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EXPERIMENTAL METHOD OF AMIDE NITROGEN CONCENTRATION DETERMINING IN CONSTRUCTION MATERIALS 建筑材料中酰胺态氮浓度测定的实验方法
Pub Date : 2023-09-28 DOI: 10.61260/1998-8990-2023-3-169-180
Lyudmila Medvedeva, Galina Makarchuk, Gennady Brantsevich
The article actualizes the environmental problem of ammonia emission in industrial and residential buildings into the indoor air environment. In the process of studies it has been established that the main sources of ammonia emission into the indoor air are concrete structures (concrete walls, ceilings, columns, etc.) and finishing materials. In concrete, ammonia is formed as a result of hydrolysis of urea (NH2)2CO contained in concrete, and urea (urea) and other similar substances are used as hardening gas pedals and anti-freeze additives, including ammonized fly ash. It is possible to prevent ammonia emission into the indoor air not only by checking construction materials for cases of exceeding the maximum permissible concentration of urea in them, but also by experimental determination of amide nitrogen concentration in concrete mixtures at the stage of their delivery to construction sites. The aim of the article is to present an experimental technique to determine amide nitrogen concentration in construction materials developed to control amide nitrogen concentration at the stage of concrete mixture delivery to construction sites to exclude ammonia formation after putting construction sites of different functional purposes into operation. Experimental method for determining the concentration of amide nitrogen in building materials is the result of solving the following research tasks: – examination of building materials by methods of physical and chemical analysis for the quantitative determination of amide nitrogen; – comparison of the obtained results with the data of research laboratories with the conclusions about the quality of performed analyses. Approbation of the proposed experimental method for determining the concentration of amide nitrogen in building materials was carried out in the laboratory of the test center «OOO«Settle City» in Kudrovo.
本文对工业建筑和住宅建筑氨排放到室内空气环境中的环境问题进行了实际分析。在研究过程中,确定了室内空气中氨排放的主要来源是混凝土结构(混凝土墙、天花板、柱子等)和装修材料。 在混凝土中,氨是由混凝土中含有的尿素(NH2)2CO水解而成,尿素(urea)等类似物质用作硬化气踏板和防冻添加剂,包括氨化粉煤灰。 防止氨排放到室内空气中,不仅可以通过检查建筑材料中尿素的最大允许浓度,而且可以通过在混凝土混合物运送到建筑工地的阶段对其酰胺氮浓度进行实验测定。本文介绍了一种测定建筑材料中酰胺态氮浓度的实验技术,目的是在不同功能用途的建筑工地投入使用后,控制混凝土拌合料输送到施工现场阶段的酰胺态氮浓度,以防止氨的形成。测定建筑材料中酰胺态氮浓度的实验方法是解决以下研究任务的结果: -用酰胺氮定量测定的物理和化学分析方法检验建筑材料; -将获得的结果与研究实验室的数据进行比较,并得出有关所进行分析质量的结论。 在库德罗沃«OOO«Settle City»测试中心的实验室中,对确定建筑材料中酰胺氮浓度的拟议实验方法进行了批准。
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 In the process of studies it has been established that the main sources of ammonia emission into the indoor air are concrete structures (concrete walls, ceilings, columns, etc.) and finishing materials.
 In concrete, ammonia is formed as a result of hydrolysis of urea (NH2)2CO contained in concrete, and urea (urea) and other similar substances are used as hardening gas pedals and anti-freeze additives, including ammonized fly ash.
 It is possible to prevent ammonia emission into the indoor air not only by checking construction materials for cases of exceeding the maximum permissible concentration of urea in them, but also by experimental determination of amide nitrogen concentration in concrete mixtures at the stage of their delivery to construction sites.
 The aim of the article is to present an experimental technique to determine amide nitrogen concentration in construction materials developed to control amide nitrogen concentration at the stage of concrete mixture delivery to construction sites to exclude ammonia formation after putting construction sites of different functional purposes into operation.
 Experimental method for determining the concentration of amide nitrogen in building materials is the result of solving the following research tasks:
 – examination of building materials by methods of physical and chemical analysis for the quantitative determination of amide nitrogen;
 – comparison of the obtained results with the data of research laboratories with the conclusions about the quality of performed analyses.
 Approbation of the proposed experimental method for determining the concentration of amide nitrogen in building materials was carried out in the laboratory of the test center «OOO«Settle City» in Kudrovo.","PeriodicalId":497475,"journal":{"name":"Problems of risk management in the technosphere","volume":"74 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135470775","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
FEATURES OF SELECTION OF UNMANNED AIRCRAFT SYSTEM 无人机系统选型的特点
Pub Date : 2023-09-28 DOI: 10.61260/1998-8990-2023-3-50-59
Tatiana Sysoyeva
To perform many tasks in the system of EMERCOM of Russia, databases have been developed with the ability to select an aircraft model according to tactical and technical characteristics of helicopter and airplane types. Databases are presented in the form of digital and text invariants, in a certain range of numerical values, which provides search, processing and identification using a computer, on the SQLite3 database management system and for Windows 7 and higher operating systems. The databases in question can be used by employees and specialists of search and rescue teams and other services of EMERCOM of Russia to streamline and differentiate the approach in choosing the necessary unmanned aircraft system of the aircraft type to perform the tasks, taking into account the terrain and conditions of their use. The principle of operation is in the process of filling the database with information about the available models designed to equip the units of EMERCOM of Russia, so that in the future it would be possible to conduct a sample.
为了在俄罗斯的EMERCOM系统中执行许多任务,已经开发了数据库,能够根据直升机和飞机类型的战术和技术特征选择飞机型号。数据库以数字和文本不变量的形式呈现,在一定范围内的数值,提供了在计算机上,在SQLite3数据库管理系统和Windows 7及以上操作系统上的搜索、处理和识别。所涉及的数据库可由俄罗斯EMERCOM的搜救队和其他服务部门的雇员和专家使用,以便在考虑到地形和使用条件的情况下,简化和区分选择飞机类型的必要无人飞机系统来执行任务的方法。操作的原则是在数据库中填入有关俄罗斯EMERCOM部队装备的现有型号的资料,以便将来有可能进行抽样。
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引用次数: 0
CRITERIA MODEL ASSESSMENT OF TECHNOLOGICAL EQUIPMENT FIRE HAZARD LEVEL IN HYDROGEN POWER INDUSTRY 氢能工业工艺设备火灾危险等级评定标准模型
Pub Date : 2023-09-28 DOI: 10.61260/1998-8990-2023-3-96-105
Gafur Samigullin, Artem Timoshenko
The work is aimed at the solving the problem of fire safety by quantitative risk assessment during the operation of process equipment where hydrogen-containing gas is used, transported or stored. Such process areas mainly include hydrogen storage tanks, electrolysis plants, rooms containing hydrogen receivers, hydrogen compressor stations, etc. The list of hydrogen gas fire hazard indicators is presented in the work, the ways of definition of these indicators (parameters of criterial model) for a technological site are described, on the basis of the developed program for electronic computing machine the method of reference of technological object to a certain risk category is offered. This model is applicable only for closed technological sites where apparatuses and (or) pipelines in which hydrogen-containing gas with purity not less than 99,9 % is circulating are placed.
该工作旨在通过对使用、运输或储存含氢气体的工艺设备运行过程中的定量风险评估,解决消防安全问题。这类工艺区域主要包括储氢罐、电解厂、含氢接收器的房间、氢压缩站等。本文提出了氢气火灾危险指标清单,阐述了工艺现场的危险指标(标准模型参数)的定义方法,并在电子计算机程序开发的基础上,提出了工艺对象对某一危险类别的参考方法。本模型仅适用于封闭的工艺场所,其中放置了纯度不低于99.9%的含氢气体循环的设备和(或)管道。
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引用次数: 0
DETERMINATION OF THE CONTENT OF POLLUTANTS IN THE EXHAUST EMISSIONS OF THE YAMZ-238 GM2 SHIP ENGINE yamz - 238gm2型船用发动机废气中污染物含量的测定
Pub Date : 2023-09-28 DOI: 10.61260/1998-8990-2023-3-158-168
Olga Lozhkina, Konstantin Malchikov
In order to develop reliable calculation methods for monitoring and predicting the impact of emissions from boats on the environment in cities, it is necessary to carry out experimental studies of the exhaust emissions of boat engines. The purpose of the present study was to carry out mooring (stationary) tests to measure the concentrations of carbon monoxide, carbon dioxide, nitrogen oxides and hydrocarbons in the exhaust emissions of the YaMZ-238 GM2 engine used as a power unit on single-deck tourist motor ships, crew boats, etc., by means of the gas analyzer «Infracar 5M3T.02L». It was found that the content of pollutants in the exhaust emissions of the engine did not exceed standard values, and the obtained values of average specific emissions for the YaMZ-238 GM2 engine correlated well with the corresponding values of foreign methods.
为了开发可靠的计算方法来监测和预测船舶排放对城市环境的影响,有必要开展船舶发动机排气排放的实验研究。本研究的目的是进行系泊(静止)试验,通过气体分析仪«Infracar 5M3T.02L»测量YaMZ-238 GM2发动机废气中一氧化碳、二氧化碳、氮氧化物和碳氢化合物的浓度,YaMZ-238 GM2发动机用作单层旅游机动船、船员艇等的动力单元。结果表明,该发动机的废气排放中污染物的含量没有超标,所得到的YaMZ-238 GM2发动机的平均比排放值与国外方法的相应值具有较好的相关性。
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引用次数: 0
DEVELOPMENT OF A NANOMODIFIED FIRE EXTINGUISHING COMPOSITION FOR ROBOTIZED FIRE EXTINGUISHING INSTALLATIONS AT OIL PRODUCTS TRANSPORTATION FACILITIES 一种用于石油产品运输设施自动化灭火装置的纳米改性灭火组合物的研制
Pub Date : 2023-09-28 DOI: 10.61260/1998-8990-2023-3-196-203
Viktoriya Kiseleva
The purpose of the research is to substantiate the possibility of using carbon nanostructures in robotic fire extinguishing installations at facilities with the circulation of petroleum products. The paper presents the results of measuring the surface tension and viscosity of water with a wetting agent modified with carbon nanostructures (astralens), as well as determining the mass burnout rate of a flammable liquid under the conditions of supplying a fire extinguishing agent. The results of measurements of the extinguishing time of a class B model focus and the time of thermal destruction of a foaming agent film on the surface of a combustible liquid are presented. Based on the research, it was concluded that fire extinguishing compositions modified with astralenes should be used in robotic fire extinguishing installations at facilities with the circulation of petroleum products in order to provide thermal protection and reduce the time to extinguish a fire.
这项研究的目的是证实在石油产品循环设施的机器人灭火装置中使用碳纳米结构的可能性。本文介绍了用碳纳米结构修饰的润湿剂(astralens)测量水的表面张力和粘度,以及在提供灭火剂的条件下测定可燃液体的质量燃尽率的结果。本文介绍了B类模型焦点的灭火时间和可燃液体表面发泡剂膜的热破坏时间的测量结果。研究认为,在有石油产品流通的设施中,应采用含星烯改性的灭火组合物,以提供热保护,缩短灭火时间。
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引用次数: 0
MODERN MEANS OF ENSURING FIRE PROTECTION OF STEEL STRUCTURES OF OIL AND GAS FACILITIES 现代油气设施钢结构防火保障手段
Pub Date : 2023-09-28 DOI: 10.61260/1998-8990-2023-3-120-130
Andrey Kalach, Ekaterina Golovina, Alexander Krutolapov
Modern polymer materials used in construction, transport and household products characterized, as a rule, by high flammability and combustibility, which has a significant impact on ensuring the required level of fire protection. A variant of the formalization of the choice of a flame retardant coating is proposed and an algorithm for its justification is proposed. The proposed algorithm for choosing a fire-retardant coating assumes a preliminary quantitative assessment of fire danger; analysis of possible scenarios of fire development; the choice of the type of fire protection system taking into account the operating environment, the size of potential damage from fire, technical, economic and human factors, and the rationale for choosing a fire-resistant coating that provides the specified (required) level of fire protection.
用于建筑、运输和家居产品的现代高分子材料通常具有高可燃性和可燃性,这对确保所需的防火水平具有重大影响。提出了阻燃涂层选择形式化的一种变体,并提出了一种判别算法。所提出的防火涂料选择算法假设了对火灾危险性的初步定量评估;分析火警发展的可能情况;防火系统类型的选择要考虑到操作环境、火灾潜在损害的大小、技术、经济和人为因素,以及选择提供规定(要求)防火等级的防火涂料的基本原理。
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引用次数: 0
ANALYSIS OF FOAM DOSING SYSTEMS IN PUMP UNITS OF FIRE VEHICLES: STATUS, PROBLEMS, TECHNICAL SOLUTIONS 消防车辆泵机组泡沫加药系统分析:现状、问题及技术解决方案
Pub Date : 2023-09-28 DOI: 10.61260/1998-8990-2023-3-106-119
Alexander Pechurin, Aleksey Presnov, Nina Markova
The effect of the dosing accuracy of the foaming agent on the properties of the resulting foaming agent solution is shown, depending on the dosing accuracy, the parameters of the design and technological characteristics of the feeding systems and the dosage of the foaming agent. The technical solutions of foaming agent dosing in the systems of fire pumps of mobile fire equipment are considered. The technical solutions and operational characteristics of foam mixers in the systems of fire pumps of fire trucks of State fire service of EMERCOM of Russia are analyzed. The basic requirements for the dosing systems of the foam of fire pumps have been formed, which must be taken into account when developing and manufacturing dosing systems for pumping units of fire trucks.
给出了发泡剂的加量精度对所得发泡剂溶液性能的影响,这取决于加量精度、加料系统的设计参数和工艺特点以及发泡剂的加量。探讨了移动消防设备消防泵系统中发泡剂加药的技术解决方案。分析了泡沫搅拌器在俄罗斯国家消防局EMERCOM消防车消防泵系统中的技术方案和使用特点。形成了消防泵泡沫给药系统的基本要求,在开发和制造消防车抽水机给药系统时必须考虑到这些要求。
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引用次数: 0
INVESTIGATION OF THE POSSIBILITY OF IDENTIFYING THERMALLY MODIFIED PETROLEUM PRODUCTS BY ATOMIC EMISSION SPECTRAL ANALYSIS 用原子发射光谱法鉴别热改性石油产品的可行性研究
Pub Date : 2023-09-28 DOI: 10.61260/1998-8990-2023-3-89-95
Sergey Ivakhnyuk
The trend observed in recent years towards an increase in crimes involving the use of combustion accelerators focuses the attention of specialists on issues related to the identification of two or more samples of thermally modified petroleum products. The solution of this problem will give results not only in establishing the circumstances of criminal crimes, but also in identifying the perpetrators of spills of liquid petroleum hydrocarbons, as well as spill fires. The article presents the results of a study of thermally altered samples of various brands of light petroleum products by atomic emission spectral analysis in terms of diagnosing metal impurities, the quantitative contents of which are proposed as identification criteria. The analysis of the obtained results substantiates the need for further research aimed at solving the problem of establishing the identity of two or more samples of petroleum products.
近年来所观察到的涉及使用燃烧助燃剂的犯罪增加的趋势使专家们把注意力集中在与鉴定两个或两个以上的热改性石油产品样品有关的问题上。这一问题的解决将不仅有助于确定刑事犯罪的情况,而且有助于查明液体石油碳氢化合物泄漏和泄漏火灾的肇事者。本文介绍了用原子发射光谱分析方法对不同牌号轻质油热蚀样进行金属杂质诊断的结果,并提出了金属杂质定量含量作为鉴定标准。对所得结果的分析表明,需要进一步研究,以解决确定两个或多个石油产品样品的身份的问题。
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引用次数: 0
THE EFFECTIVENESS OF FLAME RETARDANT IMPREGNATING COMPOUNDS FOR WOODEN STRUCTURES 木结构阻燃浸渍剂的有效性
Pub Date : 2023-09-28 DOI: 10.61260/1998-8990-2023-3-67-78
Ilya Fedotov, Andrey Sivenkov, Yuri Naganovsky
The article considers the results of evaluating the flame retardant effectiveness of various flame retardants by the method of fire exposure according to GOST 53292–2009 and by methods of thermal analysis (thermogravimetry, differential thermogravimetry, derivative thermal analysis). According to the results of fire of surface application of flame retardants from 350 to 550 kg/m2, group I or II of flame retardant efficiency is provided (mass loss from 8,67 to 25 %). It is shown that the group of flame-retardant effectiveness does not actually reflect the nature and degree of realization of the mechanism of flame retardant action of flame retardants, their ability to influence the features of thermal transformations of wood. It has been established that the type of flame retardant, its chemical component composition and the mechanism of flame retardant action to varying degrees affect the main stages of thermal oxidative decomposition of wood. The results obtained can be used to evaluate the effectiveness of fire protection in reducing the intensity of the charring process and predicting the intensity of smoldering (flameless) combustion of wood. tests, it was found that with the consumption
本文考虑了根据GOST 53292-2009的火灾暴露法和热分析方法(热重法、差分热重法、导数热分析)对各种阻燃剂的阻燃效果进行评价的结果。根据防火结果表面应用的阻燃剂为350 ~ 550 kg/m2, I类或II类阻燃剂 提供效率(质量损失从8.67 - 25%)。结果表明,组阻燃效果并不能实际反映阻燃剂的阻燃作用机理的性质和实现程度,其对木材热转化特性的影响能力。研究表明,阻燃剂的种类、化学成分组成和阻燃作用机理不同程度地影响木材热氧化分解的主要阶段。所得结果可用于评价防火在降低炭化过程强度和预测木材阴燃(无焰)燃烧强度方面的有效性。经检测,发现与消费有关
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 efficiency is provided (mass loss from 8,67 to 25 %). It is shown that the group of flame-retardant effectiveness does not actually reflect the nature and degree of realization of the mechanism of flame retardant action of flame retardants, their ability to influence the features of thermal transformations of wood. It has been established that the type of flame retardant, its chemical component composition and the mechanism of flame retardant action to varying degrees affect the main stages of thermal oxidative decomposition of wood. The results obtained can be used to evaluate the effectiveness of fire protection in reducing the intensity of the charring process and predicting the intensity of smoldering (flameless) combustion of wood. tests, it was found that with the consumption","PeriodicalId":497475,"journal":{"name":"Problems of risk management in the technosphere","volume":"37 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135470763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MONITORING ROAD SAFETY UNDER SMOG EMERGENCY PEAT FIRE 雾霾紧急泥炭火灾下道路安全监测
Pub Date : 2023-09-28 DOI: 10.61260/1998-8990-2023-3-8-16
V Lozhkin, Alexey Smirnov, Sergey Vladimirovich Sharapov
The physical phenomenon of smog formation from burning peat bogs and its persistent air pollution on the highway is investigated. It is shown that particulate smog particles of small sizes PM10 and PM2.5 are capable, as on condensation nuclei, of creating optically dense aerosol fogs and, thereby, reducing the visibility range on the roadway to 50 meters or less, significantly increasing the risk of traffic accidents. It is proved that, together with carbon monoxide CO, smog saturates the air with pollutants to dangerous concentrations that can significantly weaken the reflex reactions of drivers to changing traffic conditions. In combination, this leads to an emergency situation, accompanied by a transport collapse, requiring the involvement of forces and means of emergency response.
研究了泥炭沼泽燃烧形成雾霾的物理现象及其对高速公路大气的持续污染。研究表明,小尺寸的雾霾颗粒PM10和PM2.5能够像在凝结核上一样,形成光学密集的气溶胶雾,从而将道路上的能见度范围降低到50米或更低,大大增加了交通事故的风险。事实证明,烟雾与一氧化碳一起使空气中的污染物饱和到危险的浓度,可以大大削弱驾驶员对变化的交通状况的反射反应。综合起来,这导致紧急情况,同时运输崩溃,需要部队和应急手段的参与。
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引用次数: 0
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Problems of risk management in the technosphere
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