Pub Date : 2025-01-22DOI: 10.1038/s41528-024-00378-0
Dong Hyeon Lee, Younghoon Park, Yoon Seo, Hannah Noh, Hyunbeen Jeong, Jongmo Seo, Min-Ho Seo, Kyungsik Eom, Joonsoo Jeong
Increasing the proximity of microelectrode arrays (MEA) to targeted neural tissues can establish efficient neural interfaces for both recording and stimulation applications. This has been achieved by constructing protruding three-dimensional (3D) structures on top of conventional planar microelectrodes via additional micromachining steps. However, this approach adds fabrication complexities and limits the 3D structures to certain shapes. We propose a one-step fabrication of MEAs with versatile microscopic 3D structures via “microelectrothermoforming (μETF)” of thermoplastics, by utilizing 3D-printed molds to locally deform planar MEAs into protruding and recessing shapes. Electromechanical optimization enabled a 3D MEA with 80 μm protrusions and/or recession for 100 μm diameter. Its simple and versatile shaping capabilities are demonstrated by diverse 3D structures on a single MEA. The benefits of 3D MEA are evaluated in retinal stimulation through numerical simulations and ex vivo experiments, confirming a threshold lowered by 1.7 times and spatial resolution enhanced by 2.2 times.
{"title":"Microelectrothermoforming (μETF): one-step versatile 3D shaping of flexible microelectronics for enhanced neural interfaces","authors":"Dong Hyeon Lee, Younghoon Park, Yoon Seo, Hannah Noh, Hyunbeen Jeong, Jongmo Seo, Min-Ho Seo, Kyungsik Eom, Joonsoo Jeong","doi":"10.1038/s41528-024-00378-0","DOIUrl":"https://doi.org/10.1038/s41528-024-00378-0","url":null,"abstract":"<p>Increasing the proximity of microelectrode arrays (MEA) to targeted neural tissues can establish efficient neural interfaces for both recording and stimulation applications. This has been achieved by constructing protruding three-dimensional (3D) structures on top of conventional planar microelectrodes via additional micromachining steps. However, this approach adds fabrication complexities and limits the 3D structures to certain shapes. We propose a one-step fabrication of MEAs with versatile microscopic 3D structures via “microelectrothermoforming (μETF)” of thermoplastics, by utilizing 3D-printed molds to locally deform planar MEAs into protruding and recessing shapes. Electromechanical optimization enabled a 3D MEA with 80 μm protrusions and/or recession for 100 μm diameter. Its simple and versatile shaping capabilities are demonstrated by diverse 3D structures on a single MEA. The benefits of 3D MEA are evaluated in retinal stimulation through numerical simulations and ex vivo experiments, confirming a threshold lowered by 1.7 times and spatial resolution enhanced by 2.2 times.</p>","PeriodicalId":48528,"journal":{"name":"npj Flexible Electronics","volume":"103 1","pages":""},"PeriodicalIF":14.6,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142992330","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-16DOI: 10.1038/s41528-024-00357-5
Deyin Tao, Ping Su, Aiping Chen, Dawei Gu, Mustafa Eginligil, Wei Huang
Electro-Spun nanofibers (ESNs), with their design flexibility, tailorable morphologies, and high surface area, are well-favored as triboelectric nanogenerator (TENG) materials for wearable electronics. Here, various aspects of ESNs-based wearable TENGs were examined. After introducing the most common TENG operating modes, an insightful overview of wearable TENG applications based on ESNs was presented. In this survey, a special attention is paid to wearable sensing, human-machine interaction, self-powered devices, and amplified energy harvesting. Efforts towards improving energy conversion efficiency, material durability, and compatibility with diverse wearable platforms were visited. Finally, a perspective based on particularly material aspect of ESNs is given, which could be insightful in tackling prevailing challenges and giving birth to new directions.
电纺纳米纤维(ESNs)具有设计灵活、形态可定制和表面积高等特点,是可穿戴电子设备的三电纳米发电机(TENG)材料。在此,我们对基于 ESNs 的可穿戴 TENG 的各个方面进行了研究。在介绍了最常见的 TENG 工作模式之后,对基于 ESNs 的可穿戴 TENG 应用进行了深入概述。在这项调查中,特别关注了可穿戴传感、人机交互、自供电设备和放大能量采集。此外,还考察了为提高能量转换效率、材料耐用性以及与各种可穿戴平台的兼容性所做的努力。最后,还特别从 ESN 的材料方面提出了一个视角,这对解决当前的挑战和开辟新的方向具有重要意义。
{"title":"Electro-spun nanofibers-based triboelectric nanogenerators in wearable electronics: status and perspectives","authors":"Deyin Tao, Ping Su, Aiping Chen, Dawei Gu, Mustafa Eginligil, Wei Huang","doi":"10.1038/s41528-024-00357-5","DOIUrl":"https://doi.org/10.1038/s41528-024-00357-5","url":null,"abstract":"<p>Electro-Spun nanofibers (ESNs), with their design flexibility, tailorable morphologies, and high surface area, are well-favored as triboelectric nanogenerator (TENG) materials for wearable electronics. Here, various aspects of ESNs-based wearable TENGs were examined. After introducing the most common TENG operating modes, an insightful overview of wearable TENG applications based on ESNs was presented. In this survey, a special attention is paid to wearable sensing, human-machine interaction, self-powered devices, and amplified energy harvesting. Efforts towards improving energy conversion efficiency, material durability, and compatibility with diverse wearable platforms were visited. Finally, a perspective based on particularly material aspect of ESNs is given, which could be insightful in tackling prevailing challenges and giving birth to new directions.</p>","PeriodicalId":48528,"journal":{"name":"npj Flexible Electronics","volume":"29 1","pages":""},"PeriodicalIF":14.6,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142986511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-12DOI: 10.1038/s41528-024-00374-4
D. Narbón, J. L. Soler-Fernández, A. Santos, P. Barquinha, R. Martins, A. Diéguez, J. D. Prades, O. Alonso
Flexible integrated circuits (FlexICs) have drawn increasing attention, particularly in remote sensors and wearables operating in a limited power budget. Here, we present an ultra-low power timer designed to wake-up an external circuit periodically, from a deep-sleep state into an active state, thereby largely reducing the system power consumption. We achieved this with a circuit topology that exploits the transistor’s leakage current to generate a low frequency wake-up signal. This topology is compatible with IC technologies where only n-type transistors are available. The design was implemented with the sustainable FlexIC process of PragmatIC, that is based on Indium Gallium Zinc Oxide (IGZO) thin-film transistors. Our timer generates mean wake-up frequency of 0.24 ± 0.15 Hz, with a mean power consumption of 26.7 ± 14.1 nW. In this paper, we provide details of the Wake-Up timer’s design and performance at different supply voltages, under temperature variations and different light conditions.
{"title":"An ultra-low power wake-Up timer compatible with n-FET based flexible technologies","authors":"D. Narbón, J. L. Soler-Fernández, A. Santos, P. Barquinha, R. Martins, A. Diéguez, J. D. Prades, O. Alonso","doi":"10.1038/s41528-024-00374-4","DOIUrl":"https://doi.org/10.1038/s41528-024-00374-4","url":null,"abstract":"<p>Flexible integrated circuits (FlexICs) have drawn increasing attention, particularly in remote sensors and wearables operating in a limited power budget. Here, we present an ultra-low power timer designed to wake-up an external circuit periodically, from a deep-sleep state into an active state, thereby largely reducing the system power consumption. We achieved this with a circuit topology that exploits the transistor’s leakage current to generate a low frequency wake-up signal. This topology is compatible with IC technologies where only n-type transistors are available. The design was implemented with the sustainable FlexIC process of PragmatIC, that is based on Indium Gallium Zinc Oxide (IGZO) thin-film transistors. Our timer generates mean wake-up frequency of 0.24 ± 0.15 Hz, with a mean power consumption of 26.7 ± 14.1 nW. In this paper, we provide details of the Wake-Up timer’s design and performance at different supply voltages, under temperature variations and different light conditions.</p>","PeriodicalId":48528,"journal":{"name":"npj Flexible Electronics","volume":"3 1","pages":""},"PeriodicalIF":14.6,"publicationDate":"2025-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142962776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sn-based perovskite solar cells (PSCs) have attracted attention because of their low environmental impact. Unfortunately, the readily occurring oxidation of Sn2+ inhibits further improvement of their efficiency and stability. Ruddlesden–Popper (RP) Sn-based perovskites are considered promising candidates as absorbers that improve the performance and stability of Sn-based PSCs. However, microscopic understanding of performance-enhancing mechanisms remains insufficient. For this study, electron spin resonance (ESR) spectroscopy measurements were taken of RP Sn-based PSCs with poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) hole-transport layers and (BA0.5PEA0.5)2FA3Sn4I13 perovskite layers to clarify the space-charge region formation mechanism at the PEDOT:PSS/(BA0.5PEA0.5)2FA3Sn4I13 interface. These results indicated electron-barrier formation in the (BA0.5PEA0.5)2FA3Sn4I13 layer near the PEDOT:PSS layer. Moreover, the electron barrier was found to be enhanced during device operation. The enhanced interface band bending reduces interface recombination and thereby improves the device's performance. These findings might provide important progress in practical applications of PSCs and might advance the realization of a carbon-neutral society.
{"title":"Operando spin observation elucidating performance-improvement mechanisms during operation of Ruddlesden–Popper Sn-based perovskite solar cells","authors":"Yizhou Chen, Seira Yamaguchi, Atsushi Sato, Dong Xue, Kazuhiro Marumoto","doi":"10.1038/s41528-024-00376-2","DOIUrl":"https://doi.org/10.1038/s41528-024-00376-2","url":null,"abstract":"<p>Sn-based perovskite solar cells (PSCs) have attracted attention because of their low environmental impact. Unfortunately, the readily occurring oxidation of Sn<sup>2+</sup> inhibits further improvement of their efficiency and stability. Ruddlesden–Popper (RP) Sn-based perovskites are considered promising candidates as absorbers that improve the performance and stability of Sn-based PSCs. However, microscopic understanding of performance-enhancing mechanisms remains insufficient. For this study, electron spin resonance (ESR) spectroscopy measurements were taken of RP Sn-based PSCs with poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) hole-transport layers and (BA<sub>0.5</sub>PEA<sub>0.5</sub>)<sub>2</sub>FA<sub>3</sub>Sn<sub>4</sub>I<sub>13</sub> perovskite layers to clarify the space-charge region formation mechanism at the PEDOT:PSS/(BA<sub>0.5</sub>PEA<sub>0.5</sub>)<sub>2</sub>FA<sub>3</sub>Sn<sub>4</sub>I<sub>13</sub> interface. These results indicated electron-barrier formation in the (BA<sub>0.5</sub>PEA<sub>0.5</sub>)<sub>2</sub>FA<sub>3</sub>Sn<sub>4</sub>I<sub>13</sub> layer near the PEDOT:PSS layer. Moreover, the electron barrier was found to be enhanced during device operation. The enhanced interface band bending reduces interface recombination and thereby improves the device's performance. These findings might provide important progress in practical applications of PSCs and might advance the realization of a carbon-neutral society.</p>","PeriodicalId":48528,"journal":{"name":"npj Flexible Electronics","volume":"13 1","pages":""},"PeriodicalIF":14.6,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142936915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-04DOI: 10.1038/s41528-024-00375-3
T. Barker, A. Gray, M. P. Weir, J. S. Sharp, A. Kenton, Z. R. Kudrynskyi, H. Rostami, A. Patané
Understanding the bending behaviour of a crystal onto a flexible platform is crucial for flexible electronics. The Young’s modulus, a measure of how easily a material deforms, plays a critical role in the coupled deformation of a crystal on a flexible substrate, as well as the transfer of strain from the substrate onto the layer. Here, we report on the bending behaviour of gallium selenide (GaSe), a van der Waals semiconductor with a small Young’s modulus and strain-dependent electronic band structure. A controllable, reproducible uniaxial strain, ϵ, is applied to nanometer-thick GaSe layers via their bending on a mica substrate. The spectral shift ΔE of the room temperature photoluminescence emission corresponds to a strain coefficient ΔE/ϵ of up to ~100 eV, the largest value reported in the literature to date. This is accompanied by coupled electronic and vibrational states under strain-induced resonant excitation conditions, as probed by Raman spectroscopy.
{"title":"Giant elasto-optic response of gallium selenide on flexible mica","authors":"T. Barker, A. Gray, M. P. Weir, J. S. Sharp, A. Kenton, Z. R. Kudrynskyi, H. Rostami, A. Patané","doi":"10.1038/s41528-024-00375-3","DOIUrl":"https://doi.org/10.1038/s41528-024-00375-3","url":null,"abstract":"<p>Understanding the bending behaviour of a crystal onto a flexible platform is crucial for flexible electronics. The Young’s modulus, a measure of how easily a material deforms, plays a critical role in the coupled deformation of a crystal on a flexible substrate, as well as the transfer of strain from the substrate onto the layer. Here, we report on the bending behaviour of gallium selenide (GaSe), a van der Waals semiconductor with a small Young’s modulus and strain-dependent electronic band structure. A controllable, reproducible uniaxial strain, <i>ϵ</i>, is applied to nanometer-thick GaSe layers via their bending on a mica substrate. The spectral shift Δ<i>E</i> of the room temperature photoluminescence emission corresponds to a strain coefficient Δ<i>E</i>/<i>ϵ</i> of up to ~100 eV, the largest value reported in the literature to date. This is accompanied by coupled electronic and vibrational states under strain-induced resonant excitation conditions, as probed by Raman spectroscopy.</p>","PeriodicalId":48528,"journal":{"name":"npj Flexible Electronics","volume":"20 1","pages":""},"PeriodicalIF":14.6,"publicationDate":"2025-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142924443","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-19DOI: 10.1038/s41528-024-00373-5
Yanbo Du, Chuanli Zhou, Yanhui Feng, Lin Qiu
Body core temperature is an important physiological indicator for self-health management and medical diagnosis. However, existing devices always fails to achieve continuous monitoring of core body temperature due to their invasive or motion-restricted measurement principles. Here, a wearable flexible device which can continuously monitor the core body temperature was developed. The flexible device integrated with fourteen temperature sensors and one thermal conductivity sensor on the polydimethylsiloxane substrate can be conformally attached to the human skin. With the wearable data processing module and wireless communication module, the continuous monitoring of the core body temperature for 24 h and the portable monitoring of the skin thermal conductivity were realized using this device. Owing to the annular distribution design of the temperature sensor and the directional heat transfer design of the thermal conductivity sensor, this device is comparable in accuracy and stability compared to standard instruments that require invasive or motion-restricted measurements.
{"title":"Flexible, multimodal device for measurement of body temperature, core temperature, thermal conductivity and water content","authors":"Yanbo Du, Chuanli Zhou, Yanhui Feng, Lin Qiu","doi":"10.1038/s41528-024-00373-5","DOIUrl":"10.1038/s41528-024-00373-5","url":null,"abstract":"Body core temperature is an important physiological indicator for self-health management and medical diagnosis. However, existing devices always fails to achieve continuous monitoring of core body temperature due to their invasive or motion-restricted measurement principles. Here, a wearable flexible device which can continuously monitor the core body temperature was developed. The flexible device integrated with fourteen temperature sensors and one thermal conductivity sensor on the polydimethylsiloxane substrate can be conformally attached to the human skin. With the wearable data processing module and wireless communication module, the continuous monitoring of the core body temperature for 24 h and the portable monitoring of the skin thermal conductivity were realized using this device. Owing to the annular distribution design of the temperature sensor and the directional heat transfer design of the thermal conductivity sensor, this device is comparable in accuracy and stability compared to standard instruments that require invasive or motion-restricted measurements.","PeriodicalId":48528,"journal":{"name":"npj Flexible Electronics","volume":" ","pages":"1-12"},"PeriodicalIF":12.3,"publicationDate":"2024-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41528-024-00373-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142849078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-19DOI: 10.1038/s41528-024-00372-6
Jung Woo Moon, Seunghan Kim, Jin Hyeon Kim, Sunil V. Barma, Sang Young Jeong, Jinho Keum, Ho Sun Lim, Youngjae Yoo, Han Young Woo, Sae Byeok Jo, Moon Sung Kang, Jeong Ho Cho
This study demonstrates multithreshold engineering of a solution-processed heterojunction electrochemical transistor using a blend of n-type CdSe tetrapod-shaped nanocrystals (TpNCs) and an n-type polymeric organic semiconductor (OSC). The unique geometry of TpNCs enables a broad concentration range of charge percolation, where charge transfer between TpNC and OSC domains determines multiple threshold voltages. The OSC domain’s threshold voltage shifts from 1 to −1 V as TpNC content increases, while the TpNC domain maintains a threshold above 1.5 V. This allows for stable intermediate states, crucial for multivalued logic operations. Charge percolation and photoluminescence studies show selective charge redistribution, shifting the threshold voltages in the polymer networks. Ternary logic gates, including TNOT, TNAND, and TNOR, based on these heterojunction transistors, were also demonstrated, highlighting the potential of this approach for advanced logic applications.
{"title":"Self-defined dual charge percolation networks for solution-processed multithreshold transistors","authors":"Jung Woo Moon, Seunghan Kim, Jin Hyeon Kim, Sunil V. Barma, Sang Young Jeong, Jinho Keum, Ho Sun Lim, Youngjae Yoo, Han Young Woo, Sae Byeok Jo, Moon Sung Kang, Jeong Ho Cho","doi":"10.1038/s41528-024-00372-6","DOIUrl":"10.1038/s41528-024-00372-6","url":null,"abstract":"This study demonstrates multithreshold engineering of a solution-processed heterojunction electrochemical transistor using a blend of n-type CdSe tetrapod-shaped nanocrystals (TpNCs) and an n-type polymeric organic semiconductor (OSC). The unique geometry of TpNCs enables a broad concentration range of charge percolation, where charge transfer between TpNC and OSC domains determines multiple threshold voltages. The OSC domain’s threshold voltage shifts from 1 to −1 V as TpNC content increases, while the TpNC domain maintains a threshold above 1.5 V. This allows for stable intermediate states, crucial for multivalued logic operations. Charge percolation and photoluminescence studies show selective charge redistribution, shifting the threshold voltages in the polymer networks. Ternary logic gates, including TNOT, TNAND, and TNOR, based on these heterojunction transistors, were also demonstrated, highlighting the potential of this approach for advanced logic applications.","PeriodicalId":48528,"journal":{"name":"npj Flexible Electronics","volume":" ","pages":"1-10"},"PeriodicalIF":12.3,"publicationDate":"2024-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41528-024-00372-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142849077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
With the increasing demand for wearable electronic products, there is a pressing need to develop electronic devices that seamlessly conform to the contours of the human body while delivering excellent performance and reliability. Traditional rigid electronic fabrication technologies fall short of meeting these requirements, necessitating the exploration of advanced flexible fabrication technologies that offer new possibilities for designing and fabricating flexible and stretchable electronic products, particularly in wearable devices. Over time, the continuous development of innovative fabrication techniques has ushered in significant improvements in the design freedom, lightweight, seamless integration, and multifunctionality of wearable electronics. Here, we provide a comprehensive overview of the advancements facilitated by advanced fabrication technology in wearable electronics. It specifically focuses on key fabrication methods, including printed electronics fabrication, soft transfer, 3D structure fabrication, and deformation fabrication. By highlighting these advancements, it sheds light on the challenges and prospects for further development in wearable electronics fabrication technologies. The introduction of advanced fabrication technologies has revolutionized the landscape of wearable/conformable electronics, expanding their application domains, streamlining system complexity associated with customization, manufacturing, and production, and opening up new avenues for innovation and development of body-conformable electronics.
{"title":"Revolutionizing wearable technology: advanced fabrication techniques for body-conformable electronics","authors":"Ruilai Wei, Haotian Li, Zhongming Chen, Qilin Hua, Guozhen Shen, Kai Jiang","doi":"10.1038/s41528-024-00370-8","DOIUrl":"10.1038/s41528-024-00370-8","url":null,"abstract":"With the increasing demand for wearable electronic products, there is a pressing need to develop electronic devices that seamlessly conform to the contours of the human body while delivering excellent performance and reliability. Traditional rigid electronic fabrication technologies fall short of meeting these requirements, necessitating the exploration of advanced flexible fabrication technologies that offer new possibilities for designing and fabricating flexible and stretchable electronic products, particularly in wearable devices. Over time, the continuous development of innovative fabrication techniques has ushered in significant improvements in the design freedom, lightweight, seamless integration, and multifunctionality of wearable electronics. Here, we provide a comprehensive overview of the advancements facilitated by advanced fabrication technology in wearable electronics. It specifically focuses on key fabrication methods, including printed electronics fabrication, soft transfer, 3D structure fabrication, and deformation fabrication. By highlighting these advancements, it sheds light on the challenges and prospects for further development in wearable electronics fabrication technologies. The introduction of advanced fabrication technologies has revolutionized the landscape of wearable/conformable electronics, expanding their application domains, streamlining system complexity associated with customization, manufacturing, and production, and opening up new avenues for innovation and development of body-conformable electronics.","PeriodicalId":48528,"journal":{"name":"npj Flexible Electronics","volume":" ","pages":"1-20"},"PeriodicalIF":12.3,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41528-024-00370-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142762892","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Flexible sensors are promising candidates in personalized healthcare, while desired sensors that allow implantation for biomedical applications with optimal sensing and favorable biological properties remain challenges. Here, a multifunctional hydrogel sensor was developed with gallic acid-modified chitosan (CSGA) and 3-carboxyphenylboronic acid-modified chitosan (CSPBA) by encapsulating Ag-decorated polydopamine (Ag@PDA) nanoparticles, namely Ag@PDA-(CSPBA/CSGA). The optimized hydrogel sensor showed desired sensitivity (gauge factor = 2.49), a rapid response/recovery time of 263 ms and good durability. Due to the presence of abundant reactive groups within Ag@PDA-(CSPBA/CSGA), the hydrogel sensor exhibited a comprehensive performance of self-healing, tissue adhesiveness, antioxidative activity, and antibacterial effects against Escherichia coli (92.76%) and Staphylococcus aureus (98.08%). Moreover, the hydrogel sensor could be utilized as a wound dressing, facilitating accelerated wound closure and tissue regeneration. Both subtle activities and large-scale movements could be monitored and distinguished by the hydrogel sensor. This study provides a promising epidermal sensor that offers multifunctionality for health monitoring and wound management.
{"title":"Ag@polydopamine-functionalized borate ester-linked chitosan hydrogel integrates monitoring with wound healing for epidermal sensor","authors":"Wei Shi, Hui Li, Chengsheng Xu, Gaoyi Wu, Jing Chen, Jinyong Zhang, Lixin Liang, Qingyang Wu, Yongsheng Liang, Guanglin Li, Wei Tang","doi":"10.1038/s41528-024-00366-4","DOIUrl":"10.1038/s41528-024-00366-4","url":null,"abstract":"Flexible sensors are promising candidates in personalized healthcare, while desired sensors that allow implantation for biomedical applications with optimal sensing and favorable biological properties remain challenges. Here, a multifunctional hydrogel sensor was developed with gallic acid-modified chitosan (CSGA) and 3-carboxyphenylboronic acid-modified chitosan (CSPBA) by encapsulating Ag-decorated polydopamine (Ag@PDA) nanoparticles, namely Ag@PDA-(CSPBA/CSGA). The optimized hydrogel sensor showed desired sensitivity (gauge factor = 2.49), a rapid response/recovery time of 263 ms and good durability. Due to the presence of abundant reactive groups within Ag@PDA-(CSPBA/CSGA), the hydrogel sensor exhibited a comprehensive performance of self-healing, tissue adhesiveness, antioxidative activity, and antibacterial effects against Escherichia coli (92.76%) and Staphylococcus aureus (98.08%). Moreover, the hydrogel sensor could be utilized as a wound dressing, facilitating accelerated wound closure and tissue regeneration. Both subtle activities and large-scale movements could be monitored and distinguished by the hydrogel sensor. This study provides a promising epidermal sensor that offers multifunctionality for health monitoring and wound management.","PeriodicalId":48528,"journal":{"name":"npj Flexible Electronics","volume":" ","pages":"1-12"},"PeriodicalIF":12.3,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41528-024-00366-4.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142754185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-26DOI: 10.1038/s41528-024-00367-3
Hai-Tao Deng, Yi-Xuan Xia, Yu-Chi Liu, Beomjoon Kim, Xiao-Sheng Zhang
Multifunctional integration and heterogeneous surface integration are two crucial challenges in the in-depth use and development of triboelectric nanogenerators (TENGs) in the wearable electronic field. A promising solution is to develop stretchable TENGs (STENG), which have the potential for microenergy supply and self-powered sensing. The key challenge is to endow its functional components with good deformability and realize heterogeneous surface integration. Herein, we proposed a fully stretchable, surface adaptable TENG using stretchable micro-nano hierarchical friction interfaces. It integrated microenenrgy supply and multifunctional self-powered sensing (i.e., bend, force, and frequency sensing) abilities successfully. The highly-linear sensing abilities endows the STENG with a good biometric ability. As an application, a STENG array based-stretchable wearable keyboard was proposed. It identified dynamic keystroke motions of all users with a Support Vector Machine, with a high accuracy of 93.21%. Besides, the intruders who were not sampled were distinguished from users, with an accuracy of 81.50%.
{"title":"Stretchable nanogenerator with micro-nano hierarchical interfaces for self-powered biometric authentication","authors":"Hai-Tao Deng, Yi-Xuan Xia, Yu-Chi Liu, Beomjoon Kim, Xiao-Sheng Zhang","doi":"10.1038/s41528-024-00367-3","DOIUrl":"10.1038/s41528-024-00367-3","url":null,"abstract":"Multifunctional integration and heterogeneous surface integration are two crucial challenges in the in-depth use and development of triboelectric nanogenerators (TENGs) in the wearable electronic field. A promising solution is to develop stretchable TENGs (STENG), which have the potential for microenergy supply and self-powered sensing. The key challenge is to endow its functional components with good deformability and realize heterogeneous surface integration. Herein, we proposed a fully stretchable, surface adaptable TENG using stretchable micro-nano hierarchical friction interfaces. It integrated microenenrgy supply and multifunctional self-powered sensing (i.e., bend, force, and frequency sensing) abilities successfully. The highly-linear sensing abilities endows the STENG with a good biometric ability. As an application, a STENG array based-stretchable wearable keyboard was proposed. It identified dynamic keystroke motions of all users with a Support Vector Machine, with a high accuracy of 93.21%. Besides, the intruders who were not sampled were distinguished from users, with an accuracy of 81.50%.","PeriodicalId":48528,"journal":{"name":"npj Flexible Electronics","volume":" ","pages":"1-10"},"PeriodicalIF":12.3,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41528-024-00367-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142712484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}