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Deformable micro-supercapacitor fabricated via laser ablation patterning of Graphene/liquid metal 通过激光烧蚀石墨烯/液态金属图案制造可变形微型超级电容器
IF 14.6 1区 材料科学 Q1 Engineering Pub Date : 2024-03-14 DOI: 10.1038/s41528-024-00306-2
Keon-Woo Kim, Seong Ju Park, Su-Jeong Park, Inae Kim, Bomi Park, Se Hyun Kim, Unyong Jeong, Jin Kon Kim, Chanwoo Yang
Deformable and miniaturized energy storage devices are essential for powering soft electronics. Herein, we fabricate deformable micro supercapacitors (MSCs) based on eutectic gallium-indium liquid metal (EGaIn) current collectors with integrated graphene. The well-define interdigitated electrode patterning with controlled gap is successfully realized by using the laser ablation because of a strong laser absorption of graphene and EGaIn. By judicious control of gap size between neighboring interdigitated electrodes and mass loading of graphene, we achieve a high areal capacitance (1336 µF cm−2) with reliable rate performance. In addition, owing to the intrinsic liquid characteristics of EGaIn current collector, the areal capacitance of fabricated MSC retains 90% of original value even after repetitive folding and 20% stretching up to 1000 cycles. Finally, we successfully integrate deformable MSC with a commercial light-emitting diode to demonstrate the feasibility of MSC as a deformable power source. The fabricated MSCs operate stably under various mechanical deformations, including stretching, folding, twisting, and wrinkling.
可变形和微型化的储能设备对于为软电子器件供电至关重要。在此,我们基于集成了石墨烯的共晶镓铟液态金属(EGaIn)集流体,制造出了可变形微型超级电容器(MSCs)。由于石墨烯和 EGaIn 对激光有很强的吸收能力,利用激光烧蚀技术成功实现了具有可控间隙的轮廓清晰的电极间图案化。通过合理控制相邻插接电极之间的间隙大小和石墨烯的质量负载,我们获得了具有可靠速率性能的高面积电容(1336 µF cm-2)。此外,由于 EGaIn 集流体的固有液态特性,即使反复折叠和拉伸 20%(最多 1000 次),所制造的 MSC 的面积电容仍能保持原始值的 90%。最后,我们成功地将可变形的 MSC 与商用发光二极管集成在一起,证明了 MSC 作为可变形电源的可行性。制成的间充质干细胞可在拉伸、折叠、扭曲和起皱等各种机械变形条件下稳定运行。
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引用次数: 0
Highly reliable and stretchable OLEDs based on facile patterning method: toward stretchable organic optoelectronic devices 基于简易图案化方法的高可靠性和可拉伸有机发光二极管:走向可拉伸有机光电器件
IF 14.6 1区 材料科学 Q1 Engineering Pub Date : 2024-03-09 DOI: 10.1038/s41528-024-00303-5
Minwoo Nam, Jaehyeock Chang, Hagseon Kim, Young Hyun Son, Yongmin Jeon, Jeong Hyun Kwon, Kyung Cheol Choi
Stretchable displays attract significant attention because of their potential applications in wearable electronics, smart textiles, and human-conformable devices. This paper introduces an electrically stable, mechanically ultra-robust, and water-resistant stretchable OLED display (SOLED) mounted on a stress-relief pillar platform. The SOLED is fabricated on a thin, transparent polyethylene terephthalate (PET) film using conventional vacuum evaporation, organic-inorganic hybrid thin film encapsulation (TFE), and a nonselective laser patterning process. This simple and efficient process yields an OLED display with exceptional stretchability, reaching up to 95% strain and outstanding durability, enduring 100,000 stretch-release cycles at 50% strain. Operational lifetime and water-resistant storage lifetime measurements confirm that the TFE provides effective protection even after the nonselective laser patterning process. A 3 × 3 array SOLED display module mounted on a stress-relief pillar platform is successfully implemented, marking the first case of water-resistant display array operation in the field of SOLEDs. This work aims to develop practical stretchable displays by offering a reliable fabrication method and device design for creating mechanically robust and adaptable displays, potentially paving the way for future advances in human-conformable electronics and other innovative applications.
可拉伸显示器因其在可穿戴电子设备、智能纺织品和人体适形设备中的潜在应用而备受关注。本文介绍了一种安装在应力消除支柱平台上的电气稳定、机械超坚固且防水的可拉伸有机发光二极管显示器(SOLED)。该 SOLED 采用传统的真空蒸发、有机-无机混合薄膜封装 (TFE) 和非选择性激光图案化工艺,在透明的聚对苯二甲酸乙二醇酯 (PET) 薄膜上制造而成。这种简单而高效的工艺生产出的 OLED 显示屏具有卓越的拉伸性,应变高达 95%,并且具有出色的耐用性,在应变为 50%的情况下可经受 100,000 次拉伸释放循环。工作寿命和防水存储寿命测量证实,即使在非选择性激光图案化工艺之后,TFE 仍能提供有效的保护。安装在应力消除支柱平台上的 3 × 3 阵列 SOLED 显示模块已成功实现,这标志着 SOLED 领域首个防水显示阵列的运行案例。这项工作旨在开发实用的可拉伸显示器,提供可靠的制造方法和器件设计,以制造机械坚固、适应性强的显示器,为未来可适应人体的电子产品和其他创新应用的发展铺平道路。
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引用次数: 0
Ultrathin damage-tolerant flexible metal interconnects reinforced by in-situ graphene synthesis 通过原位合成石墨烯强化超薄耐损伤柔性金属互连器件
IF 14.6 1区 材料科学 Q1 Engineering Pub Date : 2024-03-08 DOI: 10.1038/s41528-024-00300-8
Kaihao Zhang, Mitisha Surana, Jad Yaacoub, Sameh Tawfick
Conductive patterned metal films bonded to compliant elastomeric substrates form meshes which enable flexible electronic interconnects for various applications. However, while bottom-up deposition of thin films by sputtering or growth is well-developed for rigid electronics, maintaining good electrical conductivity in sub-micron thin metal films upon large deformations or cyclic loading remains a significant challenge. Here, we propose a strategy to improve the electromechanical performance of nanometer-thin palladium films by in-situ synthesis of a conformal graphene coating using chemical vapor deposition (CVD). The uniform graphene coverage improves the thin film’s damage tolerance, electro-mechanical fatigue, and fracture toughness owing to the high stiffness of graphene and the conformal CVD-grown graphene-metal interface. Graphene-coated Pd thin film interconnects exhibit stable increase in electrical resistance even when strained beyond 60% and longer fatigue life up to a strain range of 20%. The effect of graphene is more significant for thinner films of < 300 nm, particularly at high strains. The experimental observations are well described by the thin film electro-fragmentation model and the Coffin-Manson relationship. These findings demonstrate the potential of CVD-grown graphene nanocomposite materials in improving the damage tolerance and electromechanical robustness of flexible electronics. The proposed approach offers opportunities for the development of reliable and high-performance ultra-conformable flexible electronic devices.
导电图案金属膜与顺应性弹性基材粘合形成网状,可实现各种应用中的柔性电子互连。然而,虽然通过溅射或生长自下而上沉积薄膜的技术已在刚性电子器件中得到广泛应用,但要在亚微米级金属薄膜发生大变形或循环加载时保持良好的导电性仍然是一项重大挑战。在此,我们提出了一种利用化学气相沉积(CVD)原位合成保形石墨烯涂层来改善纳米级薄钯膜机电性能的策略。由于石墨烯的高刚度和保形 CVD 生长的石墨烯-金属界面,石墨烯的均匀覆盖提高了薄膜的损伤容限、机电疲劳和断裂韧性。涂有石墨烯的钯薄膜互连器件即使在应变超过 60% 的情况下也能稳定地增加电阻,并且在 20% 的应变范围内具有更长的疲劳寿命。石墨烯对 300 nm 薄膜的影响更为显著,尤其是在高应变条件下。薄膜电破碎模型和 Coffin-Manson 关系很好地描述了实验观察结果。这些发现证明了 CVD 生长的石墨烯纳米复合材料在提高柔性电子器件的损伤耐受性和机电稳健性方面的潜力。所提出的方法为开发可靠、高性能的超成型柔性电子器件提供了机会。
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引用次数: 0
Inherently integrated microfiber-based flexible proprioceptive sensor for feedback-controlled soft actuators 用于反馈控制软致动器的固有集成微纤维柔性本体感觉传感器
IF 14.6 1区 材料科学 Q1 Engineering Pub Date : 2024-03-07 DOI: 10.1038/s41528-024-00302-6
Hwajoong Kim, Hyunbin Na, Seungbeom Noh, Shinwon Chang, Jinho Kim, Taejune Kong, Gyowook Shin, Chankyu Lee, Seonggyu Lee, Yong-Lae Park, Sehoon Oh, Jaehong Lee
For the accurate and continuous control of soft actuators in dynamic environments, the movements of the soft actuators must be monitored in real-time. To this end, various soft actuators capable of self-monitoring have been developed by separately integrating sensing devices into actuators. However, integrating such heterogeneous sensing components into soft actuators results in structural complexity, high manufacturing costs, and poor interfacial stability. Here, we report on intelligent pneumatic fiber-reinforced soft actuators with an inherent flexible proprioceptive sensor that uses only the essential components of typical fiber-reinforced soft actuators. The inherent flexible proprioceptive sensor is achieved by leveraging two parallel conductive microfibers around an elastomeric chamber of the soft actuator, which simultaneously acts as both a capacitive bending sensor and radial expansion limiting fibers of typical fiber-reinforced soft actuators. The proprioceptive soft actuator exhibits excellent mechanical actuation up to 240° bending motion and proprioceptive sensing performance with high sensitivity of 1.2 pF rad−1. Mathematical analysis and simulations of the soft actuator can effectively predict the bending actuation and capacitive responses against input pressures. We demonstrate that proprioceptive soft actuators can be used to construct a soft gripping system and prosthetic hand which express various hand gestures and perform dexterous manipulation with real-time proprioceptive sensing capability.
为了在动态环境中对软执行器进行精确和连续的控制,必须对软执行器的运动进行实时监测。为此,通过将传感设备单独集成到致动器中,开发出了各种能够自我监测的软致动器。然而,将这种异构传感元件集成到软致动器中会导致结构复杂、制造成本高和界面稳定性差。在此,我们报告了带有固有柔性本体感觉传感器的智能气动纤维增强软推杆,该推杆仅使用了典型纤维增强软推杆的基本组件。固有的柔性本体感觉传感器是通过利用软推杆弹性腔周围的两条平行导电微纤维实现的,这两条微纤维同时充当典型纤维增强软推杆的电容弯曲传感器和径向膨胀限制纤维。本体感觉软致动器具有出色的机械致动性能,弯曲运动可达 240°,本体感觉传感性能灵敏度高达 1.2 pF rad-1。软致动器的数学分析和模拟可以有效预测弯曲致动和电容响应对输入压力的影响。我们证明,本体感觉软致动器可用于构建软抓握系统和假手,从而表达各种手势并进行灵巧的操作,同时具有实时本体感觉传感能力。
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引用次数: 0
Ultra-sensitive, highly linear, and hysteresis-free strain sensors enabled by gradient stiffness sliding strategy 利用梯度刚度滑动策略实现超灵敏、高线性和无滞后应变传感器
IF 14.6 1区 材料科学 Q1 Engineering Pub Date : 2024-03-07 DOI: 10.1038/s41528-024-00301-7
Fuhua Xue, Qingyu Peng, Renjie Ding, Pengyang Li, Xu Zhao, Haowen Zheng, Liangliang Xu, Zhigong Tang, Xinxing Zhang, Xiaodong He
Developing strain sensors with both high sensitivity and high linearity has always been the goal of researchers. Compared to resistive strain sensors, capacitive strain sensors have incomparable linearity advantages, but have always been limited by low sensitivity. Here, we report a gradient stiffness sliding design strategy that addresses this problem, significantly improving sensitivity while maintaining high linearity. By controlling the distribution of the locally enhanced electric field and the heterogeneous deformation of the substrate, a strain sensor with excellent performance is successfully prepared, exhibiting a giant gauge factor (9.1 × 106) and linearity (R2 = 0.9997) over the entire sensing range, together with almost no hysteresis and fast response time (17 ms). The gradient stiffness sliding design is a general strategy expected to be applied to other types of sensors to achieve ultra-high sensitivity and ultra-high linearity at the same time.
开发兼具高灵敏度和高线性度的应变传感器一直是研究人员的目标。与电阻式应变传感器相比,电容式应变传感器具有无可比拟的线性优势,但一直受限于低灵敏度。在此,我们报告了一种梯度刚度滑动设计策略,它能解决这一问题,在保持高线性度的同时显著提高灵敏度。通过控制局部增强电场的分布和基底的异质变形,我们成功制备出了一种性能卓越的应变传感器,在整个传感范围内表现出巨大的量规因子(9.1 × 106)和线性度(R2 = 0.9997),同时几乎没有滞后,响应时间快(17 毫秒)。梯度刚度滑动设计是一种通用策略,有望应用于其他类型的传感器,以同时实现超高灵敏度和超高线性度。
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引用次数: 0
Squid-inspired and wirelessly controllable display for active camouflage in aquatic-environment 受乌贼启发的无线可控显示器,用于水生环境中的主动伪装
IF 14.6 1区 材料科学 Q1 Engineering Pub Date : 2024-03-05 DOI: 10.1038/s41528-024-00292-5
Doyoung Kim, Seung Won Seon, Minkyung Shin, Jihwan Kim, Bogeun Kim, Janghoon Joo, Sang Uk Park, Wooseok Kim, Hee Kyu Lee, Byeong Woon Lee, Se Gi Lee, Su Eon Lee, Ji-Hun Seo, Seung Ho Han, Bong Hoon Kim, Sang Min Won
Achieving optimal camouflage in an aquatic environment necessitates the ability to modulate transmittance in response to the surrounding obscurity and potential threats. This adaptation involves a dynamic transition from transparency to a deep-blue color, especially in low-light or dark situations. Such a strategy promotes a seamless assimilation with the surroundings, enabling the absorption of searchlights and, subsequently, diminishing the risk of detection by predators. Therefore, the presence of sophisticated mechanisms that facilitates stable and efficient control of transmittance is imperative, enabling smooth transition between transparent and deep-blue hues within the aquatic environment. This study presents nature-inspired programmable camouflage system that integrates an electrochromic display as the primary transmittance change element and a wireless base module for power and data transmission. Such technology offers a robust and flexible construction, ensuring stable operation as demonstrated through mechanical-fatigue experiments and quantitative simulation. A custom circuit and a power-control software package enable active control of multiple electrochromic displays while submerged in water.
要在水生环境中达到最佳伪装效果,就必须能够根据周围的遮蔽物和潜在威胁调节透光率。这种适应包括从透明到深蓝色的动态过渡,尤其是在弱光或黑暗环境中。这种策略可以促进与周围环境的无缝同化,使其能够吸收探照灯,从而降低被捕食者发现的风险。因此,必须要有先进的机制来稳定有效地控制透射率,使水生环境中的透明色调和深蓝色调之间能够平稳过渡。本研究介绍了受大自然启发的可编程伪装系统,该系统集成了作为主要透射率变化元件的电致变色显示屏和用于电源和数据传输的无线基础模块。通过机械疲劳实验和定量模拟,这种技术具有坚固灵活的结构,可确保稳定运行。通过定制电路和电源控制软件包,可以在浸入水中时主动控制多个电致变色显示屏。
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引用次数: 0
Multilayer stretchable electronics with designs enabling a compact lateral form 多层可拉伸电子器件的设计实现了紧凑的横向外形
IF 14.6 1区 材料科学 Q1 Engineering Pub Date : 2024-02-21 DOI: 10.1038/s41528-024-00299-y
Dongwuk Jung, Hunpyo Ju, Sungbum Cho, Taeyeon Lee, Changeui Hong, Jongho Lee
Stretchable electronics are of huge interest as they can be useful in various irregular non-planar or deformable surfaces including human bodies. High density multi-functional stretchable electronics are beneficial as they can be reliably used in more compact regions. However, simply stacking multiple layers may increase induced strain, reducing degree of stretchability. Here, we present the design approach for the stretchable multilayer electronics that provide a similar degree of stretchability compare to a single layer electronics although the multilayer electronics are in much more compact form. We provide experimental and computational analyses for the benefits of the approach along with demonstrations with compact form of the multi-functional stretchable implantable bio-electronics and of the stretchable multilayer passive matrix LEDs array. The results presented here should be useful for a wide range of applications that require stretchable high-density electronics.
可拉伸电子器件可用于包括人体在内的各种不规则非平面或可变形表面,因此备受关注。高密度多功能可拉伸电子器件可以在更紧凑的区域内可靠地使用,因此非常有益。然而,简单地堆叠多层可能会增加诱导应变,降低可拉伸程度。在此,我们介绍了可拉伸多层电子元件的设计方法,这种电子元件与单层电子元件相比具有相似的可拉伸性,但多层电子元件的结构更为紧凑。我们对该方法的优点进行了实验和计算分析,并展示了紧凑型多功能可拉伸植入式生物电子器件和可拉伸多层无源矩阵 LED 阵列。本文介绍的结果将有助于需要可拉伸高密度电子器件的广泛应用。
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引用次数: 0
Stretchable liquid metal based biomedical devices 基于可拉伸液态金属的生物医学设备
IF 14.6 1区 材料科学 Q1 Engineering Pub Date : 2024-02-20 DOI: 10.1038/s41528-024-00298-z
Yifan Deng, Fan Bu, Yujie Wang, Pei Song Chee, Xiangye Liu, Cao Guan
Pursuit of improved living quality has stimulated great demand for high-performance conformal healthcare devices in modern human society. However, manufacturing of efficient, comfortable and stretchable biomedical apparatus faces huge challenges using traditional materials. Liquid metals (LMs) show remarkable potential to solve this problem due to their extraordinary biocompatibility, stretchability, thermal and electrical conductivity. In recent years, tremendous explorations have attempted to make stretchable biomedical devices with LMs. Herein, we review the stretchable LM-based biomedical devices on the topics of disease treatment and human function augmenting. The representative and up-to-date neural interfaces, alloy cement, e-vessels, soft heaters, exoskeletons, and e-skins are summarized. The existing issues of LMs applied for biomedical devices are also discussed. This review can provide guidance for the follow-up research in LM-based biomedical devices.
现代人类社会对提高生活质量的追求激发了对高性能保形医疗设备的巨大需求。然而,使用传统材料制造高效、舒适、可拉伸的生物医学设备面临着巨大挑战。液态金属(LMs)因其非凡的生物相容性、可拉伸性、导热性和导电性,在解决这一问题方面显示出巨大的潜力。近年来,人们在利用液态金属制作可拉伸生物医学设备方面进行了大量探索。在此,我们以疾病治疗和人体功能增强为主题,综述了基于 LM 的可拉伸生物医学设备。总结了具有代表性的最新神经接口、合金水泥、电子血管、软加热器、外骨骼和电子皮肤。此外,还讨论了将 LMs 应用于生物医学设备的现有问题。本综述可为基于 LM 的生物医学设备的后续研究提供指导。
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引用次数: 0
Intelligent upper-limb exoskeleton integrated with soft bioelectronics and deep learning for intention-driven augmentation 集成了软生物电子学和深度学习的智能上肢外骨骼,可实现意图驱动的增强功能
IF 14.6 1区 材料科学 Q1 Engineering Pub Date : 2024-02-10 DOI: 10.1038/s41528-024-00297-0
Jinwoo Lee, Kangkyu Kwon, Ira Soltis, Jared Matthews, Yoon Jae Lee, Hojoong Kim, Lissette Romero, Nathan Zavanelli, Youngjin Kwon, Shinjae Kwon, Jimin Lee, Yewon Na, Sung Hoon Lee, Ki Jun Yu, Minoru Shinohara, Frank L. Hammond, Woon-Hong Yeo
The age and stroke-associated decline in musculoskeletal strength degrades the ability to perform daily human tasks using the upper extremities. Here, we introduce an intelligent upper-limb exoskeleton system that utilizes deep learning to predict human intention for strength augmentation. The embedded soft wearable sensors provide sensory feedback by collecting real-time muscle activities, which are simultaneously computed to determine the user’s intended movement. Cloud-based deep learning predicts four upper-limb joint motions with an average accuracy of 96.2% at a 500–550 ms response rate, suggesting that the exoskeleton operates just by human intention. In addition, an array of soft pneumatics assists the intended movements by providing 897 newtons of force while generating a displacement of 87 mm at maximum. The intent-driven exoskeleton can reduce human muscle activities by 3.7 times on average compared to the unassisted exoskeleton.
年龄增长和中风导致肌肉骨骼力量下降,从而降低了使用上肢完成日常人类任务的能力。在此,我们介绍一种智能上肢外骨骼系统,该系统利用深度学习预测人类增强力量的意图。嵌入式软性可穿戴传感器通过收集实时肌肉活动来提供感官反馈,同时通过计算来确定用户的意图动作。基于云的深度学习以 500-550 毫秒的响应速度预测了四个上肢关节的运动,平均准确率为 96.2%,这表明外骨骼只需根据人类意图进行操作。此外,软气动装置阵列可提供 897 牛顿的力,同时产生 87 毫米的最大位移,从而辅助预期运动。与无辅助外骨骼相比,意图驱动外骨骼可将人类肌肉活动平均减少 3.7 倍。
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引用次数: 0
Digitally-defined ultrathin transparent wireless sensor network for room-scale imperceptible ambient intelligence 数字定义的超薄透明无线传感器网络,实现房间规模的不可感知环境智能
IF 14.6 1区 材料科学 Q1 Engineering Pub Date : 2024-02-06 DOI: 10.1038/s41528-024-00293-4
Yunxia Jin, Mengxia Yu, Dat T. Nguyen, Xin Yang, Zhipeng Li, Ze Xiong, Chenhui Li, Yuxin Liu, Yong Lin Kong, John S. Ho
Wireless and battery-free radio-frequency (RF) sensors can be used to create physical spaces that ambiently sense and respond to human activities. Making such sensors ultra-flexible and transparent is important to preserve the aesthetics of living environments, accommodate daily activities, and functionally integrate with objects. However, existing RF sensors are unable to simultaneously achieve high transparency, flexibility, and the electrical conductivity required for remote room-scale operation. Here, we report 4.5 µm RF tag sensors achieving transparency exceeding 90% that provide capabilities in room-scale ambient wireless sensing. We develop a laser-assisted water-based adhesion-reversion process to digitally realize computer-aided RF design at scale. By individually tagging multiple objects and regions of the human body, we demonstrate multiplexed wireless tracking of human-environment interactions and physiological signals at a range of up to 8 m. These radio-frequency identification sensors open opportunities for non-intrusive wireless sensing of daily living spaces for applications in health monitoring and elderly care.
无线和免电池射频(RF)传感器可用于创建能感知和响应人类活动的物理空间。要保持生活环境的美感、适应日常活动并在功能上与物体集成,就必须使这种传感器具有超强的灵活性和透明度。然而,现有的射频传感器无法同时实现高透明度、灵活性和远程房间级操作所需的导电性。在此,我们报告了透明度超过 90% 的 4.5 µm 射频标签传感器,为房间级环境无线传感提供了能力。我们开发了一种激光辅助水基附着力还原工艺,以数字方式实现计算机辅助射频设计的规模化。通过对人体的多个物体和区域进行单独标记,我们展示了在最远 8 米的范围内对人与环境的互动和生理信号进行多路复用无线跟踪。这些射频识别传感器为日常生活空间的非侵入式无线传感提供了机会,可应用于健康监测和老年人护理。
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引用次数: 0
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npj Flexible Electronics
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