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An Assessment of Commonly Used Equivalent Circuit Models for Corrosion Analysis: A Bayesian Approach to Electrochemical Impedance Spectroscopy 腐蚀分析中常用等效电路模型的评估:电化学阻抗光谱的贝叶斯方法
Pub Date : 2024-07-29 DOI: arxiv-2407.20297
Runze Zhang, Debashish Sur, Kangming Li, Julia Witt, Robert Black, Alexander Whittingham, John R. Scully, Jason Hattrick-Simpers
Electrochemical Impedance Spectroscopy (EIS) is a crucial technique forassessing corrosion of a metallic materials. The analysis of EIS hinges on theselection of an appropriate equivalent circuit model (ECM) that accuratelycharacterizes the system under study. In this work, we systematically examinedthe applicability of three commonly used ECMs across several typical materialdegradation scenarios. By applying Bayesian Inference to simulated corrosionEIS data, we assessed the suitability of these ECMs under different corrosionconditions and identified regions where the EIS data lacks sufficientinformation to statistically substantiate the ECM structure. Additionally, weposit that the traditional approach to EIS analysis, which often requiresmeasurements to very low frequencies, might not be always necessary tocorrectly model the appropriate ECM. Our study assesses the impact of omittingdata from low to medium-frequency ranges on inference results and reveals thata significant portion of low-frequency measurements can be excluded withoutsubstantially compromising the accuracy of extracting system parameters.Further, we propose simple checks to the posterior distributions of the ECMcomponents and posterior predictions, which can be used to quantitativelyevaluate the suitability of a particular ECM and the minimum frequency requiredto be measured. This framework points to a pathway for expediting EISacquisition by intelligently reducing low-frequency data collection andpermitting on-the-fly EIS measurements
电化学阻抗光谱法(EIS)是评估金属材料腐蚀情况的一项重要技术。对 EIS 的分析取决于选择一个合适的等效电路模型 (ECM),以准确描述所研究系统的特征。在这项工作中,我们系统地研究了三种常用 ECM 在几种典型材料降解情况下的适用性。通过将贝叶斯推理应用于模拟腐蚀 EIS 数据,我们评估了这些 ECM 在不同腐蚀条件下的适用性,并确定了 EIS 数据缺乏足够信息的区域,以便从统计学角度证实 ECM 结构。此外,我们还发现,传统的 EIS 分析方法通常需要测量非常低的频率,但并不总是有必要对适当的 ECM 进行正确建模。我们的研究评估了省略中低频数据对推理结果的影响,结果表明,可以省略相当一部分低频测量,而不会严重影响提取系统参数的准确性。这一框架指出了通过智能减少低频数据收集和允许即时 EIS 测量来加快 EIS 采集的途径
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引用次数: 0
Superuniversal Statistics of Complex Time-Delays in Non-Hermitian Scattering Systems 非赫米提散射系统中复杂时延的超通用统计
Pub Date : 2024-07-26 DOI: arxiv-2408.05343
Nadav Shaibe, Jared M. Erb, Steven M. Anlage
The Wigner-Smith time-delay of flux conserving systems is a real quantitythat measures how long an excitation resides in an interaction region. Thecomplex generalization of time-delay to non-Hermitian systems is still underdevelopment, in particular, its statistical properties in the short-wavelengthlimit of complex chaotic scattering systems has not been investigated. From theexperimentally measured multi-port scattering ($S$)-matrices of one-dimensionalgraphs, a two-dimensional billiard, and a three-dimensional cavity, wecalculate the complex Wigner-Smith ($tau_{WS}$), as well as each individualreflection ($tau_{xx}$) and transmission ($tau_{xy}$) time-delays. Thecomplex reflection time-delay differences ($tau_{delta R}$) between each portare calculated, and the transmission time-delay differences ($tau_{delta T}$)are introduced for systems exhibiting non-reciprocal scattering. Largetime-delays are associated with coherent perfect absorption, reflectionlessscattering, slow light, and uni-directional invisibility. We demonstrate thatthe large-delay tails of the distributions of the real and imaginary parts ofeach of these time-delay quantities are superuniversal, independent ofexperimental parameters: uniform attenuation $eta$, number of scatteringchannels $M$, wave propagation dimension $mathcal{D}$, and Dyson symmetryclass $beta$. This superuniversality is in direct contrast with thewell-established time-delay statistics of unitary scattering systems, where thetail of the $tau_{WS}$ distribution depends explicitly on the values of $M$and $beta$. Due to the direct analogy of the wave equations, the time-delaystatistics described in this paper are applicable to any non-Hermitianwave-chaotic scattering system in the short-wavelength limit, such as quantumgraphs, electromagnetic, optical and acoustic resonators, etc.
通量守恒系统的维格纳-史密斯(Wigner-Smith)时间延迟是一个实量,用于度量激发在相互作用区域的驻留时间。时间延迟在非赫米提系统中的复杂泛化仍处于发展阶段,特别是其在复杂混沌散射系统短波长极限中的统计特性尚未得到研究。根据实验测得的一维图形、二维台球和三维空腔的多端口散射($S$)矩阵,我们计算了复维格纳-史密斯($tau_{WS}$)以及每个单独的反射($tau_{xx}$)和透射($tau_{xy}$)时延。计算了每个端口之间的复合反射时延差($tau_{delta R}$),并为表现出非互易散射的系统引入了透射时延差($tau_{delta T}$)。大时延与相干完美吸收、无反射散射、慢光和单向隐形有关。我们证明了这些时间延迟量的实部和虚部分布的大延迟尾部是超普遍的,与实验参数无关:均匀衰减 $eta$、散射通道数 $M$、波传播维度 $mathcal{D}$和戴森对称类 $beta$。这种超普遍性与已确立的单元散射系统的时间延迟统计形成了直接对比,在单元散射系统中,$tau_{WS}$分布的尾部明确取决于$M$和$beta$的值。由于波方程的直接类比,本文描述的时延统计适用于短波长极限的任何非赫米梯波混沌散射系统,如量子图、电磁、光学和声学谐振器等。
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引用次数: 0
Towards unveiling the large-scale nature of gravity with the wavelet scattering transform 利用小波散射变换揭示万有引力的大尺度性质
Pub Date : 2024-07-26 DOI: arxiv-2407.18647
Georgios Valogiannis, Francisco Villaescusa-Navarro, Marco Baldi
We present the first application of the Wavelet Scattering Transform (WST) inorder to constrain the nature of gravity using the three-dimensional (3D)large-scale structure of the universe. Utilizing the Quijote-MG N-bodysimulations, we can reliably model the 3D matter overdensity field for the f(R)Hu-Sawicki modified gravity (MG) model down to $k_{rm max}=0.5$ h/Mpc.Combining these simulations with the Quijote $nu$CDM collection, we thenconduct a Fisher forecast of the marginalized constraints obtained on gravityusing the WST coefficients and the matter power spectrum at redshift z=0. Ourresults demonstrate that the WST substantially improves upon the 1$sigma$error obtained on the parameter that captures deviations from standard GeneralRelativity (GR), yielding a tenfold improvement compared to the correspondingmatter power spectrum result. At the same time, the WST also enhances theprecision on the $Lambda$CDM parameters and the sum of neutrino masses, byfactors of 1.2-3.4 compared to the matter power spectrum, respectively. Despitethe overall reduction in the WST performance when we focus on larger scales, itstill provides a relatively $4.5times$ tighter 1$sigma$ error for the MGparameter at $k_{rm max}=0.2$ h/Mpc, highlighting its great sensitivity to theunderlying gravity theory. This first proof-of-concept study reaffirms theconstraining properties of the WST technique and paves the way for excitingfuture applications in order to perform precise large-scale tests of gravitywith the new generation of cutting-edge cosmological data.
我们首次应用小波散射变换(WST),利用宇宙的三维(3D)大尺度结构来约束引力的性质。利用Quijote-MG N-bodysimulations,我们可以可靠地模拟f(R)Hu-Sawicki修正引力(MG)模型的三维物质超密度场,最小可达$k_{rm max}=0.5$ h/Mpc.将这些模拟与Quijote $nu$CDM 集合相结合,我们就可以利用WST系数和红移z=0时的物质功率谱对引力的边际约束进行费雪预测。我们的结果表明,在捕捉偏离标准广义相对论(GR)的参数上,WST大大改善了1$sigma$的误差,与相应的物质功率谱结果相比,WST改善了10倍。与此同时,WST还提高了$Lambda$CDM参数和中微子质量总和的精度,与物质功率谱相比分别提高了1.2-3.4倍。尽管当我们聚焦于更大尺度时,WST的整体性能有所下降,但它仍然在$k_{rm max}=0.2$ h/Mpc时为MG参数提供了相对较小的4.5/times$ 1$sigma$误差,突出了它对基础引力理论的极大敏感性。这项首次概念验证研究再次证实了WST技术的约束特性,并为今后的应用铺平了道路,以便利用新一代尖端宇宙学数据对引力进行精确的大尺度检验。
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引用次数: 0
Physics-guided machine learning predicts the planet-scale performance of solar farms with sparse, heterogeneous, public data 物理引导的机器学习利用稀疏、异构的公共数据预测太阳能发电场的地球级性能
Pub Date : 2024-07-25 DOI: arxiv-2407.18284
Jabir Bin Jahangir, Muhammad Ashraful Alam
The photovoltaics (PV) technology landscape is evolving rapidly. To predictthe potential and scalability of emerging PV technologies, a globalunderstanding of these systems' performance is essential. Traditionally,experimental and computational studies at large national research facilitieshave focused on PV performance in specific regional climates. However,synthesizing these regional studies to understand the worldwide performancepotential has proven difficult. Given the expense of obtaining experimentaldata, the challenge of coordinating experiments at national labs across apolitically-divided world, and the data-privacy concerns of large commercialoperators, however, a fundamentally different, data-efficient approach isdesired. Here, we present a physics-guided machine learning (PGML) scheme todemonstrate that: (a) The world can be divided into a few PV-specific climatezones, called PVZones, illustrating that the relevant meteorological conditionsare shared across continents; (b) by exploiting the climatic similarities,high-quality monthly energy yield data from as few as five locations canaccurately predict yearly energy yield potential with high spatial resolutionand a root mean square error of less than 8 kWhm$^{2}$, and (c) even withnoisy, heterogeneous public PV performance data, the global energy yield can bepredicted with less than 6% relative error compared to physics-basedsimulations provided that the dataset is representative. This PGML scheme isagnostic to PV technology and farm topology, making it adaptable to new PVtechnologies or farm configurations. The results encourage physics-guided,data-driven collaboration among national policymakers and researchorganizations to build efficient decision support systems for accelerated PVqualification and deployment across the world.
光伏(PV)技术的发展日新月异。要预测新兴光伏技术的潜力和可扩展性,就必须在全球范围内了解这些系统的性能。传统上,大型国家研究机构的实验和计算研究侧重于特定区域气候下的光伏性能。然而,要综合这些地区性研究来了解全球范围内的性能潜力却很困难。考虑到获取实验数据的费用、在政治分裂的世界中协调国家实验室实验的挑战以及大型商业运营商对数据隐私的担忧,我们需要一种根本不同的、数据高效的方法。在这里,我们提出了一种物理引导的机器学习(PGML)方案,以证明(a) 可以将全球划分为几个特定的光伏气候区,称为光伏区,说明各大洲共享相关的气象条件;(b) 通过利用气候的相似性,来自少至五个地点的高质量月度发电量数据可以准确预测年发电量潜力,具有较高的空间分辨率,均方根误差小于 8 kWhm$^{2}$,以及 (c) 只要数据集具有代表性,即使使用杂乱、异构的公共光伏性能数据,与基于物理的模拟相比,全球发电量的预测相对误差也小于 6%。这种 PGML 方案与光伏技术和电站拓扑结构无关,因此可适用于新的光伏技术或电站配置。研究结果鼓励国家政策制定者和研究机构之间开展以物理为指导、数据为驱动的合作,以建立高效的决策支持系统,加快全球的光伏认证和部署。
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引用次数: 0
Unraveling Complexity: Singular Value Decomposition in Complex Experimental Data Analysis 揭示复杂性:复杂实验数据分析中的奇异值分解
Pub Date : 2024-07-23 DOI: arxiv-2407.16267
Judith F. Stein, Aviad Frydman, Richard Berkovits
Analyzing complex experimental data with multiple parameters is challenging.We propose using Singular Value Decomposition (SVD) as an effective solution.This method, demonstrated through real experimental data analysis, surpassesconventional approaches in understanding complex physics data. Singular valuesand vectors distinguish and highlight various physical mechanisms and scales,revealing previously challenging elements. SVD emerges as a powerful tool fornavigating complex experimental landscapes, showing promise for diverseexperimental measurements.
分析具有多个参数的复杂实验数据具有挑战性。我们建议使用奇异值分解(SVD)作为有效的解决方案。通过实际实验数据分析证明,这种方法在理解复杂物理数据方面超越了传统方法。奇异值和向量区分并突出了各种物理机制和尺度,揭示了以前具有挑战性的元素。SVD 是导航复杂实验景观的强大工具,为各种实验测量带来了希望。
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引用次数: 0
Setting of the Poincaré section for accurately calculating the phase of rhythmic spatiotemporal dynamics 为准确计算节奏时空动态的相位而设置波因卡雷截面
Pub Date : 2024-07-22 DOI: arxiv-2407.16080
Takahiro Arai, Yoji Kawamura, Toshio Aoyagi
The synchronization analysis of limit-cycle oscillators is prevalent in manyfields, including physics, chemistry, and life sciences. It relies on the phasecalculation that utilizes measurements. However, the synchronization ofspatiotemporal dynamics cannot be analyzed because a standardized method forcalculating the phase has not been established. The presence of spatialstructure complicates the determination of which measurements should be usedfor accurate phase calculation. To address this, we explore a method forcalculating the phase from the time series of measurements taken at a singlespatial grid point. The phase is calculated to increase linearly between eventtimes when the measurement time series intersects the Poincar'e section. Thedifference between the calculated phase and the isochron-based phase, resultingfrom the discrepancy between the isochron and the Poincar'e section, isevaluated using a linear approximation near the limit-cycle solution. We foundthat the difference is small when measurements are taken from regions thatdominate the rhythms of the entire spatiotemporal dynamics. Furthermore, weinvestigate an alternative method where the Poincar'e section is applied tothe time series obtained through orthogonal decomposition of the entirespatiotemporal dynamics. We present two decomposition schemes that utilize theprincipal component analysis. For illustration, the phase is calculated fromthe measurements of spatiotemporal dynamics exhibiting target waves oroscillating spots, simulated by weakly coupled FitzHugh-Nagumoreaction-diffusion models.
极限周期振荡器的同步分析在物理、化学和生命科学等许多领域都很普遍。它依赖于利用测量进行的相位计算。然而,由于尚未建立相位计算的标准化方法,因此无法分析时空动态的同步性。空间结构的存在使确定应使用哪些测量值来精确计算相位变得更加复杂。为了解决这个问题,我们探索了一种从单个空间网格点的测量时间序列中计算相位的方法。当测量时间序列与 Poincar'e 截面相交时,相位在事件时间之间线性增加。计算相位与基于等时线的相位之间的差异,是由等时线与 Poincar'e 截面之间的差异引起的,使用极限周期解附近的线性近似值进行评估。我们发现,当从主导整个时空动态节奏的区域进行测量时,差异很小。此外,我们还研究了另一种方法,即将 Poincar'e 部分应用于通过对整个时空动态进行正交分解而获得的时间序列。我们提出了两种利用主要成分分析的分解方案。为了说明问题,我们通过弱耦合 FitzHugh-Nagumoreaction-diffusion 模型模拟的、表现出目标波或振荡点的时空动态测量来计算相位。
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引用次数: 0
Investigating the Event-Shape Methods in Search for the Chiral Magnetic Effect in Relativistic Heavy Ion Collisions 研究在相对论重离子碰撞中寻找手性磁效应的事件形状方法
Pub Date : 2024-07-19 DOI: arxiv-2407.14489
Han-Sheng Li, Yicheng Feng, Fuqiang Wang
Chiral Magnetic Effect (CME) is a phenomenon in which electric charge isseparated by a strong magnetic field from local domains of chirality imbalanceand parity violation in quantum chromodynamics (QCD). The CME-sensitiveobservable, charge-dependent three-point azimuthal correlator $Deltagamma$,is contaminated by a major physics background proportional to the particle'selliptic anisotropy $v_2$. Event-shape engineering (ESE) binning events indynamical fluctuations of $v_2$ and event-shape selection (ESS) binning eventsin statistical fluctuations of $v_2$ are two methods to search for the CME byprojecting $Deltagamma$ to the $v_2=0$ intercept. We conduct a systematicstudy of these two methods using physics models as well as toy modelsimulations. It is observed that the ESE method requires significantly morestatistics than the ESS method to achieve the same statistical precision of theintercept. It is found that the intercept from the ESS method depends on thedetails of the event content, such as the mixtures of background contributingsources, and thus is not a clean measure of the CME.
手性磁效应(CME)是指在量子色动力学(QCD)中,电荷被强磁场从手性不平衡和奇偶性违反的局部区域分离出来的现象。对 CME 敏感的可观测电荷相关三点方位角相关因子 $Deltagamma$ 受到与粒子的抛物线各向异性 $v_2$ 成比例的主要物理背景的污染。事件形状工程(ESS)在v_2$的非线性波动中对事件进行分选,以及事件形状选择(ESS)在v_2$的统计波动中对事件进行分选,是通过将$Deltagamma$投射到v_2=0$截距来寻找CME的两种方法。我们利用物理模型和玩具模型模拟对这两种方法进行了系统研究。结果表明,要达到相同的截距统计精度,ESE 方法需要的统计量明显多于 ESS 方法。研究还发现,ESS 方法的截距取决于事件内容的细节,如背景贡献源的混合物,因此不是对 CME 的精确测量。
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引用次数: 0
Theoretical Analysis on Block Time Distributions in Byzantine Fault-Tolerant Consensus Blockchains 拜占庭容错共识区块链的区块时间分布理论分析
Pub Date : 2024-07-19 DOI: arxiv-2407.14299
Akihiro Fujihara
Some blockchain networks employ a distributed consensus algorithm featuringByzantine fault tolerance. Notably, certain public chains, such as Cosmos andTezos, which operate on a proof-of-stake mechanism, have adopted thisalgorithm. While it is commonly assumed that these blockchains maintain anearly constant block creation time, empirical analysis reveals fluctuations inthis interval; this phenomenon has received limited attention. In this paper,we propose a mathematical model to account for the processes of blockpropagation and validation within Byzantine fault-tolerant consensusblockchains, aiming to theoretically analyze the probability distribution ofblock time. First, we propose stochastic processes governing the broadcastingcommunications among validator nodes. Consequently, we theoreticallydemonstrate that the probability distribution of broadcast time among validatornodes adheres to the Gumbel distribution. This finding indicates that thedistribution of block time typically arises from convolving multiple Gumbeldistributions. Additionally, we derive an approximate formula for the blocktime distribution suitable for data analysis purposes. By fitting thisapproximation to real-world block time data, we demonstrate the consistentestimation of block time distribution parameters.
一些区块链网络采用了具有拜占庭容错功能的分布式共识算法。值得注意的是,某些公有链采用了这种算法,如 Cosmos 和Tezos,它们采用的是权益证明机制。虽然人们通常认为这些区块链的区块创建时间几乎保持恒定,但实证分析表明,这个时间间隔会出现波动;这一现象受到的关注有限。在本文中,我们提出了一个数学模型来解释拜占庭容错共识区块链中的区块传播和验证过程,旨在从理论上分析区块时间的概率分布。首先,我们提出了验证器节点间广播通信的随机过程。因此,我们从理论上证明了验证器节点间广播时间的概率分布符合 Gumbel 分布。这一发现表明,块时间的分布通常是由多个冈贝尔分布卷积而成的。此外,我们还推导出了适用于数据分析的块时间分布近似公式。通过将该近似公式拟合到真实世界的块时间数据中,我们证明了对块时间分布参数的一致估计。
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引用次数: 0
Measuring dynamical phase transitions in time series 测量时间序列中的动态相变
Pub Date : 2024-07-18 DOI: arxiv-2407.13452
Bulcsú Sándor, András Rusu, Károly Dénes, Mária Ercsey-Ravasz, Zsolt I. Lázár
There is a growing interest in methods for detecting and interpreting changesin experimental time evolution data. Based on measured time series, thequantitative characterization of dynamical phase transitions at bifurcationpoints of the underlying chaotic systems is a notoriously difficult task.Building on prior theoretical studies that focus on the discontinuities at$q=1$ in the order-$q$ R'enyi-entropy of the trajectory space, we measure thederivative of the spectrum. We derive within the general context of Markovprocesses a computationally efficient closed-form expression for this measure.We investigate its properties through well-known dynamical systems exploringits scope and limitations. The proposed mathematical instrument can serve as apredictor of dynamical phase transitions in time series.
人们对检测和解释实验时间演化数据变化的方法越来越感兴趣。基于测得的时间序列,对底层混沌系统分叉点的动态相变进行定量表征是一项众所周知的艰巨任务。先前的理论研究侧重于轨迹空间的阶次-q$ R'enyi-entropy 在 q=1$ 时的不连续性,在此基础上,我们对频谱的阶次-q$ R'enyi-entropy 进行了测量。我们在马尔可夫过程的一般背景下推导出了这种度量的计算效率闭式表达式,并通过著名的动力学系统探索其范围和局限性,研究其特性。所提出的数学工具可以作为时间序列中动态相变的预测器。
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引用次数: 0
False positives for gravitational lensing: the gravitational-wave perspective 引力透镜的假阳性:引力波视角
Pub Date : 2024-07-17 DOI: arxiv-2407.12974
David Keitel
For the first detection of a novel astrophysical phenomenon, scientificstandards are particularly high. Especially in a multi-messenger context, thereare also opportunity costs to follow-up observations on any detection claims.So in searching for the still elusive lensed gravitational waves, care needs tobe taken in controlling false positives. In particular, many methods foridentifying strong lensing rely on some form of parameter similarity orwaveform consistency, which under rapidly growing catalog sizes can expose themto false positives from coincident but unlensed events if proper care is nottaken. And searches for waveform deformations in all lensing regimes aresubject to degeneracies we need to mitigate between lensing, intrinsicparameters, insufficiently modelled effects such as orbital eccentricity, oreven deviations from general relativity. Robust lensing studies also requireunderstanding and mitigating glitches and non-stationarities in the detectordata. This article reviews sources of possible false positives (and their flipside: false negatives) in gravitational-wave lensing searches and the mainapproaches the community is pursuing to mitigate them.
对于首次探测到新的天体物理现象,科学标准特别高。特别是在多信使的情况下,对任何探测结果进行后续观测都需要付出机会成本。因此,在寻找仍然难以捉摸的透镜引力波时,需要注意控制假阳性。特别是,许多识别强透镜的方法都依赖于某种形式的参数相似性或波形一致性,在星表规模快速增长的情况下,如果不加以适当的注意,就会暴露在来自重合但未透镜事件的误报中。而且,在所有透镜状态下对波形变形的搜索,都会受到我们需要缓解的透镜、固有参数、未充分建模的效应(如轨道偏心率),甚至广义相对论偏差之间的退行性的影响。稳健的透镜研究还需要了解并减少探测数据中的故障和非稳态现象。这篇文章回顾了引力波透镜搜索中可能出现假阳性(及其反面:假阴性)的原因,以及研究界为减少这些原因而采取的主要方法。
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引用次数: 0
期刊
arXiv - PHYS - Data Analysis, Statistics and Probability
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