首页 > 最新文献

IEEE Journal of Photovoltaics最新文献

英文 中文
Data-Driven Soiling Estimation and Optimized Cleaning Strategies for Industrial Rooftop PV Systems 数据驱动的工业屋顶光伏系统污染评估与优化清洁策略
IF 2.5 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-01-20 DOI: 10.1109/JPHOTOV.2025.3527124
Ankit Pal;Saravana Ilango Ganesan;Maddikara Jaya Bharata Reddy
The accumulation of dust and dirt on solar photovoltaic (PV) panels, known as soiling, reduces energy generation and conversion efficiency of a PV plant. Therefore, regular cleaning is essential to maintain optimal plant performance and economic viability. Fixed-interval cleaning schedules become uneconomical during periods such as low-insolation, rainy, or cloudy events. This study proposes a data-driven method to estimate the soiling ratio (SR) for a 504-kWp rooftop PV plant in India using power, temperature, and irradiance data. A PV panel temperature estimation model is employed, based on ambient temperature and solar irradiance, which simplifies the process by eliminating the need for direct temperature measurements. The analysis reveals that regular cleaning is essential despite rainfall, with energy losses due to soiling ranging from 32% to 47% across inverters, with soiling rates of 4.6–5.5% per day. A dynamic cleaning schedule, considering weather and soiling conditions, was developed to reduce these losses. Economic evaluation demonstrated that manual cleaning following the proposed dynamic schedule is cost effective, with profit margins of 48–77%, comparing energy gain and cleaning cost. Compared with fixed-interval cleaning, the proposed method maintained the same average SR but yielded 25–49% higher profitability across inverters.
太阳能光伏(PV)面板上的灰尘和污垢积聚,即所谓的污染,会降低光伏电站的能量产生和转换效率。因此,定期清洁对于保持最佳工厂性能和经济可行性至关重要。固定间隔的清洁计划在低日照、阴雨或多云天气时变得不经济。本研究提出了一种数据驱动的方法,利用电力、温度和辐照度数据来估计印度504kwp屋顶光伏电站的污染比(SR)。采用基于环境温度和太阳辐照度的光伏板温度估计模型,通过消除直接温度测量的需要,简化了过程。分析显示,尽管下雨,定期清洁是必不可少的,由于污染造成的能量损失在逆变器中从32%到47%不等,每天的污染率为4.6-5.5%。考虑到天气和污染情况,制定了动态清洁计划,以减少这些损失。经济评估表明,按照拟议的动态时间表进行人工清洁是具有成本效益的,比较能源收益和清洁成本,利润率为48-77%。与固定间隔清洗相比,该方法保持了相同的平均SR,但在逆变器上的盈利能力提高了25-49%。
{"title":"Data-Driven Soiling Estimation and Optimized Cleaning Strategies for Industrial Rooftop PV Systems","authors":"Ankit Pal;Saravana Ilango Ganesan;Maddikara Jaya Bharata Reddy","doi":"10.1109/JPHOTOV.2025.3527124","DOIUrl":"https://doi.org/10.1109/JPHOTOV.2025.3527124","url":null,"abstract":"The accumulation of dust and dirt on solar photovoltaic (PV) panels, known as soiling, reduces energy generation and conversion efficiency of a PV plant. Therefore, regular cleaning is essential to maintain optimal plant performance and economic viability. Fixed-interval cleaning schedules become uneconomical during periods such as low-insolation, rainy, or cloudy events. This study proposes a data-driven method to estimate the soiling ratio (SR) for a 504-kWp rooftop PV plant in India using power, temperature, and irradiance data. A PV panel temperature estimation model is employed, based on ambient temperature and solar irradiance, which simplifies the process by eliminating the need for direct temperature measurements. The analysis reveals that regular cleaning is essential despite rainfall, with energy losses due to soiling ranging from 32% to 47% across inverters, with soiling rates of 4.6–5.5% per day. A dynamic cleaning schedule, considering weather and soiling conditions, was developed to reduce these losses. Economic evaluation demonstrated that manual cleaning following the proposed dynamic schedule is cost effective, with profit margins of 48–77%, comparing energy gain and cleaning cost. Compared with fixed-interval cleaning, the proposed method maintained the same average SR but yielded 25–49% higher profitability across inverters.","PeriodicalId":445,"journal":{"name":"IEEE Journal of Photovoltaics","volume":"15 2","pages":"353-361"},"PeriodicalIF":2.5,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143455249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Encapsulant Degradation on Photovoltaic Modules Performances Installed in Different Climates 不同气候条件下封装剂降解对光伏组件性能的影响
IF 2.5 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-01-09 DOI: 10.1109/JPHOTOV.2024.3523546
Chiara Barretta;Astrid E. Macher;Marc Köntges;Julian Ascencio-Vásquez;Marko Topič;Gernot Oreski
A damage analysis was conducted on photovoltaic modules with identical bill of materials exposed to different climates: Cfb moderate and Af tropical, according to the Köppen-Geiger climate classification. The combination of high temperature, relative humidity, and high ultraviolet (UV) radiation was the cause of severe degradation for the modules exposed to tropical climates (TR), whereas the module exposed to a moderate climate did not experience a significant loss in performance. The modules installed in TR, on the contrary, showed significant power degradation after approximately 8 years of exposure, primarily attributed to acetic acid-related degradation modes. Encapsulant samples were extracted from the selected modules and characterized to determine changes in chemical structure, thermal stability, and consumption of additives and stabilizers. The results of qualitative additive analysis showed that the UV absorber was no longer detectable in the front encapsulant extracted from modules exposed in TR. The consumption of the stabilizers was considered as the main cause of reduction of molar mass. The presence of acetic acid was evident in both electroluminescence images and ion chromatography results. While differential scanning calorimetry successfully detected a reduction in molar mass, thermogravimetric analysis, and infrared spectroscopy proved unsuitable for identifying chain scission phenomena.
根据Köppen-Geiger气候分类,使用相同材料的光伏组件暴露在不同的气候条件下进行了损伤分析:Cfb温和和热带。高温、相对湿度和高紫外线(UV)辐射的组合是暴露在热带气候(TR)下的模块严重退化的原因,而暴露在温和气候下的模块在性能上没有显著损失。相反,安装在TR中的模块在暴露大约8年后显示出明显的功率下降,主要归因于醋酸相关的降解模式。从选定的模块中提取包封剂样品,并对其进行表征,以确定化学结构、热稳定性以及添加剂和稳定剂消耗的变化。定性添加剂分析结果表明,从TR中暴露的组件提取的前封装剂中不再检测到紫外线吸收剂,稳定剂的消耗被认为是摩尔质量减少的主要原因。电致发光图像和离子色谱结果均显示乙酸的存在。虽然差示扫描量热法成功地检测到摩尔质量的减少,但热重分析和红外光谱被证明不适合识别链断裂现象。
{"title":"Effect of Encapsulant Degradation on Photovoltaic Modules Performances Installed in Different Climates","authors":"Chiara Barretta;Astrid E. Macher;Marc Köntges;Julian Ascencio-Vásquez;Marko Topič;Gernot Oreski","doi":"10.1109/JPHOTOV.2024.3523546","DOIUrl":"https://doi.org/10.1109/JPHOTOV.2024.3523546","url":null,"abstract":"A damage analysis was conducted on photovoltaic modules with identical bill of materials exposed to different climates: Cfb moderate and Af tropical, according to the Köppen-Geiger climate classification. The combination of high temperature, relative humidity, and high ultraviolet (UV) radiation was the cause of severe degradation for the modules exposed to tropical climates (TR), whereas the module exposed to a moderate climate did not experience a significant loss in performance. The modules installed in TR, on the contrary, showed significant power degradation after approximately 8 years of exposure, primarily attributed to acetic acid-related degradation modes. Encapsulant samples were extracted from the selected modules and characterized to determine changes in chemical structure, thermal stability, and consumption of additives and stabilizers. The results of qualitative additive analysis showed that the UV absorber was no longer detectable in the front encapsulant extracted from modules exposed in TR. The consumption of the stabilizers was considered as the main cause of reduction of molar mass. The presence of acetic acid was evident in both electroluminescence images and ion chromatography results. While differential scanning calorimetry successfully detected a reduction in molar mass, thermogravimetric analysis, and infrared spectroscopy proved unsuitable for identifying chain scission phenomena.","PeriodicalId":445,"journal":{"name":"IEEE Journal of Photovoltaics","volume":"15 2","pages":"290-296"},"PeriodicalIF":2.5,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143455097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Novel Method for Performance Estimation of PV Modules Using Equivalent Irradiance and Temperature 利用等效辐照度和温度估算光伏组件性能的新方法
IF 2.5 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-01-09 DOI: 10.1109/JPHOTOV.2024.3521090
Jinlong Zhang;Zhenguang Liang;Yunpeng Zhang;Hai Zhou;Ji Wu;Honglu Zhu
The yield of photovoltaic (PV) modules is influenced by various environmental factors, particularly solar irradiance and temperature. However, the measured solar irradiance does not accurately represent the real light intensity absorbed by different types of solar cells, and the measured temperature does not represent the actual cell temperature in PV modules. In this article, equivalent irradiance and temperature are proposed and used to improve the accuracy of output performance estimation of PV modules. First, equivalent irradiance and temperature under different operating condition are obtained by fitting measured I–V data by using the guaranteed convergence particle swarm optimization. Second, the relationship between the equivalent irradiance and temperature and environmental factors is established by an artificial neural network (ANN) model. Two types of ANNs with different input vector are proposed to calculated equivalent irradiance and temperature. The accuracy of the proposed method was validated by experimental data for four different types of PV modules under wide operating conditions.
光伏(PV)组件的产率受到各种环境因素的影响,特别是太阳辐照度和温度。然而,测量到的太阳辐照度并不能准确地代表不同类型太阳能电池吸收的真实光强,测量到的温度也不能代表光伏组件中电池的实际温度。本文提出了等效辐照度和等效温度来提高光伏组件输出性能估计的准确性。首先,利用保证收敛粒子群算法对实测I-V数据进行拟合,得到不同工况下的等效辐照度和温度;其次,利用人工神经网络(ANN)模型建立等效辐照度与温度及环境因子之间的关系。提出了两种输入矢量不同的人工神经网络来计算等效辐照度和等效温度。通过四种不同类型光伏组件在广泛工况下的实验数据验证了所提方法的准确性。
{"title":"A Novel Method for Performance Estimation of PV Modules Using Equivalent Irradiance and Temperature","authors":"Jinlong Zhang;Zhenguang Liang;Yunpeng Zhang;Hai Zhou;Ji Wu;Honglu Zhu","doi":"10.1109/JPHOTOV.2024.3521090","DOIUrl":"https://doi.org/10.1109/JPHOTOV.2024.3521090","url":null,"abstract":"The yield of photovoltaic (PV) modules is influenced by various environmental factors, particularly solar irradiance and temperature. However, the measured solar irradiance does not accurately represent the real light intensity absorbed by different types of solar cells, and the measured temperature does not represent the actual cell temperature in PV modules. In this article, equivalent irradiance and temperature are proposed and used to improve the accuracy of output performance estimation of PV modules. First, equivalent irradiance and temperature under different operating condition are obtained by fitting measured <italic>I–V</i> data by using the guaranteed convergence particle swarm optimization. Second, the relationship between the equivalent irradiance and temperature and environmental factors is established by an artificial neural network (ANN) model. Two types of ANNs with different input vector are proposed to calculated equivalent irradiance and temperature. The accuracy of the proposed method was validated by experimental data for four different types of PV modules under wide operating conditions.","PeriodicalId":445,"journal":{"name":"IEEE Journal of Photovoltaics","volume":"15 2","pages":"274-279"},"PeriodicalIF":2.5,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143455099","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Spot-Area Method to Evaluate the Incidence Angle Modifier of Photovoltaic Devices-Part 2: Modules (Differential Method) 光电器件入射角修正量的点面积法-第二部分:模块(微分法)
IF 2.5 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-01-09 DOI: 10.1109/JPHOTOV.2024.3521121
Mauro Pravettoni;Min Hsian Saw;Muhammad Nabil Bin Abdul Aziz;Stephen En Rong Tay
In Part 1 of our article, we presented a method to quantify the incidence angle modifier (IAM) of photovoltaic (PV) devices, which differs from the methods proposed in IEC 61853-2 through the following: it utilizes a spot-area irradiation, delivered by an optical fiber system, a customized angle probe holder, and a current-to-voltage converter. Part 1 focused on single-cell devices and presented the validation of the new method on two different cell architectures. In Part 2, we generalize that method to commercial-size silicon PV modules, mirroring by the approach already used for module-level spectral responsivity measurements described in IEC 60904-8:2014. The proposed method is motivated by inclusion in the currently ongoing revision of IEC 61853-2, providing research centers and testing laboratories with an additional option to perform IAM measurements indoors. The reproducibility of the proposed method is addressed in this work via interlaboratory comparison with a different measurement method for the same quantity and with a detailed uncertainty analysis.
在本文的第1部分中,我们提出了一种量化光伏(PV)器件入射角修正器(IAM)的方法,该方法与IEC 61853-2中提出的方法有以下不同:它利用由光纤系统、定制角度探头支架和电流-电压转换器提供的点区域照射。第1部分侧重于单细胞设备,并介绍了在两种不同的细胞架构上验证新方法的方法。在第2部分中,我们将该方法推广到商业尺寸的硅光伏模块,通过IEC 60904-8:2014中描述的用于模块级光谱响应度测量的方法进行镜像。拟议的方法被纳入目前正在进行的IEC 61853-2修订版,为研究中心和测试实验室提供了在室内进行IAM测量的额外选择。本文通过与相同数量的不同测量方法的实验室间比较和详细的不确定度分析来解决所提出方法的可重复性问题。
{"title":"A Spot-Area Method to Evaluate the Incidence Angle Modifier of Photovoltaic Devices-Part 2: Modules (Differential Method)","authors":"Mauro Pravettoni;Min Hsian Saw;Muhammad Nabil Bin Abdul Aziz;Stephen En Rong Tay","doi":"10.1109/JPHOTOV.2024.3521121","DOIUrl":"https://doi.org/10.1109/JPHOTOV.2024.3521121","url":null,"abstract":"In Part 1 of our article, we presented a method to quantify the incidence angle modifier (IAM) of photovoltaic (PV) devices, which differs from the methods proposed in IEC 61853-2 through the following: it utilizes a spot-area irradiation, delivered by an optical fiber system, a customized angle probe holder, and a current-to-voltage converter. Part 1 focused on single-cell devices and presented the validation of the new method on two different cell architectures. In Part 2, we generalize that method to commercial-size silicon PV modules, mirroring by the approach already used for module-level spectral responsivity measurements described in IEC 60904-8:2014. The proposed method is motivated by inclusion in the currently ongoing revision of IEC 61853-2, providing research centers and testing laboratories with an additional option to perform IAM measurements indoors. The reproducibility of the proposed method is addressed in this work via interlaboratory comparison with a different measurement method for the same quantity and with a detailed uncertainty analysis.","PeriodicalId":445,"journal":{"name":"IEEE Journal of Photovoltaics","volume":"15 2","pages":"280-289"},"PeriodicalIF":2.5,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143455240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparison of Reflector Materials for a Vertical Bifacial Solar Canal 垂直双面太阳能管反射材料的比较
IF 2.5 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-01-06 DOI: 10.1109/JPHOTOV.2024.3521089
Jeremiah Reagan;Brandi McKuin;Sarah Kurtz
In this article, we assessed five reflector materials for hypothetical vertical bifacial arrays as a solar canal technology option. We screened the materials (CoverMax, CoverTuff, polyvinyl chloride (PVC) Poly, polyester canvas, and Vivosun aluminized Mylar) for reflectivity, tensile strength to minimum mounting load, vapor barrier performance to reduce evaporation, and energy production. Vivosun had the highest reflectivity (albedo of 0.87–0.93) and increased annual energy production more than 40% compared with a system without reflector, but plastically deformed under tensile strength testing. All materials reduced evaporation at least fivefold compared with the control. Following our preliminary assessment, we calculated the levelized cost of electricity of a hypothetical vertical bifacial array with two height configurations (short system at 2 m and tall system at 3 m) and four hybrid reflectors (fabricated from strong base layer materials with a top layer of Vivosun) and compared these results with systems with single-material reflectors and with systems without reflectors. We found that the tall system with a hybrid reflector made from PVC Poly had the lowest levelized cost of electricity. However, when considering other performance metrics, such as tensile strength and vapor barrier performance, a hybrid reflector made from CoverMax emerged as the best candidate of the options considered.
在本文中,我们评估了五种反射材料,假设垂直双面阵列作为太阳能管道技术的选择。我们筛选了材料(CoverMax、CoverTuff、聚氯乙烯(PVC)聚氯乙烯、聚酯帆布和Vivosun镀铝聚酯薄膜)的反射率、抗拉强度(最小安装负荷)、防蒸汽性能(减少蒸发)和能量产生。与没有反射镜的系统相比,Vivosun具有最高的反射率(反照率为0.87-0.93),年发电量增加了40%以上,但在拉伸强度测试中出现了塑性变形。与对照组相比,所有材料的蒸发量都减少了至少五倍。根据我们的初步评估,我们计算了一个假设的垂直双面阵列的平电成本,该阵列具有两种高度配置(2米短系统和3米高系统)和四个混合反射器(由坚固的底层材料制成,顶层是Vivosun),并将这些结果与具有单一材料反射器的系统和没有反射器的系统进行了比较。我们发现,由PVC聚氯乙烯制成的混合反射器的高系统具有最低的电力成本。然而,考虑到其他性能指标,如抗拉强度和防蒸汽性能,CoverMax制造的混合反射器成为了最佳选择。
{"title":"Comparison of Reflector Materials for a Vertical Bifacial Solar Canal","authors":"Jeremiah Reagan;Brandi McKuin;Sarah Kurtz","doi":"10.1109/JPHOTOV.2024.3521089","DOIUrl":"https://doi.org/10.1109/JPHOTOV.2024.3521089","url":null,"abstract":"In this article, we assessed five reflector materials for hypothetical vertical bifacial arrays as a solar canal technology option. We screened the materials (CoverMax, CoverTuff, polyvinyl chloride (PVC) Poly, polyester canvas, and Vivosun aluminized Mylar) for reflectivity, tensile strength to minimum mounting load, vapor barrier performance to reduce evaporation, and energy production. Vivosun had the highest reflectivity (albedo of 0.87–0.93) and increased annual energy production more than 40% compared with a system without reflector, but plastically deformed under tensile strength testing. All materials reduced evaporation at least fivefold compared with the control. Following our preliminary assessment, we calculated the levelized cost of electricity of a hypothetical vertical bifacial array with two height configurations (short system at 2 m and tall system at 3 m) and four hybrid reflectors (fabricated from strong base layer materials with a top layer of Vivosun) and compared these results with systems with single-material reflectors and with systems without reflectors. We found that the tall system with a hybrid reflector made from PVC Poly had the lowest levelized cost of electricity. However, when considering other performance metrics, such as tensile strength and vapor barrier performance, a hybrid reflector made from CoverMax emerged as the best candidate of the options considered.","PeriodicalId":445,"journal":{"name":"IEEE Journal of Photovoltaics","volume":"15 2","pages":"343-352"},"PeriodicalIF":2.5,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143455264","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Golden List of Reviewers 评审者黄金名单
IF 2.5 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-12-24 DOI: 10.1109/JPHOTOV.2024.3506132
{"title":"Golden List of Reviewers","authors":"","doi":"10.1109/JPHOTOV.2024.3506132","DOIUrl":"https://doi.org/10.1109/JPHOTOV.2024.3506132","url":null,"abstract":"","PeriodicalId":445,"journal":{"name":"IEEE Journal of Photovoltaics","volume":"15 1","pages":"200-203"},"PeriodicalIF":2.5,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://ieeexplore.ieee.org/stamp/stamp.jsp?tp=&arnumber=10814113","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880301","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IEEE Journal of Photovoltaics Publication Information IEEE光电杂志出版信息
IF 2.5 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-12-24 DOI: 10.1109/JPHOTOV.2024.3513575
{"title":"IEEE Journal of Photovoltaics Publication Information","authors":"","doi":"10.1109/JPHOTOV.2024.3513575","DOIUrl":"https://doi.org/10.1109/JPHOTOV.2024.3513575","url":null,"abstract":"","PeriodicalId":445,"journal":{"name":"IEEE Journal of Photovoltaics","volume":"15 1","pages":"C2-C2"},"PeriodicalIF":2.5,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://ieeexplore.ieee.org/stamp/stamp.jsp?tp=&arnumber=10814918","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigating the Crosslinking, Degradation, and Adhesion Behavior of Photovoltaic Encapsulants Under Thermal Accelerated Aging 热加速老化下光伏封装材料的交联、降解和粘附行为研究
IF 2.5 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-12-16 DOI: 10.1109/JPHOTOV.2024.3496512
Kuan Liu;David C. Miller;Nick Bosco;Jimmy M. Newkirk;Tomoko Sakamoto;Reinhold H. Dauskardt
Degradation of photovoltaic (PV) module encapsulant characteristics that lead to mechanical embrittlement and delamination remains a cause of failure in solar installations. A multiscale reliability model connecting the encapsulant mechanical and fracture properties to the degraded molecular structure and interfacial bonding to adjacent solar cell and glass substrates was previously published. The model, developed primarily for poly(ethylene-co-vinyl acetate) acetate (EVA) encapsulants, remains to be experimentally validated. Determining the degradation and crosslinking kinetics of alternative encapsulants, such as polyolefin elastomer (POE) and EVA/POE/EVA composites (EPE), can generalize the model. In this work, we subject fully cured EVA, POE, and EPE encapsulants to accelerated thermal aging to determine how high temperatures impact reaction kinetics. An increase in gel content (crosslinking) and decrease in crystallinity of the encapsulants under hot-aerobic (90 °C, 22% RH) and hot-anaerobic (90 °C, sealed in N2 air) aging were observed, even in the absence of UV and crosslinking initiators. Fourier transform infrared spectroscopy (FTIR)-attenuated total reflectance analysis showed insignificant encapsulant degradation, demonstrating the critical role of UV and moisture in accelerating degradation. Adhesion testing performed on coupon-level specimens (cell/encapsulant/glass laminates) showed decreases in adhesion energy, Gc, from 5000 h of hot-dry (90 °C, ∼1% RH) and hot-humid (90 °C, 60% RH) aging. POE coupons demonstrated the best stability, followed by EPE then EVA. For EVA and POE, hot-humid aged coupons experienced a larger decrease in Gc due to enhanced hydrolytic degradation. Hot-dry aging condition demonstrated that thermal degradation of the interface could be significant even if the encapsulant experiences negligible degradation in the absence of UV and elevated humidity.
光伏(PV)组件密封剂特性的退化导致机械脆化和分层仍然是太阳能装置失败的一个原因。先前发表了一个多尺度可靠性模型,将密封剂的力学和断裂性能与降解的分子结构以及与相邻太阳能电池和玻璃基板的界面结合联系起来。该模型主要用于聚(乙烯-醋酸乙烯)醋酸酯(EVA)密封剂,仍有待实验验证。确定替代封装剂的降解和交联动力学,如聚烯烃弹性体(POE)和EVA/POE/EVA复合材料(EPE),可以推广该模型。在这项工作中,我们将完全固化的EVA, POE和EPE密封剂进行加速热老化,以确定高温如何影响反应动力学。在热好氧(90℃,22% RH)和热厌氧(90℃,密封在N2空气中)老化条件下,即使在没有紫外线和交联引发剂的情况下,也观察到凝胶含量(交联)的增加和结晶度的降低。傅里叶变换红外光谱(FTIR)-衰减全反射分析显示封装剂降解不明显,表明紫外线和水分在加速降解中起关键作用。粘附测试显示,在5000小时的热干(90°C, ~ 1% RH)和湿热(90°C, 60% RH)老化过程中,粘附能(Gc)下降。POE券表现出最好的稳定性,其次是EPE,然后是EVA。对于EVA和POE,湿热老化券由于水解降解增强,Gc降低幅度较大。热干老化条件表明,即使封装剂在没有紫外线和高湿度的情况下经历可忽略的降解,界面的热降解也可能是显著的。
{"title":"Investigating the Crosslinking, Degradation, and Adhesion Behavior of Photovoltaic Encapsulants Under Thermal Accelerated Aging","authors":"Kuan Liu;David C. Miller;Nick Bosco;Jimmy M. Newkirk;Tomoko Sakamoto;Reinhold H. Dauskardt","doi":"10.1109/JPHOTOV.2024.3496512","DOIUrl":"https://doi.org/10.1109/JPHOTOV.2024.3496512","url":null,"abstract":"Degradation of photovoltaic (PV) module encapsulant characteristics that lead to mechanical embrittlement and delamination remains a cause of failure in solar installations. A multiscale reliability model connecting the encapsulant mechanical and fracture properties to the degraded molecular structure and interfacial bonding to adjacent solar cell and glass substrates was previously published. The model, developed primarily for poly(ethylene-co-vinyl acetate) acetate (EVA) encapsulants, remains to be experimentally validated. Determining the degradation and crosslinking kinetics of alternative encapsulants, such as polyolefin elastomer (POE) and EVA/POE/EVA composites (EPE), can generalize the model. In this work, we subject fully cured EVA, POE, and EPE encapsulants to accelerated thermal aging to determine how high temperatures impact reaction kinetics. An increase in gel content (crosslinking) and decrease in crystallinity of the encapsulants under hot-aerobic (90 °C, 22% RH) and hot-anaerobic (90 °C, sealed in N<sub>2</sub> air) aging were observed, even in the absence of UV and crosslinking initiators. Fourier transform infrared spectroscopy (FTIR)-attenuated total reflectance analysis showed insignificant encapsulant degradation, demonstrating the critical role of UV and moisture in accelerating degradation. Adhesion testing performed on coupon-level specimens (cell/encapsulant/glass laminates) showed decreases in adhesion energy, <italic>G<sub>c</sub></i>, from 5000 h of hot-dry (90 °C, ∼1% RH) and hot-humid (90 °C, 60% RH) aging. POE coupons demonstrated the best stability, followed by EPE then EVA. For EVA and POE, hot-humid aged coupons experienced a larger decrease in <italic>G<sub>c</sub></i> due to enhanced hydrolytic degradation. Hot-dry aging condition demonstrated that thermal degradation of the interface could be significant even if the encapsulant experiences negligible degradation in the absence of UV and elevated humidity.","PeriodicalId":445,"journal":{"name":"IEEE Journal of Photovoltaics","volume":"15 2","pages":"309-319"},"PeriodicalIF":2.5,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143455239","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of an Optical Library for Coevaporated CdSexTe1−x 共蒸发CdSexTe1−x光学库的研制
IF 2.5 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-12-04 DOI: 10.1109/JPHOTOV.2024.3507079
António J. N. Oliveira;Bin Du;Kevin D. Dobson;Jennifer P. Teixeira;Maria R. P. Correia;Pedro M. P. Salomé;William N. Shafarman
The conversion efficiency of CdTe solar cells may be improved by bandgap engineering, i.e., changing the bandgap value through the addition of Se in the absorber. The Se alloying enables a short-circuit current density improvement, as it leads to a bandgap energy value decrease. Furthermore, it has been associated with increased minority carrier lifetimes, assuring high open-circuit voltage values. An Se gradient profile control can further optimize the solar cell performance. Thus, an optical model baseline of the CdSexTe1−x (CST) compound was developed. Spectroscopic ellipsometry measurements were conducted to accurately extract the optical constants of ten CST layers deposited through coevaporation with x varying from 0 to 1. Using the measured dielectric function spectra from the discrete CST layers with varying x, and considering the composition-induced shift in the critical point energies, an energy-shift model was employed to develop the accurate optical library for the CST compound for any x value to provide data for future modeling and optimization. The library accuracy was validated through optical simulations of the quantum efficiency of a graded CST solar cell using the finite-difference time-domain method by replicating the Se profile in the absorber layer measured through secondary ion mass spectrometry.
带隙工程可以提高CdTe太阳能电池的转换效率,即通过在吸收剂中添加硒来改变带隙值。硒合金可以提高短路电流密度,因为它可以降低带隙能量值。此外,它还增加了少数载流子寿命,确保了高开路电压值。硒梯度轮廓控制可以进一步优化太阳能电池的性能。因此,开发了CdSexTe1−x (CST)化合物的光学模型基线。在x为0 ~ 1的条件下,利用椭偏光谱测量准确地提取了共蒸发沉积的10层CST层的光学常数。利用不同x值的CST离散层的介电函数光谱,考虑组分引起的临界点能量偏移,采用能量偏移模型建立了任意x值下CST化合物的精确光学库,为今后的建模和优化提供数据。利用有限差分时域方法模拟梯度CST太阳能电池的量子效率,通过复制二次离子质谱法测量的吸收层中的Se分布,验证了库的准确性。
{"title":"Development of an Optical Library for Coevaporated CdSexTe1−x","authors":"António J. N. Oliveira;Bin Du;Kevin D. Dobson;Jennifer P. Teixeira;Maria R. P. Correia;Pedro M. P. Salomé;William N. Shafarman","doi":"10.1109/JPHOTOV.2024.3507079","DOIUrl":"https://doi.org/10.1109/JPHOTOV.2024.3507079","url":null,"abstract":"The conversion efficiency of CdTe solar cells may be improved by bandgap engineering, i.e., changing the bandgap value through the addition of Se in the absorber. The Se alloying enables a short-circuit current density improvement, as it leads to a bandgap energy value decrease. Furthermore, it has been associated with increased minority carrier lifetimes, assuring high open-circuit voltage values. An Se gradient profile control can further optimize the solar cell performance. Thus, an optical model baseline of the CdSe<italic><sub>x</sub></i>Te<sub>1−</sub><italic><sub>x</sub></i> (CST) compound was developed. Spectroscopic ellipsometry measurements were conducted to accurately extract the optical constants of ten CST layers deposited through coevaporation with <italic>x</i> varying from 0 to 1. Using the measured dielectric function spectra from the discrete CST layers with varying <italic>x</i>, and considering the composition-induced shift in the critical point energies, an energy-shift model was employed to develop the accurate optical library for the CST compound for any <italic>x</i> value to provide data for future modeling and optimization. The library accuracy was validated through optical simulations of the quantum efficiency of a graded CST solar cell using the finite-difference time-domain method by replicating the Se profile in the absorber layer measured through secondary ion mass spectrometry.","PeriodicalId":445,"journal":{"name":"IEEE Journal of Photovoltaics","volume":"15 2","pages":"252-260"},"PeriodicalIF":2.5,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143455248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrical Modeling of Bifacial PV Modules 双面光伏组件的电气建模
IF 2.5 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-12-04 DOI: 10.1109/JPHOTOV.2024.3501403
Preeti Kumari Sahu;Efstratios I. Batzelis;Chandan Chakraborty;J. N. Roy
Although the bifacial photovoltaic (PV) module is now a mature technology, there still exists a gap in the literature on its electrical modeling and equivalent circuit representation. Most published studies have mainly focused on the photocurrent while overlooking other crucial parameters for the electrical response of the module. Even so, the photocurrent of the bifacial module is simplistically treated as the sum of individual currents of the front and rear sides, a hypothesis challenged in this study. Notably, our research has uncovered a discrepancy that can exceed 15%, and we address this issue by introducing a correction factor in this article. This article introduces a comprehensive electrical model that effectively integrates bifacial PV modules' front and rear sides into a single $-$ circuit representation. This novel model adopts the single $-$ diode equivalent circuit, formulating each of the five parameters as a function of the individual side's parameters. Indoor and outdoor measurements validate the accuracy improvement brought by this model, which can benefit energy yield studies and our theoretical understanding of bifacial PV systems.
虽然双面光伏组件已经是一种成熟的技术,但在其电气建模和等效电路表示方面的文献还存在空白。大多数已发表的研究主要集中在光电流上,而忽略了模块电响应的其他关键参数。即便如此,双面模块的光电流被简单地处理为前后两侧单个电流的总和,这一假设在本研究中受到挑战。值得注意的是,我们的研究发现了一个可能超过15%的差异,我们通过在本文中引入校正因子来解决这个问题。本文介绍了一个全面的电气模型,有效地将双面光伏模块的前后两面集成到一个单一的$-$电路表示中。这种新颖的模型采用单$-$二极管等效电路,将五个参数中的每一个作为单个侧参数的函数。室内和室外测量验证了该模型带来的精度提高,这有助于研究发电量和我们对双面光伏系统的理论认识。
{"title":"Electrical Modeling of Bifacial PV Modules","authors":"Preeti Kumari Sahu;Efstratios I. Batzelis;Chandan Chakraborty;J. N. Roy","doi":"10.1109/JPHOTOV.2024.3501403","DOIUrl":"https://doi.org/10.1109/JPHOTOV.2024.3501403","url":null,"abstract":"Although the bifacial photovoltaic (PV) module is now a mature technology, there still exists a gap in the literature on its electrical modeling and equivalent circuit representation. Most published studies have mainly focused on the photocurrent while overlooking other crucial parameters for the electrical response of the module. Even so, the photocurrent of the bifacial module is simplistically treated as the sum of individual currents of the front and rear sides, a hypothesis challenged in this study. Notably, our research has uncovered a discrepancy that can exceed 15%, and we address this issue by introducing a correction factor in this article. This article introduces a comprehensive electrical model that effectively integrates bifacial PV modules' front and rear sides into a single \u0000<inline-formula><tex-math>$-$</tex-math></inline-formula>\u0000 circuit representation. This novel model adopts the single \u0000<inline-formula><tex-math>$-$</tex-math></inline-formula>\u0000 diode equivalent circuit, formulating each of the five parameters as a function of the individual side's parameters. Indoor and outdoor measurements validate the accuracy improvement brought by this model, which can benefit energy yield studies and our theoretical understanding of bifacial PV systems.","PeriodicalId":445,"journal":{"name":"IEEE Journal of Photovoltaics","volume":"15 1","pages":"117-125"},"PeriodicalIF":2.5,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
IEEE Journal of Photovoltaics
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1