 2023-08-01 DOI: 10.14489/glc.2023.08.pp.048-055
Sh. M. Shamuratova, D. I. Alimdjanova, Z. T. Matkarimov
The paper presents the results of the research on the production of electrical porcelain on the basis of available traditional raw materials of Uzbekistan. It is shown that in conditions of a shortage of high-grade mineral raw materials for the production of electrical porcelain, it is advisable to add about half of the kaolin in the pre-fired state to the batch. At the same time, the products of firing at 1350 ?С of primary and secondary Angren kaolins allow us to consider them as a mullite-containing component, which further provides high physical, mechanical and dielectric properties of the porcelain material. The phase composition of the obtained porcelain is mainly represented by new crystalline components such as mullite and cristobalite, which gives the right to relate it to the mullite type of electro porcelain.
本文介绍了在乌兹别克斯坦现有传统原材料基础上生产电瓷的研究成果。结果表明,在电瓷生产所需的高级矿物原料短缺的情况下,最好在批次中加入约一半的预烧状态的高岭土。同时,初级和次级安格伦高岭土在 1350°C 煅烧后的产物允许我们将其视为含莫来石的成分,这进一步提供了瓷器材料的高物理、机械和介电性能。所获得瓷器的相组成主要由新的结晶成分如莫来石和嵴钴石组成,因此可以将其与莫来石类型的电瓷联系起来。
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引用次数: 0
NUCLEATION AND CRYSTALS GROWTH IN THE VOLUME OF GLASS Li2O–Al2O3–SiO2 SYSTEM 玻璃 Li2O-Al2O3-SiO2 系统体积中的核化和晶体生长
Pub Date : 2023-08-01 DOI: 10.14489/glc.2023.08.pp.003-011
A. S. Naumov, R. O. Alekseev, V. I. Savinkov, V. Sigaev
By the Marotta et al method, temperature of 670 ?C at a holding time of 2 hours provides the maximum rate of nucleation the crystalline phase of ?-eucryptite-like solid solutions was found. The activation energy of nucleation and the Avrami parameter were measured by the DSC method, allowing to estimate the crystallization characteristics. The gradient crystallization method has established the temperature range of heat treatment, within which it is possible to obtain a transparent glass-ceramic. The refinement of regime the nucleation stage made it possible to reduce the time of the second stage crystallization required for the complete formation of the transparent glass-ceramic structure. Varying the holding time at a temperature of 710 ?C makes it possible to smoothly change the CTE in the range of ?(3…+41)?10–7 K?1 in the temperature range from ?120 to +500 ?C.
根据马罗塔等人的方法,在 670 摄氏度的温度和 2 小时的保温时间下,"褐铁矿 "类固溶体结晶相的成核率达到最大。通过 DSC 方法测量了成核活化能和阿夫拉米参数,从而估算出结晶特性。梯度结晶法确定了热处理的温度范围,在此范围内可以获得透明的玻璃陶瓷。对成核阶段的制度进行改进,可以缩短完全形成透明玻璃陶瓷结构所需的第二阶段结晶时间。在 710 摄氏度的温度下改变保温时间,可以在 120 摄氏度到 500 摄氏度的温度范围内平滑地改变热膨胀系数,范围为(3...+41)?10-7 K?1。
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引用次数: 0
INFLUENCE OF TECHNOLOGICAL PARAMETERS OF THE FLOAT PROCESS ON THE ADHESION OF TIN OXIDES TO SHEET GLASS 浮法工艺的技术参数对氧化锡与玻璃板粘附性的影响
Pub Date : 2023-08-01 DOI: 10.14489/glc.2023.08.pp.012-017
E. R. Khorosheva, R. I. Makarov
The influence of the operating mode of the float bath on the adhesion of tin oxides to the lower surface of the produced glass ribbon was studied. Statistical analysis of the experimental data and modeling made it possible to quantify the influence of the glass ribbon formation mode and the chemical composition of the glass on the amount of tin oxide sticking.
研究了浮槽的运行模式对氧化锡粘附在所生产的玻璃丝带下表面的影响。通过对实验数据的统计分析和建模,可以量化玻璃带形成模式和玻璃的化学成分对氧化锡粘附量的影响。
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引用次数: 0
THERMODYNAMIC ANALYSIS OF OXIDE-CARBON AND CARBON MONOXIDE CHEMICAL REACTIONS IN ORDER TO SELECT ADDITIVES FOR CARBON NANOTUBE REINFORCED CORUNDUM CERAMICS 氧化物-碳和一氧化碳化学反应的热力学分析,以便为碳纳米管增强刚玉陶瓷选择添加剂
Pub Date : 2023-08-01 DOI: 10.14489/glc.2023.08.pp.026-032
M. I. Komarov, N. A. Makarov
The calculation of Gibbs energy for reactions of interaction of ZrO2, Al2O3, SiO2, TiO2, CaO and MnO with carbon and carbon monoxide in temperature range 1273 – 2273 К (1000 – 2000 ?С) is made to select eutectic additive for structural ceramics in Al2O3–ZrO2–eutectic additive–carbon nanotube system. Considering the multi-component structure of the ceramic matrix composite in the system Al2O3–ZrO2–eutectic additive–carbon nanotube system, it is necessary to consider the process of possible carbidization, worsening the strength characteristics of the synthesized material. As a result of the analysis, it was found that eutectic additives containing Al2O3, SiO2, TiO2, CaO.
计算了ZrO2、Al2O3、SiO2、TiO2、CaO和MnO在1273 - 2273 К (1000 - 2000 С)温度范围内与碳和一氧化碳相互作用的吉布斯能,以选择Al2O3-ZrO2-共晶添加剂-碳纳米管体系中结构陶瓷的共晶添加剂。考虑到 Al2O3-ZrO2-共晶添加剂-碳纳米管体系中陶瓷基复合材料的多组分结构,有必要考虑可能出现的碳化过程,从而恶化合成材料的强度特性。分析结果表明,含有 Al2O3、SiO2、TiO2 和 CaO 的共晶添加剂在碳纳米管体系中会产生碳化现象。
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引用次数: 0
APPLICATION OF BISMUTHATE GLASSES AS A SUBSTRATE FOR GAS SENSORS 铋酸玻璃作为气体传感器基底的应用
Pub Date : 2023-08-01 DOI: 10.14489/glc.2023.08.pp.018-025
V. A. Kjutvitsky, I. A. Romanova, E. V. Mironova, V. V. Borisova, O. I. Ostanina, F. N. Karashevtsev
The synthesis of bismuth-borate glasses was carried out Composition (mass content, %): 70 Bi2O3, 2 GeO2, 25 B2O3, 3 MoO3; 70 Bi2O3, 17 GeO2, 10 B2O3, 3 MoO3 and bismuth glasses. Composition (mass content, %): 80 Bi2O3, 4 GeO2, 5 MoO3, 11 SiO2; 80 Bi2O3, 8 GeO2, 8,5 SiO2, 3,5 MoO3. Processes have been developed for forming a layer based on glass receptors using the method of ultrasonic spraying of interacting components and applying a water-insoluble polymer film obtained by a chemical reaction between a poly-N,N-dimethyl-3,4-dimethylenepyrrolidinium chloride polymer and a modifier potassium hexacyanoferrate (II). The sensors obtained on the basis of glasses make it possible to determine the content of hydrogen sulfide and water vapor in the air with an error of 2 – 4 %.
铋硼玻璃的合成是在以下条件下进行的: 70 Bi2O3, 2 GeO2, 25 B2O3, 3 MoO370 Bi2O3、2 GeO2、25 B2O3、3 MoO3;70 Bi2O3、17 GeO2、10 B2O3、3 MoO3 和铋玻璃。成分(质量含量,%):80 Bi2O3、4 GeO2、5 MoO3、11 SiO2;80 Bi2O3、8 GeO2、8.5 SiO2、3.5 MoO3。已开发出利用超声波喷涂相互作用成分的方法,在玻璃受体的基础上形成一层,并涂上由聚-N,N-二甲基-3,4-二亚甲基吡咯烷氯化物聚合物和改性剂六氰基铁酸钾(II)发生化学反应而得到的不溶于水的聚合物膜的工艺。利用这种玻璃制成的传感器可以测定空气中硫化氢和水蒸气的含量,误差在 2 - 4 % 之间。
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引用次数: 0
INCREASING THE HYDROPHILICITY OF THE SURFACE OF CASTING MODELS WHEN APPLYING A PRIMER LAYER OF CERAMICS WITH A DEVELOPED SURFACE 在使用表面发达的陶瓷底层时,增加铸造模型表面的亲水性
Pub Date : 2023-08-01 DOI: 10.14489/glc.2023.08.pp.033-038
E. Novokreshchennykh, N. Uglev
For the manufacture of metal parts of complex shape, the most promising method is casting according to smelted or burnt models. As a smelted material, a complex composition of wax with other organic compounds is used, characterized by high constancy of physico-chemical and mechanical properties, since the accuracy of multiple reproduction of critical parts, for example, the blades of a turbojet engine, depends on it. The wax model is necessary for growing a ceramic shell around it, the accuracy of which is crucial for obtaining a high-quality casting. Since the surface of the wax model is hydrophobic, and the ceramic suspension applied to the model is created on a water basis, a critical factor in the shell manufacturing technology is the ideal wettability of the model surface by the suspension applied to it. Improvement of wettability can be achieved not only by introducing special surfactants into the aqueous phase, but also by changing the properties of the wax surface itself, i.e. giving it the properties of hydrophilicity. The paper presents a method of physical modification of the wax model surface, which consists in applying a thin layer of ceramic powder on it, which is well wetted with aqueous ceramic suspensions.
要制造形状复杂的金属零件,最有前途的方法是根据熔炼或烧制模型进行铸造。作为熔炼材料,使用蜡与其他有机化合物的复合成分,其特点是物理化学和机械性能的高度稳定性,因为关键部件(如涡轮喷气发动机的叶片)的多次复制精度取决于此。蜡模是在其周围生长陶瓷壳体的必要条件,而陶瓷壳体的精度对于获得高质量的铸件至关重要。由于蜡模表面是疏水性的,而涂抹在蜡模上的陶瓷悬浮液是在水的基础上形成的,因此壳体制造技术中的一个关键因素就是蜡模表面与涂抹在蜡模上的悬浮液的理想润湿性。改善润湿性不仅可以通过在水相中引入特殊的表面活性剂,还可以通过改变蜡表面本身的特性,即赋予其亲水性。本文介绍了一种对蜡模型表面进行物理改性的方法,即在蜡模型表面涂上一层薄薄的陶瓷粉末,然后用含水陶瓷悬浮液将其充分润湿。
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引用次数: 0
INVESTIGATION OF THE CHEMICAL INTERACTION OF HEAT-RESISTANT STEELS WITH ELECTROVACUUM GLASS G93-3M 耐热钢与电真空玻璃 G93-3M 的化学相互作用研究
Pub Date : 2023-07-01 DOI: 10.14489/glc.2023.07.pp.003-008
S. D. Gostev, I. Y. Gotz, T. G. Nasad
The paper considers the issue of the possible use of stainless steel grade 20Cr23Ni18 and its foreign analogue AISI 310S, instead of steel 12Cr18Ni10T, as a material for the manufacture of a shaping die in the production of glass insulators from electrovacuum glass grade G93-3M, widely used in the radio-electronic industry as cases for magnetic contacts. It is shown that at working temperatures there is a chemical interaction between both steels and glass of grade G93-3M, which leads to a deterioration in the quality of products due to the appearance of a large number of gas bubbles in it. It has also been shown that due to additional heat treatment it is possible to reduce the consequences of this chemical interaction, thereby increasing the quality of the resulting product.
本文探讨了在使用 G93-3M 级电真空玻璃生产玻璃绝缘子时,是否可能使用 20Cr23Ni18 不锈钢及其国外类似材料 AISI 310S,而不是 12Cr18Ni10T 钢,作为制造成型模具的材料,G93-3M 级电真空玻璃在无线电电子工业中广泛用作磁触点外壳。研究表明,在工作温度下,两种钢材和 G93-3M 级玻璃之间会发生化学作用,由于其中出现大量气泡,导致产品质量下降。研究还表明,通过额外的热处理,可以减少这种化学作用的后果,从而提高产品的质量。
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引用次数: 0
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Steklo i Keramika
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