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Trends of surface ozone based on hourly concentrations in the Beijing–Tianjin–Hebei region during 2017–2021 2017-2021 年京津冀地区基于小时浓度的地表臭氧变化趋势
IF 2.3 4区 地球科学 Q3 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2024-11-01 DOI: 10.1016/j.aosl.2024.100514
Xiaoyan Wang, Huihui Zheng, Bing Liu, Shuyan Xie, Yonghai Huang, Shuai Wang
As a typical secondary air pollutant, surface ozone has been monitored routinely since 2013 in China. Most studies on the spatiotemporal variation of ozone have been centered around the daily maximum 8-h average, with little attention paid to the trends of hourly ozone, especially hourly ozone exceedances. Focusing on hourly ozone exceedances and peak values, the spatiotemporal trends of hourly ozone at 77 sites in 13 cities of the Beijing–Tianjin–Hebei (BTH) region during 2017–2021 were analyzed in this study. The number of hours with exceedances (NH200) in 2019 was nearly three times that of 2021. On a five-year average, the percentage of cumulative NH200 in June accounted for up to 40.5 % of all hourly exceedances. Cities in central Hebei Province had the highest cumulative annual NH200. June had the highest average hourly ozone exceeded multiples of 0.158. The top two cities with the highest average exceeded multiple were Tangshan (0.166) and Beijing (0.158). Tangshan and Xingtai ranked as the top two in terms of the mean of the 10 highest daily maximum ozone concentrations (MTDM), with 286.74 and 285.37 µg m−3, respectively. The gap between the MTDM and the daily maximum of hourly ozone averaged over all sites had narrowed to 97.88 µg m−3 in 2021, much lower than that in other years, which indicated that the stability and convergence of ozone pollution in BTH region had been enhanced in 2021 to some extent.
摘要
本文以京津冀地区为研究对象, 采用国际常用的评价指标, 在分析2017–2021年臭氧小时浓度变化趋势的基础上, 重点讨论了小时浓度超标情况及其峰值水平. 结果显示, 2019年臭氧小时浓度超标数约为2021年的3倍, 6月份小时浓度超标数占比高达40.5%, 河北中部城市小时浓度超标情况突出; 2017年和2019年臭氧小时浓度超标倍数在高位区间的占比相对最高, 唐山和邢台的小时浓度峰值水平相对较高. 本文可为后续进一步研究局地臭氧污染特征和异常污染事件提供基础参考.
作为典型的二次空气污染物,地表臭氧自 2013 年起在中国开始常规监测。对臭氧时空变化的研究大多围绕臭氧日最大值的 8 小时平均值展开,很少关注臭氧小时值的变化趋势,尤其是臭氧小时超标情况。本研究以臭氧小时超标和峰值为重点,分析了 2017-2021 年京津冀地区 13 个城市 77 个站点的臭氧小时时空变化趋势。2019年的超标小时数(NH200)是2021年的近3倍。从五年平均值来看,6 月份累计 NH200 小时数占所有超标小时数的比例高达 40.5%。河北省中部城市的 NH200 年累计值最高。6 月份臭氧平均小时超标倍数最高,为 0.158。平均超标倍数最高的前两个城市是唐山(0.166)和北京(0.158)。唐山和邢台分别以 286.74 微克/立方米和 285.37 微克/立方米的 10 个最高日臭氧浓度(MTDM)平均值位居前两位。2021 年,所有站点臭氧日最大小时浓度平均值与臭氧日最大小时浓度平均值的差距缩小至 97.88 µg m-3,远低于其他年份,这表明 2021 年京津冀地区臭氧污染的稳定性和趋同性得到了一定程度的增强。摘要本文以京津冀地区为研究对象,采用国际常用的评价指标,在分析 2017-2021 年臭氧小时浓度变化趋势的基础上,重点讨论了小时浓度超标情况及其峰值水平。结果显示,2019年臭氧小时浓度超标数约为2021年的3倍,6月份臭氧小时浓度超标数占比高达40.5%,河北中部城市臭氧小时浓度超标情况突出;2017年和2019年臭氧小时浓度超标倍数在高位区间的占比相对最高,唐山和邢台的臭氧小时浓度峰值水平相对较高。本文可为后续进一步研究局地臭氧污染特征和异常污染事件提供基础参考。
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引用次数: 0
Implications of the extremely hot summer of 2022 on urban ozone control in China 2022 年酷暑对中国城市臭氧控制的影响
IF 2.3 4区 地球科学 Q3 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2024-11-01 DOI: 10.1016/j.aosl.2024.100470
Wenhao Qiao, Ke Li, Zhenjiang Yang, Lei Chen, Hong Liao
Frequent occurrences of extreme heat are causing severe ozone pollution over China. This study examined the driving factors of urban ozone pollution in China during the extremely hot summer of 2022 and the impact of emission control strategies using surface measurements and the GEOS-Chem model. The results show that ozone pollution was extremely severe in summer 2022, with a significant rebound by 12–15 ppbv in the North China Plain (NCP), Yangtze River Delta (YRD), and Sichuan basin (SCB), compared to 2021. Especially over the NCP, the MDA8 (maximum daily 8-hourly average) ozone exceeded 160 ppbv, and the number of ozone exceedances was over 42 days. Based on an IPR (integrated process rate) analysis, the authors found that the net chemical production was the dominant factor contributing to the strong ozone increase in summer 2022. For example, in June over the NCP, the net chemical production resulted in an increase by 3.08 Gg d−1 (∼270%) in ozone mass change. Sensitivity simulations showed that both NOx (nitrogen oxides) and VOC (volatile organic compound) reductions were important over the NCP, and NOx reductions were more important than VOCs over southern China. To keep the ozone of 2022 at the same level as 2021, a joint reduction of NOx and VOCs by at least 50%–60% would have been required. This study highlights the urgency to develop effective ozone management since extreme heat will become more frequent.
摘要
本文利用地面观测和数值模式研究了2022年夏季极端高温下我国城市臭氧污染的控制策略. 研究表明, 2022年夏季臭氧污染极为严重, 相较于2021年有显著的反弹, 其中华北, 长三角和四川盆地的月均臭氧上升12–15 ppbv. 模式过程分析结果表明净化学生产是高温时造成臭氧浓度升高的主导因素. 模式多组敏感性试验表明, 华北地区需要NOx和VOC协同控制, 南方城市需要侧重对NOx排放管控, 并且需要对NOx和VOC协同减排至少50%–60% 才会使2022年夏季臭氧污染水平与2021年一致. 在极端高温愈发频繁的形势下, 本研究强调未来亟需研究更为有效的臭氧调控策略.
频繁出现的极端高温导致中国上空臭氧污染严重。本研究利用地面测量数据和 GEOS-Chem 模型,研究了 2022 年酷暑期间中国城市臭氧污染的驱动因素以及排放控制策略的影响。结果表明,2022 年夏季臭氧污染极为严重,与 2021 年相比,华北平原、长江三角洲和四川盆地的臭氧污染显著反弹了 12-15 ppbv。特别是在华北平原,MDA8(最大日 8 小时平均值)臭氧超过 160 ppbv,臭氧超标天数超过 42 天。根据 IPR(综合过程率)分析,作者发现净化学生产是导致 2022 年夏季臭氧剧增的主要因素。例如,6 月份在国家臭氧中心上空,净化学生产导致臭氧质量变化增加了 3.08 Gg d-1(∼270%)。敏感性模拟结果表明,氮氧化物(NOx)和挥发性有机化合物(VOC)的减少在国家臭氧方案中都很重要,而在华南地区,氮氧化物的减少比挥发性有机化合物更重要。要将 2022 年的臭氧保持在与 2021 年相同的水平上,需要将氮氧化物和挥发性有机化合物共同减少至少 50%-60%。摘要本文利用地面观测和数值模式研究了 2022 年夏季极端高温下我国城市臭氧污染的控制策略。研究表明,2022 年夏季臭氧污染极为严重,相较于 2021 年有显著的反弹,其中华北、长三角和四川盆地的月均臭氧上升 12-15 ppbv。模式过程分析结果表明净化学生产是高温时造成臭氧浓度升高的主导因素。多组敏感性试验表明, 华北地区需要对 NOx 和 VOC 协同控制, 南方城市需要侧重对 NOx 排放管控, 并且需要对 NOx 和 VOC 协同减排至少 50%-60% 才会使 2022 年夏季臭氧污染水平与 2021 年一致。在极端高温愈发频繁的形势下,本研究强调未来亟需研究更为有效的臭氧调控策略。
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引用次数: 0
Impacts of global biogenic isoprene emissions on surface ozone during 2000–2019 2000-2019 年间全球生物源异戊二烯排放对地表臭氧的影响
IF 2.3 4区 地球科学 Q3 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2024-11-01 DOI: 10.1016/j.aosl.2024.100490
Yang Cao , Xu Yue
Biogenic isoprene is an important precursor of tropospheric ozone (O3). Here, a coupled chemistry–vegetation model was used to quantify the contributions of isoprene emissions to surface O3 pollution on the global scale during 2000–2019. The biogenic isoprene emissions showed high values in mid–low latitudes and seasonal peaks in the summer hemispheres. They promote global surface O3 concentrations by 1.75 ppbv annually with regional hotspots of 4.39 ppbv (8.8%) in China and 5.36 ppbv (11.1%) in the U.S. in boreal summer. In the past two decades, isoprene emissions increased by 1.32 TgC yr−1 (0.67% yr−1) in the Northern Hemisphere but decreased by 0.71 TgC yr−1 (0.44% yr−1) in the Southern Hemisphere. Such changes of isoprene made opposite contributions to the surface O3 trend, with 0.26 ppbv yr−1 in eastern China but −0.32 ppbv yr−1 in the southeastern U.S. due to the changes in the background regime of chemical reactions. The impact of anthropogenic changes on the O3 trend is consistent with that of biogenic isoprene, but two to four times stronger in magnitude. This study revealed that the effective control of anthropogenic NOx emissions could mitigate regional O3 pollution even with the increased isoprene emissions under global warming.
生物异戊二烯是对流层臭氧(O3)的重要前体物。本文利用化学-植被耦合模型量化了 2000-2019 年间异戊二烯排放对全球地表臭氧污染的贡献。生物源异戊二烯排放量在中低纬度地区呈现高值,并在夏半球出现季节性峰值。它们每年使全球地表臭氧浓度增加 1.75 ppbv,其中中国和美国在北方夏季的区域热点分别为 4.39 ppbv(8.8%)和 5.36 ppbv(11.1%)。在过去二十年中,北半球的异戊二烯排放量增加了 1.32 TgC yr-1(0.67% yr-1),而南半球则减少了 0.71 TgC yr-1(0.44% yr-1)。由于化学反应背景机制的变化,异戊二烯的这种变化对地表 O3 趋势的贡献相反,在中国东部为 0.26 ppbv yr-1,而在美国东南部则为-0.32 ppbv yr-1。人为变化对臭氧趋势的影响与生物源异戊二烯的影响一致,但影响程度要强 2 到 4 倍。这项研究表明,即使在全球变暖的情况下异戊二烯排放量增加,有效控制人为氮氧化物排放也能减轻区域臭氧污染。
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引用次数: 0
Enhanced nitrous acid (HONO) formation via NO2 uptake and its potential contribution to heavy haze formation during wintertime 通过吸收二氧化氮增强亚硝酸(HONO)的形成及其对冬季重度灰霾形成的潜在作用
IF 2.3 4区 地球科学 Q3 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2024-11-01 DOI: 10.1016/j.aosl.2024.100491
Zirui Liu , Rong Yang , Jingyun Liu , Keding Lu , Guiqian Tang , Yuepeng Pan , Dongsheng Ji , Yuesi Wang , Bo Hu
A full understanding of the sources of atmospheric nitrous acid (HONO) in the polluted urban atmosphere remains a challenge. In this study, ambient HONO and relevant species were measured during January 2019 at an urban site in Beijing, China, and a budget analysis of HONO was conducted using a box model combined with field observations. Large nighttime “missing sources” of HONO were identified on heavily polluted days based on traditional sources, which had a significant correlation with the relative humidity, ammonia (NH3), and aerosol surface area, and the promotional effect of NH3 for nitrogen dioxide (NO2) uptake on the wet aerosol surface was discussed. Then, an updated parameterization scheme for quantifying the enhanced heterogeneous reactions of NO2 on aerosol surfaces is proposed, and the missing nighttime sources of HONO could be substantially compensated after the new scheme was incorporated. Further evaluation on the contributions of HONO to hydroxyl radicals was conducted, and the authors found that the photolysis of HONO played a dominant role in the primary OH production on the polluted days (78%–90%). The study reveals great potential of an NH3-enhanced uptake coefficient of NO2 on the aerosol surface in the nocturnal HONO budget, and highlights the significance of HONO in the strong atmospheric oxidation capability during episodes with a heavily polluted atmosphere.
摘要
本文研究了重污染过程中气态亚硝酸 (HONO) 的关键来源并基于化学箱模型对其源汇过程进行了闭合分析. 结果显示, 现有的HONO 源汇机制并不能解释观测期间出现的高HONO事件, 尤其是重污染过程夜间存在大量的HONO "未知源". 本文提出了一套新的HONO 源汇参数化方案, 可以较好的模拟观测期间HONO日间和夜间来源, 并进一步评估了HONO 对羟基自由基 (OH) 的贡献, 发现 HONO 光解主导了重污染天OH生成 (78%–90%). 研究结果揭示了华北城市富氨大气环境促进 NO2在气溶胶表面的摄取和非均相反应进而主导了夜间HONO生成, 凸显了HONO化学对于重污染过程维持大气氧化能力的重要作用.
全面了解受污染城市大气中的大气亚硝酸(HONO)来源仍然是一项挑战。在本研究中,我们于 2019 年 1 月在中国北京的一个城市站点测量了环境中的 HONO 和相关物种,并使用箱式模型结合实地观测结果对 HONO 进行了预算分析。根据传统来源确定了重污染日夜间大量的HONO "缺失源",与相对湿度、氨(NH3)和气溶胶表面积有显著相关性,并讨论了NH3对湿气溶胶表面二氧化氮(NO2)吸收的促进作用。然后,提出了一种用于量化二氧化氮在气溶胶表面增强的异质反应的最新参数化方案,在纳入新方案后,缺失的夜间 HONO 来源可以得到大幅补偿。作者进一步评估了 HONO 对羟基自由基的贡献,发现 HONO 的光解在污染日的一次羟基自由基生成中占主导地位(78%-90%)。该研究揭示了气溶胶表面的 NH3 增强吸收系数在夜间 HONO 预算中的巨大潜力,并强调了 HONO 在大气重污染过程中对大气强氧化能力的重要作用。摘要本文研究了重污染过程中气态亚硝酸 (hono) 的关键来源并基于化学箱模型对其源汇过程进行了闭合分析。结果显示, 现有的 hono 源汇机制并不能解释观测期间出现的高 hono 事件, 尤其是重污染过程夜间存在大量的 hono "未知源"。本文提出了一套新的 hono 源汇参数化方案, 可以较好的模拟观测期间 hono 日间和夜间来源, 并进一步评估了 hono 对羟基自由基 (oh) 的贡献, 发现 hono 光解主导了重污染天oh 生成 (78%-90%)。研究结果揭示了华北城市富氨大气环境促进 no2 在气溶胶表面的摄取和非均相反应进而主导了夜间 hono 生成, 凸显了 hono 化学对于重污染过程维持大气氧化能力的重要作用。
{"title":"Enhanced nitrous acid (HONO) formation via NO2 uptake and its potential contribution to heavy haze formation during wintertime","authors":"Zirui Liu ,&nbsp;Rong Yang ,&nbsp;Jingyun Liu ,&nbsp;Keding Lu ,&nbsp;Guiqian Tang ,&nbsp;Yuepeng Pan ,&nbsp;Dongsheng Ji ,&nbsp;Yuesi Wang ,&nbsp;Bo Hu","doi":"10.1016/j.aosl.2024.100491","DOIUrl":"10.1016/j.aosl.2024.100491","url":null,"abstract":"<div><div>A full understanding of the sources of atmospheric nitrous acid (HONO) in the polluted urban atmosphere remains a challenge. In this study, ambient HONO and relevant species were measured during January 2019 at an urban site in Beijing, China, and a budget analysis of HONO was conducted using a box model combined with field observations. Large nighttime “missing sources” of HONO were identified on heavily polluted days based on traditional sources, which had a significant correlation with the relative humidity, ammonia (NH<sub>3</sub>), and aerosol surface area, and the promotional effect of NH<sub>3</sub> for nitrogen dioxide (NO<sub>2</sub>) uptake on the wet aerosol surface was discussed. Then, an updated parameterization scheme for quantifying the enhanced heterogeneous reactions of NO<sub>2</sub> on aerosol surfaces is proposed, and the missing nighttime sources of HONO could be substantially compensated after the new scheme was incorporated. Further evaluation on the contributions of HONO to hydroxyl radicals was conducted, and the authors found that the photolysis of HONO played a dominant role in the primary OH production on the polluted days (78%–90%). The study reveals great potential of an NH<sub>3</sub>-enhanced uptake coefficient of NO<sub>2</sub> on the aerosol surface in the nocturnal HONO budget, and highlights the significance of HONO in the strong atmospheric oxidation capability during episodes with a heavily polluted atmosphere.</div><div>摘要</div><div>本文研究了重污染过程中气态亚硝酸 (HONO) 的关键来源并基于化学箱模型对其源汇过程进行了闭合分析. 结果显示, 现有的HONO 源汇机制并不能解释观测期间出现的高HONO事件, 尤其是重污染过程夜间存在大量的HONO \"未知源\". 本文提出了一套新的HONO 源汇参数化方案, 可以较好的模拟观测期间HONO日间和夜间来源, 并进一步评估了HONO 对羟基自由基 (OH) 的贡献, 发现 HONO 光解主导了重污染天OH生成 (78%–90%). 研究结果揭示了华北城市富氨大气环境促进 NO<sub>2</sub>在气溶胶表面的摄取和非均相反应进而主导了夜间HONO生成, 凸显了HONO化学对于重污染过程维持大气氧化能力的重要作用.</div></div>","PeriodicalId":47210,"journal":{"name":"Atmospheric and Oceanic Science Letters","volume":"17 6","pages":"Article 100491"},"PeriodicalIF":2.3,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140401827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Clarifying the relationship between PM2.5 and ozone complex pollution and synoptic patterns in a typical petrochemical city in the Bohai Rim region of China: Implications for air pollution forecasting and control 厘清中国环渤海地区典型石化城市 PM2.5 和臭氧复合污染与同步模式之间的关系:对空气污染预报和控制的启示
IF 2.3 4区 地球科学 Q3 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2024-11-01 DOI: 10.1016/j.aosl.2024.100539
Yongxin Yan , Cong An , Junling Li , Yuanyuan Ji , Rui Gao , Hong Wang , Fanyi Shang , Linlin Ma , Xiaoshuai Gao , Hong Li
Meteorological conditions are vital to PM2.5 and ozone (O3) complex pollution. Herein, the T-mode principal component analysis method was employed to objectively classify the 925-hPa geopotential height field of Dongying from 2017 to 2022. Synoptic patterns associated with four pollution types—namely, PM2.5-only pollution, O3-only pollution, Co-occurring of PM2.5 and O3 pollution, Non-occurring of PM2.5 and O3 pollution—were characterized at different time scales. The results indicated that synoptic classes conducive to PM2.5-only pollution were “high-pressure top front”, “offshore high-pressure rear”, and “high-pressure inside”, while those conducive to O3-only pollution were “offshore high-pressure rear”, “subtropical high”, and “high and low systems”. The Co-occurring of PM2.5 and O3 pollution were influenced by high pressure, and the Non-occurring of PM2.5 and O3 pollution were linked to precipitation and strong northerly winds. The variation in dominant synoptic patterns is crucial in the frequency changes of the four pollution types, which was further validated through the analysis of typical cases. Under the favorable meteorological conditions of high-pressure control with strong northerly winds or a subtropical high and inverted trough both with strong precipitation, there is potential to achieve coordinated control of PM2.5 and O3 in Dongying. Additionally, measures like artificially manipulating local humidity could be adopted to alleviate pollution levels. This study reveals the importance of comprehending the meteorological factors contributing to the formation of PM2.5 and O3 complex pollution for the improvement of urban air quality in the Bohai Rim region of China when emissions are high and the concentration of air pollutants exhibits high meteorological sensitivity.
摘要
本文研究了中国环渤海地区典型石化城市东营市近年来PM2.5与臭氧复合污染的天气形势特征. 结果表明, 有利于促发PM2.5单独污染的环流形势与高压顶前部型, 海上高压后部型, 高压内部型有关; 有利于促发臭氧单独污染的天气型与海上高压后部, 副高和高低值系统有关; PM2.5和臭氧双高污染的发生主要受高压系统的控制; 不利于PM2.5和臭氧污染发生的环流类型则与降水和较强的偏北风有关. 优势天气型的变化是导致四种污染类型发生频率变化的重要因素. 研究结果揭示了当一次排放处于高位, 且空气污染物浓度变化具有高气象敏感性的情况下, 弄清PM2.5和臭氧复合污染的气象成因对于中国环渤海地区城市空气质量持续改善的重要意义.
气象条件对PM2.5和臭氧(O3)复合污染至关重要。本文采用T模式主成分分析方法,对2017年至2022年东营925-hPa位势高度场进行了客观分类。在不同时间尺度上对四种污染类型--纯PM2.5污染、纯O3污染、PM2.5和O3共存污染、PM2.5和O3非共存污染--相关的天气模式进行了表征。结果表明,"高压顶锋"、"近海高压后部 "和 "高压内部 "是有利于PM2.5污染的天气等级,而 "近海高压后部"、"副热带高压 "和 "高低系统 "是有利于PM2.5污染的天气等级。PM2.5和O3污染同时出现受高压影响,PM2.5和O3污染不出现与降水和强偏北风有关。主导合流模式的变化对四种污染类型的频率变化至关重要,这一点通过对典型案例的分析得到了进一步验证。在高压控制伴有强偏北风或副热带高压和倒槽同时伴有强降水的有利气象条件下,东营市有可能实现PM2.5和O3的协同控制。此外,还可以采取人工调节当地湿度等措施来缓解污染程度。本研究揭示了在中国环渤海地区大气污染物排放高、空气污染物浓度表现出高气象敏感性的情况下,理解导致 PM2.5 和 O3 复合污染形成的气象因素对于改善城市空气质量的重要性。摘要本文研究了中国环渤海地区典型石化城市东营市近年来pm2.5与臭氧复合污染的天气形势特征。结果表明, 有利于促发pm2.5单独污染的环流形势与高压顶前部型, 海上高压后部型, 高压内部型有关; 有利于促发臭氧单独污染的天气型与海上高压后部, 副高和高低值系统有关; pm2.5和臭氧双高污染的发生主要受高压系统的控制; 不利于pm2.5和臭氧污染发生的环流类型则与降水和较强的偏北风有关.天气优势型的变化是导致四种污染类型发生频率变化的重要因素。研究结果揭示了当一次排放处于高位, 且空气污染物浓度变化具有高气象敏感性的情况下, 弄清pm2.5和臭氧复合污染的气象成因对于中国环渤海地区城市空气质量持续改善的重要意义。
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引用次数: 0
Coordinated control of PM2.5 and O3: Investigating the physical and chemical processes underlying regional complex air pollution 协调控制 PM2.5 和 O3:研究区域复杂空气污染的物理和化学过程
IF 2.3 4区 地球科学 Q3 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2024-11-01 DOI: 10.1016/j.aosl.2024.100562
Aijun Ding , Meigen Zhang , Likun Xue
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引用次数: 0
Vertical distributions of VOCs in the Tibetan Plateau background region 青藏高原本底区域挥发性有机化合物的垂直分布
IF 2.3 4区 地球科学 Q3 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2024-11-01 DOI: 10.1016/j.aosl.2024.100516
Xuanxuan Xue , Fugeng Zha , Yinghong Wang , Yang Zhang , Yu Wang , Ying Shen , Yanyu Kang , Dan Yao , Guiqian Tang , Jianchun Bian , Yuesi Wang
Exploring the vertical variation in volatile organic compounds (VOCs) in background regions can provide information on the spatial distribution of pollutants, providing a scientific basis for atmospheric pollution prevention and control strategies. From 15 August to 5 September 2023, at the Southeast Tibet Mountain Comprehensive Environmental Observation Station (SETS), a tethered balloon was used to sample VOCs every 100 m from the ground to 1000 m. A total of 403 air bag samples were collected, and 39 vertical profiles of VOCs were obtained. Ninety-two VOC species were detected. The VOC concentration at the SETS did not change significantly vertically, and the average VOC concentration was 11.1 ± 2.4 ppbv. The main components were alkanes (51.4 %), alkenes (18.7 %), and halohydrocarbons (18.1 %). There was no obvious diurnal change in VOCs and no significant difference between the different layers. When the surface VOC concentration was less than 10 ppbv, the concentrations, components, and sources of VOCs were evenly distributed vertically, and the main sources of VOCs at different heights were vehicle exhaust and background. When the surface VOC concentration exceeded 10 ppbv, the VOC concentration gradually decreased with height. The proportion of alkanes in surface VOCs increased, and the source was mainly vehicle exhaust. This study confirmed that VOCs are vertically homogeneous in the background of the Tibetan Plateau, emphasizing the importance of vehicle emissions as a potential source of VOCs.
摘要
研究背景区域挥发性有机物 (VOCs) 的垂直变化规律, 可以提供污染物的空间分布信息, 为制定大气污染防治策略提供科学依据. 2023年夏季, 利用系留气艇对藏东南背景区域VOCs垂直分布规律进行研究, 共获取92种VOC的39条垂直廓线. 结果表明, VOC浓度垂直分布均一, 平均浓度为11.1 ± 2.4 ppbv; 主要成分为烷烃 (51.4 %), 烯烃 (18.7 %) 和卤代烃 (18.1 %). 地表VOC浓度小于10 ppbv时, 不同高度VOCs的主要来源为机动车尾气和背景贡献. 而地表VOC浓度超过10 ppbv时, 烷烃占比增加, 来源以机动车尾气为主. 该研究证实了青藏高原VOC在垂直方向上分布均一, 强调了机动车排放作为VOCs潜在来源的重要性.
探索本底区域挥发性有机物(VOCs)的垂直变化,可以提供污染物的空间分布信息,为大气污染防治策略提供科学依据。2023 年 8 月 15 日至 9 月 5 日,在藏东南山地环境综合观测站(SETS),利用系留气球从地面至 1000 米处每隔 100 米进行一次 VOCs 采样,共采集 403 个气囊样品,获得 39 条 VOCs 垂直剖面图。共检测到 92 种挥发性有机化合物。在垂直方向上,SETS 的挥发性有机化合物浓度变化不大,平均浓度为 11.1 ± 2.4 ppbv。主要成分为烷烃(51.4%)、烯烃(18.7%)和卤代烃(18.1%)。挥发性有机化合物没有明显的昼夜变化,不同层之间也没有显著差异。当地表挥发性有机化合物浓度小于 10 ppbv 时,挥发性有机化合物的浓度、成分和来源呈均匀的垂直分布,不同高度的挥发性有机化合物主要来源于汽车尾气和背景。当地表挥发性有机化合物浓度超过 10 ppbv 时,挥发性有机化合物浓度随高度逐渐降低。表面挥发性有机化合物中烷烃的比例增加,其来源主要是汽车尾气。这项研究证实了青藏高原背景区域挥发性有机物在垂直方向上是均匀的,强调了汽车尾气作为挥发性有机物潜在来源的重要性。摘要研究背景区域挥发性有机物 (VOCs) 的垂直变化规律,可以提供污染物的空间分布信息,为制定大气污染防治策略提供科学依据。2023 年夏季,利用系留气艇对东南背景区域 VOCs 垂直分布规律进行研究, 共获取 92 种 VOC 的 39 条垂直廓线。结果表明,VOC 浓度垂直分布均一,平均浓度为 11.1 ± 2.4 ppbv; 主要成分为烷烃 (51.4 %), 烯烃 (18.7 %) 和卤代烃 (18.1 %)。地表 VOC 浓度小于 10 ppbv 时,不同高度 VOCs 的主要来源为机动车尾气和背景贡献。而地表 VOC 浓度超过 10 ppbv 时, 烷烃占比增加, 来源以机动车尾气为主。该研究证实了青藏高原 VOC 在垂直方向上分布均一, 强调了机动车排放作为 VOCs 潜在来源的重要性。
{"title":"Vertical distributions of VOCs in the Tibetan Plateau background region","authors":"Xuanxuan Xue ,&nbsp;Fugeng Zha ,&nbsp;Yinghong Wang ,&nbsp;Yang Zhang ,&nbsp;Yu Wang ,&nbsp;Ying Shen ,&nbsp;Yanyu Kang ,&nbsp;Dan Yao ,&nbsp;Guiqian Tang ,&nbsp;Jianchun Bian ,&nbsp;Yuesi Wang","doi":"10.1016/j.aosl.2024.100516","DOIUrl":"10.1016/j.aosl.2024.100516","url":null,"abstract":"<div><div>Exploring the vertical variation in volatile organic compounds (VOCs) in background regions can provide information on the spatial distribution of pollutants, providing a scientific basis for atmospheric pollution prevention and control strategies. From 15 August to 5 September 2023, at the Southeast Tibet Mountain Comprehensive Environmental Observation Station (SETS), a tethered balloon was used to sample VOCs every 100 m from the ground to 1000 m. A total of 403 air bag samples were collected, and 39 vertical profiles of VOCs were obtained. Ninety-two VOC species were detected. The VOC concentration at the SETS did not change significantly vertically, and the average VOC concentration was 11.1 ± 2.4 ppbv. The main components were alkanes (51.4 %), alkenes (18.7 %), and halohydrocarbons (18.1 %). There was no obvious diurnal change in VOCs and no significant difference between the different layers. When the surface VOC concentration was less than 10 ppbv, the concentrations, components, and sources of VOCs were evenly distributed vertically, and the main sources of VOCs at different heights were vehicle exhaust and background. When the surface VOC concentration exceeded 10 ppbv, the VOC concentration gradually decreased with height. The proportion of alkanes in surface VOCs increased, and the source was mainly vehicle exhaust. This study confirmed that VOCs are vertically homogeneous in the background of the Tibetan Plateau, emphasizing the importance of vehicle emissions as a potential source of VOCs.</div><div>摘要</div><div>研究背景区域挥发性有机物 (VOCs) 的垂直变化规律, 可以提供污染物的空间分布信息, 为制定大气污染防治策略提供科学依据. 2023年夏季, 利用系留气艇对藏东南背景区域VOCs垂直分布规律进行研究, 共获取92种VOC的39条垂直廓线. 结果表明, VOC浓度垂直分布均一, 平均浓度为11.1 ± 2.4 ppbv; 主要成分为烷烃 (51.4 %), 烯烃 (18.7 %) 和卤代烃 (18.1 %). 地表VOC浓度小于10 ppbv时, 不同高度VOCs的主要来源为机动车尾气和背景贡献. 而地表VOC浓度超过10 ppbv时, 烷烃占比增加, 来源以机动车尾气为主. 该研究证实了青藏高原VOC在垂直方向上分布均一, 强调了机动车排放作为VOCs潜在来源的重要性.</div></div>","PeriodicalId":47210,"journal":{"name":"Atmospheric and Oceanic Science Letters","volume":"17 6","pages":"Article 100516"},"PeriodicalIF":2.3,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141028294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Global warming intensifies once-in-a-decade extreme precipitation in summer in China 全球变暖加剧了中国十年一遇的夏季极端降水
IF 2.3 4区 地球科学 Q3 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2024-10-25 DOI: 10.1016/j.aosl.2024.100561
Aoqi Zhou , Chaoxia Yuan
The intensification of extreme precipitation (EP) under global warming presents a substantial risk to human safety and societal progress. Studying the specific impacts of global warming on rare EP events in China not only enhances the comprehension of these shifts, but also paves the way for the development of proactive strategies to alleviate associated damages. Results from large-ensemble simulation data demonstrate that global warming has led to an enhancement in once-in-a-decade EP events in parts of western and central China over the past few decades, with the strengthening of the South Asia high (SAH) caused by global warming playing a dominant role. The strengthening of the SAH corresponds to an intensification and westward extension of the western Pacific subtropical high in the lower troposphere. The region between these two systems experiences enhanced upward motion and increased southwesterly water vapor transport, leading to a rise in climatological precipitation in western and central China, thereby raising the threshold for once-in-a-decade EP events.
摘要
全球变暖下极端降水 (EP) 的加剧对人类安全和社会发展构成了重大威胁. 研究全球变暖对中国罕见极端降水事件的影响, 不仅能加深大家对这些变化的理解, 还为制定应对政策铺平了道路. 大样本模拟数据表明, 在过去几十年中, 全球变暖加剧了中国西部和中部部分地区十年一遇的极端降水事件, 其中因全球变暖而增强的南亚高压 (SAH) 起到了主导作用. SAH的增强与对流层低层西太副高的增强西伸密切相关. 这两个系统间的区域经历了更强的上升运动和增强的西南水汽输送, 导致中国西部和中部的气候态降水增加, 从而提高了十年一遇极端降水事件的阈值.
全球变暖背景下极端降水的加剧给人类安全和社会进步带来了重大威胁。研究全球变暖对中国罕见EP事件的具体影响,不仅可以增强对这些变化的理解,而且可以为制定积极的策略来减轻相关损害铺平道路。大集合模拟结果表明,近几十年来,全球变暖导致中国西部和中部部分地区10年一遇的EP事件增加,其中南亚高压(SAH)的增强起主导作用。南亚高压的增强与对流层下层西太平洋副热带高压的增强和向西扩展相对应。这两个系统之间的区域向上运动增强,西南水汽输送增加,导致中国西部和中部气候降水增加,从而提高了十年一遇的EP事件的阈值。中文意思是:“我的意思是,我的意思是,我的意思是,我的意思是,我的意思是。”研究全球变暖对中国罕见极端降水事件的影响, 不仅能加深大家对这些变化的理解, 还为制定应对政策铺平了道路. 大样本模拟数据表明,在过去几十年中,全球变暖加剧了中国西部和中部部分地区十年一遇的极端降水事件,其中因全球变暖而增强的南亚高压(SAH)起到了主导作用。这句话的意思是:“我的意思是,我的意思是。”这两个系统间的区域经历了更强的上升运动和增强的西南水汽输送, 导致中国西部和中部的气候态降水增加, 从而提高了十年一遇极端降水事件的阈值.
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引用次数: 0
Evaluating vector winds over eastern China in 2022 predicted by the CMA-MESO model and ECMWF forecast CMA-MESO模式和ECMWF预测的2022年中国东部矢量风的评价
IF 2.3 4区 地球科学 Q3 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2024-10-24 DOI: 10.1016/j.aosl.2024.100559
Fang Huang , Mingjian Zeng , Zhongfeng Xu , Boni Wang , Ming Sun , Hangcheng Ge , Shoukang Wu
Vector winds play a crucial role in weather and climate, as well as the effective utilization of wind energy resources. However, limited research has been conducted on treating the wind field as a vector field in the evaluation of numerical weather prediction models. In this study, the authors treat vector winds as a whole by employing a vector field evaluation method, and evaluate the mesoscale model of the China Meteorological Administration (CMA-MESO) and ECMWF forecast, with reference to ERA5 reanalysis, in terms of multiple aspects of vector winds over eastern China in 2022. The results show that the ECMWF forecast is superior to CMA-MESO in predicting the spatial distribution and intensity of 10-m vector winds. Both models overestimate the wind speed in East China, and CMA-MESO overestimates the wind speed to a greater extent. The forecasting skill of the vector wind field in both models decreases with increasing lead time. The forecasting skill of CMA-MESO fluctuates more and decreases faster than that of the ECMWF forecast. There is a significant negative correlation between the model vector wind forecasting skill and terrain height. This study provides a scientific evaluation of the local application of vector wind forecasts of the CMA-MESO model and ECMWF forecast.
摘要
本文利用矢量场评估VFE方法, 从矢量场角度系统性评估CMA-MESO模式与ECMWF模式对2022年华东地区10 m高度矢量风场的预报技巧. 结果表明, ECMWF模式对矢量风场空间分布与风场强度的预报均优于CMA-MESO模式. CMA-MESO模式明显高估了矢量风场的强度. 模式预报技巧随着预报时效的延长而下降, 其中以CMA-MESO模式的预报技巧波动更大, 衰减更迅速. 本研究将为CMA-MESO模式与ECMWF模式风场预报产品的本地化应用, 提供一个科学的评估依据.
矢量风在天气和气候中起着至关重要的作用,也是风能资源的有效利用。然而,将风场作为矢量场来评价数值天气预报模式的研究却很少。本研究采用矢量场评价方法,将矢量风作为一个整体,结合ERA5再分析,对中国气象局(CMA-MESO)中尺度模式和ECMWF预报的2022年中国东部矢量风的多个方面进行了评价。结果表明,ECMWF预报在10 m矢量风的空间分布和强度预测上优于CMA-MESO预报。两种模式均高估了华东地区的风速,CMA-MESO高估的程度更大。两种模式对矢量风场的预测能力均随提前时间的增加而降低。CMA-MESO预报能力比ECMWF预报能力波动大,下降快。模式矢量风预报技能与地形高度呈显著负相关。本研究对CMA-MESO模式和ECMWF预报的矢量风预报在局部应用进行了科学评价。摘要本文利用矢量场评估VFE方法,从矢量场角度系统性评估CMA-MESO模式与ECMWF模式对2022年华东地区10米高度矢量风场的预报技巧。“”“”“”“”“”“”“”“”“”“”“”这是一个很好的例子。模式预报技巧随着预报时效的延长而下降,其中以CMA-MESO模式的预报技巧波动更大,衰减更迅速。“”“”“”“”“”“”“”
{"title":"Evaluating vector winds over eastern China in 2022 predicted by the CMA-MESO model and ECMWF forecast","authors":"Fang Huang ,&nbsp;Mingjian Zeng ,&nbsp;Zhongfeng Xu ,&nbsp;Boni Wang ,&nbsp;Ming Sun ,&nbsp;Hangcheng Ge ,&nbsp;Shoukang Wu","doi":"10.1016/j.aosl.2024.100559","DOIUrl":"10.1016/j.aosl.2024.100559","url":null,"abstract":"<div><div>Vector winds play a crucial role in weather and climate, as well as the effective utilization of wind energy resources. However, limited research has been conducted on treating the wind field as a vector field in the evaluation of numerical weather prediction models. In this study, the authors treat vector winds as a whole by employing a vector field evaluation method, and evaluate the mesoscale model of the China Meteorological Administration (CMA-MESO) and ECMWF forecast, with reference to ERA5 reanalysis, in terms of multiple aspects of vector winds over eastern China in 2022. The results show that the ECMWF forecast is superior to CMA-MESO in predicting the spatial distribution and intensity of 10-m vector winds. Both models overestimate the wind speed in East China, and CMA-MESO overestimates the wind speed to a greater extent. The forecasting skill of the vector wind field in both models decreases with increasing lead time. The forecasting skill of CMA-MESO fluctuates more and decreases faster than that of the ECMWF forecast. There is a significant negative correlation between the model vector wind forecasting skill and terrain height. This study provides a scientific evaluation of the local application of vector wind forecasts of the CMA-MESO model and ECMWF forecast.</div><div>摘要</div><div>本文利用矢量场评估VFE方法, 从矢量场角度系统性评估CMA-MESO模式与ECMWF模式对2022年华东地区10 m高度矢量风场的预报技巧. 结果表明, ECMWF模式对矢量风场空间分布与风场强度的预报均优于CMA-MESO模式. CMA-MESO模式明显高估了矢量风场的强度. 模式预报技巧随着预报时效的延长而下降, 其中以CMA-MESO模式的预报技巧波动更大, 衰减更迅速. 本研究将为CMA-MESO模式与ECMWF模式风场预报产品的本地化应用, 提供一个科学的评估依据.</div></div>","PeriodicalId":47210,"journal":{"name":"Atmospheric and Oceanic Science Letters","volume":"18 4","pages":"Article 100559"},"PeriodicalIF":2.3,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144169722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fluctuations in the relationship between the Silk Road Pattern and the summer North Atlantic Oscillation 丝绸之路格局与夏季北大西洋涛动的波动关系
IF 2.3 4区 地球科学 Q3 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2024-10-23 DOI: 10.1016/j.aosl.2024.100558
Yong Liu , Zhencai Du
This study investigated the fluctuations in the relationship between the Silk Road Pattern (SRP) and the boreal summer North Atlantic Oscillation (SNAO). The results indicated that the SRP–SNAO relationship was relatively weak during 1958–2022, which was primarily due to fluctuations, particularly the reversal in their relationship since the late 1990s. Using wavelet coherence analysis, the authors identified a strong SRP–SNAO linkage on a 4–8-yr timescale, in particular during the mid-1970s to the early/mid-1990s. This strong linkage is mainly attributable to the intensification and eastward movement of the southern part of the SNAO around the mid/late 1970s, which favored the strong connection between the SNAO and the SRP. Additionally, the interdecadal changes of the atmospheric circulations over the North Atlantic and Eurasia around the mid/late 1970s that resembled the circulation anomalies related to the strong SRP–SNAO linkage, may also have provided a favorable background for the strong connection between the two teleconnections. These findings on the fluctuations in the SRP–SNAO linkage may offer important implications for understanding the impact of the SNAO on the SRP and the variability of the SRP.
摘要
本文利用近60年大气再分析数据, 研究了丝绸之路型遥相关 (Silk Road Pattern, SRP) 与夏季北大西洋涛动 (North Atlantic Oscillation, SNAO) 关系的不稳定性及其可能成因. 结果表明, 近60年来, SRP与SNAO的关系具有明显的不稳定性. 两者关系在1970s中期至1990s中期显著增强, 特别在4-8年时间尺度上. 两者关系的增强主要与1970s中后期以来SNAO南部中心增强, 位置东移有关. 同时, 北大西洋和欧亚区域夏季大气环流在1970s末的年代际异常也为两者之间关系的增强提供了有利的气候背景.
研究了丝绸之路模式(SRP)与北半球夏季北大西洋涛动(SNAO)之间的波动关系。结果表明,1958-2022年期间SRP-SNAO关系相对较弱,这主要是由于波动,特别是20世纪90年代末以来两者关系的逆转。利用小波相干性分析,作者发现在4 - 8年的时间尺度上,特别是在20世纪70年代中期至20世纪90年代初/中期,存在很强的SRP-SNAO联系。这种强联系主要是由于70年代中后期前后SNAO南部的强化和东移,有利于SNAO与SRP之间的强联系。此外,20世纪70年代中后期北大西洋和欧亚大陆大气环流的年代际变化类似于与SRP-SNAO强联系相关的环流异常,也可能为这两个遥相关之间的强联系提供了有利的背景。这些关于SRP - SNAO联系波动的发现可能为理解SNAO对SRP的影响和SRP的变异性提供重要启示。摘要本文利用近60年大气再分析数据,研究了丝绸之路型遥相关(丝绸之路模式,SRP)与夏季北大西洋涛动(北大西洋振荡,SNAO)关系的不稳定性及其可能成因。【中文翻译】:【中文翻译】4-8个英文单词【中文译文】同时,北大西洋和欧亚区域夏季大气环流在1970年代末的年代际异常也为两者之间关系的增强提供了有利的气候背景。
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Atmospheric and Oceanic Science Letters
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