Pub Date : 2024-06-01DOI: 10.3390/lubricants12060200
S. Makowski, Fabian Härtwig, M. Soldera, Mahmoud Ojeil, L. Lorenz, Frank Kaulfuß, A. Lasagni
Vacuum and air atmospheres impose very different requirements on tribological-loaded contacts, which usually require different surface materials. While hard tetrahedral amorphous carbon (ta-C) coatings provide good tribological properties in air, soft coatings such as molybdenum disulfide (MoS2) work well in a vacuum. Tribological performance in the respective other environment, however, is poor. In this work, the combination of laser microstructured (direct laser interference patterning) steel substrates and the deposition of ta-C and MoSx coatings with vacuum arc evaporation (LaserArc™) was studied, resulting in steel/DLIP, steel/DLIP/ta-C, steel/DLIP/MoSx, steel/DLIP/ta-C/MoSx, and steel/MoSx surface combinations. The tribological properties were studied using a ball-on-disk tribometer with a steel ball counter body in air and in a vacuum (p < 5 × 10−7 mbar). The type of the topmost coating governed their tribological properties in the respective atmosphere, and no general beneficial influence of the microstructure was found. However, steel/DLIP/ta-C/MoSx performed best in both conditions and endured the highest contact pressure, which is attributed to the mechanical support of the ta-C coating and MoSx reservoir in the remaining structure, as evidenced by Raman spectroscopy. The findings suggest that such combination allows for surfaces bearing a high load capacity that can be applied in both a vacuum and in air, for example, in multi-use space applications.
{"title":"Improved Tribological Performance of ta-C/MoSx Coatings Deposited on Laser Micro-Structured Steel Substrates in Both Vacuum and Air","authors":"S. Makowski, Fabian Härtwig, M. Soldera, Mahmoud Ojeil, L. Lorenz, Frank Kaulfuß, A. Lasagni","doi":"10.3390/lubricants12060200","DOIUrl":"https://doi.org/10.3390/lubricants12060200","url":null,"abstract":"Vacuum and air atmospheres impose very different requirements on tribological-loaded contacts, which usually require different surface materials. While hard tetrahedral amorphous carbon (ta-C) coatings provide good tribological properties in air, soft coatings such as molybdenum disulfide (MoS2) work well in a vacuum. Tribological performance in the respective other environment, however, is poor. In this work, the combination of laser microstructured (direct laser interference patterning) steel substrates and the deposition of ta-C and MoSx coatings with vacuum arc evaporation (LaserArc™) was studied, resulting in steel/DLIP, steel/DLIP/ta-C, steel/DLIP/MoSx, steel/DLIP/ta-C/MoSx, and steel/MoSx surface combinations. The tribological properties were studied using a ball-on-disk tribometer with a steel ball counter body in air and in a vacuum (p < 5 × 10−7 mbar). The type of the topmost coating governed their tribological properties in the respective atmosphere, and no general beneficial influence of the microstructure was found. However, steel/DLIP/ta-C/MoSx performed best in both conditions and endured the highest contact pressure, which is attributed to the mechanical support of the ta-C coating and MoSx reservoir in the remaining structure, as evidenced by Raman spectroscopy. The findings suggest that such combination allows for surfaces bearing a high load capacity that can be applied in both a vacuum and in air, for example, in multi-use space applications.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"4 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141281178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-01DOI: 10.3390/lubricants12060199
Yanfei Liu, Xiangyu Ge
Tribology is the science and engineering of interacting surfaces in relative motion [...]
摩擦学是研究相对运动中相互作用表面的科学和工程学 [...]
{"title":"Tribology of 2D Nanomaterials","authors":"Yanfei Liu, Xiangyu Ge","doi":"10.3390/lubricants12060199","DOIUrl":"https://doi.org/10.3390/lubricants12060199","url":null,"abstract":"Tribology is the science and engineering of interacting surfaces in relative motion [...]","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"28 10","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141276201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-17DOI: 10.3390/lubricants12050182
Xiaohan Lu, Min Zhu, Shengao Wang, Shengnan Li, Zi-jian Xu, Yilong Liu
Bolt connection structure is a common form of connecting large and complex equipment. Its object contact surfaces under normal and tangential loads will appear in the form of slip and adhesion, which affects the service life of mechanical equipment. Bolted connection structures cause changes in stiffness and damping, which have great impacts on the dynamic characteristics. Experimental studies and numerical simulations have difficulty predicting the overall performance of bolts in a timely manner, hence cannot ensure the reliability and safety of complex equipment. In order to improve the overall performance of complex equipment, it is necessary to study the contact theory model of bolt connection structures. Based on the relationship between friction force and velocity in the classical friction model, the mathematical expressions of restoring force and tangential displacement in the kinetic theory model are deduced to predict the stiffness degradation of the bolted structure and to characterise the kinetic properties and laws of the bolted structure. From the perspective of theoretical calculation, it makes up for the situation in which it is difficult to measure the performance of bolts due to the existence of spanning scale and provides theoretical support for the reliability of connecting complex equipment. This paper summarises and analyses the contact theory model of bolt connection structures, ranging from macroscopic to microscopic; describes the static friction model, kinetic friction model, statistical summation contact model, fractal contact model; and analyses the influencing factors of the microscopic contact mechanism. The advantages and disadvantages of the kinetic theoretical models are described, the manifestation of friction and the relationship between tangential force–displacement are discussed, and the key research directions of the kinetic theoretical models of bolted structures in the future are elucidated.
{"title":"Progress in Theoretical Modelling of Macroscopic and Microscopic Dynamics of Bolted Joints in Complex Equipment","authors":"Xiaohan Lu, Min Zhu, Shengao Wang, Shengnan Li, Zi-jian Xu, Yilong Liu","doi":"10.3390/lubricants12050182","DOIUrl":"https://doi.org/10.3390/lubricants12050182","url":null,"abstract":"Bolt connection structure is a common form of connecting large and complex equipment. Its object contact surfaces under normal and tangential loads will appear in the form of slip and adhesion, which affects the service life of mechanical equipment. Bolted connection structures cause changes in stiffness and damping, which have great impacts on the dynamic characteristics. Experimental studies and numerical simulations have difficulty predicting the overall performance of bolts in a timely manner, hence cannot ensure the reliability and safety of complex equipment. In order to improve the overall performance of complex equipment, it is necessary to study the contact theory model of bolt connection structures. Based on the relationship between friction force and velocity in the classical friction model, the mathematical expressions of restoring force and tangential displacement in the kinetic theory model are deduced to predict the stiffness degradation of the bolted structure and to characterise the kinetic properties and laws of the bolted structure. From the perspective of theoretical calculation, it makes up for the situation in which it is difficult to measure the performance of bolts due to the existence of spanning scale and provides theoretical support for the reliability of connecting complex equipment. This paper summarises and analyses the contact theory model of bolt connection structures, ranging from macroscopic to microscopic; describes the static friction model, kinetic friction model, statistical summation contact model, fractal contact model; and analyses the influencing factors of the microscopic contact mechanism. The advantages and disadvantages of the kinetic theoretical models are described, the manifestation of friction and the relationship between tangential force–displacement are discussed, and the key research directions of the kinetic theoretical models of bolted structures in the future are elucidated.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"56 14","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140965492","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-17DOI: 10.3390/lubricants12050180
Yongjing Zeng, Zichen Shang, Zeni Zheng, Ning Shi, Bo Yang, Sheng Han, Jincan Yan
In order to cope with the shortage of non-renewable energy and the increasingly environmental pollution, sustainable vegetable oils, as competitive alternatives, have widely been held in the good graces of the researchers. Vegetable oils are suitable for a wide range of applications such as biofuels and biodiesel. However, the development of vegetable oils is limited due to the characteristics of unsatisfactory oxidation stability and poor cold-flow properties. Chemical modification is considered as an effective solution to enhance the performance. The research progress of the chemical modification methods and applications of vegetable oils in recent years are summarized in this review. Reducing the content of carbon–carbon double bonds and increasing the degree of saturation are the keys to improve the physicochemical properties of vegetable oils. The prospects for the development direction and challenges of vegetable oils are proposed. Future research may focus on the use of multifunctional catalysts to optimize reaction conditions or to introduce active groups with lubricating properties in epoxidation reactions and explore the combination of chemical and auxiliary methods.
{"title":"A Review of Chemical Modification of Vegetable Oils and Their Applications","authors":"Yongjing Zeng, Zichen Shang, Zeni Zheng, Ning Shi, Bo Yang, Sheng Han, Jincan Yan","doi":"10.3390/lubricants12050180","DOIUrl":"https://doi.org/10.3390/lubricants12050180","url":null,"abstract":"In order to cope with the shortage of non-renewable energy and the increasingly environmental pollution, sustainable vegetable oils, as competitive alternatives, have widely been held in the good graces of the researchers. Vegetable oils are suitable for a wide range of applications such as biofuels and biodiesel. However, the development of vegetable oils is limited due to the characteristics of unsatisfactory oxidation stability and poor cold-flow properties. Chemical modification is considered as an effective solution to enhance the performance. The research progress of the chemical modification methods and applications of vegetable oils in recent years are summarized in this review. Reducing the content of carbon–carbon double bonds and increasing the degree of saturation are the keys to improve the physicochemical properties of vegetable oils. The prospects for the development direction and challenges of vegetable oils are proposed. Future research may focus on the use of multifunctional catalysts to optimize reaction conditions or to introduce active groups with lubricating properties in epoxidation reactions and explore the combination of chemical and auxiliary methods.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"40 13","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140965919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-16DOI: 10.3390/lubricants12050179
Haichao Liu, Haibo Zhang, Xiaoyu Ding
Advancements in contact mechanics play an important role in the design of modern mechanical and bio-medical systems, enhancing their efficiency, power density, and reliability [...]
{"title":"Advances in Contact Mechanics","authors":"Haichao Liu, Haibo Zhang, Xiaoyu Ding","doi":"10.3390/lubricants12050179","DOIUrl":"https://doi.org/10.3390/lubricants12050179","url":null,"abstract":"Advancements in contact mechanics play an important role in the design of modern mechanical and bio-medical systems, enhancing their efficiency, power density, and reliability [...]","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"59 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140970335","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-15DOI: 10.3390/lubricants12050178
R. Kreivaitis, Jolanta Treinytė, A. Kupčinskas, M. Gumbytė, E. Sendžikienė
Water-based lubricating fluids (WBLFs), known for their significant environmental benefits, are the focus of this study. The properties of WBLFs directly influence lubricated mechanisms’ longevity and operating efficiency. WBLFs are enhanced using additives, which must improve their properties and, at the same time, remain environmentally friendly. This study combines bis(2-hydroxyethyl) ammonium erucate protic ionic liquid and titanium oxide nanoparticles to formulate the hybrid additive. The lubricity was investigated using Alumina/Bearing steel and WC/Bearing steel friction pairs in a reciprocating ball-on-plate tribo-tester. The results show that protic ionic liquid can significantly improve lubricity and the corrosion-preventing ability of the base fluid. Applying a hybrid additive further improved the wear reduction ability in the WC/Bearing steel friction pair. However, the wear reduction ability was diminished when a hybrid additive was used to lubricate the Alumina/Bearing steel friction pair. The proposed lubricity improvement mechanism is based on forming an adsorption layer of ionic liquid molecules and rolling and tribo-sintering titanium oxide nanoparticles.
{"title":"Investigation of the Tribological Properties of Hybrid Additive-Modified Water-Based Lubricating Fluid","authors":"R. Kreivaitis, Jolanta Treinytė, A. Kupčinskas, M. Gumbytė, E. Sendžikienė","doi":"10.3390/lubricants12050178","DOIUrl":"https://doi.org/10.3390/lubricants12050178","url":null,"abstract":"Water-based lubricating fluids (WBLFs), known for their significant environmental benefits, are the focus of this study. The properties of WBLFs directly influence lubricated mechanisms’ longevity and operating efficiency. WBLFs are enhanced using additives, which must improve their properties and, at the same time, remain environmentally friendly. This study combines bis(2-hydroxyethyl) ammonium erucate protic ionic liquid and titanium oxide nanoparticles to formulate the hybrid additive. The lubricity was investigated using Alumina/Bearing steel and WC/Bearing steel friction pairs in a reciprocating ball-on-plate tribo-tester. The results show that protic ionic liquid can significantly improve lubricity and the corrosion-preventing ability of the base fluid. Applying a hybrid additive further improved the wear reduction ability in the WC/Bearing steel friction pair. However, the wear reduction ability was diminished when a hybrid additive was used to lubricate the Alumina/Bearing steel friction pair. The proposed lubricity improvement mechanism is based on forming an adsorption layer of ionic liquid molecules and rolling and tribo-sintering titanium oxide nanoparticles.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"60 7","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140975295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Temperature has a great influence on the stability of bearing performance. For the study of bearing steady-state temperature, this paper proposes a test method to quickly predict the steady-state temperature of the outer ring of a bearing, which solves the problems in traditional theoretical calculations and simulation analysis methods such as the large number of calculations, complex models, and large errors. Firstly, a mathematical prediction model is established according to the bearing temperature-rise law; then, a bearing steady-state temperature detection device is designed; and finally, the prediction model parameters are solved according to the experimental results, and experimental verification is carried out. It is shown that the prediction model has high accuracy under different load and speed conditions, and the error between the predicted steady-state temperature and the tested steady-state temperature is less than 0.7 °C. This prediction method reduces the single test time of the same speed to 60 min, which greatly improves the efficiency of the temperature detection test. The steady-state temperature model has important theoretical significance in guiding the study of the limiting speed of bearings.
{"title":"Test Method for Rapid Prediction of Steady-State Temperature of Outer Rings of Bearings under Grease Lubrication Conditions","authors":"Zhongbing Xia, Fang Yang, Xiqiang Ma, Nan Guo, Xiao Wang, Yunhao Cui, Yuchen Duan","doi":"10.3390/lubricants12050177","DOIUrl":"https://doi.org/10.3390/lubricants12050177","url":null,"abstract":"Temperature has a great influence on the stability of bearing performance. For the study of bearing steady-state temperature, this paper proposes a test method to quickly predict the steady-state temperature of the outer ring of a bearing, which solves the problems in traditional theoretical calculations and simulation analysis methods such as the large number of calculations, complex models, and large errors. Firstly, a mathematical prediction model is established according to the bearing temperature-rise law; then, a bearing steady-state temperature detection device is designed; and finally, the prediction model parameters are solved according to the experimental results, and experimental verification is carried out. It is shown that the prediction model has high accuracy under different load and speed conditions, and the error between the predicted steady-state temperature and the tested steady-state temperature is less than 0.7 °C. This prediction method reduces the single test time of the same speed to 60 min, which greatly improves the efficiency of the temperature detection test. The steady-state temperature model has important theoretical significance in guiding the study of the limiting speed of bearings.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"91 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140973483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-14DOI: 10.3390/lubricants12050175
Juan Xu, Bin Ma, Weiwei Chen, Chengwei Shan
The remaining useful life (RUL) of bearings is vital for the manipulation and maintenance of industrial machines. The existing domain adaptive methods have achieved major achievements in predicting RUL to tackle the problem of data distribution discrepancy between training and testing sets. However, they are powerless when the target bearing data are not available or unknown for model training. To address this issue, we propose a single-source domain generalization method for RUL prediction of unknown bearings, termed as the adaptive stage division and parallel reversible instance normalization model. First, we develop the instance normalization of the vibration data from bearings to increase data distribution diversity. Then, we propose an adaptive threshold-based degradation point identification method to divide the healthy and degradation stages of the run-to-failure vibration data. Next, the data from degradation stages are selected as training sets to facilitate the RUL prediction of the model. Finally, we combine instance normalization and instance denormalization of the bearing data into a unified GRU-based RUL prediction network for the purpose of leveraging the distribution bias in instance normalization and improving the generalization performance of the model. We use two public datasets to verify the proposed method. The experimental results demonstrate that, in the IEEE PHM Challenge 2012 dataset experiments, the prediction accuracy of our model with the average RMSE value is 1.44, which is 11% superior to that of the suboptimal comparison model (Transformer model). It proves that our model trained on one-bearing data achieves state-of-the-art performance in terms of prediction accuracy on multiple bearings.
{"title":"AsdinNorm: A Single-Source Domain Generalization Method for the Remaining Useful Life Prediction of Bearings","authors":"Juan Xu, Bin Ma, Weiwei Chen, Chengwei Shan","doi":"10.3390/lubricants12050175","DOIUrl":"https://doi.org/10.3390/lubricants12050175","url":null,"abstract":"The remaining useful life (RUL) of bearings is vital for the manipulation and maintenance of industrial machines. The existing domain adaptive methods have achieved major achievements in predicting RUL to tackle the problem of data distribution discrepancy between training and testing sets. However, they are powerless when the target bearing data are not available or unknown for model training. To address this issue, we propose a single-source domain generalization method for RUL prediction of unknown bearings, termed as the adaptive stage division and parallel reversible instance normalization model. First, we develop the instance normalization of the vibration data from bearings to increase data distribution diversity. Then, we propose an adaptive threshold-based degradation point identification method to divide the healthy and degradation stages of the run-to-failure vibration data. Next, the data from degradation stages are selected as training sets to facilitate the RUL prediction of the model. Finally, we combine instance normalization and instance denormalization of the bearing data into a unified GRU-based RUL prediction network for the purpose of leveraging the distribution bias in instance normalization and improving the generalization performance of the model. We use two public datasets to verify the proposed method. The experimental results demonstrate that, in the IEEE PHM Challenge 2012 dataset experiments, the prediction accuracy of our model with the average RMSE value is 1.44, which is 11% superior to that of the suboptimal comparison model (Transformer model). It proves that our model trained on one-bearing data achieves state-of-the-art performance in terms of prediction accuracy on multiple bearings.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"26 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140979521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lubricants must exhibit good tribological behavior at low temperatures to ensure reliable startups in very cold regions. This study investigates the performance of lubricants, with a specific focus on their capacity for high-temperature lubrication and ensuring reliable low-temperature startup in engines. Experiments were conducted to assess the friction and wear characteristics of polydiethylsiloxane in conjunction with a Si3N4 ball and M50 (8Cr4Mo4V) steel across a temperature range of −80 °C to 25 °C. The results indicate that the coefficient of friction, as determined through friction and wear tests at various temperatures, remained below 0.1. As temperatures progressively decreased, the system’s friction coefficient increased, and wear volumes recorded at 25 °C and −60 °C were 9749.513 µm³ and 105.006 µm³, respectively, culminating in lubrication failure at −100 °C. This failure is primarily attributed to the increased viscosity and decreased mobility of polydiethylsiloxane at extremely low temperatures. Additionally, the reduced temperature increases the strength of the quenched steel, leading to hard particles or protrusions on the material’s surface, which collide with the Si3N4 ball during friction, causing adhesion and spalling. Despite this, polydiethylsiloxane forms a stable protective oil film on the surface, enhancing the system’s lubrication performance. However, below −80 °C, this oil film begins to tear, leading to diminished lubrication efficacy. This study provides valuable data supporting the field of cryogenic lubrication.
润滑油必须在低温条件下表现出良好的摩擦学性能，以确保在极寒地区可靠启动。本研究调查了润滑油的性能，重点关注其高温润滑和确保发动机可靠低温启动的能力。实验评估了聚二乙基硅氧烷与 Si3N4 球和 M50 (8Cr4Mo4V) 钢在 -80 °C 至 25 °C 温度范围内的摩擦和磨损特性。结果表明，在不同温度下通过摩擦和磨损测试确定的摩擦系数一直低于 0.1。随着温度逐渐降低，系统的摩擦系数增大，在 25 °C 和 -60 °C 时记录的磨损量分别为 9749.513 µm³ 和 105.006 µm³，最终在 -100 °C 时润滑失效。润滑失效的主要原因是聚二乙基硅氧烷在极低温度下粘度增加，流动性降低。此外，温度降低会增加淬火钢的强度，导致材料表面出现硬质颗粒或突起，在摩擦过程中与 Si3N4 球碰撞，造成粘附和剥落。尽管如此，聚二乙基硅氧烷仍能在表面形成一层稳定的保护油膜，提高系统的润滑性能。然而，当温度低于 -80 °C 时，油膜会开始撕裂，导致润滑效果降低。这项研究为低温润滑领域提供了宝贵的数据支持。
{"title":"Tribological Behavior of Polydiethylsiloxane (PDES) in a Si3N4 and M50 System under Low Temperatures from −80 to 25 °C","authors":"Junhao Han, Yong Tang, Luo Yue, Xianzhen Ma, Hao Jia, Ningxia Liu, Pengpeng Bai, Yonggang Meng, Yu Tian","doi":"10.3390/lubricants12050176","DOIUrl":"https://doi.org/10.3390/lubricants12050176","url":null,"abstract":"Lubricants must exhibit good tribological behavior at low temperatures to ensure reliable startups in very cold regions. This study investigates the performance of lubricants, with a specific focus on their capacity for high-temperature lubrication and ensuring reliable low-temperature startup in engines. Experiments were conducted to assess the friction and wear characteristics of polydiethylsiloxane in conjunction with a Si3N4 ball and M50 (8Cr4Mo4V) steel across a temperature range of −80 °C to 25 °C. The results indicate that the coefficient of friction, as determined through friction and wear tests at various temperatures, remained below 0.1. As temperatures progressively decreased, the system’s friction coefficient increased, and wear volumes recorded at 25 °C and −60 °C were 9749.513 µm³ and 105.006 µm³, respectively, culminating in lubrication failure at −100 °C. This failure is primarily attributed to the increased viscosity and decreased mobility of polydiethylsiloxane at extremely low temperatures. Additionally, the reduced temperature increases the strength of the quenched steel, leading to hard particles or protrusions on the material’s surface, which collide with the Si3N4 ball during friction, causing adhesion and spalling. Despite this, polydiethylsiloxane forms a stable protective oil film on the surface, enhancing the system’s lubrication performance. However, below −80 °C, this oil film begins to tear, leading to diminished lubrication efficacy. This study provides valuable data supporting the field of cryogenic lubrication.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"14 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140981854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-12DOI: 10.3390/lubricants12050174
A. Vasilev, A. Dyakonov, S. N. Danilova, Igor S. Makarov, Anastasia V. Okoneshnikova, A. Okhlopkova
In this study, the tribological properties of nanocomposites based on ultra-high molecular weight polyethylene (UHMWPE) filled with nano-CuO and 2-mercaptobenzothiazole (CuO/MBT) in mass ratios of 1:1 and 2:1 were investigated. In the supramolecular structure of UHMWPE nanocomposites, spherulites of several hundred micrometers in size are formed. The density of UHMWPE nanocomposites slightly increases relative to the pure polymer, reaching a maximum at 2 wt.% CuO/MBT in both ratios. The Shore D hardness and compressive stress of the UHMWPE nanocomposites showed an improvement of 5–6% and 23–35%, respectively. The wear resistance and coefficient of friction of UHMWPE nanocomposites were tested using a pin-on-disk configuration under dry friction conditions on #45 steel and on P320 sandpaper. It was shown that the wear rate of UHMWPE nanocomposites filled with 2 wt.% CuO/MBT decreased by ~3.2 times compared to the pure polymer, and the coefficient of friction remained at the level of the polymer matrix. Abrasive wear showed an improvement in UHMWPE nanocomposites filled with 1 wt.% CuO/MBT compared to the polymer matrix and other samples. The worn surfaces of the polymer composites after dry friction were examined by scanning electron microscopy and IR spectroscopy. The formation of secondary structures in the form of tribofilms that protect the material from wear was demonstrated. Due to this, the wear mechanism of UHMWPE nanocomposites is transformed from adhesive to fatigue wear. The developed materials, due to improved mechanical and tribological properties, can be used as parts in friction units of machines and equipment.
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