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Analytic modeling and validation of strain in textile-based OLEDs for advanced textile display technologies 先进纺织品显示技术中基于纺织品的有机发光二极管应变的分析建模和验证
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-30 DOI: 10.1038/s41528-024-00361-9
Junwoo Lee, Chang-Yeon Gu, Jaehyeock Chang, Eun Hae Cho, Taek-Soo Kim, Kyung Cheol Choi
In the IoT era, the demand for wearable displays is rapidly growing, catalyzing the advancement of research into textile-based organic light-emitting diodes (OLEDs). This growing interest stems particularly from the inherent flexibility of textile-based OLEDs1,2, allowing for seamless integration into the dynamic and interactive functionalities of cutting-edge wearable technology, alongside their superior electrical performance. The durability and mechanical robustness of these displays, especially under physical stress and deformation, are critical to their practical application and longevity. Thus, understanding and enhancing the mechanical properties of textile-based OLEDs is paramount for their successful integration into wearable technologies. However, many studies assessing the mechanical properties of OLEDs have predominantly relied on simplistic bending test outcomes determined by the radius, often neglecting or insufficiently analyzing the strain exerted on the OLEDs atop textile substrates in relation to curvature of these devices. Existing analyses typically presume pure bending, though such an assumption leads to considerable errors in strain estimations, making such approaches problematic if the goal is practical application in actual wearable display products. To address these limitations, an analytic model that includes a comprehensive energy equation is introduced, considering the stretching energy, bending energy, and shear energy of each layer composing the textile substrate. This holistic approach provides a novel formula specifically designed to calculate the top surface strain of textile substrates. Robust validation of this formula is conducted by comparing its results with strain measurements obtained from digital image correlation (DIC) and finite element analysis (FEA) outcomes from ANSYS across various bending radii (or equivalently, curvatures). The close alignment of the calculated strain values with those derived from DIC and FEA not only underscores the precision of this formula but also highlights its significant potential for enhancing the designs and functionalities of future wearable display technologies under real-world conditions.
在物联网时代,对可穿戴显示器的需求迅速增长,促进了对基于纺织品的有机发光二极管(OLED)的研究。这种日益增长的兴趣主要源于基于纺织品的有机发光二极管固有的灵活性1,2,这种灵活性使其能够无缝集成到尖端可穿戴技术的动态和交互功能中,同时还具有卓越的电气性能。这些显示器的耐用性和机械坚固性,尤其是在物理应力和变形条件下的耐用性和机械坚固性,对其实际应用和使用寿命至关重要。因此,了解并增强基于纺织品的有机发光二极管的机械性能,对于将其成功集成到可穿戴技术中至关重要。然而,许多评估 OLED 机械性能的研究主要依赖于由半径确定的简单弯曲测试结果,往往忽视或未充分分析纺织基底上的 OLED 所受的应变与这些设备的曲率之间的关系。现有的分析通常假定是纯弯曲,但这种假定会导致应变估计出现相当大的误差,如果目标是实际应用于实际的可穿戴显示产品,那么这种方法就会出现问题。为了解决这些局限性,我们引入了一个包含综合能量方程的分析模型,其中考虑了组成纺织品基底的每一层的拉伸能、弯曲能和剪切能。这种综合方法提供了一种专门用于计算纺织品基底表面应变的新公式。通过将计算结果与数字图像相关性(DIC)和 ANSYS 的有限元分析(FEA)结果中不同弯曲半径(或等同于曲率)的应变测量值进行比较,对该公式进行了可靠的验证。计算出的应变值与数字图像相关性和有限元分析得出的应变值非常接近,这不仅强调了该公式的精确性,还突出了其在实际条件下增强未来可穿戴显示技术的设计和功能的巨大潜力。
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引用次数: 0
Fully biodegradable electrochromic display for disposable patch 用于一次性贴片的完全可生物降解的电致变色显示屏
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-29 DOI: 10.1038/s41528-024-00360-w
Se-Hun Kang, Ju-Yong Lee, Joo-Hyeon Park, Sung-Geun Choi, Sang-Ho Oh, Young-Chang Joo, Seung-Kyun Kang
Flexible and biodegradable electronics have emerged as a promising solution for escalating electronic waste issue caused by the rapid development of skin patch electronics. Fully biodegradable displays are essential for visualizing biological/physical/chemical/electrochemical signals measured by a wide range of skin patch electronics. Here we propose fully biodegradable electrochromic display providing low operating voltage and low power consumption. The biodegradable transparent conductive electrode was fabricated by transferring free-standing tungsten nanomesh onto poly lactic-co-glycolic acid substrate using electrospinning templating, minimizing damage to the substrate. Electrochromic layer was tungsten oxide which is biodegradable, and a ferrocyanide/ferricyanide redox agent was utilized as a counter electrode reaction to enhance operational stability in an aqueous electrolyte by reducing operating voltage and side reactions. This display successfully visualized diverse signals from various biodegradable electronics such as UV sensors and electrochemical transistors, and finally underwent eco-friendly degradation in phosphate-buffered saline or soil under mild conditions.
随着皮肤贴片电子设备的快速发展,柔性可生物降解电子设备已成为解决日益严重的电子垃圾问题的一种可行方案。完全可生物降解的显示屏对于可视化各种皮肤贴片电子设备测量到的生物/物理/化学/电化学信号至关重要。在此,我们提出了可完全生物降解的电致变色显示屏,它具有低工作电压和低功耗的特点。这种可生物降解的透明导电电极是利用电纺丝模板将独立的钨纳米网转移到聚乳酸-共聚乙酸基底上制成的,从而最大限度地减少了对基底的损害。电致变色层是可生物降解的氧化钨,并使用了亚铁氰化物/铁氰化物氧化还原剂作为反电极反应,通过降低工作电压和副反应来增强在水性电解质中的工作稳定性。这种显示屏成功地将紫外线传感器和电化学晶体管等各种可生物降解电子器件发出的各种信号可视化,并最终在磷酸盐缓冲盐水或土壤中进行了温和条件下的生态友好降解。
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引用次数: 0
Strain-dependent charge trapping and its impact on the operational stability of polymer field-effect transistors 应变电荷捕获及其对聚合物场效应晶体管工作稳定性的影响
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-24 DOI: 10.1038/s41528-024-00359-3
Sangsik Park, Seung Hyun Kim, Hansol Lee, Kilwon Cho
Despite recent dramatic improvements in the electronic characteristics of stretchable organic field-effect transistors (FETs), their low operational stability remains a bottleneck for their use in practical applications. Here, the operational stability, especially the bias-stress stability, of semiconducting polymer-based FETs under various tensile strains is investigated. Analyses on the structure of stretched semiconducting polymer films and spectroscopic quantification of trapped charges within them reveal the major cause of the strain-dependent bias-stress instability of the FETs. Devices with larger strains exhibit lower stability than those with smaller strains because of the increased water content, which is accompanied by the formation of cracks and nanoscale cavities in the semiconducting polymer film as results of the applied strain. The strain-dependence of bias-stress stability of stretchable OFETs can be eliminated by passivating the devices to avoid penetration of water molecules. This work provides new insights for the development of bias-stable stretchable OFETs.
尽管可拉伸有机场效应晶体管(FET)的电子特性最近有了显著改善,但其较低的工作稳定性仍然是其实际应用的瓶颈。本文研究了基于半导体聚合物的场效应晶体管在各种拉伸应变下的工作稳定性,尤其是偏压稳定性。对拉伸半导体聚合物薄膜结构的分析以及对其内部俘获电荷的光谱量化揭示了场效应晶体管随应变变化的偏压不稳定性的主要原因。应变较大的器件比应变较小的器件稳定性要低,原因是含水量增加,同时在半导体聚合物薄膜中形成裂缝和纳米级空腔,这是施加应变的结果。通过对器件进行钝化以避免水分子渗透,可以消除可拉伸 OFET 偏压稳定性的应变依赖性。这项研究为开发偏压稳定的拉伸型 OFET 提供了新的思路。
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引用次数: 0
Flexible TiO2-WO3−x hybrid memristor with enhanced linearity and synaptic plasticity for precise weight tuning in neuromorphic computing 具有增强线性和突触可塑性的柔性 TiO2-WO3-x 混合记忆晶体管,可用于神经形态计算中的精确权重调整
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-22 DOI: 10.1038/s41528-024-00356-6
Jianyong Pan, Hao Kan, Zhaorui Liu, Song Gao, Enxiu Wu, Yang Li, Chunwei Zhang
Tungsten oxide (WO3)-based memristors show promising applications in neuromorphic computing. However, single-layer WO3 memristors suffer from issues such as weak memory performance and nonlinear conductance variations. In this work, a functional layer based on the hybrids of WO3−x and TiO2 is proposed for constructing flexible memristors featuring outstanding synaptic characteristics. Applying diverse electrical stimulations to the memristor enables a range of synaptic functions, elucidating its conduction mechanism through the conductive filament model. The incorporation of TiO2 not only enhances the memristor’s memory characteristics but makes its conductance more linear, symmetrical and uniform during the long-term changes. Furthermore, in view of the enhanced device performance by TiO2 doping, the potential of this device for simple behavioral simulation and processing of complex computing problems is explored. The “learning-forgetting-relearning” characteristics and device integrability are visually demonstrated. Applying the device to a convolutional neural network, the recognition accuracy of MNIST handwritten digits reaches 98.7%.
基于氧化钨(WO3)的忆阻器在神经形态计算中的应用前景广阔。然而,单层 WO3 记忆晶体管存在记忆性能弱和非线性电导变化等问题。本研究提出了一种基于 WO3-x 和 TiO2 混合体的功能层,用于构建具有出色突触特性的柔性忆阻器。对该忆阻器施加不同的电刺激可实现一系列突触功能,并通过导电丝模型阐明了其传导机制。二氧化钛的加入不仅增强了忆阻器的记忆特性,还使其在长期变化过程中的传导更加线性、对称和均匀。此外,鉴于掺杂 TiO2 增强了器件性能,该器件在简单行为模拟和复杂计算问题处理方面的潜力也得到了探索。该器件的 "学习-遗忘-再学习 "特性和可集成性得到了直观的展示。将该器件应用于卷积神经网络,MNIST 手写数字的识别准确率达到 98.7%。
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引用次数: 0
Real-time deep learning-assisted mechano-acoustic system for respiratory diagnosis and multifunctional classification 用于呼吸诊断和多功能分类的实时深度学习辅助机械声学系统
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-21 DOI: 10.1038/s41528-024-00355-7
Hee Kyu Lee, Sang Uk Park, Sunga Kong, Heyin Ryu, Hyun Bin Kim, Sang Hoon Lee, Danbee Kang, Sun Hye Shin, Ki Jun Yu, Juhee Cho, Joohoon Kang, Il Yong Chun, Hye Yun Park, Sang Min Won
Epidermally mounted sensors using triaxial accelerometers have been previously used to monitor physiological processes with the implementation of machine learning (ML) algorithm interfaces. The findings from these previous studies have established a strong foundation for the analysis of high-resolution, intricate signals, typically through frequency domain conversion. In this study we integrate a wireless mechano-acoustic sensor with a multi-modal deep learning system for the real-time analysis of signals emitted by the laryngeal prominence area of the thyroid cartilage at frequency ranges up to 1 kHz. This interface provides real-time data visualization and communication with the ML server, creating a system that assesses severity of chronic obstructive pulmonary disease and analyzes the user’s speech patterns.
使用三轴加速度计的表皮安装传感器以前曾被用于监测生理过程,并实施了机器学习(ML)算法接口。这些研究结果为分析高分辨率的复杂信号奠定了坚实的基础,通常是通过频域转换。在这项研究中,我们将无线机械声学传感器与多模态深度学习系统集成在一起,用于实时分析甲状软骨喉突出部位发出的频率范围高达 1 kHz 的信号。该接口可提供实时数据可视化并与 ML 服务器进行通信,从而创建一个可评估慢性阻塞性肺病严重程度并分析用户说话模式的系统。
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引用次数: 0
Author Correction: Stretchable wireless optoelectronic synergistic patches for effective wound healing 作者更正:用于伤口有效愈合的可伸缩无线光电协同贴片
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-21 DOI: 10.1038/s41528-024-00358-4
Qian Wang, Siyuan Cai, Guang Yao, Liyuan Zhang, Wenhao Lou, Youxin Chen, Qingqing Li, Maowen Xie, Xingyi Gan, Chenzheng Zhou, Taisong Pan, Min Gao, Kangning Zhao, Zhen Cai, Yuan Lin
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引用次数: 0
Metallization of leaf-derived lignocellulose scaffolds for high-performance flexible electronics and oligodynamic disinfection 将源自树叶的木质纤维素支架金属化,用于高性能柔性电子器件和低聚消毒剂
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-18 DOI: 10.1038/s41528-024-00353-9
Rakesh Rajendran Nair, Mihai Nita-Lazar, Valeriu Robert Badescu, Cristina Iftode, Jakob Wolansky, Tobias Antrack, Hans Kleemann, Karl Leo
Vascular tubules in natural leaves form quasi-fractal networks that can be metallized. Traditional metallization techniques for these lignocellulose structures are complex, involving metal sputtering, nanoparticle solutions, or multiple chemical pretreatments. Here we present a novel, facile, and reliable method for metallizing leaf-derived lignocellulose scaffolds using silver microparticles. The method achieves properties on-par with the state-of-the-art, such as broadband optical transmittance of over 80%, sheet resistances below 1 Ω/sq., and a current-carrying capacity exceeding 6 A over a 2.5 × 2.5 cm² quasi-fractal electrode. We also demonstrate copper electrodeposition as a cost-effective approach towards fabricating such conductive, biomimetic quasi-fractals. Additionally, we show that these metallized structures can effectively eliminate pathogenic microorganisms like fecal coliforms and E. coli, which are bacterial indicators of microbiological contamination of water. We finally show that these oligodynamic properties can be significantly enhanced with a small externally applied voltage, indicating the noteworthy potential of such structures for water purification and pollution control.
天然树叶中的维管形成了可金属化的准分形网络。这些木质纤维素结构的传统金属化技术非常复杂,涉及金属溅射、纳米粒子溶液或多种化学预处理。在这里,我们提出了一种新颖、简便、可靠的方法,利用银微颗粒对源自树叶的木质纤维素支架进行金属化。该方法实现了与最先进方法相当的性能,如超过 80% 的宽带光学透射率、低于 1 Ω/sq 的薄片电阻,以及在 2.5 × 2.5 平方厘米准分形电极上超过 6 A 的载流能力。我们还证明了铜电沉积是制造这种导电仿生物准分形的一种具有成本效益的方法。此外,我们还展示了这些金属化结构可有效消除粪大肠菌群和大肠杆菌等病原微生物,这些细菌是水质微生物污染的细菌指标。最后,我们还展示了这些寡动力特性可以在施加少量外部电压的情况下显著增强,这表明此类结构在水净化和污染控制方面具有值得关注的潜力。
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引用次数: 0
Identification of gas-liquid two-phase flow patterns based on flexible ultrasound array and machine learning 基于柔性超声阵列和机器学习的气液两相流模式识别
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-18 DOI: 10.1038/s41528-024-00354-8
Hang Liu, Jinhui Fan, Xinyi Lin, Kai Lin, Suhao Wang, Songyuan Liu, Fei Wang, Jizhou Song
Ultrasound technology has been recognized as the mainstream approach for the identification of gas-liquid two-phase flow patterns, which holds great value in engineering domain. However, commercial rigid probes are bulky, limiting their adaptability to curved surfaces. Here, we propose a strategy for autonomous identification of flow patterns based on flexible ultrasound array and machine learning. The array features high-performance 1–3 piezoelectric composite material, stretchable serpentine wires, soft Eco-flex layers and a polydimethylsiloxane (PDMS) adhesive layer. The resulting ultrasound array exhibits excellent electromechanical characteristics and offers a large stretchability for an intimate interfacial contact to curved surface without the need of ultrasound coupling agents. We demonstrated that the flexible ultrasound array combined with machine learning can accurately identify gas-liquid two-phase flow patterns, in a circular pipeline. This work presents an effective tool for recognizing gas-liquid two-phase flow patterns, offering engineering opportunities in petroleum extraction and natural gas transportation.
超声技术已被公认为识别气液两相流模式的主流方法,在工程领域具有重要价值。然而,商用刚性探头体积庞大,限制了其对曲面的适应性。在此,我们提出了一种基于柔性超声阵列和机器学习的流动模式自主识别策略。该阵列采用高性能 1-3 压电复合材料、可拉伸蛇形线、柔软的 Eco-flex 层和聚二甲基硅氧烷 (PDMS) 粘合层。由此产生的超声阵列具有出色的机电特性和较大的可拉伸性,无需超声耦合剂即可与曲面进行亲密的界面接触。我们证明,柔性超声阵列与机器学习相结合,可以准确识别圆形管道中的气液两相流模式。这项工作为识别气液两相流模式提供了有效工具,为石油开采和天然气运输提供了工程机会。
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引用次数: 0
Active-type piezoelectric smart textiles with antifouling performance for pathogenic control 用于病原体控制的具有防污性能的主动型压电智能纺织品
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-09 DOI: 10.1038/s41528-024-00350-y
Su Eon Lee, Hanna Lee, Jang Hwan Kim, Jae Chul Park, Sooah Kyung, Hayoung Choi, Su Hyun Baek, Jun Hyun Park, Sohyun Park, Jeong-Min Kim, Hye-Jun Jo, Seung Hyeon Cho, Jiwoong Kim, Hojun Kim, Seung Ho Han, Jun Kyun Oh, Bong Hoon Kim
Recently, an investigation into preventive measures for coronavirus disease 2019 (COVID-19) has garnered considerable attention. Consequently, strategies for the proactive prevention of viral pathogens have also attracted significant interest in the field of wearable devices and electronic textiles research, particularly due to their potential applications in personal protective equipment. In this study, we introduce smart textiles designed with optimized piezoelectric devices that exhibit antifouling performance against microorganisms and actively inactivate viruses. These active-type smart textiles, which incorporate advanced lead zirconate titanate (PZT) ceramics, a stretchable interconnector array, and polymeric fabric, demonstrate effective antifouling capabilities, detaching approximately 90% of Escherichia coli and 75% of SARS-CoV-2. Furthermore, they inactivate viruses, releasing ~26.8 ng of N protein from ruptured SARS-CoV-2, using ultrasonic waves within the wearable platform. Experimental results show that piezoelectric smart textiles significantly reduce the spread of COVID-19 by leveraging the electrical and acoustic properties of PZT ceramics.
最近,对 2019 年冠状病毒疾病(COVID-19)预防措施的调查引起了广泛关注。因此,主动预防病毒病原体的策略也引起了可穿戴设备和电子纺织品研究领域的极大兴趣,特别是由于其在个人防护设备中的潜在应用。在本研究中,我们介绍了采用优化压电器件设计的智能纺织品,它们具有抗微生物和主动灭活病毒的防污性能。这些主动型智能纺织品采用了先进的锆钛酸铅(PZT)陶瓷、可拉伸互联器阵列和聚合织物,具有有效的防污能力,可分离约 90% 的大肠杆菌和 75% 的 SARS-CoV-2 病毒。此外,它们还利用可穿戴平台内的超声波灭活病毒,从破裂的 SARS-CoV-2 中释放出约 26.8 纳克的 N 蛋白。实验结果表明,压电智能纺织品利用 PZT 陶瓷的电学和声学特性,大大减少了 COVID-19 的传播。
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引用次数: 0
Stretchable wireless optoelectronic synergistic patches for effective wound healing 用于伤口有效愈合的可伸缩无线光电协同贴片
IF 12.3 1区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-10-08 DOI: 10.1038/s41528-024-00351-x
Qian Wang, Siyuan Cai, Guang Yao, Liyuan Zhang, Wenhao Lou, Youxin Chen, Qingqing Li, Maowen Xie, Xingyi Gan, Chenzheng Zhou, Taisong Pan, Min Gao, Kangning Zhao, Zhen Cai, Yuan Lin
Physiotherapies play a crucial role in noninvasive tissue engineering for wound healing. However, challenges such as the implementation of complex interventions and unsatisfactory treatment outcomes impede widespread application. Here, we proposed a stretchable and wirelessly-powered optoelectronic synergistic patch with a dual-layer serpentine wireless receiver circuit to drive the optoelectronic modulation component. Optimized structure and impedance matching enable the patch to seamlessly attach to irregular skin surfaces and operate robustly over a 30% tensile strain range. Based on Sprague-Dawley rat wound model. The wound closure rate of the optoelectronic synergistic group significantly outperformed both monointervention and blank control groups. Mechanistically, optoelectronic synergistic intervention enhances the secretion of vascular endothelial marker proteins and growth factors, and stabilizes mitochondrial function during oxidative stress. Overall, the scalable amalgamation of flexible electronics, wireless transmission, and synergistic interventions promise to improve wound care.
物理疗法在促进伤口愈合的无创组织工程中发挥着至关重要的作用。然而,复杂的干预措施和不理想的治疗效果等挑战阻碍了其广泛应用。在这里,我们提出了一种可拉伸、无线供电的光电协同贴片,它采用双层蛇形无线接收电路来驱动光电调制元件。优化的结构和阻抗匹配使该贴片能够无缝附着在不规则的皮肤表面,并在 30% 的拉伸应变范围内稳定工作。基于 Sprague-Dawley 大鼠伤口模型。光电协同组的伤口闭合率明显优于单一干预组和空白对照组。从机理上讲,光电协同干预能增强血管内皮标志蛋白和生长因子的分泌,并在氧化应激过程中稳定线粒体功能。总之,灵活的电子设备、无线传输和协同干预的可扩展组合有望改善伤口护理。
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引用次数: 0
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npj Flexible Electronics
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