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Revolutionizing wearable technology: advanced fabrication techniques for body-conformable electronics 革命性的可穿戴技术:适合人体的电子产品的先进制造技术
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-12-04 DOI: 10.1038/s41528-024-00370-8
Ruilai Wei, Haotian Li, Zhongming Chen, Qilin Hua, Guozhen Shen, Kai Jiang
With the increasing demand for wearable electronic products, there is a pressing need to develop electronic devices that seamlessly conform to the contours of the human body while delivering excellent performance and reliability. Traditional rigid electronic fabrication technologies fall short of meeting these requirements, necessitating the exploration of advanced flexible fabrication technologies that offer new possibilities for designing and fabricating flexible and stretchable electronic products, particularly in wearable devices. Over time, the continuous development of innovative fabrication techniques has ushered in significant improvements in the design freedom, lightweight, seamless integration, and multifunctionality of wearable electronics. Here, we provide a comprehensive overview of the advancements facilitated by advanced fabrication technology in wearable electronics. It specifically focuses on key fabrication methods, including printed electronics fabrication, soft transfer, 3D structure fabrication, and deformation fabrication. By highlighting these advancements, it sheds light on the challenges and prospects for further development in wearable electronics fabrication technologies. The introduction of advanced fabrication technologies has revolutionized the landscape of wearable/conformable electronics, expanding their application domains, streamlining system complexity associated with customization, manufacturing, and production, and opening up new avenues for innovation and development of body-conformable electronics.
随着人们对可穿戴电子产品的需求不断增加,迫切需要开发出无缝符合人体轮廓的电子设备,同时提供卓越的性能和可靠性。传统的刚性电子制造技术无法满足这些要求,因此有必要探索先进的柔性制造技术,为设计和制造柔性和可拉伸电子产品提供新的可能性,特别是在可穿戴设备中。随着时间的推移,创新制造技术的不断发展,在可穿戴电子产品的设计自由度、轻量化、无缝集成和多功能方面取得了重大进展。在这里,我们全面概述了先进制造技术在可穿戴电子产品中的应用。它特别侧重于关键的制造方法,包括印刷电子制造,软转移,3D结构制造和变形制造。通过强调这些进步,它揭示了可穿戴电子制造技术进一步发展的挑战和前景。先进制造技术的引入彻底改变了可穿戴/可穿戴电子产品的格局,扩展了它们的应用领域,简化了与定制、制造和生产相关的系统复杂性,并为可穿戴电子产品的创新和发展开辟了新的途径。
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引用次数: 0
Ag@polydopamine-functionalized borate ester-linked chitosan hydrogel integrates monitoring with wound healing for epidermal sensor Ag@polydopamine-functionalized硼酸酯连接壳聚糖水凝胶集成监测伤口愈合表皮传感器
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-30 DOI: 10.1038/s41528-024-00366-4
Wei Shi, Hui Li, Chengsheng Xu, Gaoyi Wu, Jing Chen, Jinyong Zhang, Lixin Liang, Qingyang Wu, Yongsheng Liang, Guanglin Li, Wei Tang
Flexible sensors are promising candidates in personalized healthcare, while desired sensors that allow implantation for biomedical applications with optimal sensing and favorable biological properties remain challenges. Here, a multifunctional hydrogel sensor was developed with gallic acid-modified chitosan (CSGA) and 3-carboxyphenylboronic acid-modified chitosan (CSPBA) by encapsulating Ag-decorated polydopamine (Ag@PDA) nanoparticles, namely Ag@PDA-(CSPBA/CSGA). The optimized hydrogel sensor showed desired sensitivity (gauge factor = 2.49), a rapid response/recovery time of 263 ms and good durability. Due to the presence of abundant reactive groups within Ag@PDA-(CSPBA/CSGA), the hydrogel sensor exhibited a comprehensive performance of self-healing, tissue adhesiveness, antioxidative activity, and antibacterial effects against Escherichia coli (92.76%) and Staphylococcus aureus (98.08%). Moreover, the hydrogel sensor could be utilized as a wound dressing, facilitating accelerated wound closure and tissue regeneration. Both subtle activities and large-scale movements could be monitored and distinguished by the hydrogel sensor. This study provides a promising epidermal sensor that offers multifunctionality for health monitoring and wound management.
柔性传感器是个性化医疗保健中很有前途的候选者,而允许植入具有最佳传感和有利生物特性的生物医学应用的传感器仍然是挑战。本文以没食子酸修饰壳聚糖(CSGA)和3-羧基苯基硼酸修饰壳聚糖(CSPBA)为材料,包封ag修饰的聚多巴胺(Ag@PDA)纳米粒子Ag@PDA-(CSPBA/CSGA),制备了多功能水凝胶传感器。优化后的水凝胶传感器具有理想的灵敏度(测量因子= 2.49)、263 ms的快速响应/恢复时间和良好的耐用性。由于Ag@PDA-(CSPBA/CSGA)中存在丰富的反应基团,该水凝胶传感器对大肠杆菌(92.76%)和金黄色葡萄球菌(98.08%)具有自愈、组织粘附、抗氧化和抗菌等综合性能。此外,水凝胶传感器可以用作伤口敷料,促进伤口愈合和组织再生。水凝胶传感器可以监测和区分细微的活动和大规模的运动。该研究提供了一种具有多种功能的表皮传感器,可用于健康监测和伤口管理。
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引用次数: 0
Stretchable nanogenerator with micro-nano hierarchical interfaces for self-powered biometric authentication 具有微纳分层界面的可伸缩纳米发电机,用于自供电生物识别身份验证
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-26 DOI: 10.1038/s41528-024-00367-3
Hai-Tao Deng, Yi-Xuan Xia, Yu-Chi Liu, Beomjoon Kim, Xiao-Sheng Zhang
Multifunctional integration and heterogeneous surface integration are two crucial challenges in the in-depth use and development of triboelectric nanogenerators (TENGs) in the wearable electronic field. A promising solution is to develop stretchable TENGs (STENG), which have the potential for microenergy supply and self-powered sensing. The key challenge is to endow its functional components with good deformability and realize heterogeneous surface integration. Herein, we proposed a fully stretchable, surface adaptable TENG using stretchable micro-nano hierarchical friction interfaces. It integrated microenenrgy supply and multifunctional self-powered sensing (i.e., bend, force, and frequency sensing) abilities successfully. The highly-linear sensing abilities endows the STENG with a good biometric ability. As an application, a STENG array based-stretchable wearable keyboard was proposed. It identified dynamic keystroke motions of all users with a Support Vector Machine, with a high accuracy of 93.21%. Besides, the intruders who were not sampled were distinguished from users, with an accuracy of 81.50%.
多功能集成和异质表面集成是三电纳米发电机(TENGs)在可穿戴电子领域深入应用和发展的两大关键挑战。一个有前景的解决方案是开发可拉伸的 TENG(STENG),它具有微能量供应和自供电传感的潜力。关键的挑战在于赋予其功能部件良好的变形能力,并实现异质表面集成。在此,我们利用可拉伸的微纳分层摩擦界面,提出了一种完全可拉伸、表面可适应的 TENG。它成功集成了微能源供应和多功能自供电传感(即弯曲、力和频率传感)能力。高线性传感能力赋予 STENG 良好的生物识别能力。作为一种应用,提出了一种基于 STENG 阵列的可伸缩可穿戴键盘。它利用支持向量机识别了所有用户的动态按键动作,准确率高达 93.21%。此外,还将未被采样的入侵者与用户区分开来,准确率为 81.50%。
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引用次数: 0
Kinetic liquid metal synthesis of flexible 2D conductive oxides for multimodal wearable sensing 用于多模态可穿戴传感的柔性二维导电氧化物的动力学液态金属合成
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-23 DOI: 10.1038/s41528-024-00371-7
Md Saifur Rahman, Simon A. Agnew, Samuel W. Ong, William J. Scheideler
Transparent conducting oxides (TCOs) are crucial for high-performance displays, solar cells, and wearable sensors. However, their high process temperatures and brittle nature have hindered their use in flexible electronics. In this paper, we overturn these limitations by harnessing Cabrera-Mott oxidation to fabricate large-area, two-dimensional (2D) transparent electrodes via liquid metal printing. Our robotic, vacuum-free process deposits ultrathin (2–10 nm) indium tin oxide (ITO) with exceptional flexibility, transparency (>95%) and conductivity (>1300 S/cm) by utilizing hypoeutectic In-Sn alloys to print at <140 °C. Detailed characterization reveals the efficacy of Sn-doping and high crystallinity with large, platelike grains. The ultrathin nature enhances bending strain tolerance and scratch resistance, exceeding durability of PEDOT and offering low contact impedance to skin comparable to Ag/AgCl. We implement 2D ITO in synchronous, multimodal electrocardiography (ECG) and pulse plethysmography (PPG) measurements. This order-of-magnitude improvement to printed TCOs could enable wearable biometrics and display-integrated sensors.
透明导电氧化物(TCO)对于高性能显示器、太阳能电池和可穿戴传感器至关重要。然而,它们的加工温度高且易碎,阻碍了它们在柔性电子器件中的应用。在本文中,我们利用卡布雷拉-莫特氧化技术,通过液态金属印刷制造出大面积、二维(2D)透明电极,从而颠覆了这些限制。我们的机器人无真空工艺利用次共晶铟锡合金在 140 °C 下打印,沉积出超薄(2-10 nm)的氧化铟锡(ITO),具有优异的柔韧性、透明度(95%)和导电性(1300 S/cm)。详细的特性分析表明了掺杂锡的功效以及大晶粒、板状晶粒的高结晶性。其超薄特性增强了弯曲应变耐受性和抗划伤性,耐久性超过了 PEDOT,并提供了与 Ag/AgCl 相当的低皮肤接触阻抗。我们在同步多模态心电图(ECG)和脉搏胸压计(PPG)测量中使用了二维 ITO。这种对印刷 TCO 的数量级改进可实现可穿戴生物识别和显示集成传感器。
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引用次数: 0
Autonomous self-healing in a stretchable polybutadiene-based urethane and eutectic gallium indium conductive composite 可拉伸聚丁二烯基聚氨酯和共晶镓铟导电复合材料中的自主自愈功能
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-22 DOI: 10.1038/s41528-024-00368-2
Tran Duc Khanh, Jinho Joo, Jong-Woong Kim
In the burgeoning field of wearable electronics, flexible and durable conductors that can maintain consistent electrical properties under various conditions are critically needed. This research introduces a novel composite material comprising eutectic gallium-indium (EGaIn) and a polybutadiene-based urethane (PBU) specifically designed to address this challenge. EGaIn, renowned for its superior conductivity due to its liquid state at room temperature, is strategically combined with PBU, which offers inherent flexibility and remarkable self-healing capabilities derived from reversible Diels–Alder reactions. Additionally, the composite maintains exceptional electrical resistance stability, withstanding mechanical strains up to 135% without compromising performance. The material’s self-healing capability is attributed to the autonomous mending properties of EGaIn and the reversible Diels–Alder reactions in the PBU matrix. The result is an efficient restoration of the composite’s original properties upon incurring damage. Furthermore, the composite’s adaptability is showcased through its printability, allowing for precise patterning conducive to custom-designed wearable devices.
在蓬勃发展的可穿戴电子设备领域,迫切需要能在各种条件下保持稳定电气性能的柔性耐用导体。本研究介绍了一种新型复合材料,由共晶镓铟 (EGaIn) 和聚丁二烯基聚氨酯 (PBU) 组成,专门用于应对这一挑战。EGaIn 因其在室温下的液态而以其卓越的导电性而闻名,它与 PBU 战略性地结合在一起,PBU 具有固有的柔韧性,并通过可逆的 Diels-Alder 反应而具有显著的自愈能力。此外,这种复合材料还能保持优异的电阻稳定性,在不影响性能的情况下承受高达 135% 的机械应变。这种材料的自愈合能力归功于 EGaIn 的自主修复特性和 PBU 基体中的可逆 Diels-Alder 反应。因此,复合材料在受到损害时能有效恢复其原有性能。此外,这种复合材料的适应性还体现在它的可印刷性上,允许精确的图案设计,有利于定制设计可穿戴设备。
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引用次数: 0
Tailoring threshold voltage of R2R printed SWCNT thin film transistors for realizing 4 bit ALU 调整 R2R 印刷 SWCNT 薄膜晶体管的阈值电压以实现 4 位 ALU
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-20 DOI: 10.1038/s41528-024-00369-1
Sajjan Parajuli, Younsu Jung, Sagar Shrestha, Jinhwa Park, Chanyeop Ahn, Kiran Shrestha, Bijendra Bishow Maskey, Tae-Yeon Cho, Ji-Ho Eom, Changwoo Lee, Jeong-Taek Kong, Byung-Sung Kim, Taik-Min Lee, SoYoung Kim, Gyoujin Cho
Despite the roll-to-roll (R2R) gravure printing method emerging as an alternative sustainable technology for fabricating logic circuits based on p- and n-types of single-walled carbon nanotube thin film transistors (p,n-SWCNT-TFTs), the wide variation of large threshold voltage (Vth > ~8) in the R2R printed p,n-SWCNT-TFTs prevents the integration of complementary logic circuit. Here, the Vth variation of the p,n-SWCNT-TFTs was narrowed down by developing a method of using the first gravure roll with the minimized superposition error (< ±40 µm) of engraved registration marks and implementing the R2R doping process for tailoring the Vth using polymer-based p- and n-doping inks. Through those two methods, the R2R printed the p,n-SWCNT-TFTs was tailored to shift Vth to near ±2.7 V and reduce Vth variation to ±1.6 V while the noise margin was improved by 24% so that a large number of R2R printed logic gates could be integrated with clear logic levels at ±10 V of operation voltage. Based on the tailored p,n-SWCNT-TFTs, a fully R2R printed 4-bit arithmetic and logic unit was successfully demonstrated by integrating 156 p,n-SWCNT-TFTs.
尽管卷对卷(R2R)凹版印刷方法已成为基于 p 型和 n 型单壁碳纳米管薄膜晶体管(p,n-SWCNT-TFTs)制造逻辑电路的另一种可持续技术,但 R2R 印刷的 p,n-SWCNT-TFTs 的阈值电压(Vth > ~8)变化很大,阻碍了互补逻辑电路的集成。在此,我们开发了一种方法,即使用雕刻套准标记的叠加误差最小(< ±40 µm)的第一凹版辊,并使用聚合物基 p 和 n 掺杂油墨实施 R2R 掺杂工艺以定制 Vth,从而缩小了 p、n-SWCNT-TFT 的 Vth 变化。通过这两种方法,印刷在 p、n-SWCNT-TFT 上的 R2R 被定制为将 Vth 值移至接近 ±2.7 V,并将 Vth 值变化降低到 ±1.6 V,同时将噪声裕度提高了 24%,这样就可以集成大量 R2R 印刷逻辑门,并在 ±10 V 工作电压下具有清晰的逻辑电平。基于定制的 p、n-SWCNT-TFT,通过集成 156 个 p、n-SWCNT-TFT,成功演示了完全 R2R 印刷的 4 位算术和逻辑单元。
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引用次数: 0
Flash synthesis of high-performance and color-tunable copper(I)-based cluster scintillators for efficient dynamic X-ray imaging 用于高效动态 X 射线成像的高性能、颜色可调的铜(I)基簇闪烁体的闪速合成
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-16 DOI: 10.1038/s41528-024-00365-5
Wenjing Zhao, Yanze Wang, Ruizi Li, Xiaowang Liu, Wei Huang
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引用次数: 0
Full textile-based body-coupled electrical stimulation for wireless, battery-free, and wearable bioelectronics 基于全纺织品的人体耦合电刺激,实现无线、免电池和可穿戴生物电子技术
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-14 DOI: 10.1038/s41528-024-00364-6
Myunghwan Song, Junyoung Moon, Hyungseok Yong, Hyeonhui Song, Juneil Park, Jiwoong Hur, Dongchang Kim, Kyungtae Park, Sungwon Jung, Gyeongmo Kim, Sangeui Lee, Deokjae Heo, Kyunghwan Cha, Patrick T. J. Hwang, Jinkee Hong, Giuk Lee, Sangmin Lee
Electrical stimulation is effective for various therapeutic applications; however, to increase convenience, it is crucial to eliminate generators and batteries for wireless power transmission. This paper presents a full textile-based body-coupled electrical stimulation (BCES) system designed for wireless electrical stimulation using energy loss from electronic devices and static electricity from physical activity. We developed the BCES socks by knitting conductive threads to ensure stability and comfort. BCES socks generate electric fields ranging from tens to hundreds of millivolts per millimeter, which are sufficient to activate muscle fibers. Experimental and computational analyses confirmed the effective concentration of the electric fields. Human trials demonstrated significant improvements in exercise performance, with a 21.47% increase in calf raise frequency, an 11.97% increase in repetition count, and a 6.25% reduction in muscle fatigue. These results indicate the potential of BCES socks as a practical battery-free solution for enhancing muscle activity and reducing fatigue.
电刺激在各种治疗应用中都很有效;然而,为了提高便利性,关键是要消除用于无线输电的发电机和电池。本文介绍了一种基于全纺织品的身体耦合电刺激(BCES)系统,该系统设计用于利用电子设备的能量损耗和身体活动产生的静电进行无线电刺激。我们通过编织导电线开发了 BCES 袜子,以确保其稳定性和舒适性。BCES 袜子能产生每毫米数十至数百毫伏的电场,足以激活肌肉纤维。实验和计算分析证实了电场的有效浓度。人体试验表明,运动表现有了明显改善,小腿抬高次数增加了 21.47%,重复次数增加了 11.97%,肌肉疲劳减少了 6.25%。这些结果表明,BCES 运动袜作为一种实用的无电池解决方案,具有增强肌肉活动和减轻疲劳的潜力。
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引用次数: 0
Unobstructive and safe-to-wear watt-level wireless charger 无障碍、可安全佩戴的瓦特级无线充电器
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-08 DOI: 10.1038/s41528-024-00363-7
Sangjun Kim, Jonathan Wells, Sarnab Bhattacharya, Hamsi Nathan, Jiaming He, Isabella Tubilla, Heeyong Huh, Pooja Kakani, Ali Farshkaran, Praveenkum Pasupathy, Jianshi Zhou, Emily Porter, Nathan Lazarus, Nanshu Lu
A wearable microgrid that centralizes and distributes harvested energy across different body regions can optimize power utilization and reduce overall battery weight. This setup underscores the importance of developing cable-free wireless power transfer (WPT) systems for mobile and portable devices to eliminate the risks posed by wired connections, especially in dynamic and hazardous environments. We introduce a thin, stretchable, and safe hand band capable of watt-level wireless charging through the widely adopted Qi protocol operating at 130 kHz. The implementation of non-adhesive fabric encapsulation serves to protect the 50-μm-thin spiral copper antenna from mechanical strain, ensuring an overall hand band stretchability of 50%. We also create a stretchable “Ferrofabric”, characterized by a magnetic permeability of 11.3 and a tensile modulus of 75.3 kPa, that provides magnetic shielding for the antenna without compromising wearability. The “Ferrofabric” improves the coil inductance but induces core loss in AC application. By fully understanding and managing loss mechanisms such as the skin effect, proximity effect, core loss, and joule heating, we achieve a wireless charging efficiency of 71% and power delivery of 3.81 W in the kHz frequency range. Our WPT hand band is unobstructive to hand motion and can charge a handheld smartphone as fast as a desktop charger or power a battery-free chest-laminated e-tattoo sensor, with well-managed thermal and electromagnetic safety. Through a holistic electromagnetic, structural, and thermal design, our device culminates in a safe, rugged, and versatile solution for wearable WPT systems.
可穿戴微电网可将采集到的能量集中并分配到身体的不同区域,从而优化电能利用率并减轻电池总重量。这种设置强调了为移动和便携设备开发无线缆无线电力传输(WPT)系统的重要性,以消除有线连接带来的风险,尤其是在动态和危险环境中。我们介绍了一种轻薄、可拉伸且安全的手带,它能够通过广泛采用的工作频率为 130 kHz 的 Qi 协议进行瓦特级无线充电。采用非粘性织物封装可保护 50 微米薄的螺旋铜天线免受机械应变的影响,确保手环整体可拉伸 50%。我们还创造了一种可拉伸的 "Ferrofabric",其磁导率为 11.3,拉伸模量为 75.3 kPa,可为天线提供磁屏蔽,同时不影响佩戴性。Ferrofabric "提高了线圈电感,但在交流应用中会导致磁芯损耗。通过充分了解和管理损耗机制,如趋肤效应、邻近效应、磁芯损耗和焦耳热,我们实现了 71% 的无线充电效率和千赫频率范围内 3.81 W 的功率输出。我们的 WPT 手带不妨碍手部运动,可以像台式充电器一样快速地为手持智能手机充电,或为无电池的胸前贴片电子纹身传感器供电,同时具有良好的热管理和电磁安全性。通过全面的电磁、结构和热设计,我们的设备最终成为安全、坚固和多功能的可穿戴 WPT 系统解决方案。
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引用次数: 0
Combustion-assisted low-temperature ZrO2/SnO2 films for high-performance flexible thin film transistors 用于高性能柔性薄膜晶体管的燃烧辅助低温 ZrO2/SnO2 薄膜
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-02 DOI: 10.1038/s41528-024-00362-8
Bongho Jang, Junil Kim, Jieun Lee, Geuntae Park, Gyuwon Yang, Jaewon Jang, Hyuk-Jun Kwon
We developed high-performance flexible oxide thin-film transistors (TFTs) using SnO2 semiconductor and high-k ZrO2 dielectric, both formed through combustion-assisted sol-gel processes. This method involves the exothermic reaction of fuels and oxidizers to produce high-quality oxide films without extensive external heating. The combustion ZrO2 films were revealed to have an amorphous structure with a higher proportion of oxygen corresponding to the oxide network, which contributes to the low leakage current and frequency-independent dielectric properties. The ZrO2/SnO2 TFTs fabricated on flexible substrates using combustion synthesis exhibited excellent electrical characteristics, including a field-effect mobility of 26.16 cm2/Vs, a subthreshold swing of 0.125 V/dec, and an on/off current ratio of 1.13 × 106 at a low operating voltage of 3 V. Furthermore, we demonstrated flexible ZrO2/SnO2 TFTs with robust mechanical stability, capable of withstanding 5000 cycles of bending tests at a bending radius of 2.5 mm, achieved by scaling down the device dimensions.
我们利用二氧化硫(SnO2)半导体和高k ZrO2电介质开发出了高性能柔性氧化物薄膜晶体管(TFT),这两种物质都是通过燃烧辅助溶胶-凝胶工艺形成的。这种方法涉及燃料和氧化剂的放热反应,无需大量外部加热即可生成高质量的氧化物薄膜。燃烧 ZrO2 薄膜具有无定形结构,氧化物网络中氧的比例较高,这有助于实现低漏电流和与频率无关的介电性能。利用燃烧合成法在柔性衬底上制造的 ZrO2/SnO2 TFT 具有出色的电气特性,包括 26.16 cm2/Vs 的场效应迁移率、0.125 V/dec 的阈下摆动和 3 V 低工作电压下 1.13 × 106 的开/关电流比。此外,我们还展示了具有强大机械稳定性的柔性 ZrO2/SnO2 TFT,它能在弯曲半径为 2.5 mm 的条件下经受住 5000 次弯曲测试,这是通过缩小器件尺寸实现的。
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引用次数: 0
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npj Flexible Electronics
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