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Performance enhancement and emissions reduction in a diesel engine using oleander and croton biodiesel doped with graphene nanoparticles 使用夹竹桃和巴豆生物柴油掺杂石墨烯纳米颗粒的柴油发动机的性能增强和排放减少
IF 2.5 Q3 ENERGY & FUELS Pub Date : 2023-05-03 DOI: 10.14710/ijred.2023.51785
Treza Wambui, Meshack Hawi, Francis Njoka, J. Kamau
Biodiesel is considered a suitable substitute for petroleum diesel because it is renewable, environment-friendly, and has a low carbon footprint. However, its high density, high viscosity and low heating value prevents it from replacing petroleum diesel completely. This study investigates the performance and emission characteristics of a compression ignition engine operating on oleander and croton biodiesel doped with graphene nanoparticles. Five fuel samples are used, including diesel (D100), diesel - 80% blended with oleander and croton biodiesel - 20% (OCB20) and OCB20 dosed with graphene nanoparticles at mass fractions of 50 ppm (mg/L), 75 ppm (mg/L) and 100 ppm (mg/L), respectively. The chemical composition of biodiesel and graphene nanoparticles is analyzed using Fourier Transform Infrared (FTIR) spectroscopy while the morphology of the nanoparticles is analyzed using Scanning Electron Microscope (SEM). Engine tests reveal a significant improvement in brake thermal efficiency, especially at 75 ppm concentration which is 2.76%  and 18.93% higher than diesel and OCB20, respectively, and a reduction in brake specific fuel consumption by 2.44% and 16.67% compared to diesel and OCB20, respectively. Carbon monoxide (CO) and unburnt hydrocarbon emissions (UHC) decreases for the 50 ppm sample, recording 8.58% and 21.65% reduction in CO and 52.2% and 50% in UHC compared to the diesel and OCB20, respectively. However, Oxides of Nitrogen (NOx) emissions increase. The results indicate that graphene nanoparticle-enhanced biodiesel can adequately substitute petroleum diesel, albeit with NOx reduction techniques. 
生物柴油被认为是石油柴油的合适替代品,因为它是可再生的、环保的、低碳足迹的。但它的高密度、高粘度和低热值使其无法完全取代石油柴油。本研究研究了夹竹桃和巴豆生物柴油掺杂石墨烯纳米颗粒的压缩点火发动机的性能和排放特性。使用了五种燃料样品,包括柴油(D100),柴油- 80%与夹竹桃和巴豆生物柴油混合- 20% (OCB20)和OCB20添加石墨烯纳米颗粒,质量分数分别为50 ppm (mg/L), 75 ppm (mg/L)和100 ppm (mg/L)。利用傅里叶变换红外(FTIR)光谱分析了生物柴油和石墨烯纳米颗粒的化学成分,并用扫描电子显微镜(SEM)分析了纳米颗粒的形态。发动机试验表明,在75 ppm浓度下制动热效率显著提高,比柴油和OCB20分别提高2.76%和18.93%,制动比油耗分别比柴油和OCB20降低2.44%和16.67%。与柴油和OCB20相比,50 ppm样品的一氧化碳(CO)和未燃烧碳氢化合物(UHC)排放量分别减少了8.58%和21.65%,UHC排放量分别减少了52.2%和50%。然而,氮氧化物(NOx)排放增加。结果表明,石墨烯纳米颗粒增强的生物柴油可以充分替代石油柴油,尽管需要使用氮氧化物还原技术。
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引用次数: 1
Simulation and experimental study of refuse-derived fuel gasification in an updraft gasifier 垃圾燃料在上升气流气化炉中的气化模拟与实验研究
IF 2.5 Q3 ENERGY & FUELS Pub Date : 2023-05-01 DOI: 10.14710/ijred.2023.53994
T. Nguyen-Thi, Thi Minh Tu Bui, V. G. Bui
Refuse-derived fuel (RDF) made from the mixture of wood and loose rice husk increases the porosity of the fuel in the furnace to facilitate the gasification process. Simulation results show that CO is concentrated in the incomplete combustion zone and CO2 forms mainly in the fully burned area; CH4 forms in the reduction region, while H2 forms in the region of high temperature of the furnace. When the mixture composition was f=0.3, the CO concentration in the syngas reached about 21%, the H2 concentration reached about 2% and the CH4 concentration was too low to be ignored. When the mixture composition increased to f = 0.5, the CO concentration reached about 26%, the H2 concentration remained almost unchanged and the CH4 content increased to 6%. The calorific value of the syngas reached a maximum when f = 0.5 and the temperature of the reduction zone is in the range of 900K to 1200K. Air humidity affects CO concentration but not much on CH4 and H2 concentration as well as the syngas calorific value. The difference between simulation and experimental results is not more than 10% for CH4 concentration and not more than 14% for CO2 concentration. The power of the spark ignition engine is reduced by 30% when running on syngas compared to when running on gasoline.
由木材和松散稻壳的混合物制成的垃圾衍生燃料(RDF)增加了炉中燃料的孔隙率,以促进气化过程。模拟结果表明,CO主要集中在未完全燃烧区,CO2主要在完全燃烧区形成;CH4在还原区域中形成,而H2在熔炉的高温区域中形成。当混合物组成为f=0.3时,合成气中的CO浓度达到约21%,H2浓度达到约2%,CH4浓度太低而不能忽略。当混合物组成增加到f=0.5时,CO浓度达到约26%,H2浓度几乎保持不变,CH4含量增加到6%。当f=0.5并且还原区的温度在900K至1200K的范围内时,合成气的热值达到最大值。空气湿度影响CO浓度,但对CH4和H2浓度以及合成气热值影响不大。模拟结果和实验结果之间的差异对于CH4浓度不超过10%,对于CO2浓度不超过14%。与使用汽油时相比,使用合成气时火花点火式发动机的功率降低了30%。
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引用次数: 2
The application of equilibrium optimizer for solving modern economic load dispatch problem considering renewable energies and multiple-fuel thermal units 平衡优化器在考虑可再生能源和多燃料机组的现代经济负荷调度问题中的应用
IF 2.5 Q3 ENERGY & FUELS Pub Date : 2023-04-26 DOI: 10.14710/ijred.2023.52835
H. Nguyen, K. H. Truong, N. A. Le
This study presents a modern version of the economic load dispatch (MELD) problem with the contribution of renewable energies and conventional energy, including wind, solar and thermal power plants. In the study, reduction of electricity generation cost is the first priority, while the use of multiple fuels in the thermal power plant is considered in addition to the consideration of all constraints of power plants. Two meta-heuristic algorithms, one conventional and one recently published, including Particle swarm optimization (PSO) and Equilibrium optimizer (EO), are applied to determine the optimal solutions for MELD. A power system with ten thermal power plants using multiple fossil fuels, one wind power plant, and three solar power plants is utilized to evaluate the performance of both PSO and EO. Unlike other previous studies, this paper considers the MELD problem with the change of load demands over one day with 24 periods as a real power system. In addition, the power generated by both wind and solar power plants varies at each period. The results obtained by applying the two algorithms indicate that EO is completely superior to PSO, and the solutions found by EO can satisfy all constraints. Particularly in Case 1 with different load demand values, EO achieves better total electricity production cost (TEGC) than PSO by 0.75%, 0.87%, 0.13%, and 0.45% for the loads of 2400 MW, 2500 MW, 2600 MW and 2700 MW. Moreover, EO also provides a faster response capability over PSO through the four subcases although EO and PSO are run by the same selection of control parameters. In Case 2, the high efficiency provided by EO is still maintained, though the scale of the considered problem has been substantially enlarged. Specifically, EO can save $51.2 compared to PSO for the minimum TEGC. The savings cost is equal to 0.33% for the whole schedule of 24 hours. With these results, EO is acknowledged as a favourable search method for dealing with the MELD problem. Besides, this study also points out the difference in performance between a modern meta-heuristic algorithm (EO) and the classical one (PSO). The modern metaheuristic algorithm with special structure is highly valuable for complicated problem as MELD.
本研究提出了一个现代版本的经济负荷调度(MELD)问题,其中包括可再生能源和传统能源的贡献,包括风能、太阳能和火力发电厂。本研究以降低发电成本为第一要务,在考虑电厂各方面约束条件的基础上,考虑了火电厂多种燃料的使用。采用粒子群算法(PSO)和平衡优化算法(EO)两种传统的和最近发表的元启发式算法来确定MELD的最优解。利用一个由10个使用多种化石燃料的火力发电厂、1个风力发电厂和3个太阳能发电厂组成的电力系统来评估PSO和EO的性能。与以往的研究不同,本文考虑的是一个真实的电力系统,即24个时段的一天负荷需求变化的MELD问题。此外,风能和太阳能发电厂的发电量在每个时期都是不同的。两种算法的应用结果表明,蚁群算法完全优于粒子群算法,且蚁群算法的解能够满足所有约束条件。尤其在Case 1不同负荷需求值的情况下,在2400 MW、2500 MW、2600 MW和2700 MW负荷下,EO比PSO实现的总电力生产成本(TEGC)分别高0.75%、0.87%、0.13%和0.45%。此外,尽管EO和PSO在相同的控制参数选择下运行,但EO通过四个子案例也提供了比PSO更快的响应能力。在案例2中,尽管所考虑问题的规模已大大扩大,但EO提供的高效率仍然保持不变。具体来说,与PSO相比,EO可以为最低TEGC节省51.2美元。节约成本为24小时全程0.33%。基于这些结果,EO被认为是处理MELD问题的一种有利的搜索方法。此外,本文还指出了现代元启发式算法(EO)与经典元启发式算法(PSO)在性能上的差异。具有特殊结构的现代元启发式算法对MELD等复杂问题具有很高的应用价值。
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引用次数: 0
Mediating role of stock market volatility to evaluate asymmetries in the growth-degradation nexus in Nigeria 股票市场波动对评估尼日利亚增长-退化关系不对称性的中介作用
IF 2.5 Q3 ENERGY & FUELS Pub Date : 2023-04-18 DOI: 10.14710/ijred.2023.52322
Abdullah AlGhazali, Nana Ize Musa, S. S. Ibrahim, A. Samour
This study explores the mediating role of stock market volatility in the economic growth and environmental degradation nexus in Nigeria using data covering period from 1984 until 2020. The study uses Nonlinear Autoregressive Distributed Lag (NARDL) and a nonparametric asymmetric causality model. While the Wald test in model 1 reveals evidence of weak long-run asymmetric nexus between C02 and economic growth however, findings in model 2 indicates that stock market volatility (SMV) exerts a strong asymmetric effect in growth-C02 relation in the long-run. The result of nonlinear model validates the inverted U-shaped growth-degradation nexus consistent with EKC hypothesis. The finding in model 1 reveals that investment exerts a strong impact on C02 in both the short-run and long-run. On the other hand, the results in model 2 show that the positive component of economic growth has a positive and significant impact on C02 in Nigeria. However, the negative component of economic growth has a negative impact on C02. Moreover, the dynamic causality model reveals: (i) a feedback causality between C02 and the negative component of GDP; and (ii) a unidirectional causality flowing from C02 to the positive component of GDP. Similarly, result of nonlinear causality test reveals a feedback causality between CO2 and GDP. The implication of the finding suggests that while asymmetric properties of economic growth must be controlled in efforts of promoting environmental sustainability, the stock market has a dedicated role to play in widening access to funds for green investment in Nigeria and other developing economies
本研究利用1984年至2020年的数据,探讨了股票市场波动在尼日利亚经济增长和环境退化关系中的中介作用。研究采用非线性自回归分布滞后(NARDL)和非参数不对称因果关系模型。然而,模型1中的Wald检验表明,二氧化碳与经济增长之间存在较弱的长期不对称关系,而模型2的研究结果表明,股票市场波动(SMV)在长期增长-二氧化碳关系中具有很强的不对称效应。非线性模型的结果验证了倒u型生长-退化关系符合EKC假设。模型1的结果表明,投资对二氧化碳的短期和长期影响都很大。另一方面,模型2的结果表明,经济增长的正成分对尼日利亚的co2有显著的正向影响。然而,经济增长的负面成分对二氧化碳的影响是负面的。此外,动态因果关系模型表明:(1)co2与GDP负分量之间存在反馈因果关系;(ii)从二氧化碳到GDP正成分的单向因果关系。同样,非线性因果检验的结果显示CO2与GDP之间存在反馈因果关系。这一发现的含义表明,虽然在促进环境可持续性的努力中必须控制经济增长的不对称特性,但在尼日利亚和其他发展中经济体,股票市场在扩大绿色投资资金获取渠道方面可以发挥专门的作用
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引用次数: 0
Response surface optimization and social impact evaluation of Houttuynia cordata Thunb solar drying technology for community enterprise in Chiangrai, Thailand 泰国清莱社区企业鱼腥草太阳能干燥技术响应面优化及社会影响评价
IF 2.5 Q3 ENERGY & FUELS Pub Date : 2023-04-16 DOI: 10.14710/ijred.2023.52402
T. Kreetachat, S. Imman, K. Suwannahong, S. Wongcharee, N. Suriyachai
Drying has emerged as one of the most important ways of preserving high-quality and quantity food goods. A force convection solar drying is considered an ecologically and environmentally friendly alternative. This research presents parameter optimization of greenhouse tunnel dryer  of  Houttuynia cordata Thunb (H. cordata) using response surface methodology with the assessment of economic feasibility and social return on invesment. The influence parameters of the drying process were evaluated to obtain maximum efficiency. The individual parameters were temperature (40 – 60 °C), material length (10 – 30 cm), and relative humidity (30 – 50%). The individual parameters of drying temperature showed an extreme effect on the response of moisture content and color value change, while the relative humidity had only an influence on moisture content. On the other hand, the parameter of material length was not significance in both responses. When compared to open-air drying, solar drying reduced the drying time of H. cordata by 57.14%. The payback period of the dryer was found to be 2.5 years. Furthermore, the results reveal that the social return on investment ratio in 2021 was 2.18, then increasing to 2.52 in 2022 and 2.91 in 2023. According to the findings, solar drying technology has the potential to be an adequate product quality improvement technology for H. cordata. It is a feasible drying technology in terms of economic evaluation.
干燥已成为保存高质量和数量食品的最重要的方法之一。强制对流太阳能干燥被认为是一种生态和环境友好的替代方案。采用响应面法对鱼腥草温室隧道干燥机进行了参数优化,并对其经济可行性和社会投资回报率进行了评价。为了获得最大的干燥效率,对干燥过程的影响参数进行了评价。单个参数为温度(40 - 60°C),材料长度(10 - 30 cm)和相对湿度(30 - 50%)。干燥温度单项参数对水分含量和色值变化的响应有极端影响,相对湿度仅对水分含量有影响。另一方面,材料长度参数在两种响应中均不显著。与露天干燥相比,日光干燥可使天麻干燥时间缩短57.14%。烘干机的投资回收期为2.5年。此外,研究结果表明,2021年社会投资收益率为2.18,2022年和2023年分别增加到2.52和2.91。根据研究结果,太阳能干燥技术有潜力成为一种适当的产品质量改进技术。从经济评价上看,这是一种可行的干燥技术。
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引用次数: 1
Three-dimensional CFD-solid mechanics analysis of the hydrogen internal combustion engine piston subjected to thermomechanical loads 氢内燃机活塞在热机械载荷作用下的三维CFD固体力学分析
IF 2.5 Q3 ENERGY & FUELS Pub Date : 2023-04-07 DOI: 10.14710/ijred.2023.52496
M. Al-Baghdadi, S. Ahmed, N. Ghyadh
Fueling internal combustion engines with hydrogen is one of the most recommended alternative fuels today in order to combat the energy crisis, pollution problems, and climate change. Despite all the advantages of hydrogen fuel, it produces a higher combustion temperature than gasoline. In an internal combustion engine, the piston is among the numerous complex and highly loaded components. Piston surfaces are directly affected by combustion flames, making them critical components of engines. To examine the stress distribution and specify the critical fracture zones in the piston for hydrogen fuel engines, a three-dimensional CFD-solid-mechanics model of the internal combustion engine piston subjected to real thermomechanical loads was analyzed numerically to investigate the distribution of the temperature on the piston body, the interrelated thermomechanical deformations map, and the pattern of the stresses when fueling the engine with hydrogen fuel. With the aid of multiphysics COMSOL software, the CFD-solid-mechanics equations were solved with high accuracy. Despite the increase in pressure on the piston and its temperature when the engine is running on hydrogen fuel, the results show that the hydrogen fuel engine piston can withstand, safely, the thermomechanical loads. In comparison to gasoline fuel, hydrogen fuel caused a deformation of 0.34 mm, an increase of 17%. This deformation is within safe limits, with an average clearance of 0.867 mm between the cylinder liner and piston.
为内燃机提供氢燃料是当今最受推荐的替代燃料之一,以应对能源危机、污染问题和气候变化。尽管氢燃料有很多优点,但它的燃烧温度比汽油高。在内燃机中,活塞是众多复杂和高负荷部件之一。活塞表面直接受到燃烧火焰的影响,使其成为发动机的关键部件。为了研究氢燃料发动机活塞内部的应力分布,明确其临界断裂区域,建立了内燃机活塞在实际热力载荷作用下的三维cfd -固体力学模型,对其进行了数值分析,研究了活塞体上的温度分布、相关的热力变形图以及加氢时的应力分布规律。借助多物理场COMSOL软件,对cfd -固体力学方程进行了高精度求解。实验结果表明,在使用氢燃料时,活塞承受的压力和温度都有所增加,但氢燃料发动机活塞能够安全承受热机械载荷。与汽油燃料相比,氢燃料引起的变形量为0.34 mm,增加了17%。这种变形在安全范围内,缸套和活塞之间的平均间隙为0.867毫米。
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引用次数: 0
Experimental thermal and electrical performances of a PVT-air collector coupled to a humidification-dehumidification (HDH) cycle 与加湿-除湿(HDH)循环耦合的pvt -空气收集器的实验热学和电学性能
IF 2.5 Q3 ENERGY & FUELS Pub Date : 2023-04-04 DOI: 10.14710/ijred.2023.51808
Ahmed Ghazy
Despite their low electrical efficiencies, PVs are widely used to generate electricity from abundant solar energy. In order to maximize the utilization of incident solar energy, PVT collectors have been used to simultaneously generate electricity and thermal energy. Furthermore, combining PVTs with humidification-dehumidification (HDH) cycles can provide electricity and potable water in remote, arid rural areas that are not connected to the grid. In this paper, a PVT-air collector was coupled to an air-heated closed HDH cycle. Air was heated within the PVT collector and humidified by saline water spray inside the humidifier. Fresh water was produced by cooling humid air inside a dehumidifier that is cooled by saline water. The thermal and electrical performances of the PVT-HDH system were experimentally studied and compared to the electrical performance of a PV module with similar characteristics. The results demonstrated a significant decrease in PV temperature within the PVT-HDH system, which resulted in a 20% increase in the output power of the PVT-HDH system at midday compared to the identical PV module. In addition, the PVT-HDH system produced about 3.8 liters of water distillate for a PV module surface area of 1.48 m × 0.68 m, which contributed about 38% to the overall efficiency of the PVT-HDH system.
尽管它们的电效率很低,但pv被广泛用于利用丰富的太阳能发电。为了最大限度地利用入射太阳能,采用PVT集热器同时发电和发电。此外,将pvt与加湿-除湿(HDH)循环相结合,可以为没有连接到电网的偏远干旱农村地区提供电力和饮用水。在本文中,一个pvt -空气收集器耦合到一个空气加热的封闭HDH循环。空气在PVT集热器内加热,并在加湿器内用盐水喷雾加湿。淡水是通过在除湿机内用盐水冷却的潮湿空气来产生的。实验研究了PVT-HDH系统的热学和电学性能,并与具有相似特性的光伏组件的电学性能进行了比较。结果表明,PVT-HDH系统内的PV温度显著降低,与相同的PV组件相比,正午时PVT-HDH系统的输出功率增加了20%。此外,PV组件表面积为1.48 m × 0.68 m时,PVT-HDH系统产生约3.8升馏分水,这对PVT-HDH系统的整体效率贡献了约38%。
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引用次数: 0
Removal efficiency and reaction kinetics of phenolic compounds in refinery wastewater by nano catalytic wet oxidation 纳米催化湿式氧化法去除炼油废水中酚类化合物的效果及反应动力学
IF 2.5 Q3 ENERGY & FUELS Pub Date : 2023-03-30 DOI: 10.14710/ijred.2023.52044
Yousif S. Issa, K. Hamad, R. J. Algawi, Jasim I. Humadi, Sara Al-Salihi, Mustafa A. Ahmed, Ahmed A. Hassan, Abdul-Kareem Abd Jasim
A novel nano-catalyst based on iron oxide (MnO2/Fe2O3) was developed to promote wet oxidation of phenol. MnO2 was doped in Fe2O3 matrix to prepare composite nano-catalyst with different doping percentage (0, 2 and 5%). The catalytic phenol oxidation was conducted under different reaction temperatures and residence times. To evaluate the optimal kinetic parameters aiming to maximize phenol removal under the optimal conditions for the catalytic wet phenol oxidation process, modeling was applied on the batch reactor using the novel synthesis nano-catalyst (MnO2/Fe2O3) and the model developed was fed with the experimental data. gPROMS package was used to model the process of phenol oxidation and to optimize the experimental data. The error predicted between the simulated and experimental data was less than 5%. The optimal operating conditions were 294 min residence time, 70oC reaction temperature, and 764 ppm initial concentration of phenol over the prepared 5% MnO2/Fe2O3. Running of wet oxidation of phenol under the optimal operating conditions resulted in 98% removal of phenol from refinery wastewater.
研制了一种新型纳米氧化铁催化剂(MnO2/Fe2O3)促进苯酚湿式氧化。在Fe2O3基体中掺杂MnO2,制备不同掺杂比例(0、2、5%)的复合纳米催化剂。在不同的反应温度和停留时间下对苯酚进行了催化氧化。为评价湿式苯酚催化氧化工艺在最佳条件下最大限度去除苯酚的最佳动力学参数,对采用新型合成纳米催化剂(MnO2/Fe2O3)的间歇反应器进行了建模,并将模型与实验数据进行了比较。采用gPROMS软件对苯酚氧化过程进行了模拟,并对实验数据进行了优化。模拟结果与实验结果的误差小于5%。最佳操作条件为:反应时间294 min,反应温度70℃,苯酚初始浓度764 ppm,制备的MnO2/Fe2O3为5%。在最佳操作条件下对苯酚进行湿式氧化处理,苯酚去除率达98%。
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引用次数: 1
Willingness to pay for green energy sources in the United Arab Emirates (UAE) 阿拉伯联合酋长国(UAE)购买绿色能源的意愿
IF 2.5 Q3 ENERGY & FUELS Pub Date : 2023-03-29 DOI: 10.14710/ijred.2023.50575
Haileslasie Tadele, Baliira Kalyebara
This study investigates the willingness of customers in the UAE to pay a premium for green energy (GE) sources. Given the huge initial investment required for GE projects, raising capital is often achieved by increasing energy bills or taxes. To explore this issue, the study surveyed 192 small and medium-sized businesses using the contingent valuation method. The results indicate that while most businesses are aware of solar and wind energy sources and the importance of combating climate change, half of them are not willing to compromise their current energy use and do not support an increase in utility bills or taxes to finance GE projects. However, older businesses tend to be more willing to pay a premium for GE compared to younger businesses. Overall, majority of the businesses support a voluntary increase in electricity bills. The findings highlight the crucial role of current electricity bills and knowledge about GE sources in shaping customers' willingness to pay. This study contributes to the literature on energy finance and the contingent valuation method in the context of green energy in the UAE.
本研究调查了阿联酋客户为绿色能源(GE)支付溢价的意愿。鉴于通用电气项目需要巨额初始投资,筹集资金通常是通过增加能源账单或税收来实现的。为了探讨这一问题,本研究采用条件估值法对192家中小企业进行了调查。调查结果表明,虽然大多数企业都意识到太阳能和风能的重要性,以及应对气候变化的重要性,但其中一半的企业不愿意在目前的能源使用上妥协,也不支持增加公用事业账单或税收来为通用电气项目提供资金。然而,与年轻企业相比,老牌企业往往更愿意为通用电气支付溢价。总的来说,大多数企业支持自愿增加电费。研究结果强调了当前的电费账单和对通用电气资源的了解在影响客户支付意愿方面的关键作用。本研究对阿联酋绿色能源背景下的能源金融和条件评估方法的文献做出了贡献。
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引用次数: 0
Agricultural waste-based magnetic biochar produced via hydrothermal route for petroleum spills adsorption 水热法制备农业废弃物磁性生物炭用于石油泄漏吸附
IF 2.5 Q3 ENERGY & FUELS Pub Date : 2023-03-27 DOI: 10.14710/ijred.2023.52180
D. Ariyanti, I. N. Widiasa, M. Widiyanti, Dina Lesdantina, W. Gao
Oil spills are one of the marine pollution events triggered by the results of tanker operations (air ballast), ship repairs and maintenance (docking), mid-ocean loading and unloading terminals, air bilge (drainage of water, oil, and engine-processed lubricants), ship scrapping, and the most common accidents/collisions of tankers. The impacts vary from the death of marine organisms, especially fish, changes in reproduction and behavior of organisms, plankton contamination, fish migration, as well as ecosystem damage, and economic loss. Bio-based absorbents such as biochar can be an environmentally friendly alternative to chemical sorbents that works to adsorb oil spills faster. In this study, the effectiveness of magnetic biochar in oil spill removal was investigated. It also includes the synthesisation of magnetic biochar from agricultural waste (bagasse, rice husks, and sawdust) using the hydrothermal method at a temperature of 200°C. Hydrothermal carbonization is considered a cost-effective method for biochar production because the process can be carried out at low temperatures around 180°- 250°C. Biochar characterization was carried out with a Scanning Electron Microscope and Energy Dispersive X-Ray (SEM-EDX), Fourier Transform Infrared Spectroscopy (FTIR), and X-Ray Diffraction (XRD). The Brunauer, Emmett, and Teller (BET) and Barrett–Joyner–Halenda (BJH) were used to analyse the surface area and pore size distribution. Based on the results of the SEM-EDX analysis, only biochar was made from rice husk and sugarcane bagasse which contained Fe elements, as a result of the FeCl3.6H2O reaction. This condition is also proven by the presence of the FeO on both samples based on FTIR. The three synthesized biochar are amorphous and categorized as mesopores due to pore size around 15 to 16 nm, which can absorb petroleum spills with a percentage of 81% for sugarcane bagasse-based biochar, 84% for rice husk-based biochar, and 70% for sawdust-based biochar. Biochar from rice husk has excellent adsorption effectiveness with an adsorption capacity of 0.21 g/g in 60 min due to its large functional group area and the excellent attachment of magnetic compound into the biochar surface to form magnetic biochar.
石油泄漏是由油轮作业(压载)、船舶维修和维护(停靠)、海洋中部装卸码头、空气舱底(水、油和发动机加工润滑油的排放)、船舶报废以及油轮最常见的事故/碰撞引发的海洋污染事件之一。影响各不相同,包括海洋生物,特别是鱼类的死亡、生物繁殖和行为的变化、浮游生物污染、鱼类迁徙以及生态系统破坏和经济损失。生物炭等生物吸收剂是化学吸收剂的环保替代品,可以更快地吸附漏油。在本研究中,研究了磁性生物炭在清除溢油中的有效性。它还包括在200°C的温度下使用水热法从农业废弃物(甘蔗渣、稻壳和锯末)中合成磁性生物炭。水热碳化被认为是一种成本效益高的生物炭生产方法,因为该工艺可以在180°-250°C左右的低温下进行。利用扫描电子显微镜和能量分散X射线(SEM-EDX)、傅立叶变换红外光谱(FTIR)和X射线衍射(XRD)对生物炭进行了表征。Brunauer、Emmett和Teller(BET)和Barrett–Joyner–Halenda(BJH)用于分析表面积和孔径分布。基于SEM-EDX分析的结果,由于FeCl3.6H2O反应,仅由含有Fe元素的稻壳和甘蔗渣制成生物炭。基于FTIR,FeO在两个样品上的存在也证明了这种条件。三种合成的生物炭是无定形的,由于孔径约为15至16nm,被归类为中孔,其可以吸收石油泄漏,甘蔗渣基生物炭的吸收率为81%,稻壳基生物炭为84%,木屑基生物炭则为70%。稻壳生物炭具有良好的吸附效果,60分钟内吸附量为0.21 g/g,这是因为其官能团面积大,磁性化合物能很好地附着在生物炭表面形成磁性生物炭。
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引用次数: 1
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International Journal of Renewable Energy Development-IJRED
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