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Fifteenth International Conference on Thermoelectrics. Proceedings ICT '96最新文献

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Orientational distribution and procedure parameters in hot pressed (Bi2Te3)/sub 0.90/(Bi2Se3)/sub 0.10/ 热压(Bi2Te3)/sub 0.90/(Bi2Se3)/sub 0.10/的取向分布及工艺参数
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553252
K. Fukuda, H. Imaizumi, T. Ishii, F. Toyoda, M. Yamanashi, Y. Kibayashi
Single crystals of Bi/sub 2/Te/sub 3/ and its solid solutions with Bi/sub 2/Se/sub 3/ for n type material show anisotropy of thermoelectric property. Hot-pressed materials also show the anisotropy, but it is weaker than the single crystals and the one directional polycrystals. In a hot pressed material, crystal grains orient with an orientational distribution. In this work, we compared the orientational distributions of hot-pressed materials which were made by different process conditions and attempted to lead the best procedure parameters of a hot-pressed material that give a high Z-value.
n型材料的Bi/sub 2/Te/sub 3/单晶及其与Bi/sub 2/Se/sub 3/的固溶体表现出热电性能的各向异性。热压材料也表现出各向异性,但弱于单晶和单向多晶。在热压材料中,晶粒以定向分布定向。在本研究中,我们比较了不同工艺条件下热压材料的取向分布,并试图找出具有高z值的热压材料的最佳工艺参数。
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引用次数: 2
Analysis of quadrupole splitting of transition metal doped /spl beta/-FeSi2 掺杂/spl β /-FeSi2过渡金属的四极分裂分析
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553261
S. Kondo, M. Hasaka, T. Morimura
Large quadrupole splittings (Q.S.) are observed in Co doped specimen, compared with other transition metal doped specimens while isomer shifts (I.S.) do not show large value. Since Q.S. is associated with the electric field gradient at nucleus of iron atom; we calculate the potential at nucleus site, assuming the interaction between LA-phonon-conduction electron. Through the calculations, it is found that electric field gradient increase with the number of phonons attached to a conduction electron (=). Accordingly large Q.S. for Co doped specimen are considered to be due to large in comparison with those for other transition metal doped specimen.
与其他过渡金属掺杂样品相比,在Co掺杂样品中观察到较大的四极分裂(Q.S.),而异构体位移(I.S.)没有显示出大的值。由于q.s与铁原子原子核处的电场梯度有关;假设la -声子传导电子之间存在相互作用,我们计算了原子核位置的电势。通过计算发现,电场梯度随着附着在传导电子上的声子数的增加而增大(=)。因此,与其他过渡金属掺杂样品相比,认为Co掺杂样品的q.s较大。
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引用次数: 0
Thin film thermoelectric generator cell of Bi-Sb-Te-Se system Bi-Sb-Te-Se系统薄膜热电发电电池
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553520
Ii Kim, Dong-Hi Lee
Thin film thermoelectric generator cells (TFTEGCs) of the Bi-Sb-Te-Se system were fabricated and their performances were investigated. The generator cells were composed of several layers of plate-modules, and each plate-module contained 15 p/n couples and was connected electrically in series or in parallel. Variations of the open circuit voltage, short circuit current and maximum output power as a function of temperature difference showed a linear relationship for the first two values, but there was a second-order relationship for the latter. The output power produced per couple and per unit temperature difference was a 3.5 nW/K couple.
制备了Bi-Sb-Te-Se体系薄膜热电发电电池(TFTEGCs),并对其性能进行了研究。发电机电池由几层板模块组成,每个板模块包含15个p/n对,并以串联或并联的方式电连接。开路电压、短路电流和最大输出功率随温差的变化,前两个值呈线性关系,后两个值呈二阶关系。每对和每单位温差产生的输出功率为3.5 nW/K对。
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引用次数: 8
Electrical properties of /spl beta/-FeSi2 bulk crystal grown by horizontal gradient freeze method 水平梯度冷冻法生长/spl β /-FeSi2块状晶体的电学性质
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553257
H. Shibata, Y. Makita, H. Kakemoto, Y. Tsai, S. Sakuragi, H. Katsumata, A. Obara, N. Kobayashi, S. Uekusa, T. Tsukamoto, T. Tsunoda, Y. Imai
The growth of bulk iron silicide by Horizontal Gradient Freeze (HGF) method was achieved using different growth and annealing conditions. Two types of annealing process, in-situ annealing and ex-situ annealing, were examined. Three types of samples were prepared and examined; (i) samples which were not applied any annealing processes, (ii) samples which were applied in-situ annealing, and (iii) samples which were applied both in-situ and ex-situ annealing. The influence of annealing and growth conditions upon the material qualities was examined and discussed, putting special emphasis on the structural properties and electrical properties. Results of the X-ray diffraction revealed that only the in-situ annealing was not sufficient for the peritectic reaction from /spl alpha/+/spl epsi/ eutectic to peritectic /spl beta/-phase. However, it was revealed that, if the ex-situ annealing is applied after the in-situ annealing, the condition of 900/spl deg/C for 200 hours is enough for the ex-situ annealing to obtain almost single /spl beta/-phase. It was also confirmed in the aspect of electrical properties that ex-situ annealing at 900/spl deg/C for 300 hours is enough to realize electrically semiconducting /spl beta/-FeSi/sub 2/. The sample prepared under such a condition exhibited p-type conductivity with hole concentration and hole mobility about 5.68/spl times/10/sup 17/ cm/sup -3/ and 1.36 cm/sup 2/Ns, respectively.
在不同的生长条件和退火条件下,采用水平梯度冻结法(HGF)制备了块状硅化铁。研究了原位退火和非原位退火两种退火工艺。制备并检测了三种类型的样品;(i)未采用任何退火工艺的样品,(ii)采用原位退火工艺的样品,以及(iii)既采用原位退火又采用非原位退火工艺的样品。考察和讨论了退火和生长条件对材料质量的影响,重点讨论了材料的结构性能和电学性能。x射线衍射结果表明,原位退火不足以使/spl α /+/spl epsi/共晶向包晶/spl β /-相转变。结果表明,原位退火后再进行离地退火,在900/spl℃的温度下进行200小时的离地退火就足以获得几乎单/spl的β /-相。在电学性能方面也证实了900/spl℃脱位退火300小时足以实现电半导体/spl β /-FeSi/sub 2/。在此条件下制备的样品具有p型电导率,空穴浓度和空穴迁移率分别约为5.68/spl倍/10/sup 17/ cm/sup -3/和1.36 cm/sup 2/Ns。
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引用次数: 1
Evaluation of thermal junction quality in thermoelectric assemblies using transient analysis technology 利用瞬态分析技术评价热电组件的热结质量
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553320
T. Ritzer, M.J. Nagy, R. Buist
This paper describes the application of the transient analysis test method to evaluate the integrity of thermal junctions in a thermoelectric (TE) assembly. The quality of thermal junctions in assemblies was measured by creating a thermal gradient in the TE modules comprising an assembly and analyzing the decay of the residual Seebeck voltage. A study was made of various junction conditions that exist between the TE module and its heatsinks which are common to most assembly techniques. Poor thermal contacts were deliberately introduced such as insufficient thermal grease, inadequate compression and improper surface finishes in test assemblies in order to simulate typical assembly defects. A direct correlation between good and inadequate thermal junctions was established and illustrated through graphic test data evaluation.
本文介绍了瞬态分析测试方法在热电(TE)组件热结完整性评估中的应用。通过在包含组件的TE模块中创建热梯度并分析残余塞贝克电压的衰减,可以测量组件中热结的质量。对大多数组装技术中常见的TE模块与其散热器之间存在的各种结条件进行了研究。为了模拟典型的装配缺陷,在测试组件中故意引入了不良的热接触,例如导热油脂不足、压缩不足和表面处理不当。建立了良好和不充分热结之间的直接关系,并通过图形测试数据评价说明了这一点。
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引用次数: 2
Radiation defects induced by ion implantation as a promising method of doping semiconductor type AIVBIV films 离子注入诱导辐射缺陷是一种很有前途的掺杂半导体型AIVBIV薄膜的方法
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553523
Z. Dashevsky
Radiation defects in PbTe single crystals and epitaxial films induced by ion implantation of various impurities amounting to as much as 2/spl middot/10/sup 4/ /spl mu/C/cm/sup 2/ have been investigated. It has been found that the formation of point defects (for the most part, Te vacancies) running as deep as 3 /spl mu/m and more determine transport properties due to the stabilization of electron concentration at a level of 2+4/spl middot/10/sup 18/ cm/sup -3/. The data are interpreted based on the model of the quasi-local (doublet) energy level of Te vacancies in the PbTe conduction band. The formation of solid solutions accompanied by the increase of band gap was detected in PbTe thin layers implanted with Zn.
研究了不同杂质离子注入在PbTe单晶和外延膜中引起的辐射缺陷,缺陷大小可达2/spl middot/10/sup 4/ /spl mu/C/cm/sup 2/。由于电子浓度稳定在2+4/spl / middot/10/sup / 18/ cm/sup -3/这一水平上,深达3/ spl μ m以上的点缺陷(大部分为Te空位)的形成决定了输运性质。基于PbTe导带中Te空位的准局域(双重态)能级模型对数据进行了解释。在注入Zn的PbTe薄层中发现了固溶体的形成,并伴有带隙的增大。
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引用次数: 0
Evaluation of metal-Bi2Te3 contacts by electron tunneling spectroscopy 电子隧穿光谱评价金属- bi2te3接触
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553515
J. Nagao, E. Hatta, K. Mukasa
Understanding the states of the metal electrode-semiconductor junctions is important for improving the performance of the thermoelectric devices. Tunneling spectroscopy has been applied to the evaluation of metal-semiconductor Schottky junctions. In this study, tunneling spectroscopy is applied to understanding the states of a metal/Bi/sub 2/Te/sub 3/ or a metal/Bi/sub 2/Se/sub 3/ junction. Bi/sub 2/Te/sub 3/ and Bi/sub 2/Se/sub 3/ single crystals were prepared by Bridgman method. The metal contacts were made on the cleavage surface of Bi/sub 2/Te/sub 3/ or Bi/sub 2/Se/sub 3/ by the thermal evaporation in the vacuum of 10/sup -3/ Pa. All tunnel conductance were measured at 4.2 K. Mg/, Al/ and Ag/Bi/sub 2/Te/sub 3/ junctions exhibit V-shaped tunnel conductance curves which indicate that these contacts ate the Schottky barrier. A Au/Bi/sub 2/Te/sub 3/ junction shows a flat conductance characteristic, so that we expect to be an ohmic contact formed in this junction. It becomes clear that the Schottky barrier is formed on the Mg/, Al/, or Ag/-Bi/sub 2/Te/sub 3/ junction. In the case of Au/ or Al/Bi/sub 2/Se/sub 3/ is also formed the Schottky barrier. Since Bi/sub 2/Te/sub 3/ and Bi/sub 2/Se/sub 3/, which are narrow energy gap semiconductors, form the Schottky barriers with those metals, the characterization of metal-semiconductor contacts is important to improve the performance of thermoelectric devices.
了解金属电极-半导体结的状态对提高热电器件的性能具有重要意义。隧道光谱已被应用于金属-半导体肖特基结的评价。在本研究中,隧道光谱应用于了解金属/Bi/sub 2/Te/sub 3/或金属/Bi/sub 2/Se/sub 3/结的状态。采用Bridgman法制备了Bi/sub 2/Te/sub 3/单晶和Bi/sub 2/Se/sub 3/单晶。采用10/sup -3/ Pa真空热蒸发的方法,在Bi/sub 2/Te/sub 3/或Bi/sub 2/Se/sub 3/的解理表面形成金属触点。在4.2 K下测量所有隧道电导。Mg/、Al/和Ag/Bi/sub 2/Te/sub 3/结呈现出v型隧道电导曲线,表明这些接点处于肖特基势垒中。Au/Bi/sub 2/Te/sub 3/结显示出平坦的电导特性,因此我们期望在该结中形成欧姆接触。结果表明,在Mg/、Al/或Ag/-Bi/sub 2/Te/sub 3/结上形成了肖特基势垒。在Au/或Al/Bi/sub 2/Se/sub 3/的情况下也形成肖特基势垒。由于Bi/sub 2/Te/sub 3/和Bi/sub 2/Se/sub 3/是窄能隙半导体,它们与这些金属形成肖特基势垒,因此金属-半导体接触特性的表征对提高热电器件的性能具有重要意义。
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引用次数: 7
Influence of air heat sink geometry on the performance of thermoelectric cooling modules 空气散热器几何形状对热电冷却模块性能的影响
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553498
W. Zheng, G. Xu
Maximizing the rate of heat removal from the hot side of thermoelectric cooling modules is necessary to obtain optimum performance for any thermoelectric cooling device. The thickness, shape, height of fins and number of fins per inch are all important variables in a finned heat sink design. The area and thickness of the heat sink base plate relative to the area of the thermoelectric module is also important. This paper provides a means to calculate the effectiveness of these variables as they affect heat dissipation from the hot side of a thermoelectric module operated in the cooling mode. Although the focus is on cooling devices, the results of this model should be equally useful in evaluating power-generating devices.
最大化热电冷却模块热侧的热量排出率对于任何热电冷却装置都是获得最佳性能所必需的。翅片的厚度、形状、高度和每英寸鳍片的数量都是翅片式散热器设计的重要变量。相对于热电模块的面积,散热器底板的面积和厚度也很重要。本文提供了一种方法来计算这些变量的有效性,因为它们影响在冷却模式下运行的热电模块的热侧散热。虽然重点是冷却设备,但该模型的结果在评估发电设备方面同样有用。
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引用次数: 4
Potential applications of advanced thermoelectrics in the automobile industry 先进热电技术在汽车工业中的潜在应用
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553509
D. Morelli
Several proposed applications of thermoelectric devices in the automobile industry are reviewed. These are: exhaust gas thermoelectric generator; air conditioning (thermoelectric cooling); and microelectronics cooling using thin-film thermoelectrics. The key to the realization of these technologies is the continued development of new materials with increased thermoelectric efficiency.
综述了几种热电器件在汽车工业中的应用。这些有:废气热电发电机;空调(热电制冷);和微电子冷却使用薄膜热电。实现这些技术的关键是不断开发具有更高热电效率的新材料。
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引用次数: 26
The design problems of thermoelectric heat pumps for transportation facilities 交通运输用热电热泵的设计问题
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553310
A. A. Aivazov, Y.I. Stern, K. Makhratchev, A.V. Morgal
The paper describes the problems of design and construction development of thermoelectric (TH) air chillers for different means of transport. The report contains the description of the temperature operating conditions of TH air chillers and the procedures of the TH air chiller testing. The results of the stand operation of the TH air chiller at various voltages are analyzed. The paper highlights TH module mathematical modeling by means of equations account for the variation of the main TH properties across the thermocouple with the temperature gradient. The modeling of TH module operation is based on the numerical solution of a second order nonlinear differential equation. The solution obtained is compared with the results from a crude method and from the stand testing.
介绍了针对不同运输工具的热电空冷机组的设计和施工开发问题。该报告包含TH空冷机温度运行条件的描述和TH空冷机测试程序。分析了TH型空冷机组在不同电压下的运行结果。本文重点介绍了热电偶上主要TH特性随温度梯度变化的数学建模方法。TH模块运行的建模是基于一个二阶非线性微分方程的数值解。将所得解与原始法和台架试验结果进行了比较。
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引用次数: 0
期刊
Fifteenth International Conference on Thermoelectrics. Proceedings ICT '96
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