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Effect of NaCl and SO2 on the stress corrosion cracking of CMSX-4 at 550°C NaCl和SO2对550℃CMSX-4应力腐蚀开裂的影响
IF 1.3 4区 材料科学 Q2 Materials Science Pub Date : 2023-05-01 DOI: 10.1080/09603409.2023.2205760
F. Duarte Martinez, A. Syed, K. Dawson, G. Tatlock, N. Morar, M. Kothari, C. Tang, J. Leggett, J. Mason-Flucke, G. Gibson, J. Nicholls, S. Gray, G. Castelluccio
ABSTRACT In the pursuit of more efficient gas turbine engines, components are required to operate for longer times at elevated temperatures. This increased time in service, together with a complex loading regime, can expose the material to environmental attack. This work has demonstrated that the interaction of stress, NaCl and a sulphur-containing environment is critical to cause crack initiation in the early stages of the exposure and accelerated corrosion rates in CMSX-4 at 550°C. The effect of having small concentrations of moisture in the gaseous environment or as water crystallisation in the salt is still to be investigated. A working hypothesis is that the interaction of alkali chlorides with a sulphur-containing atmosphere is the trigger to a self-sustaining cycle where metal chloride formation, vaporisation and oxidation lead to high amounts of hydrogen injection in a rapid manner and, therefore, hydrogen embrittlement.
为了追求更高效的燃气涡轮发动机,部件需要在高温下工作更长时间。这种增加的使用时间,加上复杂的加载制度,可以使材料暴露于环境攻击。这项工作表明,应力、NaCl和含硫环境的相互作用是导致CMSX-4在550°C时暴露早期产生裂纹和加速腐蚀速率的关键。在气体环境中有少量水分或在盐中有水结晶的影响仍有待研究。一个可行的假设是,碱氯化物与含硫大气的相互作用触发了一个自我维持的循环,在这个循环中,金属氯化物的形成、汽化和氧化导致大量的氢以快速的方式注入,因此,氢脆。
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引用次数: 0
Low cycle fatigue and creep–fatigue performance of 316SS formed by selective laser melting 选择性激光熔化成形316SS的低周疲劳和蠕变疲劳性能
IF 1.3 4区 材料科学 Q2 Materials Science Pub Date : 2023-05-01 DOI: 10.1080/09603409.2023.2205761
Lingfeng Pan, Peishan Ding, Dezhou Kong, Lijun Liu, Xiaotao Zheng
ABSTRACT The fatigue and creep–fatigue properties of 316SS formed by selective laser melting (SLM) were investigated, considering the effects of different peak stresses, stress rates and peak-holding times on the ratcheting and creep-ratcheting behaviour of SLM 316 SS specimens at different sampling angles (0°, 90°) and high temperatures (550°C, 650°C, 750°C). Results show that the 90° specimens exhibited better fatigue life than that of the 0° specimens. Moreover, the ratcheting evolution can be divided into three stages, but the first stage is very short and the main ratcheting behaviour takes place in the second and third stages. Interestingly, it was found that at stress rates above 10 MPa/s, the ratcheting evolution curves are highly overlapping. Furthermore, the creep–fatigue interaction promotes the evolution of material damage. Besides, creep increases the total strain of 316SS even with a short dwell time (0.5 min).
研究了选择性激光熔化(SLM) 316SS试样的疲劳和蠕变疲劳性能,考虑了不同的峰值应力、应力速率和峰值保持时间对不同取样角度(0°、90°)和高温(550°C、650°C、750°C)下SLM 316SS试样棘轮和蠕变-棘轮行为的影响。结果表明,90°试样的疲劳寿命优于0°试样。棘轮演化可分为三个阶段,但第一阶段很短,主要棘轮行为发生在第二和第三阶段。有趣的是,当应力速率大于10 MPa/s时,棘轮演化曲线高度重叠。蠕变-疲劳相互作用促进了材料损伤的演化。此外,即使停留时间较短(0.5 min),蠕变也会使316SS的总应变增加。
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引用次数: 0
Study on the composition, microstructure and properties of new W-Al alloyed ethylene cracking furnace tube under 1100 ℃ carburising test conditions 1100℃渗碳试验条件下新型W-Al合金乙烯裂解炉管的组成、组织和性能研究
IF 1.3 4区 材料科学 Q2 Materials Science Pub Date : 2023-04-27 DOI: 10.1080/09603409.2023.2205763
C. Liu, Tao Chen, Zhigang Wu, Xinglei Wang, H. Luo, Jiantao Wang
ABSTRACT The carburising tests were carried out at 1100 ℃ for 50 h, 100 h, 150 h and 200 h for a new type of tungsten-aluminium alloyed ethylene cracking furnace tube. The composition, microstructure transformation and performance of furnace tubes were analysed. The results showed that the average carbon content within 1 mm of the inner wall increased with the prolongation of carburising time. The thickness of carburised layer increased from 0.3 mm to 1.5 mm. The carbides in as cast structure were mainly massive (Cr, Fe, W)23C6 on the outside and fishbone (Cr, Fe, W)7C3 on the inside. During carburising process, the external (Cr, Fe, W)23C6 carbides coarsened and transformed into (Cr, Fe)7C3, and then gradually transformed into (Cr, Fe, W)7C3. Carbide coarsening mainly occurred in internal (Cr, Fe, W)7C3 during carburising. The carbide precipitation and transformation also led to Vickers hardness value of furnace tube increased.
对一种新型钨铝合金乙烯裂解炉管进行了1100℃、50 h、100 h、150 h和200 h的渗碳试验。分析了炉管的成分、组织变化及性能。结果表明:随着渗碳时间的延长,合金内壁1mm内的平均含碳量增加;渗碳层厚度由0.3 mm增加到1.5 mm。铸态组织中碳化物主要为块状(Cr, Fe, W)23C6,内部为鱼骨状(Cr, Fe, W)7C3。渗碳过程中,外部的(Cr, Fe, W)23C6碳化物变粗,转变为(Cr, Fe)7C3,再逐渐转变为(Cr, Fe, W)7C3。渗碳过程中碳化物粗化主要发生在内部(Cr, Fe, W)7C3中。碳化物的析出和相变也导致炉管的维氏硬度值升高。
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引用次数: 0
High-temperature oxidation of Haynes 282 microtubes in CO2 Haynes 282微管在CO2中的高温氧化
IF 1.3 4区 材料科学 Q2 Materials Science Pub Date : 2023-04-25 DOI: 10.1080/09603409.2023.2205666
Narayanan Murali, A. Ghazari, Shiqi Zheng, Kaiyuan Jin, T. Fisher, N. Ghoniem, Xiaochun Li
ABSTRACT The oxidation characteristics of Haynes 282 microtubes measuring 1 mm in diameter and 200 µm thick exposed to CO2 at elevated temperature are reported. After 215 hours at 700°C and 1 atm, a thin, protective chromia scale accumulates up to 2.03 µm from the outer surface, approximately 1% of the thickness, and internal aluminum oxidation is observed 2.59 µm from the inner surface. The results suggest that oxidation is limited by oxygen diffusion through the growing oxide scale layer. The average grain size in the microtube is 10 µm, and it decreases to 5 µm closer to the inner surface. Severe plastic deformation and variable dynamic recovery and recrystallization from the manufacturing process were observed throughout the microtube. Overall grain size and distribution in the microtube were found to be independent of thermal exposure, despite the occurrence of recrystallization. The superalloy microtube geometry shows promising performance in high-temperature thermal applications.      
本文报道了直径为1mm、厚度为200µm的Haynes 282微管在高温下暴露于CO2中的氧化特性。在700°C和1atm下加热215小时后,一层薄薄的保护性铬垢从外表面累积到2.03µm,约为厚度的1%,并且在2.59µm处观察到内部铝氧化。结果表明,氧化受到氧通过氧化垢层扩散的限制。微管的平均晶粒尺寸为10µm,靠近内表面的晶粒尺寸减小到5µm。在整个微管中观察到严重的塑性变形和可变的动态恢复和再结晶。尽管发生了再结晶,但微管中的总体晶粒尺寸和分布与热暴露无关。高温合金微管几何结构在高温热应用中表现出良好的性能。
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引用次数: 1
Creep behaviour of Q245R steel at 550 ℃ 550℃时Q245R钢的蠕变行为
IF 1.3 4区 材料科学 Q2 Materials Science Pub Date : 2023-04-11 DOI: 10.1080/09603409.2023.2201713
Jinquan Guo, Chao Tang, Fang Wang, K. Liu, Jingwei Zhang, H. Lai
ABSTRACT Q245R steel has good heat and corrosion resistant and is used in various applications, such as reactors, regenerators, reformed gas steam generators, and other equipment. In this study, the creep behaviour of Q245R steel at the temperature of 550 ℃ is investigated. In addition to the modified Kachanov-Robotnov (K-R) method, the traditional and modified θ projection methods were employed to establish the creep constitutive equations of Q245R steel. The results revealed that at small strains, the creep prediction curve was in good agreement with the test curve, and the prediction accuracy of the modified θ projection method was better than that of the other two models.
Q245R钢具有良好的耐热性和耐腐蚀性,广泛应用于反应器、蓄热器、重整燃气蒸汽发生器等设备中。本文研究了550℃时Q245R钢的蠕变行为。在改进Kachanov-Robotnov (K-R)方法的基础上,采用传统的θ投影法和改进的θ投影法建立了Q245R钢的蠕变本构方程。结果表明,在小应变下,蠕变预测曲线与试验曲线吻合较好,修正θ投影法的预测精度优于其他两种模型。
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引用次数: 0
Creep ductility and modified Monkman-Grant equation for Gr.92 by incorporating total strain 包含总应变的Gr.92的蠕变延性和修正的Monkman-Grant方程
IF 1.3 4区 材料科学 Q2 Materials Science Pub Date : 2023-04-03 DOI: 10.1080/09603409.2023.2195060
F. Abe
ABSTRACT A modified Monkman-Grant equation, which can provide a more accurate means of predicting creep rupture life than the standard Monkman-Grant formula, has been investigated for Gr.92 using creep data in the NIMS Creep Data Sheets at 550 to 750°C. The t r versus minimum creep rate min plot, which is called the Monkman-Grant relation, deviates downward at low stresses and long times. Better correlation of the t r with the min is obtained by the replacement of t r with (t r /ε r), where ε r is the total or rupture strain. The (t r /ε r) is inversely proportional to the min over a wide range of stress, temperature and test duration, and the magnitude of data scattering is only a little bit even at low stresses and long times. The creep life of Gr.92 can be predicted by evaluating the min, together with the ε r evaluated from the stress and or min dependence.
本文利用NIMS蠕变数据表中的蠕变数据,对Gr.92进行了研究。与标准的Monkman-Grant公式相比,修正的Monkman-Grant方程可以提供更准确的预测蠕变断裂寿命的方法。在低应力和长时间条件下,tr与最小蠕变速率最小图(称为Monkman-Grant关系)向下偏离。用(t r /ε r)代替tr可以得到tr与最小应变的更好的相关性,其中ε r为总应变或断裂应变。在较宽的应力、温度和测试时间范围内,(t r /ε r)与最小值成反比,即使在低应力和长时间下,数据散射的幅度也很小。Gr.92的蠕变寿命可以通过求最小值和由应力和最小依赖关系求出的ε r来预测。
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引用次数: 0
Fabrication of Ni-Co film for enhancing the high-temperature corrosion resistance of interconnects in solid oxide fuel cells (SOFCs) 提高固体氧化物燃料电池互连层耐高温腐蚀性能的Ni-Co膜的制备
IF 1.3 4区 材料科学 Q2 Materials Science Pub Date : 2023-03-29 DOI: 10.1080/09603409.2023.2195706
Rungsan Sriwilai, Piyapong Tongsong, Jennarong Tungtrongpairoj, P. Visuttipitukul, Kattareeya Taweesup
ABSTRACT Low-cost Ni-Co alloy coating was performed by electroplating technique to improve the high-temperature corrosion resistance of stainless steel interconnects in solid oxide fuel cells (SOFCs). The effect of plating on the surface morphology, microstructure and composition of Ni-Co alloys was investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD) and atomic force microscopy (AFM). The Ni-Co coatings were fabricated at thickness of around two microns and compared at different Ni-Co molar ratios. Corrosion performance of Ni-Co coating was evaluated in a muffle furnace under ambient atmosphere at 800℃ for 110 h. Co2NiO4 spinel oxides and Cr2O3 were found on the Ni-Co coated samples after the oxidation test. Results indicated that steel substrate corrosion protection improved with a low parabolic rate constant of 20 times after Ni-Co alloy electrodeposition coating. A smooth coating layer containing Co2NiO4 oxide with fewer defects promoted high oxidation resistance of the steel samples.
为了提高固体氧化物燃料电池(SOFCs)不锈钢互连件的耐高温腐蚀性能,采用电镀技术制备了低成本的Ni-Co合金涂层。采用扫描电镜(SEM)、x射线衍射仪(XRD)和原子力显微镜(AFM)研究了镀层对Ni-Co合金表面形貌、显微组织和成分的影响。制备了厚度约为2微米的Ni-Co涂层,并在不同的Ni-Co摩尔比下进行了比较。在马弗炉中,在室温800℃下腐蚀110 h,对Ni-Co涂层的腐蚀性能进行了评价。氧化试验后,在Ni-Co涂层样品上发现了Co2NiO4尖晶石氧化物和Cr2O3。结果表明,镍钴合金电沉积涂层后,钢基体的防腐性能提高了20倍,其抛物线速率常数较低。含Co2NiO4氧化物的涂层光滑,缺陷少,提高了钢样品的抗氧化性。
{"title":"Fabrication of Ni-Co film for enhancing the high-temperature corrosion resistance of interconnects in solid oxide fuel cells (SOFCs)","authors":"Rungsan Sriwilai, Piyapong Tongsong, Jennarong Tungtrongpairoj, P. Visuttipitukul, Kattareeya Taweesup","doi":"10.1080/09603409.2023.2195706","DOIUrl":"https://doi.org/10.1080/09603409.2023.2195706","url":null,"abstract":"ABSTRACT Low-cost Ni-Co alloy coating was performed by electroplating technique to improve the high-temperature corrosion resistance of stainless steel interconnects in solid oxide fuel cells (SOFCs). The effect of plating on the surface morphology, microstructure and composition of Ni-Co alloys was investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD) and atomic force microscopy (AFM). The Ni-Co coatings were fabricated at thickness of around two microns and compared at different Ni-Co molar ratios. Corrosion performance of Ni-Co coating was evaluated in a muffle furnace under ambient atmosphere at 800℃ for 110 h. Co2NiO4 spinel oxides and Cr2O3 were found on the Ni-Co coated samples after the oxidation test. Results indicated that steel substrate corrosion protection improved with a low parabolic rate constant of 20 times after Ni-Co alloy electrodeposition coating. A smooth coating layer containing Co2NiO4 oxide with fewer defects promoted high oxidation resistance of the steel samples.","PeriodicalId":49877,"journal":{"name":"Materials at High Temperatures","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2023-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83789756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Fireside performance of different coatings in biomass power plant 生物质发电厂不同涂料炉边性能研究
IF 1.3 4区 材料科学 Q2 Materials Science Pub Date : 2023-03-12 DOI: 10.1080/09603409.2023.2188351
S. Mori, Andrew Pidcock, J. Sumner, N. Simms, J. Oakey
ABSTRACT The energy sector will need to employ novel strategies to reduce greenhouse gas emissions, such as the increase of steam temperatures/pressures or the use of low carbon fuels (i.e. biomass). Both cause heat exchanger materials’ degradation issues, due to the formation of more/different corrosive deposits, which requires the use of expensive nickel-based materials or coatings. This paper focuses on the behaviour of three different coatings (HVOF NiCrFeSi, laser clad FeCrAl and Laser Clad NiCrFeSi) deposited on TP347HFG, at 700°C (up to 1000 h exposure). Tests were performed using the ‘deposit recoat’ method (KCl deposit) in simulated biomass combustion environments. Cross-sections were analysed using dimensional metrology, to determine distributions of metal loss and internal damage. Intergranular damage and pits were identified using SEM/EDX. A ‘diffusion cell’ behaviour was observed, which led to depletion of alloying elements from the coating and consequent increase in damage. The results suggested a severe degradation of all coatings.
能源部门将需要采用新的策略来减少温室气体排放,例如提高蒸汽温度/压力或使用低碳燃料(即生物质)。由于形成更多/不同的腐蚀性沉积物,两者都会导致热交换器材料的降解问题,这需要使用昂贵的镍基材料或涂层。本文重点研究了三种不同涂层(HVOF NiCrFeSi,激光熔覆FeCrAl和激光熔覆NiCrFeSi)在TP347HFG上在700°C(曝光1000小时)下的行为。在模拟生物质燃烧环境中,使用“沉积涂覆”方法(KCl沉积)进行了试验。横截面分析使用尺寸计量,以确定金属损失和内部损伤的分布。通过SEM/EDX分析发现了晶间损伤和凹坑。观察到“扩散池”行为,这导致涂层中合金元素的耗尽,从而导致损伤的增加。结果表明,所有涂层都发生了严重的降解。
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引用次数: 0
A microscopy study of nickel-based superalloys performance in type I hot corrosion conditions 镍基高温合金在I型热腐蚀条件下性能的显微研究
IF 1.3 4区 材料科学 Q2 Materials Science Pub Date : 2023-03-10 DOI: 10.1080/09603409.2023.2188355
Manon Waeytens, A. Syed, Tracey Roberts, F. D. Martinez, S. Gray, J. Nicholls
ABSTRACT Alloy material selection for sustainable, efficient, and cost-effective use in components is a key requirement for both power generation and aerospace sectors. Superalloys are manufactured using a combination of different elements, selected carefully to balance mechanical performance and environmental resistance to be used in a variety of different service conditions. Therefore, a fundamental understanding of each element is critical to alloy design. In this paper, the interaction of alloy chemistry, particularly chromium as a corrosion-resistant element along with titanium and molybdenum, and their effect on alloys performance for the relevant gas turbine industries were discussed. Based on the findings, the single-crystal alloy is found to be a better corrosion resistant alloy exhibited higher corrosion resistance in comparison to polycrystal alloys and proved that microstructure has a significant impact on alloy performance. This study also established that molybdenum level in chromia former alloys can significantly enhance the corrosion damage.
选择可持续、高效、低成本的合金材料是发电和航空航天领域的关键要求。高温合金是使用不同元素的组合制造的,经过精心挑选,以平衡机械性能和环境阻力,以便在各种不同的使用条件下使用。因此,对每个元素的基本理解对合金设计至关重要。本文讨论了合金化学,特别是作为耐腐蚀元素的铬与钛、钼的相互作用,以及它们对相关燃气轮机行业合金性能的影响。结果表明,与多晶合金相比,单晶合金是一种更好的耐腐蚀合金,具有更高的耐腐蚀性能,并证明了微观组织对合金性能有显著影响。研究还表明,钼含量对原铬合金的腐蚀损伤有显著的促进作用。
{"title":"A microscopy study of nickel-based superalloys performance in type I hot corrosion conditions","authors":"Manon Waeytens, A. Syed, Tracey Roberts, F. D. Martinez, S. Gray, J. Nicholls","doi":"10.1080/09603409.2023.2188355","DOIUrl":"https://doi.org/10.1080/09603409.2023.2188355","url":null,"abstract":"ABSTRACT Alloy material selection for sustainable, efficient, and cost-effective use in components is a key requirement for both power generation and aerospace sectors. Superalloys are manufactured using a combination of different elements, selected carefully to balance mechanical performance and environmental resistance to be used in a variety of different service conditions. Therefore, a fundamental understanding of each element is critical to alloy design. In this paper, the interaction of alloy chemistry, particularly chromium as a corrosion-resistant element along with titanium and molybdenum, and their effect on alloys performance for the relevant gas turbine industries were discussed. Based on the findings, the single-crystal alloy is found to be a better corrosion resistant alloy exhibited higher corrosion resistance in comparison to polycrystal alloys and proved that microstructure has a significant impact on alloy performance. This study also established that molybdenum level in chromia former alloys can significantly enhance the corrosion damage.","PeriodicalId":49877,"journal":{"name":"Materials at High Temperatures","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2023-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75132509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Evaluation of the environmental impacts and economical study of Solar Salt in CSP-parabolic trough technology 光热抛物面槽技术中太阳能盐的环境影响评价及经济性研究
IF 1.3 4区 材料科学 Q2 Materials Science Pub Date : 2023-03-06 DOI: 10.1080/09603409.2023.2182588
M. Lambrecht, G. García-Martin, M. I. Lasanta, M. Miguel, R. Díaz, F. Pérez-Trujillo
ABSTRACT The performance of a concentrated solar power plant is strongly driven by its heat storage capacity and is evolving through the development of new salt mixtures. Molten nitrates, which have already proved their high potential, can be further improved in terms of economic and environmental aspects, with the mitigation of toxic compounds and a higher electricity generation capability. In this work, stability range and energy density characterisations were performed on the nitrate ‘Solar’ salt, along with its life cycle assessment, environmental impact, and cost analysis.
聚光太阳能发电厂的性能受到其蓄热能力的强烈驱动,并通过开发新的盐混合物而不断发展。熔融硝酸盐已经证明了其巨大的潜力,在经济和环境方面可以进一步改进,减少有毒化合物,提高发电能力。在这项工作中,对硝酸盐“太阳能”盐进行了稳定性范围和能量密度表征,以及其生命周期评估、环境影响和成本分析。
{"title":"Evaluation of the environmental impacts and economical study of Solar Salt in CSP-parabolic trough technology","authors":"M. Lambrecht, G. García-Martin, M. I. Lasanta, M. Miguel, R. Díaz, F. Pérez-Trujillo","doi":"10.1080/09603409.2023.2182588","DOIUrl":"https://doi.org/10.1080/09603409.2023.2182588","url":null,"abstract":"ABSTRACT The performance of a concentrated solar power plant is strongly driven by its heat storage capacity and is evolving through the development of new salt mixtures. Molten nitrates, which have already proved their high potential, can be further improved in terms of economic and environmental aspects, with the mitigation of toxic compounds and a higher electricity generation capability. In this work, stability range and energy density characterisations were performed on the nitrate ‘Solar’ salt, along with its life cycle assessment, environmental impact, and cost analysis.","PeriodicalId":49877,"journal":{"name":"Materials at High Temperatures","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2023-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81013321","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Materials at High Temperatures
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