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Microelectrothermoforming (μETF): one-step versatile 3D shaping of flexible microelectronics for enhanced neural interfaces 微电热成形(μETF):用于增强神经接口的柔性微电子一步通用3D成形
IF 14.6 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-01-22 DOI: 10.1038/s41528-024-00378-0
Dong Hyeon Lee, Younghoon Park, Yoon Seo, Hannah Noh, Hyunbeen Jeong, Jongmo Seo, Min-Ho Seo, Kyungsik Eom, Joonsoo Jeong

Increasing the proximity of microelectrode arrays (MEA) to targeted neural tissues can establish efficient neural interfaces for both recording and stimulation applications. This has been achieved by constructing protruding three-dimensional (3D) structures on top of conventional planar microelectrodes via additional micromachining steps. However, this approach adds fabrication complexities and limits the 3D structures to certain shapes. We propose a one-step fabrication of MEAs with versatile microscopic 3D structures via “microelectrothermoforming (μETF)” of thermoplastics, by utilizing 3D-printed molds to locally deform planar MEAs into protruding and recessing shapes. Electromechanical optimization enabled a 3D MEA with 80 μm protrusions and/or recession for 100 μm diameter. Its simple and versatile shaping capabilities are demonstrated by diverse 3D structures on a single MEA. The benefits of 3D MEA are evaluated in retinal stimulation through numerical simulations and ex vivo experiments, confirming a threshold lowered by 1.7 times and spatial resolution enhanced by 2.2 times.

增加微电极阵列(MEA)与目标神经组织的接近度可以为记录和刺激应用建立有效的神经接口。这是通过在传统的平面微电极上通过额外的微加工步骤构建突出的三维(3D)结构来实现的。然而,这种方法增加了制造的复杂性,并将3D结构限制在某些形状。我们提出了一种通过热塑性塑料的“微电热成形(μETF)”一步制造具有多种微观三维结构的mea,利用3D打印模具将平面mea局部变形成突出和凹陷的形状。机电优化使3D MEA具有80 μm的凸起和/或100 μm直径的凹陷。其简单和通用的塑造能力是由不同的3D结构在一个单一的MEA证明。通过数值模拟和离体实验评估了3D MEA在视网膜刺激中的优势,确认阈值降低了1.7倍,空间分辨率提高了2.2倍。
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引用次数: 0
Electro-spun nanofibers-based triboelectric nanogenerators in wearable electronics: status and perspectives 可穿戴电子设备中基于电纺纳米纤维的三电纳米发电机:现状与前景
IF 14.6 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-01-16 DOI: 10.1038/s41528-024-00357-5
Deyin Tao, Ping Su, Aiping Chen, Dawei Gu, Mustafa Eginligil, Wei Huang

Electro-Spun nanofibers (ESNs), with their design flexibility, tailorable morphologies, and high surface area, are well-favored as triboelectric nanogenerator (TENG) materials for wearable electronics. Here, various aspects of ESNs-based wearable TENGs were examined. After introducing the most common TENG operating modes, an insightful overview of wearable TENG applications based on ESNs was presented. In this survey, a special attention is paid to wearable sensing, human-machine interaction, self-powered devices, and amplified energy harvesting. Efforts towards improving energy conversion efficiency, material durability, and compatibility with diverse wearable platforms were visited. Finally, a perspective based on particularly material aspect of ESNs is given, which could be insightful in tackling prevailing challenges and giving birth to new directions.

电纺纳米纤维(ESNs)具有设计灵活、形态可定制和表面积高等特点,是可穿戴电子设备的三电纳米发电机(TENG)材料。在此,我们对基于 ESNs 的可穿戴 TENG 的各个方面进行了研究。在介绍了最常见的 TENG 工作模式之后,对基于 ESNs 的可穿戴 TENG 应用进行了深入概述。在这项调查中,特别关注了可穿戴传感、人机交互、自供电设备和放大能量采集。此外,还考察了为提高能量转换效率、材料耐用性以及与各种可穿戴平台的兼容性所做的努力。最后,还特别从 ESN 的材料方面提出了一个视角,这对解决当前的挑战和开辟新的方向具有重要意义。
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引用次数: 0
An ultra-low power wake-Up timer compatible with n-FET based flexible technologies 超低功耗唤醒定时器兼容基于n-FET的灵活技术
IF 14.6 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-01-12 DOI: 10.1038/s41528-024-00374-4
D. Narbón, J. L. Soler-Fernández, A. Santos, P. Barquinha, R. Martins, A. Diéguez, J. D. Prades, O. Alonso

Flexible integrated circuits (FlexICs) have drawn increasing attention, particularly in remote sensors and wearables operating in a limited power budget. Here, we present an ultra-low power timer designed to wake-up an external circuit periodically, from a deep-sleep state into an active state, thereby largely reducing the system power consumption. We achieved this with a circuit topology that exploits the transistor’s leakage current to generate a low frequency wake-up signal. This topology is compatible with IC technologies where only n-type transistors are available. The design was implemented with the sustainable FlexIC process of PragmatIC, that is based on Indium Gallium Zinc Oxide (IGZO) thin-film transistors. Our timer generates mean wake-up frequency of 0.24 ± 0.15 Hz, with a mean power consumption of 26.7 ± 14.1 nW. In this paper, we provide details of the Wake-Up timer’s design and performance at different supply voltages, under temperature variations and different light conditions.

柔性集成电路(flexic)已经引起了越来越多的关注,特别是在远程传感器和可穿戴设备中,在有限的功率预算下运行。在这里,我们提出了一个超低功耗定时器,旨在周期性地唤醒外部电路,从深度睡眠状态进入活动状态,从而大大降低了系统功耗。我们通过利用晶体管的漏电流产生低频唤醒信号的电路拓扑实现了这一点。这种拓扑结构兼容仅使用n型晶体管的IC技术。该设计采用了PragmatIC公司基于铟镓锌氧化物(IGZO)薄膜晶体管的可持续FlexIC工艺。我们的计时器平均唤醒频率为0.24±0.15 Hz,平均功耗为26.7±14.1 nW。在本文中,我们详细介绍了唤醒定时器在不同电源电压、温度变化和不同光照条件下的设计和性能。
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引用次数: 0
Operando spin observation elucidating performance-improvement mechanisms during operation of Ruddlesden–Popper Sn-based perovskite solar cells Operando自旋观测阐明了Ruddlesden-Popper锡基钙钛矿太阳能电池运行过程中性能改善机制
IF 14.6 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-01-09 DOI: 10.1038/s41528-024-00376-2
Yizhou Chen, Seira Yamaguchi, Atsushi Sato, Dong Xue, Kazuhiro Marumoto

Sn-based perovskite solar cells (PSCs) have attracted attention because of their low environmental impact. Unfortunately, the readily occurring oxidation of Sn2+ inhibits further improvement of their efficiency and stability. Ruddlesden–Popper (RP) Sn-based perovskites are considered promising candidates as absorbers that improve the performance and stability of Sn-based PSCs. However, microscopic understanding of performance-enhancing mechanisms remains insufficient. For this study, electron spin resonance (ESR) spectroscopy measurements were taken of RP Sn-based PSCs with poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) hole-transport layers and (BA0.5PEA0.5)2FA3Sn4I13 perovskite layers to clarify the space-charge region formation mechanism at the PEDOT:PSS/(BA0.5PEA0.5)2FA3Sn4I13 interface. These results indicated electron-barrier formation in the (BA0.5PEA0.5)2FA3Sn4I13 layer near the PEDOT:PSS layer. Moreover, the electron barrier was found to be enhanced during device operation. The enhanced interface band bending reduces interface recombination and thereby improves the device's performance. These findings might provide important progress in practical applications of PSCs and might advance the realization of a carbon-neutral society.

锡基钙钛矿太阳能电池(PSCs)因其低环境影响而备受关注。不幸的是,容易发生的Sn2+氧化抑制了它们效率和稳定性的进一步提高。Ruddlesden-Popper (RP) sn基钙钛矿被认为是有前途的吸收剂,可以提高sn基psc的性能和稳定性。然而,对性能增强机制的微观理解仍然不足。在本研究中,采用电子自旋共振(ESR)光谱测量了具有聚(3,4-乙烯二氧噻吩):聚(苯乙烯磺酸盐)(PEDOT:PSS)空穴传输层和(BA0.5PEA0.5)2FA3Sn4I13钙钛矿层的RP sn基PSCs,以阐明PEDOT:PSS/(BA0.5PEA0.5)2FA3Sn4I13界面的空间电荷区形成机制。这些结果表明在PEDOT:PSS层附近的(BA0.5PEA0.5)2FA3Sn4I13层中形成了电子势垒。此外,在器件运行过程中发现电子势垒增强。增强的接口带弯曲减少了接口的复合,从而提高了器件的性能。这些发现可能为psc的实际应用提供重要进展,并可能推动碳中和社会的实现。
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引用次数: 0
Giant elasto-optic response of gallium selenide on flexible mica 硒化镓在柔性云母上的巨弹光响应
IF 14.6 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-01-04 DOI: 10.1038/s41528-024-00375-3
T. Barker, A. Gray, M. P. Weir, J. S. Sharp, A. Kenton, Z. R. Kudrynskyi, H. Rostami, A. Patané

Understanding the bending behaviour of a crystal onto a flexible platform is crucial for flexible electronics. The Young’s modulus, a measure of how easily a material deforms, plays a critical role in the coupled deformation of a crystal on a flexible substrate, as well as the transfer of strain from the substrate onto the layer. Here, we report on the bending behaviour of gallium selenide (GaSe), a van der Waals semiconductor with a small Young’s modulus and strain-dependent electronic band structure. A controllable, reproducible uniaxial strain, ϵ, is applied to nanometer-thick GaSe layers via their bending on a mica substrate. The spectral shift ΔE of the room temperature photoluminescence emission corresponds to a strain coefficient ΔE/ϵ of up to ~100 eV, the largest value reported in the literature to date. This is accompanied by coupled electronic and vibrational states under strain-induced resonant excitation conditions, as probed by Raman spectroscopy.

了解晶体在柔性平台上的弯曲行为对柔性电子产品至关重要。杨氏模量是衡量材料变形难易程度的一种方法,它在柔性衬底上晶体的耦合变形以及从衬底到层的应变传递中起着关键作用。在这里,我们报告了硒化镓(GaSe)的弯曲行为,这是一种具有小杨氏模量和应变依赖电子能带结构的范德瓦尔斯半导体。通过在云母衬底上的弯曲,将可控的、可重复的单轴应变λ应用于纳米厚的GaSe层。室温光致发光发射的光谱位移ΔE对应的应变系数ΔE/ λ高达~100 eV,这是迄今为止文献中报道的最大值。这是伴随着耦合的电子和振动状态,在应变诱导的共振激励条件下,通过拉曼光谱探测。
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引用次数: 0
Flexible, multimodal device for measurement of body temperature, core temperature, thermal conductivity and water content 用于测量体温、核心温度、导热系数和含水量的灵活的多模态装置
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-12-19 DOI: 10.1038/s41528-024-00373-5
Yanbo Du, Chuanli Zhou, Yanhui Feng, Lin Qiu
Body core temperature is an important physiological indicator for self-health management and medical diagnosis. However, existing devices always fails to achieve continuous monitoring of core body temperature due to their invasive or motion-restricted measurement principles. Here, a wearable flexible device which can continuously monitor the core body temperature was developed. The flexible device integrated with fourteen temperature sensors and one thermal conductivity sensor on the polydimethylsiloxane substrate can be conformally attached to the human skin. With the wearable data processing module and wireless communication module, the continuous monitoring of the core body temperature for 24 h and the portable monitoring of the skin thermal conductivity were realized using this device. Owing to the annular distribution design of the temperature sensor and the directional heat transfer design of the thermal conductivity sensor, this device is comparable in accuracy and stability compared to standard instruments that require invasive or motion-restricted measurements.
核心体温是自我健康管理和医学诊断的重要生理指标。然而,现有设备由于其侵入性或运动受限的测量原理,往往无法实现对核心体温的连续监测。本课题研制了一种可连续监测人体核心体温的可穿戴柔性装置。在聚二甲基硅氧烷衬底上集成了14个温度传感器和一个导热传感器的柔性装置可以保形地附着在人体皮肤上。通过可穿戴数据处理模块和无线通信模块,实现了24小时核心体温的连续监测和皮肤导热系数的便携式监测。由于温度传感器的环形分布设计和导热传感器的定向传热设计,与需要侵入性或运动受限测量的标准仪器相比,该设备在精度和稳定性方面具有可比性。
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引用次数: 0
Self-defined dual charge percolation networks for solution-processed multithreshold transistors 溶液处理多阈值晶体管的自定义双电荷渗透网络
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-12-19 DOI: 10.1038/s41528-024-00372-6
Jung Woo Moon, Seunghan Kim, Jin Hyeon Kim, Sunil V. Barma, Sang Young Jeong, Jinho Keum, Ho Sun Lim, Youngjae Yoo, Han Young Woo, Sae Byeok Jo, Moon Sung Kang, Jeong Ho Cho
This study demonstrates multithreshold engineering of a solution-processed heterojunction electrochemical transistor using a blend of n-type CdSe tetrapod-shaped nanocrystals (TpNCs) and an n-type polymeric organic semiconductor (OSC). The unique geometry of TpNCs enables a broad concentration range of charge percolation, where charge transfer between TpNC and OSC domains determines multiple threshold voltages. The OSC domain’s threshold voltage shifts from 1 to −1 V as TpNC content increases, while the TpNC domain maintains a threshold above 1.5 V. This allows for stable intermediate states, crucial for multivalued logic operations. Charge percolation and photoluminescence studies show selective charge redistribution, shifting the threshold voltages in the polymer networks. Ternary logic gates, including TNOT, TNAND, and TNOR, based on these heterojunction transistors, were also demonstrated, highlighting the potential of this approach for advanced logic applications.
本研究展示了利用n型CdSe四足形纳米晶体(tpnc)和n型聚合物有机半导体(OSC)的混合物进行溶液处理异质结电化学晶体管的多阈值工程。TpNC独特的几何形状使得电荷渗透的浓度范围很宽,TpNC和OSC域之间的电荷转移决定了多个阈值电压。随着TpNC含量的增加,OSC域的阈值电压从1 V移动到−1 V,而TpNC域的阈值保持在1.5 V以上。这允许稳定的中间状态,这对于多值逻辑操作至关重要。电荷渗透和光致发光研究表明,选择性电荷重新分配,改变了聚合物网络中的阈值电压。基于这些异质结晶体管的三元逻辑门,包括TNOT、TNAND和TNOR,也被展示出来,突出了这种方法在高级逻辑应用中的潜力。
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引用次数: 0
Revolutionizing wearable technology: advanced fabrication techniques for body-conformable electronics 革命性的可穿戴技术:适合人体的电子产品的先进制造技术
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-12-04 DOI: 10.1038/s41528-024-00370-8
Ruilai Wei, Haotian Li, Zhongming Chen, Qilin Hua, Guozhen Shen, Kai Jiang
With the increasing demand for wearable electronic products, there is a pressing need to develop electronic devices that seamlessly conform to the contours of the human body while delivering excellent performance and reliability. Traditional rigid electronic fabrication technologies fall short of meeting these requirements, necessitating the exploration of advanced flexible fabrication technologies that offer new possibilities for designing and fabricating flexible and stretchable electronic products, particularly in wearable devices. Over time, the continuous development of innovative fabrication techniques has ushered in significant improvements in the design freedom, lightweight, seamless integration, and multifunctionality of wearable electronics. Here, we provide a comprehensive overview of the advancements facilitated by advanced fabrication technology in wearable electronics. It specifically focuses on key fabrication methods, including printed electronics fabrication, soft transfer, 3D structure fabrication, and deformation fabrication. By highlighting these advancements, it sheds light on the challenges and prospects for further development in wearable electronics fabrication technologies. The introduction of advanced fabrication technologies has revolutionized the landscape of wearable/conformable electronics, expanding their application domains, streamlining system complexity associated with customization, manufacturing, and production, and opening up new avenues for innovation and development of body-conformable electronics.
随着人们对可穿戴电子产品的需求不断增加,迫切需要开发出无缝符合人体轮廓的电子设备,同时提供卓越的性能和可靠性。传统的刚性电子制造技术无法满足这些要求,因此有必要探索先进的柔性制造技术,为设计和制造柔性和可拉伸电子产品提供新的可能性,特别是在可穿戴设备中。随着时间的推移,创新制造技术的不断发展,在可穿戴电子产品的设计自由度、轻量化、无缝集成和多功能方面取得了重大进展。在这里,我们全面概述了先进制造技术在可穿戴电子产品中的应用。它特别侧重于关键的制造方法,包括印刷电子制造,软转移,3D结构制造和变形制造。通过强调这些进步,它揭示了可穿戴电子制造技术进一步发展的挑战和前景。先进制造技术的引入彻底改变了可穿戴/可穿戴电子产品的格局,扩展了它们的应用领域,简化了与定制、制造和生产相关的系统复杂性,并为可穿戴电子产品的创新和发展开辟了新的途径。
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引用次数: 0
Ag@polydopamine-functionalized borate ester-linked chitosan hydrogel integrates monitoring with wound healing for epidermal sensor Ag@polydopamine-functionalized硼酸酯连接壳聚糖水凝胶集成监测伤口愈合表皮传感器
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-30 DOI: 10.1038/s41528-024-00366-4
Wei Shi, Hui Li, Chengsheng Xu, Gaoyi Wu, Jing Chen, Jinyong Zhang, Lixin Liang, Qingyang Wu, Yongsheng Liang, Guanglin Li, Wei Tang
Flexible sensors are promising candidates in personalized healthcare, while desired sensors that allow implantation for biomedical applications with optimal sensing and favorable biological properties remain challenges. Here, a multifunctional hydrogel sensor was developed with gallic acid-modified chitosan (CSGA) and 3-carboxyphenylboronic acid-modified chitosan (CSPBA) by encapsulating Ag-decorated polydopamine (Ag@PDA) nanoparticles, namely Ag@PDA-(CSPBA/CSGA). The optimized hydrogel sensor showed desired sensitivity (gauge factor = 2.49), a rapid response/recovery time of 263 ms and good durability. Due to the presence of abundant reactive groups within Ag@PDA-(CSPBA/CSGA), the hydrogel sensor exhibited a comprehensive performance of self-healing, tissue adhesiveness, antioxidative activity, and antibacterial effects against Escherichia coli (92.76%) and Staphylococcus aureus (98.08%). Moreover, the hydrogel sensor could be utilized as a wound dressing, facilitating accelerated wound closure and tissue regeneration. Both subtle activities and large-scale movements could be monitored and distinguished by the hydrogel sensor. This study provides a promising epidermal sensor that offers multifunctionality for health monitoring and wound management.
柔性传感器是个性化医疗保健中很有前途的候选者,而允许植入具有最佳传感和有利生物特性的生物医学应用的传感器仍然是挑战。本文以没食子酸修饰壳聚糖(CSGA)和3-羧基苯基硼酸修饰壳聚糖(CSPBA)为材料,包封ag修饰的聚多巴胺(Ag@PDA)纳米粒子Ag@PDA-(CSPBA/CSGA),制备了多功能水凝胶传感器。优化后的水凝胶传感器具有理想的灵敏度(测量因子= 2.49)、263 ms的快速响应/恢复时间和良好的耐用性。由于Ag@PDA-(CSPBA/CSGA)中存在丰富的反应基团,该水凝胶传感器对大肠杆菌(92.76%)和金黄色葡萄球菌(98.08%)具有自愈、组织粘附、抗氧化和抗菌等综合性能。此外,水凝胶传感器可以用作伤口敷料,促进伤口愈合和组织再生。水凝胶传感器可以监测和区分细微的活动和大规模的运动。该研究提供了一种具有多种功能的表皮传感器,可用于健康监测和伤口管理。
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引用次数: 0
Stretchable nanogenerator with micro-nano hierarchical interfaces for self-powered biometric authentication 具有微纳分层界面的可伸缩纳米发电机,用于自供电生物识别身份验证
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-26 DOI: 10.1038/s41528-024-00367-3
Hai-Tao Deng, Yi-Xuan Xia, Yu-Chi Liu, Beomjoon Kim, Xiao-Sheng Zhang
Multifunctional integration and heterogeneous surface integration are two crucial challenges in the in-depth use and development of triboelectric nanogenerators (TENGs) in the wearable electronic field. A promising solution is to develop stretchable TENGs (STENG), which have the potential for microenergy supply and self-powered sensing. The key challenge is to endow its functional components with good deformability and realize heterogeneous surface integration. Herein, we proposed a fully stretchable, surface adaptable TENG using stretchable micro-nano hierarchical friction interfaces. It integrated microenenrgy supply and multifunctional self-powered sensing (i.e., bend, force, and frequency sensing) abilities successfully. The highly-linear sensing abilities endows the STENG with a good biometric ability. As an application, a STENG array based-stretchable wearable keyboard was proposed. It identified dynamic keystroke motions of all users with a Support Vector Machine, with a high accuracy of 93.21%. Besides, the intruders who were not sampled were distinguished from users, with an accuracy of 81.50%.
多功能集成和异质表面集成是三电纳米发电机(TENGs)在可穿戴电子领域深入应用和发展的两大关键挑战。一个有前景的解决方案是开发可拉伸的 TENG(STENG),它具有微能量供应和自供电传感的潜力。关键的挑战在于赋予其功能部件良好的变形能力,并实现异质表面集成。在此,我们利用可拉伸的微纳分层摩擦界面,提出了一种完全可拉伸、表面可适应的 TENG。它成功集成了微能源供应和多功能自供电传感(即弯曲、力和频率传感)能力。高线性传感能力赋予 STENG 良好的生物识别能力。作为一种应用,提出了一种基于 STENG 阵列的可伸缩可穿戴键盘。它利用支持向量机识别了所有用户的动态按键动作,准确率高达 93.21%。此外,还将未被采样的入侵者与用户区分开来,准确率为 81.50%。
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引用次数: 0
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npj Flexible Electronics
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