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Application of Nano-Delivery Systems in Lymph Nodes for Tumor Immunotherapy 纳米递送系统在淋巴结肿瘤免疫治疗中的应用
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-03 DOI: 10.1007/s40820-023-01125-2
Yiming Xia, Shunli Fu, Qingping Ma, Yongjun Liu, Na Zhang

Highlights

  • The physiological structure and the drug delivery barriers of lymph nodes were described.

  • The factors affecting lymph nodes accumulation in nano-delivery systems were discussed.

  • The recent progress of nano-delivery carriers applied for lymph nodes immunotherapy was further categorized and reviewed.

重点介绍了淋巴结的生理结构和给药屏障。讨论了纳米递送系统中影响淋巴结积聚的因素。对近年来纳米载体在淋巴结免疫治疗中的应用进行了分类和综述。
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引用次数: 6
Oxidative Molecular Layer Deposition Tailoring Eco-Mimetic Nanoarchitecture to Manipulate Electromagnetic Attenuation and Self-Powered Energy Conversion 氧化分子层沉积剪裁生态模拟纳米结构操纵电磁衰减和自供电能量转换
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-05-31 DOI: 10.1007/s40820-023-01112-7
Jin-Cheng Shu, Yan-Lan Zhang, Yong Qin, Mao-Sheng Cao

Advanced electromagnetic devices, as the pillars of the intelligent age, are setting off a grand transformation, redefining the structure of society to present pluralism and diversity. However, the bombardment of electromagnetic radiation on society is also increasingly serious along with the growing popularity of "Big Data". Herein, drawing wisdom and inspiration from nature, an eco-mimetic nanoarchitecture is constructed for the first time, highly integrating the advantages of multiple components and structures to exhibit excellent electromagnetic response. Its electromagnetic properties and internal energy conversion can be flexibly regulated by tailoring microstructure with oxidative molecular layer deposition (oMLD), providing a new cognition to frequency-selective microwave absorption. The optimal reflection loss reaches ≈  − 58 dB, and the absorption frequency can be shifted from high frequency to low frequency by increasing the number of oMLD cycles. Meanwhile, a novel electromagnetic absorption surface is designed to enable ultra-wideband absorption, covering almost the entire K and Ka bands. More importantly, an ingenious self-powered device is constructed using the eco-mimetic nanoarchitecture, which can convert electromagnetic radiation into electric energy for recycling. This work offers a new insight into electromagnetic protection and waste energy recycling, presenting a broad application prospect in radar stealth, information communication, aerospace engineering, etc.

先进的电磁设备作为智能时代的支柱,正在掀起一场大变革,重新定义社会结构,呈现出多元化和多样性。然而,随着“大数据”的日益普及,电磁辐射对社会的轰击也日益严重。在此基础上,借鉴大自然的智慧和灵感,首次构建了一种仿生纳米结构,高度融合了多种成分和结构的优势,具有优异的电磁响应性能。利用氧化分子层沉积(oMLD)技术对其微结构进行裁剪,可灵活调节其电磁特性和内能转换,为频率选择性微波吸收提供新的认识。最优反射损耗达到≈−58 dB,并且通过增加oMLD循环次数可以将吸收频率从高频移到低频。同时,设计了一种新型电磁吸收表面,实现了几乎覆盖整个K和Ka波段的超宽带吸收。更重要的是,利用仿生纳米结构构建了一个巧妙的自供电装置,它可以将电磁辐射转化为电能进行循环利用。该研究为电磁保护和废能回收提供了新的思路,在雷达隐身、信息通信、航空航天等领域具有广阔的应用前景。
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引用次数: 35
All-Polymer Solar Cells and Photodetectors with Improved Stability Enabled by Terpolymers Containing Antioxidant Side Chains 含抗氧化侧链三元共聚物增强稳定性的全聚合物太阳能电池和光电探测器
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-05-29 DOI: 10.1007/s40820-023-01114-5
Chunyang Zhang, Ao Song, Qiri Huang, Yunhao Cao, Zuiyi Zhong, Youcai Liang, Kai Zhang, Chunchen Liu, Fei Huang, Yong Cao

Highlights

  • Two series of terpolymers with improved photostability were realized by the introduction of appropriate ratio of antioxidant butylated hydroxytoluene unit containing side chains.

  • All-polymer solar cells and organic photodetectors (OPDs) with these terpolymers as both donors and acceptors have been prepared with simultaneously improved efficiency and stability.

  • A feasible approach to develop terpolymers with antioxidant efficacy for improving the lifetime of organic solar cells and OPDs is proposed.

通过引入适当比例的含侧链抗氧化剂丁基羟基甲苯单元,实现了两个系列光稳定性提高的三元共聚物。制备了以三聚体为供体和受体的全聚合物太阳能电池和有机光电探测器(OPDs),同时提高了效率和稳定性。为提高有机太阳能电池和opd的寿命,提出了一种开发具有抗氧化性能的三元共聚物的可行途径。
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引用次数: 5
Highly Efficient and Stable FAPbI3 Perovskite Solar Cells and Modules Based on Exposure of the (011) Facet 基于(011)面曝光的高效稳定的FAPbI3钙钛矿太阳能电池和组件
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-05-28 DOI: 10.1007/s40820-023-01103-8
Kai Zhang, Bin Ding, Chenyue Wang, Pengju Shi, Xianfu Zhang, Cheng Liu, Yi Yang, Xingyu Gao, Rui Wang, Li Tao, Keith G. Brooks, Songyuan Dai, Paul J. Dyson, Mohammad Khaja Nazeeruddin, Yong Ding

Highlights

  • The (011) facet has excellent charge transport properties achieving closer alignment of energy levels.

  • By exploiting the (011) facet a device (0.06 cm2) and a module (29 cm2) achieved power conversion efficiencies of 25.24% and 21.12%, respectively.

(011)面具有优异的电荷输运特性,实现更紧密的能级排列。通过利用(011)面,器件(0.06 cm2)和模块(29 cm2)分别实现了25.24%和21.12%的功率转换效率。
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引用次数: 1
Construction of Self-Assembly Based Tunable Absorber: Lightweight, Hydrophobic and Self-Cleaning Properties 基于自组装的可调吸收剂的构建:轻质、疏水和自清洁特性
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-05-28 DOI: 10.1007/s40820-023-01108-3
Zehua Zhou, Qianqian Zhu, Yue Liu, Yan Zhang, Zirui Jia, Guanglei Wu

Highlights

  • NiCo/C aerogel was prepared by pyrolysis carbonization self-assembly of NiCo- metal–organic frameworks (MOFs).

  • The assembly mechanism of MOF aerogel was studied by adjusting the ratio of metal ion /BTC.

  • Aerogel combines hydrophobic, lightweight, self-cleaning, and electromagnetic wave absorption properties.

通过镍金属有机骨架(MOFs)的热解碳化自组装制备了NiCo/C气凝胶。通过调整金属离子/BTC的比例,研究了MOF气凝胶的组装机理。气凝胶结合了疏水、轻质、自清洁和电磁波吸收特性。
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引用次数: 52
Polyimides as Promising Materials for Lithium-Ion Batteries: A Review 聚酰亚胺作为锂离子电池材料的研究进展
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-05-24 DOI: 10.1007/s40820-023-01104-7
Mengyun Zhang, Li Wang, Hong Xu, Youzhi Song, Xiangming He

Highlights

  • Polyimides (PIs) as coatings, separators, binders, solid-state electrolytes, and active storage materials help toward safe, high-performance, and long-life lithium-ion batteries (LIBs).

  • Strategies to design and utilize PI materials have been discussed, and the future development trends of PIs in LIBs are outlooked.

聚酰亚胺(pi)作为涂层、分离器、粘合剂、固态电解质和活性存储材料,有助于实现安全、高性能和长寿命的锂离子电池(lib)。讨论了PI材料的设计和利用策略,并展望了PI材料在lib中的未来发展趋势。
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引用次数: 7
Functionalized Hydrogel-Based Wearable Gas and Humidity Sensors 功能化基于水凝胶的可穿戴气体和湿度传感器
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-05-24 DOI: 10.1007/s40820-023-01109-2
Yibing Luo, Jianye Li, Qiongling Ding, Hao Wang, Chuan Liu, Jin Wu

Highlights

  • A systematic summary of the research progress of hydrogel-based gas and humidity sensors is presented.

  • The sensing mechanism of hydrogel-based gas and humidity sensors is elaborated.

  • The potential of hydrogel-based vapor sensors in different fields of application is demonstrated.

本文系统地综述了水凝胶气体和湿度传感器的研究进展。阐述了水凝胶气湿传感器的传感机理。论证了水凝胶型蒸汽传感器在不同应用领域的潜力。
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引用次数: 12
Correction to: Recent Advances on Early-Stage Fire-Warning Systems: Mechanism, Performance, and Perspective 更正:早期火灾预警系统的最新进展:机制、性能和前景
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-11-23 DOI: 10.1007/s40820-022-00973-8
Xiaolu Li, Antonio Vázquez-López, José Sánchez del Río Sáez, De-Yi Wang
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引用次数: 0
Human Machine Interface with Wearable Electronics Using Biodegradable Triboelectric Films for Calligraphy Practice and Correction 使用生物可降解三电薄膜的可穿戴电子设备人机界面,用于书法练习和校正。
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-11-15 DOI: 10.1007/s40820-022-00965-8
Shen Shen, Jia Yi, Zhongda Sun, Zihao Guo, Tianyiyi He, Liyun Ma, Huimin Li, Jiajia Fu, Chengkuo Lee, Zhong Lin Wang

Highlights

  • A wearable triboelectric nanogenerator (denoted as CSF-TENG) is designed using biodegradable and carboxymethyl chitosan-silk fibroin (CSF) film.

  • In vitro biodegradation of CSF film is performed through trypsin and lysozyme. 63.1% of CSF film is removed by trypsin and lysozyme after degrading for 11 days.

  • An intuitive writing system is designed by CSF-TENGs-based human-machine interface to promptly track writing steps, highlight the stroke in advance, and access the accuracy of letters.

字母笔迹,尤其是笔画修正,对于个人行为和公众记录语言、表达和交流思想具有重要意义。本研究制备了一种可生物降解和导电的羧甲基壳聚糖-丝纤维蛋白(CSF)薄膜,用于设计可穿戴式三电纳米发电机(简称 CSF-TENG),其输出 Voc ≈ 165 V,Isc ≈ 1.4 μA,Qsc ≈ 72 mW cm-2。此外,还通过胰蛋白酶和溶菌酶对 CSF 薄膜进行了体外生物降解。结果表明,胰蛋白酶和溶菌酶具有稳定和良好的生物降解特性,在降解 11 天后,可去除 63.1% 的 CSF 薄膜。此外,基于 CSF-TENG 的人机界面(HMI)可及时跟踪书写步骤并获取字母的准确性,是一种直观的人机交流媒介。基于 CSF-TENG 的人机界面可自动识别和纠正三个具有代表性的字母(F、H 和 K),并由人机界面系统进行数据处理和分析。基于 CSF-TENG 的人机界面可以为下一个笔画做出决定,提前用红色替换突出显示笔画,这可以作为书法练习和纠正的候选。最后,还进行了各种实时演示,以实现虚拟和现实世界的控制,包括书写、车辆移动和医疗保健。
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引用次数: 0
Significantly Enhanced Electromagnetic Interference Shielding Performances of Epoxy Nanocomposites with Long-Range Aligned Lamellar Structures 具有长距离排列片状结构的环氧纳米复合材料的电磁干扰屏蔽性能显著增强
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-11-15 DOI: 10.1007/s40820-022-00949-8
Lei Wang, Zhonglei Ma, Hua Qiu, Yali Zhang, Ze Yu, Junwei Gu

High‑efficiency electromagnetic interference (EMI) shielding materials are of great importance for electronic equipment reliability, information security and human health. In this work, bidirectional aligned Ti3C2Tx@Fe3O4/CNF aerogels (BTFCA) were firstly assembled by bidirectional freezing and freeze-drying technique, and the BTFCA/epoxy nanocomposites with long-range aligned lamellar structures were then prepared by vacuum-assisted impregnation of epoxy resins. Benefitting from the successful construction of bidirectional aligned three-dimensional conductive networks and electromagnetic synergistic effect, when the mass fraction of Ti3C2Tx and Fe3O4 are 2.96 and 1.48 wt%, BTFCA/epoxy nanocomposites show outstanding EMI shielding effectiveness of 79 dB, about 10 times of that of blended Ti3C2Tx@Fe3O4/epoxy (8 dB) nanocomposites with the same loadings of Ti3C2Tx and Fe3O4. Meantime, the corresponding BTFCA/epoxy nanocomposites also present excellent thermal stability (Theat-resistance index of 198.7 °C) and mechanical properties (storage modulus of 9902.1 MPa, Young's modulus of 4.51 GPa and hardness of 0.34 GPa). Our fabricated BTFCA/epoxy nanocomposites would greatly expand the applications of MXene and epoxy resins in the fields of information security, aerospace and weapon manufacturing, etc.

高效电磁干扰(EMI)屏蔽材料对电子设备的可靠性、信息安全和人类健康具有重要意义。本研究首先利用双向冷冻和冻干技术组装了双向排列的 Ti3C2Tx@Fe3O4/CNF 气凝胶(BTFCA),然后利用真空辅助环氧树脂浸渍法制备了具有长程排列片层结构的 BTFCA/epoxy 纳米复合材料。当 Ti3C2Tx 和 Fe3O4 的质量分数分别为 2.96 和 1.48 wt% 时,BTFCA/环氧纳米复合材料成功构建了双向排列的三维导电网络,并产生了电磁协同效应,其电磁干扰屏蔽效果达到 79 dB,是相同 Ti3C2Tx 和 Fe3O4 负载的混合 Ti3C2Tx@Fe3O4/epoxy 纳米复合材料(8 dB)的 10 倍。同时,相应的 BTFCA/epoxy 纳米复合材料还具有优异的热稳定性(耐热指数为 198.7 ℃)和机械性能(存储模量为 9902.1 MPa,杨氏模量为 4.51 GPa,硬度为 0.34 GPa)。我们制备的 BTFCA/epoxy 纳米复合材料将大大拓展 MXene 和环氧树脂在信息安全、航空航天和武器制造等领域的应用。
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引用次数: 0
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Nano-Micro Letters
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