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Current advances on sea-island microfiber nonwoven materials preparation technology and its applications: a review 海岛超细纤维非织造材料制备技术及其应用研究进展
4区 工程技术 Q2 Agricultural and Biological Sciences Pub Date : 2023-11-11 DOI: 10.1080/00405000.2023.2278373
Hiroshi Fu, Tong Zhang, Songnan Zhang, Xiaoming Qian
AbstractWith the increasing textile industry demand for personalized fiber product, leading to the development and application of new fiber, sea-island microfiber become one of the representative new textile materials. Recently, the sea-island microfiber received extensive attention of researchers as a new composite fiber in high technology and high added value. In order to have a comprehensive understanding of the development of sea-island microfiber nonwovens at present, based on the development of sea-island microfiber nonwovens, the paper focused on the development of preparation technology-conjugate spinning and compound spinning, and the melt spinning. Based on the characteristics of sea-island microfiber nonwovens, the applications of the products in the fields of fashion fabrics, microfiber leather, filtration materials, high-performance cleaning cloth and biomedical materials are comprehensively introduced, and the future research orientations of the products are prospected.Keywords: sea-islandmicrofibernonwoven materialscompound spinningmelt spinning Disclosure statementThe authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.Additional informationFundingThe authors thank the Shandong Provincial Key Research and Development Program (Major Scientific and Technological Innovation Project) [2021CXGC011001], Huafon Microfibre (Jiangsu) Co. Ltd. [2021120011000234], Textile Vision Basic Research Program [J202306].
摘要随着纺织工业对个性化纤维产品需求的不断增加,导致新型纤维的开发和应用,海岛微纤维成为具有代表性的纺织新材料之一。海岛超细纤维作为一种高技术、高附加值的新型复合纤维,近年来受到了研究人员的广泛关注。为了全面了解海岛超细纤维非织造布的发展现状,在海岛超细纤维非织造布发展的基础上,重点研究了海岛超细纤维非织造布的制备技术——共轭纺丝和复合纺丝以及熔融纺丝的发展。根据海岛超纤维非织造布的特点,全面介绍了海岛超纤维非织造布产品在时尚面料、超纤维皮革、过滤材料、高性能清洁布、生物医用材料等领域的应用,并对海岛超纤维非织造布产品未来的研究方向进行了展望。关键词:海岛微纤维非织造材料复合纺丝熔体纺丝披露声明作者声明他们没有已知的竞争经济利益或个人关系可能会影响本文所报道的工作。作者感谢山东省重点研发计划(重大科技创新项目)[2021CXGC011001],华丰微纤维(江苏)有限公司[2021120011000234],纺织视觉基础研究计划[J202306]。
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引用次数: 0
Analysing barriers of digitalization in apparel sector: a fuzzy DEMATEL approach 服装行业数字化障碍分析:模糊DEMATEL方法
4区 工程技术 Q2 Agricultural and Biological Sciences Pub Date : 2023-11-11 DOI: 10.1080/00405000.2023.2279197
Ahmet Özbek, Alper Kiraz, Enes Furkan Erkan
AbstractThe digital transformation process entails the creation of new business models, processes, software, and technologically advanced systems. This study aims to analyze the barriers that businesses in the apparel sector face during the process of digitalization. So far, no comprehensive study has been found in the literature that analyses how these barriers interact with each other to make better decisions for digital transformation. This study initiates by conducting an identification of the barriers faced by companies operating in the apparel sector during their pursuit of digitalization. Then, prioritizing important barriers and the relationships between these barriers are analyzed using the Fuzzy DEMATEL method. Research results showed that lack of expertise, lack of management support, insufficient financial resources and lack of IT system are the four main barriers. It is thought that the development of digitalization in the apparel clothing industry will increase by keeping these barriers in focus.Keywords: Appareldigitalizationfuzzy DEMATELmanufacturing Disclosure statementNo potential conflict of interest was reported by the authors.
摘要数字化转换过程需要创建新的业务模型、流程、软件和技术先进的系统。本研究旨在分析服装行业企业在数字化过程中所面临的障碍。到目前为止,在文献中还没有发现全面的研究来分析这些障碍如何相互作用,从而为数字化转型做出更好的决策。本研究首先确定了在服装行业经营的公司在追求数字化过程中面临的障碍。然后,利用模糊DEMATEL方法对重要障碍进行优先排序,并分析了这些障碍之间的关系。研究结果表明,缺乏专业知识、缺乏管理支持、资金资源不足和缺乏IT系统是四大主要障碍。人们认为,通过关注这些障碍,服装行业的数字化发展将会加快。关键词:服装数字化模糊dematel制造披露声明作者未报告潜在利益冲突。
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引用次数: 0
Yarn breakage detection in ring spinning through ring temperature drop 利用环温降检测环锭纺纱断纱
4区 工程技术 Q2 Agricultural and Biological Sciences Pub Date : 2023-11-11 DOI: 10.1080/00405000.2023.2280282
Xi Wu, Wenbin Li, Christopher Hurren, Xungai Wang
AbstractYarn breakage or ends-down in ring spinning adversely affects spinning efficiency. An ends-down event may continue for an extended period of time before it is detected and attended to. This study explored a novel approach to detect yarn breakage or ends-down in ring spinning, through changes in ring temperature after an ends-down. Numerical simulation and experimental verification were used to examine the ring temperature changes during the yarn breakage process. The results showed that higher ambient temperature, spindle speed and yarn count (tex) resulted in a higher ring temperature and a longer ring cooling time. But the rate of ring temperature decrease immediately after yarn breakage was quite high, dropping 50% between equilibrium and ambient temperatures in approximately 16 s for most spinning conditions. The model and results of this study offer the basis for a new yarn breakage detection option in ring spinning based on the temperature change of the ring.Keywords: Ring spinningyarn breakagering temperaturenumerical modelends-down detection AcknowledgmentWe would like to acknowledge support provided to the first author under the Deakin-WTU joint PhD program.Disclosure statementThe authors declared no potential conflicts of interest with respect to the research, authorship and/or publication of this article.
摘要环锭纺纱过程中出现断纱或落纱现象,严重影响纺纱效率。在检测和处理结束事件之前,它可能会持续一段较长的时间。本研究探索了一种利用环锭温度变化来检测环锭纺纱断纱或落纱的新方法。采用数值模拟和实验验证相结合的方法,研究了纱线断裂过程中环温的变化规律。结果表明,较高的环境温度、锭子转速和纱线支数会导致锭子温度升高和锭子冷却时间延长。但断纱后环温立即下降的速率相当高,在大多数纺纱条件下,平衡温度与环境温度在16 s左右下降50%。该模型和研究结果为基于环锭温度变化的环锭纺纱断纱检测提供了依据。关键词:环锭纺纱;断纱温度;数值模型;披露声明作者声明在本文的研究、作者身份和/或发表方面没有潜在的利益冲突。
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引用次数: 0
Development of a textronic system by machine embroidery for sportsmen 运动员用机绣织纹系统的研制
4区 工程技术 Q2 Agricultural and Biological Sciences Pub Date : 2023-11-08 DOI: 10.1080/00405000.2023.2278764
Ewa Skrzetuska, Paulina Szablewska
Numerous solutions for pulse measurement by athletes exist, most commonly in the form of watches or bands. However, some athletes do not tolerate or do not want additional devices on their bodies during exercise. This work aims to replace the existing commercial solutions with textile sensors embedded in clothing. Such a solution would increase comfort and facilitate physical activity. To select the best solution, four knitted fabrics were tested to select the one with the best parameters as a substrate for the system. Three different densities of the embroidery with electrically conductive thread 100%, 85% and 65% were also tested and in two sizes for bands and belts. Mechanical and utility tests were performed such as resistance to perspiration or tensile stress. All tests were carried out in an accredited laboratory, in accordance with applicable standards and our own methodology. The results showed the best material, embroidery density and embroidery size to create an airy, heat-dissipating, and durable textronic system for athletes. Prototype of the solution was created, and its operation was tested during simulation. Conducted tests of the conductive properties of embroidered materials confirm the possibility of making textronic sensors responding to the pulse. The knitted fabrics selected for the tests meet the requirements of sports materials for the parameters of thermal resistance and air permeability. The results showed the correct operation of the prototype.
运动员脉搏测量的解决方案有很多,最常见的是手表或腕带。然而,一些运动员不容忍或不希望在运动期间在他们的身体上额外的设备。这项工作旨在用嵌入服装的纺织品传感器取代现有的商业解决方案。这样的解决方案将增加舒适度并促进身体活动。为了选择最佳方案,对4种针织物进行了测试,以选择具有最佳参数的织物作为该系统的基材。我们还测试了三种不同密度的刺绣,导电线分别为100%、85%和65%,以及两种尺寸的带子和腰带。进行了机械和实用测试,如抗排汗或抗拉应力。所有测试均在认可的实验室按照适用的标准和我们自己的方法进行。结果表明,最佳的材料、刺绣密度和刺绣尺寸可以为运动员创造一个通风、散热和耐用的textronic系统。建立了解决方案的原型,并在仿真过程中对其运行进行了测试。对刺绣材料的导电性能进行的测试证实了制造对脉冲响应的textronic传感器的可能性。试验选用的针织物的热阻和透气性参数符合运动材料的要求。结果表明,样机的运行是正确的。
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引用次数: 0
Step-by-step assembly of antimony tin oxide/polymer coatings on cotton fabrics for enhanced electrical conductivity and fire resistance properties 在棉织物上逐步组装氧化锑锡/聚合物涂层,以增强导电性和耐火性能
4区 工程技术 Q2 Agricultural and Biological Sciences Pub Date : 2023-11-08 DOI: 10.1080/00405000.2023.2279206
Min Guo, Di Wu, Xueshuai Wang, Yuan Huang, Zengge Guo, Zhaohui Jiang
AbstractTo prepare functional cotton fabric with good electrical conductive property, tin oxide antimony (ATO) and polymer was alternately assembled on the cotton fabric for fabricating functional coating by dipping-assisted layer-by-layer assembly technique. The microstructure of ATO/polymer coated fabric was characterized by scanning electron microscope and energy-dispersive X-ray (EDX) spectroscopy, the electrical conductivity and air permeability were measured by multimeter, four-point resistance tester and air permeability tester. The results showed that the addition of ATO imparted electrical conductive property to the ordinary cotton fabric, and the polyanionic waterborne polyurethane (WPU) was beneficial to the deposition of ATO and polycationic polyethyleneimine (PEI) and thus improving the conductive property of the fabric. With the increase of the number of assembly layers, the quality, thickness and electrical conductive property increased, but the air permeability decreased. When the number of assembly layers increased from 3 to 6 and 9, the resistivity of the fabric decreased from 41.8 Ω·m to 6.1 and 4.7 Ω·m. Meanwhile, the addition of ATO and PEI improved the fire resistance property of cotton fabric. The exploration of the conductive fabric provides a feasible strategy for multi-functional wearable textiles.Keywords: Antimony tin oxideconductive coatingcotton fabric modificationstep-by-step assemblyfire resistance Disclosure statementThe authors declare no competing financial interest.Additional informationFundingThis work was supported by Natural Science Foundation of Shandong Province of China (No. ZR2022QE211), Natural Science Foundation of Shandong Province of China (No. ZR2020QE095), Open Fund of Hubei Key Laboratory of Biomass Fibers and Eco-Dyeing & Finishing (Wuhan Textile University) (No. STRZ202107), Open Fund of State Key Laboratory of Biobased Fiber Manufacturing Technology (No. SKL202204), Opening Project of Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, Project Number: QJRZ2113 Innovation and Entrepreneurship Training Program for Shandong Students (No. S202210433061), Laboratory Construction Project of Shandong University of Technology (No. 2022018) and Doctoral Research Startup Foundation of Shandong University of Technology (No. 4033/721025).
摘要为了制备导电性能良好的功能棉织物,采用浸渍辅助逐层组装技术,在棉织物上交替组装氧化锡锑(ATO)和聚合物,制备功能涂层。采用扫描电镜和能谱仪对ATO/聚合物涂层织物的微观结构进行了表征,采用万用表、四点电阻测试仪和透气性测试仪测量了涂层织物的电导率和透气性。结果表明,ATO的加入使普通棉织物具有导电性能,而聚阴离子水性聚氨酯(WPU)有利于ATO和聚阳离子聚乙烯亚胺(PEI)的沉积,从而提高织物的导电性能。随着装配层数的增加,其质量、厚度和导电性均有所提高,但透气性下降。当装配层数从3层增加到6层和9层时,织物的电阻率从41.8 Ω·m降低到6.1和4.7 Ω·m。同时,ATO和PEI的加入提高了棉织物的耐火性能。对导电织物的探索为多功能可穿戴纺织品的发展提供了可行的策略。关键词:锑锡氧化导电涂层;棉织物改性;分步组装;项目资助:山东省自然科学基金资助项目(No. 1138226);山东省自然科学基金项目(ZR2022QE211);ZR2020QE095),生物质纤维与生态染整湖北省重点实验室开放基金(武汉纺织大学);生物基纤维制造技术国家重点实验室开放基金(STRZ202107);SKL202204),浙江省清洁染整技术重点实验室开放项目,项目编号:QJRZ2113山东省大学生创新创业训练计划(QJRZ2113);山东理工大学实验室建设项目(No. 2022018)和山东理工大学博士科研启动基金(No. 4033/721025)。
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引用次数: 0
New dispersions for pigment printing binders in the manufacture of light industry goods 用于轻工产品制造的颜料印刷粘合剂的新型分散体
4区 工程技术 Q2 Agricultural and Biological Sciences Pub Date : 2023-11-08 DOI: 10.1080/00405000.2023.2277147
G. A. Kasymova, K. I. Badanov, I. K. Badanov, K. T. Makhanbetaliyeva, R. B. Badanova, T. T. Togatayev, D. S. Nabiyev, M. S. Kalmakhanova
AbstractPigment printing using screen technology has certain problems associated with the limited use of domestic raw materials. The expansion of the range of printing inks fills the need for small-circulation production of textile products with original artistic and color design and the use of modern printing equipment. In this work, the possibility of using new aqueous polyurethane dispersions as binders in pigment printing was explored for the first time. This will expand the range of thickeners through the use of polyurethane dispersions, ensuring the production of strong and elastic polymer films during low-temperature processing. Such dispersions are environmentally friendly products, since toxic solvents are not used. We propose the application of new polyurethane thickeners in compositions with polyurethane dispersions as a rheological modifier. The rheological parameters of printed compositions and the physical and mechanical properties of films of polyurethane dispersions were determined and it was found that the dispersions used are capable of forming a soft and plastic film. This confirms the suitability of these film-forming preparations for use in pigment printing. The new binders based on polyurethane dispersions make possible to create effective printing compositions, to improve the quality of prints and to impart improved performance properties.Keywords: Pigment printingpolyurethane dispersioneco-friendly bindersrheological propertiesperformance propertiesthickeners Disclosure StatementNo potential conflict of interest was reported by the authors.
摘要采用丝网技术进行颜料印刷存在一定的问题,这与国内原料的有限使用有关。印刷油墨范围的扩大,填补了具有原创艺术和色彩设计的纺织产品小循环生产和使用现代印刷设备的需要。本研究首次探索了新型水性聚氨酯分散体作为颜料印刷粘合剂的可能性。这将通过使用聚氨酯分散体扩大增稠剂的范围,确保在低温加工过程中生产出坚固而有弹性的聚合物薄膜。这种分散体是环保产品,因为不使用有毒溶剂。提出了新型聚氨酯增稠剂在以聚氨酯分散体为流变改性剂的组合物中的应用。测定了印刷组合物的流变参数和聚氨酯分散体薄膜的物理力学性能,发现所使用的分散体能够形成柔软的塑料薄膜。这证实了这些成膜制剂用于颜料印刷的适用性。基于聚氨酯分散体的新型粘合剂使制造有效的印刷组合物成为可能,从而提高印刷品的质量,并赋予改进的性能。关键词:颜料印刷聚氨酯分散体环保粘合剂流变性能性能增稠剂披露声明作者未报告潜在利益冲突。
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引用次数: 0
Numerical investigation on the high-velocity impact resistance of textile reinforced composite mesh designs inspired by spider web 受蛛网启发的纺织增强复合材料网高速抗冲击性能的数值研究
4区 工程技术 Q2 Agricultural and Biological Sciences Pub Date : 2023-11-07 DOI: 10.1080/00405000.2023.2276863
Prashant Rawat, Sai Liu, None Mahesh, Ramesh Kumar, Nand Kishore Singh
AbstractThe need for thin and highly deformable textile reinforcements is constant in sectors like thin composites, catching nets, and complex construction designs (like dome-shape). The conventional rectangular-patterned meshed wovens are used in thin composite structures as reinforcement at the commercial level. These woven textiles are bidirectional and exhibit approximately the same strength along both axes. However, these conventional rectangular-patterned mesh designs show poor impact stress distribution capacity. Interestingly, very thin and fine mesh designs are available in nature. One such example is the spider web structure. These structures have evolved with time and optimised their mesh pattern design for better impact damage resistance and load transfer. In this study, the basalt fibre reinforced mortar textile composites are considered for the investigation due to their growing interest in civil and construction applications. To demonstrate how the mesh geometry in textiles significantly influences the stress transfer, energy absorption, and deformation of reinforcements under various impact situations, three different geometries, (a) square shape mesh, (b) diamond-shaped mesh, and (c) bio-inspired spider web mesh, are modelled and meshed based on the reference geometry’s meshing pattern and dimensions. The results of numerical simulations show that a meshed reinforcement design inspired by spider-orb-web has improved mechanical features compared to conventional square and diamond shape mesh designs under high velocity impact loading.Keywords: Basalt wovenbio-inspired designspider-orb-webhigh velocity impact Disclosure statementNo potential conflict of interest was reported by the authors.Additional informationFundingResearch reported herein was supported by the National Natural Science Foundation of China (No. 52208266), Natural Science Foundation of Shandong Province (No. ZR2021QE068) and China Postdoctoral Science Foundation (No. 2023M732575).
摘要在薄复合材料、渔网和复杂的结构设计(如圆顶)等领域,对薄且高度可变形的纺织品增强材料的需求是恒定的。传统的矩形图案网状织物在薄型复合结构中用作商业层面的加固。这些编织的纺织品是双向的,沿两个轴表现出大致相同的强度。然而,这些传统的矩形网格设计显示出较差的冲击应力分布能力。有趣的是,自然界中有非常薄和精细的网格设计。其中一个例子就是蜘蛛网结构。这些结构随着时间的推移而发展,并优化了它们的网格图案设计,以获得更好的抗冲击损伤性和负载转移。由于玄武岩纤维增强砂浆纺织复合材料在民用和建筑领域的应用日益受到关注,因此本研究考虑对其进行研究。为了演示纺织品中的网格几何形状如何在各种冲击情况下显着影响应力传递,能量吸收和增强物的变形,三种不同的几何形状(a)方形网格,(b)菱形网格和(c)仿生蜘蛛网网格)基于参考几何形状的网格模式和尺寸进行建模和网格划分。数值模拟结果表明,与传统的方形和菱形网格设计相比,基于蜘蛛球网的网格加固设计在高速冲击载荷下具有更好的力学性能。关键词:玄武岩编织生物启发设计蜘蛛球网高速撞击披露声明作者未报告潜在利益冲突。本研究得到国家自然科学基金项目(52208266)、山东省自然科学基金项目(52208266)资助。ZR2021QE068)和中国博士后科学基金(2023M732575)。
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引用次数: 0
Three-dimensional braiding machine with variable braiding pattern 具有可变编织图案的三维编织机
4区 工程技术 Q2 Agricultural and Biological Sciences Pub Date : 2023-11-03 DOI: 10.1080/00405000.2023.2276929
Jing Li, Yajun Yin, Qing Huang, Gui Yang, Feng Jiang
AbstractThree-dimensional (3D) braided composites have a wide range of applications and are known for their flexible designability, structural integrity, high specific stiffness, high specific strength, and higher damage tolerance. However, the current production of 3D braided preforms primarily relies on manual labor, particularly when it comes to the special-shaped structures, resulting in limited capacity to meet diverse and large-scale demands. In order to swiftly and cheaply braid preforms of various structures, this research proposes a novel braiding machine model. The proposed machine is extendable, capable of changing patterns quickly, and incorporates multiple functionalities. So it is appropriate for automated manufacturing preforms with different cross-sections, including Τ-shaped, H-shaped, ∏-shaped, and other structures, while also facilitating the development of new braiding structures to satisfy various application requirements. More importantly, it can automatically braid a variety of shapes, such as tapered structures, branch pipes, variable thickness preforms and so on. Comparative analysis with existing machines highlights the superior mechanical structure, operational mode, and functional characteristics of the robotic arm braiding machine. This advanced machine contributes to the evolution of the braiding industry. By breaking the limitations of traditional equipment that can only produce a single type of structure, this advanced braiding machine has the potential to significantly reduce equipment costs for braiding factories.Keywords: 3D braiding machinebraiding structurespattern changecomposites Authors’ contributionJing Li (First Author): Conceptualization, Methodology, Investigation, Validation, Formal Analysis, Writing - Original Draft, Writing - Review & Editing; Yajun Yin: Conceptualization, Resources, Supervision; Qing Huang: Investigation, Formal analysis; Gui Yang: Conceptualization, Software; Feng Jiang: Project administrationDisclosure statementNo potential conflict of interest was reported by the author(s).
摘要三维编织复合材料具有设计灵活、结构完整、高比刚度、高比强度、高损伤容限等特点,具有广泛的应用前景。然而,目前3D编织预制件的生产主要依靠人工,特别是在异形结构方面,导致满足多样化和大规模需求的能力有限。为了快速、廉价地编织各种结构的预制件,本研究提出了一种新型的编织机模型。所建议的机器是可扩展的,能够快速更改模式,并包含多种功能。因此适用于自动化制造不同截面的预制件,包括Τ-shaped、h形、∏形等结构,同时也便于开发新的编织结构,以满足各种应用要求。更重要的是,它可以自动编织各种形状,如锥形结构,分支管,变厚度预制件等。通过与现有机器的对比分析,突出了机械臂编织机优越的机械结构、工作方式和功能特点。这台先进的机器促进了编织工业的发展。通过打破传统设备只能生产单一类型结构的限制,这种先进的编织机有可能大大降低编织厂的设备成本。关键词:三维编织机编织结构图案变化复合材料作者贡献李静(第一作者):概念、方法、调查、验证、形式分析、写作-原稿、写作-审校;尹亚军:概念、资源、监督;黄青:调查,形式分析;杨桂:概念化,软件;披露声明作者未发现潜在的利益冲突。
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引用次数: 0
Silica aerogel in textiles and nanofibers: a comprehensive review of synthesis techniques and embedding strategies 纺织品和纳米纤维中的二氧化硅气凝胶:合成技术和包埋策略的综合综述
4区 工程技术 Q2 Agricultural and Biological Sciences Pub Date : 2023-11-03 DOI: 10.1080/00405000.2023.2274630
Prashant D. Jinde, M. Y. Gudiyawar
AbstractSilica aerogel is a remarkable material known for its exceptional thermal insulation properties and low density. The synthesis of silica aerogel involves a sol–gel process, which consists of gelation, aging, and drying steps. This process allows for the formation of a highly porous, interconnected network structure. Silica aerogel exhibits unique mechanical properties, such as high compressibility and brittleness, which can be improved through various reinforcement techniques. In this study, four different strategies for reinforcing silica aerogel to enhance its mechanical properties are reviewed. These strategies include the incorporation of hybridization of silica aerogels, compounding the silica network with a polymer, embedding fibers into a silica matrix, padding silica aerogel into multilayer nonwovens/nanofibers, and many more. Each method offers a distinct mechanism for reinforcing the aerogel matrix and improving its strength, flexibility, and durability. Moreover, the electrospinning process is explored as a method for fabricating silica aerogel-embedded nanofibers. Electrospinning equipment, including spinnerets and power supplies, is discussed, along with various techniques used to control fiber morphology and alignment. The integration of silica aerogel into nanofiber provides an opportunity to create lightweight, flexible composites with improved mechanical and thermal properties, making them promising materials for applications requiring efficient heat management that opens up avenues for various technological applications.Keywords: Silica aerogelsilica aerogel compositenanofiberneedle and needleless electrospinningthermal behavior of silica aerogelsilica aerogel in textile Disclosure StatementNo potential conflict of interest was reported by the author(s).
摘要二氧化硅气凝胶以其优异的保温性能和低密度特性而著称。二氧化硅气凝胶的合成涉及一个溶胶-凝胶过程,该过程包括凝胶化、老化和干燥步骤。这个过程允许形成一个高度多孔的,相互连接的网络结构。二氧化硅气凝胶具有独特的力学性能,如高压缩性和脆性,可以通过各种增强技术来改善。本文综述了四种增强二氧化硅气凝胶以提高其力学性能的不同策略。这些策略包括混合二氧化硅气凝胶、将二氧化硅网络与聚合物复合、将纤维嵌入二氧化硅基体、将二氧化硅气凝胶填充到多层非织造布/纳米纤维中等等。每种方法都提供了一种独特的机制来增强气凝胶基质,提高其强度、柔韧性和耐久性。此外,还探讨了静电纺丝法制备二氧化硅气凝胶包埋纳米纤维的方法。讨论了静电纺丝设备,包括喷丝器和电源,以及用于控制纤维形态和排列的各种技术。将二氧化硅气凝胶集成到纳米纤维中,为制造轻质、柔性的复合材料提供了机会,这种复合材料具有更好的机械和热性能,使其成为需要高效热管理的应用材料,为各种技术应用开辟了道路。关键词:二氧化硅气凝胶二氧化硅气凝胶复合材料纳米纤维针和无针电纺丝二氧化硅气凝胶在纺织品中的热行为披露声明作者未报告潜在的利益冲突。
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引用次数: 0
Naphthoquinone disperse dyes and their dyeing application to polyethylene terephthalate fabrics 萘醌分散染料及其在聚对苯二甲酸乙二醇酯织物上的染色应用
4区 工程技术 Q2 Agricultural and Biological Sciences Pub Date : 2023-11-02 DOI: 10.1080/00405000.2023.2271667
Nahide Gulsah Deniz, Aysegul Iscan, Cigdem Sayil, Ozan Avinc, Ece Kalayci
AbstractExamination of natural quinone dyes and their dyeing properties exist in the literature. However, disperse dyeing of synthetic quinone dyes on textile materials and examination of these properties are quite rare. In this study, the derivatives of new N-,O-heteroatom-substituted-1,4-naphthoquinone dyes were synthesized with the reactions between 2,3-dichloro-1,4-naphthoquinone with some aromatic and aliphatic N-nucleophiles according to Michael addition mechanism and the exact structure of dyes were specified by using various spectroscopic methods (FT-IR, 1H NMR, 13C NMR, MS, and UV/Vis.) and microanalyses. In the second step of this work, the polyethylene terephthalate fabrics were dyed with these newly synthesized disperse dyes. Dyeing performances such as dye exhaustion (%), color, and color fastness (to washing, alkaline perspiration, acidic perspiration, water, seawater, wet rub, dry rub, sublimation, and light fastness) properties of these dyes on PET fiber fabrics were investigated and compared. The highest color yield (K/S) by 12.33 was obtained with dye compound 10 at a dyeing depth of 3% owf and displayed better dyeing performance than the other dyes studied. In conclusion, PET fibers dyed with dye 2-4-(4-Chlorofenoxyaniline)-3-chloro-1,4-naphthoquinone (dye compound 10) displayed the highest dye exhaustion (%) values, the highest color yields, and excellent washing, perspiration (alkaline and acidic), water and seawater and rub (dry and wet) fastness values with no staining whatsoever.Keywords: Quinonesdyeing propertiescolor strengthfastness propertiesdisperse dyescolor yield Disclosure statementNo potential conflict of interest was reported by the authors.Additional informationFundingThe authors would like to express their gratitude to the Scientific Research Projects Coordination Unit of Istanbul University-Cerrahpasa for financial support (Project Number: FYL-2020-35257).
摘要已有文献对天然醌类染料及其染色性能进行了研究。然而,合成醌染料在纺织材料上的分散染色及其性能的研究却很少。本研究以2,3-二氯-1,4-萘醌为原料,根据Michael加成机理合成了N-, o-杂原子取代-1,4-萘醌染料衍生物,并通过FT-IR、1H NMR、13C NMR、MS、UV/Vis等多种光谱方法和微量分析确定了染料的确切结构。在本工作的第二步,用这些新合成的分散染料对聚对苯二甲酸乙二醇酯织物进行染色。考察并比较了这些染料在PET纤维织物上的染色性能,如染料耗损率(%)、色度、色牢度(耐洗涤、耐碱性汗、耐酸性汗、耐水、耐海水、耐湿摩擦、耐干摩擦、耐升华、耐光牢度)。在染深为3% owf时,化合物10的显色率(K/S)最高,为12.33,表现出较好的染色性能。综上所述,用染料2-4-(4-氯苯氧苯胺)-3-氯-1,4-萘醌(染料化合物10)染色的PET纤维表现出最高的染料耗光率(%),最高的显色率,并且具有良好的洗涤,排汗(碱性和酸性),水和海水以及摩擦(干和湿)牢度值,没有任何染色。关键词:醌类染色性能;色强牢度;分散染料;作者感谢伊斯坦布尔大学cerrahpasa科研项目协调单位的资金支持(项目编号:FYL-2020-35257)。
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Journal of the Textile Institute
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