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Leave no stone unturned: Exploring the metaproteome of beerstone for the identification of archaeological beer production 不遗余力:探索啤酒石的元蛋白组以鉴定考古啤酒的生产
IF 2.6 1区 地球科学 Q1 ANTHROPOLOGY Pub Date : 2024-07-10 DOI: 10.1016/j.jas.2024.106019
Lindsey Paskulin , Krista McGrath , Richard Hagan , Camilla Speller , Marian Berihuete-Azorín , Hans-Peter Stika , Soultana-Maria Valamoti , Jessica Hendy

In archaeological contexts, identifying processes of beer production and consumption has contributed to our understanding of agriculture, labor mobilization, economic surplus, feasting, gender dynamics, social structure, tribute, community, identity and politics. Nevertheless, in the absence of pictorial representations and characteristic objects, beer brewing is difficult to identify in the archaeological record, and molecular methods are often limited by constraints of preservation and specificity. A potential target for studies of ancient beer production are residues formed during brewing activity, including beerstone, a calcium oxalate residue. Here, we apply shotgun proteomics analyses to a sample of modern beerstone to explore this residue's capacity as a marker for beer in archaeological contexts. The beerstone proteome was compared to the protein profiles of ungerminated and germinated barley to identify key proteins indicative of malted grains which may be encased by the residue. Proteins matching to barley grain (Hordeum vulgare) and Baker's/Brewer's yeast (Saccharomyces cerevisiae) were successfully identified in the beerstone. In particular, we identified hordeins, lipid transfer proteins, trypsin/α-amylase inhibitors, and protein Z, which are barley proteins abundant in proteomic characterisations of beer. In comparison to ungerminated and germinated barley grains, we find that beerstone preserves only a subset of the barley proteome, with the residue being more reflective of the final brewing product than of earlier brewing steps such as malting. Overall, we demonstrate that beerstone has potential to entrap and preserve proteins reflective of the beer-making process and identify proteins that we might anticipate in future archaeological analyses.

在考古学背景下,确定啤酒的生产和消费过程有助于我们了解农业、劳动力动员、经济盈余、盛宴、性别动态、社会结构、贡品、社区、身份和政治。然而,由于缺乏图像和特征物品,啤酒酿造在考古记录中很难确定,分子方法往往受到保存和特异性的限制。研究古代啤酒生产的一个潜在目标是酿造活动中形成的残留物,包括啤酒石(一种草酸钙残留物)。在这里,我们对现代啤酒石样本进行了枪弹蛋白质组学分析,以探索这种残留物作为考古背景下啤酒标记物的能力。我们将啤酒石蛋白质组与未发芽和已发芽大麦的蛋白质图谱进行了比较,以确定表明可能被残留物包裹的麦芽颗粒的关键蛋白质。在啤酒石中成功鉴定出了与大麦粒(Hordeum vulgare)和面包酵母/酿酒酵母(Saccharomyces cerevisiae)相匹配的蛋白质。特别是,我们鉴定出了大麦蛋白酶、脂质转移蛋白、胰蛋白酶/α-淀粉酶抑制剂和蛋白 Z,这些都是在啤酒蛋白质组学特征中含量丰富的大麦蛋白。与未发芽和已发芽的大麦粒相比,我们发现啤酒石只保留了大麦蛋白质组的一部分,其残留物更多反映的是最终酿造产品,而不是发芽等早期酿造步骤。总之,我们证明了啤酒石具有捕获和保存反映啤酒酿造过程的蛋白质的潜力,并确定了我们在未来考古分析中可能会发现的蛋白质。
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引用次数: 0
Crafting illusions: Human-made composite coating used to simulate amber beads in prehistoric Iberia 制造幻象:史前伊比利亚用于模拟琥珀珠的人造复合涂层
IF 2.6 1区 地球科学 Q1 Social Sciences Pub Date : 2024-06-22 DOI: 10.1016/j.jas.2024.106011
Carlos P. Odriozola , José Ángel Garrido-Cordero , Ana C. Sousa , José María Martínez-Blanes , Galo Romero-García , Daniel Sánchez-Gómez , Manel Edo i Benaigues , Diego Romero-Vera , María Dolores Simón-Vallejo , María Dolores Zambrana Vega , José Luis Molina González

The discovery of a set of beads, comprising both Sicilian amber and resin-coated beads in the Middle Bronze Age burial site of Cova del Gegant (Sitges, Barcelona, Spain), has sparked inquiries into whether the coating was intended for imitation or counterfeiting of amber. We assert that human-made materials, such as bead coatings, are intentionally conceived, designed, and crafted to fulfill specific functions. Thus, for an object to effectively fulfill its intended purpose, it must meet particular performance criteria influenced by situational factors.

This paper aims to construct an empirically grounded narrative elucidating the development and function of resin-coated bead technology. Our methodology includes a comprehensive quantitative analysis of the coating and beads, an exploration of the interplay between technical choices and situational factors, and an investigation into whether the simulation of sensory performance characteristics played a pivotal role in the concept and design of resin-coated beads. Additionally, we synthesize data to unveil broader patterns related to the crafting and utilization of resin-coated and amber beads across time and space.

We have documented resin-coated beads in the Iberian Peninsula from the Neolithic period (5th to 3rd millennia BCE) until at least the Middle Bronze Age (first half of the 2nd millennium BCE), where they coexisted with amber beads. Analysis employing ATR-FTIR and μ-CT imaging has revealed a composite coating comprising pine resin, beeswax, and carotene, adhered to shell beads with bone glue. This composite material represents the earliest known development in human history, unique to the Iberian Peninsula and without parallel in Prehistoric Europe.

Our examination of the performance characteristics and functional roles of resin-coated beads suggests their potential as substitutes for amber beads, particularly in regions where amber was scarce or inaccessible. Despite being crafted from commonplace materials, these coated beads exhibit intentional design choices likely aimed at simulating the visual performance characteristics of amber. This deliberate effort, alongside their widespread distribution across time and space, indicates that composite-coated beads held symbolic and social significance akin to amber beads.

在中青铜时代的科瓦德尔格甘特(西班牙巴塞罗那锡切斯)墓葬遗址中发现了一套珠子,包括西西里琥珀和树脂涂层珠子,这引发了人们对涂层是否用于仿制或伪造琥珀的探究。我们认为,人类制造的材料,如珠子涂层,都是为了实现特定功能而有意构思、设计和制作的。因此,一件物品要有效实现其预期目的,就必须满足受环境因素影响的特定性能标准。
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引用次数: 0
Violent death of a warrior in the destruction of Roca Vecchia, Apulia, Italy: Insights on hostilities and Aegean connections in the Bronze Age 意大利阿普利亚 Roca Vecchia 毁坏事件中一名战士的暴力死亡:青铜时代敌对行动与爱琴海联系的启示
IF 2.8 1区 地球科学 Q1 Social Sciences Pub Date : 2024-06-08 DOI: 10.1016/j.jas.2024.106009
G. Vincenti , R. Guglielmino , D. Panetta , P.A. Salvadori , L. Reitsema , J. Krigbaum , K.L. Reinberger , D. Melica , M. Lettieri , M. Masieri , P.F. Fabbri

This study recreates aspects of the life and death of a young adult male who died during the siege of Roca Vecchia, a Bronze Age fortified coastal site in Italy. The partially charred and unburied individual, Roca US813A, was found among the debris in the southern room of the main gate to the city.

This paper highlights information that can be retrieved from a single partially preserved skeleton. Detailed bioarchaeological, forensic, and taphonomic analysis, and thorough examination of archaeological and contextual data permit an osteobiography of this individual to be developed, which we situate in the overall picture of Middle Bronze Age regional events and exchanges between Italy and the Aegean world.

This individual represents a unique example of information derived from bones from an archaeological context. After suffering fatal blows to the body, the individual was accidently exposed to heat. This allowed us to analyze wounds that had undergone thermal alteration. Since the combustion of the body was only partial and the same bone retains both highly burned and unburned parts, we were able to document the variations induced by heat at a macroscopic and microscopic level.

To investigate the circumstances of his death, we focus on macroscopic and microscopic details of taphonomy and trauma using micro-CT, forensic, and multi-isotopic analysis. This may be the first secure evidence of a Middle Bronze Age (MBA) war casualty in Italy. In addition to detailed information about their manner of death, we discuss implications for the peopling of the site, tactics in Bronze Age warfare, and the nature of relations between Roca and the Aegean region.

这项研究再现了一名青壮年男性的生平和死亡经历,这名男性死于意大利青铜时代海岸防御工事遗址罗卡维奇亚(Roca Vecchia)被围攻期间。这具名为 Roca US813A 的骸骨部分烧焦且未下葬,是在通往该城的正门南侧房间的废墟中发现的。通过详细的生物考古学、法医学和陶器学分析,以及对考古学和背景资料的深入研究,我们得以绘制出这具骸骨的骨传记,并将其置于青铜时代中期意大利与爱琴海世界之间的地区事件和交流的全貌中。在身体遭受致命打击后,这个人意外地暴露在高温下。这使我们能够分析经过热改变的伤口。由于尸体只是部分燃烧,而且同一块骨头既保留了高度燃烧的部分,也保留了未燃烧的部分,因此我们能够在宏观和微观层面上记录热引起的变化。这可能是意大利青铜时代中期(MBA)战争伤亡人员的首个可靠证据。除了他们死亡方式的详细信息外,我们还讨论了该遗址的人口、青铜时代的战争战术以及罗卡与爱琴海地区关系的性质等方面的影响。
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引用次数: 0
Ancient DNA reveals the origin and history of early dogs in northeastern China 古代DNA揭示了中国东北地区早期狗的起源和历史
IF 2.8 1区 地球科学 Q1 Social Sciences Pub Date : 2024-06-07 DOI: 10.1016/j.jas.2024.106010
Xingcheng Wang , Wenqi Wei , Ning Kang , Naifan Zhang , Zhuowei Tang , Quanjia Chen , Lixin Wang , Wei Zhang , He Tian , Wei Liu , Dawei Cai

Research has suggested that domestic dogs may have undergone simultaneous domestication in both the eastern and western parts of the Eurasian continent. Alternatively, domestication may have originated in the eastern part of Eurasia and subsequently spread westwards. The northeastern region of China, which serves as a link between the expansive Eurasian steppe and the northern regions of China, is of paramount importance for investigating the origin and domestication of dogs. To establish a precise spatiotemporal framework for the genetic history of ancient dogs in China, this study conducted mitochondrial genome analysis on 110 samples obtained from five archaeological sites in the northeastern region of China, spanning from the Neolithic period to the Bronze Age. This study reveals the developmental history of domestic dogs in the Northeast region, emphasizing the close connections between domestic dogs in Northeast China approximately 10,000 to 7000 years ago and ancient domestic dogs from the Siberian Arctic and the Americas. Furthermore, around 6000 years ago, domestic dogs from the Yangtze and Yellow River basins in China gradually spread to Northeast China, leading to the replacement of the original domestic dog haplotypes. These findings provide new insights into the early spread and diffusion of domestic dogs, as well as the origin and domestication of ancient dogs in China, contributing to a more comprehensive understanding of this phenomenon.

研究表明,家犬可能是在欧亚大陆的东部和西部同时被驯化的。或者,驯化可能起源于欧亚大陆东部,随后向西传播。中国东北地区是连接广袤的欧亚大草原和中国北方地区的纽带,对研究狗的起源和驯化至关重要。为了建立中国古代狗遗传史的精确时空框架,本研究对从中国东北地区五个考古遗址中获得的 110 个样本进行了线粒体基因组分析,时间跨度从新石器时代到青铜时代。该研究揭示了东北地区家犬的发展历史,强调了距今约1万年至7000年前中国东北地区的家犬与西伯利亚北极地区和美洲古代家犬之间的密切联系。此外,距今约6000年前,中国长江流域和黄河流域的家犬逐渐扩散到中国东北地区,导致原始家犬单倍型的更替。这些发现为家犬的早期传播和扩散,以及中国古代家犬的起源和驯化提供了新的见解,有助于更全面地了解这一现象。
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引用次数: 0
Lost-wax casting: A widespread technique to produce copper alloy adornments in Atlantic Europe since the mid-second millennium BC 失蜡铸造:自公元前两千年中期以来,欧洲大西洋地区普遍采用这种技术来制作铜合金装饰品
IF 2.8 1区 地球科学 Q1 Social Sciences Pub Date : 2024-06-04 DOI: 10.1016/j.jas.2024.106008
Marilou Nordez

Lost-wax casting is a metalworking technique that has long been regarded as an innovation imported from the eastern Mediterranean and only widely used in Western Europe since the Late Bronze Age. We now have evidence that this technique was in fact largely in use from the Middle Bronze Age onwards for the production of copper alloy adornments in the Atlantic area. Along with palstaves, these objects are the most abundant in Atlantic hoards from the 15th to the 13th centuries BC. Thanks to detailed morphological and technological study, combined with an experimental approach and analysis of their elemental composition, we can propose new chaînes opératoires for the manufacture of massive annular bracelets with geometric decoration.

失蜡铸造是一种金属加工技术,长期以来一直被认为是从地中海东部传入的创新技术,自青铜时代晚期才在西欧广泛使用。我们现在有证据表明,实际上从青铜时代中期开始,大西洋地区就已经在很大程度上使用这种技术来制作铜合金装饰品。在公元前 15 世纪到公元前 13 世纪的大西洋囤积品中,这些器物与棕榈杖一起最为丰富。通过详细的形态和技术研究,并结合实验方法和元素成分分析,我们可以为制造带有几何装饰的大型环形手镯提出新的操作方法。
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引用次数: 0
On Liangzhu Culture Tremolite-Tempered Pottery: Social complexity, logistical networks and cross-craft interaction in Neolithic China 论良渚文化透闪石陶器:中国新石器时代的社会复杂性、物流网络和跨工艺互动
IF 2.8 1区 地球科学 Q1 Social Sciences Pub Date : 2024-05-31 DOI: 10.1016/j.jas.2024.106000
Xiaohan Zhao , Ye Zhao , Xiaoli Qin , Rong Wang

This investigation delves into the utilization of tremolite, a rare mineral, as a pottery temper for cooking vessels of the late Neolithic lower Yangtze Liangzhu culture. Raman spectroscopy analysis of 165 mineral-tempered pottery sherds from the Dazemiao site revealed that tremolite was the predominant tempering material for tripods (ding), whereas a mixture of feldspar and quartz was used for open-topped vats (da-kou-gang). SEM images indicate that the tremolite temper exhibits relatively coarse fiber structure, corresponding to one of the nephrite materials used for the Liangzhu jade. It is suggested that the Liangzhu miners reallocated materials according to nephrite quality, formulating different product lines, including different types of jade objects and pottery temper. Additionally, the utilization of tremolite temper persisted throughout the entire Liangzhu culture. The presence of tremolite-tempered pottery in regions without indigenous tremolite mines necessitated robust logistical networks for the transportation of these bulky materials. The tremolite temper not only reconfirms the strong ‘jade culture’ of Liangzhu, but also provides evidence of extensive socio-economic exchanges between different geographical regions on the Yangtze River delta.

本研究探讨了新石器时代晚期长江下游良渚文化利用透闪石这种稀有矿物作为陶器回火材料的情况。对大庙遗址出土的 165 件矿物调质陶器碎片进行的拉曼光谱分析表明,透闪石是鼎(鼎)的主要调质材料,而长石和石英的混合物则用于敞口大缸(大口缸)。扫描电子显微镜图像显示,透闪石回火呈现出相对较粗的纤维结构,与良渚玉器所用的软玉材料之一相对应。这表明良渚玉器的开采者根据软玉的质量重新分配材料,形成了不同的产品系列,包括不同类型的玉器和陶器。此外,透闪石质地的利用贯穿整个良渚文化。在没有本地透闪石矿的地区出现透闪石质陶器,就需要有强大的物流网络来运输这些笨重的材料。透闪石质陶不仅再次印证了良渚文化中浓厚的 "玉文化",也为长江三角洲不同地域之间广泛的社会经济交流提供了证据。
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引用次数: 0
Micro-photogrammetry and traceology: new on-site documentation approaches using portable digital microscopes 显微摄影测量和痕迹学:使用便携式数码显微镜的新现场记录方法
IF 2.8 1区 地球科学 Q1 Social Sciences Pub Date : 2024-05-30 DOI: 10.1016/j.jas.2024.106004
Giulia Previti, Beatrice Luci, Cristina Lemorini

This paper introduces a novel micro-photogrammetric application for the examination of technological traces using a portable digital microscope. The aim is to evaluate its potential, advantages, and level of detail within the context of traceology studies, highlighting its importance in particular for field documentation of unmovable items. The technique is non-invasive and applicable to samples that cannot be transported outside their regions/countries of origin.

Moreover, this methodological presentation aims to provide an extensive account of the utilized technology, the accessories, the possible uses and a series of experiments designed to replicate environmental and logistical conditions commonly encountered in the field.

The goal is also to compare a 3D model obtained with a portable digital microscope to one obtained with a camera equipped with a macro lens, in order to highlight the level of detail achieved in trace visualization.

The results are also expanded and discussed, including an examination of an archaeological case study. Additionally, to evaluate the validity and accuracy of the detected traces, the data obtained has been analyzed in the context of a qualitative assessment conducted using a stereomicroscope coupled with an optical fiber reflected light system.

本文介绍了使用便携式数码显微镜检查技术痕迹的新型微观摄影测量应用。目的是评估其在痕迹学研究方面的潜力、优势和详细程度,特别强调其对不可移动物品实地记录的重要性。该技术是非侵入性的,适用于无法运出原产地/原产国的样本。
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引用次数: 0
Neanderthal hunting grounds: The case of Teixoneres Cave (Spain) and Pié Lombard rockshelter (France) 尼安德特人的狩猎场:特克索内雷洞穴(西班牙)和皮埃隆巴德岩洞(法国)的案例
IF 2.8 1区 地球科学 Q1 Social Sciences Pub Date : 2024-05-29 DOI: 10.1016/j.jas.2024.106007
Antigone Uzunidis , Ruth Blasco , Jean-Philip Brugal , Tiffanie Fourcade , Juan Ochando , Jordi Rosell , Audrey Roussel , Anna Rufà , Maria Fernanda Sánchez Goñi , Pierre-Jean Texier , Florent Rivals

The study of Neanderthal-Environment interactions very often lacks precise data that match the chrono-geographical frame of human activities. Here, we reconstruct Neanderthals’ hunting grounds within three distinct habitats using dental microwear analysis combined with zooarchaeological data. The predation patterns toward ungulates are discussed in term of frequency (NISP/MNI) and potential meat intake (MAM). Unit IIIa of Teixoneres Cave (MIS 3, NE Spain) corresponds to a mosaic landscape, Unit IIIb was more forested, and, in the “Ensemble” II of Pié Lombard (MIS 4, SE France), forest cover dominated. At Pié Lombard, Neanderthals rely on a high diversity of taxa from closed and semi-open hunting grounds, mostly two ungulate species as well as rabbits and several bird taxa. At Teixoneres Cave, mainly open areas are exploited in summer with a predation mostly focused on large gregarious ungulates. The larger size of ungulate herds in open spaces may have allowed Neanderthals to restrict their subsistence behaviour only to very few species, in specific hunting strategies. In Unit IIIa, they do not appear to have made any selection within the most abundant species, while in Unit IIIb, they focused on aurochs and also opportunistically and heavily on newborn red deer. Neanderthal subsistence strategies seem, therefore, only partially linked to the hunting grounds they had access to. While it impacted the diversity of the prey they selected, Neanderthal groups were able to develop distinct hunting strategies within similar environments.

尼安德特人与环境互动的研究往往缺乏与人类活动的时间地理框架相匹配的精确数据。在这里,我们利用牙齿微磨损分析和动物考古学数据重建了尼安德特人在三个不同栖息地的狩猎场。我们从捕食频率(NISP/MNI)和潜在食肉量(MAM)两个方面讨论了尼安德特人对有蹄类动物的捕食模式。Teixoneres洞穴(MIS 3,西班牙东北部)的IIIa单元为马赛克地貌,IIIb单元森林覆盖率较高,而在Pié Lombard(MIS 4,法国东南部)的 "组合 "II单元,森林覆盖率占主导地位。在 Pié Lombard,尼安德特人依赖于封闭和半开放狩猎场的多种分类群,主要是两种有蹄类动物、兔子和几种鸟类。在特克索内尔斯洞穴,夏季主要是在开阔地狩猎,捕食对象主要是大型群居蹄类动物。开阔地上的大型蹄类动物群可能使尼安德特人在特定的狩猎策略中将其生存行为限制在极少数物种上。在IIIa单元,尼安德特人似乎没有对最丰富的物种进行任何选择,而在IIIb单元,尼安德特人则主要捕食驼鹿,并伺机大量捕食新生红鹿。因此,尼安德特人的生存策略似乎只与他们能够进入的狩猎场有部分联系。虽然尼安德特人所选择的猎物的多样性受到影响,但尼安德特人群体能够在相似的环境中发展出不同的狩猎策略。
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引用次数: 0
SPEED-E: A modified version of the sample preparation by Easy extraction and Digestion(-free) protocol for enamel-based sex estimation in archaeological remains SPEED-E:用于考古遗存中基于珐琅质的性别估计的 "简易提取和消化(-free)"样本制备方案的改进版
IF 2.8 1区 地球科学 Q1 Social Sciences Pub Date : 2024-05-25 DOI: 10.1016/j.jas.2024.106006
Timothy P. Cleland , Sara A. McGuire , Jared S. Beatrice , Kimberlee S. Moran , Christine A.M. France

Accurate estimation of biological sex in archaeological human remains is critical when considering demographic, resource partitioning, and various sex-based cultural issues in historic societies. Recent developments in paleoproteomics of enamel have allowed for the estimation of biological sex through sex chromosome-linked amelogenins. This method is highly advantageous when traditional osteological sex estimation is precluded by incompleteness, poor preservation, or juvenile age. Here, we have developed Sample Preparation by Easy Extraction and Digestion-free for Enamel (SPEED-E), building on the Sample Preparation by Easy Extraction and Digestion (SPEED) method and direct stage tip clean-up used in paleoproteomic studies. The SPEED-E protocol is similar in extraction time to acid etching protocols, is overall much shorter than digestion-based protocols, and uses relatively less sample. This new method facilitates a rapid analysis of large sample batches where sample value is high and sample material is very limited. Using SPEED-E, we were able to estimate the sex of 85 of 89 deciduous and permanent teeth from the assemblage of archaeological human skeletal remains from the historic First Baptist Church of Philadelphia, Pennsylvania, USA. The indeterminate teeth had limited or no detected amelogenins because of overprinting larger proteins, likely from sampled dentin.

在考虑历史社会中的人口、资源分配和各种基于性别的文化问题时,准确估计考古人类遗骸中的生物性别至关重要。珐琅质古蛋白质组学的最新发展使得我们可以通过与性染色体相连的珐琅质酶原来估计生物性别。当传统的骨学性别估计因不完整、保存不善或幼年而无法进行时,这种方法就非常有优势。在此,我们在古蛋白质组研究中使用的简易提取和消化样品制备(SPEED)方法和直接阶段尖端清理的基础上,开发了釉质的简易提取和免消化样品制备(SPEED-E)。SPEED-E 方法的提取时间与酸蚀刻方法相似,总体上比基于消化的方法短得多,而且样品用量相对较少。这种新方法有助于快速分析样品价值高、样品材料非常有限的大批量样品。利用 SPEED-E,我们能够估算出美国宾夕法尼亚州费城历史上第一浸信会教堂考古人类骨骼遗骸中 89 颗落叶牙和恒牙中 85 颗的性别。不确定的牙齿检测到的淀粉样蛋白有限或没有检测到淀粉样蛋白,这是因为较大的蛋白质可能来自取样的牙本质。
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引用次数: 0
Multiple luminescence dating on heated materials at the nanzuo archaeological site, central Chinese Loess Plateau 中国黄土高原中部南佐考古遗址受热材料的多重发光测年法
IF 2.8 1区 地球科学 Q1 Social Sciences Pub Date : 2024-05-24 DOI: 10.1016/j.jas.2024.106005
Daobin Tang , Xiangjun Liu , Guanghui Dong , Jianye Han , Xiaoning Zhang , Kartika Goswami , Xianjiao Ou

Nanzuo is a key Neolithic archaeological site in the central Chinese Loess Plateau (CCLP). The site is important for understanding the origin and development of the Chinese civilization, yet, it lacks a robust chronological framework. The current work, for the first time, dates two different types of heated materials (pottery and burnt soil) from a profile near the main excavation of the Nanzuo archaeological site using various luminescence dating techniques. These techniques included single grain (SG) quartz OSL and K-feldspar post-infrared infrared-stimulated (pIRIR) dating for burnt soil samples and pottery, and pIRIR dating for pottery slices using the rock surface luminescence technique (RSL). The reliability of luminescence dating was investigated by comparing SG quartz, K-feldspar and pottery slice ages with radiocarbon (14C) ages obtained from the same cultural layer. The results show that the SG quartz OSL and K-feldspar pIRIR225 age estimates of the two coarse potteries are consistent with the 14C ages, however, the age estimates of the pottery slice (NZ22-CPS150) are significantly younger, which is primarily explained by underestimation in equivalent doses (De). Moreover, it is noted that while there is a considerable variation in the De of coarse pottery slices with depth, no significant correlation is observed between K- content and De. Heterogeneous K content was revealed by μ-XRF scanning on coarse pottery slices. Conversely, fine pottery displayed homogeneous K-content distribution and age estimates consistent with the 14C ages. Thus fine pottery slices are suggested to be more suitable for pIRIR dating relative to coarse pottery slices. The underestimation of De values in mixed minerals is observed as the primary reason for underestimated slice ages compared to SG K-feldspar, with grain size of K-feldspar and K content variation playing only a minor role. Therefore, by integrating the 14C ages with the luminescence ages of the pottery, it is inferred that human occupation of the Nanzuo site occurred around 5100 to 4500 years ago, which aligns with the 14C ages obtained from the main section of the Nanzuo site. The current work further concludes that the single-grain luminescence dating method is reliable for pottery. The study recommends to prioritize materials characterized by relatively uniform potassium (K) content for pIRIR dating using pottery slices.

南佐是中国黄土高原中部一处重要的新石器时代考古遗址。该遗址对了解中华文明的起源和发展非常重要,但却缺乏一个强有力的年代框架。本次研究首次使用各种发光测年技术对南召考古遗址主发掘区附近剖面上两种不同类型的受热材料(陶器和烧土)进行了测年。这些技术包括对烧土样本和陶器进行单颗粒(SG)石英 OSL 和 K 长石后红外激发(pIRIR)测年,以及利用岩石表面发光技术(RSL)对陶片进行 pIRIR 测年。通过将 SG 石英、钾长石和陶片的年代与同一文化层的放射性碳(14C)年代进行比较,研究了发光测年的可靠性。结果表明,两件粗陶器的 SG 石英 OSL 和 K 长石 pIRIR225 年龄估计值与 14C 年龄一致,但陶片(NZ22-CPS150)的年龄估计值明显偏小,主要原因是等效剂量(De)估计不足。此外,虽然粗陶片的 De 随深度变化很大,但钾含量与 De 之间没有明显的相关性。μ-XRF扫描显示,粗陶片的钾含量不均匀。相反,细陶显示出均匀的钾含量分布和与 14C 年龄一致的年龄估计。因此,与粗陶片相比,细陶片更适合进行 pIRIR 测定。与 SG K 长石相比,混合矿物中的 De 值被低估是造成切片年代被低估的主要原因,而 K 长石的粒度和 K 含量的变化仅起次要作用。因此,通过将 14C 年龄与陶器的发光年龄相整合,可以推断南左遗址的人类活动发生在距今约 5100 至 4500 年之间,这与南左遗址主断面获得的 14C 年龄相吻合。目前的工作进一步得出结论,单颗粒发光测年法对于陶器是可靠的。研究建议优先使用钾(K)含量相对均匀的材料,利用陶片进行 pIRIR 测定。
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Journal of Archaeological Science
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