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Influence mechanism of government subsidy on the green transformation of coal company in China 政府补贴对中国煤炭企业绿色转型的影响机制
IF 11.7 1区 工程技术 Q1 MINING & MINERAL PROCESSING Pub Date : 2024-07-01 DOI: 10.1016/j.ijmst.2024.07.013
Xiaolei Li , Changsong Wu
The optimization of government subsidies to enhance the efficiency of coal companies’ green transformation constitutes a critical component in the pursuit of global sustainability. We investigate the influence mechanism of government subsidies on the green transformation using data from the listed coal companies in China from 2007 to 2022. According to our findings and hypothesis testing, previous government subsidies did not have a significant direct impact on coal companies’ green transformation. Nevertheless, government subsidies can help coal companies transition to greener practices by promoting innovative green initiatives. Furthermore, we confirmed an indirect route: that government subsidies enable the adoption of low-carbon initiatives, which in turn could facilitate the transition of coal companies towards green practices. In addition, we discovered that the coal company’s digitization will improve this indirect route. Thus, we propose increasing the effectiveness of government subsidies in facilitating coal companies’ transition to green practices by focusing on technological advancements and enhancing company digitalization.
优化政府补贴,提高煤炭企业绿色转型的效率,是实现全球可持续发展的关键环节。我们利用 2007 年至 2022 年中国煤炭上市公司的数据,研究了政府补贴对煤炭企业绿色转型的影响机制。根据我们的研究结果和假设检验,以往的政府补贴并没有对煤炭企业的绿色转型产生显著的直接影响。然而,政府补贴可以通过促进创新性绿色举措帮助煤炭企业向绿色转型。此外,我们还证实了一种间接途径:政府补贴能够促进低碳措施的采用,进而推动煤炭企业向绿色实践转型。此外,我们还发现,煤炭企业的数字化将改善这一间接途径。因此,我们建议通过关注技术进步和加强公司数字化,提高政府补贴在促进煤炭公司向绿色实践转型方面的有效性。
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引用次数: 0
Failure evolution and disaster prediction of rock under uniaxial compression based on non-extensive statistical analysis of electric potential 基于电势非广延性统计分析的单轴压缩下岩石的破坏演化与灾害预测
IF 11.7 1区 工程技术 Q1 MINING & MINERAL PROCESSING Pub Date : 2024-07-01 DOI: 10.1016/j.ijmst.2024.07.008
Tiancheng Shan , Zhonghui Li , Haishan Jia , Enyuan Wang , Xiaoran Wang , Yue Niu , Xin Zhang , Dong Chen , Shan Yin , Quancong Zhang
Rock failure can cause serious geological disasters, and the non-extensive statistical features of electric potential (EP) are expected to provide valuable information for disaster prediction. In this paper, the uniaxial compression experiments with EP monitoring were carried out on fine sandstone, marble and granite samples under four displacement rates. The Tsallis entropy q value of EPs is used to analyze the self-organization evolution of rock failure. Then the influence of displacement rate and rock type on q value are explored by mineral structure and fracture modes. A self-organized critical prediction method with q value is proposed. The results show that the probability density function (PDF) of EPs follows the q-Gaussian distribution. The displacement rate is positively correlated with q value. With the displacement rate increasing, the fracture mode changes, the damage degree intensifies, and the microcrack network becomes denser. The influence of rock type on q value is related to the burst intensity of energy release and the crack fracture mode. The q value of EPs can be used as an effective prediction index for rock failure like b value of acoustic emission (AE). The results provide useful reference and method for the monitoring and early warning of geological disasters.
岩石崩塌会引发严重的地质灾害,而电位(EP)的非广义统计特征有望为灾害预测提供有价值的信息。本文对细砂岩、大理石和花岗岩样品在四种位移速率下进行了带 EP 监测的单轴压缩实验。利用 EP 的 Tsallis 熵 q 值分析岩石破坏的自组织演化过程。然后通过矿物结构和断裂模式探讨了位移速率和岩石类型对 q 值的影响。提出了一种具有 q 值的自组织临界预测方法。结果表明,EPs 的概率密度函数(PDF)遵循 q-Gaussian 分布。位移速率与 q 值呈正相关。随着位移速率的增加,断裂模式发生变化,破坏程度加剧,微裂缝网络变得更加密集。岩石类型对 q 值的影响与能量释放的爆发强度和裂缝断裂模式有关。EPs 的 q 值与声发射(AE)的 b 值一样,可作为岩石破坏的有效预测指标。研究结果为地质灾害的监测和预警提供了有益的参考和方法。
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引用次数: 0
Identifying the real fracture hidden in rock microcrack zone by acoustic emission energy 利用声发射能量识别隐藏在岩石微裂缝带中的真正断裂
IF 11.7 1区 工程技术 Q1 MINING & MINERAL PROCESSING Pub Date : 2024-06-01 DOI: 10.1016/j.ijmst.2024.06.006
Yuekun Xing , Bingxiang Huang , Guangqing Zhang , Binghong Li , Hang Xu , Xuejie Jiao , Yang Yu , Taisen Han , Jinlong Chen

Identifying the real fracture of rock hidden in acoustic emission (AE) source clusters (AE-depicted microcrack zone) remains challenging and crucial. Here we revealed the AE energy (representing dissipated energy) distribution rule in the rock microcrack zone and proposed an AE-energy-based method for identifying the real fracture. (1) A set of fracture experiments were performed on granite using wedge-loading, and the fracture process was detected and recorded by AE. The microcrack zone associated with the energy dissipation was characterized by AE sources and energy distribution, utilizing our self-developed AE analysis program (RockAE). (2) The accumulated AE energy, an index representing energy dissipation, across the AE-depicted microcrack zone followed the normal distribution model (the mean and variance relate to the real fracture path and the microcrack zone width). This result implies that the nucleation and coalescence of massive cracks (i.e., real fracture generation process) are supposed to follow a normal distribution. (3) Then, we obtained the real fracture extension path by joining the peak positions of the AE energy normal distribution curve at different cross-sections of the microcrack zone. Consequently, we distinguished between the microcrack zone and the concealed real fracture within it. The deviation was validated as slight as 1–3 mm.

识别隐藏在声发射(AE)源群(AE 显示的微裂缝区)中的岩石真实断裂仍然是一项具有挑战性的关键工作。在此,我们揭示了岩石微裂缝区的声发射能量(代表耗散能量)分布规律,并提出了一种基于声发射能量的真实断裂识别方法。(1) 利用楔形加载在花岗岩上进行了一组断裂实验,并通过 AE 检测和记录了断裂过程。利用我们自主开发的 AE 分析程序(RockAE),通过 AE 源和能量分布对与能量耗散相关的微裂缝区进行了表征。(2) AE 显示的微裂缝区的累积 AE 能量(代表能量耗散的指标)遵循正态分布模型(均值和方差与实际断裂路径和微裂缝区宽度有关)。这一结果意味着大块裂纹的成核和凝聚(即真实的断裂产生过程)应该遵循正态分布。(3) 然后,我们通过连接微裂纹区不同截面上 AE 能量正态分布曲线的峰值位置,得到了真正的断裂扩展路径。因此,我们区分了微裂缝区和其中隐藏的真实断裂。经验证,偏差最小为 1-3 毫米。
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引用次数: 0
Mechanical behavior and damage constitutive model of sandstone under hydro-mechanical (H-M) coupling 水力机械(H-M)耦合作用下砂岩的力学行为和损伤构成模型
IF 11.7 1区 工程技术 Q1 MINING & MINERAL PROCESSING Pub Date : 2024-06-01 DOI: 10.1016/j.ijmst.2024.07.002
Tao Tan , Chunyang Zhang , Yanlin Zhao , Xiaoshuang Li

Underground engineering often passes through water-rich fractured rock masses, which are prone to fracture and instability under the long-term coupling of in-situ stress field and pore water (P-W) pressure, ultimately threatening the stability of underground structures. In order to explore the mechanical properties of rocks under H-M coupling, the corresponding damage constitutive (D-C) model has become the focus of attention. Considering the inadequacy of the current research on rock strength parameters, energy evolution characteristics and D-C model under H-M coupling, the mechanical properties of typical sandstone samples are discussed based on laboratory tests. The results show that the variation of characteristic stresses of sandstone under H-M coupling conforms to the normalized attenuation equation and Mohr-Coulomb (M−C) criterion. The P-W pressure mechanism of sandstone exhibits a dynamic change from softening effect to H-M fracturing effect. The closure stress is mainly provided by cohesive strength, while the initiation stress, damage stress, and peak stress are jointly dominated by cohesive strength and friction strength. In addition, residual stress is attributed to the friction strength formed by the bite of the fracture surface. Subsequently, the energy evolution characteristics of sandstone under H-M coupling were studied, and it was found that P-W pressure weakened the energy storage capacity and energy dissipation capacity of sandstone, and H-M fracturing was an important factor in reducing its energy storage efficiency. Finally, combined with energy dissipation theory and statistical damage theory, two types of D-C models considering P-W pressure are proposed accordingly, and the model parameters can be determined by four methods. The application results indicate that the proposed and modified D-C models have high reliability, and can characterize the mechanical behavior of sandstone under H-M coupling, overcome the inconvenience of existing D-C models due to excessive mechanical parameters, and can be applied to the full-range stress–strain process. The results are conducive to revealing the deformation and damage mechanisms of rocks under H-M coupling, and can provide theoretical guidance for related engineering problems.

地下工程经常经过富水断裂岩体,在原位应力场和孔隙水(P-W)压力的长期耦合作用下,易发生断裂和失稳,最终威胁地下结构的稳定性。为了探索 H-M 耦合条件下岩石的力学特性,相应的损伤构成(D-C)模型成为关注的焦点。考虑到目前对 H-M 耦合作用下岩石强度参数、能量演化特征和 D-C 模型的研究不足,本文以实验室试验为基础,探讨了典型砂岩样品的力学特性。结果表明,H-M 耦合下砂岩特征应力的变化符合归一化衰减方程和莫尔-库仑(M-C)准则。砂岩的 P-W 压力机制呈现出从软化效应到 H-M 断裂效应的动态变化。封闭应力主要由内聚强度提供,而起始应力、破坏应力和峰值应力则由内聚强度和摩擦强度共同主导。此外,残余应力归因于断裂面咬合形成的摩擦强度。随后,研究了 H-M 耦合作用下砂岩的能量演化特征,发现 P-W 压力削弱了砂岩的储能能力和耗能能力,H-M 断裂是降低其储能效率的重要因素。最后,结合能量耗散理论和统计损伤理论,相应提出了两种考虑 P-W 压力的 D-C 模型,并通过四种方法确定了模型参数。应用结果表明,提出和修正的 D-C 模型具有较高的可靠性,能够表征 H-M 耦合作用下砂岩的力学行为,克服了现有 D-C 模型因力学参数过多而带来的不便,可应用于全范围应力应变过程。其结果有利于揭示岩石在 H-M 耦合作用下的变形和破坏机理,可为相关工程问题提供理论指导。
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引用次数: 0
IFC: Editorial 国际金融公司: 编辑
IF 11.7 1区 工程技术 Q1 MINING & MINERAL PROCESSING Pub Date : 2024-06-01 DOI: 10.1016/S2095-2686(24)00087-9
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引用次数: 0
Adjustment mechanism of blasting dynamic-static action in the water decoupling charge 水上解耦装药爆破动静作用的调整机制
IF 11.7 1区 工程技术 Q1 MINING & MINERAL PROCESSING Pub Date : 2024-06-01 DOI: 10.1016/j.ijmst.2024.07.001
Hao Zhang , Xueyang Xing , Yiteng Du , Tingchun Li , Jianxin Yu , Qingwen Zhu

Water decoupling charge blasting excels in rock breaking, relying on its uniform pressure transmission and low energy dissipation. The water decoupling coefficients can adjust the contributions of the stress wave and quasi-static pressure. However, the quantitative relationship between the two contributions is unclear, and it is difficult to provide reasonable theoretical support for the design of water decoupling blasting. In this study, a theoretical model of blasting fracturing partitioning is established. The mechanical mechanism and determination method of the optimal decoupling coefficient are obtained. The reliability is verified through model experiments and a field test. The results show that with the increasing of decoupling coefficient, the rock breaking ability of blasting dynamic action decreases, while quasi-static action increases and then decreases. The ability of quasi-static action to wedge into cracks changes due to the spatial adjustment of the blast hole and crushed zone. The quasi-static action plays a leading role in the fracturing range, determining an optimal decoupling coefficient. The optimal water decoupling coefficient is not a fixed value, which can be obtained by the proposed theoretical model. Compared with the theoretical results, the maximum error in the model experiment results is 8.03%, and the error in the field test result is 3.04%.

水解耦装药爆破因其压力传递均匀、能量耗散小而在岩石破碎方面表现出色。水去耦系数可以调节应力波和准静压的贡献。然而,这两种贡献之间的定量关系并不明确,难以为水解耦爆破设计提供合理的理论支持。本研究建立了爆破压裂分区理论模型。获得了最优解耦系数的力学机理和确定方法。通过模型实验和现场测试验证了其可靠性。结果表明,随着解耦系数的增大,爆破动态作用的破岩能力减小,而准静态作用的破岩能力先增大后减小。准静作用楔入裂缝的能力因爆破孔和破碎带的空间调整而发生变化。准静态作用在压裂范围内起主导作用,决定了最佳解耦系数。最佳解耦系数并不是一个固定值,可以通过提出的理论模型得到。与理论结果相比,模型实验结果的最大误差为 8.03%,现场测试结果的误差为 3.04%。
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引用次数: 0
Failure behavior and strength model of blocky rock mass with and without rockbolts 有岩块和无岩块的块状岩体的破坏行为和强度模型
IF 11.7 1区 工程技术 Q1 MINING & MINERAL PROCESSING Pub Date : 2024-06-01 DOI: 10.1016/j.ijmst.2024.06.008
Chun Zhu , Xiansen Xing , Manchao He , Zhicheng Tang , Feng Xiong , Zuyang Ye , Chaoshui Xu

To better understand the failure behaviours and strength of bolt-reinforced blocky rocks, large scale extensive laboratory experiments are carried out on blocky rock-like specimens with and without rockbolt reinforcement. The results show that both shear failure and tensile failure along joint surfaces are observed but the shear failure is a main controlling factor for the peak strength of the rock mass with and without rockbolts. The rockbolts are necked and shear deformation simultaneously happens in bolt‑reinforced rock specimens. As the joint dip angle increases, the joint shear failure becomes more dominant. The number of rockbolts has a significant impact on the peak strain and uniaxial compressive strength (UCS), but little influence on the deformation modulus of the rock mass. Using the Winkler beam model to represent the rockbolt behaviours, an analytical model for the prediction of the strength of bolt-reinforced blocky rocks is proposed. Good agreement between the UCS values predicted by proposed model and obtained from experiments suggest an encouraging performance of the proposed model. In addition, the performance of the proposed model is further assessed using published results in the literature, indicating the proposed model can be used effectively in the prediction of UCS of bolt-reinforced blocky rocks.

为了更好地了解螺栓加固块状岩石的破坏行为和强度,对有无岩螺栓加固的块状岩石试样进行了大规模、广泛的实验室实验。结果表明,沿接合面可观察到剪切破坏和拉伸破坏,但剪切破坏是有无锚杆加固岩体峰值强度的主要控制因素。在螺栓加固的岩石试样中,螺栓缩颈和剪切变形同时发生。随着节理倾角的增大,节理剪切破坏变得更加主要。锚杆数量对峰值应变和单轴抗压强度(UCS)有显著影响,但对岩体的变形模量影响不大。利用温克勒梁模型表示岩体螺栓行为,提出了一个用于预测螺栓加固块状岩石强度的分析模型。所提模型预测的 UCS 值与实验结果之间的良好一致性表明,所提模型的性能令人鼓舞。此外,利用文献中已发表的结果进一步评估了所提模型的性能,表明所提模型可有效用于预测螺栓加固块状岩石的 UCS。
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引用次数: 0
Hydraulic fracturing behaviors of shale under coupled stress and temperature conditions simulating different burial depths 模拟不同埋藏深度的应力和温度耦合条件下的页岩水力压裂行为
IF 11.7 1区 工程技术 Q1 MINING & MINERAL PROCESSING Pub Date : 2024-06-01 DOI: 10.1016/j.ijmst.2024.06.005
Qin Zhou , Zheming Zhu , Wei Liu , Huijun Lu , Zidong Fan , Xiaofang Nie , Cunbao Li , Jun Wang , Li Ren

Fracture propagation in shale under in situ conditions is a critical but poorly understood mechanical process in hydraulic fracturing for deep shale gas reservoirs. To address this, hydraulic fracturing experiments were conducted on hollow double-wing crack specimens of the Longmaxi shale under conditions simulating the ground surface (confining pressure σcp=0, room temperature (Tr)) and at depths of 1600 m (σcp=40 MPa, Ti=70 °C) and 3300 m (σcp=80 MPa, high temperature Ti=110 °C) in the study area. High in situ stress was found to significantly increase fracture toughness through constrained microcracking and particle frictional bridging mechanisms. Increasing the temperature enhances rather than weakens the fracture resistance because it increases the grain debonding length, which dissipates more plastic energy and enlarges grains to close microdefects and generate compressive stress to inhibit microcracking. Interestingly, the fracture toughness anisotropy in the shale was found to be nearly constant across burial depths, despite reported variations with increasing confining pressure. Heated water was not found to be as important as the in situ environment in influencing shale fracture. These findings emphasize the need to test the fracture toughness of deep shales under coupled in situ stress and temperature conditions rather than focusing on either in situ stress or temperature alone.

页岩在原位条件下的裂缝扩展是深层页岩气藏水力压裂过程中的一个关键力学过程,但人们对这一过程知之甚少。为解决这一问题,在模拟地表(约束压力 σcp=0,室温 (Tr))和研究区 1600 米(σcp=40 兆帕,Ti=70 °C)和 3300 米(σcp=80 兆帕,高温 Ti=110°C)深度的条件下,对龙马溪页岩空心双翼裂缝试样进行了水力压裂实验。研究发现,高原位应力可通过约束微裂纹和颗粒摩擦架桥机制显著提高断裂韧性。温度升高会增强而不是削弱断裂韧性,因为温度升高会增加晶粒脱粘长度,从而耗散更多的塑性能,并增大晶粒以封闭微缺陷,产生压应力来抑制微裂纹。有趣的是,尽管有报告称页岩中的断裂韧性各向异性会随着封闭压力的增加而变化,但在不同埋深的页岩中,断裂韧性各向异性几乎保持不变。在影响页岩断裂方面,加热水的作用不如原位环境重要。这些发现强调了在原位应力和温度耦合条件下测试深层页岩断裂韧性的必要性,而不是仅仅关注原位应力或温度。
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引用次数: 0
A stepwise approach to enhancing flotation of low-grade zinnwaldite through the cationic/DL-2-octanol/anionic reagent combinations: Behavior and mechanism analysis 通过阳离子/DL-2-辛醇/阴离子试剂组合逐步提高低品位黝帘石的浮选效果:行为和机理分析
IF 11.7 1区 工程技术 Q1 MINING & MINERAL PROCESSING Pub Date : 2024-06-01 DOI: 10.1016/j.ijmst.2024.04.004

In order to alleviate the pressure on the supply of lithium resources, this research proposes the use of binary/ternary collectors with high selectivity and collecting ability to enhance the flotation purification of low-grade zinnwaldite ore. The binary collector is a mixture of dodecylamine polyoxyethylene ether and DL-2-octanol. A binary collector is added first, followed by sodium oleate, known as a ternary collector. Under acidic conditions, the recovery of Li2O in the concentrate was increased by 8.26% with the binary collector and 13.70% with the ternary collector, compared to the dodecylamine polyoxyethylene ether. The binary collector enhanced the dispersibility of the single collector, while co-adsorption strengthened the hydrophobic nature of the zinnwaldite surface. Consequently, zinnwaldite particles, after the application of binary collector, displayed inter-particle flocculation and attachment to bubbles within 60×10−9 m compared to other particles. Ternary collector exhibited the capacity to lower critical micelle concentration and surface tension, subsequently inducing a denser and thicker hydrophobic layer through electrostatic forces, hydrophobic interactions, and chemical reactions. The objective of this research is to facilitate the recovery of lithium resources from low-grade ores in order to meet the needs of sustainable development.

为了缓解锂资源的供应压力,本研究提出使用具有高选择性和高收集能力的二元/三元捕收剂来提高低品位锌钒铁矿的浮选提纯效果。二元捕收剂是十二胺聚氧乙烯醚和 DL-2 辛醇的混合物。先加入二元捕收剂,再加入油酸钠,称为三元捕收剂。在酸性条件下,与十二烷基胺聚氧乙烯醚相比,二元捕收剂使浓缩物中 Li2O 的回收率提高了 8.26%,三元捕收剂提高了 13.70%。二元捕收剂提高了单一捕收剂的分散性,而共吸附则加强了菱镁矿表面的疏水性。因此,与其他颗粒相比,使用二元捕集剂后的紫云英颗粒在 60×10-9 m 的范围内显示出颗粒间的絮凝和气泡附着。三元捕集剂具有降低临界胶束浓度和表面张力的能力,从而通过静电力、疏水相互作用和化学反应形成更致密、更厚的疏水层。这项研究的目的是促进从低品位矿石中回收锂资源,以满足可持续发展的需要。
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引用次数: 0
Comparison of microwave- and thermal-assisted rock fragmentation methods at different temperatures and loading rates 不同温度和装载率下微波和热辅助岩石破碎方法的比较
IF 11.7 1区 工程技术 Q1 MINING & MINERAL PROCESSING Pub Date : 2024-06-01 DOI: 10.1016/j.ijmst.2024.06.009
Wei Yao , Shuai Wang , Bangbiao Wu , Ying Xu , Kaiwen Xia

Understanding the effects of microwave irradiation and thermal treatment on the dynamic compression and fragmentation properties of rocks is essential to quantify energy consumption in rock engineering. In this study, Fangshan granite (FG) specimens were exposed to microwave irradiation and heat treatment. The damage of FG specimens induced by these two methods was compared using X-ray CT scanning and ultrasonic wave method. The temperatures of FG after microwave irradiation and thermal treatment were effectively evaluated using a newly proposed technique. A novelty method for precisely determining the geometric features of fragments is developed to estimate the fragmentation energy. Thus, the dynamic uniaxial compressive strength (UCS), the dynamic fragmentation characteristics, and the fragmentation energy of FG after these two pretreatment methods can be reasonably compared. The noticeable distinction of loading rate effect on the dynamic UCS of FG between these two pretreatment methods is first observed. A relationship is established between the dynamic UCS and the damage induced by microwave irradiation and heat treatment. Moreover, fragmentation energy fan analysis is introduced to accurately compare the fragmentation properties of FG after two pretreatment methods in dynamic compression tests.

了解微波辐照和热处理对岩石动态压缩和破碎特性的影响对于量化岩石工程中的能耗至关重要。本研究对房山花岗岩(FG)试样进行了微波辐照和热处理。使用 X 射线 CT 扫描和超声波方法比较了这两种方法对房山花岗岩试样造成的破坏。利用一种新提出的技术,有效评估了微波辐照和热处理后 FG 的温度。开发了一种精确测定碎片几何特征的新方法来估算碎片能量。因此,可以合理地比较两种预处理方法后 FG 的动态单轴抗压强度(UCS)、动态碎裂特征和碎裂能。首先观察到两种预处理方法的加载速率对 FG 动态单轴抗压强度影响的明显区别。建立了动态 UCS 与微波辐照和热处理引起的损伤之间的关系。此外,还引入了碎裂能量扇形分析法,以准确比较两种预处理方法后 FG 在动态压缩试验中的碎裂特性。
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引用次数: 0
期刊
International Journal of Mining Science and Technology
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